Nanoscience and Nanotechnology Commons^™

Clustering On Magnesium Surfaces – Formation And Diffusion Energies, Haijian Chu, Hanchen Huang, Jian Wang

Department of Mechanical and Materials Engineering: Faculty Publications

The formation and diffusion energies of atomic clusters on Mg surfaces determine the surface roughness and formation of faulted structure, which in turn affect the mechanical deformation of Mg. This paper reports first principles density function theory (DFT) based quantum mechanics calculation results of atomic clustering on the low energy surfaces {0001} and {1011}. In parallel, molecular statics calculations serve to test the validity of two interatomic potentials and to extend the scope of the DFT studies. On a {0001} surface, a compact cluster consisting of few than three atoms energetically prefers a facecentered- cubic stacking, to serve as a …

Review Of Sustainability Issues In Non-Traditional Machining Processes, Kamlakar Rajurkar, H. Hadidi, J. Pariti, G. C. Reddy

Department of Mechanical and Materials Engineering: Faculty Publications

Non-traditional machining processes (such as EDM and ECM) provide alternatives or sometimes the only alternative in generating highly complex 3-D features in very difficult-to -machine materials. This paper reviews recently published work on sustainability issues related to these processes. For example in Electrochemical machining (ECM) the effect of sludge generation and selection of dielectric in Electrodischarge machining (EDM) need to be investigated from the sustainability point of view. All processes need to be studied not only for resulting productivity and accuracy but also their environmental impact during product generation and usage. This paper addresses process mechanisms, surface integrity, sensing and …

Accommodation Of The Human Lens Capsule Using A Finite Element Model Based On Nonlinear Regionally Anisotropic Biomembranes, G. David, Ryan M. Pedrigi, J. D. Humphrey

Department of Mechanical and Materials Engineering: Faculty Publications

Accommodation of the eyes, the mechanism that allows humans to focus their vision on near objects, naturally diminishes with age via presbyopia. People who have undergone cataract surgery, using current surgical methods and artificial lens implants, are also left without the ability to accommodate. The process of accommodation is generally well known; however the specific mechanical details have not been adequately explained due to difficulties and consequences of performing in vivo studies. Most studies have modeled the mechanics of accommodation under assumptions of a linearly elastic, isotropic, homogenous lens and lens capsule. Recent experimental and numerical studies showed that the …

Growth Mechanisms Of Multiscale, Mound-Like Surface Structures On Titanium By Femtosecond Laser Processing, Edwin Peng, Ryan Bell, Craig A. Zuhlke, Meiyu Wang, Dennis R. Alexander, George Gogos, Jeffrey E. Shield

Department of Mechanical and Materials Engineering: Faculty Publications

Femtosecond laser surface processing (FLSP) can be used to functionalize many surfaces, imparting specialized properties such as increased broadband optical absorption or superhydrophobicity/-hydrophilicity. In this study, the subsurface microstructure of a series of mound-like FLSP structures formed on commercially pure titanium using five combinations of laser fluence and cumulative pulse counts was studied. Using a dual beam Scanning Electron Microscope with a Focused Ion Beam, the subsurface microstructure for each FLSP structure type was revealed by cross-sectioning. The microstructure of the mounds formed using the lowest fluence value consists of the original Ti grains. This is evidence that preferential laser …

Design And Field Testing Of A Combined Flaming And Cultivation Implement For Effective Weed Control, Brian D. Neilson, Chris A. Bruening, Strahinja Stepanovic, Avishek Datta, Stevan Z. Knezevic, George Gogos

Department of Mechanical and Materials Engineering: Faculty Publications

Flaming is a thermal weed control method that uses heat to control weeds within or between crop rows. Mechanical cultivation is another weed control method which undercuts weeds between crop rows, while leaving a strip of weeds within the crop row. A combination flamer/cultivator implement was designed to take advantage of the good qualities of both flaming and cultivation methods to provide a more consistent weed control than using either flaming or mechanical cultivation alone. Flaming hoods were designed in the spring of 2010 and retrofitted on an existing row crop cultivator. The flaming hoods were redesigned in the spring …

Robotic Surgical Devices, Systems, And Related Methods, Shane M. Farritor, Erik Mumm, Philip Chu, Nishant Kumar, Jason Dumpert, Yutaka Tsutano

Department of Mechanical and Materials Engineering: Faculty Publications

The embodiments disclosed herein relate to various medical device components, including components that can be incorporated into robotic and/or in vivo medical devices. Certain embodiments include various modular medical devices for in vivo medical procedures.

Methods , Systems , And Devices Relating To Surgical End Effectors, Shane M. Farritor, Tom Fredrick, Joe Bartels

Department of Mechanical and Materials Engineering: Faculty Publications

The embodiments disclosed herein relate to various medical device components, including components that can be incorporated into robotic and/or in vivo medical devices, and more specifically including end effectors that can be incorporated into such devices. Certain end effector embodiments include various vessel cautery devices that have rotational movement as well as cautery and cutting functions while maintaining a relatively compact structure. Other end effector embodiments include various end effector devices that have more than one end effector.

System For Imaging And Measuring Rail Deflection, Shane M. Farritor

Department of Mechanical and Materials Engineering: Faculty Publications

Devices, systems, and methods for imaging and measuring deflections in structures such as railroad rail are disclosed. One exemplary embodiment relates to a vision system having a high-speed, visible-light imaging camera and an evaluation unit configured for analyzing images from the camera to detect geometric variations in the structure. In a second example, additional sensors are used to identify the wheel location(s) in the same reference frame as the mea Surement system. In analyzing structures Such as railroad track rail, the imaging camera can be coupled to a moving rail vehicle and configured for generating images of the rail as …

Effect Of Random Ethylene Comonomer On Relaxation Of Flow-Induced Precursors In Isotactic Polypropylene, Benjamin Schammé, Eric Dargent, Lucia Fernandez-Ballester

Department of Mechanical and Materials Engineering: Faculty Publications

The effect of comonomer on structure and relaxation of flow-induced precursors was investigated in a series of isotactic polypropylene and random propylene−ethylene copolymers. The polymers were subjected to flow by fiber pulling and allowed to relax above their nominal melting temperature for specific times. The type of morphology developed after cooling revealed whether flow-induced precursors were still present or the melt had fully reequilibrated. Precursors were long-lived and, at fixed temperature, decayed significantly faster with higher ethylene content. The critical time for precursor relaxation followed an Arrhenius-type dependence with temperature. The apparent energy of activation for precursor dissolution decreased with …

Rapidly Solidified Rare-Earth Permanent Magnets: Processing, Properties, And Applications, Shampa Aich, Dillip K. Satapathy, Jeffrey E. Shield

Department of Mechanical and Materials Engineering: Faculty Publications

Rapidly solidified rare-earth-based permanent magnets are considered to have better potential as permanent magnets compared to the conventional bulk materials, which can be attributed to their improved microstructure and better magnetic properties compared to rare-earth magnets synthesized by the conventional (powder metallurgy) routes. The performance (quality) of these magnets depends on the thermodynamics and kinetics of the different processing routes, such as atomization, melt spinning, and melt extraction. Here, we review the various processing routes of rapidly solidified rare-earth permanent magnets and the related properties and applications. In the review, some specific alloy systems, such as Sm–Co-based alloys, Nd–Fe–B, and …

Biodegradable Elastic Nanofibrous Platforms With Integrated Flexible Heaters For On-Demand Drug Delivery, Ali Tamayol, Alireza Hassani Najafabadi, Pooria Mostafalu, Ali K. Yetisen, Mattia Commotto, Musab Aldhahri, Mohamed Shaaban Abdel-Wahab, Zeynab Izadi Najafabadi, Shahrzad Latifi, Mohsen Akbari, Nasim Annabi, Seok Hyun Yun, Adnan Memic, Mehmet R. Dokmeci, Ali Khademhosseini

Department of Mechanical and Materials Engineering: Faculty Publications

Delivery of drugs with controlled temporal profiles is essential for wound treatment and regenerative medicine applications. For example, bacterial infection is a key challenge in the treatment of chronic and deep wounds. Current treatment strategies are based on systemic administration of high doses of antibiotics, which result in side effects and drug resistance. On-demand delivery of drugs with controlled temporal profile is highly desirable. Here, we have developed thermally controllable, antibiotic-releasing nanofibrous sheets. Poly(glycerol sebacate)- poly(caprolactone) (PGS-PCL) blends were electrospun to form elastic polymeric sheets with fiber diameters ranging from 350 to 1100 nm and substrates with a tensile modulus …

Nondestructive Testing System Design For Biological Product Based On Vibration Signal Analysis Of Acceleration Sensor, Xiaohao Li, Tao Shen

Department of Mechanical and Materials Engineering: Faculty Publications

In order to reduce the disadvantages of current biological product quality testing methods, taking the quality testing in cocoon trade markets as an example, this paper has proposed a quality nondestructive testing method for biological products based on the analysis of vibration signal from acceleration sensors. According to the wavelet transformation analysis on the random vibration signal acquired from the acceleration sensor, the random vibration signal related to the silkworm chrysalis quality has been analyzed and reconstructed; then the characteristic values such as: mean value, variance, mean square root, waveform index, pulse factor, and so on of the quality signal …

Solution Nuclear Magnetic Resonance Spectroscopy On A Nanostructured Diamond Chip, P. Kehayias, A. Jarmola, N. Mosavian, I. Fescenko, F.M. Benito, A. Laraoui, J. Smits, L. Bougas, D. Budker, A. Neumann, S.R.J. Brueck, V.M. Acosta

Department of Mechanical and Materials Engineering: Faculty Publications

Sensors using nitrogen-vacancy centers in diamond are a promising tool for small-volume nuclear magnetic resonance (NMR) spectroscopy, but the limited sensitivity remains a challenge. Here we show nearly two orders of magnitude improvement in concentration sensitivity over previous nitrogen-vacancy and picoliter NMR studies. We demonstrate NMR spectroscopy of picoliter-volume solutions using a nanostructured diamond chip with dense, high-aspect-ratio nanogratings, enhancing the surface area by 15 times. The nanograting sidewalls are doped with nitrogen-vacancies located a few nanometers from the diamond surface to detect the NMR spectrum of roughly 1 pl of fluid lying within adjacent nanograting grooves. We perform 1H …

Micro/Nanostructures Formation By Femtosecond Laser Surface Processing On Amorphous And Polycrystalline Ni60nb40, Edwin Peng, Alfred Tsubaki, Craig A. Zuhlke, Meiyu Wang, Ryan Bell, Michael J. Lucis, Troy P. Anderson, Dennis R. Alexander, George Gogos, Jeffrey E. Shield

Department of Mechanical and Materials Engineering: Faculty Publications

Femtosecond laser surface processing is a technology that can be used to functionalize many surfaces, imparting specialized properties such as increased broadband optical absorption or superhydrophilicity/superhydrophobicity. In this study, two unique classes of surface structures, below surface growth (BSG) and above surface growth (ASG) mounds, were formed by femtosecond laser surface processing on amorphous and polycrystalline Ni₆₀Nb₄₀ with two different grain sizes. Cross sectional imaging of these mounds revealed thermal evidence of the unique formation processes for each class of surface structure. BSG mounds formed on all three substrates using the same laser parameters had similar surface …

Methods , Systems , And Devices Relating To Robotic Surgical Devices , End Effectors , And Controllers, Shane M. Farritor, Thomas Frederick, Joe Bartels, Eric Markvicka, Jack Mondry

Department of Mechanical and Materials Engineering: Faculty Publications

The various embodiments disclosed herein relate to improved robotic surgical systems, including robotic surgical devices having improved arm components and/or bio metric sensors, contact detection systems for robotic surgical devices, gross positioning systems and devices for use in robotic surgical systems, and improved external controllers and consoles.

Fabrication Of Flexible, Biofunctional Architectures From Silk Proteins, Ramendra K. Pal

Theses and Dissertations

Advances in the biomedical field require functional materials and processes that can lead to devices that are biocompatible, and biodegradable while maintaining high performance and mechanical conformability. In this context, a current shift in focus is towards natural polymers as not only the structural but also functional components of such devices. This poses material-specific functionalization and fabrication related questions in the design and fabrication of such systems. Silk protein biopolymers from the silkworm show tremendous promise in this regard due to intrinsic properties: mechanical performance, optical transparency, biocompatibility, biodegradability, processability, and the ability to entrap and stabilize biomolecules. The unique …

Utilization Of Bio-Renewable Lignin In Building High Capacity, Durable, And Low-Cost Silicon-Based Negative Electrodes For Lithium-Ion Batteries, Tao Chen

Theses and Dissertations--Chemical and Materials Engineering

Silicon-based electrodes are the most promising negative electrodes for the next generation high capacity lithium ion batteries (LIB) as silicon provides a theoretical capacity of 3579 mAh g^-1, more than 10 times higher than that of the state-of-the-art graphite negative electrodes. However, silicon-based electrodes suffer from poor cycle life due to large volume expansion and contraction during lithiation/delithiation. In order to improve the electrochemical performance a number of strategies have been employed, such as dispersion of silicon in active/inactive matrixes, devising of novel nanostructures, and various coatings for protection. Amongst these strategies, silicon-carbon coating based composites are one …

Deconvolving The Steps To Control Morphology, Composition, And Structure, In The Synthesis Of High-Aspect-Ratio Metal Oxide Nanomaterials, Lei Yu

Theses and Dissertations--Chemistry

Metal oxides are of interest not only because of their huge abundance but also for their many applications such as for electrocatalysts, gas sensors, diodes, solar cells and lithium ion batteries (LIBs). Nano-sized metal oxides are especially desirable since they have larger surface-to-volume ratios advantageous for catalytic properties, and can display size and shape confinement properties such as magnetism. Thus, it is very important to explore the synthetic methods for these materials. It is essential, therefore, to understand the reaction mechanisms to create these materials, both on the nanoscale, and in real-time, to have design control of materials with desired …

Degradation Resistant Surface Enhanced Raman Spectroscopy Substrates, Ryan D. Scherzer

UNF Graduate Theses and Dissertations

Raman spectroscopy is employed by NASA, and many others, to detect trace amounts of substances. Unfortunately, the Raman signal is generally too weak to detect when very small, but non-trivial, amounts of molecules are present. One way around this weak signal is to use surface enhanced Raman spectroscopy (SERS).

When used as substrates for SERS, metallic nanorods grown using physical vapor deposition (PVD) provide a large enhancement factor to the Raman signal, as much as 10¹². However, Silver (Ag) nanorods that give high enhancement suffer from rapid degradation as a function of time and exposure to harsh environment. …

Light Soaking Phenomena In Organic-Inorganic Mixed Halide Perovskite Single Crystals, Hye Ryung Byun, Dae Young Park, Hye Min Oh, Gon Namkoong, Mun Seok Jeong

Electrical & Computer Engineering Faculty Publications

Recently, organic inorganic mixed halide perovskite (MAPbX₃; MA = CH₃NH₃^+, X = Cl^-, Br^-, or I^-) single crystals with low defect densities have been highlighted as candidate materials for high-efficiency photovoltaics and optoelectronics. Here we report the optical and structural investigations of mixed halide perovskite (MAPbBr_3-xI_x) single crystals. Mixed halide perovskite single crystals showed strong light soaking phenomena with light illumination conditions that were correlated to the trapping and detrapping events from defect sites. By systematic investigation with optical analysis, we found that the …