Materials Science and Engineering Commons^™

Licoo2 As Sulfur Host To Enhance Cathode Volumetric Capacity For Lithium-Sulfur Battery, Lu Wang, Xue-Ping Gao

Journal of Electrochemistry

Lithium-sulfur battery is one of the most promising secondary battery systems due to its super high theoretical gravimetric and volumetric energy densities (2600 Wh·kg^-1 and 2800 Wh·L^-1, respectively). However, the practical volumetric capacity of sulfur cathode is still unsatisfied due to the overuse of low-density host materials, such as carbon nanomaterials. Herein, commercial LiCoO₂ with the high tap density of 2.94 g·cm^-3 was used as the host material to build high density sulfur-based composite and compact electrode for increasing the volumetric capacity. Obviously, the tap density of the as-prepared S/LiCoO₂ composite was 1.90 g·cm …

Research Progress Of Key Components In Lithium-Sulfur Batteries, Jia-Jia Chen, Quan-Feng Dong

Journal of Electrochemistry

Due to the much higher theoretical specific capacity and energy density than the ones of traditional lithium ion battery, Li-S batteries have long been at the pinnacle in the realms of high-energy Li-metal batteries. However, the complicated electrochemical reactions on the sulfur cathode and Li anode, induced by the thermodynamic and kinetic behaviors of lithium polysulfides, are the intrinsic bottleneck to realize the full potential of Li-S batteries for practical application. In this review, we firstly discuss the roles, and thermodynamic and kinetic behaviors of polysulfides in the charging and discharging processes of Li-S batteries. Then, the functional design and …

Research Progress Of Sulfur Cathode Catalytic Conversions For Lithium-Sulfur Batteries, Qin-Jun Shao, Jian Chen

Journal of Electrochemistry

The electrochemical reduction of sulfur (S) takes place through multistep reactions when S is used as a cathode material. The complete discharge of S to form final product lithium sulfide (Li₂S) is a two-electron reaction. The formation of low-order lithium polysulfides (LiPS) needs to overcome certain energy barriers. And the reduction of Li₂S₂ to Li₂S is the rate-limited step. The reaction kinetic of sulfur cathode is the critical key to determine the electrochemical performance of Li-S batteries, such as specific energy, specific power and low temperature performance, etc. Accelerating the rate-limited step kinetics …

Liquid Metal Electrodes For Electrochemical Energy Storage Technologies, Hao-Miao Li, Hao Zhou, Kang-Li Wang, Kai Jiang

Journal of Electrochemistry

Electrochemical energy storage technologies (ESTs) with low cost, long lifespan and high safety are of great importance for efficient integration of renewable energy into the grid. Liquid metal electrodes (LMEs) possessing the merits of high electronic conductivity, easy manufacture and amorphous structure is of great application value in the field of energy storage batteries. During charge-discharge processing, the LMEs could avoid the issues of structural deformation and dendrite growth in solid metal electrodes, which could effectively extend the cycle life of the LME based batteries. Moreover, LME based batteries are easy to be scaled up and less expensive, which are …

Highly Efficient Co2 Utilization Via Molten Salt Co2 Capture And Electrochemical Transformation Technology, Bo-Wen Deng, Hua-Yi Yin, Di-Hua Wang

Journal of Electrochemistry

The molten electrolytes exhibit high CO₂ absorption capacities, wide electrochemical windows and excellent reaction kinetics, which are promising electrolyte candidates for efficient capture and electrochemical conversion of high-flux CO₂ driven by renewable and clean electricity sources. This short review introduces the recent advancements of CO₂ electroreduction achieved by the authors using molten salt CO₂ capture and electrochemical transformation (MSCC-ET) technology, involving CO₂ absorption kinetics, cathodic kinetics, controllable synthesis of carbon products with unique nanostructures, development of inert oxygen evolution anodes and CO₂ conversion efficiency as well as energy efficiency. The challenges and prospects are …

Temporally Multiplexed Ladar Polarimeter, Christian Keyser, Richard Kenneth Martin

AFIT Patents

In a polarimeter, a polarization modulator changes a polarization phase of an output optical pulse with a modulation function that varies in time over the duration of the optical pulse. A static polarization state analyzer, which includes a one or more static polarization component analyzers and detectors, receives the modulated optical pulse after interaction with a target medium and provides time varying intensities of the polarization components of the received pulse. A signal processing module determines a polarization property of the target medium, such as a Mueller matrix, dependent upon time varied intensities over the duration of the received optical …

In Vitro Study Of Biodegradation Of Glass And Glass Crystals Of The R2o-Ro-Caf2-P2o5-Al2o3-Sio2 System, Aripova Mastura, Mkrtchyan Ripsime

CHEMISTRY AND CHEMICAL ENGINEERING

For bioactive glasses and glass crystals, biodegradation is the most important parameter. The biodegradation process was studied for glasses and glass crystals synthesized in the R2O-RO-CaF2-P2O5-Al2O3-SiO2 system. Degradation analysis of samples was carried out on a Hitachi 902 biochemical analyzer in 0.9% NaCl, 3.8% sodium citrate solution and human serum. . The kinetics of leaching in various environments, the influence of the components of glasses and glass crystals on their biodegradation have been determined. The composition of glass that is most susceptible to degradation has been determined. IR spectroscopic analysis of glasses and crystallized glasses in vitro showed that all …

Configuration And Competitive Reactivity Of Ligands In Mixed Ligand Complexes Of Dialkylditiophosphates And Aminobenbenzimidazole (Part 2. Zn, Fe, Ni), Esbergenova Botakoz, Daminova Shakhlo, Kadirova Zuhra, Sharipov Khasan

CHEMISTRY AND CHEMICAL ENGINEERING

With the aim of determination of electronic and geometrical structures of mixed-ligand complexes, theoretical modeling of the structures of coordination compounds of transition metals with dialkyldithiophosphate chelating ligands with aminobenzimidazoles carried out using quantum chemical methods. Using BIOVIA Materials Accelrys Studio 2017 software packages, the geometry, electron density distribution, and frontier orbitals calculated for the mixed ligand complexes Zn(II), Cu(II), Ni(II), Fe(III), which is necessary for understanding the electronic structure of coordination compounds with chelating ligands.

Fully Inkjet-Printed Multilayered Graphene-Based Flexible Electrodes For Repeatable Electrochemical Response, Twinkle Pandhi, Kiyo Fujimoto, Pete Barnes, Jasmine Cox, Hui Xiong, Paul H. Davis, Harish Subbaraman, David Estrada

Materials Science and Engineering Faculty Publications and Presentations

Graphene has proven to be useful in biosensing applications. However, one of the main hurdles with printed graphene-based electrodes is achieving repeatable electrochemical performance from one printed electrode to another. We have developed a consistent fabrication process to control the sheet resistance of inkjet-printed graphene electrodes, thereby accomplishing repeatable electrochemical performance. Herein, we investigated the electrochemical properties of multilayered graphene (MLG) electrodes fully inkjet-printed (IJP) on flexible Kapton substrates. The electrodes were fabricated by inkjet printing three materials – (1) a conductive silver ink for electrical contact, (2) an insulating dielectric ink, and (3) MLG ink as the sensing material. …

Far Infrared Radiation Property Of Elbaite/Alumina Composite Materials, Qi Lu, Bowen Li, Huan Zhang

Michigan Tech Publications, Part 1

Far infrared materials have been prepared by precipitation method using natural elbaite powder as raw materials, which belongs to tourmaline group. The chemical formula of elbaite is Na(Al, Li)3Al6B3Si6O27(O, OH, F)4. X-ray powder diffraction (XRD) shows that elbaite and alumina in composite material has good crystal form. In addition, XRD results indicate the formation of alumina crystallites show that alumina powder exists as nano-meter particles on the surface of elbaite powder. It can be calculated the particles diameter of Al2O3 is 47.86nm. The maximum infrared radiation rate of tourmaline/alumina composite materials is 0.89 when the ratio of alumina in elbaite …

Comparative Study Of Silk-Based Magnetic Materials: Effect Of Magnetic Particle Types On The Protein Structure And Biomaterial Properties, Ye Xue, Samuel Lofland, Xiao Hu

College of Science & Mathematics Departmental Research

This study investigates combining the good biocompatibility and flexibility of silk protein with three types of widely used magnetic nanoparticles to comparatively explore their structures, properties and potential applications in the sustainability and biomaterial fields. The secondary structure of silk protein was quantitatively studied by infrared spectroscopy. It was found that magnetite (Fe3O4) and barium hexaferrite (BaFe12O19) can prohibit β-sheet crystal due to strong coordination bonding between Fe3+ ions and carboxylate ions on silk fibroin chains where cobalt particles showed minimal effect. This was confirmed by thermal analysis, where a high temperature degradation peak was found above 640 °C in …

Mechanochemical Conversion Kinetics Of Red To Black Phosphorus And Scaling Parameters For High Volume Synthesis, Samuel V. Pedersen, Florent Muramutsa, Joshua D. Wood, Chad Husko, David Estrada, Brian J. Jaques

Materials Science and Engineering Faculty Publications and Presentations

Adopting black phosphorus (BP) as a material in electronic and optoelectronic device manufacturing requires the development and understanding of a large-scale synthesis technique. To that end, high-energy planetary ball milling is demonstrated as a scalable synthesis route, and the mechanisms and conversion kinetics of the BP phase transformation are investigated. During the milling process, media collisions rapidly compress amorphous red phosphorus (RP) into crystalline, orthorhombic BP flakes, resulting in a conversion yield of ≈90% for ≈5 g of bulk BP powder. Milling conversion kinetics, monitored via ex situ x-ray diffraction, manifest a sigmoidal behavior best described by the Avrami rate …

Research Of The Process Of Deformation Of Extractional Phosphoric Acid From Phosphorites Of Central Kyzylkum, Khodjamkulov Sakhomiddin, Mirzakulov Kholtura, Melikulova Gavkhar, Usmanov Ilkham

CHEMISTRY AND CHEMICAL ENGINEERING

The purpose of this research was to determine the optimal technological parameters for the purification of extraction phosphoric acid based on phosphorites of Central Kyzylkum from fluorine by precipitation with sodium salts. The influence of the norm of sodium silicate and the total norm of sodium carbonate and sodium metasilicate salts on the chemical composition and degree of precipitation of sodium silicofluoride was research. It is shown that the optimal norm of sodium metasilicate is the stoichiometric norm for binding fluorine present in the extraction phosphoric acid to silicofluoride and the total norm of sodium salts is 120-140%, the temperature …

Modeling Of Craft Oil- Water Emulsion Under Laboratory Conditions, Arslanov Sharafutdin, Dengaev Aleksey, Getalov Andrey, Sarigin Boris

CHEMISTRY AND CHEMICAL ENGINEERING

The purpose of this research is to study the possibilities of modeling oil-water emulsion in the laboratory. The study of the ratio of components and conditions of dispersion (formation) of oil-water emulsions on their stability at different settling temperatures using a laboratory model can optimize the separation of oil-water emulsions in field conditions. The possibility of modeling commercial oil and water emulsions in laboratory conditions is investigated, the average diameters of water globules in simulated oil and water emulsions at different times of their formation are determined, and the obtained average globule diameters are compared with the average diameter of …

The Possibilities Of Using Loess Clay Of Kattabog Deposit In The Production Of Ceramic Products, Ruzibaev Bahrom, Saloxidinova Salima

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the research was to determine the properties of loess clay in Kattabog deposit (Uzbekistan) to identify possible areas of use. Modern methods of physicochemical analysis are used: spectroscopic, x-ray phase, electron microscopic methods of analysis. The research results showed that the main phases of clay are hydromica, quartz, kaolinite, calcite and orthoclase. Based on the research, it can be stated that the clay of Kattabog deposit has good physical and technical properties and mineralogical composition, which is a valuable raw material for the production of various ceramics, bricks, tiles, majolica and other products.

Influence Of The Aluminum Oxide Additive On The Phase Composition Of Mullit-Forming Aluminosilicate Minerals, Mkrtchyan Ripsime, Aripova Mastura

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the research is to determine the effect of alumina on the phase composition of shale of the Jerdanak deposit and the quartz-pyrophyllite rock of the Baynaksay deposit during high-temperature firing. X-ray phase analysis determined changes in the phase composition of rocks with additives from 5 to 20% aluminum oxide as a result of firing at 1300 and 1400 °C. A comparative analysis revealed the absence of cristobalite formation, a decrease in the quartz content, and an increase in the amount of mullite for shale samples. No positive effect of alumina additives on the phase composition of quartz-pyrophyllite …

Coordination Compounds Of Copper, Cobalt And Nickel Formates With Formamide And Carbamide, Jumaniyazova Mukaddas, Azizov Tohir

CHEMISTRY AND CHEMICAL ENGINEERING

The synthesis of mixed ligand coordination compounds of copper, cobalt and nickel formates with formamide and urea in an aqueous solution was carried out. The metal content in the complexes was determined by complexometric titration. Using IR spectroscopy, it was proved that the coordination of formamide and urea with the complexing atom is carried out through the oxygen atom of the carbonyl group. The absorption spectrum of coordinated water is also present in the IR spectrum. The nature of the change in the frequency of stretching vibrations of the –OH group in the composition of water indicates its location in …

Configuration And Competitive Reactivity Of Ligands In Mixed Ligand Complexes Of Dialkylditiophosphates And Aminobenbenzimidazole (Part I: Au, Pt, Ag), Esbergenova Botakoz, Daminova Shakhlo, Kadirova Zuhra, Sharipov Khasan

CHEMISTRY AND CHEMICAL ENGINEERING

With the aim of determination of electronic and geometrical structures of mixed-ligand complexes, theoretical modeling of the structures of coordination compounds of transition metals with dialkyldithiophosphate chelating ligands with aminobenzimidazoles carried out using quantum chemical methods. Using BIOVIA Materials Accelrys Studio 2017 software packages, the geometry, electron density distribution, and frontier orbitals calculated for the mixed ligand complexes of Au(III), Pt(II), Ag(I), Cu(II), Ni(II), Fe(III), which are necessary for understanding the electronic structure of coordination compounds with chelating ligands.

Educational Cluster - Foundation Of The National Economy And Regional Innovation System, Usmonov Botir, Kushiev Khabibjon

CHEMISTRY AND CHEMICAL ENGINEERING

The paper analyzes the available resources for the creation of a cluster approach to the integration of education, science and industry in order to create a mechanism to bring the development of the economy to the level of modern requirements. The article describes the collaboration of science, education and industry through the clustering process. Ways to introduce clustering in the national innovation system are described. At the same time, the role of the integration of education, science and industry with the elements of the National Innovation System is analyzed. In conclusion, the role of the education cluster in the regional …

Obtaining Microcrystalline Cellulose From Melon Crops And Studying Its Structure, Umarova Vasila, Mardonov Asror, Khamdamova Dilnoza, Akmalova Guzal

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the study was to obtain microcrystalline cellulose from gourds. Cellulose was isolated from the stems of watermelon and pumpkin by acid and alkaline heat treatment. Microcrystalline cellulose was obtained from cellulose by hydrolysis. Cellulose was hydrolyzed in a mixture of sulfuric acid and hydrogen peroxide. The optical parameters of the microcrystalline cellulose sample, ash content, bulk density, water swelling, and moisture sorption were determined. The structural features of the obtained microcrystalline cellulose were studied by IR spectroscopy. The functional groups present under various conditions for the production of microcrystalline cellulose were determined. The influence of the duration …

Radiopaque Activity Of Iodine Containing Methylene-Bis-Carbamate, Baltabaev Ubaydulla, Djuraev Abdukahhor, Abduvakilov Jahongir, Abdullaeva Matluba

CHEMISTRY AND CHEMICAL ENGINEERING

Considering that many derivatives of bis carbamates have different biological activity, it was intuitive to produce a targeted synthesis of new derivatives of bis carbamates by the interaction of hexamethylene diisocyanate with 3,5-diode-4-hydroxybenzoic acid and 2,4,6-triiodophenol (1: 2 mol, respectively) in freshly distilled dry pyridine at 95-110 оC for 6 hours, the corresponding derivatives were obtained - methylene bis carbamates. Experimental studies have been conducted to identify the acute toxicity and radiopaque properties of the synthesized new N, -hexamethylene bis (2,6-diode-4-carboxyphenylcarbamate).

Modification Of Lithium Lubricants, Azimova Shodiyakhon, Arslanov Sharafutdin, Aripdjanov Oybek, Azimov Dilmurod

CHEMISTRY AND CHEMICAL ENGINEERING

The aim is to study the effect of the presence of free alkalis and acids on the properties of the complex lithium greases and the choice of the optimal dispersion medium, which provides the required physicochemical characteristics of the developed grease. The dispersed phase of lithium greases studied in the polyalphaolefin oils media. It was found that the use of a mixture of polyalphaolefin oil-4 and polyalphaolefin oil-40 as a percentage of 23/77 with a total content of 83.0% provides a relatively low effective viscosity of the lubricant at low temperatures and a relatively high tensile strength at high temperature.

Effective Oil Extraction From Bombyx Mori Silkworm Pupae And Its Structural Characteristics, Avazova Oynavod, Yugai Sveta, Rashidova Sayora

CHEMISTRY AND CHEMICAL ENGINEERING

The conditions for the effective isolation of oil from the silkworm Bombyx mori pupae, based on the extraction of extracted oil with organic reagents, have been studied. The quantitative content of oil was determined in the samples. It is revealed that the oils extracted using gasoline have a high fat-wax composition compared with ethyl alcohol and hexane. When dried pupae processed with gasoline, it is possible to extract up to 16% of fatty substances as much as possible. Physical-chemical characteristics of the oil from silkworm pupae are characterized by high quality indicators. In particular, the presence of unsaturated fatty acids …

Composition Of Liquid Paraffins For Flotation Enrichment Of Potassium Chloride, Vaqqosov Sobir, Xolmuratov Shamsitdin, Buxarov Shuhrat, Kodirov Orifjon

CHEMISTRY AND CHEMICAL ENGINEERING

The purpose of this work is to determine the source of liquid paraffins from secondary products of the local chemical industry, compare the performance properties and use the resulting products as apolar co-reagents in silvinite flotation. The experiments were conducted with secondary used hexane and pyrocondensation. To improve the efficiency of flotation, the dependences of the order of reagent’s supply into the process and the time of action were studied. Experiments have shown that when adding tetradecane and pentadecane in an amount of 2.5 to 7.5% to hexane liquid paraffins, it is possible to reduce the tail of KCl to …

Influence Of Technological Parameters On The Chemical Composition Of Calcium Polyphosphates From Phosphorites Central Kyzylkum, Ulugberdieva Ziyada, Khujamberdiev Sherzod, Mirzakulov Kholtura, Usmanov Ilkham

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the research was to study the effect of temperature, the ratio of P2O5EPA:P2O5PRM and the duration of calcination on the content of various forms of P2O5 in calcium polyphosphate. The effect of calcination temperature from 150 to 300 °C, the ratio of P2O5EPA:P2O5FRM from 2,15 to 4,50 and the duration of the process from 20 to 120 minutes on the changes in various forms of P2O5 were studied. It was shown that with increasing temperature to 200-250 °C the content of the total (ortho + poly) assimilable form of Р2О5 increases and then decreases, passing through a …

Bases Of Development Of Technologies Of Synthesis Of Oxide Materials In Big Solar Furnace (Parkent), Gulamova Dilbara, Baxronov Khayot, Bobokhulov Sirojiddin, Eshonkulov Elyor

CHEMISTRY AND CHEMICAL ENGINEERING

The advantages of synthesis of complex oxide compounds by solar energy, the possibility of obtaining highly textured nano materials are shown. The development of heliomaterial science, aimed at the synthesis of new materials, is inextricably linked with the use of effective optical energy systems. On the example of obtaining superconducting materials of nominal composition Bi1.7Pb0.3Sr2Ca(n-1)CunOy (n = 3-20), optimization of the parameters of the optical-energy system of the Big Solar Furnace (Parkent) is shown. The ideology of developing heliotechnology for the synthesis of inorganic materials in a solar furnace is presented. The properties of a superconducting material of nominal Bi1.7Pb0.3Sr2Ca(n1)CunOy …

Framing Energy And Minerals For Future Pathways, Michelle Michot Foss, Michael S. Moats, Kwame Awuah-Offei

Materials Science and Engineering Faculty Research & Creative Works

We present a challenge for Group of Twenty (G20) discussions that entails (1) greater awareness of the role of non-fuel minerals in the global economy overall, but specifically in the energy sector; and (2) the introduction and acceleration of alternative energy sources and technologies. We focus on chemical battery energy storage, given its prominence in all views and outlooks of energy futures, especially for mobility. We present recommendations for G20 discussions and actions on battery materials, and the crucial underlying supply chains for mineral commodities.

Dynamic Analysis Of Viscoelastic Circular Diaphragm Of A Mems Capacitive Pressure Sensor Using Modified Differential Transformation Method, Dr Olurotimi A. Adeleye, Muritala Yusuf, Oluwaseyi .. Balogun

Karbala International Journal of Modern Science

In this paper, a dynamic analysis of the viscoelastic circular diaphragm of a Micro-Electro-Mechanical System (MEMS) capacitive pressure sensor using the Modified Differential Transformation Method (MDTM) is presented. The MEMS technology has been increasingly used to fabricate sensors and actuators and the MEMS capacitive pressure sensor is emerging in many high-performance applications. The deflection of these sensors diaphragm (plate) depends largely on the material of the diaphragm. In this study, a circular diaphragm of viscoelastic material is modeled using the classical plate theory. The governing differential equation is solved using Modified Differential Transformation Method (MDTM) and the result is validated …

Particle Tracking Of A Simulated Melt Pool Of Selective Laser Melting, Prakash Gautam

Graduate Theses & Non-Theses

Metal additive manufacturing (AM) produces parts by addition as compared to subtraction of material. Selective laser melting (SLM) is an AM technique that prints objects layer-by-layer, selectively melting powders using a laser. The mechanical properties of SLM parts are affected by processing parameters and powder characteristics, both of which alter the molten melt pool flow field. Marangoni convection (M-flow) is a thermo-capillary mass transfer from a region of lower surface tension to a region of higher surface tension, referred to as a radially outward flow for SLM. However, in the presence of surface-active elements such as oxides and sulfides, the …

Effect Of Global Energy Density On Dynamic Strain Hardening Of Selective Laser Melted Alsi10mg, Md Salah Uddin

Graduate Theses & Non-Theses

The characteristics of strain hardening of selective laser melting (SLM) processed AlSi10Mg under dynamic impact was investigated. The dynamic impact at high strain rate loading conditions occurs in many engineering applications, such as collisions of flying objects on aircraft engine components like bird impact, vehicle collisions, and impacts occur in sports events like club impact on golf balls and helmet impact. Among these various applications, the strength of the materials needs to characterize accurately for product quality, performance, and reliability.

AlSi10Mg is a lightweight metal alloy, and it has a growing demand in aircraft, military, and automotive applications. SLM is …