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Articles 2281 - 2310 of 14237

Full-Text Articles in Chemical Engineering

Air Pre-Heat System Optimization For Flash Dryers, Sophia Louden Apr 2023

Air Pre-Heat System Optimization For Flash Dryers, Sophia Louden

Honors Theses

Primient, a leading producer of food and industrial ingredients made from plant-based, renewable sources is the industrial sponsor for this project. The company is currently using Plate & Frame Heat exchangers to heat up a 40% by-weight glycol and water solution that is then used to preheat the incoming ambient air. Glycol is being added to reduce the risks of freezing in the system during the winter season. It is important to highlight that this fact affects the heat transfer properties of the liquid overall. Since air heating is a highly energy-demanding process, an outlet stream of hot water produced …

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Cobalt Oxide Functionalized Ceramic Membrane For 4-Hydroxybenzoic Acid Degradation Via Peroxymonosulfate Activation, Rajan Arjan Kalyan Hirani, Hong Wu, Abdul Hannan Asif, Nasir Rafique, Lei Shi, Shu Zhang, Zhentao Wu, Lai-Chang Zhang, Shaobin Wang, Yu Yin, Martin Saunders, Hongqi Sun Apr 2023

Cobalt Oxide Functionalized Ceramic Membrane For 4-Hydroxybenzoic Acid Degradation Via Peroxymonosulfate Activation, Rajan Arjan Kalyan Hirani, Hong Wu, Abdul Hannan Asif, Nasir Rafique, Lei Shi, Shu Zhang, Zhentao Wu, Lai-Chang Zhang, Shaobin Wang, Yu Yin, Martin Saunders, Hongqi Sun

Research outputs 2022 to 2026

Membrane separation and sulfate radicals-based advanced oxidation processes (SR-AOPs) can be combined as an efficient technique for the elimination of organic pollutants. The immobilization of metal oxide catalysts on ceramic membranes can enrich the membrane separation technology with catalytic oxidation avoiding recovering suspended catalysts. Herein, nanostructured Co3O4 ceramic catalytic membranes with different Co loadings were fabricated via a simple ball-milling and calcination process. Uniform distribution of Co3O4 nanoparticles in the membrane provided sufficient active sites for catalytic oxidation of 4-hydroxybenzoic acid (HBA). Mechanistic studies were conducted to determine the reactive radicals and showed that …

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Influence Of Henna Extracts On Static And Dynamic Adsorption Of Sodium Dodecyl Sulfate And Residual Oil Recovery From Quartz Sand, Mohd Syazwan Mohd Musa, Priveqa Yaashini Gopalan, Nurudeen Yekeen, Ahmed Al-Yaseri Apr 2023

Influence Of Henna Extracts On Static And Dynamic Adsorption Of Sodium Dodecyl Sulfate And Residual Oil Recovery From Quartz Sand, Mohd Syazwan Mohd Musa, Priveqa Yaashini Gopalan, Nurudeen Yekeen, Ahmed Al-Yaseri

Research outputs 2022 to 2026

The application of surfactant flooding for enhanced oil recovery (EOR) promotes hydrocarbon recovery through reduction of oil-water interfacial tension and alteration of oil-wet rock wettability into the water-wet state. Unfortunately, surfactant depletion in porous media, due to surfactant molecule adsorption and retention, adversely affects oil recovery, thus increasing the cost of the surfactant flooding process. Chemical-based materials are normally used as inhibitors or sacrificial agents to minimize surfactant adsorption, but they are quite expensive and not environmentally friendly. Plant-based materials (henna extracts) are far more sustainable because they are obtained from natural sources. However, there is limited research on the …

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Corrosion Case Study On Automobile, Grace Ajayi, Xinran Pan, Geethu Sasikala, Marshall S. Yang Apr 2023

Corrosion Case Study On Automobile, Grace Ajayi, Xinran Pan, Geethu Sasikala, Marshall S. Yang

Chemistry Publications

No abstract provided.

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Mitochondrial Complex Iii Bypass Complex I To Induce Ros In Gpr17 Signaling Activation In Gbm, Sana Kari, Jeyalakshmi Kandhavelu, Akshaya Murugesan, Ramesh Thiyagarajan, Srivatsan Kidambi, Meenakshisundaram Kandhavelu Apr 2023

Mitochondrial Complex Iii Bypass Complex I To Induce Ros In Gpr17 Signaling Activation In Gbm, Sana Kari, Jeyalakshmi Kandhavelu, Akshaya Murugesan, Ramesh Thiyagarajan, Srivatsan Kidambi, Meenakshisundaram Kandhavelu

Department of Chemical and Biomolecular Engineering: Faculty Publications

Guanine nucleotide binding protein (G protein) coupled receptor 17 (GPR17) plays crucial role in Glioblastoma multiforme (GBM) cell signaling and is primarily associated with reactive oxidative species (ROS) production and cell death. However, the underlying mechanisms by which GPR17 regulates ROS level and mitochondrial electron transport chain (ETC) complexes are still unknown. Here, we investigate the novel link between the GPR17 receptor and ETC complex I and III in regulating level of intracellular ROS (ROSi) in GBM using pharmacological inhibitors and gene expression profiling. Incubation of 1321N1 GBM cells with ETC I inhibitor and GPR17 agonist decreased the ROS level, …

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Dynamic And Equilibrium Contribution Of Nematic Order In Wetting And Contact Angles, Partho Neogi, Xianjie Qiu, Amer Al-Shareef Apr 2023

Dynamic And Equilibrium Contribution Of Nematic Order In Wetting And Contact Angles, Partho Neogi, Xianjie Qiu, Amer Al-Shareef

Chemical and Biochemical Engineering Faculty Research & Creative Works

A Model for the Dynamic Contact Angles and the Spreading Kinetics of Nematic Liquid Crystals on a Solid Surface is Presented for the First Time using the Continuum Theory of Liquid Crystals. the Equations of Motion for This System Are Integrated for a Wedge or a Drop that is Thin and Moves Slowly. the Dynamic Contact Angle is Found to Depend on the Capillary Number that Represents the Importance of Viscocapillarity and on the Elasticity Number that is the Ratio between the Elastic and Surface Forces. the Model Provides an Explanation for the Extra Volume Dependence that is Reported in …

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Design And Synthesis Of Plasmonic Nanoparticles For Nir Bioimaging: Investigating The Role Of Absorption And Scattering, Luis Dias Bumba Manuel Apr 2023

Design And Synthesis Of Plasmonic Nanoparticles For Nir Bioimaging: Investigating The Role Of Absorption And Scattering, Luis Dias Bumba Manuel

LSU Doctoral Dissertations

Nanoparticles have made vast advances in the realm of nanomedicine and bioimaging, enabling technologies such as photothermal therapy of malignant tumors and noninvasive monitoring of living tissue. Many of these innovations have only arisen in the last few decades with potential for growth in many avenues. The research shown in this work addresses some of the existing literature's void. Particularly solving synthesis challenges that have existed for more than 20 years in synthesizing Au nanoshells and establishing the potential for molecular-level deep imaging of plants. A novel investigation of the role of light absorption and scattering in bioimaging led to …

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Beirut Arab University - Faculty Of Engineering - Newsletter Issue 0, Faculty Of Engineering, Beirut Arab University Apr 2023

Beirut Arab University - Faculty Of Engineering - Newsletter Issue 0, Faculty Of Engineering, Beirut Arab University

Engineering Newsletters

No abstract provided.

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Improving Wastewater-Based Epidemiology Performance Through Streamlined Automation, Mohammad Dehghan Banadaki, Soroosh Torabi, William Strike, Ann Noble, James W. Keck, Scott M. Berry Apr 2023

Improving Wastewater-Based Epidemiology Performance Through Streamlined Automation, Mohammad Dehghan Banadaki, Soroosh Torabi, William Strike, Ann Noble, James W. Keck, Scott M. Berry

UK CARES Faculty Publications

Wastewater-based epidemiology (WBE) has enabled us to describe Severe Acute Respiratory Syndrome Coronavirus 2 (SARS-CoV-2) infections in populations. However, implementation of wastewater monitoring of SARS- CoV-2 is limited due to the need for expert staff, expensive equipment, and prolonged processing times. As WBE increases in scope (beyond SARS-CoV-2) and scale (beyond developed regions), there is a need to make WBE processes simpler, cheaper, and faster. We developed an automated workflow based on a simplified method termed exclusion-based sample preparation (ESP). Our automated workflow takes 40 min from raw wastewater to purified RNA, which is several times faster than conventional WBE …

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On Hydrophobic Deep Eutectic Solvents: Thermo-Physical Properties And Applications In Gas Solubility, Shan Khai Liew Apr 2023

On Hydrophobic Deep Eutectic Solvents: Thermo-Physical Properties And Applications In Gas Solubility, Shan Khai Liew

Masters Theses

Carbon dioxide (CO2) has been widely recognized as one of the greenhouse gases (GHGs) in the atmosphere. GHGs cause global warming, which will bring a lot of problems and irreversible changes. To curb CO2 emissions, much effort has been done. There are many technologies available for CO2 capture, such as amine scrubbing, pressure or temperature swing adsorption, membrane separation, and many solvents and absorbents that have been proposed for CO2 capture (e.g., zeolite, silica materials, graphene, activated carbon, etc.) at every stage (pre-combustion, post-combustion, oxy-combustion). However, these materials have their own drawbacks. Hydrophobic deep eutectic solvents (HDES) is a green …

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Hydrogen Storage In Depleted Gas Reservoirs: A Comprehensive Review, Nasiru S. Muhammed, Md Bashirul Haq, Dhafer A. Al Shehri, Amir Al-Ahmed, Mohammad M. Rahman, Ehsan Zaman, Stefan Iglauer Apr 2023

Hydrogen Storage In Depleted Gas Reservoirs: A Comprehensive Review, Nasiru S. Muhammed, Md Bashirul Haq, Dhafer A. Al Shehri, Amir Al-Ahmed, Mohammad M. Rahman, Ehsan Zaman, Stefan Iglauer

Research outputs 2022 to 2026

Hydrogen future depends on large-scale storage, which can be provided by geological formations (such as caverns, aquifers, and depleted oil and gas reservoirs) to handle demand and supply changes, a typical hysteresis of most renewable energy sources. Amongst them, depleted natural gas reservoirs are the most cost-effective and secure solutions due to their wide geographic distribution, proven surface facilities, and less ambiguous site evaluation. They also require less cushion gas as the native residual gases serve as a buffer for pressure maintenance during storage. However, there is a lack of thorough understanding of this technology. This work aims to provide …

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Advanced Materials For High Performance Lithium-Sulfur Batteries, Jian Yang Apr 2023

Advanced Materials For High Performance Lithium-Sulfur Batteries, Jian Yang

Dissertations

With the advantages of high capacity and low cost, lithium-sulfur batteries (LSBs) have been considered as one of the most promising candidates for next-generation batteries. However, the wide adoption of LSBs to the commercial markets is limited due to the fast capacity decay and low utilization of sulfur. To address these issues, advanced cathodes with high electronic conductivity and strong affinity to elemental sulfur and lithium polysulfides, which are intermediate products during the charge/discharge process, have been developed in this program. Carbon aerogels (RFCs) with controllable porous architectures have been fabricated through adjusting the process parameters and used as the …

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Targeting Lncrna Ddit4-As1 Sensitizes Triple Negative Breast Cancer To Chemotherapy Via Suppressing Of Autophagy, Ting Jiang, Jiaojiao Zhu, Shilong Jiang, Zonglin Chen, Ping Xu, Rong Gong, Changxin Zhong, Yueying Cheng, Xinyuan Sun, Wenjun Yi, Jinming Yang, Wenhu Zhou, Yan Cheng Apr 2023

Targeting Lncrna Ddit4-As1 Sensitizes Triple Negative Breast Cancer To Chemotherapy Via Suppressing Of Autophagy, Ting Jiang, Jiaojiao Zhu, Shilong Jiang, Zonglin Chen, Ping Xu, Rong Gong, Changxin Zhong, Yueying Cheng, Xinyuan Sun, Wenjun Yi, Jinming Yang, Wenhu Zhou, Yan Cheng

Markey Cancer Center Faculty Publications

In this study, it is found that the lncRNA, DNA damage inducible transcript 4 antisense RNA1 (DDIT4-AS1), is highly expressed in triple-negative breast cancer (TNBC) cell lines and tissues due to H3K27 acetylation in the promoter region, and promotes the proliferation, migration, and invasion of TNBC cells via activating autophagy. Mechanistically, it is shown that DDIT4-AS1 induces autophagy by stabilizing DDIT4 mRNA via recruiting the RNA binding protein AUF1 and promoting the interaction between DDIT4 mRNA and AUF1, thereby inhibiting mTOR signaling pathway. Furthermore, silencing of DDIT4-AS1 enhances the sensitivity of TNBC cells to chemotherapeutic agents such as paclitaxel both …

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Development And The Use Of A New Kinetically Limited Linear Driving Force Model For Diffusion-Based Adsorptive Separations, Sulaimon Adedayo Adegunju Apr 2023

Development And The Use Of A New Kinetically Limited Linear Driving Force Model For Diffusion-Based Adsorptive Separations, Sulaimon Adedayo Adegunju

Theses and Dissertations

A new kinetically limited linear driving force (KLLDF) model, in terms of a modified extended Langmuir (EL) isotherm, was developed. This KLLDF model augments the equilibrium driving force in the linear driving force (LDF) model in such a way that the equilibrium loading of each component in the LDF model depends on the actual, kinetically limited, loading of the other components in a gas mixture, not their partial pressures. In contrast, the LDF model assumes the presence of a slower diffusing adsorbate in a gas mixture affects the equilibrium of a faster diffusing adsorbate in a pore structure via its …

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Design Of A Tvsa Cycle For Co2 Removal From Spacecraft Cabins Using A Structured Adsorbent, Pravin Bosco Charles Antony Amalraj Apr 2023

Design Of A Tvsa Cycle For Co2 Removal From Spacecraft Cabins Using A Structured Adsorbent, Pravin Bosco Charles Antony Amalraj

Theses and Dissertations

Pressure Swing Adsorption (PSA) and Temperature Swing Adsorption (TSA) are some of the most used cyclic adsorption technologies that is used for separating gas components from its mixture. Carbon Dioxide Removal Assembly (CDRA) in the International Space Station (ISS) facilitates the continuous removal of CO2 by the cyclic adsorption process. The use of structured adsorbents has drawn attention due its several advantages over traditional beaded adsorbents. This work evaluates the role of different design variables on the effective thermal conductivity of a structured adsorbent bed for its possible application in a temperature swing adsorption (TVSA) process for space applications. The …

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New Perspectives And Insights Into Direct Epoxidation Of C3H6 Using O2 And Ag Based Catalysts And Measurement Of Active Ag Site Concentration Of Promoted Ag Catalyst For C2H4 Epoxidation By H2 Pulse Titration Over Oxygen Pre-Covered Surface, Md Masudur Rahman Apr 2023

New Perspectives And Insights Into Direct Epoxidation Of C3H6 Using O2 And Ag Based Catalysts And Measurement Of Active Ag Site Concentration Of Promoted Ag Catalyst For C2H4 Epoxidation By H2 Pulse Titration Over Oxygen Pre-Covered Surface, Md Masudur Rahman

Theses and Dissertations

Direct epoxidation of C3H6 using molecular O2 and Ag catalysts to produce propylene oxide (PO) selectively is a long-sought goal in the field of heterogeneous catalysis. In the early 1990’s Scientists at ARCO reported promising results of 58 – 59% selectivity to PO at 3.2% conversion of C3H6 over an unusual composition of 54.0 wt% Ag, 2.0 wt% K+, 0.5 wt% Mo and balance CaCO3. Feed additives of ethyl chloride (EtCl), nitric oxide (NO) and CO2 were stated necessary to achieve the claimed high PO selectivities. The roles …

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Mathematical Analysis Of Electrochemical Systems, Shiv Krishna Reddy Madi Reddy Apr 2023

Mathematical Analysis Of Electrochemical Systems, Shiv Krishna Reddy Madi Reddy

Theses and Dissertations

A solid electrolyte interphase (SEI) growth model is developed in a mixed modethat contains solvent diffusion through the SEI layer and corresponding solvent reduction kinetics at the SEI/electrode interface. The governing equations are solved by the Landau transformation, which makes the moving layer fixed to predict the open circuit potential, SEI layer thickness, and capacity loss. The estimated parameters fitted with experimental data from the literature are computed using COMSOL and MATLAB. Results show that the mixed mode model predicts lower capacity loss and thinner SEI layer due to its growth under open circuit conditions than previously reported by others. …

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Hydrothermal Liquefaction Of Saccharina Latissima For The Production Of Biofuel, Mayokun A. Oke Apr 2023

Hydrothermal Liquefaction Of Saccharina Latissima For The Production Of Biofuel, Mayokun A. Oke

Mechanical Engineering Theses

We performed hydrothermal liquefaction of brown macroalga (Saccharina latissima) in the presence of homogenous and heterogenous catalysts such as KOH, Na2CO3, Pd/C, HZSM-5, Ce/HZSM-5, and Ni/SiO2-Al2O3 in hot compressed water, to investigate their effects on product yield and composition in the biocrude. To investigate hydrocarbon production, we used methanol as co-solvent (methanol-to-water 1/4 vol.%) and as the only liquefaction solvent. We carried out the experiments in a batch reactor at 330oC and 120-130 bar, and varying temperature, algae-to-water ratio, residence time, and pretreatment method. The biocrude yields …

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Biodegradable Preformed Particle Gel (Ppg) Made Of Natural Chitosan Material For Water Shut-Off Application, Reem Elaf, Ahmed Ben Ali, Mohammed Saad, Ibnelwaleed A. Hussein, Hassan Nimir, Baojun Bai Apr 2023

Biodegradable Preformed Particle Gel (Ppg) Made Of Natural Chitosan Material For Water Shut-Off Application, Reem Elaf, Ahmed Ben Ali, Mohammed Saad, Ibnelwaleed A. Hussein, Hassan Nimir, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Oil and Gas Extraction Frequently Produces Substantial Volumes of Produced Water, Leading to Several Mechanical and Environmental Issues. Several Methods Have Been Applied over Decades, Including Chemical Processes Such as In-Situ Crosslinked Polymer Gel and Preformed Particle Gel, Which Are the Most Effective Nowadays. This Study Developed a Green and Biodegradable PPG Made of PAM and Chitosan as a Blocking Agent for Water Shutoff, Which Will Contribute to Combating the Toxicity of Several Commercially Used PPGs. the Applicability of Chitosan to Act as a Crosslinker Has Been Confirmed by FTIR Spectroscopy and Observed by Scanning Electron Microscopy. Extensive Swelling Capacity …

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Estimating Aquifer System Storage Loss With Water Levels, Pumping And Insar Data In The Parowan Valley, Utah, Ryan G. Smith, Jiawei Li, Katherine R. Grote, Jim Butler Apr 2023

Estimating Aquifer System Storage Loss With Water Levels, Pumping And Insar Data In The Parowan Valley, Utah, Ryan G. Smith, Jiawei Li, Katherine R. Grote, Jim Butler

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

In the Parowan Valley of Utah, Groundwater Levels Have Declined by as Much as 30 M over the Past 50 Years with Accompanying Subsidence Rates of Up to 5 Cm/year. Traditional Methods to Estimate Groundwater Storage Change Use a Combination of Groundwater Level and Storativity Estimates, But There is Often Considerable Uncertainty in These. in This Study, We Demonstrate a New Method that Relies on a Combination of Geodetic Data from InSAR, as Well as Groundwater Level and Pumping Data, to Estimate Both the Total Groundwater Storage Loss and the Percentages of Storage Loss in Fine- and Coarse-Grained Layers within …

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Laboratory Comparative Study Of Anionic And Cationic High-Viscosity Friction Reducers In Moderate To Extremely High Total Dissolved Solids Environments, Xiaojing Ge, Abdulmohsin Imqam Apr 2023

Laboratory Comparative Study Of Anionic And Cationic High-Viscosity Friction Reducers In Moderate To Extremely High Total Dissolved Solids Environments, Xiaojing Ge, Abdulmohsin Imqam

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

High-Viscosity Friction Reducers (HVFRs) Have Been Recently Gaining More Attention and Increasing in Use, Not Only as Friction-Reducing Agents But Also as Proppant Carriers. Reusing Produced Water Has Also Been Driven by Both Environmental and Economic Benefits. Currently, Most Friction Reducers on the Market Are Anionic Friction Reducers, Which Are Fully Compatible with Most Produced Water with Low to Medium Level of Total Dissolved Solids (TDS) But Show a Significant Drop at High TDS Conditions in Terms of their Friction Reduction Performance in Most Cases. on the Contrary, Cationic Friction Reducers Are Believed to Have Better TDS Tolerance and Friction …

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Organic Matter Assessment And Paleoenvironmental Changes Of The Middle Jurassic Main Source Rocks (Khatatba Formation) In The North Western Desert, Egypt: Palynofacies And Palynomorph Perspectives, Ahmed Mansour, Sameh S. Tahoun, Aya Raafat, Mohamed S. Ahmed, Francisca Oboh-Ikuenobe, Thomas Gentzis, Xiugen Fu Apr 2023

Organic Matter Assessment And Paleoenvironmental Changes Of The Middle Jurassic Main Source Rocks (Khatatba Formation) In The North Western Desert, Egypt: Palynofacies And Palynomorph Perspectives, Ahmed Mansour, Sameh S. Tahoun, Aya Raafat, Mohamed S. Ahmed, Francisca Oboh-Ikuenobe, Thomas Gentzis, Xiugen Fu

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The Middle Jurassic in the north Western Desert, Egypt, was a time of complex tectonics and increased environmental perturbations attributed to the predominant sedimentation of organic carbon-rich fine siliciclastic and carbonate deposits of the Khatatba Formation. Although some studies have addressed the hydrocarbon potential and source rock characteristics of the Khatatba Formation, a regional-scale investigation of the prevalent paleoenvironmental conditions and organic matter characteristics is still necessary. In this study, the Khatatba Formation is investigated for detailed palynofacies analysis and palynomorph composition to assess organic matter kerogen types and reconstruct the depositional paleoenvironmental patterns on a regional scale. For this …

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The Impact Of Using Tanks For The Equalization Step On The Performance Of A Psa Process, Behnam Fakhari Kisomi Apr 2023

The Impact Of Using Tanks For The Equalization Step On The Performance Of A Psa Process, Behnam Fakhari Kisomi

Theses and Dissertations

The pressure equalization step between two adsorption beds is a key cycle step in many pressure swing adsorption (PSA) processes. It involves connecting two beds together, or two beds and a tank as a medium. The utilization of tanks for equalization in a bed-to-tank-to-bed (BTB) configuration could be advantageous to reduce the number of beds in PSA cycle. In this study, a binary gas mixture A and B, with A more strongly adsorbed than B, was used for the investigation of Stafstrom-type PSA cycles with bed-to-bed (BB) and bed-to-tank-to-bed (BTB) equalization steps using linear isotherm and isothermal equilibrium theory. For …

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Integrated Experimental And Dft Study Of Palladium And Nickel Metals Supported On Reducible Metallic Oxides For Selective Hydrogenation Of Alkynes And Dienes Bonds, Toyin Daniel Shittu Apr 2023

Integrated Experimental And Dft Study Of Palladium And Nickel Metals Supported On Reducible Metallic Oxides For Selective Hydrogenation Of Alkynes And Dienes Bonds, Toyin Daniel Shittu

Dissertations

This dissertation investigates the capacity of ceria (CeO2) to serve as a stand-alone reactive catalyst, and to act as catalyst support for different catalyst configurations. Experimental and density functional theory (DFT) approach were used to critically predict and to design ceria-containing catalysts. Ceria owes the catalytic propensity to the ability to undergo switch in the oxidation state from the +4 to +3 states. Motivated by experimental studies involving CeO2 catalysts, defects CeO2 surface with an oxygen vacancy (CeO2(111)_Vo) was used to explore the decomposition chemistry of methanethiol based on DFT. The potential formation pathways revealed that …

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Clickable Polymer Scaffolds Enable Ce Recovery With Peptide Ligands, Jacob D. Hostert, Maura R. Sepesy, Christine E. Duval, Julie N. Renner Mar 2023

Clickable Polymer Scaffolds Enable Ce Recovery With Peptide Ligands, Jacob D. Hostert, Maura R. Sepesy, Christine E. Duval, Julie N. Renner

Faculty Scholarship

Rare earth elements (REEs) are a vital part of many technologies with particular importance to the renewable energy sector and there is a pressing need for environmentally friendly and sustainable processes to recover and recycle them from waste streams. Functionalized polymer scaffolds are a promising means to recover REEs due to the ability to engineer both transport properties of the porous material and specificity for target ions. In this work, REE adsorbing polymer scaffolds were synthesized by first introducing poly(glycidyl methacrylate) (GMA) brushes onto porous polyvinylidene fluoride (PVDF) surface through activator generated electron transfer atom transfer radical polymerization (AGET ATRP). …

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Improved Selectivity And Stability In Methane Dry Reforming By Atomic Layer Deposition Onto Ni-Ceo2-Zro2/Al2o3 Catalysts, Jonathan Lucas Mar 2023

Improved Selectivity And Stability In Methane Dry Reforming By Atomic Layer Deposition Onto Ni-Ceo2-Zro2/Al2o3 Catalysts, Jonathan Lucas

LSU Master's Theses

The use of Ni in the dry reforming of methane (DRM) has been widely studied as a replacement for noble metal catalysts (Pt, Pd, Rh) due to Ni’s low cost compared to noble metals, its abundance, and the fact that its DRM activity is near that of noble metal catalysts. However, Ni has been shown to deactivate quickly under DRM conditions. Rare earth oxides such as CeO2, or as CeO2-ZrO2 (CZO) are supports that improve both the activity and stability of Ni DRM systems due to their redox activity. However, this same activity is thought …

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Sustainable Design And Systems Medicine Laboratory, Kirti Maheshkumar Yenkie Mar 2023

Sustainable Design And Systems Medicine Laboratory, Kirti Maheshkumar Yenkie

Henry M. Rowan College of Engineering Departmental Research

No abstract provided.

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Bimetallic Compound Catalysts With Multiple Active Centers For Accelerated Polysulfide Conversion In Li-S Batteries, Wu-Xing Hua, Jing-Yi Xia, Zhong-Hao Hu, Huan Li, Wei Lv, Quan-Hong Yang Mar 2023

Bimetallic Compound Catalysts With Multiple Active Centers For Accelerated Polysulfide Conversion In Li-S Batteries, Wu-Xing Hua, Jing-Yi Xia, Zhong-Hao Hu, Huan Li, Wei Lv, Quan-Hong Yang

Journal of Electrochemistry

Practical applications of lithium-sulfur (Li-S) batteries are hindered mainly by the low sulfur utilization and severe capacity fading derived from the polysulfide shuttling. Catalysis is an effective remedy to those problems by promoting the conversion of polysulfides to reduce their accumulation in the electrolyte, which needs the catalyst to have efficient adsorption ability to soluble polysulfides and high activity for their conversion. In this work, we have proposed a bimetallic compound of NiCo2S4 anchored onto sulfur-doped graphene (NCS@SG) to fabricate a catalytic interlayer for Li-S batteries. Compared to CoS, the NiCo2S4 demonstrated much higher …

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Scale-Up Of Perovskite Oxides For Conversion Of Co2 To Co Through Reverse Water-Gas Shift Chemical Looping, Hanzhong Shi Mar 2023

Scale-Up Of Perovskite Oxides For Conversion Of Co2 To Co Through Reverse Water-Gas Shift Chemical Looping, Hanzhong Shi

USF Tampa Graduate Theses and Dissertations

CO2 conversion to CO has the benefit of further conversion to hydrocarbon-based fuels and chemicals. Due to CO2 being an important greenhouse gas, its conversion to CO and an increase of the carbon cycling will help reduce the greenhouse effect. Reverse water-gas shift chemical looping (RWSG-CL) is a two-step process that can be employed for the conversion of CO2 to CO. The first step involves partial reduction of oxygen by hydrogen to form oxygen vacant oxide, and the second step is the conversion of CO2 to CO over these partially reduced materials to regain their original structures. The RWSG-CL process …

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Application Of Pinch Analysis For Energy Saving And Reducing Gas Emissions Based On Mathematical Model In The Hydrocracking Unit, Badiea S. Babaqi Mar 2023

Application Of Pinch Analysis For Energy Saving And Reducing Gas Emissions Based On Mathematical Model In The Hydrocracking Unit, Badiea S. Babaqi

Hadhramout University Journal of Natural & Applied Sciences

Pinch analysis approach of the heat exchanger network in the hydrocracking unit was carried out to save the energy consumption and reduce the gas emissions simultaneously. This method based on mathematical model of the hydrocracking unit for a heat exchanger network using LINGO program to achieve the minimization of environmental impacts and the reduction of energy cost. The presented energy demands for the heat exchanger network are 20.38 MMBtu/hr and 26.52 MMBtu/hr for heating and cooling loads, respectively. The current analysis shows a huge opportunity in order to decrease energy consumption of the hydrocracking process at a minimum temperature difference …

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