Chemical Engineering Commons^™

Instructional Slides From Molten Salt Electrochemistry Symposium (Moses) 2026, Devin Rappleye, Carlos Mejia, Alex Peroff

Faculty Publications

This instructional slide set was developed for the 2026 Molten Salt Electrochemistry Symposium (MoSES) as an introduction and review of fundamental electrochemical concepts and methods used in molten salt systems. The material is intended for students, researchers, and practitioners seeking to better understand and interpret electrochemical measurements in high-temperature molten salts.

Topics include electrochemical thermodynamics, kinetics, mass transfer, electrode potentials, cyclic voltammetry, chronopotentiometry, chronoamperometry, square-wave voltammetry, electrochemical impedance spectroscopy (EIS), and common approaches for analyzing electrochemical data. Emphasis is placed on building physical intuition, understanding underlying assumptions, recognizing common experimental artifacts, and connecting electrochemical signals to real chemical and transport …

Modified Anodic Stripping Voltammetry For In Situ Analysis Of Liquid Metal Composition In Molten Salt Electrorefining Systems, James H. Manner

Reviews, Analyses, and Instructional Studies in Electrochemistry (RAISE)

The development of in-situ analytical techniques for high-temperature molten salt systems is critical for advancing electrorefining in nuclear fuel recycling and metallurgical purification. This study proposes Modified Anodic Stripping Voltammetry (MASV), using a “dip-and-strip” approach where a tungsten electrode captures molten Sn–Ni alloy before stripping in LiCl–KCl–CaCl₂ at 415 °C. OCP results showed rapid loss of the metal layer due to poor wetting, and stripping peaks gave compositions inconsistent with the alloy, likely reflecting Sn/Sn²⁺ and Sn²⁺/Sn⁴⁺ redox processes. These results highlight interfacial limitations and the need for improved electrode materials and surface modification.

C. Difficile Detection Method For First Responder Glove Application, Alli N. Senedak

Williams Honors College, Honors Research Projects

Clostridioides Difficile (C. diff) is a Anaerobic Gram-positive bacillus that is capable of spore formation, making it difficult to control its spread and duration in clinical environments. This phenomenon can provide danger to first responders, healthcare workers, and patients. The goal of this project is to create a biosensor capable of detecting C. diff in a clinical setting that can be applied to a glove apparatus. The project will involve the use of C. diff aptamers activated on the surface of an electrode. Once surface activation has been verified via surface analysis, the electrodes will be exposed to C. diff …

Application Of Bimetallic Transition Metal Oxides Electrocatalysts For Li-Co2 Batteries And Li-O2 Batteries, Jianda Wang

Chemical and Biological Engineering ETDs

Li-ion batteries are the dominant commercial rechargeable batteries nowadays, which are used in electronic devices and electrified transportation widely. However, undesirable energy density of Li-ion batteries prohibits them from meeting requirements of new generation electronic devices. Therefore, it is important to find more alternative electronic energy storage systems with higher capacity. Fortunately, Li-CO2 batteries, featured high capacity and ability to convert CO2, have become a promising candidate to replace Li-ion batteries. In addition, Li-O2 batteries also attract people’s attention due to their high energy density and low cost. However, Li-CO2 batteries and Li-O2 batteries both face challenges of terrible cycle …

Collection Of Instructional Slides From Molten Salt Electrochemistry Symposium (Moses), Devin Rappleye, Carlos Mejia

Faculty Publications

During the Molten Salt Electrochemistry Symposium (MoSES) on July 30-31, 2025, interactive instruction was given to the attendees including live demonstrations. These slides contain the introductory instructions given for each learning module at MoSES 2025. Please visit https://pyro.byu.edu/moses for more information.

Modeling Self-Discharge In Li/S Batteries Through Electrochemical Anode Reactions: A Theoretical Perspective, Ralph E. White, Paul T. Coman

Faculty Publications

The growing demand for high-energy-density batteries has renewed interest in lithium–sulfur (Li/S) systems, which offer significant advantages but suffer from severe self-discharge during rest. While prior studies attribute this degradation to chemical parasitic reactions or polysulfide shuttling, they overlook the inherently electrochemical nature of anode-side processes. In this work, a 1D physics-based model of a Li/S battery was developed to explicitly incorporate lithium-metal oxidation and the stepwise electrochemical reduction of polysulfides at the anode. Using COMSOL Multiphysics, galvanostatic discharge followed by open-circuit rest under two conditions was analyzed - with and without parasitic anode reactions. The results show that when …

Electrochemically Active Liquid Organic Hydrogen Carriers For Energy Generation And Storage, Jinyao Tang

Theses and Dissertations

The growing demand for sustainable energy has spurred interest in hydrogen as a clean energy carrier, yet its widespread adoption is limited by storage and transport challenges. Liquid organic hydrogen carriers (LOHCs) offer a promising solution by enabling reversible hydrogen storage through chemical redox reactions under ambient conditions. Compared to conventional thermal methods, LOHC electrochemistry provides improved energy efficiency, operational safety, and integration into electrochemical systems. However, key challenges remain, such as catalyst deactivation, limited redox reversibility, and low system-level performance that hinder broader application. Alcohols like isopropanol (IPA) and cyclohexanol (CHOL), and amines like ethylamine, have emerged as promising …

Understanding The Effects Of Binder Dissolution Dynamics On The Chemistry And Performance Of Lithium–Sulfur Batteries, Saheed A. Lateef, John Chmiola, Fabio Albano, William E. Mustain, Golareh Jalilvand

Faculty Publications

Lithium–sulfur batteries (LSBs) are promising next-generation energy storage devices due to their higher theoretical specific energy and lower cost compared to conventional Lithium-ion batteries. However, their practical implementation has been hindered by severe performance degradation during extended cycling, primarily driven by shuttling of soluble sulfur discharge products (polysulfides) between the cathode and anode leading to capacity loss. In this work, we investigate the impact of selected binders and solvents, highlighting the effect of the dissolution process of the binder in solvent, on the structural properties and electrochemical performance of sulfur cathode. It is demonstrated for a variety of binders that …

Methods For Rotating Electrodes In High-Temperature Molten Salts, Ranon Fuller, Eloise Cluff, Edward Mercado, Carlos Mejia, Devin Rappleye

Faculty Publications

In this paper, we describe and validate a custom apparatus for performing high-speed (250-3,500 rpm) rotating electrode and dilatometer density experiments in molten salts. The reported details can aid in decreasing the difficulty and increasing the quality of such experiments. We discuss the design challenges and the solutions identified. We investigate methods for accurately measuring the solution resistance using electrochemical impedance spectroscopy (EIS), calculating the working electrode area using cyclic voltammetry (CV), and measuring the mass transfer-limited current of rotating electrodes using a series of chronoamperometry (CA) pulses. We further demonstrate the efficacy of our methods in producing accurate results.

Nanostructured Transition Metal Oxides For Electrochemical Co2 And Methane Conversion, Olumide O. Oladoyin

Chemical and Biological Engineering ETDs

Rising atmospheric CO₂ and CH₄ drive climate change, prompting research into their electrochemical conversion to valuable products. This study investigates electrodeposited nanostructured transition metal oxides (TMOs), unary (CuO, Co₃O₄) and dual (Cu-Co oxide) as catalysts for CO₂ reduction and CH₄ oxidation under ambient conditions. Fabricated on various substrates (Cu foil, SS316, carbon paper) and characterized by SEM, their electrochemical performance was evaluated via cyclic voltammetry.

Cu-Co oxide showed superior CO₂ reduction, leveraging the strengths of individual oxides. Co₃O₄ exhibited higher current densities for CH₄ oxidation, with SS316 proving the best substrate. Catalyst composition, morphology, and substrate significantly influenced efficiency. While …

Comsol Simulation Of Pipeline Corrosion With Cathodic Protection, Ethan Scalzo

Williams Honors College, Honors Research Projects

Cathodic protection (CP) is a widely used technique to mitigate corrosion in buried steel pipelines. This study uses COMSOL Multiphysics to model and analyze the performance of both sacrificial anode and impressed current systems in a simulated 3D environment. The model solves for pipeline potential, current density, and corrosion rate within a surrounding soil domain to assess protection coverage across the pipeline. Simulations were conducted to evaluate the influence of electrode and electrolyte properties on CP effectiveness. The study demonstrates that COMSOL Multiphysics is an effective tool for modeling CP systems, offering insights that align with established industry practices. While …

Using Nano-Ities For Detection Of Metal Ions In Complex Aqueous Solutions, Mohammed Muzammil Nishar Ahmed

Theses and Dissertations

Recent urbanization has induced a rapid increase in heavy metal exposure to humans. The exploitation of heavy metals for economic gains coupled with poor and economically infeasible recycling methods have led to poor management of heavy metal wastes, which has opened up several pathways for heavy metals to enter the human body. Such heavy metals target many vital organs, but the early symptoms are common and difficult to diagnose. Severe symptoms appear in later stages and are very expensive to treat and the damage caused to the health are not typically reversable in such later stages. To counter this issue, …

Development And Characterization Of Organic Electrocatalysts For Use In Zinc-Air Batteries, Christopher John Merkel

Department of Chemical and Biomolecular Engineering: Dissertations, Theses, and Student Research

The global deployment of solar photovoltaic and wind power is projected by the International Energy Agency as the primary pathway to reduce dependence on fossil fuels. However, these technologies face a critical bottleneck: their inherently intermittent power generation. For “intermittent renewables” to become the dominant source of electrical energy, efficient energy storage systems are essential. Current storage solutions are not viable on a global scale due to material scarcity, safety concerns, and high capital costs. Among emerging technologies, zinc-air batteries (ZABs) have garnered significant interest. ZABs offer a theoretical energy density five times greater than traditional lithium-ion batteries, utilize safe …

Mixed Potential Sensor For Natural Gas Leak Detection Design, Manufacturing, And Simulation, Sleight Halley

Chemical and Biological Engineering ETDs

There is a need for a low-cost robust sensor accurately detecting leaks from oil and gas infrastructure. This work presents the development of an electrochemical sensor based on an yttria stabilized zirconia (YSZ) electrolyte with La_0.87Sr_0.13CrO₃, Indium Tin Oxide (In₂O₃ 90 wt%, SnO₂ 10 wt%), Au, Pt electrodes. Selectivity to target gasses of the three sensing electrodes in conjunction with machine learning allows for the accurate discrimination between possible methane sources as well as the quantification of methane concentration. Sensor sensitivity is improved through a low-ionic conductivity substrate of magnesia …

Comparison Of Ligands In Palladium-Catalyzed Electrochemical Allyl 4-Pyridinylation, Wei-Jie Ding, Chun-Hui Yang, Zhong-Tao Feng, Shi-Rong Lu, Xu Cheng

Journal of Electrochemistry

4-CN-pyridine is a widely applied 4-pyridinylation reagent for diverse transformations. Conventionally, the reaction proceeds via an open-shell radical cross-coupling pathway. Following our previous study, in this work, we report the Pd-catalyzed allyl 4-pyrinylation reaction under electrochemical conditions. The reaction proceeds via radical-polar crossover pathway in which the role of phosphine ligand in reactivity and selectivity was extensively investigated.

Recent Advance In Electrochemical Dehalogenative Deuteration, Peng-Fei Li, Guang-Sheng Kou, Li-Ping Qi, You-Ai Qiu

Journal of Electrochemistry

In recent years, the incorporation of deuterium atoms into organic compounds has emerged as a vital focus in the development of pharmaceutical molecules. This trend is driven by the increasing recognition of the significance of compounds containing deuterium atoms across various domains, including materials and biopharmaceuticals, where they have found widespread applications in mechanistic studies within the realms of chemistry and biology. Meanwhile, organic electrochemistry, as a relatively environmentally friendly catalytic mode with broad adaptability to redox reactions, has emerged as a crucial alternative to traditional halogen-deuterium exchange in the context of the reduction deuteration of halides. This approach circumvents …

Electrocatalytic Cyclopropanation Of Active Methylene Compounds, Liang-Hua Jie, Hai-Chao Xu

Journal of Electrochemistry

The development of novel strategies to access cyclopropanes has become increasingly important due to the vital role of these three-membered ring structures in synthetic intermediates, natural products, and pharmaceuticals. Herein, we present an electrocatalytic method for the synthesis of cyclopropanes through intermolecular dehydrogenative annulation of active methylene compounds and arylalkenes. This electrochemical process requires no chemical oxidants, allowing for a speedy access to various functionalized cyclopropanes from inexpensive and readily available materials.

Electrodeposition Of Gadolinium Metal Thin Films For Neutron Phase Contrast Imaging, Mary Louise Gucik

Chemical and Biological Engineering ETDs

A rare earth metal, gadolinium has unique magnetic properties and the largest neutron absorption cross section making it highly sought after in emerging technology. However, unlike most metals, it is difficult to work with and lacks a damascene process. When incorporated into alloys, gadolinium’s properties are muted and the film thickness must increase to account for the low concentration. Gadolinium metal films have been deposited successfully through sputter coating, but these films have density deficiencies and are limited to line-of-sight substrates. In this work, the deposition of gadolinium metal thin films was investigated for use on complex geometries via electrophoretic …

Metal Organic Frameworks With Carbon Black For The Enhanced Electrochemical Detection Of 2,4,6-Trinitrotoluene, Shaghraf Javaid, Muhammad R. Azhar, Xinyu Li, Juliette I. Phillips, Tanveer Hussain, Hussein Abid, Jun Chen, Xiaobo Ji, Debbie S. Silvester

Research outputs 2022 to 2026

The sensing of explosives such as 2,4,6-trinitrotoluene (TNT) directly at an explosion site requires a fast, simple and sensitive detection method, to which electrochemical techniques are well suited. Herein, we report an electrochemical sensor material for TNT based on an ammonium hydroxide (NH4OH) sensitized zinc-1,4–benzenedicarboxylate Zn(BDC) metal organic framework (MOF) mixed with carbon black on a glassy carbon electrode. In the solvent modulation mechanism, by merely changing the concentration of NH4OH during synthesis, two Zn(BDC) MOFs with novel morphologies were fabricated via a hydrothermal approach. The as-prepared MOFs were characterized using X-ray powder diffraction (XRD), scanning electron microscopy (SEM), Fourier …

Band Alignments Of Metal/Oxides-Water Interfaces Using Ab Initio Molecular Dynamics, Yong-Bin Zhuang, Jun Cheng

Journal of Electrochemistry

Band alignments of electrode-water interfaces are of crucial importance for understanding electrochemical interfaces. In the scenario of electrocatalysis, applied potentials are equivalent to the Fermi levels of metals in the electrochemical cells; in the scenario of photo(electro)catalysis, semiconducting oxides under illumination have chemical reactivities toward redox reactions if the redox potentials of the reactions straddle the conduction band minimums (CBMs) or valence band maximums (VBMs) of the oxides. Computational band alignments allow us to obtain the Fermi level of metals, as well as the CBM and VBM of semiconducting oxides with respect to reference electrodes. In this tutorial, we describe …

From Waste To Energy: The Electrochemical Reduction Of Co2 Using Recycled Nanostructured Catalysts, Ibrahim Badawy

Theses and Dissertations

The reduction of carbon dioxide (CO₂RR) using electrochemistry is a promising solution for the burgeoning global energy crisis. The overall vision of its implementation relies on renewable energy sources to power the reaction creating carbon neutral products and effectively closing the carbon cycle. Research in this field has come a long way since its inception in the mid-1900s. However, there remain significant hurdles and important considerations to overcome in order to reach full commercialization. Most electrocatalysts tested for CO₂RR have been designed solely for maximum performance while ignoring the environmental consequences if such a material were …

The Study Of Corrosion On Additive-Manufactured Metals., Braydan Daniels

Electronic Theses and Dissertations

The purpose of this study was to investigate and compare the corrosion mechanisms between wrought and additive-manufactured (3D-printed) copper and stainless steel. The experimental procedure consisted of measuring the open circuit potential, electrochemical impedance spectroscopy, linear sweep voltammetry, Tafel analysis, surface topology, and scanning electron microscopy for each metal within salt water, tap water, sulfuric acid, and synthetic body fluid (excluding copper in synthetic body fluid).

Overall, printed stainless steel was more corrosion-resistant than wrought stainless steel in tap water and synthetic body fluid based on OCP, LSV, and surface topology results. Additionally, printed copper was more corrosion-resistant than wrought …

Hybrid Modeling For Electrochemical Systems, Luis Alejandro Briceno-Mena

LSU Doctoral Dissertations

The discovery of new materials like catalysts, polymeric films, and biomolecules, is driven by industrial needs such as improving reaction or separation selectivity, enhancing therapeutic effects on medical treatments, or reducing costs of replacement. However, deployment of these advances in industrial applications is often hindered by the lack of models needed for design and optimization. Due to the novelty of materials and devices, experimental data and first principles' knowledge are scarce, making it hard to build models either via data-driven or knowledge based approaches. In this context, a way to efficiently combine domain knowledge with data could provide a pathway …

Figure Data From "Electrochemical Identification Of Metal Chlorides In Eutectic Licl-Kcl Without Prior Knowledge Of Analyte Identities", Tyler Williams, Jason Torrie, Mark Schvaneveldt, Ranon Fuller, Greg Chipman, Devin Rappleye

ScholarsArchive Data

This is the data associated with figures found in a publication by the authors with the name of "Electrochemical Identification of Metal Chlorides in Eutectic LiCl-KCl Without Prior Knowledge of Analyte Identities".

Some of the data saved here is raw data collected by an Autolab potentiostat, while other data was derived from this raw data. Please reach out to the corresponding author for further questions.

Studies On Non-Transition Metal Substitution To Ab2 Metal Hydride Alloys For Battery Application, Shiuan Chang

Wayne State University Dissertations

Nowadays, multiphase transition metal-based AB2 metal hydride alloys and the rare-earth metal-based AB5 alloys (currently used in consumer NiMH batteries) are used as negative electrodes in NiMH batteries. It is of great interest to explore the possibility of significantly improving NiMH battery performance to compete with Li-ion batteries. In this area, the effect of dopant elements from Group-IA, -IIA, -IIIA non-transition metal family has not been thoroughly studied. In this study, lithium, magnesium, and boron (a metalloid considered metal in this study) were chosen as modifiers in the C14-phase predominant AB2 alloy by different dopant concentrations and synthesis methods, doping …

Faceted Nanomaterial Synthesis, Characterizations And Applications In Reactive Electrochemical Membrane Filtration, Qingquan Ma

Dissertations

Facet engineering of nanomaterials, especially metals and metal oxides has become an important strategy for tuning catalytic properties and functions from heterogeneous catalysis to electrochemical catalysis, photocatalysis, biomedicine, fuel cells, and gas sensors. The catalytic properties are highly related to the surface electronic structures, surface electron transport characteristics, and active center structures of catalysts, which can be tailored by surface facet control. The aim of this doctoral dissertation research is to study the facet-dependent properties of metal or metal oxide nanoparticles using multiple advanced characterization techniques. Specifically, the novel atomic force microscope-scanning electrochemical microscope (AFM-SECM) and density functional theory (DFT) …

New Solid Polymer Electrolytes For Lithium, Sodium, And Calcium-Based Batteries, Francielli Silva Genier

Dissertations - ALL

The establishment of sustainable energy sources highly depends on efficient storage devices to guarantee a consistent power supply. The growing demand for lithium-ion batteries (LIBs) for this purpose, combined with concerns about lithium availability, has motivated the search for viable storage alternatives, such as sodium and calcium. While several studies have investigated different lithium-free liquid electrolytes, the transport of these alternative ions in their polymer counterparts remains understudied. The advantages of solid polymer electrolytes include the possibility of higher energy density in solid-state devices and the elimination of safety concerns associated with liquid electrolytes, such as flammability, leakage, and dendrite …

Materials And Interfaces For Electrocatalytic Hydrogen Production And Utilization., Alexander Jiya Gupta

Electronic Theses and Dissertations

Mass industrialization over the last few centuries has created a global economy which is dependent upon fossil fuels to satisfy an exponentially increasing demand for energy. Aside from the possible depletion of this finite resource, the combustion of fossil fuels releases greenhouse gases into the atmosphere which cause the global temperature to rise – a phenomenon which has already begun to create geologic and geopolitical instability and shows no signs of abatement. One proposed method to rid humanity of its dependence on fossil fuels is to use green hydrogen as an energy carrier. In this scheme, excess electricity from a …

Highly Active And Stable Low-Pgm And Pgm-Free Catalysts For Anion Exchange Membrane Fuel Cells, Horie Adabi Firouzjaie

Theses and Dissertations

Anion exchange membrane fuel cells (AEMFCs) have recently seen significant growth in interest as their achievable current density, peak power density, and longevity have been dramatically improved. Though these advances in performance have been important for demonstrating the feasibility of the technology, nearly all AEMFCs reported in the literature have required a relatively high loading of platinum group metal (PGM)- based catalysts at both the anode and cathode electrodes. However, to take command of the low-temperature fuel cell market, AEMFCs cannot simply reach the same performance as incumbent proton exchange membrane fuel cells (PEMFCs), which have had decades of development …

A Comparison Of Square-Wave Voltammetry Models To Determine The Number Of Electrons Exchanged In Metal Deposition, Ranon Fuller, Tyler Williams, Mark H. Schvaneveldt, Devin Rappleye

Faculty Publications

A comparison of square-wave voltammetry models for calculating the number of electrons exchanged in a metal deposition reaction. Experiments were conducted for silver deposition on platinum in an aqueous HNO₃ solution and for nickel and lanthanum deposition on platinum in molten LiCl. Diffusion coefficients for Ni²⁺ and La³⁺ in LiCl at 700^oC are calculated. Accuracy of soluble-soluble models versus a soluble-insoluble model is discussed. A simple method for determining the number of electrons exchanged under the constraint of well-compensated ohmic drop is proposed and evaluated.