Chemical Engineering Commons^™

Control Education For Societal-Scale Challenges: A Community Roadmap, John Anthony Rossiter, Christos G. Cassandras, João Hespanha, Sebastian Dormido, Luis De La Torre, Gireeja Ranade, Antonio Visioli, John Hedengren, Richard M. Murray, Panos Antsaklis, Francoise Lamnabhi-Lagarrigue, Thomas Parisini

Faculty Publications

This article focuses on extending, disseminating and interpreting the findings of an IEEE Control Systems Society working group looking at the role of control theory and engineering in solving some of the many current and future societal challenges. The findings are interpreted in a manner designed to give focus and direction to both future education and research work in the general control theory and engineering arena, interpreted in the broadest sense. The paper is intended to promote discussion in the community and also provide a useful starting point for colleagues wishing to re-imagine the design and delivery of control-related topics …

Simulations Of Morphology Control Of Self-Assembled Amphiphilic Surfactants, Qinyu Zhu, Douglas R. Tree

Faculty Publications

One of the grand challenges of amphiphilic self-assembly is the design of ordered structures whose morphology or shape can be explicitly and dynamically controlled by adjusting the properties of the amphiphiles or their surroundings. Such a capacity would enable researchers to create synthetic systems with functionality that meets or exceeds biological cells, and provide a robust platform for a broad range of engineering applications such as artificial tissues, drug delivery, and separation membranes. Despite significant progress, important fundamental questions remain unanswered, due in part to the limited resolution and the restricted parameter spaces that are readily accessible in experiments. Computational …

Synergistic Effect Of Temperature And Acid Catalyst To Enhance L-Ald, Prabhsimran Singh

USF Tampa Graduate Theses and Dissertations

Liquid Atomic layer deposition (LALD) is an emergent technology used for depositing thin films. Extensive research has been done on this method, designing different techniques and modifications for the deposition of films. Wastage of alkoxide precursors, extra purging cycle, and extensive time for the reaction when added stoichiometrically are some of the drawbacks which shift the focus from metal alkoxide as precursors. In this thesis, modifications for the L-ALD method for the complete reaction of alkoxide precursors when added stoichiometrically were achieved. Temperature and catalyst’s synergistic effects were utilized for the modification. This modified method was applied for the doping …

A Data-Driven Multivariate Process Monitoring Platform For Knowledge Discovery And Model Building In Industrial Applications, Estelle E. Seghers

LSU Master's Theses

In industrial chemical manufacturing processes, the amount of raw data generated can add complexity in the analysis and understanding of the process dynamics. Being able to properly interpret this data can help improve plant operation, especially regarding safety and profitability. This research has culminated in FastMan-JMP, a platform proposed for monitoring of industrial processes and optimization of the offline data-driven model-building process as part of the process monitoring workflow. FastMan-JMP is a tool developed in Python to apply various data mining and machine learning techniques quickly and easily to better understand valuable patterns and hidden trends in process data. One …

Protocol To Engineer Nanofilms Embedded Lipid Nanoparticles For Controlled And Targeted Drug Delivery (Nectar), Rashi Porwal, Stephen L. Hayward, Srivatsan Kidambi

Department of Chemical and Biomolecular Engineering: Faculty Publications

We present a protocol to engineer a substrate-mediated delivery platform comprising hyaluronic acid-coated lipid nanoparticles (HALNPs) embedded into polyelectrolyte multilayer (PEM) films. This platform allows controlled spatiotemporal release of lipid nanoparticles (LNP) by embedding them within the polyelectrolyte multilayer films matrix. HALNP conjugate with antibodies also adds the ability for targeted delivery. The use of LNP enables this platform to encapsulate both hydrophobic and hydrophilic drugs. This platform can easily be reproduced and utilized for various biomedical drug delivery applications. For complete details on the use and execution of this protocol, please refer to Hayward et al. (2015, 2016a, 2016b), …

Simulations Of Morphology Control Of Self-Assembled Amphiphilic Surfactants, Qinyu Zhu, Douglas R. Tree

Faculty Publications

One of the grand challenges of amphiphilic self-assembly is the design of ordered structures whose morphology or shape can be explicitly and dynamically controlled by adjusting the properties of the amphiphiles or their surroundings. Such a capacity would enable researchers to create synthetic systems with functionality that meets or exceeds biological cells, and provide a robust platform for a broad range of engineering applications such as artificial tissues, drug delivery, and separation membranes. Despite significant progress, important fundamental questions remain unanswered, due in part to the limited resolution and the restricted parameter spaces that are readily accessible in experiments. Computational …

Computational Discovery Of Active And Selective Metal- Nitrogen-Graphene Catalysts For Electrooxidation Of Water To H2O2, Payal Chaudhary, Iman Evazzade, Rodion Belosludov,, Vitaly Alexandrov

Department of Chemical and Biomolecular Engineering: Faculty Publications

A direct electrosynthesis of H₂O₂ from either O₂ or H₂O is an attractive strategy to replace the energy-intensive industrial anthraquinone process. Two-electron water oxidation reaction (2e-WOR) offers several advantages over the oxygen reduction reaction such as better mass transfer due to the absence of gasphase reactants. However, 2e-WOR is a more challenging and less studied process with only a handful of metal oxides exhibiting reasonable activity/selectivity properties. Herein, we employ density-functional-theory calculations to screen a variety of metal-nitrogen-graphene structures for 2e-WOR. As a consequence of scaling between the adsorption energies of reaction intermediates, we …

Interfacial Tensions Of (Brine + H2 + Co2) Systems At Gas Geo-Storage Conditions, Zoha Dalal Isfehani, Ali Sheidaie, Mirhasan Hosseini, Jalal Fahimpour, Stefan Iglauer, Alireza Keshavarz

Research outputs 2022 to 2026

In hydrogen geological storage, cushion gas has vital role to retain adequate reservoir pressure to keep the hydrogen withdrawal stable. Presence of the cushion gas in the storage reservoir can affect the flow characteristics of hydrogen during injection and production cycles. One of the most crucial parameters that control the fluids flow in porous media is interfacial tension (IFT) between fluids. However, the literature data lacks in terms of IFT between cushion gas mixed with hydrogen and brine at geo-storage conditions. In this study, the pendant drop method was used to measure the IFT of (brine + H₂ + …

Oh, My Darling Clementine: A Detailed History And Data Repository Of The Los Alamos Plutonium Fast Reactor, Hannah K. Patenaude, Franz J. Freibert

College of Sciences Graduate Student Research

The Los Alamos Plutonium Fast Reactor, Clementine, provided the first fast neutron spectrum using a metallic plutonium fuel system and liquid mercury coolant. Clementine is often mentioned in the history of fast, metal-fueled, or metal-cooled designs, with little public information regarding the specifications or timeline. This paper contains a synopsis of each report regarding the development, operation, experimental results, failures, and subsequent disassembly of Clementine to explore this unique reactor within the context of modern advanced reactor development.

Molecular And Cellular Level Characterization Of Cytoskeletal Mechanics Using A Quartz Crystal Microbalance, Emily M. Kerivan, Lyle Tobin, Mihir Basil, Dana N. Reinemann

Faculty and Student Publications

A quartz crystal microbalance (QCM) is an instrument that has the ability to measure nanogram-level changes in mass on a quartz sensor and is traditionally used to probe surface interactions and assembly kinetics of synthetic systems. The addition of dissipation monitoring (QCM-D) facilitates the study of viscoelastic systems, such as those relevant to molecular and cellular mechanics. Due to real-time recording of frequency and dissipation changes and single protein-level precision, the QCM-D is effective in interrogating the viscoelastic properties of cell surfaces and in vitro cellular components. However, few studies focus on the application of this instrument to cytoskeletal systems, …

Magnetic Nanocomposites For The Remote Activation Of Sulfate Radicals For The Removal Of Rhodamine B, Pranto Paul, Marissa Nicholson, J. Zach Hilt

UK CARES Faculty Publications

The widespread presence of numerous organic contaminants in water poses a threat to the ecological environment and human health. Magnetic nanocomposites exposed to an alternating magnetic field (AMF) have a unique ability for magnetically mediated energy delivery (MagMED) resulting from the embedded magnetic nanoparticles; this localized energy delivery and associated chemical and thermal effects are a potential method for removing contaminants from water. This work developed a novel magnetic nanocomposite—a polyacrylamide-based hydrogel loaded with iron oxide nanoparticles. For this magnetic nanocomposite, persulfate activation and the contamination removal in water were investigated. Magnetic nanocomposites were exposed to AMF with a model …

A Review Of Hydrogen/Rock/Brine Interaction: Implications For Hydrogen Geo-Storage, Masoud Aslannezhad, Muhammad Ali, Azim Kalantariasl, Mohammad Sayyafzadeh, Zhenjiang You, Stefan Iglauer, Alireza Keshavarz

Research outputs 2022 to 2026

Hydrogen (H₂) is currently considered a clean fuel to decrease anthropogenic greenhouse gas emissions and will play a vital role in climate change mitigation. Nevertheless, one of the primary challenges of achieving a complete H₂ economy is the large-scale storage of H₂, which is unsafe on the surface because H₂ is highly compressible, volatile, and flammable. Hydrogen storage in geological formations could be a potential solution to this problem because of the abundance of such formations and their high storage capacities. Wettability plays a critical role in the displacement of formation water and determines …

Ferric Chloride-Induced Arterial Thrombosis And Sample Collection For 3d Electron Microscopy Analysis, Smita Joshi, Alexis N. Smith, Kanakanagavalli Shravani Prakhya, Hammodah Rawhi Hammodah Alfar, Joshua Lykins, Ming Zhang, Irina D. Pokrovskaya, Maria A. Aronova, Richard D. Leapman, Brian Storrie, Sidney W. Whiteheart

Saha Cardiovascular Research Center Faculty Publications

Cardiovascular diseases are a leading cause of mortality and morbidity worldwide. Aberrant thrombosis is a common feature of systemic conditions like diabetes and obesity, and chronic inflammatory diseases like atherosclerosis, cancer, and autoimmune diseases. Upon vascular injury, usually the coagulation system, platelets, and endothelium act in an orchestrated manner to prevent bleeding by forming a clot at the site of the injury. Abnormalities in this process lead to either excessive bleeding or uncontrolled thrombosis/insufficient antithrombotic activity, which translates into vessel occlusion and its sequelae. The FeCl3-induced carotid injury model is a valuable tool in probing how thrombosis initiates and progresses …

Influence Of Adhesive Application Method And Thermocycling On The Bonding Performance Of Different Adhesive Systems To Dentin, Lamiaa Mahmoud Moharam, Rasha Hassan Afifi

Chemical and Biochemical Engineering Faculty Research & Creative Works

Aim: To assess the effect of multiple layers application of different adhesive systems on the microshear bond strength (μSBS) of dentin with and without thermocycling. Materials and Methods: Two hundred forty sound human premolars had their enamel surfaces removed to expose even surfaces of dentin. The teeth were mounted in acrylic resin blocks and then assigned arbitrarily into four main groups (n = 60) representing the investigated adhesives (a self-etch [SE] adhesive, a total-etch [TE] adhesive, and a multimode [MM] adhesive used in TE and SE modes). Individually, the main groups were equally alienated into three subgroups (n = 20), …

Engineering Oxygen Vacancy-Rich Ceox Overcoating Onto Ni/Al2o3 By Atomic Layer Deposition For Bi-Reforming Of Methane, Baitang Jin, Kaiying Wang, Han Yu, Xiaoqing He, Xinhua Liang

Chemical and Biochemical Engineering Faculty Research & Creative Works

Atomic Layer Deposition (ALD) Was Applied to Develop CeO_x-Overcoated Ni/Al₂O₃ Catalyst for Bi-Reforming of Methane (BRM), as the Combination of Dry Reforming of Methane (DRM) and Steam Reforming of Methane (SRM). Non-Stoichiometric CeO_x Thin Films Were Successfully Deposited on Ni/Al₂O₃ Particles by ALD, Which Constructed a Beneficial Ni-CeO_x Interface and Modified the Catalyst Property. Ascribed to the Unique ALD Growth Mode, a High Amount of Ce(III) and Oxygen Vacancies Existed in the ALD-Deposited CeO_x overcoating. a Reduction Process Before the BRM Reaction Contributed to the Further Reduction of Ce(IV) …

Incoherency In Central American Hydroclimate Proxy Records Spanning The Last Millennium, Jonathan Obrist-Farner, Byron A. Steinman, Nathan D. Stansell, Jeremy Maurer

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Continued Global Warming is Expected to Result in Reduced Precipitation and a Drier Climate in Central America. Projections of Future Changes Are Highly Uncertain, However, Due to the Spatial Resolution Limitations of Models and Insufficient Observational Data Coverage Across Space and Time. Paleoclimate Proxy Data Are Therefore Critical for Understanding Regional Climate Responses during Times of Global Climate Reorganization. Here We Present Two Lake-Sediment based Records of Precipitation Variability in Guatemala Along with a Synthesis of Central American Hydroclimate Records Spanning the Last Millennium (800–2000 CE). the Synthesis Reveals that Regional Climate Changes Have Been Strikingly Heterogeneous, even over Relatively …

Dendrimer And Dendrimer Gel-Derived Drug Delivery Systems: Breaking Bottlenecks Of Topical Administration Of Glaucoma Medications, Juan Wang, Boxuan Li, Uday B. Kompella, Hu Yang

Chemical and Biochemical Engineering Faculty Research & Creative Works

Due to high structural flexibility, multidrug carrying capability, and tunable size, dendrimers have been used as suitable carriers for ophthalmic drug delivery. Drug molecules can be either encapsulated or chemically coupled to dendrimers. the nanoscopic size, spheroidal shape, and cationic surface of Poly amidoamine (PAMAM) dendrimers promote their interaction with the cornea and result in prolonged precorneal retention. Dendrimers could be further cross-linked to produce three-dimensional hydrogel networks or dendrimer hydrogels (DH). the properties of the DH can be readily adjusted to maintain both fluidity and adhesiveness, making them suitable for developing topical ocular drug formulations. Micro-/nano- sized DHs, that …

Using Switchable Solvents For Enhanced Biodiesel Production, Eyad Abdel Rahman Sowan

Theses

This thesis presents a sustainable approach to biodiesel production using in-situ technology for direct conversion of microalgae-to-biodiesel. The proposed method operates on wet, untreated microalgae, thereby eliminating the cost/energy intensive drying and cell disruption steps. Owing to their favorable properties, the use of enzymes, specifically lipase, as a catalyst for the process was suggested over acid/base catalysts. However, the high cost of the enzyme necessitates its reuse at sustained activity for the process to be economically feasible. The use of non-toxic green solvents, such as switchable solvents, as an alternative to conventional organic solvents was a significant challenge for the …

Optimization Of Co2 Huff-N-Puff In Unconventional Reservoirs With A Focus On Pore Confinement Effects, Fluid Types, And Completion Parameters, Aaditya Khanal, Md Fahim Shahriar

Jasper Department of Chemical Engineering Faculty Publications and Presentations

The cyclic injection of CO2, referred to as the huff-n-puff (HnP) method, is an attractive option to improve oil recovery from unconventional reservoirs. This study evaluates the optimization of the CO2 HnP method and provides insight into the aspects of CO2 sequestration for unconventional reservoirs. Furthermore, this study also examines the impact of nanopore confinement, fluid composition, injection solvent, diffusivity parameters, and fracture properties on the long-term recovery factor. The results from over 500 independent simulations showed that the optimal recovery is obtained for the puff-to-huff ratio of around 2.73 with a soak period of fewer than 2.7 days. After …

Exploring Current And Future Research Trends On Safety Climate In Construction Projects, Kamugisha Joseph Kajumulo

Tanzania Journal of Engineering and Technology (TJET)

Clients, consultants, and contractors in the construction industry can benefit from a safety climate by obtaining knowledge of attitudes and perceptions for better safety outcomes. However, the current and future research trends for safety climate in construction projects have not yet been fully examined. In order to solve this problem, a systematic review of previous research findings using a social network approach must be conducted, and future trends for the safety climate in building projects must be identified. Sixty-three peer reviewed articles were gathered to study the literature on safety climate in construction projects. A social network approach was employed …

The Fourth Industrial Revolution: Opportunities And Challenges To The Future Of Mechanical Engineering, Ulingeta O.L. Mbamba

Tanzania Journal of Engineering and Technology (TJET)

This paper provides a conceptual overview of the developments of the Fourth Industrial Revolution (4IR) and derives challenges and opportunities for the future of the mechanical engineering profession. The paper broadly defines 4IR as the fusion of technologies and interaction across physical, digital and biological aspects, while defining mechanical engineering as "a multi-faceted discipline that encompasses the teaching, practice and guidance of others in the development and application of scientific principles to mechanical systems". The paper looks specifically at developments in the Internet of Things (IoT), blockchain technology, robotics, Big Data analytics, biotechnology, nanotechnology, 3D printing and artificial intelligence and …

Model For Calculating The Static Characteristics Of Hydraulic Systems Of Hydro Technical Buildings, Mirkhalil Ismailov, Dong Zhang, Farkhod Kasimov

Chemical Technology, Control and Management

Hydraulic mechanisms that actuate flat gates, widely used in hydraulic structures, are studied as hydraulic actuators of the system. Their static mathematical models are developed using an integrated methodology with a hydraulic pump, inlet and suction pipes, and internal and external resistance factors. Unlike existing mathematical models, the model developed in this paper allows a detailed description of the characteristics of hydraulic drives due to the fact that pressure losses in the throttle, regulator, and power amplifier, as well as local resistances in hydraulic pipelines, are taken into account.

Synchronization Of The Training Of Specialists In The Automation Of Technological Processes In Accordance With The Dynamics Of The Taxonomy Of Learning Goals, Yusuf Shodievich Avazov, Kamola Abdullaeva

Chemical Technology, Control and Management

Changes in the characteristics of modern ones, reflecting them as the "digital generation", inevitably necessitate electronic interactive, mobile and mixed, machine learning, especially in the field of automation and control of technological processes and production. As a consequence of reflecting these realities, there have been parallel changes in the taxonomy of learning objectives - from the classical to the revised rethought and digital.

In order to study the problem of synchronizing the training of future specialists in the field of automation and control of technological processes and production and funny knowledge in accordance with the dynamics of the taxonomy of …

Analysis Of Vegetable Oil Refining Technology, Elyor Samadov

Chemical Technology, Control and Management

Innovative technologies for refining vegetable oils are presented, as well as the qualitative characteristics of raw vegetable oils obtained by extraction and mechanical methods. A general review of the chemical composition and impurities of vegetable oils resulting from the reaction between glycerol and fatty acids is carried out, and a brief review of the study to determine the effect of refining on biologically active components.

The analytical review is devoted to a comparative comparison of two types of refining - chemical and physical refining.

Research Of Three-Phases Current’S Transducers Of Filter-Compensation Devices For Control Reactive Power’S Consumption Of Asynchronous Motor, Ilkhomjon Khakimovich Siddikov, Dilyorbek Karimjonov Doniyorbek O'G'Li -, Abdumutal Abdikarimovich Abdigapirov

Chemical Technology, Control and Management

In the article given materials of developing of three-phase electromagnetic current transducers of reactive power, using with asynchronous motor, methods connecting of two sensing element, series, parallel and differential and loops suitable for each phase, dynamic characteristics of output signals of three-phase electromagnetic current transducers asynchronous motor.

On the basis of modern calculation and design complexes are of great importance in the research variable sizes of three-phase current electromagnetic transducers of filter-compensation devices of reactive power of asynchronous motors. Presented mathematical model of research of electrical, electromagnetic and magnetic elements of electromagnetic current transducers in the …

3d Printed Composite Structures For Bone Repair And Drug Delivery Application, Innocent J. Macha

Tanzania Journal of Engineering and Technology (TJET)

Due to the increase in traffic accidents, industrial contingencies, and natural disasters, there is a high demand for bone regeneration biomaterials. Although bone can regenerate and self-repair, it is difficult to do so when the defect area exceeds the critical repair area due to trauma, tumour resection, or congenital diseases. The traditional methods for bone repair are autograft, allograft, and xenograft. However, these methods have flaws and limitations, such as complications in the donor bone area, a limited number of donors, rejection, and infectious diseases. However, in recent years, the use of additive manufacturing technologies in bone tissue engineering has …

Towards Lean Manufacturing In Developing Countries: Research Gaps And Directions In Tanzania, Francis D. Sinkamba

Tanzania Journal of Engineering and Technology (TJET)

In the current knowledge-driven economy, many industries across the globe are forced to adopt manufacturing technologies such as lean manufacturing to remain competitive in the globalized world. Despite the increase in lean manufacturing implementations, the adoption rate in Tanzania is very low and estimated to be 8 percent. Likewise, the sustainability of lean manufacturing tools and practices is still questionable, which shows the need to develop lean maturity models. To date, several lean maturity models have been developed but there is ARTICLE INFO Submitted: July 5, 2022 Revised: Sept. 28, 2022 Presented: Oct. 20, 2022 a lack of maturity models …

Factors Influencing Total Productive Maintenance Implementation For Thermal Generation Plants, Ismail W. R. Taifa Dr

Tanzania Journal of Engineering and Technology (TJET)

This study accepts that the technical and administrative factors can amplify effective total productive maintenance (TPM) implementation at thermal generation plants. It is noted that there is a limited number of studies that have attempted to understand the subject of TPM implementation in the energy sector. Noting this shortcoming, the authors thought it crucial to generate empirical evidence on the factors influencing effective TPM implementation for thermal generation plants, with evidence from gas-fired plants. A sample of 88 respondents was selected and consulted. Data were collected through questionnaires and analyzed quantitatively by inferential statistics and qualitatively through thematic analysis using …

Preparation And Characterization Of Microporous Cellulose Membranes As Potential Pathogen Filters, Peresi M. Bulemo

Tanzania Journal of Engineering and Technology (TJET)

Growth and development in the textile and fashion industry have resulted in the generation of large amounts of industrial pre consumer textile wastes. It is estimated that 10 to 20% of textile fabrics are wasted during garment manufacturing, with most of the wastes being burned or landfilled. Reusing pre-consumer fabric wastes is therefore considered a viable approach to alleviate environmental impacts associated with their disposal. To achieve a higher porosity membrane, pre-consumer cotton fabrics were partially dissolved in a solution of dimethyl acetamide (DMAc) and lithium chloride (LiCl), and the resulting fibre suspension was utilized to prepare a microporous cellulose …

Extraction And Characterization Of Collagen From Cattle Horns For Potential Wound Healing, Yeriko Halson

Tanzania Journal of Engineering and Technology (TJET)

The need for bandages and gauze for wound dressing and healing is inevitable due to the high increase in accidents. Most of the material used for the production of bandages and gauzes for wound healing are from non-renewable synthetic material. The sustainability of non renewable resources is at jeopardy due to the health and associated environmental impact. Consequently, the use of naturally occurring and biodegradable material is a promising solution to the sustainability challenges of synthetic material. In this paper, the extraction of collagen films from cattle horns for potential wound healing is reported. Collagen was extracted from cattle horns …