Materials Science and Engineering Commons^™

Effect Of Polystyrene Molecular Weight And Zinc Oxide Concentration On Dewetting Behavior Of Polymeric Thin Films, Kattaleeya Sujaroon, Phanawan Whangdee, Nampueng Pangpaiboon

Journal of Metals, Materials and Minerals

The separation between ultra-thin polymer film on metal oxide substrate is called dewetting. Dewetting causes the polymer films to loss their stability and other important properties, for example, the films may short circuit or reduce their transparency. Therefore, the stability of polymer thin films on substrate need to be improved. Addition of nanoparticles is one of the most popular technique used to increase the stability of polymer thin films. The correlation between the different of molecular weight and ZnO concentration on dewetting behavior was studied in this research. The appropriate concentration of ZnO on dewetting suppression in each molecular weight …

Production Of Silica-Based Ceramics Sintered Under Nitrogen Atmosphere From Rice Husk And Sugarcane Bagasse Ash, Wiphawan Khopthong, Benya Cherdhirunkorn

Journal of Metals, Materials and Minerals

Nitride silica-based ceramics were prepared by sintering under nitrogen atmosphere using rice husk ash and bagasse ash as raw materials. X-ray Fluorescence Spectrometry (XRF) and X-ray Diffractometor (XRD) studies revealed that the main phase of rice husk ash (after calcined at 600C for 6 h.) was amorphous silica, whereas the sugarcane bagasse ash contained quartz and CaCO3. Thus, both ashes would be a good source for silica. Two batches of the 100 wt% rice husk ash (RHA100) and the mixture of 50 wt% rice husk ash and 50 wt% bagasse ash (RHA50BA50) were wet milled using planetary ball milling machine, …

Tribology, Mechanical Properties And Coloration Of A Mica Glass-Ceramic, Sahadsaya Prasertwong, Sukanda Angkulpipat, Thapanee Srichumpong, Kallaya Suputtamongkol, Chanchana Thanachayanont, Ramona Sola4, Greg Heness, Cristina Leonelli, Duangrudee Chaysuwan

Journal of Metals, Materials and Minerals

The research employed pigments, Fe2O3 and CeO2, into the glass frit for adjustable mechanical properties and coloration. Disc samples were prepared to determine microstructures and mechanical properties in terms of tribology and nano-indentation hardness as well as biaxial flexural strength. The glass system presented the crystalline phases, by XRD, of phlogopite Ca-mica, fluorapatite, stishovite, anorthite and strontium apatite. Furthermore, SEM micrographs revealed rod-like microstructures and parent glass phase in all specimens 1) GC, 2) GC + 1wt% CeO2, 3) GC + 0.1wt% Fe2O3 and 4) GC + 1wt% CeO2 + 0.1wt% Fe2O3. For the tribology test, specimens were tested by …

Effects Of Sodium Silicate As Liquid Phase Sintering Additives On Properties Of Alumina Ceramics, Kanyapak Siriphaisarntavee, Charusporn Mongkolkachit, Mateekul Jiarawattananon, Karn Serivalsatit, Thanakorn Wasanapiarnpong

Journal of Metals, Materials and Minerals

This research focused on the production of high-performance alumina products. The feasibility of using soluble alkali silicate in liquid phase sintering of alumina was studied. Liquid soluble alkali silicate was used to enhance the plastic forming of alumina and formed liquid phase sintering to attain fired alumina products with high strength, high alumina content and low water absorption. The methodology consisted of the mixing of organic binder with sodium silicate (Na2SiO3), used as liquid phase sintering additive, of 0-15 wt%. Magnesium carbonate (MgCO3), used as the grain growth inhibitor, of 0-1 wt% were added and followed by alumina powders. The …

Properties Of Wood-Plastic Composites Based On Pvc/Pla/Pbat Ternary Blend, Laksamon Raksaksri, Phasawat Chaiwutthinan, Amnouy Larpkasemsuk, Saowaroj Chuayjuljit, Anyaporn Boonmahitthisud

Journal of Metals, Materials and Minerals

The objective of this work was to improve mechanical properties, thermal resistance, and biodegradability of poly(vinyl chloride) (PVC) by the addition of poly(lactic acid) (PLA), poly(butylene adipate-co-terephthalate) (PBAT), and wood flour (WF). The samples made from a mixture of PVC/PBAT exhibited the highest impact and tensile properties, while properties of the samples made from PVC/PLA had the highest flexural and thermal properties, PVC/PLA/PBAT mixed samples exhibited average mechanical properties. The addition of WF to all the blends increased impact strength, flexural properties, Young's modulus, thermal resistance, and biodegradability of the samples in comparison to those of the neat PVC and …

Analysis Of Burning Wood In The Transient State And The Application To Structural Design, Roberta Veliz, Kimberly Guzman

Architectural Engineering

Determining the extent of the contribution of exposed timber on compartment fire dynamics in open floor plans is a complex process. Designers traditionally used compartmentalization design methods which create spaces where flashover is likely, given the fuel load and ventilation conditions. However, due to the large geometric dimensions and spread of fuel, fires in open floor plans are more likely to remain as localized or traveling fires. As such, an understanding of not only ignition potential but also flame spread is critical to characterizing the contribution of exposed timber. An integral step in characterizing the potential contribution is through an …

Nature-Inspired Electrode Materials For Next Generation Sustainable Energy Storage, Mikhail Miroshnikov

Dissertations, Theses, and Capstone Projects

Despite revolutionizing the world of portable electronics, the contemporary lithium-ion battery (LIB) suffers from challenges associated with the cost, safety, and environmental impact of transition metal oxide-based intercalation cathodes. To alleviate these issues, naturally occurring organic molecules may serve as sustainable alternatives to traditional inorganic cathode materials. The electrochemical properties of organic compounds are derived from redox-active functional groups containing oxygen, nitrogen and sulfur. Additionally, these functional groups are capable of coordinating metal ions beyond lithium, allowing for compatibility with sodium-ion batteries (SIBs) and other earth abundant metal-based energy storage systems. However, despite competitive performance against commercialized cathode materials, much …

Effects Of Ring Rolling On Grain Size In Inconel 718 And Waspaloy, David Webster

Materials Engineering

Carlton Forge Works, an industry leader in the manufacture of rolled rings, has observed anomalous grain structures in parts made from Inconel 718 and Waspaloy. These take the form of unusually large grains at the surface of the rings, causing them to fail industry grain size standards. Grain size testing is a critical part of evaluating parts before they are used as grain size and structure control many mechanical properties including creep resistance, low and high cycle fatigue life, and yield strength. These unusually large grains are only present within the first tenth of an inch of the surface of …

Microstructure And Tensile Properties Of Close-Die Forged Ti-6al-4v Aircraft Engine Mount, Renee Roeder, Nick Chen, Michael Viksne

Materials Engineering

The microstructural characteristics of a Ti-6Al-4V close-die forging that passes yield strength specifications are examined and found to be consistent with literature recommendations. Originally, the intent was to compare the microstructure of a forging that passed specification to the microstructure of a forging that did not pass specifications using the imaging software ImageJ. Due to time and safety constraints considering the COVID-19 pandemic, the data that is presented is incomplete data on only the forging that passes specifications. There are no comparisons between the forging that did not pass and the forging that passed.

Non-Toxic Soil Thickeners For Reducing Mudslide Intensity, Mitchell William Jensen

Materials Engineering

This project was intended to be a continuation of senior project work done last year by a group consisting of two Materials Engineering students and a Soil Science student. Their report was crucial in identifying a range of food thickeners that could be capable of performing in the mud thickening application. All thickeners that were chosen both this year and last year are biocompatible, to alleviate some toxicity concerns. The food thickeners all belong to a class of compounds known as colloids. Since water is the fluid being thickened, these compounds are more accurately referred to as hydrocolloids. Hydrocolloids are …

Pitting Corrosion Of Oerlikon’S Abrasion Resistant Ferritic Stainless Steels, Matthew P. Nalty, Emma Wagstaff

Materials Engineering

Existing hardfacing coatings for hydraulic cylinders and brake disc applications crack during use leaving the components susceptible to corrosion. To address this problem, Oerlikon has designed three new alloys to be abrasion and corrosion resistant. This paper reviews the literature necessary to understand and quantify pitting resistance of stainless-steel alloys. It documents one round of testing ASTM G48 method A: Ferric Chloride Pitting Test of Stainless Steels on the new alloys P72-X9, P72-X13, P129-X9, as well as samples of 431, 316, and 2205 stainless steels. This paper also discusses improvements to the G48 testing method and industry use of the …

Investigation Of Ceramic Firing Processes For Investment Casting Shell Molds, Leonardo Ken Hoaakua Nakamura, Rileigh Anne Cotter

Materials Engineering

PCC Structurals aims to improve the quality and consistency of their ceramic mold production for their investment casting processes to decrease product loss figures. Although their current production processes result in acceptable quantities of high-quality molds, a significant percentage of defective molds are produced. These defective molds cause appreciable product loss due to casting defects and mold failure. Available literature dictates that high-quality investment casting molds must exhibit fracture strengths within a desired range in order to perform adequately. However, information regarding specific firing procedures which consistently result in ceramic mold strengths within this range is not readily available. To …

Alternative To Custom 450© Stainless Steel For Use In Investment Cast Golf Club Heads, William Henry Armstrong Iv, Davis Martin Loen

Materials Engineering

This investigation seeks to improve on the mechanical property of yield strength, while maintaining 10% elongation prior to fracture observed with of Custom 450 stainless steel in an air-melted investment casting operation. Improving this performance includes an additional heat treatment step of homogenization, as well as replacing the alloy. After identifying and downselecting available high strength stainless steels, a trial of Custom 455 stainless steel is recommended due to its high strength compared to the other alternative alloys. A trial has been developed to analyze the effect air melting has on the chemical composition and mechanical properties of Custom 455 …

Failure Analysis Of Investment Cast Near-Alpha Titanium Alloys, Garrett Ryan Bader, Jonathan Anton Linquist

Materials Engineering

In this project, fracture surfaces of three titanium investment castings were studied as part of a failure analysis on a TaylorMade metalwood. The crack formation occurred between investment cast Ti 9-1-1 and rolled Ti 6-4 joined by laser beam welding. The microstructure of the Ti 9-1-1 contained alpha colonies in large prior beta grains, while the Ti 6-4 was primarily Widmanstätten in basket weave morphology, refined with subsequent rolling. Over a period of cyclic loading, cracking occurred at the face-sole transition in the metalwoods that had been cast from a certain supplier B, while metalwoods that had undergone similar treatment …

Effects Of Surface Finish On High Cycle Fatigue Of Inconel 718, Jessica A. Mcroskey, Matthew Busse

Materials Engineering

Inconel 718 is a nickel-based superalloy and commonly used rocket engine material due to its excellent properties at elevated temperatures. Its fatigue life relies heavily on the surface roughness, as fatigue introduces and propagates cracks at the surface. Part standards set by Aerojet Rocketdyne typically necessitate surface roughness values from 64 to 125 Ra. However, surface topography and residual stresses incurred from the finishing process also affect the fatigue performance. The specific goal of the project is to perform a literature review and write experimental methods to determine how the surface roughness, topography, and residual stresses from turning, grit blasting, …

The Influence Of Time And Temperature On 7781 Prepreg Outside Storage, Matthew L. Fuentez, Edwin Stuart Ross Viii

Materials Engineering

Investigation into the issue of out of specification flow data revealed that unregulated transportation conditions exposed 7781 prepreg with phenolic resin to temperature fluctuations up to 125°F. The temperature fluctuations have the potential to advance unwanted curing in the prepreg, making it unsuitable for manufacturing. However, this explanation does not account for the prepreg exceeding specifications above the upper limit. Another explanation was investigated that involved exposure to moisture. Moisture could be preventing curing from taking place and thus resulting in higher flow values. Data collection was unable to proceed past the preliminary stages due to the COVID-19 pandemic and …

Study Of Permeability Testing Methods For Composite Laminates, Thomas S. Busse, Giannina Marie M. Yu

Materials Engineering

Permeability measurements are strong indicators of the effectiveness of evacuation channels within a composite prepreg. The effectiveness of these evacuation channels directly relates to the void content within a processed composite laminate. The goal of Toray Advanced Composites was to compare two permeability tests and determine which one was more reliable, accurate, and economical. The first permeability test method was the Cirrus method, designed by Cirrus Aircraft, a customer of Toray Advanced Composites. The second test was ASTM D8132, the standard method for permeability testing. Additionally, Toray sought to investigate the effect out-time had on the permeability of three different …

Mechanical Properties Of Boehmeria Nivea Natural Fabric Reinforced Epoxy Matrix Composite Prepared By Vacuum-Assisted Resin Infusion Molding, Fabio Da Costa Garcia Filho, Fernanda Santos Da Luz, Lucio Fabio Cassiano Nascimento, Kestur Gundappa Satyanarayana, Jaroslaw W. Drelich, Sergio Neves Monteiro

Michigan Tech Publications, Part 1

Natural lignocellulosic fibers and corresponding fabrics have been gaining notoriety in recent decades as reinforcement options for polymer matrices associated with industrially applied composites. These natural fibers and fabrics exhibit competitive properties when compared with some synthetics such as glass fiber. In particular, the use of fabrics made from natural fibers might be considered a more ecient alternative, since they provide multidirectional reinforcement and allow the introduction of a larger volume fraction of fibers in the composite. In this context, it is important to understand the mechanical performance of natural fabric composites as a basic condition to ensure ecient engineering …

The Effect Of Distal Core Flattening And Heat Treatment On 304 Stainless Steel Guide Wires, Andrew Spencer Yap, Bryce Eric Veit, Matthew Frederick Lopez Villena

Materials Engineering

The mechanical response of 304 stainless steel guide wires due to different temper conditions and amounts of flattening is to be explored in this project. For this specific project, there is no public literature on the mechanical properties of guide wires with the above conditions through tensile testing or Turns to Failure Testing. To address this, the project with Abbott Vascular will measure the mechanical properties of guide wires using the aforementioned factors. Due to a lack of previous literature on this research topic, there are no quantitative goals for the project, however, any new research compiled in this area …

Miniaturized Ultraviolet Imager Phase Iii, Bradley D. Albright, Nicolas A. Armenta, Colin W. Harrop

Mechanical Engineering

This document details the work to date, June 9, 2020, done by the Cal Poly Mechanical Engineering senior project team, Miniaturized Ultraviolet Imager: Phase III (MUVI III), sponsored by the University of California, Berkeley – Space Sciences Laboratory (UCB SSL). MUVI III is the third senior project team of an ongoing design, MUVI: the prototype of a 2U sized CubeSat intended to capture aurora images in the ionosphere. The first team, MUVI I, finished development of the UV imager. The second team, MUVI II, designed the mirror mounting and deployable door mechanisms. The goal of MUVI phase III is to …

Distributed Manufacturing Of Open Source Medical Hardware For Pandemics, Joshua M. Pearce

Michigan Tech Publications, Part 1

Distributed digital manufacturing offers a solution to medical supply and technology shortages during pandemics. To prepare for the next pandemic, this study reviews the state-of-the-art of open hardware designs needed in a COVID-19-like pandemic. It evaluates the readiness of the top twenty technologies requested by the Government of India. The results show that the majority of the actual medical products have some open source development, however, only 15% of the supporting technologies required to produce them are freely available. The results show there is still considerable research needed to provide open source paths for the development of all the medical …

Effects Of New And Recycle Flux On The Mechanical Properties Of Submerged Arc Welded (Saw) Line Pipe Grade X52m And X65m, Taib Meor Mohd Adli

Student Works (2020-2029)

Two line pipe grade X52M and X65M were manufactured using submerged arc welding process. For each grade, two different welding flux condition were simulated, i.e. 100% new flux and 100% recycle flux. The flux used was aluminate basic type trade name OP 132. The outside diameter and wall thickness for X52M was 610mm x 12.7mm and for X65M was 762mm x 14.3mm. Lower weld re-entrant angle and higher weld bead height were observed in recycle flux condition. Lower weld manganese content recorded in recycle flux condition. And lower mechanical tests (i.e. tensile, impact, and hardness) value reported for recycle flux …

Synthesis And Characterization Of Porous Carbon Composite Derived From Biomass Waste For Supercapacitor Application, Cheng Kim Sim

Student Works (2020-2029)

Energy storage devices have gradually dominated human daily activities and indispensable to economy development such as supercapacitor and battery. There are few factors determining the performance of supercapacitor and active material is one of the crucial. Therefore, biomass such as pineapple peel (PP) and green waste (GW) were preferred and prior mixed with manganese and tin carbonate to synthesize carbon composite (PP/GW-ZMO and PP/GW-ZTO) via combustion. Brunauer–Emmett–Teller (BET) was employed to study the textural properties with the highest specific surface area obtained in PP-C (1765.92 m2g-1) and GW-C (1613.92 m2g-1). The existence of composite materials was examined using x-ray diffraction …

Tension-Tension Fatigue Behavior Of Nextel™ 720/Alumina-Mullite Ceramic Composite At 1200°C In Air And In Steam, Sarah A. Witzgall

Theses and Dissertations

Uniaxial tension-tension fatigue performance of an oxide-oxide continuous fiber ceramic composite was studied at 1200°C in laboratory air and in steam. The composite is reinforced with laminated, 0/90 mullite/alumina (NEXTEL™720) fibers woven in an eight-harness satin weave and has a porous alumina/mullite matrix. There is no interphase between the fiber and matrix. The composite relies on the porous matrix for crack deflection and flaw tolerance. Tension-tension fatigue was examined for maximum stresses of 45 – 136 MPa in air and in steam. To assess the effects of the steam environment on fatigue performance, experimental results obtained in air are compared …

Numerical And Analytical Methods To Predict Behavior Of Reinforced Ductile Concrete Composites, Mandeep Pokhrel

Dissertations

Structural components constructed with ductile concrete composites, such as high-performance fiber-reinforced cementitious composites (HPFRCC), are known to perform exceptionally well under extreme mechanical and environmental loading conditions compared to traditional concrete. HPFRCC flexural components exhibit enhanced performance in terms of displacement ductility, energy dissipation capacity, and damage tolerance capacity. However, recent research suggests that the flexural behavior of reinforced HPFRCCs in terms of crack progression, reinforcement plasticity, and failure mechanism is significantly different than conventional reinforced concrete. Specifically, the failure mode of flexural members is found to be predominantly through the fracture of longitudinal reinforcement rather than compression crushing of …

The Impact Of Conversion On The Durability Of Calcium Aluminate Cement Concrete Systems, Marwa Mohsen Korayem

Dissertations

The deterioration of infrastructure in North America has resulted in a significant need for concrete repair materials that can be used to maintain service life of these structures. Hydraulic cement based rapid repair materials can be used to repair pavement and bridge deterioration with minimal impact on economic activities such as freight handling or public transportation. While there are many options for use in repair situations, calcium aluminate cements have become more popular recently, particularly in situations where repairs must be completed rapidly.

Calcium aluminate cement (CAC) is a cement characterized by its rapid strength gain, even at low temperatures …

Modeling Single Microtubules As A Colloidal System To Measure The Harmonic Interactions Between Tubulin Dimers In Bovine Brain Derived Versus Cancer Cell Derived Microtubules, Arooj Aslam

Dissertations

The local properties of tubulin dimers dictate the properties of the larger microtubule assembly. In order to elucidate this connection, tubulin-tubulin interactions are be modeled as harmonic interactions to map the stiffness matrix along the length of the microtubule. The strength of the interactions are measured by imaging and tracking the movement of segments along the microtubule over time, and then performing a fourier transform to extract the natural vibrational frequencies. Using this method the first ever reported experimental phonon spectrum of the microtubule is reported. This method can also be applied to other biological materials, and opens new doors …

Schwann Cells In Combination With Gag-Mimetic Scaffolds For Spinal Cord Repair, Sharareh Hashemi

Dissertations

Spinal cord injury (SCI) being a devastating neurological dysfunction can cause extensive irreversible neuronal loss and axonal damage. Fifty-four cases of spinal cord injury per million people occur annually in the United States. Due to the loss of glial cells and demyelination of axons, the neuronal function of surviving neurons is disrupted leading to permanent loss of sensory and motor functions. The glial scar formed by astrogliosis at the chronic stage protects undamaged tissues, but it is known to be a major barrier for axonal regeneration. The limited regeneration capacity of spinal cord makes it challenging to successfully treat the …

Open Source High-Temperature Reprap For 3-D Printing Heat-Sterilizable Ppe And Other Applications, Noah G. Skrzypczak, Nagendra Gautam Tanikella, Joshua M. Pearce

Michigan Tech Publications, Part 1

Thermal sterilization is generally avoided for 3-D printed components because of the relatively low deformation temperatures for common thermoplastics used for material extrusion-based additive manufacturing. 3-D printing materials required for high-temperature heat sterilizable components for COVID-19 and other applications demands 3-D printers with heated beds, hot ends that can reach higher temperatures than polytetrafluoroethylene (PTFE) hot ends and heated chambers to avoid part warping and delamination. There are several high temperature printers on the market, but their high costs make them inaccessible for full home-based distributed manufacturing required during pandemic lockdowns. To allow for all these requirements to be met …

Fly Ash Based Geopolymer For High Temperature And High Compressive Strength Applications In Aggressive Environment, Aaryan Manoj Nair, Akm S. Rahman

Publications and Research

Geopolymers are the results of geosynthetic reactions between aluminosilicates and strong bases. This results in chemical bonds between aluminum (Al), Silicon (Si)and oxygen (O) composing polymer rings in tetrahedral coordination. These bonds give them widespread useful applications such as high heat bearing ceramics, and base construction material whilst being far more environmentally conscious. The purpose of the experiment is to examine the effect of Silicon Carbide whisker and inorganic glass particles on thermal and mechanical properties of Geopolymers. This study will help understand the effect of various compositions and concentrations of SiO₂ in mechanical strength. In this experiment, the …