Ceramic Materials Commons^™

Fly Ash Proppant Developed For Hydraulic Fracturing, Raz Rzgar Haydar

Theses and Dissertations

Proppants are critical components in hydraulic fracturing, used to maintain fracture conductivity and enhance reservoir stimulation. In high-pressure and harsh reservoir environments, the use of high-strength proppants is essential to ensure well performance. Conventional proppants, being sand, ceramic, and sintered bauxite can be expensive, and their use often requires costly fracture fluids. This study investigates the possibility of utalizing fly ash geopolymers as a sustainable alternative that is also cost-effective for proppants manufacturing. Fly ash, a by-product from the combustion of coal and other materials, was explored as a base material for proppants, utilizing an alkaline solution as an activator …

A Study In The Advanced Manufacturing Of Full Solids Oxide Fuel Cells (Sofcs) Via Aerosol Deposition (Ad) Methods With Macro- And Microstructural Defect Characterization, Davis A. Warmuth

Graduate Theses, Dissertations, and Problem Reports (ETD)

The goal of this work is to 3D print a full SOFC layer-by-layer using aerosol deposition (AD) at a resolution of 5 μm. To achieve this goal, several studies were undertaken to develop and optimize an AD system to use ceramic inks. A 130 kHz AD system was developed with 4 material pumps to allow for depositions of individual compositions of the in-situ mixture of multiple solutions to allow for the fabrication of functional gradients in three dimensions. This system was then programmed to deposit air electrode layers containing different material ratios and porous microstructures, comparing their electrochemical performance to …

Advanced Ysz/Si(B)Cn And Bnnt/Si(B)Cn Ceramics Matrix Composites For Extreme Environments In Hydrogen Combustion, Yiting Wang

Graduate Studies Theses and Dissertations 2026

The growing demand for carbon-neutral energy conversion has accelerated the development of hydrogen-fueled gas turbine systems, which operate at significantly higher temperatures and more chemically aggressive environments than conventional natural gas turbines. To meet these stringent requirements, ceramic matrix composite (CMC) materials consisting of yttria-stabilized zirconia (YSZ) fiber reinforced Si(B)CN ceramic matrix were developed. To further enhance in-plane heat dissipation, thermal stability, thermal shock resistance, and thermal cycling performance, a Si(B)CN/Boron Nitride Nanotubes (BNNT) nanocomposite coating was incorporated onto the YSZ/Si(B)CN composites. Microstructural characterization confirmed the formation of a continuous Si(B)CN ceramic matrix reinforced with uniformly distributed BNNTs. The resulting …

Zirconium Carbide Based Materials For Extreme Aerospace Environments, Nathaniel Hyman Blatt

Doctoral Dissertations

This research focuses on the processing and properties of zirconium carbide-based materials to promote their use in extreme environment aerospace applications, including nuclear thermal propulsion and hyper sonics. Several carbide systems including ZrC, ZrC-Mo cermets, (Zr, Nb)C, and a high entropy carbide were developed. The ZrC-Mo cermet was studied extensively to understand the effect of starting carbide grain size on the final microstructure, composition, elastic moduli, hardness, fracture toughness, room and elevated temperature flexural strength, thermal diffusivity, electrical resistivity, thermal expansion coefficient, and thermal conductivity. It was shown that heat transport in the cermets was dominated by the ZrC phase …

Bridging Physics-Based Modeling And Machine Learning To Predict Material Behavior: Applications In Fatigue Crack Growth And Dielectric Property Characterization, Ansan Pokharel

Graduate Theses, Dissertations, and Problem Reports (ETD)

This dissertation integrates physics-based modeling with machine learning (ML) to predict how materials behave under complex thermal and mechanical conditions. A key innovation of this work is the use of finite element analysis (FEA) to supplement experimental data. This approach creates more diverse and representative synthetic datasets, helping to reduce the limitations and biases that arise when training ML models solely on experimental measurements. The research focuses on two applications: improving the prediction of fatigue properties in superalloys and estimating temperature-dependent, high-frequency dielectric properties relevant to microwave-based chemical processing.

In the first study, low-cycle fatigue experiments were performed on the …

Strontium Titanate For Capacitor And Energy Storage Applications At Cryogenic Temperatures, Hung Trinh

Doctoral Dissertations

This study investigates the dielectric properties of single crystal and ceramic strontium titanate (SrTiO₃) for cryogenic capacitor applications from room temperature to 4 K. Permittivity (k) and loss tangent are dependent on temperature, frequency, mechanical stress, and applied DC electric field. Accordingly, the dielectric constant and loss tangent were measured at various frequencies and DC bias levels. Loss tangent data are also presented as equivalent series resistance (ESR). For single crystal SrTiO₃, an impurity level of ≈500 ppm barium resulted in an increase of the maximum permittivity to approximately 50,000 at 6 K. This relatively high …

In-Situ Investigations Of Calcium-Magnesium-Aluminosilicates (Cmas) Infiltration Effects On Thermal Barrier Coatings Under Extreme Environments Replicating Jet Engines, Zachary Stein

Doctoral Dissertations and Master's Theses

Calcium-magnesium-aluminosilicate (CMAS) particulates, such as sand or volcanic ash, are ingested by gas turbine jet engines during operation. When operating within high abundance regions, these particulates negatively interact and degrade the high temperature thermal barrier coatings (TBC) protecting underlying superalloy turbine blades vital to engine operation. These CMAS particulates melt within the engine and infiltrate into the ceramic coatings. In electron-beam physical vapor deposited (EB-PVD) TBCs, the CMAS within the intercolumnar gaps stiffens the coatings and causes thermomechanical induced high stress concentrations, risking crack formation. While molten, the CMAS thermochemically alters and destabilizes the coating, also risking coating failure. Premature, …

Active Measurement Of A Micron-Order Gap Under High-Speed And High-Temperature Conditions, Andrew Becker

Doctoral Dissertations and Master's Theses

The hypersonic regime poses numerous challenges that researchers face in the development of hypersonic flight vehicles. Due to their excellent thermomechanical properties, ultra-high-temperature ceramics (UHTCs) have risen as a promising solution to act as a protective barrier between the harsh environment and surface materials of these flight bodies. The mechanical operation of a portable hypersonic simulation device was developed in-house and tested at Argonne National Laboratories (ANL) to gather in-situ material response of prospective UHTC samples when exposed to a hypersonic regime. An edge detection-based algorithm was developed and used in LabVIEW to monitor the health and operation of the …

Tensile Creep Of A Hybrid Polymer-Matrix/Ceramic-Matrix Composite At Elevated Temperature, Waleed S. Alshehri

Theses and Dissertations

Advanced aerospace systems require structural materials that can perform reliably in high-temperature environments for long durations. The performance of standard polymer matrix composites (PMCs) in these conditions is often limited by their susceptibility to time-dependent deformation, such as creep. The objective of this research is to characterize the high-temperature creep behavior of a novel unitized material system comprising a polymer matrix composite (PMC) and a ceramic matrix composite (CMC) co-cured together. The PMC part consists of the polyimide matrix reinforced with laminated carbon fibers woven in an eight harness satin weave (8HSW). The CMC part consists of a zirconia-based ceramic …

Investigation Of Solid-State Reactive Sintering And Rapid Laser Reactive Sintering For Al-Doped Li7la3zr2o12 Solid-State Electrolyte, Aaron Santomauro

All Dissertations

As a society, we’ve exhausted an extreme amount of fossil fuels and put an overwhelming strain on Earth’s natural resources. From this, it is critical to think about the successful future of our planet and ourselves by developing energy devices such as all-solid-state lithium-ion batteries (ASSLIBs). These devices offer a greener and more efficient alternative to power our daily lives, such as electric vehicles (EVs), portable electronics, medical devices, grid-scale energy storage, and aerospace/aviation. ASSLIBs are an excellent alternative to liquid-state batteries, which pose dangerous safety concerns (e.g., flammability, electrolyte leakage, etc.). These ASSLIBs are known to have generally high …

Discovery Of High-Performance Cathode Materials For Protonic Ceramic Fuel Cells, Liang Han

All Dissertations

Environmental pollution and rapid energy consumption have become common problems in global development and will continue to grow with the world population. PCFCs use proton-conducting ceramics as electrolytes, with low activation energy and high ionic conductivity at intermediate temperatures, enabling them to operate at intermediate-temperature conditions, which can effectively solve the problems of poor stability and high cost of exotic materials of traditional solid oxide fuel cells. However, as the operating temperature decreases, the electrocatalytic activity of the cathode decreases significantly, seriously affecting PCFC’s performance. Therefore, developing high-performance cathode material suitable for working under intermediate-temperature conditions has become the key …

Mno2 Nanoscale Interface Modification, Alexander C. Skoppe

Doctoral Dissertations and Master's Theses

Interface modification of carbon fibers has been shown to improve the mechanical performance of composites. In addition, interface modification of carbon fiber composites can impart multifunctionality into the resulting composite. This work will explore ZnO and MnO2 as interface modifications for use on carbon fibers. When exposed to high temperatures, carbon fibers undergo fiber degradation, leading to the need for low-temperature hydrothermal processes. This work will develop and characterize a nanoscale ZnO and MnO2 interface modification for use on carbon fibers. These nanomodifications will be developed with low-temperature processes, minimizing the fiber degradation that the fibers undergo. Fourier transform infrared …

Fire Fossils: Biomineral Infrastructures In Untangling Climates, Tanmayee More

Masters Theses

Diatoms drift, sediments sink, wildfires generate their own weather. Lightning strikes can blast sand into glass, and microscopic organisms do the same in the cold recesses of the ocean. What alchemies and metabolisms catalyze space, time, and energy? What are the thermodynamics of infrastructure in Climate Change?

Places, materials, and beings are afterimages. Through alchemical experiments, and multi-scalar imaging, I develop simulations of wildfires, and their profound, reverberating effects. In this thesis, a glass-meets-landscape experimental process enters these obscured conditions and renders new material relations for the built environment.

The Evolution Of Nanoparticles In Nanoparticle Doped Optical Fibers, Mary Cahoon

All Dissertations

Optical fiber and fiber laser technologies based on silica glass are critical to many technologies today. One method to improve the optical performance of laser fibers is engineer the local environment around the active elements in the glass. To that end, this Dissertation focused on the fabrication and characterization of fibers made with nanoparticles incorporated into the glass to control the local composition. First, the nanoparticle composition and structure was analyzed as it evolved from from the initially-synthesized form to incorporation into the dense aluminum-silicate glass. The aluminum oxide in the glass was found to be important not only to …

Advanced Manufacturing Of Multifunctional Shape Memory Polymer Composites And Self-Healing Systems, John B. Konlan

LSU Doctoral Dissertations

The need for multifunctional light weight structures for engineering applications is on the rise. Multifunctional composites are desired because of their ability to combine multiple functionalities into one structure. The advantages of a high strength-to-weight ratio of multifunctional composites make them desirable and suitable for use in energy-efficient applications. Shape-memory polymers (SMPs) have attracted interest over the past several decades because of their multifunctional nature. They have found use in many applications such as aerospace, satellites, automobiles, textiles, and biomedical devices, where lightweight and multifunctionality are key. The self-healing nature of most SMPs makes them suitable for use in lightweight …

Mg And Fe Co-Doped Perovskites For The Electrochemical Oxidative Coupling Of Methane In Solid Oxide Electrolyzers, Luke H. Denoyer

Chemical and Biological Engineering ETDs

More efficient usage of shale gas reserves and natural gas resources will allow for higher olefin yields and lower greenhouse gas emissions. The oxidative coupling of methane (OCM) is a direct pathway for converting methane to ethylene at temperatures >700 °C. The OCM process is typically regulated via the choice of catalyst, reactor conditions, temperature range and gas mixing. The electrochemical oxidative coupling of methane (E-OCM) is a modification to the OCM reaction by controlling the oxygen content via externally applied potentials to an SOEC. Perovskite oxide catalysts are useful for E-OCM due to their flexible bond networks and desired …

Microwave-Assisted Reduction Of Critical Metal Oxides From E-Waste Mixture, Kurundu Shavinka Jayasekera

Graduate Theses, Dissertations, and Problem Reports (ETD)

The efficient recovery of critical metals such as tantalum (Ta), manganese (Mn), gallium (Ga), and indium (In) from electronic waste (e-waste) is essential for resource sustainability and environmental protection. This research uses microwave-assisted treatment to investigate the carbothermal reduction of these four specific metals from their oxides in a simulated e-waste mixture, with carbon black serving as both a microwave coupling and reduction agent. Microwave processing is used specifically because it offers a rapid and energy-efficient alternative to conventional thermal methods, with the benefits of intrinsic heating and selective heating of materials. The first experiments centered on understanding the effects …

La2nio4+Δ-Based Solid Oxide Electrolysis Cell (Soecs) Electrodes Enhanced With Complex Perovskite Nanocatalyst Processed By Surfactant-Enabled Infiltration, Cole Samuel Klemstine

Graduate Theses, Dissertations, and Problem Reports (ETD)

As the world seeks to reduce its reliance on hydrocarbons, the demand for sustainable hydrogen production methods has become increasingly critical. Hydrogen is a versatile energy carrier that can be produced from various sources, including water, natural gas, and biomass. Replacing the burning of hydrocarbons with hydrogen could significantly reduce greenhouse gas emissions, contributing to global climate goals like those set by the US H2NEW program. The joint technologies of solid oxide fuel and electrolysis cells present the ability to both produce and process clean hydrogen to meet these goals. Development into solid oxide fuel cells has been met with …

Novel Design And Fabrication Of A High-Speed Transient Heat Flux Sensor For Application To Rotating Detonation Engines, Zachary Todd Tallman

Graduate Theses, Dissertations, and Problem Reports (ETD)

Rotating detonation engine (RDE) combustion systems have been a topic of interest in the pressure gain combustion community for their benefits over traditional gas turbine engine combustors. However, cooling requirements for these engines are significantly higher and less predictable than those of non-detonating engines. To understand and quantify the high-speed heat transfer dynamics within an RDE, a novel high-frequency heat flux sensor is presented. This study aims to design a robust, single-sided sensor that can withstand the high temperature and harsh environment of an RDE for extended durations. Screen printing is used to deposit a layered, platinum-yttria-stabilized zirconia (YSZ) film …

The Structure, Properties And Dissolution Behaviors Of Phosphate Glasses, Han Zhang

Doctoral Dissertations

The poor chemical durability remains a critical challenge for the application of phosphate glasses. This study investigates the compositional influences on the structure, properties and chemical durability of Li2O-ZnO-P₂O₅ glasses. Their structural characteristics were analyzed utilizing high-performance liquid chromatography, Raman spectroscopy, and X-ray photoelectron spectroscopy. The incorporation of (Li2O+ZnO) in LZeq glasses depolymerizes the phosphate network. In LZ40P and LZ45P glasses, Li⁺ initially replaces Zn²⁺ associated with non-bridging oxygens (NBOs) in Q² tetrahedra. Once the substitution in Q² is complete, further Li⁺ incorporation leads to the replacement of Zn²⁺ in Q^{1 …}

Investigating The Effects Of Fly Ash On The Properties Of Silica-Deficient High Alumina Materials, Sai Akshay Ponduru

Doctoral Dissertations

This research is made up of five studies mainly focused on attaining sustainability in high alumina cements like calcium aluminate cement (CAC) and calcium sulfoaluminate belite cements (CSAB) by partially replacing them with additives and supplementary cementitious materials (SCMs) like fly ash (FA). The first study focused on understanding the reaction kinetics of CAC and FA binders at different replacement levels (i.e. between 10%-to-50% by mass) and their effect on mechanical properties. It was also shown that the reactive nature of FAs can be determined by calculating a single parameter called number of constraints (nc) derived from topological constraint theory. …

Design And Manufacturing Of Multifunctional Piezoelectric Composites, Huan Zhao

Dartmouth College Ph.D Dissertations

Piezoelectric materials possess a unique ability to convert mechanical energy into electrical signals and have broad industrial applications. However, monolithic piezoelectric materials such as piezoceramics and piezopolymers often suffer from inherent trade-offs among mechanical strength, elasticity, and durability. Piezoelectric composites, typically consisting of a polymer matrix with ceramic reinforcements, offer a solution by combining the advantages of each constituent. Nevertheless, maintaining stable mechanical performance in high-temperature environments remains a significant challenge as conventional polymer matrices usually experience structural degradation.

In this thesis, a novel piezoelectric composite is developed using a preceramic polymer (PCP) matrix with barium titanate (BTO) inclusions. PCPs …

Pressureless Sintering Of Sic - Oxide Multiphase Ceramics For Protective Coating Applications, Reilly Boros

All Theses

For hydrogen-fueled combustion, there exists a demand to improve coating materials that are capable of protecting SiC_f/SiC CMC turbine material. Promising coating materials must be able to shield from harsh oxidation while working at extremely high temperatures. The work presented in this thesis aims to expand the understanding of two promising material systems for integrated environmental barrier coating (EBC) – thermal barrier coatings (TBC) by fabricating bulk composite ceramic samples and performing characterization to further understand their sintering behaviors. In this study, a processing procedure to consistently produce dense composite ceramics of PDC SiC – Y₂Si …

Advancing Biofabrication Methodologies To Develop Biomimetic Tissue Scaffolds For Musculoskeletal Applications, Nashaita Yezdi Patrawalla

Theses and Dissertations

Musculoskeletal injuries impose a significant global burden, affecting millions and generating an economic toll exceeding $14 billion. Tissue engineering has gained traction as a promising strategy offering potential for functional restoration of damaged musculoskeletal tissues. This research aims to advance biofabrication techniques for generation of biomimetic tissue scaffolds, by optimizing scaffold design and modulating fabrication process parameters to generate scaffolds for musculoskeletal regeneration with application-specific tailored properties. In this realm, collagen-based biomaterials have been extensively investigated for tendon and ligamentous applications, and in combination with bioceramics incorporated into the collagen framework to produce composite scaffolds that better recapitulate the native …

Laser Processing Of Multi-Phase Ceramics, Siddhartha Sarkar

All Dissertations

This research explores laser-based processing for multi-phase ceramics, offering a faster, more energy-efficient alternative to conventional ceramic fabrication. Four material systems are explored: silica-titania, alumina-iron, polymer-derived ceramic SiC-gadolinium zirconate, and polymer-derived ceramic SiC-yttrium silicate.

The silica-titania study presents a novel direct CO₂ laser writing approach to fabricating pure silica and silica-titania glasses with exceptional dimensional control and optical transparency, enabling fine spatial resolution, instantaneous consolidation, and eliminating post-heat treatment. Notably, the TiO₂ solubility in the silica network achieved is higher than previously reported, with structures remaining crack-free and transparent up to a specific TiO₂ percentage.

The alumina-iron …

Enhancing Protonic Ceramic Fuel Cells By Advanced Laser Processing For Superior Performance, Tianyi Zhou

All Dissertations

As global temperatures rise, the demand for clean energy solutions intensifies. Protonic ceramic fuel cells (PCFCs) offer advantages like higher conductivity at moderate temperatures (300–700 °C), fuel flexibility, stability, and lower costs. However, traditional PCFC manufacturing faces challenges with interface defects, structural imperfections, and scalability, especially in producing large-area cells and stacks.

This work addresses these issues using advanced laser processing techniques. Laser ablation and direct laser rapid additive manufacturing (DL-RAM) enable precise control of PCFC microstructures, removing surface defects and increasing bonding strength for higher efficiency. Digital layer deposition allows for large-area PCFC single cells and stack production with …

Degradation Study Of Single Crystal Barium Titanate Capacitors Under Harsh Environment, Menglin Wang

Electrical Engineering Theses and Dissertations

Capacitors are critical for voltage source converter functionality. DC-link capacitors are known to have reliability issues. Resistance degradation at high temperatures is one of the primary failure modes in capacitors. The overall goal of this program is to improve the understanding of high voltage breakdown and resistance degradation in high dielectric constant inorganic ceramic capacitors, using single crystal BaTiO₃ as a model system to understand the impact and control of oxygen vacancy migration to maximize the long-term reliability of high voltage inorganic multi-layer ceramic capacitors, which allows higher frequency operation, reducing the size and cost of passive components in …

Engineering The Properties Of Magnesium Aluminate Spinel Through Solid State Solutions, Robin Conner

All Theses

Magnesium aluminate spinel solid state solutions were prepared via the coprecipitation method and calcined in air at 900 °C for 2 h. The manipulation of magnesium aluminate spinel’s microstructure through the formation of solid state solutions with zinc and gadolinium substituting for magnesium was investigated. X-ray diffraction (XRD) and attenuated total reflectance Fourier transform infrared spectroscopy (ATR FTIR) confirmed the formation of a single cubic crystalline phase. The luminescence properties were investigated by radioluminescence (RL) under X-ray excitation and thermoluminescence (TL) measurements. In the case of zinc, all concentrations of the solid state solutions showed similar luminescence with bands at …

Secondary Electron Yield Of Metals, Alloys, And Metal Oxides From First Principles Based Monte Carlo Simulations, Raul E. Gutierrez

Electrical and Computer Engineering ETDs

Density Functional Theory (DFT) based Monte Carlo (MC) simulations of the Sec-
ondary Electron Yield (SEY) of metals, alloys, and metal oxides are performed to
find material properties that could help reduce or influence the multipactor effect.
In order to accurately model the SEY of materials, knowledge of the frequency- and
momentum-dependent Energy Loss Function (qDepELF) is required. The qDepELF
is difficult to determine from experiment; however, it can be calculated from first
principles. The DFT-MC approach for simulating the secondary electron genera-
tion, propagation, and emission processes is described herein. Material properties,
which are calculated using DFT and used …

Waste Illuminates Worlds: Printed Modular Lamp Design Based On Brick And Clay Tile, Yechen Zhu

Masters Theses

The building industry in the New England area is often in a state of entropy, with abandoned brick buildings contributing to urban decay. The recycling rate of brick and clay tile wastes generated by construction and demolition is only 12.2%, meaning the majority is sent to landfills. The expansion of landfills can lead to significant environmental and community challenges, including increased traffic from waste transport, habitat destruction, ecosystem degradation, and contributions to climate change. Specifically, the Bethlehem landfill in New Hampshire, which is planned to undergo a 5.71-acre lateral expansion through 2026, has already encountered issues such as leachate spills …