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Articles 541 - 570 of 1337

Full-Text Articles in Ceramic Materials

Thickness Effects On The Ac And Dc Electrical Behavior Of Rf-Sputtered Batio3 Nano-Capacitors With Pt And Ni Electrodes, James N. Reck, Matthew O'Keefe, Fatih Dogan Jan 2008

Thickness Effects On The Ac And Dc Electrical Behavior Of Rf-Sputtered Batio3 Nano-Capacitors With Pt And Ni Electrodes, James N. Reck, Matthew O'Keefe, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Nanoscale BaTiO3 capacitors were deposited on Si wafers at dielectric thicknesses of approximately 25, 50, 100, and 200 nm using RF-magnetron sputtering with either 25 nm thick Ni or Pt electrodes. Multiple DC and AC tests were conducted on these devices to determine the effects of BaTiO3 thickness on the measured dielectric behaviors. All films were observed to have non-linear responses for resistance, permittivity, and loss with respect to dielectric thickness. The permittivity was found to follow a standard dead layer model behavior with measured values ranging from approximately 350 to 1700 for Ni electrodes and approximately 100 …

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Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix, Kenneth Czerwinski Jan 2008

Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix, Kenneth Czerwinski

Fuels Campaign (TRP)

This project will examine inert fuels containing ZrO2 and MgO as the inert matrix. Ceramics with this inert matrix, Ce, U and eventually Pu will be synthesized and examined. While the Advanced Fuel Cycle Initiative focus is on inert fuels with Pu as the fissile component, this task will perform initial laboratory experiments with Ce and U. The initial work with Ce will be performed early in the project with results used as a basis for U studies. Reactor physics calculations will be used to examine suitable quantities of burnable poisons from the candidate elements Gd, Er, or Hf. …

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Densification, Microstructure, And Mechanical Properties Of Zirconium Diboride Based Ultra-High Temperature Ceramics, Sumin Zhu Jan 2008

Densification, Microstructure, And Mechanical Properties Of Zirconium Diboride Based Ultra-High Temperature Ceramics, Sumin Zhu

Doctoral Dissertations

"The first part of this dissertation was aimed at studying the densification of ZrB₂ ceramics by pressureless sintering techniques. Various processes have been applied to coat ZrB₂ powders with polymer precursors, which were used to produce C after charring. After sintering at 1900⁰C, relative density increased of ~70% for uncoated ZrB₂ to >99% for ZrB₂ coated with at least 1.0 wt% C. Thermodynamic analysis suggested that C reacted with and removed oxide impurities (ZrO₂ and B₂O₃) that were present on the ZrB₂ particle surfaces, which promoted densification by minimizing grain coarsening"--Abstract, page iv.

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Using Science, Engineering, And Education To Address Water Supply Challenges In The Highlands Of Guatemala, Andrew Curtis Elmore, William Fahrenholtz Dec 2007

Using Science, Engineering, And Education To Address Water Supply Challenges In The Highlands Of Guatemala, Andrew Curtis Elmore, William Fahrenholtz

Materials Science and Engineering Faculty Research & Creative Works

The Guatemalan Highlands is a Popular Destination for Non-Government Organizations Interested in Performing Relief Projects. U.S.-Based Organizations Such as Rotary International, Engineers Without Borders, and Various Religious Organizations Travel to Guatemala to Conduct Humanitarian Activities Which May Be Effective for the Short Term, But It is Not Clear that the Efforts Have a Systematic Impact. Students and Faculty at the University of Missouri-Rolla Have Systematically Studied Water Supply Issues Including Undergraduate and Graduate Research Projects and Undergraduate Engineering Courses Such as International Capstone Design. Materials Engineers Have Been Involved in the Study of Ceramic-Based Water Treatment Devices. These Microfilters Have …

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Enhanced Shrinkage Of Lanthanum Strontium Manganite (La0.90sr0.10mno3+Δ) Resulting From Thermal And Oxygen Partial Pressure Cycling, Benjamin P. Mccarthy, Larry R. Pederson, Harlan U. Anderson, Xiao Dong Zhou, Prabhakar Singh, Gregory W. Coffey, Edwin C. Thomsen Oct 2007

Enhanced Shrinkage Of Lanthanum Strontium Manganite (La0.90sr0.10mno3+Δ) Resulting From Thermal And Oxygen Partial Pressure Cycling, Benjamin P. Mccarthy, Larry R. Pederson, Harlan U. Anderson, Xiao Dong Zhou, Prabhakar Singh, Gregory W. Coffey, Edwin C. Thomsen

Materials Science and Engineering Faculty Research & Creative Works

Exposure of (La0.90Sr0.10)0.98MnO3+δ (LSM-10) to repeated oxygen partial pressure cycles (air/10 ppm O2) resulted in enhanced densification rates, similar to behavior shown previously due to thermal cycling. Shrinkage rates in the temperature range 700°-1000°C were orders of magnitude higher than Makipirtti-Meng model estimations based on stepwise isothermal dilatometry results at a high temperature. a maximum in enhanced shrinkage due to oxygen partial pressure cycling occurred at 900°C. Shrinkage was the greatest when LSM-10 bars that were first equilibrated in air were exposed to gas flows of lower oxygen fugacity than in …

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Transportation Fuel Research And Development: Statistically Validated Codes And Standards, Fatih Dogan Aug 2007

Transportation Fuel Research And Development: Statistically Validated Codes And Standards, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

The recent establishment of the National University Transportation Center at MST under the "Safe, Accountable, Flexible, Efficient Transportation Equity Act: A Legacy for Users," expands the research and education activities to include alternative transportation fuels and other issues that are at the forefront of society and the national agenda. UMR in partnership with MTI will establish a rural hydrogen transportation test bed for developing, demonstrating, evaluating, and promoting hydrogen-based technologies in a real-world environment. The State of Missouri is ideally suited to develop and demonstrate the proper operation of hydrogen highways in a rural setting, which represents over 25 percent …

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Aqueous-Based Extrusion Fabrication Of Ceramics On Demand, Michael S. Mason, Tieshu Huang, Robert G. Landers, Ming-Chuan Leu, Greg Hilmas, Michael W. Hayes Aug 2007

Aqueous-Based Extrusion Fabrication Of Ceramics On Demand, Michael S. Mason, Tieshu Huang, Robert G. Landers, Ming-Chuan Leu, Greg Hilmas, Michael W. Hayes

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Aqueous-Based Extrusion Fabrication is an additive manufacturing technique that extrudes ceramic slurries of high solids loading layer by layer for part fabrication. The material reservoir in a previously developed system has been modified to allow for starting and stopping of extrusion process on demand. Design pros and cons are examined and a comparison between two material reservoir designs is made. Tests were conducted to determine the optimal deposition parameters for starting and stopping of the extrudate on demand. The collected test data is used to create a process model that describes the relationship between ram velocity and material extrusion rate. …

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Effects Of Surface-Deposited Nanocrystalline Chromite Thin Films On The Performance Of A Ferritic Interconnect Alloy, I. Belogolovsky, X. D. Zhou, H. Kurokawa, P. Y. Hou, S. Visco, H. U. Anderson Aug 2007

Effects Of Surface-Deposited Nanocrystalline Chromite Thin Films On The Performance Of A Ferritic Interconnect Alloy, I. Belogolovsky, X. D. Zhou, H. Kurokawa, P. Y. Hou, S. Visco, H. U. Anderson

Materials Science and Engineering Faculty Research & Creative Works

LaCrO3 -Based nanocrystalline thin films, substituted with Sr and Zn and coated onto a Fe-26 atom % Cr Ebrite alloy were evaluated at 750-900°C as potential enhancers of oxide properties in ferritic alloy interconnects of a solid oxide fuel cell. It was found that at 750°C the coatings provided (i) lower oxidation rates, (ii) increased electrical conductivity, (iii) protection during 24 h cycling and at least 2375 h of isothermal oxidation, and (iv) a fine-grained and uniform oxide microstructure. Although after oxidation at 850°C the grains grew substantially and the scale seemed to be overgrowing the film, conductivity and …

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Development Of Single Chamber Solid Oxide Fuel Cells With Porous Samaria Doped Ceria Electrolytes, Nathaniel Goss Jan 2007

Development Of Single Chamber Solid Oxide Fuel Cells With Porous Samaria Doped Ceria Electrolytes, Nathaniel Goss

Opportunities for Undergraduate Research Experience Program (OURE)

Single chamber solid oxide fuel cells generate electricity using hydrogen and hydrocarbon fuel mixed with oxygen at intermediate temperatures (400-800°C) without using seals to separate the gases. A single-chamber solid oxide fuel cell was fabricated with a porous samaria doped ceria (SOC) electrolyte, nickel oxide anode, and a lanthanum strontium cobalt iron oxide (LSCF) cathode. Instead of separately sintering the different components at different temperatures, the electrolyte and electrodes were co-sintered at 1100°C. The porous SOC electrolyte approached 84% theoretical density when sintered at 1100° C. The fuel cell had a maximum open circuit voltage of .65 V at 550°C. …

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Growth Of Mc3t3-El Pre-Osteoblasts On Borate Containing Glasses & Growth Of Osteoblastic Cells On 13-93 Glass Scaffolds, Agatha Dwilewicz Jan 2007

Growth Of Mc3t3-El Pre-Osteoblasts On Borate Containing Glasses & Growth Of Osteoblastic Cells On 13-93 Glass Scaffolds, Agatha Dwilewicz

Opportunities for Undergraduate Research Experience Program (OURE)

Three borate-based glasses, compositions designated 1B, 2B, and 3B, with B203 levels of 15, 31, and 46 mole percent (Table 1), respectively, were tested for their effects on the growth of MC3T3-El mouse pre-osteoblastic cells under physiological fluid conditions. Silicate type 45S5 glass was used as a control for comparison. Independently, the biocompatibility of recently developed silicate-based porous 13-93 bioactive glass scaffolds was tested; Saos-2 human osteosarcoma cell line was used. Tests performed for the two studies included: contact assays of cell growth at the glass interface, chemical analysis of borate released into the culture medium, quantitative …

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Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix, Kenneth Czerwinski Jan 2007

Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix, Kenneth Czerwinski

Fuels Campaign (TRP)

This project will examine inert fuels containing ZrO2 and MgO as the inert matrix. Ceramics with this inert matrix, Ce, U and eventually Pu will be synthesized and examined. While the Advanced Fuel Cycle Initiative focus is on inert fuels with Pu as the fissile component, this task will perform initial laboratory experiments with Ce and U. The initial work with Ce will be performed early in the project with results used as a basis for U studies. Reactor physics calculations will be used to examine suitable quantities of burnable poisons from the candidate elements Gd, Er, or Hf. …

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Properties Of Alkaline-Resistant Calcium-Iron-Phosphate Glasses, Jiawanjun Shi Jan 2007

Properties Of Alkaline-Resistant Calcium-Iron-Phosphate Glasses, Jiawanjun Shi

Masters Theses

"The physical properties and alkaline corrosion resistant properties of calcium-iron-phosphate glasses were studied. The addition of Fe₂O₃ decreases the thermal expansion coefficient and increases the glass fiber's Young's modulus in comparison with the addition of CaO. Bulk glass dissolution behavior in alkaline Lawrence solution was studied by weight loss experiments, Raman spectroscopy, and analytical scanning electron microscopy. The corrosion of glass powder in NaOH solution was studied by X-ray diffraction, infrared spectroscopy and high pressure liquid chromatography. The results show that the dissolution rate decreases when the phosphate chain length decreases. Calcium oxide can improve the glass durability in high …

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A Simple Sol-Gel Processing For The Development Of High-Temperature Stable Photoactive Anatase Titania, Suresh Pillai, Declan Mccormack, John Colreavy Jan 2007

A Simple Sol-Gel Processing For The Development Of High-Temperature Stable Photoactive Anatase Titania, Suresh Pillai, Declan Mccormack, John Colreavy

Articles

No abstract provided.

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Enhancement Of Crystal Growth And Superconducting Properties Of Melt-Textured Yba2cu3o7−X Through Addition Of Baceo3 And Basno3, Oratai Jongprateep, Fatih Dogan Sep 2006

Enhancement Of Crystal Growth And Superconducting Properties Of Melt-Textured Yba2cu3o7−X Through Addition Of Baceo3 And Basno3, Oratai Jongprateep, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

The effects of additions of BaSnO3 in combination with BaCeO3 on the microstructure, crystal growth and superconducting properties of melt-textured YBa2Cu3O7−x (Y123) have been investigated. It has been reported that the addition of BaCeO3 to Y123 results in an increase in the critical current density. However, higher cerium concentrations affect the solidification process and inhibit the growth of melt-textured Y123 single crystals. BaSnO3 has been shown to restore the properties of Y123 with BaCeO3 additives. Increasing the amount of added BaSnO3 leads to refinement of Y211 particles, enhancement of …

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Effects Of Environment On Creep Behavior Of Two Oxide-Oxide Ceramic Matrix Composites At 1200°C, Pavlos Koutsoukos Sep 2006

Effects Of Environment On Creep Behavior Of Two Oxide-Oxide Ceramic Matrix Composites At 1200°C, Pavlos Koutsoukos

Theses and Dissertations

Previous studies by the advisor and graduate students examined creep behavior of the Nextel720/Alumina CMC in air and in 100% steam environments at 1200 and 1330°C. Results showed that while this oxide/oxide system exhibits an exceptionally high fatigue limit at 1200°C it also experiences substantial strain accumulation under sustained loading conditions. Furthermore, these earlier investigations revealed a significant degrading effect of 100% steam environment on material performance under both static and cyclic loadings. The present effort will investigate creep rupture behavior of Nextel720/Alumina composite in the inert gas environment. In addition, creep rupture behavior of Nextel720/Aluminosilicate CMC will be investigated …

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Freeform Extrusion Of High Solids Loading Ceramic Slurries, Part I: Extrusion Process Modeling, Michael S. Mason, Tieshu Huang, Robert G. Landers, Ming-Chuan Leu, Greg Hilmas Aug 2006

Freeform Extrusion Of High Solids Loading Ceramic Slurries, Part I: Extrusion Process Modeling, Michael S. Mason, Tieshu Huang, Robert G. Landers, Ming-Chuan Leu, Greg Hilmas

Mechanical and Aerospace Engineering Faculty Research & Creative Works

A novel, solid freeform fabrication method has been developed for the manufacture of ceramic-based components in an environmentally friendly fashion. The method is based on the extrusion of ceramic slurries using water as the binding media. Aluminum oxide (Al2O3) is currently being used as the part material and solids loading as high as 60 vol. % has been achieved. This paper describes a novel manufacturing machine that has been developed for the extrusion of high solids loading ceramic slurries. A critical component of the machine is the deposition system, which consists of a syringe, a plunger, …

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Freeze-Spray Processing Of Layered Ceramic Composites, Qiang Fu, Oratai Jongprateep, Ashlee Abbott, Fatih Dogan Aug 2006

Freeze-Spray Processing Of Layered Ceramic Composites, Qiang Fu, Oratai Jongprateep, Ashlee Abbott, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Thermal gradients and associated stresses are critical in designing with ceramic composites having low thermal conductivity. In order to reduce the stresses from thermal gradients, compositional gradients are employed in designing of composite structures. This study addresses development of freeze-spray process to fabricate layered ceramic structures with controlled layer thickness and microstructural development. The composites were processed by spraying of ceramic slurries with low binder content and relatively high solids loadings (up to 40 vol%) on a cooled substrate. The frozen parts were freeze-dried and sintered at elevated temperatures. The relationship between microstructural development and thermal expansion behavior of Al …

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Effects Of Frequency And Environment On Fatigue Behavior Of An Oxide-Oxide Ceramic Matrix Composite At 1200°C, Griffin Hetrick Jun 2006

Effects Of Frequency And Environment On Fatigue Behavior Of An Oxide-Oxide Ceramic Matrix Composite At 1200°C, Griffin Hetrick

Theses and Dissertations

Advances in aeronautical engineering in the 21st century depend upon materials that can perform well in extreme environments such as high temperatures and oxidizing conditions. Nextel™720/Alumina (N720/A) is an oxide/oxide ceramic matrix composite with a porous alumina matrix that has been identified as a candidate material for such applications. This research investigated the effects of frequency on fatigue response of N720/A at 1200°C in both air and steam environment. Prior investigation of this material by Eber [8] in 2005 studied fatigue behavior at 1200°C in air and in steam environments at the frequency of 1.0 Hz. The current research focused …

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Effect Of Environment On Creep Behavior Of An Oxide/Oxide Cfcc With ±45° Fiber Orientation, Gregory T. Siegert Jun 2006

Effect Of Environment On Creep Behavior Of An Oxide/Oxide Cfcc With ±45° Fiber Orientation, Gregory T. Siegert

Theses and Dissertations

Aerospace applications require materials capable of maintaining superior mechanical properties while operating at high temperatures and oxidizing environments. Nextel™ 720/A (N720/A), an oxide/oxide ceramic matrix composite (CMC) with a porous alumina matrix was developed specifically to provide improved long-term properties and performance at 1200°C. This research evaluated the creep behavior of N720/A with a ±45° fiber orientation at 1200°C in: laboratory air, steam, and argon environments. Creep-rupture tests at the creep stress levels of: 45, 40, 35, and 15 MPa were conducted in each environment.
The ultimate tensile strength of N720/A with ±45° fiber orientation was 55 MPa, the elastic …

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2nd Annual Undergraduate Research Conference Abstract Book, University Of Missouri--Rolla Apr 2006

2nd Annual Undergraduate Research Conference Abstract Book, University Of Missouri--Rolla

Undergraduate Research Conference at Missouri S&T

No abstract provided.

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Freeze-Spray Processing Of Layered Ceramic Composites (Preprint), Oratai Jongprateep, Q. Fu, A. Abbott, Fatih Dogan Apr 2006

Freeze-Spray Processing Of Layered Ceramic Composites (Preprint), Oratai Jongprateep, Q. Fu, A. Abbott, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Thermal gradients and associated stresses are critical in designing with ceramic composites having low thermal conductivity. In order to reduce the stresses from thermal gradients, compositional gradients are employed in designing of composite structures. This study addresses development of freeze-spray process to fabricate layered ceramic structures with controlled layer thickness and microstructural development. The composites were processed by spraying of ceramic slurries with low binder content and relatively high solids loadings up to 40 vol on a cooled substrate. The frozen parts were freeze-dried and sintered at elevated temperatures. The relationship between microstructural development and thermal expansion behavior of Al …

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Characterization Of Compressive Creep Behavior Of Oxide/Oxide Composite With Monazite Coating At Elevated Temperature, Patrick R. Jackson Mar 2006

Characterization Of Compressive Creep Behavior Of Oxide/Oxide Composite With Monazite Coating At Elevated Temperature, Patrick R. Jackson

Theses and Dissertations

The compressive creep behavior of a N610/monazite/alumina composite was investigated in this work. The composite consists of a porous alumina matrix reinforced with NextelTM610 fibers coated with monazite in a symmetric cross-ply (0°/90°/0°/90°)s orientation. Compressive stress-strain behavior was investigated as well. The addition of monazite coating resulted in ~ 35% loss in compressive strength at 900°C and in ~45% loss in compressive strength at 1100°C. Compressive creep behavior was examined at 900 and 1100°C for creep stresses ranging from 50 to 95 MPa. Primary and secondary creep regimes were observed at both temperatures. Minimum creep rate was reached in all …

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Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix: Quarterly Report, January 2006 To March 2006, Kiel Steven Holliday, Thomas Hartmann, Kenneth Czerwinski Mar 2006

Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix: Quarterly Report, January 2006 To March 2006, Kiel Steven Holliday, Thomas Hartmann, Kenneth Czerwinski

Fuels Campaign (TRP)

This project will examine inert matrix fuels containing ZrO2 and MgO as the inert matrix, with the relative amount of MgO varied from 30% to 70% in ZrO2. Reactor physics calculations will be used to examine suitable quantities of burnable poisons from the candidate elements Gd, Er, or Hf with reactor grade Pu providing the fissile component, with up to 10% of 239Pu. Ceramics will be synthesized and characterized based on the reactor physics results. The solubility of the fuel ceramics, in reactor conditions, reprocessing conditions, and repository conditions, will be investigated in a manner to …

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Effect Of Hold Times On Fatigue Behavior Of Nextel 720™/Alumina Ceramic Matrix Composite At 1200°C In Air And In Steam Environment, John M. Mehrman Mar 2006

Effect Of Hold Times On Fatigue Behavior Of Nextel 720™/Alumina Ceramic Matrix Composite At 1200°C In Air And In Steam Environment, John M. Mehrman

Theses and Dissertations

The aerospace field requires structural materials that can maintain superior mechanical properties while subjected to high temperatures and oxidizing environments. This research investigated the effect of hold times at maximum load on fatigue performance of a Nextel 720/Alumina ceramic matrix composite at 1200 C, explored the influence of environment on material response to cyclic loading with hold times at maximum load, and assessed the effects of loading history on material behavior and environmental durability. The N720/A composite relies on an oxide/oxide composition for inherent oxidation resistance and a porous matrix with no interphase between the fiber and matrix for damage …

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Creep-Rupture And Fatigue Behaviors Of Notched Oxide/Oxide Ceramic Matrix Composite At Elevated Temperature, Mark A. Sullivan Mar 2006

Creep-Rupture And Fatigue Behaviors Of Notched Oxide/Oxide Ceramic Matrix Composite At Elevated Temperature, Mark A. Sullivan

Theses and Dissertations

Oxide/oxide composites are being considered for use in high temperature aerospace applications where their inherent resistance to oxidation provides for better long life properties at high temperature than most other ceramic matrix composites (CMCs). One promising oxide/oxide CMC is Nextel 720/A (N720/A) which uses an 8-harness satin weave (8HSW) of Nextel 720 fibers embedded in a porous alumina matrix. Possible aerospace applications for N720/A will likely require inserting holes into the material for mounting and cooling purposes. The notch characteristics must be understood to ensure designs using the material are sufficient for the desired application. This research effort examined the …

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Effect Of Nozzle Base Material On The Rate Of Clogging During The Continuous Casting Of Aluminum-Killed Steels, Luis Trueba, Kent D. Peaslee, Jeffrey D. Smith, Musa Karakus Jan 2006

Effect Of Nozzle Base Material On The Rate Of Clogging During The Continuous Casting Of Aluminum-Killed Steels, Luis Trueba, Kent D. Peaslee, Jeffrey D. Smith, Musa Karakus

Materials Science and Engineering Faculty Research & Creative Works

One approach to solving the problem of nozzle clogging during the continuous casting of aluminum-killed steels is through careful selection of nozzle materials. in this study, the rate of clogging was measured while casting steel through simulated nozzles produced from alumina, zirconia, magnesia, zirconia-graphite, and alumina-graphite - three common base materials and two common carbon-containing nozzle materials. Spent nozzles were characterized using optical and cathodoluminescence microscopy. Interactions between the nozzles and steel were not observed in the alumina, zirconia, and zirconia-graphite nozzles. Slight interactions were observed in the magnesia nozzles as alumina inclusions within the steel interacted with the nozzle …

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Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix, Kenneth Czerwinski Jan 2006

Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix, Kenneth Czerwinski

Fuels Campaign (TRP)

This project examines inert fuels containing ZrO2 and MgO as the inert matrix, with the relative amount of MgO varied from 30% to 70% in ZrO2. Reactor physics calculations are used to examine suitable quantities of burnable poisons from the candidate elements Gd, Er, or Hf with reactor grade Pu providing the fissile component, with up to 10% of 239Pu. Ceramics are synthesized and characterized based on the reactor physics results. The solubility of the fuel ceramics, in reactor conditions, reprocessing conditions, and repository conditions, are investigated in a manner to provide thermodynamic data necessary for …

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Effect Of Baceo3 And Basno3 Additives On Microstructural Development And Critical Current Density Of Melt Textured Yba2cu3o7-X, Oratai Jongprateep, Fatih Dogan, Michael Strasik, Kevin E. Mccrary Sep 2005

Effect Of Baceo3 And Basno3 Additives On Microstructural Development And Critical Current Density Of Melt Textured Yba2cu3o7-X, Oratai Jongprateep, Fatih Dogan, Michael Strasik, Kevin E. Mccrary

Materials Science and Engineering Faculty Research & Creative Works

Improvement of superconducting properties, such as critical current density Jc and trapped magnetic field, of melt textured YBa2Cu3O7-x (Y123) require introducing of effective pinning sites, e.g., nonsuperconducting inclusions, twin boundaries and other defects. It has been shown that addition of small quantities of BaCeO3 (< 0.5 wt.%) into Y123 results in an increase of the J/sub c/. However, higher cerium concentrations affect the solidification process and inhibit the growth of melt textured Y123 single crystals. In this study, the effect of BaCeO/sub 3/ additions on the growth and microstructural development of melt textured Y123 single crystals were investigated. The relationship between the solidification kinetics, microstructural development and superconducting properties of Y123 melt textured single crystals with cerium additives is discussed.

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Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix: Quarterly Report, April 2005 To June 2005, Earl Wolfram, Thomas Hartmann, Kenneth Czerwinski Jun 2005

Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix: Quarterly Report, April 2005 To June 2005, Earl Wolfram, Thomas Hartmann, Kenneth Czerwinski

Fuels Campaign (TRP)

This project will examine inert matrix fuels containing ZrO2 and MgO as the inert matrix, with the relative amount of MgO varied from 30% to 70% in ZrO2. Reactor physics calculations will be used to examine suitable quantities of burnable poisons from the candidate elements Gd, Er, or Hf with reactor grade Pu providing the fissile component, with up to 10 % of 239Pu. Ceramics will be synthesized and characterized based on the reactor physics results. The solubility the fuel ceramics, in reactor conditions, reprocessing conditions, and repository conditions, will be investigated in a manner to …

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High-Temperature Monitoring Of Refractory Wall Recession Using Frequency-Modulated Continuous-Wave (Fm-Cw) Radar Techniques, Bivin Varghese, C. Deconick, G. Cartee, M. Velez, Robert E. Moore, R. Zoughi May 2005

High-Temperature Monitoring Of Refractory Wall Recession Using Frequency-Modulated Continuous-Wave (Fm-Cw) Radar Techniques, Bivin Varghese, C. Deconick, G. Cartee, M. Velez, Robert E. Moore, R. Zoughi

Electrical and Computer Engineering Faculty Research & Creative Works

Furnaces are among the most crucial components in the glass and metallurgical industry. Nowadays, furnaces are being operated at higher temperatures and for longer periods of time thus increasing the rate of wear on the furnace refractory lining. Consequently, there is a great need for a nondestructive tool that can accurately measure refractory wall thickness at high temperatures. In this paper the utility of a frequency-modulated continuous-wave (FM-CW) radar is investigated for this purpose.

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