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Articles 1 - 30 of 2277
Full-Text Articles in Chemical Engineering
Analysis And Study Of The Content Of Chloride Salts In Oil, Natalia Evgenievna Sheina, Muborak Akramovna Mirshomilova
Analysis And Study Of The Content Of Chloride Salts In Oil, Natalia Evgenievna Sheina, Muborak Akramovna Mirshomilova
Technical science and innovation
The article addresses the critical issue of crude oil quality control, specifically focusing on the determination of chloride salts (sodium, calcium, and magnesium), which exert a destructive impact on processing equipment. The paper provides a detailed analysis of the adverse effects of salts, which lead to severe equipment corrosion, scaling, and a reduced yield of valuable oil fractions. The chemical principles and specific applications of two standardized methods for analyzing aqueous extracts according to GOST 21534-2021 and ASTM D3230 are described: indicator (argentometric and mercurimetric) and potentiometric titration. The experimental section presents the results of a comparative analysis of crude …
Voltage-Related Power Quality Issues And Impacts On Distribution Networks With Sensitive Loads - A Review, Godwin Elinazi Mnkeni, Jackson Justo, Aviti Thadei Mushi, Bakari M. M. Mwinyiwiwa
Voltage-Related Power Quality Issues And Impacts On Distribution Networks With Sensitive Loads - A Review, Godwin Elinazi Mnkeni, Jackson Justo, Aviti Thadei Mushi, Bakari M. M. Mwinyiwiwa
Tanzania Journal of Engineering and Technology (TJET)
Voltage disturbances are the most important power quality (PQ) complications that customers and power utilities face in this smart era. The growing adoption of sophisticated electronic equipment and integration of renewable energy sources (RES) into power grids has increased the susceptibility of power distribution networks (PDNs) to voltage sags, swells, interruptions, flicker, and voltage imbalance. These disturbances, mainly caused by upstream faults, switching operations, and RES integration, compromise voltage PQ and system reliability. Consequently, they accelerate equipment degradation, increase electronic waste (e-waste), raise reactive power demand and maintenance costs, increase power losses, and impose substantial economic losses on customers and …
Feasibility Of Acetylated Icacina Trichantha Oliv. Tuber Starch As Viscosity And Fluid Loss Control Agents In Water-Based Drilling Mud. A Comparative Assessment With Commercial Starch, Kennedy I. Ogunwa, Theresa O. Uchechukwu, Ozioma Achugasim, Leo C. Osuji, Onyewuchi Akaranta
Feasibility Of Acetylated Icacina Trichantha Oliv. Tuber Starch As Viscosity And Fluid Loss Control Agents In Water-Based Drilling Mud. A Comparative Assessment With Commercial Starch, Kennedy I. Ogunwa, Theresa O. Uchechukwu, Ozioma Achugasim, Leo C. Osuji, Onyewuchi Akaranta
Tanzania Journal of Science
The need for sustainable, non-food drilling fluid additives has prompted the feasibility assessment of acetylated Icacina trichantha tuber starch as a viscosity modifier and fluid loss control agent in water-based muds. Native starch was acetylated to obtain two derivatives (Degree of Substitution DS = 0.38 and 0.68) and characterized using FTIR, swelling power, and physicochemical analyses. Drilling mud performance was assessed through rheology, gel strength, filtration loss, sorptivity, and model fitting. Acetylation improved swelling and reduced gelatinization temperature. The optimal formulation, Mud-ITO-ACS2 (DS = 0.68), exhibited the most favorable performance, combining low plastic viscosity (6 cP vs 9 cP for …
Effect Of Acid Pretreatment On The Adsorption Of Phenol Red By Cellulose Isolated From Sandbox (Hura Crepitans L.): Kinetics, Isotherms And Thermodynamics, Muibat O. Alabi-Abass, Najeem A. Adesola Babarinde, Adeola A. Ibikunle, Nurudeen O. Sanyaolu
Effect Of Acid Pretreatment On The Adsorption Of Phenol Red By Cellulose Isolated From Sandbox (Hura Crepitans L.): Kinetics, Isotherms And Thermodynamics, Muibat O. Alabi-Abass, Najeem A. Adesola Babarinde, Adeola A. Ibikunle, Nurudeen O. Sanyaolu
Tanzania Journal of Science
The removal of synthetic dyes from wastewater remains an urgent environmental concern due to their persistence and toxicity. This study evaluates cellulose from Hura crepitans (HC) and its acid-modified form (AHC) for the adsorption of phenol red (PR) dye from aqueous solutions. The adsorbents were characterized using FTIR to identify functional groups responsible for dye binding, XRD to determine the crystalline structure, SEM to examine surface morphology, and BET/BJH analyses to measure surface area and pore distribution. Acid modification enhanced surface roughness, porosity, and the abundance of active functional sites, leading to improved adsorption efficiency. Optimal conditions were pH 9.0 …
Molecular Identification Of Tannase-Producing Microbiota From Punica Granatum L. Peel, Ulugbek A. Suyundikov, Quchqor O. Dodayev, Munavvar A. Yakhyayeva, Zahro R. Akhmedova Akhmedova
Molecular Identification Of Tannase-Producing Microbiota From Punica Granatum L. Peel, Ulugbek A. Suyundikov, Quchqor O. Dodayev, Munavvar A. Yakhyayeva, Zahro R. Akhmedova Akhmedova
CHEMISTRY AND CHEMICAL ENGINEERING
Pomegranate (Punica granatum L.) is a rich source of bioactive compounds, including polyphenols, organic acids, and tannins. Pomegranate peel, a byproduct of processing, is of interest for microbiological research. The aim of this study was to produce the enzyme tannase and identify its microbiological producers. Results obtained using MALDI-TOF MS technology showed that fungi such as Aspergillus oryzae and Talaromyces albobiverticillius are the main producers with high enzymatic activity. The obtained scores (Aspergillus oryzae – 1,77; Talaromyces albobiverticillius – 2,33) confirm the reliability of the identification. Thus, the results of this study are of great importance for the selection of …
Preparation Of Liposomes And Evaluation Of Their Toxic Properties, Aygul M. Yarilkaganova, Oybek N. Ashirоv, Otabek U. Allaev, Nigora А. Tosheva, Shakhnoz S. Azimova
Preparation Of Liposomes And Evaluation Of Their Toxic Properties, Aygul M. Yarilkaganova, Oybek N. Ashirоv, Otabek U. Allaev, Nigora А. Tosheva, Shakhnoz S. Azimova
CHEMISTRY AND CHEMICAL ENGINEERING
Liposomes are nanoscale vesicular systems composed of phospholipid bilayers capable of encapsulating both hydrophilic and hydrophobic molecules. The present study investigates the effect of temperature and repeated freeze–thaw (F/T) cycles on liposomal size, polydispersity and evaluates their cytotoxicity on MDSK cell lines using the MTT assay. Liposomes were prepared by the reverse-phase evaporation method and hydrated at different temperatures (30, 40, 50, and 60 °C). The samples were subjected to multiple F/T cycles (1–9×) to study their particle size and polydispersity index (PDI) were analyzed using dynamic light scattering (DLS). Cytotoxicity was tested using the MTT method on MDSK cell …
Dft Study Of Vanadyl Acetylacetonate Complexes With Benzimidazole Derivatives And 2-Mercaptobenzothiazole, Xolida Jabborova, Shahlo Sh. Daminova
Dft Study Of Vanadyl Acetylacetonate Complexes With Benzimidazole Derivatives And 2-Mercaptobenzothiazole, Xolida Jabborova, Shahlo Sh. Daminova
CHEMISTRY AND CHEMICAL ENGINEERING
The geometric and electronic structures of the mixed-ligand complexes [VO(AcAc)2MBT], [VO(AcAc)2AFBI] and [VO(AcAc)2FBI] (MBT is 2-mercaptobenzothiazole, AFBI is 2-aminophenyl-1H-benzimidazole, FBI is 2-phenylmethyl-1H-benzimidazole) were studied by density functional theory ((U)B3LYP/6-311G(d,p)/LanL2DZ, Gaussian 09W). The MBT molecule was found to be planar, whereas in AFBI and FBI the NH group is coplanar with the imidazole ring. Analysis of effective atomic charges and molecular electrostatic potential maps shows that the pyridine-type nitrogen atoms of the imidazole and thiazole rings (q = −0.355 to −0.301 e) are the most probable coordination sites for the vanadyl ion. The HOMO–LUMO energy …
Innovation Policy Of The Fuel And Energy Complex Of The Republic Of Uzbekistan: A Conceptual Model And An Integral Assessment Of Sustainable Technological Development, Botir Sh. Usmonov, Jahongir B. Shukurillaev
Innovation Policy Of The Fuel And Energy Complex Of The Republic Of Uzbekistan: A Conceptual Model And An Integral Assessment Of Sustainable Technological Development, Botir Sh. Usmonov, Jahongir B. Shukurillaev
CHEMISTRY AND CHEMICAL ENGINEERING
The competitiveness of a fuel and energy complex (FEC) increasingly depends less on resource endowment than on the capacity to generate, adopt and commercialise innovation. This paper develops a systemic conceptual model of innovative development for the FEC of the Republic of Uzbekistan and proposes a quantitative tool for its assessment. Drawing on national strategy documents, international-agency reports (IEA, IRENA, OECD) and the scholarly literature, the study applies systemic-structural analysis, international benchmarking, conceptual modelling and a composite-indicator method. The model represents the FEC as six interacting subsystems — state innovation policy, science and education, FEC enterprises, innovation infrastructure, digital transformation …
Simulation Of Adsorption Of Aqueous Solution Of Methylene Blue On A Composite Of Phthalocyanine And Zinc Oxide, Albert R. Koldarov, Mastura Kh. Aripova, Odilzhon E. Abdurakhmonov, Zuhra Ch. Kadirova
Simulation Of Adsorption Of Aqueous Solution Of Methylene Blue On A Composite Of Phthalocyanine And Zinc Oxide, Albert R. Koldarov, Mastura Kh. Aripova, Odilzhon E. Abdurakhmonov, Zuhra Ch. Kadirova
CHEMISTRY AND CHEMICAL ENGINEERING
The aim of this work is to conduct a computer simulation of methylene blue adsorption from an aqueous solution onto a composite photocatalyst based on zinc oxide and zinc phthalocyanine. To understand the mechanisms of intermolecular interaction between the sorbates and the dominant crystal planes of the composite components, adsorption simulation was performed using the BIOVIA Adsorption Locator module. It is shown that the formation of the ZnO/ZnPc heterojunction promotes the synergistic stabilization of adsorbed molecules. The presence of the inorganic ZnO phase mitigates the electrostatic repulsion of chloride anions, ensuring the overall charge balance of the system, while the …
Catalytic Effect Of Metal Ions On The Oxidation Of Thiocyanate Ions With Hydrogen Peroxide, Sarvar B. Rajabov, Salmon M. Mukhammadiev, Berdakh T. Daniyarov, Haci Deveci, Shahlo Sh. Daminova
Catalytic Effect Of Metal Ions On The Oxidation Of Thiocyanate Ions With Hydrogen Peroxide, Sarvar B. Rajabov, Salmon M. Mukhammadiev, Berdakh T. Daniyarov, Haci Deveci, Shahlo Sh. Daminova
CHEMISTRY AND CHEMICAL ENGINEERING
Thiocyanate (SCN⁻) ions, formed during the cyanidation of gold ores, pose a significant environmental problem when present in mine processing wastewater. In this study, the oxidation of potassium thiocyanate model solutions (10–1000 mg/L) with hydrogen peroxide, in the presence and absence of Cu2+ and Fe2+ ions, was investigated at room temperature. Residual SCN⁻ concentrations were determined by bromatometric titration and UV-spectroscopy. Without a catalyst, H2O2 showed the weakest effect at all concentrations, leaving 6–17% residual SCN⁻ even at the highest applied dose. The addition of Cu2+ and Fe2+ ions markedly accelerated oxidation via …
Experimental Study On The Behavior Of High-Strength Reinforced Concrete Beams With A Longitudinal Void, With And Without Micro Steel Fibers, At Different Shear Spans, Farah M. Hussein, Saif Altai, Shatha Alasadi, Ayoob A. Ibrahim, Arshad Nadhom Shubber
Experimental Study On The Behavior Of High-Strength Reinforced Concrete Beams With A Longitudinal Void, With And Without Micro Steel Fibers, At Different Shear Spans, Farah M. Hussein, Saif Altai, Shatha Alasadi, Ayoob A. Ibrahim, Arshad Nadhom Shubber
Journal of Sustainable Construction Materials and Technologies
This study examines the impact of creating a longitudinal void in high-strength reinforced concrete (RC) beams to decrease concrete volume. Testing involved three groups: solid beams (SB), beams with a 75 mm void (VB), and beams with a void incorporating 1.2% micro-steel fibers (VBSF), across various shear spans (a/d) of 1.8, 2.7, and 3.6. Results indicated that increased a/d led to a 54.2% reduction in peak loads and a 119.2% increase in deflection for solid beams. The void negatively affected load-bearing at a/d = 1.8 with a 25% peak load reduction and brittle failure. At a/d = 2.7, effects were …
Dense Platinum Nanoparticles Confined In Mn-N-C Nanocages For Robust Heavy-Duty Pemfcs, Lei Zhao, Zhen-Min Cao, Jia-Yu Zuo, Ming-Liang Yang, Hong-Yan Qiao, Jun-Song Chen, Rui Wu
Dense Platinum Nanoparticles Confined In Mn-N-C Nanocages For Robust Heavy-Duty Pemfcs, Lei Zhao, Zhen-Min Cao, Jia-Yu Zuo, Ming-Liang Yang, Hong-Yan Qiao, Jun-Song Chen, Rui Wu
Journal of Electrochemistry
High-loading Pt cathodes are essential for heavy-duty proton exchange membrane fuel cells but suffer from a critical tradeoff between ionomer sulfonate poisoning and nanoparticle instability. Herein, we report a spatial confinement strategy to encapsulate dense Pt nanoparticles (~51.8 wt%) within Mn/N-co-doped mesoporous carbon nanocages (denoted as Pt-MnNC). This architecture excludes bulky ionomers to create an ionomer-shielded environment against sulfonate poisoning, while Mn-Nx-mediated strong metal-support interactions anchor the Pt nanoparticles to prevent agglomeration and further boost durability. In the 5 × 5 cm2 membrane electrode assembly tests, the Pt-MnNC catalyst delivers an exceptional power density of 1.26 W·cm …
Engineering Small-Sized Cations With Strong Solvation For High-Voltage Supercapacitors, Tong Huo, Pan Liu, Hao Chen, Peng Zhang, Zhen-Lei Chen, Guo-Fu Sun, Zhi-Qiang Shi, Jing Wang
Engineering Small-Sized Cations With Strong Solvation For High-Voltage Supercapacitors, Tong Huo, Pan Liu, Hao Chen, Peng Zhang, Zhen-Lei Chen, Guo-Fu Sun, Zhi-Qiang Shi, Jing Wang
Journal of Electrochemistry
Supercapacitors (SCs) have attracted much attention in the field of energy storage due to their high power density and long cycle life. However, their relatively low energy density limits their application in a wider range of fields. Methods to increase energy density include enhancing specific capacitance and extending operating voltage window. Herein, we report a novel electrolyte salt, tetramethylammonium bis(fluorosulfonyl)imide (TMA-FSI), the resulting electrolyte formed with propylene carbonate (PC), designated as TMF, exhibited a wide electrochemical stability window (ESW) of 5.09 V. On the one hand, we found that the small size of TMA+ enables it to enter the …
Efficient Acidic H2O2 Electrosynthesis Over Co Atoms Anchored On Nitrogen-Doped Hierarchical Porous Carbon, Xiao Huang, Zi-Hao Zhan, Hao-Xu Niu, Guan-Yu Luo, Jin-Tao Huang, Bo-Xuan Jin, De-Li Wang
Efficient Acidic H2O2 Electrosynthesis Over Co Atoms Anchored On Nitrogen-Doped Hierarchical Porous Carbon, Xiao Huang, Zi-Hao Zhan, Hao-Xu Niu, Guan-Yu Luo, Jin-Tao Huang, Bo-Xuan Jin, De-Li Wang
Journal of Electrochemistry
The two-electron oxygen reduction reaction (2e− ORR) presents a promising route for the on-site production of hydrogen peroxide (H2O2), offering a green alternative to energy-consuming anthraquinone process. However, the high selectivity toward the competing 4e− ORR over the desired 2e− pathway leads to low Faradaic efficiency for H2O2, posing a critical challenge in catalyst design. In this work, a nitrogen-doped hollow hierarchical porous carbon with anchored Co atoms (CoN/HPC) was constructed for high-performance H2O2 production. The as-prepared Co-N/HPC catalyst showed excellent 2e− ORR performance, achieving …
Physical Modeling To Represent Molten-Slag Entrapment Behavior Into Molten-Steel Under Simultaneous Similitude Condition Of Multiple Dimensionless Numbers, Yuichi Tsukaguchi, Sho Nakano
Physical Modeling To Represent Molten-Slag Entrapment Behavior Into Molten-Steel Under Simultaneous Similitude Condition Of Multiple Dimensionless Numbers, Yuichi Tsukaguchi, Sho Nakano
Progress in Scale Modeling, an International Journal
Physical model construction and experiment are essential for scientific investigations of flow phenomena such as high temperature two phase flow of molten metal and inert gas. It has been a common method to construct a physical model with a convenient scale then proceed experiments under similitude condition of one or two dimensionless number(s) of dominant forces to represent. It is an ideal experimental method to satisfy the simultaneous similitude condition of multiple dimensionless numbers concerned with the objective flow phenomena but has been considered difficult or impossible to realize for many years. Contrarily, the concept of the simultaneous similitude of …
Recent Advances In Bioethanol Production From Water Hyacinth: A Critical Review, Umuamina A. Matola, Mahir Mohammed Said, Olga-Ioanna Kalantzi, Abraham K. Temu
Recent Advances In Bioethanol Production From Water Hyacinth: A Critical Review, Umuamina A. Matola, Mahir Mohammed Said, Olga-Ioanna Kalantzi, Abraham K. Temu
Tanzania Journal of Engineering and Technology (TJET)
Water hyacinth (WH) is a highly invasive tropical aquatic weed with high holocellulose and low lignin content, making it a promising lignocellulosic feedstock for second-generation bioethanol production. Producing bioethanol from WH offers a sustainable approach to simultaneously managing invasive biomass and producing renewable energy. This review critically evaluates recent advancements in bioethanol production from WH by examining pretreatment, hydrolysis, and fermentation technologies reported between 2014 and 2024. A PRISMA-guided literature search was conducted using the Scopus and Web of Science databases, and fifty-nine original research articles were selected for analysis. The reviewed studies were comparatively assessed based on pretreatment strategies, …
Parametric Study On The Plastic Hinge Length Of Precast Concrete Columns With Grouted Sleeve Connections, Rizky Tri Amalia, Harun Alrasyid
Parametric Study On The Plastic Hinge Length Of Precast Concrete Columns With Grouted Sleeve Connections, Rizky Tri Amalia, Harun Alrasyid
Journal of Sustainable Construction Materials and Technologies
The use of precast concrete structures with grouted sleeve (GS) connections has gained significant traction in the acceleration of bridge construction. The plastic hinge length (Lp) is a critical parameter for assessing the seismic performance and deformation capacity of such structural members. The previous study has proposed empirical equations for Lp in monolithic columns; however, a comprehensive understanding of the influential parameters on Lp in precast concrete columns with GS connections remains limited. This study presents a detailed parametric investigation to evaluate the effects of key design parameters on the plastic hinge length of a precast concrete columns with GS …
Determination Of The Content Of Water-Soluble Vitamins In The Composition Of Beet Beetroot Composition, Jasur Esirgapovich Safarov, Shakhnoza Abduvaxitovna Sultanova, Muhammad Rasul Oglu Najafli, Doston Ishmuhammat Ugli Samandarov
Determination Of The Content Of Water-Soluble Vitamins In The Composition Of Beet Beetroot Composition, Jasur Esirgapovich Safarov, Shakhnoza Abduvaxitovna Sultanova, Muhammad Rasul Oglu Najafli, Doston Ishmuhammat Ugli Samandarov
Chemical Technology, Control and Management
The aim of this study was to determine the content of water-soluble vitamins in various parts of beetroot (pulp, leaves and stems) that had been subjected to various drying methods in a bid to explore the effect of physical processes, i.e., the application of ultrasound, on micronutrient preservation. The experiments were performed at the Department of Service Technologies of Tashkent State Technical University, and chromatographic analysis was performed in the Institute of Bioorganic Chemistry of the Academy of Sciences of the Republic of Uzbekistan. Chromatography was performed on Agilent-1200 chromatograph with Exlipse XDB C18 column and diode array detector using …
Modeling Of A Two-Stage Extractive Distillation Process For The Separation Of 1,3-Butadiene From Pyrolysis-Derived C₄ Fractions, Muxriddin Xudoyor Og‘Li Ibodullayev, Jonibek Farxod O‘G‘Li Norqulov, Olim Rustamovich Abduraxmonov, Orifjon Sharipovich Kodirov
Modeling Of A Two-Stage Extractive Distillation Process For The Separation Of 1,3-Butadiene From Pyrolysis-Derived C₄ Fractions, Muxriddin Xudoyor Og‘Li Ibodullayev, Jonibek Farxod O‘G‘Li Norqulov, Olim Rustamovich Abduraxmonov, Orifjon Sharipovich Kodirov
Chemical Technology, Control and Management
The separation of 1,3-butadiene from pyrolysis-derived C₄ fractions represents a challenging task due to the multicomponent nature of the feed and the close boiling points of accompanying hydrocarbons. In this study, a two-stage extractive distillation process was investigated using an acetonitrile–water solvent system to address these challenges. A semi-industrial experimental unit consisting of two extractive distillation columns connected in series was developed and analyzed, and the process configuration was supported by Aspen Plus simulation. The feedstock composition was characterized in detail, revealing that 1,3-butadiene constitutes approximately 40 wt.% of the C₄ fraction, accompanied by significant amounts of propylene, butanes, butanes, …
Methods For Treating Wastewater Generated During The Production Of Basalt Fiber Using Modified Bentonite Clay, Abdurasul O'Ktamovich Husenov, Baxtiyor Toxtayevich Sabirov, Diyor Asadullayevich Xadjibayev
Methods For Treating Wastewater Generated During The Production Of Basalt Fiber Using Modified Bentonite Clay, Abdurasul O'Ktamovich Husenov, Baxtiyor Toxtayevich Sabirov, Diyor Asadullayevich Xadjibayev
Chemical Technology, Control and Management
This scientific article notes that in technological processes, wastewater is contaminated with various organic and mineral substances, including poisonous and toxic substances. Sources of environmental pollution include organic and inorganic substances formed during the production of basalt fiber. In this research work, the task is set to purify wastewater formed during the production of basalt fiber from organic substances. Bentonite clay is a very good natural sorbent and has the ability to purify some cations. When conducting laboratory experiments, bentonite clays from the "Azkamar" and "Navbahor" deposits were selected to purify wastewater formed during the production of basalt fiber from …
Mathematical Models Of Magnetoelastic Acceleration Transducers Developed Based On The Theory Of Lumped Parameter Circuits, Amirov Fayzullayevich Sulton, Kamila Kamilovna Jurayeva, Shovkat Dilshodovich Turayev
Mathematical Models Of Magnetoelastic Acceleration Transducers Developed Based On The Theory Of Lumped Parameter Circuits, Amirov Fayzullayevich Sulton, Kamila Kamilovna Jurayeva, Shovkat Dilshodovich Turayev
Chemical Technology, Control and Management
In this article, based on the theory of lumped-parameter circuits, algebraic and differential equations describing the mechanical, electrical, and magnetic circuits of new magnetoelastic acceleration transducers, their analytical solutions, as well as mathematical models establishing the relationship between the electromotive forces at the outputs of the transducers and acceleration, which is the input quantity of the transducer, have been developed. Analysis of these mathematical models and the graphs constructed on their basis shows that under the influence of acceleration applied to the transducers, with an increase in the mechanical stresses arising in the magnetic circuit of the transducer, a redistribution …
Optimal Procedure For Measuring The Parameters Of Optical Signals Considering Noise, Yuriy Gennadyevich Shipulin, Azimjon Mamadaliyevich Xusanov
Optimal Procedure For Measuring The Parameters Of Optical Signals Considering Noise, Yuriy Gennadyevich Shipulin, Azimjon Mamadaliyevich Xusanov
Chemical Technology, Control and Management
It has been shown that to achieve the required level of measurement accuracy and reliability, it is necessary to transition from quality control of finished products to quality management based on cost-effective methods during the stages when product properties are formed. It is shown that the complexity of measuring optical signal parameters during analysis or synthesis requires them to be considered as part of a general information processing system. Based on the nonlinear filtration method, an optimal procedure for measuring a variable position in time against a background of spatial noise was obtained. Structural diagrams of optimal measuring instruments for …
Development And Uncertainty Assessment Of Secondary Method For Ph Measurement In Physicochemical Measurements, Sarvar Rakhmatullaev, Dostonbek Xujakulov, Mohinur Nigmatova
Development And Uncertainty Assessment Of Secondary Method For Ph Measurement In Physicochemical Measurements, Sarvar Rakhmatullaev, Dostonbek Xujakulov, Mohinur Nigmatova
Chemical Technology, Control and Management
In physicochemical measurements across various industries, laboratory analyses commonly require the determination of pH as an indicator of hydrogen ion activity in aqueous solutions. Ensuring the accuracy and reliability of these measurements, obtaining precise readings from pH measuring instruments, and maintaining overall measurement quality represent critical challenges in guaranteeing the safety of both products and processes. This requires constant monitoring, accuracy assessment, calibration, metrological verification, and control of measuring instruments. In this case, it should be carried out not with solutions prepared in any laboratory, but with certified reference materials (СRM) with appropriate regulatory framework, ensuring metrological observation. …
Robust-Adaptive Estimation Of Unmeasurable States And External Disturbances Of A Dynamic Object Based On An Augmented Kalman Filter, Husan Igamberdiev, Uktam Farkhodovich Mamirov, Lu Liu, Bohong Wang, Bunyod Buronov
Robust-Adaptive Estimation Of Unmeasurable States And External Disturbances Of A Dynamic Object Based On An Augmented Kalman Filter, Husan Igamberdiev, Uktam Farkhodovich Mamirov, Lu Liu, Bohong Wang, Bunyod Buronov
Chemical Technology, Control and Management
The paper addresses the problem of joint estimation of the directly unmeasurable states of a dynamic object and of external disturbances when information is available only on the control inputs and on the measured output signals. To solve this problem, a robust-adaptive algorithm based on an augmented Kalman filter is proposed, in which the external disturbance is included in the extended state vector. Two operating modes of the algorithm are considered. For slowly varying disturbances, a random-walk model with a constant process-noise covariance is used, whereas for rapidly varying inputs a signal adaptation driven by the normalized innovation is proposed. …
Fast Algorithms For Combined Synthesis Of Dynamic Object Control Systems, Isomiddin Khakimovich Siddikov, Gulchexra Alimova
Fast Algorithms For Combined Synthesis Of Dynamic Object Control Systems, Isomiddin Khakimovich Siddikov, Gulchexra Alimova
Chemical Technology, Control and Management
The paper considers the issues of combined synthesis of a control system for a nonlinear dynamic object. The combined synthesis algorithms are based on the hybrid application of the theory of ordinary differential equations in the Cauchy form and the theory of automatic control. In this case, the dynamics of the control system are described in the input-output representation and by state-space equations. Algorithms for solving stabilization problems, finite control, and the inverse dynamics problem are presented in explicit form. These algorithms are based on the concept of reducibility of a general Cauchy-form system to the block-canonical Frobenius form. The …
Nonlinear System Identification Based On Fuzzy Radial Basis Neural Network With Multi-Connected Weight Connections, Kabul Khudaybergenov
Nonlinear System Identification Based On Fuzzy Radial Basis Neural Network With Multi-Connected Weight Connections, Kabul Khudaybergenov
Chemical Technology, Control and Management
This paper builds on our earlier radial basis function network with multiple connections (RBFMC) by placing it within a fuzzy inference framework for nonlinear system identification. The idea is inspired by the diversity of neurotransmitters found in biological neurons: instead of a single hidden-to-output weight, RBFMC gives each hidden unit a multi-dimensional connection whose components act as independent filters. Once fuzzy logic is added, each hidden neuron becomes a fuzzy rule, and its antecedent is built from several Gaussian membership functions, one per connection. The resulting Fuzzy RBFMC produces an interpretable, multi-filter description of local regions of the input space …
Performance Evaluation Of Controllers Using Fuzzy Delphi And Ahp Techniques, Kamala. R. Aliyeva, Nihad Mehdiyev, Shamil Mehdi
Performance Evaluation Of Controllers Using Fuzzy Delphi And Ahp Techniques, Kamala. R. Aliyeva, Nihad Mehdiyev, Shamil Mehdi
Chemical Technology, Control and Management
This study introduces an enhanced decision-support framework that integrates the Fuzzy Delphi method with the Analytic Hierarchy Process (AHP) to improve controller tuning and performance evaluation in uncertain environments. Traditional tuning techniques typically depend on crisp expert judgments and deterministic performance indices; however, industrial control systems are characterized by nonlinear behaviors, uncertain parameter variations, and subjective expert evaluations that are often vague or inconsistent. The Fuzzy Delphi procedure is applied to systematically gather, filter, and consolidate expert insights, enabling a refined set of performance criteria such as stability margins, robustness to disturbances, settling time, overshoot, control effort, and energy consumption …
Documentation And Project Change Management System – Honeywell Trace, Farukh Adilov, N.R Yusupbekov, Maksim Fedorovich Astafurov, Kamola Rustamovna Abdullayeva
Documentation And Project Change Management System – Honeywell Trace, Farukh Adilov, N.R Yusupbekov, Maksim Fedorovich Astafurov, Kamola Rustamovna Abdullayeva
Chemical Technology, Control and Management
The article examines modern approaches to organizing documentation and managing changes in industrial automation projects using the Honeywell Trace software platform. The evolution of documentation tools from the Documentation Tool utility within the TDC 2000/3000 system to modern intelligent solutions is described. The architecture, functional capabilities, and supported interfaces of Honeywell Trace are analyzed. Particular attention is paid to automated configuration change tracking, comprehensive search by process tags, and the detection of potential errors. The possibilities of integrating the system with industrial process control systems, controllers, auxiliary systems, and industrial communication protocols are considered. The application of Honeywell Trace during …
Neural Network Driven By Electrochemical Performance Data For Predicting The Discharge Termination Time Of Seawater Electrolyte-Based Metal-Air Batteries, Peng-Peng Shen, Yi-Chi Pan, Yu-Rong Liu, Lu-Dan Zhang, Ning Niu, Guan-Jun Wang, De-Kun Yang, Xin-Long Tian, Peng Rao
Neural Network Driven By Electrochemical Performance Data For Predicting The Discharge Termination Time Of Seawater Electrolyte-Based Metal-Air Batteries, Peng-Peng Shen, Yi-Chi Pan, Yu-Rong Liu, Lu-Dan Zhang, Ning Niu, Guan-Jun Wang, De-Kun Yang, Xin-Long Tian, Peng Rao
Journal of Electrochemistry
Seawater electrolyte-based metal-air batteries exhibit great promise for marine energy supply systems. However, conventional statistical analysis methods, though applicable to seawater metal-air battery lifetime prediction, have inherent limitations of insufficient prediction accuracy and large error. Herein, a deep time-series regression framework based on InceptionTime and incorporating prior-biased attention pooling is proposed to construct a nonlinear mapping between electrochemical performance sequences and the discharge termination time of catalysts. Specifically, chronoamperometric profiles are employed to extract long-term stability features, while prior knowledge derived from linear sweep voltammetry is introduced to strengthen the attention weighting over critical potential regions. Under a nested leave-one-catalyst-out …
Microwave-Assisted Synthesis Of Core-Shell Structured Pd@Pdptcufe Recessed Truncated Octahedral Nanocrystals For Multifunctional Electrocatalysis, De-Zhong Hu, Wen-Dan Jiang, Wei Keat Ng, Jun Yang, Xiong-Wu Kang
Microwave-Assisted Synthesis Of Core-Shell Structured Pd@Pdptcufe Recessed Truncated Octahedral Nanocrystals For Multifunctional Electrocatalysis, De-Zhong Hu, Wen-Dan Jiang, Wei Keat Ng, Jun Yang, Xiong-Wu Kang
Journal of Electrochemistry
Developing cost-efficient and durable multifunctional electrocatalysts of hydrogen evolution reaction, oxygen reduction reaction and oxygen evolution reaction is crucial for improving energy conversion efficiency in electrolytic water splitting electrolyzer and advancing rechargeable zinc-air batteries. Polyhedral shaped nanocrystals with well-defined crystal facets represent a type of model catalysts that enables the exploration of structure-activity relationships. However, it is still very challenging to prepare alloy nanocrystals with multiple metal components due to their complicated redox potentials and mixing enthalpy. Herein, we report a rapid microwave-assisted polyol reduction method for syntheses of core-shell Pd@PdPtCu, Pd@PdPtCuNi, Pd@PdPtCuCo and Pd@PdPtCuZn octahedral nanocrystals, and recessed truncated-octahedral …