Chemical Engineering Commons^™

Adsorption Of Pfas On Bridged Functionalized Organosilica Materials, Elisha Lawerh Kabutey

Electronic Theses and Dissertations

PFAS are hazardous contaminants that have a devastating impact on human health and the environment. Their hazardous nature has led to the development of various adsorption methods for removing these contaminants from water sources. In this study, functionalized organosilica materials were synthesized from bis[3-(trimethoxysilyl)propyl] amine using the sol-gel method. The surface amino groups of the organosilica were converted into amine hydrochloride groups. Their adsorption properties were evaluated using salts of perfluorooctanoic acid, perfluorooctanesulfonic acid, and perfluorobutanesulfonic acid. Results showed excellent adsorption capacity of the materials. Adsorption of PFAS leads to particle agglomeration and flotation of the spent material. A column …

Equilibration And Transport Of Binary Mixtures On Planar And Porous Nanomaterials, Andrew Torres

Electronic Theses and Dissertations

We present results of a Kinetic Monte Carlo investigation of the adsorption dynamics of binary gas mixtures on planar and porous sorbents, with a focus on identifying and characterizing kinetic processes involved in uptake evolution and how they influence equilibrium conditions. We also investigate varying thermodynamic simulation parameters such as interactions, alkane lengths, partial pressures and pore configurations to determine how they impact these kinetic processes as well as equilibrium properties. This study matters both for better understanding how kinetics and equilibrium are connected and for improving practical techniques in separation applications. For planar surfaces, weak species overshoot kinetic processes …

Nickel Electrocatalysts On Carbon Supports For The Hydrogen Evolution Reaction., Mohan Paudel

Electronic Theses and Dissertations

Hydrogen is an important energy storage alternative to fossil fuels due to its high energy density. Currently, most hydrogen is produced through petroleum feedstocks, which produce large amounts of carbon dioxide. However, a more eco-friendly method is the electrocatalytic splitting of water into hydrogen and oxygen. Efficient catalysts for the hydrogen evolution reaction (HER) are typically platinum group metals, which are rare and expensive. There is growing interest in developing HER electrocatalysts with earth-abundant metals for water electrolysis. Nickel, which lies in the same group in the periodic table as Pt and has similar chemical properties, is explored extensively for …

High Energy Density Lithium-Ion Battery Materials., Rachel Dewees

Electronic Theses and Dissertations

Growth of the EV industry has created an increased demand for Li-ion battery electrode materials, and support of a robust lithium-ion battery supply chain is a national imperative. For mainstream acceptance in the American market, the range of EVs must be improved, i.e., the energy density of the battery must be increased. Increasing the specific capacity of the electrode materials is the most direct strategy for increasing the energy density of the battery. Silicon anode materials have a theoretical capacity of over 3700 mAh·g^-1 - an order of magnitude beyond that of the graphitic materials which are currently implemented. …

The Use Of Peracetic Acid And The Advanced Oxidation Process In Water Purification., Spencer Shipman

Electronic Theses and Dissertations

The Next Round Brewing project was a project that sought to use treated wastewater to make potable drinking water using peracetic acid (PAA) and the advanced oxidation process and break the stigma around reclaimed water. In experiments, PAA was an efficient biocide which reduced the level of pathogens to within EPA standards. When PAA was coupled with the advanced oxidation process all organic matter was also reduced to within acceptable levels, and no biocide was left over in the final product, meaning PAA properly dissociated into harmless byproducts. A series of experiments are presented that vary concentrations of PAA, effluent …

Biocargos: Capture And Release Gels For Room Temperature Cell Storage., Justin Jacobson

Electronic Theses and Dissertations

Currently, cryovials on dry ice or liquid nitrogen vapor transportation vessels are primary ways utilized to transport mammalian cells from one location to another. Due to the safety concerns of dry ice and liquid nitrogen, associated costly shipping charges, and limitations of proper packaging and labeling of materials, these conventional shipping techniques are unacceptable. It is urgent to develop a safe and environmentally friendly protocol to preserve and ship the biological samples from one place to another. In this research, a method was developed for an ecofriendly and safe protocol to preserve cancer cells. The cell viability of cell line …

Analysis Of The Relationship Between Flow Patterns In The Post-Stenotic Region Of Model Arteries And Stenosis Severity., Michael Laroche

Electronic Theses and Dissertations

In this study, contour fields of mean age and turbulence kinetic energy (TKE) in the post-stenotic region of model arteries were analyzed to explore their correlation with FFR. While both high and low FFR cases exhibited similarities with an inner low-age region and an outer high-age region, low FFR cases displayed asymmetry in their low-age regions due to eccentric stenosis. Moreover, gradients of age across the artery diameter were more pronounced for low FFR cases. Additionally, low FFR cases demonstrated significantly higher TKE in the post-stenotic blood jet stream compared to high FFR cases that are reflected in low-age boundary …

Carboxen Micropreconcentrator Performance For Analyzing Btex In Air., Raymond Daniel Spargo

Electronic Theses and Dissertations

Volatile Organic Compounds (VOCs) are a class of toxic chemicals in environmental air associated with several serious health risks. Some of the most common and concerning VOCs are Benzene, Toluene, Ethyl Benzene, and Xylene (BTEX). To maintain healthy air quality in these environments, researchers pursue instruments and processes to quickly and accurately predict sub-ppb concentrations of BTEX in indoor and outdoor air. By employing a micropreconcentrator (μPC) to combine Solid-Phase Micro-Extraction (SPME) with Gas Chromatography Mass Spectrometry (GC-MS) analysis, trace BTEX content in air samples can be captured, extracted and analyzed. In this thesis, a dual-compartment μPC with Carboxen 1000 …

Constant-Ph Molecular Dynamics At Inorganic Interfaces: Adding A New Dimension To Simulations Of Interfacial Phenomena., Ted Kalbfleisch

Electronic Theses and Dissertations

This dissertation explores the application of novel molecular dynamics simulation methods to better understand complex systems, with a particular focus on silica materials and protein interactions. Silica materials, known for their versatile surface and solution chemistries, play critical roles in catalysis, chromatography, and wastewater treatment. Despite their widespread use, the molecular-level interactions between silica surfaces and their environments remain poorly understood. To address this knowledge gap, we employed λ-dynamics enabled constant pH molecular dynamics to dynamically model protonation and deprotonation events on silica surfaces. Traditional experimental techniques such as x-ray crystallography, NMR, and cryo-EM are inadequate for probing structures in …

Natural Fiber Reinforced Composites For Sustainable Additive Manufacturing., Athira Nair Surendran

Electronic Theses and Dissertations

Carbon fiber is widely known for its exceptional strength, making it a sought-after material in composite manufacturing, especially with thermosets and thermoplastics. Its major applications span aerospace, wind turbines, sports equipment, automotive interior and exterior parts, robotics and medical equipment. Recently, carbon fiber filament manufacturing has gained attention due to the availability of desktop 3D printers and the versatility and customizability that comes with the realm of 3D printing. Commercial carbon fiber production, primarily from polyacrylonitrile (PAN), is energy-intensive and derived from crude oil, contributing to significant environmental impacts and poor recyclability. Alternatively, lignocellulosic natural fibers present a possible sustainable …

Smart Manufacturing Of Cement: From Lab-Scale Simulation And Testing To Industry-Scale Deployment., Juan David Tabares Tamayo

Electronic Theses and Dissertations

Cement kilns are controlled by experienced process operators who follow experience-based industry guidelines using data collected and fundamental knowledge. The manufacturing process, which is equipped with sensors and equipment, transfers data/information to the operators to aid standardized decision-making operations. In contrast, companies have used such data to develop and implement digital solutions for predictive control systems; in effect, FLSmidth and Rockwell Automation. However, despite the availability of automated control systems and investigation in automation for process monitoring and optimization, opportunities to radically optimize cement manufacturing are still abundant and in need of implementation. Therefore, this research developed simulation models and …

Mechanical Property Simulations Of Ploybenzimidazole Membranes., Blake Alexander Clark

Electronic Theses and Dissertations

This work explores mechanical properties of membranes made of polybenzimidazole utilizing molecular simulations. These simulations researchers to narrow down polybenzimidazole membrane compositions to viable candidates. These simulations are quicker than current purely experimental methods. The increase in throughput would be achieved by eliminating compositions that have unfavorable mechanical properties through preliminary simulation work before moving onto experimental methods. Determining polybenzimidazole membranes’ mechanical properties experimentally would, therefore, allow for researchers to speed up research in areas such as fuel cells and electrolyzers that make use of polybenzimidazole membranes. This study uses Materials Studio and the COMPASS III forcefield to perform these …

Thermal, Electrical, And Spin Transport: Encompassing Low-Damping Ferromagnets And Antiferromagnetic/Ferromagnetic Heterostructures, Matthew Ryan Natale

Electronic Theses and Dissertations

Continuing technological advancements bring forth escalating challenges in global energy consumption and subsequent power dissipation, posing significant economic and environmental concerns. In response to these difficulties, the fields of thermoelectrics, spintronics, and spincaloritronics emerge as contemporary solutions, each presenting unique advantages. Thermoelectric devices, based on the Seebeck effect, other a passive, carbon-free energy generating solution from waste heat. Although current thermoelectric technology encounters hurdles in achieving optimal efficiencies without intricate designs or complex materials engineering, recently research into low-damping metallic ferromagnetic thin films have provided a new method to enhance spin wave lifetimes, thus contributing to thermoelectric voltage improvements. As …

Air-Jet Bioprinting Of Stem Cell-Encapsulated Alginate Micro-Droplets For Organoid Biomanufacturing, Mirabella B. Stump

Electronic Theses and Dissertations

Biomanufactured 3D-organoids show promise for modeling and treating various conditions, particularly insulin-dependent diabetes mellitus (type-1 diabetes). Pancreatic islet organoids serve as sustainable sources of insulin-producing β-cells, potentially restoring insulin regulation in patients and providing a long-term solution for diabetes. Hydrogel droplet printing is an emerging technique in regenerative medicine due to its advantageous tunability and biocompatibility; however, challenges of consistency, quality control, and scalability persist. To address these issues, we developed a novel air-jetting based droplet bioprinting system for the generation of monodispersed alginate micro-droplets. The objective of this project was to incorporate human induced pluripotent stem cells (hiPSCs) into …

Addition Of Process Control Experiment To Unit Operations Ii Laboratory., Bradley Esselman

Electronic Theses and Dissertations

Process control is an essential aspect of manufacturing, contributing to improved process safety, efficiency, product consistency, and energy optimization. Chemical engineers are often responsible for ensuring the safe, efficient, and cost-effective operation of industrial processes, and process control plays a pivotal role in accomplishing this.

Chemical engineering students at the University of Louisville complete the course, Elements of Process Control, during the second semester of their fourth year. This lecture-based course offers limited hands-on, practical experience. To supplement the lack of hands-on experience in the classroom, a new process control experiment was designed and implemented into the Unit Operations …

Novel Breath Collection Techniques For Detection Of Covid-19., James Morris

Electronic Theses and Dissertations

Volatile Organic Compounds (VOC) generated endogenously in the human body can be used to detect diseases that induce oxidative stress and inflammation. Breath analysis has been used for the detection of diseases such as COPD, Depression, Lung Cancer and most recently COVID-19. Methods such as Exhaled Breath Condensate (EBC), Sorbent Tubes, Solid Phase Microextraction (SPME), and silicon microreactors have shown considerable capability in extracting and concentrating trace VOC’s present in human breath. Silicon microreactors functionalized with capture agents to derivatize carbonyl compounds are effective but the overall maximum flow rate of breath sample possible during analysis is low, making direct …

Novel Microdevices To Analyze Toxic Volatile Organic Compounds., Sujoy Halder

Electronic Theses and Dissertations

There has been a growing interest to measure volatile organic compounds (VOCs) in a range of environmental applications. The presence of toxic VOCs in the air has been associated with serious health problems including asthma, central nervous system dysfunction, cardiovascular disease and cancer, etc. Different analytical instruments such as gas chromatography-mass spectrometry (GC-MS) and sensor systems, such as metal oxide sensors are used to analyze VOCs. However, challenges still exist in the detection of airborne VOCs because of their trace concentration and interference with complex gas mixtures. In this dissertation, two microfabricated devices, a sensor array and a micropreconcentrator were …

Investigation Of Light Management Strategies And Photochemistry Of Si/Tio2 Tandem Microwire Slurries For Solar Hydrogen Generation., Saumya Gulati

Electronic Theses and Dissertations

The intermittent nature of the Sun makes it difficult to use it as a primary source of electricity and often needs to be supplemented by electricity from the grid which comes from fossil fuels. This motivates the need for solar energy storage. Photoelectrochemical (PEC) water-splitting has been explored as a means to convert solar energy into hydrogen (and oxygen), which can be stored as fuel. The current method of coupling PV and electrolyzer units has been widely commercialized, however, the cost of H₂ generated is far from the target of $1/kg set by the DOE under the Energy EarthShot …

Detection Of Toxic Aldehydes In Aerosols Of Electronic Cigarettes., Ellie Bess Reed

Electronic Theses and Dissertations

Over the past decade, use of electronic cigarettes (e-cigarettes) has increased in the younger generations of the United States. With the broad range of flavors and devices distributed on the market, American youth are prime marketing targets for the e-cigarette industry. To create a more regulated market, research of this thesis has been conducted on newer generations of e-cigarette “MOD” devices to examine how e-cigarette battery power output and coil temperature, concentrations of propylene glycol and vegetable glycerin, added flavorings (strawberry, mango, and menthol), and the presence of nicotine affect generation of aerosol particles and aldehydes in aerosols emitted by …

The Study Of Corrosion On Additive-Manufactured Metals., Braydan Daniels

Electronic Theses and Dissertations

The purpose of this study was to investigate and compare the corrosion mechanisms between wrought and additive-manufactured (3D-printed) copper and stainless steel. The experimental procedure consisted of measuring the open circuit potential, electrochemical impedance spectroscopy, linear sweep voltammetry, Tafel analysis, surface topology, and scanning electron microscopy for each metal within salt water, tap water, sulfuric acid, and synthetic body fluid (excluding copper in synthetic body fluid).

Overall, printed stainless steel was more corrosion-resistant than wrought stainless steel in tap water and synthetic body fluid based on OCP, LSV, and surface topology results. Additionally, printed copper was more corrosion-resistant than wrought …

Synthesis, Property Tuning And Degradation Studies Of Phosphorene-Based Materials., Usman Onuminya Abu

Electronic Theses and Dissertations

Two-dimensional (2D) layered materials have sparked the interest of researchers because of their interesting properties drawn from quantum confinement effects, elevated density of states (DOS), increased surface area, increased active sites, etc. Phosphorene, an interesting addition to the 2D material family in 2014, has interesting properties such as in-plane anisotropy, elevated carrier mobility and thickness-dependent bandgaps that have made it a material of intense interest. Furthermore, there have been theoretical studies predicting that phosphorene could be made even more versatile by intercalating alkali atoms into its layers. Intercalation has proven to be a veritable tool for synthesis, modification, transformation, and …

Compositional Engineering Of Precursor Inks For Intense Pulsed Light Compatible Deposition Of Perovskite Solar Cells., Blake Martin

Electronic Theses and Dissertations

Perovskite solar cell (PSC) technology offers a promising alternative to silicon-based photovoltaics (PVs), but challenges of stability, module efficiency, and scalability hinder commercialization. This study aims to explore potential solutions to overcome scalability and cost limitations of PSCs, addressing technical barriers to commercialization. We adapt the conventional three-stage perovskite deposition process (deposition, translational phase formation, and annealing) for scalable platforms using wide-area depositions, meniscus coating methods, forced laminar airflow drying, and radiative annealing methods, making it more suitable for roll-to-roll fabrication. A technoeconomic analysis shows that large-scale operations can produce solar films at a cost of $0.04-$0.10 per watt, making …

Chloramine Devulcanization Of Waste Rubber., Patrick Kroeger

Electronic Theses and Dissertations

The disposal of waste rubber, particularly tire rubber, continues to pose a challenge in the 21st century. As a result, most end-of-life tires (ELTs) are either dumped in landfills or burned as tire-derived fuel. Chloramine devulcanization may offer a viable solution to this problem. Chloramine devulcanization is a low-temperature, low-pressure, process that selectively breaks sulfur crosslinks while preserving the polymer backbone. Chloramine devulcanization enables the recovery of chloramine recovered carbon black (CrCB) and devulcanized rubber (CdR) as separate products. Initial analysis of CdR revealed that it was formable and malleable, suggesting that crosslinking was absent. Spectroscopy showed that CdR contained …

Evaluating The Impact Of Increased Cycling On Thermal Power Plants Due To Wind Energy Penetration In The Midwest: A Case Study, Joscelyne Larson

Electronic Theses and Dissertations

One of the most significant shifts in the mix of U.S. electricity generation over the past few years has been the rapid expansion of renewable energy resources, especially solar and wind. However, fossil fuels are still necessary to fulfill the world’s energy requirements. Despite efforts to increase the use of renewable energy sources, these sources can be at times unreliable, causing countries around the world to continue to rely on base load units such as coal and natural gas. This decrease in fossil fuels and increase in renewable energy sources presents many complex issues in terms of power system planning, …

Anion Alloying Of Iii-V Semiconductors For Water Splitting., Sonia Calero-Barney

Electronic Theses and Dissertations

The challenge of solar energy conversion and storage translates into the discovery and development of semiconductor materials that can transform sunlight energy into electricity and/or high-energy-density fuels in a cost-effective way. From the solar energy conversion perspective, cation-alloyed III-V solar cells hold record-breaking energy conversion efficiencies, while anion-alloyed III-V’s are particularly interesting for photoelectrochemical hydrogen generation. The major challenge for the adoption of III-V-based technologies lies in the high manufacturing costs of established synthesis techniques and the difficulty to control the composition of ternary alloys. One of the materials investigated in this work is GaSb_zP_1-z. Thermodynamic …

Surface-Functionalized Chemiresistive Films That Exploit H-Bonding, Cation-Pi, And Metal-Halide Interactions., Prasadanie Karunarathna Adhihetty

Electronic Theses and Dissertations

The development of gas sensors for detection of volatile organic compounds (VOCs) has been of interest in the sensing field for decades. To date, the use of metal nanoparticle-based chemiresistors for trace VOC detection, particularly gold nanoparticle-based sensors, is of great interest due to their high chemical stability, ease of synthesis, unique optical properties, large surface to volume ratio, and high level of conductivity. Much effort has been devoted towards gold monolayer protected clusters (Au MPCs) as chemiresistors to detect harmful VOCs. The present thesis documents the results of our efforts to exploit the advantages of functionalized Au MPCs chemiresistors …

Structural, Charge Transport, Gas Sensing, Magnetic, Pseudocapacitive, And Electrocatalytic Properties Of Perovskite Oxides., Surendra Bahadur Karki

Electronic Theses and Dissertations

Perovskites are functional materials with the general formula ABO₃ (A = alkali, alkaline earth or lanthanoid cations and B = transition metal or main group cations). These materials are marked by a variety of crystal structures and interesting properties such as colossal magnetoresistance, ferroelectricity, multiferroicity, superconductivity, pseudocapacitance, gas sensing, charge transport, and electrocatalytic properties. The formula of perovskite can be written as AA’BB’O₆, when there is ordering between two cations over A and B-sites. Such compounds are called double perovskite oxides. Some amount of oxygen could be lost from crystal structure without decomposition of the phase. Such …

Engineering Lewis Acidic Materials For Biomass Conversion And Battery Applications., Md Anwar Hossain

Electronic Theses and Dissertations

My long-term goal is to develop catalytic systems to produce renewable energy for a sustainable society. The overall research objective of my dissertation is to advance understanding of Lewis acidic materials for (1) conversion of renewable lignin into phenolics and (2) enhanced cycling stability of lithium metal batteries to safely store renewable electricity from wind and solar, thereby laying the groundwork for our transition to a sustainable society. Petroleum is a conventional feedstock for current transportation fuels (gasoline, diesel, and jet fuels). However, petroleum is a finite resource and produces greenhouse gases (CO₂ and CH₄) upon processing, …

Materials And Interfaces For Electrocatalytic Hydrogen Production And Utilization., Alexander Jiya Gupta

Electronic Theses and Dissertations

Mass industrialization over the last few centuries has created a global economy which is dependent upon fossil fuels to satisfy an exponentially increasing demand for energy. Aside from the possible depletion of this finite resource, the combustion of fossil fuels releases greenhouse gases into the atmosphere which cause the global temperature to rise – a phenomenon which has already begun to create geologic and geopolitical instability and shows no signs of abatement. One proposed method to rid humanity of its dependence on fossil fuels is to use green hydrogen as an energy carrier. In this scheme, excess electricity from a …

Development Of Porous Solid Acid Catalysts For Lignocellulose And Plastic Upcycling., Mohammad Shahinur Rahaman

Electronic Theses and Dissertations

My goal is to develop chemical processes for transforming waste to solve environmental problems and enhance sustainability. Environmental problems such as pollution and massive amounts of waste are the main drivers that stimulate my research ideas. I focused on creating novel, efficient catalytic processes for converting polymeric waste "feedstocks" into high-value chemicals by integrating my expertise in catalysis, materials science, and synthetic chemistry to develop porous solid catalytic materials. During my Ph.D., I focused on two polymeric feedstocks, lignocellulose, and discarded plastic.

Early in my Ph.D. journey, I focused on catalytic upcycling of lignocellulose. Lignocellulosic biomass is cost-effective, abundant, and …