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Articles 5491 - 5520 of 16386

Full-Text Articles in Materials Science and Engineering

Comparison Of Phytoremediation And Filtration For Diamond-Mine-Tailings Water Treatment, M. Hafidhuddin Noor, Mijani Rahman, Akhmad Gazali, Nia Kania, Aulia Rahma, Erdina L.A. Rampun, Amalia E. Pratiwi, Muthia Elma Apr 2020

Comparison Of Phytoremediation And Filtration For Diamond-Mine-Tailings Water Treatment, M. Hafidhuddin Noor, Mijani Rahman, Akhmad Gazali, Nia Kania, Aulia Rahma, Erdina L.A. Rampun, Amalia E. Pratiwi, Muthia Elma

Makara Journal of Technology

The water pollution caused by diamond mine activities can kill aquatic life. In this work, we used phytoremediation and filtration to treat pond water polluted by the tailings of a diamond mine located in South Kalimantan, Indonesia. Einchhornia crassipes (water hyacinth) was utilized as the biomass for the phytoremediation process. Gravel (10–15 mm) and sand (0.1–1 mm) were used as filter media in the simple filtration setup, using an up-flow system (bottom to top). In the experiment, 16 L of diamond tailing water was poured into five phytoremediation reactors (each 60 L in volume), which were then tested over seven …


Experimental Determination Of The (0/−) Level For Mg Acceptors In Β-Ga2O3 Crystals, Christopher A. Lenyk, Timothy D. Gustafson, Sergey A. Basun, Larry E. Halliburton, Nancy C. Giles Apr 2020

Experimental Determination Of The (0/−) Level For Mg Acceptors In Β-Ga2O3 Crystals, Christopher A. Lenyk, Timothy D. Gustafson, Sergey A. Basun, Larry E. Halliburton, Nancy C. Giles

Faculty Publications

Electron paramagnetic resonance (EPR) is used to experimentally determine the (0/−) level of the Mg acceptor in an Mg-doped β-Ga2O3 crystal. Our results place this level 0.65 eV (±0.05 eV) above the valence band, a position closer to the valence band than the predictions of several recent computational studies. The crystal used in this investigation was grown by the Czochralski method and contains large concentrations of Mg acceptors and Ir donors, as well as a small concentration of Fe ions and an even smaller concentration of Cr ions. Below room temperature, illumination with 325 nm laser light …


Development Of B-Type And Multi-Ion Doped Carbonated Hydroxyapatite Bioceramics, Safarzadeh Marjan Apr 2020

Development Of B-Type And Multi-Ion Doped Carbonated Hydroxyapatite Bioceramics, Safarzadeh Marjan

Student Works (2020-2029)

The present research is aimed to investigate the effect of varying the carbonate to phosphate (CO32−/ PO43‒) molar ratios from 0.5 to 5 on the physical and mechanical properties of carbonated hydroxyapatite (CHA) synthesized by a wet chemical method. The sintering was performed under dry carbon dioxide atmosphere at 900 °C to maintain the B-type CHA structure. It was found that increases in CO32−/ PO43‒ ratio was accompanied by an increase in the c/a lattice ratio. The diffraction peaks of the synthesized 0.5-5 CHA powders exhibited a single phase material except for 5CHA which revealed the some minor calcite or …


Poly(Vinyl Alcohol)/Α-Chitin/Nanocellulose Composites Developed From Oil Palm Empty Fruit Bunch (Opefb) For Removal Of Cationic Dyes, Chun Fah Mok Apr 2020

Poly(Vinyl Alcohol)/Α-Chitin/Nanocellulose Composites Developed From Oil Palm Empty Fruit Bunch (Opefb) For Removal Of Cationic Dyes, Chun Fah Mok

Student Works (2020-2029)

In search of an eco-friendly polymeric adsorbent for dye effluent treatment application, poly(vinyl alcohol) (PVA)/chitin/nanocellulose composites were synthesized. The composites were reinforced by oil palm empty fruit bunch fibers (OPEFB)-derived nanocrystalline cellulose (NCC). With addition of 1 wt.% NCC, a maximum improvement of 57.64% and 50.66% in tensile strength and Young’s Modulus were achieved, respectively. However, the PVA-based composites exhibited low resistance in aqueous medium. Hence, maleic acid (MA) was incorporated, in view of modifying PVA-based composites through cross-linking reactions. The effect of varying chitin content (10 wt.%-30 wt.%) and MA content (10%-50% based on total solid content of composite) …


Compaction And Residual Stress Modeling In Composite Manufactured With Automated Fiber Placement, Von Clyde Jamora Apr 2020

Compaction And Residual Stress Modeling In Composite Manufactured With Automated Fiber Placement, Von Clyde Jamora

Mechanical & Aerospace Engineering Theses & Dissertations

Automated fiber placement is a state-of-the-art manufacturing process that allows for complex layup patterns and can quickly place, cut, and restart composite tows. However, with this type of manufacturing process layup defects are inevitable, and manufacturing defects propagate after curing. Process modeling is the considered approach for exploring the defect prediction. Two different but related works were conducted, which are the thermochemical and hyperelastic model and the residual deformation model. For the model before cooling, a hyperelastic model and a thermo-chemical were made to simulate the compaction and heat transfer. Temperature dependent properties that are a function of degree of …


Through-Thickness Reinforcement And Repair Of Carbon Fiber Based Honeycomb Structures Under Flexure And Tension Of Adhesively Bonded Joints, Aleric Alden Sanders Apr 2020

Through-Thickness Reinforcement And Repair Of Carbon Fiber Based Honeycomb Structures Under Flexure And Tension Of Adhesively Bonded Joints, Aleric Alden Sanders

Mechanical & Aerospace Engineering Theses & Dissertations

Repair and reinforcement of composite honeycomb structures is an area of concern as higher demands are being placed on high strength, lightweight structural materials, such as carbon fiber reinforced plastics and corresponding honeycomb structures. A common issue with these structures is when a delamination in the facesheet may form and spread, leading to a failure scenario. An investigation of adding a through thickness reinforcement (TTR) to these structures at the sample level that undergo four-point-bending, tension, and joining methods is conducted throughout this thesis. The embedding of pultruded carbon fiber rods is found to be an ideal addition to composite …


Energy Conservation With Open Source Ad Blockers, Joshua M. Pearce Mar 2020

Energy Conservation With Open Source Ad Blockers, Joshua M. Pearce

Michigan Tech Publications, Part 1

Internet-related electricity consumption is rising rapidly as global Internet users spend more than 6.5 h per day online. Open source ad blockers have the potential to reduce the time and thus electricity spent using computers by eliminating ads during Internet browsing and video streaming. In this study, three open source ad blockers are tested against a no-ad blocker control. Page load time is recorded for browsing a representative selection of the globally most-accessed websites, and the time spent watching ads on videos is quantified for both trending and non-trending content. The results show that page load time dropped 11% with …


Influence Of Glass Fiber Reinforced Polymer Wraps On Corrosion Progression Of Bridge Piles In Marine Environments, Shayan Yazdani Mar 2020

Influence Of Glass Fiber Reinforced Polymer Wraps On Corrosion Progression Of Bridge Piles In Marine Environments, Shayan Yazdani

USF Tampa Graduate Theses and Dissertations

The Friendship Trail Bridge connecting Tampa to St. Petersburg was demolished in 2016. Thirteen 20 inches. by 20 inches. reinforced concrete piles supporting its superstructure were part of research studies conducted between 2004 and 2008 to explore the role of glass fiber reinforced polymers (GFRP) in corrosion repair. During demolition, piles were typically cut at the pile cap and in the splash zone. The resulting segments varied in length between 3 to 4 ft. These remnants were transported to the University of South Florida (USF) campus for postmortem analysis. The overarching goal was to establish the role of GFRP in …


Wideband Metasurface Antenna, Thomas A. Lepley Mar 2020

Wideband Metasurface Antenna, Thomas A. Lepley

Theses and Dissertations

This effort explored design of metasurface antennas and evaluated their suitability for ultra-wideband applications (2 to 18 GHz). Six unit cell types were characterized. Eigenmode simulations produced frequency vs. phase data for the unit cells, from which impedance vs. gap size data was computed. A holographic design equation was used to generate the metasurface antenna designs. The unit cell simulations revealed that the assumption of single mode operation is a constraint for wideband designs. An 8" by 8" metasurface antenna with a Rogers 3010 dielectric and a design frequency of 10 GHz was fabricated and tested. It had a 1.5:1 …


Alternate Materials For High-Speed Projectile Casing, Andrew W. Beard Mar 2020

Alternate Materials For High-Speed Projectile Casing, Andrew W. Beard

Theses and Dissertations

A high-speed projectile impact is a highly complex dynamic problem that can be simplified with the use of finite element analysis solvers. Abaqus/Explicit was used to evaluate the impact of various projectiles using a plane strain setup. Using a baseline stainless steel projectile, the proposed sandwich construction design was analyzed and compared to the baseline projectile. The overall goal was to see if a new composite casing could perform similarly to the simple baseline projectile. The sandwich construction used stainless steel, tungsten, and silicon-carbide reinforce aluminum as outer and inner shell materials. The core material was created using additive manufacturing …


Investigation Of Ultem 9085 For Use In Printed Orbital Structures, William R. Gallagher Mar 2020

Investigation Of Ultem 9085 For Use In Printed Orbital Structures, William R. Gallagher

Theses and Dissertations

Additive manufacturing is revolutionizing industries ranging from medicine to space. However, the structural characteristics of plastic parts created by these methods are not as well understood as their more established counterparts. This research explored two relevant areas: how the structural characteristics of ULTEM 9085 plastic behaved after exposure to orbital conditions and the design of the cross-sectional area of a beam to be 3-D printed in microgravity based on the expected loads from the printer. To study orbital effects, ULTEM 9085 was printed into 1/4th scale ASTM D638- 14 dogbones using a Stratasys 450mc printer. These dogbones were placed in …


Dynamic Micromechanical Fabry-Perot Cavity Sensors Fabricated By Multiphoton Absorption Onto Optical Fiber Tips, Jeremiah C. Williams Mar 2020

Dynamic Micromechanical Fabry-Perot Cavity Sensors Fabricated By Multiphoton Absorption Onto Optical Fiber Tips, Jeremiah C. Williams

Theses and Dissertations

This research leveraged two-photon polymerization microfabrication to integrate dynamic mechanical components with Fabry-Perot resonators onto the ends of low-loss optical fibers to prototype 3 micro-optic devices. The first device featured a multi-positional mirror that enabled thin-film deposition onto cavities of any length with mirrors of significant curvature, for refractive index sensing. The second device combined an FP cavity with a spring body featuring easily scalable stiffness for pressure sensing. The third device presented a high-speed rotating micro-anemometer for measuring a wide range of gas flows. All devices represent a significant reduction in size and weight over commercially available devices.


Cyclic Regeneration Of Nanostructured Composites For Catalytic Applications, Fatih Dogan Mar 2020

Cyclic Regeneration Of Nanostructured Composites For Catalytic Applications, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

A cermet catalyst material, defining a matrix having interconnected open pores, the matrix selected from the group consisting of YSZ and CGO and defining a substrate, a ceramic coating having a general formula AyBnOx at least partially coating the pores, and a plurality of metal particles A at least partially embedded in the ceramic coating. A is selected from the group consisting of Co, Cu, Ce, Ni, Ti, and combinations thereof and B is selected from the group consisting of Mo, W, Ce, and combinations thereof. When the coating is in a first oxidizing atmosphere …


A Novel Self-Healing System: Towards A Sustainable Porous Asphalt, Shi Xu, Xueyan Liu, Amir Tabakovic, Erik Schlangen Mar 2020

A Novel Self-Healing System: Towards A Sustainable Porous Asphalt, Shi Xu, Xueyan Liu, Amir Tabakovic, Erik Schlangen

Articles

Self-healing asphalt, aimed to produce a sustainable asphalt pavement using green technology, has been studied in the past two decades. Technologies including encapsulated rejuvenator and induction heating have been proposed, demonstrated in the laboratory, and gradually evaluated in field application. This paper looks into the synergy effect of the above two technologies, where induction heating serves as the asphalt damage repair mechanism, requiring just 2 min heating time and encapsulated rejuvenator will replenish (rejuvenate) aged asphalt binder and reinstate bitumen’s healing ability. Moreover, the increased temperature from induction heating could in turn accelerate the diffusion process of rejuvenator into aged …


Characterization Of A Sagnac Loop Mirror-Based Hybrid Passive Variable Optical Coupler/Attenuator, Simeon Bikorimana, Muhammad A. Ummy, Abdullah Hossain, Richard Lin, Roger Dorsinville Mar 2020

Characterization Of A Sagnac Loop Mirror-Based Hybrid Passive Variable Optical Coupler/Attenuator, Simeon Bikorimana, Muhammad A. Ummy, Abdullah Hossain, Richard Lin, Roger Dorsinville

Publications and Research

The implementation and performance of a unidirectional all-single mode fiber hybrid passive variable optical coupler/attenuator based on a Sagnac loop mirror with a continuous variable coupling ratio using off-the-shelf optical sub-components are discussed. Parameters of two output ports of the unidirectional hybrid passive variable optical coupler/attenuator, such as maximum coupling ratio, insertion loss, excess loss, and wavelength-dependent return loss over the C-band at room temperature are reported. The reflectivity of the Sagnac loop mirror continuously varies from 0.1% to 99.9% by adjusting retarders of a polarization controller. The 3-dB coupling ratio (i.e., 50:50) between the two output ports of the …


Physical Property And Compressive Strength Of Fired Clay Bricks Incorporated With Paper Waste, Anuwat Srisuwan, Nonthaphong Phonphuak Mar 2020

Physical Property And Compressive Strength Of Fired Clay Bricks Incorporated With Paper Waste, Anuwat Srisuwan, Nonthaphong Phonphuak

Journal of Metals, Materials and Minerals

This research is intended to evaluate the effects of paper waste addition on the physical properties and strength of fired clay bricks. Paper waste was mixed with clay in the ratios of 2.5, 5.0, 7.5 and 10 wt%. Green bricks were fired with different variations of temperature from 900-1100C for1 h in air. Fired bricks were then analyzed for physical and mechanical properties. Porosity was increased with higher paper waste content. An increase in porosity relatedly created lower density and higher shrinkage values. Additionally, porous content in fired clay bricks correlated to the deterioration of the compressive strength, due to …


Defects Of The Steel Billet In Continuous Casting, Anh-Hoa Bui, Van-Hung Nguyen Mar 2020

Defects Of The Steel Billet In Continuous Casting, Anh-Hoa Bui, Van-Hung Nguyen

Journal of Metals, Materials and Minerals

In continuous casting process, defects of the steel billet (e.g. crack, pinhole, blowhole, central shrinkage, slag entrapment and appearance deviation, etc.) negatively affect the quality and the yield of rolled products. This research has been carried out to investigate some defects which often occurred in Vietnamese steel plants. The experimental work was conducted in an industrial 4-strands continuous casting machine with the billet's cross-section of 130×130 mm2 . The position, generating cause identification of these defects and proper measures have been discussed. A change in the steel compositions and the water distribution during secondary cooling was applied to improve the …


Biomimetic Metal-Organic Nanoparticles Prepared With A 3d-Printed Microfluidic Device As A Novel Formulation For Disulfiram-Based Therapy Against Breast Cancer, Ya Chang, Jizong Jiang, Wu Chen, Wen Yang, Lili Chen, Pengyu Chen, Jianzhong Shen, Shizhi Qian, Teng Zhou, Linfeng Wu, Liang Hong, Yongzhuo Huang, Feng Li Mar 2020

Biomimetic Metal-Organic Nanoparticles Prepared With A 3d-Printed Microfluidic Device As A Novel Formulation For Disulfiram-Based Therapy Against Breast Cancer, Ya Chang, Jizong Jiang, Wu Chen, Wen Yang, Lili Chen, Pengyu Chen, Jianzhong Shen, Shizhi Qian, Teng Zhou, Linfeng Wu, Liang Hong, Yongzhuo Huang, Feng Li

Mechanical & Aerospace Engineering Faculty Publications

Disulfiram (DSF) is currently tested in several clinical trials for cancer treatment in combination with cop-per (Cu) ions. Usually, DSF and Cu are administered in two separate formulations. In the body, DSF andCu ions form diethyldithiocarbamate copper complex [Cu(DDC)2] which has potent antitumor activities.However, the “two formulation” approach often achieved low Cu(DDC)2 concentration at tumor regions and resulted in compromised anticancer efficacy. Therefore, preformed Cu(DDC)2 complex administered in a single formulation will have better anticancer efficacy. However, the poor aqueous solubility of Cu(DDC)2 is a significant challenge for its clinical use. In this work, a …


The Design Of A Continuous Wave Molecular Nitrogen Stimulated Raman Laser In The Visible Spectrum, Timothy J. Bate Mar 2020

The Design Of A Continuous Wave Molecular Nitrogen Stimulated Raman Laser In The Visible Spectrum, Timothy J. Bate

Theses and Dissertations

Hollow-core photonic crystal fibers (HCPCFs) shows promise as a hybrid laser with higher nonlinear process limits and small beam size over long gain lengths. This work focuses on the design of a CW molecular nitrogen (N2) stimulated Raman laser. N2 offers Raman gains scaling up to 900 amg, scaling higher than H2. The cavity experiment showed the need to include Rayleigh scattering in the high pressure required for N2 Raman lasing. Even at relatively low pressure ssuch as 1,500 psi, high conversion percentages should be found if the fiber length is chosen based on …


Modeling Hybrid Composites Using Tsai-Wu And Hashin Failure Criterion, Candice R. Roberts Mar 2020

Modeling Hybrid Composites Using Tsai-Wu And Hashin Failure Criterion, Candice R. Roberts

Theses and Dissertations

Hybrid composites require further study and testing for future use in various fields. This study focuses on simulating a Hybrid Composite using IM7-977-3 laminae with steel foils in Abaqus under bolt loading by using Hashin and Tsai-Wu failure criterion. Initial simulations contain only the IM7-977-3 composite with cohesive layers. Foil samples were then tested for accurate material properties from which the simulations were then updated to include steel foils. The two models show that Tsai-Wu failure criterion, while great for anisotropic material in tension, does not prove accuracy around the hole of the composite material which is in compression. Hashin …


On The Corrosion Behaviour Of As-Cast And Heat-Treated Mg-Re Alloys In 0.9% Nacl Solution, Abdelkader Hanna, Lyacine Rabahi, Mohamed Amine Soualili, Achour Dakhouche, Djamel Bradai, Hiba Azzeddine Mar 2020

On The Corrosion Behaviour Of As-Cast And Heat-Treated Mg-Re Alloys In 0.9% Nacl Solution, Abdelkader Hanna, Lyacine Rabahi, Mohamed Amine Soualili, Achour Dakhouche, Djamel Bradai, Hiba Azzeddine

Journal of Metals, Materials and Minerals

The microstructure and corrosion behaviour of as-cast and heat-treated Mg-1.44Nd and Mg-1.43Ce (wt.%) alloys in 0.9% NaCl (wt.%) solution were investigated using electrochemical tests, X-ray diffraction (XRD) and scanning electron microscopy, combined with energy-dispersive X-ray spectroscopy (SEM-EDS). The as-cast microstructure of both alloys revealed the presence of second phases. Heat treatment at 535°C for 6 h led to a more uniform distribution of the second phases in Mg-1.44Nd alloy and their dissolution along the grains boundaries in the Mg-1.43Ce alloy. As a result, the corrosion resistance was improved in the heat-treated alloys. Accordingly, the corrosion resistance values for the heat-treated …


Numerical Modeling Of Longwall Top Coal Caving Method At Thar Coalfield, Niaz Muhammad Shahani, Zhijun Wan, Xigui Zheng, Li Guichen, Cancan Liu, Fahad Irfan Siddiqui, Gu Bin Mar 2020

Numerical Modeling Of Longwall Top Coal Caving Method At Thar Coalfield, Niaz Muhammad Shahani, Zhijun Wan, Xigui Zheng, Li Guichen, Cancan Liu, Fahad Irfan Siddiqui, Gu Bin

Journal of Metals, Materials and Minerals

Thar Coalfield in Pakistan is the largest reserve of lignite coal in the country, which is outlined by thick coal seams. The preferred mining method for these thick coal seams is the Longwall Top Coal Caving (LTCC). The connection of both the top coal caving and its compactness are still rare; therefore, the capability of top coal caving mechanism is the most significant factor in LTCC that must be adequately explained and examined. Moreover, in order to achieve the ideal coal production, a comprehensive modeling of deformation and induced stress is mandatory. In this study, a 12 m thick coal …


Sm3+ Ions Doped Zinc Barium Tellurite Oxyfluoride Glasses For Laser Materials, Yaowalak Yamsuk, Patarawagee Yasaka, Jakrapong Kaewkhao, Narong Sangwaranatee Mar 2020

Sm3+ Ions Doped Zinc Barium Tellurite Oxyfluoride Glasses For Laser Materials, Yaowalak Yamsuk, Patarawagee Yasaka, Jakrapong Kaewkhao, Narong Sangwaranatee

Journal of Metals, Materials and Minerals

The Sm3+ ions were doped tellurite glasses with composition (55-x) TeO2-10ZnF2- 35BaO-xSm2O3 (where x = 0.00, 0.05, 0.10, 0.50, 1.00 and 1.50 in mol%) to investigate the physical, the optical, the luminescence and structural properties. The functional groups can be identified using FT-IR spectra of Sm3+ in the glasses. The most intense peak from emission spectra is at 600 nm (4G5/26H7/2) corresponding to reddish-orange color. The oscillator strengths were resolved from the absorption spectra and then used to calculate the Judd - Ofelt (J - O) intensity parameters. The radiative properties were calculated by J - O intensity parameters for …


Selection Of Blowing Agent For Metal Foam Production: A Review, Ankur Bisht, Brijesh Gangil, Vinay Kumar Patel Mar 2020

Selection Of Blowing Agent For Metal Foam Production: A Review, Ankur Bisht, Brijesh Gangil, Vinay Kumar Patel

Journal of Metals, Materials and Minerals

Metal foams are cellular solids in which gas is uniformly distributed throughout the metal matrix. One of the cheapest ways of evolving the gas is introducing the blowing agent in parent metal in liquid state. A blowing agent is defined as a material that decomposes under the presence of heat and releases gas which then propels the foaming process. The quality of final foam is influenced by several parameters such as composition, size and volume fraction of the blowing agent used. Different chemicals which can evolve gases such as carbonates and metal hydrides fit into the description of blowing agent. …


An Approach To Search The Potentiality Of Node In Bamboo Strip Reinforced Composites, Mohammad Irfan Iqbal, Rashed Al Mizan, Ayub Nabi Khan Mar 2020

An Approach To Search The Potentiality Of Node In Bamboo Strip Reinforced Composites, Mohammad Irfan Iqbal, Rashed Al Mizan, Ayub Nabi Khan

Journal of Metals, Materials and Minerals

Bamboo has recently entered the composite sector with some attractive labels such as 'green'. The current commercial manufacturing method of bamboo composite removes the node's portion of bamboo culm during bamboo processing. This method generates a high amount of solid waste materials along with processing complexity and the scientific merit of this practice is also questionable. This research investigates the effects of culm nodes on bamboo based composite properties. In this study an approach to produce bamboo strips reinforced epoxy composites and their mechanical properties (e.g. tensile, flexural and impact properties) were reported. It was demonstrated that mechanical properties of …


Preparation And Characterization Of Lake Pigments From Sappan Wood Using Thai Local Clays, Jitnapa Sirirak, Nattawan Worawannotai, Cheewita Suwanchawalit, Supanee Chayabutra Mar 2020

Preparation And Characterization Of Lake Pigments From Sappan Wood Using Thai Local Clays, Jitnapa Sirirak, Nattawan Worawannotai, Cheewita Suwanchawalit, Supanee Chayabutra

Journal of Metals, Materials and Minerals

Thai local clays: Munpoo clay (MC) and Dindang clay (DC) were utilized as the adsorbents for preparation of the lake pigments from sappan wood. The lake pigment which was prepared by using MC as the adsorbent (L-MC) appeared reddish-brown while a deeper reddish-brown color of the lake pigment (L-DC) was obtained by using DC as the adsorbent. Characterization of MC, DC, L-MC, and L-DC was accomplished by XRD, SEM, FT-IR, BET, TGA and UV-Vis DRS. The effects of adsorbent dosage, pH of sappan wood extract and time on the adsorption were also investigated. The results revealed that silicon oxide and …


Development Of Sr/Cao Catalyst Derived From Cuttlebone (Sepia Officinalis) For Biodiesel Production, Napat Tomano, Apisit Prokaew, Supakorn Boonyuen, Sarute Ummartyotin Mar 2020

Development Of Sr/Cao Catalyst Derived From Cuttlebone (Sepia Officinalis) For Biodiesel Production, Napat Tomano, Apisit Prokaew, Supakorn Boonyuen, Sarute Ummartyotin

Journal of Metals, Materials and Minerals

Cuttlebone (Sepia officinalis) was used as a source of calcium oxide for biodiesel catalyst. The objective of this work is to present the bio-based catalyst prepared from cuttlebone. 1, 3, 5 and 10 %wt of strontium was loaded into calcium oxide powder derived from cuttlebone. Structural properties of Sr/CaO catalyst were evaluated by Fourier transform infrared and X-ray diffraction, respectively. There is no change on morphological properties of catalyst between Sr/CaO and pristine CaO. The homogeneous distribution of strontium was confirmed by EDX mapping technique. The specific surface area of powder was estimated to be 10-30 m2 ·g-1. The thermal …


Poly(Ester Urethane)-Crosslinked Carboxymethylchitosan As A Highly Water Swollen Hydrogel, Nunthiya Deepuppha, Apiwat Kadnaim, Boonjira Rutnakornpituk, Metha Rutnakornpituk Mar 2020

Poly(Ester Urethane)-Crosslinked Carboxymethylchitosan As A Highly Water Swollen Hydrogel, Nunthiya Deepuppha, Apiwat Kadnaim, Boonjira Rutnakornpituk, Metha Rutnakornpituk

Journal of Metals, Materials and Minerals

This work focused on the synthesis and characterization of carboxymethylchitosan (CMC)-based hydrogels modified with polyester-containing polyurethane (PU). The polyester was first synthesized from the condensation between 1,6-hexane diol and malonic acid, then reacted with an excess of 1,6-hexamethylene diisocyanate (HDI), and followed by the reaction with ethylene glycol as a chain extender to gain PU. CMC was chemically crosslinked with a water soluble crosslinker in the presence of 1-60 wt% of PU to obtain highly water swollen CMC hydrogels. Upon addition of PU, the CMC hydrogel showed excellent water swellability (up to 400 times of the dried weight), and it …


The Luminescence, Optical, And Structural Properties Of Srmoo4:Ce3+ Phosphor For Photonics Material Applications, Eakgapon Kaewnuam, Nuanthip Wantana, Sasithorn Saikaew, Jakrapong Kaewkhao Mar 2020

The Luminescence, Optical, And Structural Properties Of Srmoo4:Ce3+ Phosphor For Photonics Material Applications, Eakgapon Kaewnuam, Nuanthip Wantana, Sasithorn Saikaew, Jakrapong Kaewkhao

Journal of Metals, Materials and Minerals

SrMoO4:Ce3+ phosphors with different Ce2O3 concentration were studied in the structure, optical and luminescence properties. The phosphor powders were synthesized by a solid-state reaction to investigate with the XRD, FTIR, absorption and emission spectra measurement. The XRD patterns confirm the tetragonal crystalline structure of SrMoO4 host composition. The FTIR spectra show the dominant vibrations of tetrahedral [MoO4]2- unit in powders. These phosphors absorb photons in the range of ultraviolet and visible light proved by the absorption spectra. The emission spectra represent the strongest emission at 421 nm wavelength of phosphors under 266 nm excitation. This emission occurred under the transition …


The Water Permeability Properties Of Re-Vibrated Lightweight Concrete, Muayad Mohammed Kassim Mar 2020

The Water Permeability Properties Of Re-Vibrated Lightweight Concrete, Muayad Mohammed Kassim

Journal of Metals, Materials and Minerals

Re-vibration of sequential layers of relatively deep structural members after a particular time harms the strength and water permeability properties of the concrete. The harmful effects can be observed in lightweight concrete due to the floating tendency of lightweight aggregate. In this experimental study, the influence of adding retarder plasticizer and silica fume on water permeability properties of re-vibrated lightweight concrete was investigated. The effects of re-vibration at different time lags on compressive strength and permeable voids ratio were studied. Absorption, sorptivity, and water penetration depth under pressure were also studied. Results show that the addition of a retarder increased …