Nanoscience and Nanotechnology Commons^™

Effect Of Ion Flux (Dose Rate) In Source-Drain Extension Ion Implantation For 10-Nm Node Finfet And Beyond On 300/450mm Platforms, Ming-Yi Shen

Legacy Theses & Dissertations (2009 - 2024)

The improvement of wafer equipment productivity has been a continuous effort of the semiconductor industry. Higher productivity implies lower product price, which economically drives more demand from the market. This is desired by the semiconductor manufacturing industry. By raising the ion beam current of the ion implanter for 300/450mm platforms, it is possible to increase the throughput of the ion implanter. The resulting dose rate can be comparable to the performance of conventional ion implanters or higher, depending on beam current and beam size. Thus, effects caused by higher dose rate must be investigated further. One of the major applications …

Modeling And Studying The Effect Of Texture And Elastic Anisotropy Of Copper Microstructure In Nanoscale Interconnects On Reliability In Integrated Circuits, Adarsh Basavalingappa

Legacy Theses & Dissertations (2009 - 2024)

Copper interconnects are typically polycrystalline and follow a lognormal grain size distribution. Polycrystalline copper interconnect microstructures with a lognormal grain size distribution were obtained with a Voronoi tessellation approach. The interconnect structures thus obtained were used to study grain growth mechanisms, grain boundary scattering, scattering dependent resistance of interconnects, stress evolution, vacancy migration, reliability life times, impact of orientation dependent anisotropy on various mechanisms, etc. In this work, the microstructures were used to study the impact of microstructure and elastic anisotropy of copper on thermal and electromigration induced failure.

Nanotextured Titanium Surfaces For Implants: Manufacturing And Packaging Aspects, Sachin Bhosle

Dissertations, Master's Theses and Master's Reports

It has been shown that nanotexturing the surface of otherwise smooth titanium orthopedic materials increases osteoblast proliferation in vitro, and the bone-implant contact area and pullout force in vivo. However, this prior work has not focused on the requirements for scale-up to industrial processes. This dissertation reports on titanium surface modifications by electrochemical anodization using a benign NH₄F electrolyte, and a hybrid electrolyte also containing AgF, rather than hazardous hydrofluoric acid used elsewhere. Nanotube fabrication of Ti6Al4V foils, rods, thermal plasma sprayed commercial implants, and laser and e-beam melted powder materials was demonstrated.

It was found …

Dynamic Rabi Oscillations In A Quantum Dot Embedded In A Nanobridge In The Presence Of Surface Acoustic Waves, Lev Mourokh, Achim Wixforth, Florian Beil, Max Bichler, Werner Wegscheider, Robert H. Blick

Publications and Research

A quantum dot is created within a suspended nanobridge containing a two-dimensional electron gas. The electron current through this dot exhibits well-pronounced Coulomb blockade oscillations. When surface acoustic waves (SAW) are driven through the nanobridge, Coulomb blockade peaks are shifted. To explain this feature, we derive the expressions for the quantum dot level populations and electron currents through these levels and show that SAW-induced Rabi oscillations lead to the observed phenomenology.

Tunable Nanocomposite Membranes For Water Remediation And Separations, Sebastián Hernández Sierra

Theses and Dissertations--Chemical and Materials Engineering

Nano-structured material fabrication using functionalized membranes with polyelectrolytes is a promising research field for water pollution, catalytic and mining applications. These responsive polymers react to external stimuli like temperature, pH, radiation, ionic strength or chemical composition. Such nanomaterials provide novel hybrid properties and can also be self-supported in addition to the membranes.

Polyelectrolytes (as hydrogels) have pH responsiveness. The hydrogel moieties gain or lose protons based on the pH, displaying swelling properties. These responsive materials can be exploited to synthesize metal nanoparticles in situ using their functional groups, or to immobilize other polyelectrolytes and biomolecules. Due to their properties, these …

Molecular Modeling Of Aerospace Polymer Matrices Including Carbon Nanotube-Enhanced Epoxy, Matthew Radue

Dissertations, Master's Theses and Master's Reports

Carbon fiber (CF) composites are increasingly replacing metals used in major structural parts of aircraft, spacecraft, and automobiles. The current limitations of carbon fiber composites are addressed through computational material design by modeling the salient aerospace matrix materials. Molecular Dynamics (MD) models of epoxies with and without carbon nanotube (CNT) reinforcement and models of pure bismaleimides (BMIs) were developed to elucidate structure-property relationships for improved selection and tailoring of matrices.

The influence of monomer functionality on the mechanical properties of epoxies is studied using the Reax Force Field (ReaxFF). From deformation simulations, the Young’s modulus, yield point, and Poisson’s ratio …

Surface Charge Switchable And Ph-Responsive Chitosan/Polymer Core-Shell Composite Nanoparticles For Drug Delivery Application, W. F. Huang, C. P. Tsui, M. Yang, Linxia Gu

Department of Mechanical and Materials Engineering: Faculty Publications

The mutually conflicting surface charge requirements for nanoparticles to have long circulation and good cell affinity have made the development of polymer nanoparticles for controlled drug delivery fall into a dilemma. In order to solve this problem, the first attempt has been made in this work to develop vancomycin loaded composite nanoparticles with a novel chitosan core and poly (lactide-co-glycolide) (PLGA) shell structure and with both pH-responsive and surface charge switchable properties. Spherical composite nanoparticles have been successfully fabricated through a modified emulsion-gelation method with a controllable size (316–573 nm), surface charge (–27.6–31.75 mV) and encapsulation efficiency up to 70.8%. …

Design And Field Testing Of A Combined Flaming And Cultivation Implement For Effective Weed Control, Brian D. Neilson, Chris A. Bruening, Strahinja Stepanovic, Avishek Datta, Stevan Z. Knezevic, George Gogos

Department of Mechanical and Materials Engineering: Faculty Publications

Flaming is a thermal weed control method that uses heat to control weeds within or between crop rows. Mechanical cultivation is another weed control method which undercuts weeds between crop rows, while leaving a strip of weeds within the crop row. A combination flamer/cultivator implement was designed to take advantage of the good qualities of both flaming and cultivation methods to provide a more consistent weed control than using either flaming or mechanical cultivation alone. Flaming hoods were designed in the spring of 2010 and retrofitted on an existing row crop cultivator. The flaming hoods were redesigned in the spring …

Synthesis, Characterization, And Enhanced Magnetic Properties Of Iron Carbide Nanomaterials, Brent M. Williams

Theses and Dissertations

Permanent magnets are classified as hard magnetic materials with the main purpose of generating flux for applications such as electric motors, turbines, and hard drives. High coercivity, magnetic remanence, and saturation values with high stability are some of the requirements for permanent magnets. Rare-earth magnets including neodymium and samarium based magnets are known to have superior magnetic properties due to their high magnetocrystalline anisotropy. However, due to the price of rare-earth materials development of alternate permanent magnets composed of inexpensive materials is an ongoing process. Previously cobalt carbide (Co_xC) have shown promise as a potential rare-earth free magnet …

Methods , Systems , And Devices Relating To Robotic Surgical Devices , End Effectors , And Controllers, Shane M. Farritor, Thomas Frederick, Joe Bartels, Eric Markvicka, Jack Mondry

Department of Mechanical and Materials Engineering: Faculty Publications

The various embodiments disclosed herein relate to improved robotic surgical systems, including robotic surgical devices having improved arm components and/or bio metric sensors, contact detection systems for robotic surgical devices, gross positioning systems and devices for use in robotic surgical systems, and improved external controllers and consoles.

Fabrication Of Flexible, Biofunctional Architectures From Silk Proteins, Ramendra K. Pal

Theses and Dissertations

Advances in the biomedical field require functional materials and processes that can lead to devices that are biocompatible, and biodegradable while maintaining high performance and mechanical conformability. In this context, a current shift in focus is towards natural polymers as not only the structural but also functional components of such devices. This poses material-specific functionalization and fabrication related questions in the design and fabrication of such systems. Silk protein biopolymers from the silkworm show tremendous promise in this regard due to intrinsic properties: mechanical performance, optical transparency, biocompatibility, biodegradability, processability, and the ability to entrap and stabilize biomolecules. The unique …

Low-Temperature Fabrication Process For Integrated High-Aspect Ratio Metal Oxide Nanostructure Semiconductor Gas Sensors, William Paul Clavijo

Theses and Dissertations

This work presents a new low-temperature fabrication process of metal oxide nanostructures that allows high-aspect ratio zinc oxide (ZnO) and titanium dioxide (TiO₂) nanowires and nanotubes to be readily integrated with microelectronic devices for sensor applications. This process relies on a new method of forming a close-packed array of self-assembled high-aspect-ratio nanopores in an anodized aluminum oxide (AAO) template in a thin (2.5 µm) aluminum film deposited on a silicon and lithium niobate substrate (LiNbO₃). This technique is in sharp contrast to traditional free-standing thick film methods and the use of an integrated thin aluminum film …

Theoretical Studies On Electronic Properties Of Curved Graphene Quantum Dots And Lithium Adsorption On Graphene Quantum Dots, Naruwan Pattarapongdilok

Chulalongkorn University Theses and Dissertations (Chula ETD)

Graphene quantum dots (GQDs), with their attractive properties, are of interest to apply for electronic devices. Therefore, this dissertation aimed to investigate the electronic of curved graphene quantum dots (CGQDs) and the adsorption of lithium on GQDs. For the first part, two shapes of flat GQDs, rhomboidal (RGQDs) and hexagonal (HGQDs), were modified to make CGQDs with different folding axes and angles. Stabilities and electronic properties of CGQDs were studied using PBE/DNP. The results showed that the deformation energies of GQDs depend on sizes and folding axes but not their shapes. HOMO-LUMO gap variations, both widening and narrowing the gap, …

Utilization Of Bio-Renewable Lignin In Building High Capacity, Durable, And Low-Cost Silicon-Based Negative Electrodes For Lithium-Ion Batteries, Tao Chen

Theses and Dissertations--Chemical and Materials Engineering

Silicon-based electrodes are the most promising negative electrodes for the next generation high capacity lithium ion batteries (LIB) as silicon provides a theoretical capacity of 3579 mAh g^-1, more than 10 times higher than that of the state-of-the-art graphite negative electrodes. However, silicon-based electrodes suffer from poor cycle life due to large volume expansion and contraction during lithiation/delithiation. In order to improve the electrochemical performance a number of strategies have been employed, such as dispersion of silicon in active/inactive matrixes, devising of novel nanostructures, and various coatings for protection. Amongst these strategies, silicon-carbon coating based composites are one …

Deconvolving The Steps To Control Morphology, Composition, And Structure, In The Synthesis Of High-Aspect-Ratio Metal Oxide Nanomaterials, Lei Yu

Theses and Dissertations--Chemistry

Metal oxides are of interest not only because of their huge abundance but also for their many applications such as for electrocatalysts, gas sensors, diodes, solar cells and lithium ion batteries (LIBs). Nano-sized metal oxides are especially desirable since they have larger surface-to-volume ratios advantageous for catalytic properties, and can display size and shape confinement properties such as magnetism. Thus, it is very important to explore the synthetic methods for these materials. It is essential, therefore, to understand the reaction mechanisms to create these materials, both on the nanoscale, and in real-time, to have design control of materials with desired …

Molecular Dynamics Studies Of Crystal Growth Phenomena In Cdte Based Heterostructures, Rodolfo Aguirre Ii

Open Access Theses & Dissertations

Cadmium telluride (CdTe) is a material used to make solar cells because it absorbs the sunlight very efficiently and converts it into electricity. However, CdTe modules suffer from degradation of 1% over a period of 1 year. Improvements on the efficiency and stability can be achieved by designing better materials at the atomic scale. Experimental techniques to study materials at the atomic scale, such as Atomic Probe Tomography (APT) and Transmission Electron Microscope (TEM) are expensive and time consuming. On the other hand, Molecular Dynamics (MD) offers an inexpensive and fast computer simulation technique to study the growth evolution of …

Dynamic Transition Of Vortices Into Phase Slips And Generation Of Vortex-Antivortex Pairs In Thin Film Josephson Junctions Under Dc And Ac Currents, Ahmad Sheikhzada, Alex Gurevich

Physics Faculty Publications

We present theoretical and numerical investigations of vortices driven by strong dc and ac currents in long Josephson junctions described by a nonlinear integro-differential equation which takes into account nonlocal electrodynamics of films, vortex bremsstrahlung, and Cherenkov radiation amplified by the attraction of vortices to the edges of the junction. This work focuses on the dynamics of vortices in Josephson junctions in thin films where the effects of Josephson nonlocality are essential but London screening is negligible. We obtained an exact solution for a vortex driven by an arbitrary time-dependent current in an overdamped junction where the vortex turns into …

Vorticella: A Protozoan For Bio-Inspired Engineering, Sangjin Ryu, Rachel E. Pepper, Moeto Nagai, Danielle C. France

Department of Mechanical and Materials Engineering: Faculty Publications

In this review, we introduce Vorticella as a model biological micromachine for microscale engineering systems. Vorticella has two motile organelles: the oral cilia of the zooid and the contractile spasmoneme in the stalk. The oral cilia beat periodically, generating a water flow that translates food particles toward the animal at speeds in the order of 0.1–1 mm/s. The ciliary flow of Vorticella has been characterized by experimental measurement and theoretical modeling, and tested for flow control and mixing in microfluidic systems. The spasmoneme contracts in a few milliseconds, coiling the stalk and moving the zooid at 15–90 mm/s. Because the …

Controllable Energy Absorption Of Double Sided Corrugated Tubes Under Axial Crushing, Hozhabr Mozafari, Shengmao Lin, Linxia Gu

Department of Mechanical and Materials Engineering: Faculty Publications

To maximize the controllable energy absorption of corrugation troughs as observed in the single sided corrugated (SSC) tube, we proposed and tested a new structure design, i.e., double-sided corrugated (DSC) tube made of Al 6060-T6 aluminum alloy or CF1263 carbon/epoxy composite. Finite element models were developed to test the mechanical advantage of the DSC tube in comparison with both SSC and classical straight (S) tubes under axial crushing. Results have shown that the total absorbed energy of the DSC aluminum tube with 14 corrugations was 330% and 32% higher than that of the SSC tube with 14 corrugations and the …

Novel Polyethylene Fibers Of Very High Thermal Conductivity Enabled By Amorphous Restructuring, Bowen Zhu, Jing Liu, Tianyu Wang, Shah R. Valloppilly, Shen Xu, Xinwei Wang

Department of Mechanical and Materials Engineering: Faculty Publications

High-thermal-conductivity polymers are very sought after for applications in various thermal management systems. Although improving crystallinity is a common way for increasing the thermal conductivity (k) of polymers, it has very limited capacity when the crystallinity is already high. In this work, by heat-stretching a highly crystalline microfiber, a significant k enhancement is observed. More interestingly, it coincides with a reduction in crystallinity. The sample is a Spectra S-900 ultrahigh-molecular-weight polyethylene (UHMW-PE) microfiber of 92% crystallinity and high degree of orientation. The optimum stretching condition is 131.5 °C, with a strain rate of 0.0129 s−1 to a low strain ratio …