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Articles 2341 - 2370 of 14237
Full-Text Articles in Chemical Engineering
Extraction And Characterization Of Collagen From Cattle Horns For Potential Wound Healing, Yeriko Halson
Extraction And Characterization Of Collagen From Cattle Horns For Potential Wound Healing, Yeriko Halson
Tanzania Journal of Engineering and Technology (TJET)
The need for bandages and gauze for wound dressing and healing is inevitable due to the high increase in accidents. Most of the material used for the production of bandages and gauzes for wound healing are from non-renewable synthetic material. The sustainability of non renewable resources is at jeopardy due to the health and associated environmental impact. Consequently, the use of naturally occurring and biodegradable material is a promising solution to the sustainability challenges of synthetic material. In this paper, the extraction of collagen films from cattle horns for potential wound healing is reported. Collagen was extracted from cattle horns …
Current And Future Trends Of Construction Project Performance Models: A Review, Method Mtana
Current And Future Trends Of Construction Project Performance Models: A Review, Method Mtana
Tanzania Journal of Engineering and Technology (TJET)
The construction industry (CI) has experienced outstanding growth and contributed to economic growth for many countries, with enormous foreign investments that require quality projects. High pressure to reduce the construction cost and time commonly put the industry at risk of lower quality and safety of the construction facilities. Like many other developing countries, Tanzania needs more stringent quality control measures in the construction sector to contribute positively to sustainable growth. This study thus reviews current and future trends in construction industry performance in Tanzania. The literature review on construction projects (CPs) performance is based on information on time overruns from …
Towards The Development Of A Framework For Assessing Organizational Governance Maturity For Technical Audit Of Public Works, George Haule
Towards The Development Of A Framework For Assessing Organizational Governance Maturity For Technical Audit Of Public Works, George Haule
Tanzania Journal of Engineering and Technology (TJET)
The quality of the audit work and its products is often associated with the organizational maturity of the audit function. The absence of a well-defined organizational maturity for an audit function leads to poor quality of audit work or products and ineffective audit function. The lack of a framework for measuring governance maturity was identified as a major deterrent factor to the attainment of quality audit work. Measuring the governance maturity of the technical audit of public works is challenging due to the absence of a maturity framework that fits its needs. The noted shortcomings include: (a) existing maturity frameworks …
Dynamic Multi-Dimensional Numerical Transport Study Of Lithium-Ion Battery Active Material Microstructures For Automotive Applications, Joseph S. Lopata, Taylor R. Garrick, Fengkun Wang, Han Zhang, Yangbing Zeng, Sirivatch Shimpalee
Dynamic Multi-Dimensional Numerical Transport Study Of Lithium-Ion Battery Active Material Microstructures For Automotive Applications, Joseph S. Lopata, Taylor R. Garrick, Fengkun Wang, Han Zhang, Yangbing Zeng, Sirivatch Shimpalee
Faculty Publications
In support of GM’s traction battery efforts, we derived and implemented a method to describe the electrochemical performance of a battery cell considering the nuances of the electrode microstructure at the anode and the cathode and the corresponding impact on the electrochemical transport in the solid and liquid phases. To assess the capability of the method, we compared model results from the microstructure framework with the commonly used continuum-level porous electrode model, commonly referred to as the pseudo-2-dimensional model, or the Newman Model. The microstructure modeling framework was applied to simulate the electrochemical and transport processes within the battery cell …
Cellulose-Keratin Supramolecular Composite: Conformation By Combined Fourier Transform Spectroscopy And Partial Least Square Regression Coefficient, Ngesa Ezekiel Mushi Dr
Cellulose-Keratin Supramolecular Composite: Conformation By Combined Fourier Transform Spectroscopy And Partial Least Square Regression Coefficient, Ngesa Ezekiel Mushi Dr
Tanzania Journal of Engineering and Technology (TJET)
Keratin and cellulose are important nano components with excellent mechanical and biological properties. However, the preparation route through dissolution in organic solvents to make manmade materials is challenging because of their intensive bonding interaction characteristics. Structural modification of the natural attributes is difficult to maintain after polymer regeneration. A new technique by a green route was devised to dissolve keratin from wool, hair, and feather with cellulose in situ using 1-Butyl-3-methylimidazolium chloride [BMIm] + Cl- ionic liquid as a solvent. The mixture of keratin and cellulose homogeneously and synergistically resulted in a supramolecular composite film through non-derivatized mechanochemical interactions. The …
Designing And Manufacturing Of Vegetable Slicing Machine, Juma Nuhu Msuya
Designing And Manufacturing Of Vegetable Slicing Machine, Juma Nuhu Msuya
Tanzania Journal of Engineering and Technology (TJET)
Agro-processing industry is faced with a challenge of slicing of vegetables for immediate consumption. This stems from the fact that the traditional slicing methods use bare hands, and knives. This method is faced with shortcomings of inefficiency, poor hygiene, and significant dangers to injury. If vegetables are not sliced, their drying takes longer, may possibly be spoiled, and cannot be stored for future uses. Therefore, this paper strives to design a vegetable slicing machine to increase the efficiency of the drying process as a post-processing step. The study employed a Pugh’s design model to design the machine and manufacture it. …
Modeling Of The Process Of Measuring Conversion Of The Flow Of Liquid And Gaseous Media By The Method Of Variable Pressure Drop, Shukhrat Manapovich Gulyamov, Elbek Elmirza O'G'Li Ortiqov
Modeling Of The Process Of Measuring Conversion Of The Flow Of Liquid And Gaseous Media By The Method Of Variable Pressure Drop, Shukhrat Manapovich Gulyamov, Elbek Elmirza O'G'Li Ortiqov
Chemical Technology, Control and Management
On the basis of material and heat balances, taking into account the initial and boundary conditions, a mathematical model of the process of measuring the transformation of liquid and gaseous technological media by the method of variable pressure drop is constructed. The analysis of the results of studying the influence of non-stationary flows of a controlled medium on the uncertainty of the results of measuring the flow rate of liquids and gaseous mixtures with a changing hydrodynamic structure of the flow of a controlled medium is performed. A comparative analysis of the calculated and experimental transient processes in the measuring …
Virtual Potassium Chloride Analyzer In The System Of Advanced Control Of Potash Fertilizer Production Processes, Umidjon Ruziev, Jahongir Sherboyevich Bekqulov
Virtual Potassium Chloride Analyzer In The System Of Advanced Control Of Potash Fertilizer Production Processes, Umidjon Ruziev, Jahongir Sherboyevich Bekqulov
Chemical Technology, Control and Management
It is proposed to include virtual instrumental quality analyzers of potash fertilizers in the composition of the advanced (advanced) management system. The structure of the virtual analyzer is substantiated using mathematical models of the technological process of drying potassium chloride in its composition. Based on the results of fuzzy clustering, the parameters of the modes of the technological process of drying potassium chloride are determined.
Influence Of Magnetomechanical Properties Of Ferromagnetic Materials On The Sensitivity Of A Magnetoelastic Sensor, Sulton Amirov, Kamila Komilovna Jurayeva
Influence Of Magnetomechanical Properties Of Ferromagnetic Materials On The Sensitivity Of A Magnetoelastic Sensor, Sulton Amirov, Kamila Komilovna Jurayeva
Chemical Technology, Control and Management
The requirements of high operational reliability are most fully met by automated monitoring and control systems, the elements of which are magnetoelastic sensors. Such sensors, due to their metrological characteristics, have found application in electrified railway transport, in the metallurgical, metalworking, mining and other industries. The principle of operation of such sensors is based on the fact that in the process of influencing the magnetic core of the sensor by force, there is a change in the magnetic permeability of the material, a change in the magnetic resistance of the circuit, a change in the mutual inductance coefficient of the …
Method For Solving The Kinematics Inverse Problem For Moving Along A Trajectory Objects (As An Example Of Assembly Industrial Robots), Oripjon Olimovich Zaripov, Dildora Usmonovna Sevinova
Method For Solving The Kinematics Inverse Problem For Moving Along A Trajectory Objects (As An Example Of Assembly Industrial Robots), Oripjon Olimovich Zaripov, Dildora Usmonovna Sevinova
Chemical Technology, Control and Management
The task of performing a technological operation in kinematic calculation of industrial robots and determining various kinematic parameters describing the efficiency of robots is solved. Among them, one of the urgent problems based on the analysis of the entire kinematics of the assembly industrial robot is the problem of solving the inverse problem of the kinematics of the manipulator positions, that is, the problem of determining the relative parameters that change the coordinates of the gripper according to the given position. The article presents a scheme that allows solving the inverse kinematics problem of an industrial robot manipulator moving in …
Algorithmic Methods For Developing The Structure Of A Thyristor Electric Drive For Mining Machines, N.R Yusupbekov, O.A. Jumaev, S.S. Turaev
Algorithmic Methods For Developing The Structure Of A Thyristor Electric Drive For Mining Machines, N.R Yusupbekov, O.A. Jumaev, S.S. Turaev
Chemical Technology, Control and Management
The article discusses the creation of algorithmic structures and the development of digital control systems for electric drives of mine-lifting machines, provides some concepts for creating digital control systems using thyristor converters. The analysis of the static volt-ampere characteristics of the thyristor is given, some calculations of the circuits and circuits of the thyristor converter (TP) corresponding to the different modes of operation of the TP are given, and also, based on the synthesis of the dynamic properties and characteristics of the thyristor, an algorithmic structure of the model of the thyristor converter is proposed.
Algorithms For Multi-Factory Polynomial Modeling Of Technological Processes, Farrukh Do'stmirzayevich Jo'rayev, Murodjon Ashurqulovich Ochilov
Algorithms For Multi-Factory Polynomial Modeling Of Technological Processes, Farrukh Do'stmirzayevich Jo'rayev, Murodjon Ashurqulovich Ochilov
Chemical Technology, Control and Management
The article reveals the meaning and essence of the modeling method in the study of complex technological processes based on the problematic aspects of building multifactorial relationships and the principles for their elimination. In the case of non-linearity of multifactorial connections of a complex system, the expediency of approximating such functions by polynomials is substantiated. The authors' ideas about the increasing importance of interpolation methods in practice against the background of the possibility of simplification based on the use of modern mathematical hardware and software for integration into the process of modeling and optimizing technological processes due to the complexity …
Structural Model Of The Technological Process Of Storage And Processing Of Oil Raw Materials, N.A Kabulov
Structural Model Of The Technological Process Of Storage And Processing Of Oil Raw Materials, N.A Kabulov
Chemical Technology, Control and Management
The technological method of storing and processing oilseed raw materials is structurally modelled in the article. Additionally, it is suggested that the generalized structure be presented as a three-part scheme, consisting of a raw material department, a processing shop, and transportation networks. On the basis of a thorough examination of the characteristics of the constituent parts of the technological complex, a practical model for the problem of the general characteristics of the technological complex is proposed.
Advances And Challenges On Cathode Catalysts For Lithium-Oxygen Batteries, Bo Wen, Zhuo Zhu, Fu-Jun Li
Advances And Challenges On Cathode Catalysts For Lithium-Oxygen Batteries, Bo Wen, Zhuo Zhu, Fu-Jun Li
Journal of Electrochemistry
Aprotic lithium-oxygen batteries (LOBs) with high theoretical energy density have received considerable attention over the past years. However, the oxygen reduction reaction (ORR)/oxygen evolution reaction (OER) at cathodes suffer from slow kinetics for large overvoltages in LOBs. Significant advances on catalysts have been achieved to accelerate cathode kinetics, but understanding on the formation/decomposition processes of Li2O2 is limited. Herein, this review highlights the fundamental understanding of the correlation between catalysts and formation/decomposition of Li2O2. Various types of cathode catalysts are discussed to reveal the mechanism of formation/decomposition of Li2O2, …
Recent Advances In Anode Materials Of Solid Oxide Electrolysis Cells, Geng Zou, Wei-Cheng Feng, Yue-Feng Song, Guo-Xiong Wang
Recent Advances In Anode Materials Of Solid Oxide Electrolysis Cells, Geng Zou, Wei-Cheng Feng, Yue-Feng Song, Guo-Xiong Wang
Journal of Electrochemistry
Solid oxide electrolysis cell (SOEC) as an electrochemical energy conversion device has attracted increasing attention due to its large current density, high Faradaic efficiency and energy efficiency. Oxygen evolution reaction at the anode, a four-electron transfer process, is an important half-reaction for SOEC, which contributes to the main polarization resistance and consumes most electric energy during the electrolysis process. Hence, designing anode materials with high activity and stability is crucial for the performance improvement and practical application of SOEC. Recently, some advances have been made in the development of high-performance anode. In the current review, the mechanisms for CO2 …
Preface To Special Issue On Electrocatalysis And Electrosynthesis, Fang-Yi Cheng, Shuang-Yin Wang, Tian-Hua Zhou
Preface To Special Issue On Electrocatalysis And Electrosynthesis, Fang-Yi Cheng, Shuang-Yin Wang, Tian-Hua Zhou
Journal of Electrochemistry
No abstract provided.
Anodic Electrocatalysis Of Glycerol Oxidation For Hybrid Alkali/Acid Electrolytic Hydrogen Generation, Xin Feng, Bo-Wen Liu, Ke-Xin Guo, Lin-Feng Fan, Gen-Xiang Wang, Su-Qin Ci, Zhen-Hai Wen
Anodic Electrocatalysis Of Glycerol Oxidation For Hybrid Alkali/Acid Electrolytic Hydrogen Generation, Xin Feng, Bo-Wen Liu, Ke-Xin Guo, Lin-Feng Fan, Gen-Xiang Wang, Su-Qin Ci, Zhen-Hai Wen
Journal of Electrochemistry
Electrolytic hydrogen production is heavily restricted by high-energy consumption majorly due to the relatively high potential of anodic oxygen evolution reaction (OER). Development of OER-alternative reaction at the anode has been recently proposed as a promising pathway to address the associated issues. In this work, we report a hybrid acid/alkali dual-electrolyte electrolyzer by coupling acidic hydrogen evolution reaction (HER) using commercial Pt/C cathode with alkaline Electrocatalytic glycerol oxidation (GOR) which is implemented by developing a nickel foam (NF) supporting Co3O4 nanosheets anode that shows low overpotential and high selectivity toward GOR for formate production. The hybrid acid/alkali …
Highly Dispersed Pt Nanoparticles Root In Single-Atom Fe Sites In Ldhs Toward Efficient Methanol Oxidation, Qing-Cheng Meng, Lin-Bo Jin, Meng-Ze Ma, Xue-Qing Gao, Ai-Bing Chen, Dao-Jin Zhou, Xiao-Ming Sun
Highly Dispersed Pt Nanoparticles Root In Single-Atom Fe Sites In Ldhs Toward Efficient Methanol Oxidation, Qing-Cheng Meng, Lin-Bo Jin, Meng-Ze Ma, Xue-Qing Gao, Ai-Bing Chen, Dao-Jin Zhou, Xiao-Ming Sun
Journal of Electrochemistry
Active and durable electrocatalysts for methanol oxidation reaction are of critical importance to the commercial viability of direct methanol fuel cell, which has already attracted growing popularities. However, current methanol oxidation electrocatalysts fall far short of expectations and suffer from excessive use of noble metal, mediocre activity, and rapid decay. Here we report the Pt anchored on NiFe-LDHs surface hybrid for stable methanol oxidation in alkaline media. Based on the high intrinsic methanol oxidation activity of Pt nanoparticles, the substrates NiFe-LDHs further enhanced anti-poisoning ability and maintained unaffected stability after 200,000 s cycle test compared to commercial Pt/C catalyst. The …
Design And Performance Analysis Of Dry Gas Fishbone Wells For Lower Carbon Footprint, Habib Ouadi, Aimen Laalam, Amjed Hassan, Abderraouf Chemmakh, Vamegh Rasouli, Mohamed Mahmoud
Design And Performance Analysis Of Dry Gas Fishbone Wells For Lower Carbon Footprint, Habib Ouadi, Aimen Laalam, Amjed Hassan, Abderraouf Chemmakh, Vamegh Rasouli, Mohamed Mahmoud
Petroleum Engineering Student Publications
Multilateral well drilling technology has recently assisted the drilling industry in improving borehole contact area and reducing operation time, while maintaining a competitive cost. The most advanced multilateral well drilling method is Fishbone drilling (FbD). This method has been utilized in several hydrocarbon fields worldwide, resulting in high recovery enhancement and reduced carbon emissions from drilling. FbD involves drilling several branches from laterals and can be considered as an alternative method to hydraulic fracturing to increase the stimulated reservoir volume. However, the expected productivity of applying a Fishbone well from one field to another can vary due to various challenges …
Sootlib: A Soot Model Library For Combustion Simulation, Victoria B. Stephens, Joshua Bedwell, Alex J. Josephson, Keturah Oldham, David O. Lignell
Sootlib: A Soot Model Library For Combustion Simulation, Victoria B. Stephens, Joshua Bedwell, Alex J. Josephson, Keturah Oldham, David O. Lignell
Faculty Publications
Soot formation in combustion is an important process that affects radiative heat transfer, flame temperatures, and emissions with health and environmental impacts. Soot formation involves complex chemistry for nucleation, growth, oxidation, and coagulation processes. The soot particles vary widely in size and accurate modeling requires representation of the particle size distribution (PSD). Modeling soot is not trivial, and is only one of several physical processes active in combustion systems. This paper presents a software package called SootLib, which is an open-source library for modeling soot formation and other aerosol systems. SootLib is written in C++, is documented with Doxygen, and …
Hybrid Modeling For Electrochemical Systems, Luis Alejandro Briceno-Mena
Hybrid Modeling For Electrochemical Systems, Luis Alejandro Briceno-Mena
LSU Doctoral Dissertations
The discovery of new materials like catalysts, polymeric films, and biomolecules, is driven by industrial needs such as improving reaction or separation selectivity, enhancing therapeutic effects on medical treatments, or reducing costs of replacement. However, deployment of these advances in industrial applications is often hindered by the lack of models needed for design and optimization. Due to the novelty of materials and devices, experimental data and first principles' knowledge are scarce, making it hard to build models either via data-driven or knowledge based approaches. In this context, a way to efficiently combine domain knowledge with data could provide a pathway …
Development Of A Slow-Degrading Polymerized Curcumin Coating For Intracortical Microelectrodes, Alexis M. Ziemba, Mary Clare Crochiere Woodson, Jessica L. Funnell, Douglas Wich, Bailey Balouch, Deniz Rende, Dahlia N. Amato, Jonathan Bao, Ingrid Oprea, Dominica Cao, Neda Bajalo, Evon S. Ereifej, Jeffrey R. Capadona, Edmund F. Palermo, Ryan J. Gilbert
Development Of A Slow-Degrading Polymerized Curcumin Coating For Intracortical Microelectrodes, Alexis M. Ziemba, Mary Clare Crochiere Woodson, Jessica L. Funnell, Douglas Wich, Bailey Balouch, Deniz Rende, Dahlia N. Amato, Jonathan Bao, Ingrid Oprea, Dominica Cao, Neda Bajalo, Evon S. Ereifej, Jeffrey R. Capadona, Edmund F. Palermo, Ryan J. Gilbert
Chemical and Biochemical Engineering Faculty Research & Creative Works
Intracortical microelectrodes are used with brain-computer interfaces to restore lost limb function following nervous system injury. While promising, recording ability of intracortical microelectrodes diminishes over time due, in part, to neuroinflammation. As curcumin has demonstrated neuroprotection through anti-inflammatory activity, we fabricated a 300 nm-thick intracortical microelectrode coating consisting of a polyurethane copolymer of curcumin and polyethylene glycol (PEG), denoted as poly (curcumin-PEG1000 carbamate) (PCPC). The uniform PCPC coating reduced silicon wafer hardness by two orders of magnitude and readily absorbed water within minutes, demonstrating that the coating is soft and hydrophilic in nature. Using an in vitro release model, curcumin …
Modelling And Optimization For An Operating Giant Gas Plant In Egypt, Nessren Farrag, Mohamed Shebl, Mai Fouad, Abdulaziz Abdulaziz
Modelling And Optimization For An Operating Giant Gas Plant In Egypt, Nessren Farrag, Mohamed Shebl, Mai Fouad, Abdulaziz Abdulaziz
Chemical Engineering
An Egyptian gas-producing plant located in the north of Egypt on the coast of the Mediterranean Sea near Port Said city is designed mainly to receive and treat natural gas produced from offshore wells. The plant designed capacity is around 2800 million standard cubic feet per day (MMSCFD), which gives it a highly appreciated strategic importance. The primary plant process is removing H2S associated with the produced gas using amine solutions. The plant contains seven units called gas trains, which use packed columns for the removal. An additional acid gas removal unit was involved in the early production facility, which …
A P53-Tlr3 Axis Ameliorates Pulmonary Hypertension By Inducing Bmpr2 Via Irf3, Aneel R. Bhagwani, Mehboob Ali, Bryce Piper, Mingjun Liu, Jaylen Hudson, Neil Kelly, Srimathi Bogamuwa, Hu Yang, James D. Londino, Joseph S. Bednash, Daniela Farkas, Rama K. Mallampalli, Mark R. Nicolls, John J. Ryan
A P53-Tlr3 Axis Ameliorates Pulmonary Hypertension By Inducing Bmpr2 Via Irf3, Aneel R. Bhagwani, Mehboob Ali, Bryce Piper, Mingjun Liu, Jaylen Hudson, Neil Kelly, Srimathi Bogamuwa, Hu Yang, James D. Londino, Joseph S. Bednash, Daniela Farkas, Rama K. Mallampalli, Mark R. Nicolls, John J. Ryan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Pulmonary arterial hypertension (PAH) features pathogenic and abnormal endothelial cells (ECs), and one potential origin is clonal selection. We studied the role of p53 and toll-like receptor 3 (TLR3) in clonal expansion and pulmonary hypertension (PH) via regulation of bone morphogenetic protein (BMPR2) signaling. ECs of PAH patients had reduced p53 expression. EC-specific p53 knockout exaggerated PH, and clonal expansion reduced p53 and TLR3 expression in rat lung CD117+ ECs. Reduced p53 degradation (Nutlin 3a) abolished clonal EC expansion, induced TLR3 and BMPR2, and ameliorated PH. Polyinosinic/polycytidylic acid [Poly(I:C)] increased BMPR2 signaling in ECs via enhanced binding of interferon regulatory …
An Older Diabetes-Induced Mice Model For Studying Skin Wound Healing, Carlos Poblete Jara, Guilherme Nogueira, Joseane Morari, Thaís Paulino Do Prado, Renan De Medeiros Bezerra, Lício A. Velloso, William Velander, Eliana Pereira De Araújo
An Older Diabetes-Induced Mice Model For Studying Skin Wound Healing, Carlos Poblete Jara, Guilherme Nogueira, Joseane Morari, Thaís Paulino Do Prado, Renan De Medeiros Bezerra, Lício A. Velloso, William Velander, Eliana Pereira De Araújo
Department of Chemical and Biomolecular Engineering: Faculty Publications
Advances in wound treatment depend on the availability of animal models that reflect key aspects of human wound healing physiology. To this date, the accepted mouse models do not reflect defects in the healing process for chronic wounds that are associated with type two diabetic skin ulcers. The long term, systemic physiologic stress that occurs in middle aged or older Type 2 diabetes patients is difficult to simulate in preclinical animal model. We have strived to incorporate the essential elements of this stress in a manageable mouse model: long term metabolic stress from obesity to include the effects of middle …
Turbulent Mixing Simulation Using The Hierarchical Parcel-Swapping (Hips) Model, Tommy Starick, Masoomeh Behrang, David O. Lignell, Heiko Schmidt, Alan R. Kerstein
Turbulent Mixing Simulation Using The Hierarchical Parcel-Swapping (Hips) Model, Tommy Starick, Masoomeh Behrang, David O. Lignell, Heiko Schmidt, Alan R. Kerstein
Faculty Publications
Turbulent mixing is an omnipresent phenomenon that permanently affects our everyday life. Mixing processes also
plays an important role in many industrial applications. The full resolution of all relevant flow scales often poses a major challenge to the numerical simulation and requires a modeling of the small-scale effects. In transported Probability Density Function (PDF) methods, the simplified modeling of the molecular mixing is a known weak point. At this place, the Hierarchical Parcel-Swapping (HiPS) model developed by A.R. Kerstein [J. Stat. Phys. 153, 142-161 (2013)] represents a computationally efficient and novel turbulent mixing model. HiPS simulates the effects of turbulence …
Advancing Ionomer Design To Boost Interfacial And Thin-Film Proton Conductivity Via Styrene-Calix[4]Arene-Based Ionomers, Shyambo Chatterjee, Oghenetega Allen Obewhere, Ehsan Zamani, Rajesh Keloth, Seefat Farzin, Martha D. Morton, Anandakumar Sarella, Shudipto Konika Dishari
Advancing Ionomer Design To Boost Interfacial And Thin-Film Proton Conductivity Via Styrene-Calix[4]Arene-Based Ionomers, Shyambo Chatterjee, Oghenetega Allen Obewhere, Ehsan Zamani, Rajesh Keloth, Seefat Farzin, Martha D. Morton, Anandakumar Sarella, Shudipto Konika Dishari
Department of Chemical and Biomolecular Engineering: Faculty Publications
Sub-micrometer-thick ion-conducting polymer (ionomer) layers often suffer from poor ionic conductivity at the substrate/catalyst interface. The weak proton conductivity makes the electrochemical reaction at the cathode of proton-exchange-membrane fuel cells sluggish. To address this, here we report on a class of polystyrene-based ionomers having sub-nanometer-sized, sulfonated macrocyclic calix[4]arene-based pendants (PS-calix). In films with thickness comparable to that of ionomer-based binder layers, the conductivity of PS-calix film (∼41 mS/cm) is ∼13 times higher than that of the current state-of-the-art ionomer, Nafion. We observe a similar improvement in proton conductivity when PS-calix interfaces with Pt nanoparticles, demonstrating the potential of PS-calix in …
Biofilm Formation Influences The Wettability And Settling Of Microplastics, Amber J. Pete, Philip J. Brahana, Mustapha Bello, Michael G. Benton, Bhuvnesh Bharti
Biofilm Formation Influences The Wettability And Settling Of Microplastics, Amber J. Pete, Philip J. Brahana, Mustapha Bello, Michael G. Benton, Bhuvnesh Bharti
Chemical and Biochemical Engineering Faculty Research & Creative Works
The fate of 99% of the plastics present in oceans is unknown. It is presumed that biofilm formation on plastics leads to their sinking to the ocean floor, thus making them undetectable at the surface. While it is established that biofilms lead to sinking of plastics, it is the mechanism by which biofilms enhance the vertical transport of plastics that remains unknown. It is commonly assumed that biofilms increase the effective mass density of the plastics, which drives their sinking. Here, we show that such an assumption is not always true, and formation of biofilms alone is an insufficient criterion …
Evaluation Of Liquid Loading In Gas Wells Using Machine Learning, Abderraouf Chemmakh, Olusegun Stanley Tomomewo, Kegang Ling, Ahmed Shammari
Evaluation Of Liquid Loading In Gas Wells Using Machine Learning, Abderraouf Chemmakh, Olusegun Stanley Tomomewo, Kegang Ling, Ahmed Shammari
Petroleum Engineering Student Publications
The inevitable result that gas wells witness during their life production is the liquid loading problem. The liquids that come with gas block the production tubing if the gas velocity supplied by the reservoir pressure is not enough to carry them to surface. Researchers used different theories to solve the problem naming, droplet fallback theory, liquid film reversal theory, characteristic velocity, transient simulations, and others. While there is no definitive answer on what theory is the most valid or the one that performs the best in all cases. This paper comes to involve a different approach, a combination between physics-based …
Applications Of Underbalanced Fishbone Drilling For Improved Recovery And Reduced Carbon Footprint In Unconventional Plays, Habib Ouadi, Siamak Mishani, Vamegh Rasouli
Applications Of Underbalanced Fishbone Drilling For Improved Recovery And Reduced Carbon Footprint In Unconventional Plays, Habib Ouadi, Siamak Mishani, Vamegh Rasouli
Petroleum Engineering Student Publications
Fishbone Drilling (FbD) consists of drilling several micro-holes in different directions from the main vertical or deviated wellbore. Similar to multilateral micro-hole drilling, FbD may be used to enhance hydrocarbon production in naturally fractured formations or in refracturing operations by interconnecting the existing natural fractures. When combined with underbalanced drilling using a coiled tubing rig, FbD enhances the production further by easing the natural flow of the hydrocarbon from the reservoir to the wellbore. The design aspects of the Fishbones include determining the number, length, distance between the branches, and the angle of sidetracking of the branches from the main …