Materials Science and Engineering Commons^™

Development Of Sorption Technology For Extracting Rare Earth Elements From Coal Fly Ash, Bilal Syed

Research Opportunities for Engineering Undergraduates (ROEU) Program 2017-18

Rare Earth Elements (REEs) are elements with many high tech uses (e.g., smartphones, electric cars, advanced weaponry) and have been identified by the DOE to be critical to the US economy. Currently, China supplies over 85% of REEs resulting in an undiversified market and susceptibility to supply shock and economic insecurity. To address this susceptibility, this research aims to develop an economic and environmentally-friendly method of extracting REEs from nascent, plentiful sources such as coal and coal by-products like fly ash.

Effects Of Build Parameters On The Mechanical And Di-Electrical Properties Of Am Parts, Sai Sri Munaganuru, Muthu Ram Prabhu Elenchezhian, Vamsee Vadlamudi, Rauhon Ahmed Shaik, Hari K. Adluru, Rassel Raihan

Institute of Predictive Performance Methodologies (IPPM-UTARI)-Archive

Additive manufacturing (AM) revolutionized many industries, i.e., Automotive, Biomedical, Aerospace and Defense. As opposed to traditional manufacturing methods, a part is manufactured layer by layer from 3D CAD models in AM. Though the vision of AM is impressive, there are many challenges that are hindering the widespread use of these complex parts. One of the challenges in these materials is defects grow and their orientation during the manufacturing process. In this paper we are going to investigate the effect of Build Parameters and their effects on the mechanical and electrical properties of the additively manufactured heterogeneous material system. We will …

Manufacturing A Composite Wheel Prototype Using 3d Printed Molds, Steven Thuening

All Graduate Theses, Dissertations, and Other Capstone Projects

Throughout the evolution of high performance racing, a large emphasis has been on reducing the weight of the vehicle in order to improve its performance. Over the years, new designs and materials have been introduced reducing weight in a variety of different locations. Comparing weight reduced in different areas has shown that some areas are more valuable to reduce than others are. Perhaps one of the most beneficial locations are the wheels. This is because the mass of the wheel is considered unsprung and rotational. Because of this, large improvements towards the reduction of wheel mass have been developed in …

Technology Development For Detection Of Circulating Disease Biomarkers From Liquid Biopsies Using Multifunctional Nanomaterials, Mustafa Balcioglu

Legacy Theses & Dissertations (2009 - 2024)

Despite the advance health care, devastating health conditions such as cancer and infectious diseases that affect populations worldwide are too often not diagnosed until morbid symptoms become apparent in the late phase. Obtaining an early and accurate diagnosis that reveal a hidden lethal threat before the disease becomes complicated may dramatically reduce the severity of its impact on the patient’s life and increase the probability of survival. For example, in the case of ovarian cancer, which is the fifth most common malignancy and the fifth leading cause of cancer mortality in women in the US, the 5-year relative survival is …

Dna Functionalized Nanoparticles In Nanobiosensor And Sensor Array Development For Molecular Diagnostics And In Vitro Identification Of Biomolecules, Mustafa Salih Hizir

Legacy Theses & Dissertations (2009 - 2024)

Nucleic acid technology along with vast variety of nanomaterials has demonstrated a great potential in many applications from biosensing studies to molecular diagnostics, from biomedical and bioanalytical research to environmental analysis. Especially short single stranded (ss) DNA molecules, called oligonucleotides, are extraordinary biopolymers featuring diverse functionality on the nanoparticles thanks to their high degree of programmability, target-specific binding or cleavage, molecular recognition ability, structure-switching capability, and unique interactions at the bio-nano interfaces. Among those, there have been many biosensing applications utilizing ss DNAs and numerous nanomaterials through various detection techniques such as fluorometric, colorimetric or electrochemical methods. Although many groundbreaking …

Genetically Engineered Polypeptides As Biomimetic Light Harvesting Optical Antenna, Jason P. Seeley

Legacy Theses & Dissertations (2009 - 2024)

Natural resources useful for the generation of energy are limited. The development of efficient materials capable of utilizing the abundant free solar radiation is of considerable interest. Utilization of otherwise wasted energy sources, including solar radiation, is a progressive step in the quest for sustainable energy. Solar radiation incident upon the earth’s surface exceeds current energy requirements and motivates scientists to investigate and develop functional devices and nanomaterials including light harvesting complexes (LHC) capable of capturing solar radiation for energy conversion and storage.

Direct Strength Approach To Predict The Flexural Strength Of Cold-Formed Z-Section Purlins On Sloped Roofs, Ali Parva, Michael W. Seek

Engineering Technology Faculty Publications

In this study, the strength of cold-formed Z-section purlins is predicted considering the effects of roof slope in real roof systems. The study applies to simple span purlins with torsion restraints at support locations and at paired locations along the length of the member. A previously developed method has shown through comparisons to base tests that when the biaxial bending and torsion stresses are incorporated into the analysis, the Direct Strength Method can accurately predict the strength of a purlin. These stress distributions can deviate substantially from the constrained bending approximation typically assumed in analysis and therefore impacts the local …

Fe73.5si13.5b9cu1nb3 Metallic Glass: Rapid Activation Of Peroxymonosulfate Towards Ultrafast Eosin Y Degradation, Jincheng Wang, Zhe Jia, Peng Qin, W. C. Zhang, M. D. Wang, T. B. Sercombe, Laichang Zhang

Research outputs 2014 to 2021

Discovering functional applications of metallic glasses (MGs) as heterogeneous catalysts is a fundamental and essential topic. This work reports the rapid production of sulfate radicals (SO₄⁻) from peroxymonosulfate (PMS) using Fe_73.5Si_13.5B₉Cu₁Nb₃ glassy ribbons as catalysts for Eosin Y (EY) dye wastewater treatment. The reaction rates (k) from the experimental data reveal that the EY degradation is well fitted with the pseudo-first-order kinetic model. The strong electron transfer ability is characterized by electrochemical methods, presenting an advanced catalytic performance for EY degradation. Various experimental parameters, including dye …

Photonic Crystal-Supported Long-Range Surface Plasmon-Polaritons Propagating Along High-Quality Silver Nanofilms, Sergey K. Sekatskii, Anton Smirnov, Giovanni Dietler, Mohammad Nur E. Alam, Mikhail Vasiliev, Kamal Alameh

Research outputs 2014 to 2021

Long-range surface plasmon-polaritons (LRSPP) with a propagation length equal to 180 microns at the wavelength of 633 nm have been observed at the interface of 12.5 nm-thick silver nanofilm, coated by a 20 nm-thick protective ZnS layer, with air. Their propagation has been supported by a specially prepared 40-layer 1D Photonic Crystal designed in such a manner that silver layer has been deposited directly onto thin ZnS layer, earlier shown to be a non-oxide material most suitable for the preparation of high-quality thin silver nanofilms.

Magneto-Optic Properties Of Ultrathin Nanocrystalline Ferrite Garnet Films In The 8k To 300k Temperature Interval, Viatcheslav Kotov, Vladimir Shavrov, A. Popkov, Mikhail Vasiliev, Kamal Alameh, Mohammad Alam, L. Alyabyeva, Dmitry Balabanov, Vladimir Burkov, M Virchenko

Research outputs 2014 to 2021

A study of the initial stages of crystallization in RF magnetron-sputtered ferrite garnet films is reported, in which a series of ultrathin Bi2Dy1Fe4Ga1O12 layers is fabricated and characterized. The spectral and temperature dependencies of magnetic circular dichroism (MCD) of these films are studied in the temperature range from 300 K down to 8 K. Measured magneto-optical properties are reported in the spectral range between 300 and 600 nm. In ultrathin garnets at temperatures below 160 K, we found that between 360 and 520 nm, the spectral MCD dependencies were typical of bismuth-substituted garnets with high levels of gallium dilution in …

Homogenization And Growth Behavior Of Second-Phase Particles In A Deformed Zr-Sn-Nb-Fe-Cu-Si-O Alloy, Liang-Yu Chen, Peng Sang, Lina Zhang, Dongpo Song, Yanqiu Chu, Linjiang Chai, Laichang Zhang

Research outputs 2014 to 2021

Homogeneous distribution of fine second-phase particles (SPPs) fabricated by cycles of deformation and annealing in zirconium alloys is a critical consideration for the corrosion resistance of fuel claddings. Different deformation degrees of zirconium alloys would result in distinctive microstructures, leading to a distinct growth of SPPs during subsequent annealing. Unfortunately, the homogenization and growth behavior of SPPs in deformed zirconium alloys have not been well studied. In this work, a β-quenched Zr–Sn–Nb–Fe–Cu–Si–O alloy was rolled and annealed at 580◦C or 680◦C. The morphologies, distributions, and sizes of SPPs resulting from the different processing procedures were investigated. A linear distribution of …

Effect Of High- And Low-Molecular-Weight Hyaluronic-Acid-Functionalized-Az31 Mg And Ti Alloys On Proliferation And Differentiation Of Osteoblast Cells, Sankalp Agarwal, Brendan Duffy, James Curtin, Swarna Jaiswal

Articles

The quality of patient care has increased dramatically in recent years because of the development of lightweight orthopedic metal implants. The success of these orthopedic implants may be compromised by impaired cytocompatibility and osteointegration. Biomimetic surface engineering of metal implants using biomacromolecules including hyaluronic acid (HA) has been used an effective approach to provide conditions favorable for the growth of bone forming cells. To date, there have been limited studies on osteoblasts functions in response to metal substrates modified with the hyaluronic acid of different molecular weight for orthopedic applications. In this study, we evaluated the osteoblasts functions such as …

Electro-Magnetic Responsive Ni0.5zn0.5fe2o4 Nano-Particle Composite, Jaiprakash Kanagaraj

Electronic Theses and Dissertations

The purpose of this study is to simulate and synthesize a Radar (or Radiation) Absorbent Material (RAM) by using polymers and nickel zinc ferrite (Ni0.5Zn0.5Fe2O4) magnetic nanoparticles. There is an ardent desire in military, space and electronics for lighter, faster, cheaper and widespread bandwidth providing RAM materials. Electromagnetic property such as magnetic permeability and electric permittivity play a major in controlling the radiation. The appropriate combination of permeability and permittivity properties is acquired for the synthesis of RAM providing wide-ranging bandwidth. The apt property is achieved by rule of mixture, mixing of particular composition of epoxy polymer having low permeability …

Analysis Of 3d Printed Cylindrical Members, Salvador Caballero

Electronic Theses and Dissertations

Compressive analysis of a structural member is the determination of the axial capacity of the member when it is undergoing a load causing the member to fail in either a buckling or a crushing mode. 3D printed plastic columns have not been characterized and analyzed yet. However, this research characterizes 3D-printed PLA columns and provides parameters for future researchers to investigate. The literature describes the different industries that utilize 3D-printing. In this research, we introduce an innovative approach to investigate the stresses produced in a 3D printed composite member, made of PLA and locally available soil. The compressive testing will …

Photoluminescence From Gan Co-Doped With C And Si, Mykhailo Vorobiov

Theses and Dissertations

This thesis devoted to the experimental studies of yellow and blue luminescence (YL and BL relatively) bands in Gallium Nitride samples doped with C and Si. The band BL_C was at first observed in the steady-state photoluminescence spectrum under high excitation intensities and discerned from BL1 and BL2 bands appearing in the same region of the spectrum. Using the time-resolved photoluminescence spectrum, we were able to determine the shape of the BL_C and its position at 2.87 eV. Internal quantum efficiency of the YL band was estimated to be 90\%. The hole capture coefficient of the BL_{C …}

Mechanical Annealing Of Model Glasses: Effects Of Strain Amplitude And Temperature, Nikolai V. Priezjev

Mechanical and Materials Engineering Faculty Publications

Molecular dynamics simulations are performed to examine the dynamic response of amorphous solids to oscillatory shear at finite temperatures. The data were collected from a poorly annealed binary glass, which was deformed periodically in the elastic regime during several hundred shear cycles. We found that the characteristic time required to reach a steady state with a minimum potential energy is longer at higher temperatures and larger strain amplitudes. With decreasing strain amplitude, the asymptotic value of the potential energy increases but it remains lower than in quiescent samples. The transient decay of the potential energy correlates well with a gradual …

Corrosion Performance Of Zirconium-Based Passivations On Electroplated Zinc Nickel, Madison Morgan Reed

Masters Theses

“Performance requirements for Department of Defense (DoD) electrical components include corrosion and electrical contact resistance. Historically, electroplated cadmium with a chromate conversion coating (CrCC) has been used to meet corrosion and contact resistance standards. However, replacements are needed for these materials because they are toxic and carcinogenic. Electroplated γ-ZnNi has been identified as an acceptable alternative to Cd. This study evaluated commercially available Zr-based thin films and sealers as passivations for potential replacement of CrCCs. Ten different passivations were tested and compared with bare γ-ZnNi. X-Bond and Zircobond passivations were found to provide some improvement to the bare ZnNi corrosion …

Grain Refinement Of High Alloy Stainless Steels In Sand And Directionally Solidified Castings, Dustin Alan Arvola

Masters Theses

"The goal of this research project is to develop an industrially viable melting process that will control the crystallization macrostructure of austenitic grades of cast steels. Titanium nitride (TiN) has proven to be an effective grain refiner of austenite. Theoretical simulation and experimental application has led to the development of a repeatable grain refining melt process for austenitic stainless steel alloys.

Grain refinement of the as-cast structure of Cr-Ni stainless steel alloys solidified with primary FCC, BCC and dual FCC/BCC phases was studied experimentally. Refinement was achieved in both cast ferritic and austenitic grades. Dual solidification of …

Research And Development Of Optically Transparent Join With Low Processing Temperatures, Eric Kevin Muskovin

Masters Theses

The purpose of this study was to investigate durable solar cell cover glass joins produced by diffusion bonding with deep eutectic solvents (DES) and to develop a novel process of joining optically transparent materials at low temperatures. A joined PV cell-glass specimen was characterized using Raman, μ-FTIR, SEM-EDS, and thin-film XRD. DESs were created with malonic acid (MAL) and choline chloride (ChCl) of varying composition factors (CF; CF=MAL/ChCl). Joining borosilicate glass coupons was attempted using DESs with CF = 0.65 and 1 at temperatures between 100-150 °C for 20 hours. Joining the glass coupons failed at all temperatures and oxygen …

Designed Extrudate For Ceramic Additive Manufacturing, Devin Mcmillen

Masters Theses

"The objective of this thesis work was to design ceramic paste systems that assist in achieving a high theoretical density ( > 95%) after deposition by a novel additive manufacturing process, i.e. Ceramic On-Demand Extrusion (CODE). The work is encompassed in five main sections: Sections 1 and 2 provide an introduction and literature review of relevant topics for the following sections of experimentation. Section 3 provides an analysis of a reaction chemistry to identify three discrete materials that could be combined via CODE and result in zirconium diboride (ZrB₂) post-sintering. Section 4 describes the development of a high solids …

Effect Of Microstructural Features On Steel Machinability, Mark C. Emmendorfer

Masters Theses

Non-metallic inclusions can have a tremendous impact on the machinability of steel. Some oxide inclusions such as alumina, spinel, and other refractory abrasive oxide inclusions can have a detrimental effect on machinability. Modification of oxide inclusions by calcium treatment can promote the formation of low melting point oxides such as anorthite and gehlenite inclusions that can assist in chip formation and form a lubricating layer on the rake surface of the machine tool. MnS is known to be beneficial to improving the machinability of steel. They assist in chip formation by being heavily deformed in the primary shear zone. Sulfide …

Modulated Photothermal Radiometry: Detector Sensitivity Study And Experimental Setup, Jessica Nicole Seals

Masters Theses

"This thesis outlines the development of a system used for determining the surface thermal diffusivity of both non-irradiated and irradiated materials. The motivation for this work is to establish a modulated photothermal radiometry (PTR) system on the campus of Missouri University of Science and Technology. One of the main efforts described in this thesis is the design and construction of the physical apparatus. Along the way, it was necessary to perform a detailed sensitivity analysis of the system to determine whether the expected signal emitted from the sample falls within the bounds of detectivity for the HgCdTe (MCT) detector used …

High Temperature Polymer Composites Using Out-Of-Autoclave Processing, Sudharshan Anandan

Doctoral Dissertations

"High performance polymer composites possess high strength-to-weight ratio, corrosion resistance, and have design flexibility. Carbon/epoxy composites are commonly used aerospace materials. Bismaleimide based composites are used as a replacement for epoxy systems at higher service temperatures. Aerospace composites are usually manufactured, under high pressure, in an autoclave which requires high capital investments and operating costs. In contrast, out-of-autoclave manufacturing, specifically vacuum-bag-only prepreg process, is capable of producing low cost and high performance composites. In the current study, out-of-autoclave processing of high temperature carbon/bismaleimide composites was evaluated. The cure and process parameters were optimized. The properties of out-of-autoclave cured laminates compared …

Data Driven Composites: The Challenge And Paths Forwards, Muthu Ram Prabhu Elenchezhian, Vamsee Vadlamudi, Rassel Raihan, Kenneth Reifsnider

Institute of Predictive Performance Methodologies (IPPM-UTARI)-Archive

The concept of “data driven” grew out of the general subject of data analytics, especially in the business world. The classical sequence proposed by Dykes (2010) shown below illustrates the general contents of the concept. Indeed, the idea of “predictive modeling” of the future behavior of a system has strong roots in the business community. In general, for engineering and other fields, the data driven challenge is to use the past with information from the present to predict the future behavior of a system. In turn, the user must pay for collection and processing, hosting and maintenance of the data, …

State Variable Methods Of Assessment, Prognosis, And Control Of Composite And Bonded Structures, Kenneth Reifsnider, Rassel Raihan, Vamsee Vadlamudi, Muthu Ram Prabhu Elenchezhian

Institute of Predictive Performance Methodologies (IPPM-UTARI)-Archive

It is generally recognized that the determination of material state is the baseline foundation for the assessment and prognosis of current and future performance of structural materials in which distributed damage leads to progressive property degradation. Many classes of composite materials, both naturally occurring and engineering designs, are governed by such behavior. However, finding appropriate measureable physical variables to make such assessments, especially for as-manufactured and subsequent real-time assessment and prognosis conditions is challenging. Measurement and analysis of multiple single defect initiation, interaction, and collective effects is the most rigorous current methodology, and is the foundation for certification and quality …

Global Prediction Of Discrete Local Damage Interactions Using Broadband Dielectric Spectroscopy, Vamsee Vadlamudi, Muthu Ram Prabhu Elenchezhian, Rauhon Ahmed Shaik, Aishwarya Nandini, Rassel Raihan, Kenneth Reifsnider

Institute of Predictive Performance Methodologies (IPPM-UTARI)-Archive

With the increasing demand for composites in many modern applications, it is important to predict the initiation of failure events. Due to the heterogeneous nature of these materials, a single damage mode will not lead to final failure, hence detecting the initiation and growth of a single crack (defect) will not yield accurate predictions of the strength or the material state. It is important to capture the interaction of various damage modes that tend to change the material state leading to initiation of failure. To assess the material state, one needs to determine the appropriate global physical variables that can …

Molecular Dynamics For The Prediction Of The Interfacial Shear Stress And Interface Dielectric Properties Of Carbon Fiber Epoxy Composites, Rajni Chahal, Ashfaq Adnan, Kenneth Reifsnider, Rassel Raihan, Yuan Ting Wu, Vamsee Vadlamudi, Muthu Ram Prabhu Elenchezhian

Institute of Predictive Performance Methodologies (IPPM-UTARI)-Archive

The thermoset epoxy resin Diglycidyl ether of Bisphenol F (EPON 862), crosslinked with the Diethylene Toluene Diamine (DETDA) hardening agent, are utilized as the polymer matrix component in many graphite (carbon fiber) composites. Since it is difficult to experimentally characterize the interfacial region, computational molecular modeling is a necessary tool for understanding the influence of the interfacial molecular structure on bulk-level material properties. The purpose of this research is to evaluate and compare the interfacial shear stress and dipole moment for the pristine carbon fiber composite and the one with the moisture content at the interface. Molecular models are established …

Raman Spectroscopy Of The Skeleton Of The Coral Acropora Cervicornis, Zachary C. Shepard

Honors Undergraduate Theses

Coral reefs are an important element of marine ecosystem that are critical to maintain a healthy environment. Unfortunately, in recent years coral reefs are doing poorly and many in parts of the ocean are simply dying. Therefore, study of coral’s structural response to external loads could answer what will happen with their structures, while they exhibit different types of loading. Therefore, the proposition of using in-situ micro-Raman spectroscopy to study skeletons of Acropora cervicornis was used. Coral skeleton samples I subjected to mechanical loading studied their vibrational properties by exciting the material with 532nm visible light. A uniaxial compressive load …

Optimal Sintering Temperature Of Ceria-Doped Scandia Stabilized Zirconia For Use In Solid Oxide Fuel Cells, Amanda K. Assuncao

Honors Undergraduate Theses

Carbon emissions are known to cause decay of the Ozone layer in addition to creating pollutant, poisonous air. This has become a growing concern among scientists and engineers across the globe; if this issue is not addressed, it is likely that the Earth will suffer catastrophic consequences. One of the main culprits of these harmful carbon emissions is fuel combustion. Between vehicles, power plants, airplanes, and ships, the world consumes an extraordinary amount of oil and fuel which all contributes to the emissions problem. Therefore, it is crucial to develop alternative energy sources that minimize the impact on the environment. …

Regolith-Based Construction Materials For Lunar And Martian Colonies, Kevin Grossman

Electronic Theses and Dissertations

Humankind's ambitions of exploring our solar system and parts beyond depend heavily on our ability to collect resources from local environments at our destinations rather than bringing materials on the journey. This is a concept known as in-situ resource utilization (ISRU) and it is one that has been understood by every explorer and settler in the history of humankind. Regolith on the moon and Mars has been shown to be a particularly useful resource and has the ability to provide humans with resources including water, oxygen, construction material, fabric, radiation shielding, metals, and may more. This dissertation focuses on construction …