Open Access. Powered by Scholars. Published by Universities.®

Materials Science and Engineering Commons™

Open Access. Powered by Scholars. Published by Universities.®

Discipline
Institution
Keyword
Publication Year
Publication
Publication Type
File Type

Articles 7561 - 7590 of 16793

Full-Text Articles in Materials Science and Engineering

Synthesis Of Volatile And Thermally Stable Aluminum Hydride Complexes And Their Use In Atomic Layer Deposition Of Metal Thin Films, Kyle Blakeney Jan 2018

Synthesis Of Volatile And Thermally Stable Aluminum Hydride Complexes And Their Use In Atomic Layer Deposition Of Metal Thin Films, Kyle Blakeney

Wayne State University Dissertations

The research discussed in this dissertation spans both synthetic inorganic and nanomaterials chemistry. Aluminum hydride complexes have been synthesized and characterized which are highly volatile and thermally stable and their potential as reducing agents for ALD of electropositive metal and metal-containing films was evaluated. A major discovery has been the deposition of aluminum metal films by thermal ALD using an aluminum dihydride complex supported by a simple amido-amine ligand (Chapters 2). Aluminum is the most electropositive element deposited by purely thermal ALD to date and represents a significant breakthrough for this field. This process may have important industrial applications and …

Go to article

Graphene Induced Formation Of Nanostructures In Composites, Chen Shen Jan 2018

Graphene Induced Formation Of Nanostructures In Composites, Chen Shen

Electronic Theses and Dissertations

Graphene induced nanostructures in graphene-based composites and the performance of these composites have been explored in this study. For the metallic nanoparticles decorated graphene aerogels composites, the fabrication of hierarchically structured, reduced graphene oxide (rGO) aerogels with heavily metallic nanoparticles was realized. Higher loading of palladium nanoparticles in graphene aerogels leads to improved hydrogen gas sensing performance. For polymer derived ceramics (PDCs) composites with anisotropic electrical properties, the fabrication of composites was realized by embedding anisotropic reduced graphene oxide aerogels (rGOAs) into the PDCs matrix. Raman spectroscopy and X-ray diffraction studies of PDCs composites with and without graphene indicate that …

Go to article

Assessment Of Microstructure And Mechanical Behavior Of Materials And Phases Observed In Low-Enriched Uranium Monolithic Fuel Plates After Fabrication, Ryan Newell Jan 2018

Assessment Of Microstructure And Mechanical Behavior Of Materials And Phases Observed In Low-Enriched Uranium Monolithic Fuel Plates After Fabrication, Ryan Newell

Electronic Theses and Dissertations

Low enriched uranium (LEU) fuels are being developed to reduce the use of highly enriched uranium in power generation to reduce proliferation risks. Challenges arise in providing sufficient fissile U in LEU without reactor redesign. As such, a novel monolithic fuel plate design employs LEU alloyed with 10 wt. % Mo. Throughout fabrication of these fuel plates, metallurgical transformations and reactions take place as a result of elevated temperatures during processing. The transformations include decomposition of the metastable body-centered cubic γ phase in the fuel and metallurgical interactions at interfaces between fuel plate components. This work aims to provide further …

Go to article

Slowdown Of Surface Diffusion During Early Stages Of Bacterial Colonization, T. Vourc'h, H. Peerhossaini, J. Leopoldes, A. Mejean, F. Chauvat, C. Cassier-Chauvat Jan 2018

Slowdown Of Surface Diffusion During Early Stages Of Bacterial Colonization, T. Vourc'h, H. Peerhossaini, J. Leopoldes, A. Mejean, F. Chauvat, C. Cassier-Chauvat

Civil and Environmental Engineering Publications

We study the surface diffusion of the model cyanobacterium Synechocystis sp. PCC6803 during the incipient stages of cell contact with a glass surface in the dilute regime. We observe a twitching motility with alternating immobile tumble and mobile run periods, resulting in a normal diffusion described by a continuous-time random walk with a coefficient of diffusion D. Surprisingly, D is found to decrease with time down to a plateau. This is observed only when the cyanobacterial cells are able to produce released extracellular polysaccharides, as shown by a comparative study between the wild-type strain and various polysaccharides-depleted mutants. The analysis …

Go to article

Numerical Modeling And Control Of Solids Separation Using Continuously Moving Fine Mesh Filters, Anthony Sherratt, Christopher T. Degroot, Anthony G. Straatman, Domenico Santoro Jan 2018

Numerical Modeling And Control Of Solids Separation Using Continuously Moving Fine Mesh Filters, Anthony Sherratt, Christopher T. Degroot, Anthony G. Straatman, Domenico Santoro

Mechanical and Materials Engineering Publications

No abstract provided.

Go to article

The Development And Numerical Modelling Of A Representative Elemental Volume For Packed Sand, Ashraf Thabet, Anthony G. Straatman Jan 2018

The Development And Numerical Modelling Of A Representative Elemental Volume For Packed Sand, Ashraf Thabet, Anthony G. Straatman

Mechanical and Materials Engineering Publications

No abstract provided.

Go to article

A Porous Media Model Of Alveolar Duct Flow In The Human Lung, Anthony G. Straatman, Christopher T. Degroot Jan 2018

A Porous Media Model Of Alveolar Duct Flow In The Human Lung, Anthony G. Straatman, Christopher T. Degroot

Mechanical and Materials Engineering Publications

No abstract provided.

Go to article

Hierarchical Hybrid Architectures For Robust And Reusable Nano-Devices, Sharmila M. Mukhopadhyay Jan 2018

Hierarchical Hybrid Architectures For Robust And Reusable Nano-Devices, Sharmila M. Mukhopadhyay

Mechanical and Materials Engineering Faculty Publications

No abstract provided.

Go to article

Engineering Hyaluronic Acid Carbon Nanotube Nanofibers: A Peripheral Nerve Interface To Electrically Stimulate Regeneration, Elisabeth M. Steel Jan 2018

Engineering Hyaluronic Acid Carbon Nanotube Nanofibers: A Peripheral Nerve Interface To Electrically Stimulate Regeneration, Elisabeth M. Steel

Wayne State University Dissertations

Peripheral nerve injuries annually affect hundreds of thousands of people globally. Current treatments like the gold standard autograft and commercially available nerve guide conduits (NGC) are insufficient to repair long gap peripheral nerve injuries. NGCs can aid recovery but lack key microenvironment cues that promote nerve regeneration. We hypothesized that providing topographical, mechanical, and electrical guidance cues through a nanofibrous composite biopolymer would result in improved neuron growth metrics using an in vitro model. We embedded hydrophilic carbon nanotubes (CNT) within hyaluronic acid (HA) nanofibers by electrospinning. The aims of this study were (1) to define the topographical, nanomechanical, and …

Go to article

Surfactant Driven Assembly Of Freeze-Casted, Polymer-Derived Ceramic Nanoparticles On Grapehene Oxide Sheets For Lithium-Ion Battery Anodes, Ali Zein Khater Jan 2018

Surfactant Driven Assembly Of Freeze-Casted, Polymer-Derived Ceramic Nanoparticles On Grapehene Oxide Sheets For Lithium-Ion Battery Anodes, Ali Zein Khater

Honors Undergraduate Theses

Traditional Lithium-Ion Batteries (LIBs) are a reliable and cost-efficient choice for energy storage. LIBs offer high energy density and low self-discharge. Recent developments in electric-based technologies push for replacing historically used Lead-Acid batteries with LIBs. However, LIBs do not yet meet the demands of modern technology. Silicon and graphene oxide (GO) have been identified as promising replacements to improve anode materials. Graphene oxide has a unique sheet-like structure that provides a mechanically stable, light weight material for LIB anodes. Due to its structure, reduced graphene oxide (rGO) is efficiently conductive and resistive to environmental changes. On the other hand, silicon-based …

Go to article

Can A Comprehensive Transition Plan To Barefoot Running Be The Solution To The Injury Epidemic In American Endurance Runners?, Michael A. Scarlett Jan 2018

Can A Comprehensive Transition Plan To Barefoot Running Be The Solution To The Injury Epidemic In American Endurance Runners?, Michael A. Scarlett

CMC Senior Theses

Fossils belonging to the genus Homo, dating as far back as two million years ago, exhibit uniquely efficient features suggesting that early humans had evolved to become exceptional endurance runners. Although they did not have the cushion or stability-control features provided in our modern day running shoes, our early human ancestors experienced far less of the running-related injuries we experience today. The injury rate has been estimated as high as 90% annually for Americans training for a marathon and as high as 79% annually for all American endurance runners. There is an injury epidemic in conventionally shod populations that …

Go to article

The Formation And Characterization Of Mesoscopic J- And H-Aggregates With Controlled Morphologies By The Co- And Templated Assembly Of Cyanine Dyes, Samuel Rhodes Jan 2018

The Formation And Characterization Of Mesoscopic J- And H-Aggregates With Controlled Morphologies By The Co- And Templated Assembly Of Cyanine Dyes, Samuel Rhodes

Electronic Theses and Dissertations

The supramolecular aggregates of π-conjugated molecules have become an area of great interest to the scientific community in recent years for their promise in biosensors and optoelectronic devices. Among various supramolecular aggregates, J- and H-aggregates of πconjugated dye molecules are particularly interesting because of their unique optical and excitonic properties that are not given by individual molecules. H-aggregates are composed of dye molecules in a face-to-face stacking, giving rise to a blue-shifted absorption band compared with the monomer band and a strong emission quenching. In contrast, J-aggregates represent an edge-toedge stacking of dye molecules, showing a red-shifted absorption band with …

Go to article

Processing Of Cubic Stabilized Zirconia Electrolyte Membranes For Electrolyte-Supported Single Cell Solid Oxide Fuel Cells Using Tape Casting, Arturo Coronado Rodriguez Jan 2018

Processing Of Cubic Stabilized Zirconia Electrolyte Membranes For Electrolyte-Supported Single Cell Solid Oxide Fuel Cells Using Tape Casting, Arturo Coronado Rodriguez

Honors Undergraduate Theses

Electrochemical conversion devices are a developing technology that prove to be a viable and more efficient alternative to current environmentally friendly generation devices. As such, constant research has been done in the last few decades to increase their applications and reliability. One of these systems, and the focus of this research, is the single cell Solid Oxide Fuel Cell (SOFC). These systems are a developing technology which main caveat is the need of high operating temperatures and costs. As such, most multidisciplinary research has been focused on researching materials and/or processes that help mitigate the costs or lower the operating …

Go to article

Equibiaxial Flexural Strength Testing Of Advance Ceramics, Ryan T. Jordan Jan 2018

Equibiaxial Flexural Strength Testing Of Advance Ceramics, Ryan T. Jordan

Honors Undergraduate Theses

Ceramics are very important materials with many unique properties used in numerous industrial applications. Ceramics could be very hard and very strong in comparison to metals; however, they are very brittle, thus they are prone to instantaneous and catastrophic failure. Therefore, their reliability is compromised and it is very important to have advanced techniques that allow evaluating their mechanical behavior in many unusual stress states. One of such testing methods is biaxial strength method, that allows to measure properties not only unidirectional, but also in a biaxial way. The research work for this thesis will be built on design and …

Go to article

Experimental Study On Surface Integrity Of Cryogenically Machined Ti-6al-4v Alloy For Biomedical Devices, M. Hardt, F. Klocke, B. Döbbeler, M. Binder, Ibrahim S. Jawahir Jan 2018

Experimental Study On Surface Integrity Of Cryogenically Machined Ti-6al-4v Alloy For Biomedical Devices, M. Hardt, F. Klocke, B. Döbbeler, M. Binder, Ibrahim S. Jawahir

Institute for Sustainable Manufacturing Faculty Publications

Titanium and its alloys are widely used in the biomedical sector. In this field, titanium and its alloys are the material of choice for biomedical devices such as hip and knee replacements. Usually, a Total Hip Replacement (THR) is based on four components, made out of different materials due to the material properties associated with the functional performance. One approach to lower the overall manufacturing costs and enhance the reliability of THR’s is to manufacture the prosthesis out of one material. The titanium alloy Ti-6Al-4V is, therefore, feasible as it exhibits better osseous integration compared to other metallic materials used …

Go to article

Topology Optimization Of Lightweight Structural Composites Inspired By Cuttlefish Bone, Varun Kumar Gadipudi Jan 2018

Topology Optimization Of Lightweight Structural Composites Inspired By Cuttlefish Bone, Varun Kumar Gadipudi

Electronic Theses and Dissertations

Lightweight material structure is a crucial subject in product design. The lightweight material has high strength to weight proportion which turns into an immense fascination and a territory of investigation for the researchers as its application is wide and expanding consistently. Lightweight composite material design is accomplished by choice of the cellular structure and its optimization. Cellular structure is utilized as it has wide multifunctional properties with lightweight characteristics. Unless it has been topologically optimized, each part in a assembly most likely weighs more than it needs to. Additional weight implies abundance materials are being utilized, loads on moving parts …

Go to article

Bio-Mimetic Design With 3d Printable Composites, Ramya Mitra Patnam Damodaram Jan 2018

Bio-Mimetic Design With 3d Printable Composites, Ramya Mitra Patnam Damodaram

Electronic Theses and Dissertations

Weight and stiffness are key factors in the advancement of materials and parts for use in numerous industries. Lightweight cellular structures are broadly utilized for this reason. However, these structures must satisfy several key constraints: they should be light yet structurally safe, sustainable in different loading conditions, resource efficient and easy to maintain. Bio-inspired materials/structures which results in desirable material features are a significant inspiration for engineered cellular structures. Cellular structures can be designed to have multifunctional properties along with lightweight characteristics. Currently, these structures with high strength to weight ratio are widely applied in many fields such as automotive, …

Go to article

Novel Technique Of Fabrication Of Porous Copper And Copper Oxide To Improve The Lithium Ion Battery Performance, Raju Prasad Ghimire Jan 2018

Novel Technique Of Fabrication Of Porous Copper And Copper Oxide To Improve The Lithium Ion Battery Performance, Raju Prasad Ghimire

Electronic Theses and Dissertations

Due to widespread and long-term application, Lithium-ion batteries are considered as promising power sources for portable devices, satellites, medical instruments, computers, electric vehicles and grid application. It started to occupy the market once Sony commercialized in 1991. Rechargeable lithium ion batteries drawing people attention due to their peculiar properties such as high energy density and low self-discharge compared to other alkali metals. However, these widespread and long-term applications still require better batteries in terms of performance, safety and cost, which can be achieved by better utilization of anode materials and/or an optimized design of battery configuration. There are several challenges …

Go to article

Development Of Material For 3d Printed Habitats With Extraplanetary Applications, Taylor Wait Jan 2018

Development Of Material For 3d Printed Habitats With Extraplanetary Applications, Taylor Wait

Electronic Theses and Dissertations

3D printing, also called Additive Manufacturing, has increasingly become a focus for research because of the potential to replace complicated assemblies or complex parts with a single printed item. The space industry is very interesting in studying 3d printing with parts being tested and used on rockets, a 3D printer being installed at the International Space Station and is being developed for use in manned exploration of extraplanetary bodies to build habitats. To encourage teams from around the world to develop technologies and materials for autonomous habitat construction using minimal Earth exports, NASA created the 3D Printed Habitat Challenge. NASA …

Go to article

Pathways For Mitigating Thermal Losses In Solar Photovoltaics, Rodolphe Vaillon, Oliver Dupre, Raúl Bayoán Cal, Marc Calaf Jan 2018

Pathways For Mitigating Thermal Losses In Solar Photovoltaics, Rodolphe Vaillon, Oliver Dupre, Raúl Bayoán Cal, Marc Calaf

Mechanical and Materials Engineering Faculty Publications and Presentations

To improve the performance of solar photovoltaic devices one should mitigate three types of losses: optical, electrical and thermal. However, further reducing the optical and electrical losses in modern photovoltaic devices is becoming increasingly costly. Therefore, there is a rising interest in minimizing the thermal losses. These correspond to the reduction in electrical power output resultant of working at temperatures above 25 °C and the associated accelerated aging. Here, we quantify the impact of all possible strategies to mitigate thermal losses in the case of the mainstream crystalline silicon technology. Results indicate that ensuring a minimum level of conductive/convective cooling …

Go to article

Micro-Slotting Technique For Measurement Of Local Residual Stress In Metallic Materials, Elizabeth Anne Burns Jan 2018

Micro-Slotting Technique For Measurement Of Local Residual Stress In Metallic Materials, Elizabeth Anne Burns

Doctoral Dissertations

"Micro-slotting, a micro-scale relaxation residual stress measurement technique, has been shown in recent years to be a reliable method for measuring local residual stresses in metallic materials. This technique employs an SEM-focused ion beam system for milling and imaging, digital image correlation software to track displacements due to residual stress relaxation, and finite element analysis for interpolation of the original local stress state. In this research, a micro-slotting procedure was established using finite element models and was used to obtain sub-surface residual stress measurements on machined and shot peened planar Ti-6Al-4V samples. These measurements were compared to macro-scale XRD residual …

Go to article

Quantitative Phase-Field Modeling Of Crack Propagation In Multi-Phase Materials, Arezoo Emdadi Jan 2018

Quantitative Phase-Field Modeling Of Crack Propagation In Multi-Phase Materials, Arezoo Emdadi

Doctoral Dissertations

”Research presented in this dissertation is focused on developing and validating a computational framework for study of crack propagation in polycrystalline composite ceramics capable of designing micro-architectures of phases to improve fracture toughness and damage tolerance of ZrB2-based ultra-high temperature ceramics (UHTCs). A quantitative phase-field model based on the regularized formulation of Griffith’s theory is presented for crack propagation in homogenous and heterogeneous brittle materials. This model utilizes correction parameters in the total free energy functional and mechanical equilibrium equation within the crack diffusive area to ensure that the maximum stress in front of the crack tip is …

Go to article

Electrodeposited Epitaxial Cobalt Oxides And Copper Metal, Caleb M. Hull Jan 2018

Electrodeposited Epitaxial Cobalt Oxides And Copper Metal, Caleb M. Hull

Doctoral Dissertations

"Electrochemical deposition methods are presented for the deposition of Co(OH)2 and Cu metal. Paper I shows the deposition of β-Co(OH)2 on Ti through electrochemical reduction of [Co(en)3]3+ to [Co(en)3]2+ in 2M NaOH. The catalytic properties of the deposited Co(OH)2 towards water oxidation is found comparable to Co3O4, with the surface of the Co(OH)2 converting to CoOOH during the reaction. Paper II gives the conditions suitable for epitaxial growth of Co(OH)2 on Au(100), Au(110), and Au(111) following the same reduction mechanism as described in Paper I. …

Go to article

Soy-Based Polyurethane Foam For Insulation And Structural Applications, Gurjot S. Dhaliwal Jan 2018

Soy-Based Polyurethane Foam For Insulation And Structural Applications, Gurjot S. Dhaliwal

Doctoral Dissertations

"Polyurethane (PU) foams are widely used as insulation materials due to their high insulation properties and low cost compared to conventional materials such as styrene and mineral wool. PU foams are traditionally fabricated with petroleum-based precursors. However, high crude price and higher carbon footprint has lead interest of researchers to synthesis PU foams using plant-based raw materials, that are inexpensive and renewable. In this dissertation, PU foams were fabricated using soy-based polyol and its thermal and mechanical properties were investigated. In the first part, of PU foam samples with different formulations were fabricated using soy-based polyol HB230, and varying amounts …

Go to article

Functionalized Nanoporous Carbon Scaffolds For Hydrogen Storage Applications, Christopher L. Carr Jan 2018

Functionalized Nanoporous Carbon Scaffolds For Hydrogen Storage Applications, Christopher L. Carr

Doctoral Dissertations

"Recent efforts have demonstrated confinement in porous scaffolds at the nanoscale can alter the hydrogen sorption properties of metal hydrides, though not to an extent feasible for use in onboard hydrogen storage applications, proposing the need for a method allowing further modifications. The work presented here explores how the functionalization of nanoporous carbon scaffold surfaces with heteroatoms can modify the hydrogen sorption properties of confined metal hydrides in relation to non-functionalized scaffolds (FS). Investigations of nanoconfined LiBH4 and NaAlH4 indicate functionalizing the carbon scaffold surface with nitrogen can shift the activation energy of hydrogen desorption in excess of …

Go to article

Chemistry, Design, And Processing Of Two-Stage Trip Steel, Daniel M. Field Jan 2018

Chemistry, Design, And Processing Of Two-Stage Trip Steel, Daniel M. Field

Doctoral Dissertations

"A regular solution model was developed to calculate the chemical driving force for α-martensite formation, ΔGλ→ αChem. A model for the strain energy, ΔGλ→αstr, was formulated utilizing the Young’s modulus (E), lattice misfit squared (δ²), and molar volume (Ω) which opposed the chemical driving force for α-martensite formation. The MαS was determined at a temperature at which ΔGλ→αChem + ΔGλ→αstr = 0. In conjunction with a previously developed ε-martensite model, a means of predicting the volume fraction of λ-austenite was determined; and it was shown that for values …

Go to article

Multi-Scale Investigation Of Microstructure, Fiber-Matrix Bond, And Mechanical Properties Of Ultra-High Performance Concrete, Zemei Wu Jan 2018

Multi-Scale Investigation Of Microstructure, Fiber-Matrix Bond, And Mechanical Properties Of Ultra-High Performance Concrete, Zemei Wu

Doctoral Dissertations

"The main objective of this study is to provide new insights into enhancing fiber-matrix bond and mechanical properties of ultra-high performance concrete (UHPC). Three main strategies were investigated: 1) use of supplementary cementitious materials; 2) use of nano-particles; and 3) use of deformed fibers. A multi-scale investigation involving the evaluation of non-fibrous UHPC mortar phase (matrix), fiber-matrix interface phase, and then UHPC composite material was undertaken to determine microstructural characteristics, fiber bond to matrix, and key mechanical properties of the UHPC matrix and UHPC. Test results indicate that the incorporation of 10%-20% silica fume effectively improved the fiber-matrix bond and …

Go to article

Material Thermal Property Estimation Of Fibrous Insulation: Heat Transfer Modeling And The Continuous Genetic Algorithm, Elora Frye Jan 2018

Material Thermal Property Estimation Of Fibrous Insulation: Heat Transfer Modeling And The Continuous Genetic Algorithm, Elora Frye

Theses and Dissertations

Material thermal properties are highly sought after to better understand the performance of a material under particular conditions. As new materials are created, their physical properties will determine their performance for various applications. These properties have been estimated using many techniques including experimental testing, numerical modeling, and a combination of both. Existing methods can be time consuming, thus, a time-efficient and precise method to estimate these thermal properties was desired. A one-dimensional finite difference numerical model was developed to replicate the heat transfer through an experimental apparatus. A combination of this numerical model and the Continuous Genetic Algorithm optimization technique …

Go to article

Evaluation Of The Effect Of Tack Coat Type, Application Rate, And Surface Type On Interlayer Shear Strength, Chamika Prashan Dharmarathna Jan 2018

Evaluation Of The Effect Of Tack Coat Type, Application Rate, And Surface Type On Interlayer Shear Strength, Chamika Prashan Dharmarathna

Electronic Theses and Dissertations

Tack coat is an asphaltic material applied between asphalt pavement layers. Since pavement is a multilayered structure, it is highly important to make proper bond between the layers to achieve a monolithic behavior. Hence, inadequate bond due to application of inadequate amount of tack coat may lead to poor structural behavior and premature failure. Also, applying excessive amount of tack coat may lead to layer slippage and binder migration. Therefore, it is highly important to apply an optimum amount of tack coat between layers. Over the past decades several studies have been conducted to determine the optimum tack coat application …

Go to article

Thickness Dependence Of Electrical Conductivity In A Thin Film Thermoelectric Composite, David Zagaceta, William Rogers, Andres Breucop, Brian Herrera Jan 2018

Thickness Dependence Of Electrical Conductivity In A Thin Film Thermoelectric Composite, David Zagaceta, William Rogers, Andres Breucop, Brian Herrera

Math 365 Class Projects

In this work we utilize the Van Der Pauw method for measuring and calculating the electrical conductivity of a composite material in relation to its thickness.

Go to article

First Prev Next Last