Other Chemical Engineering Commons^™

Peptide-Directed Nanoparticle Synthesis With A Denovo Pd-Binding Sequence Fused To A Reporter Protein, Rita Eloisa Tejada Vaprio

Graduate Theses and Dissertations

There is a need for low-cost nanoparticle materials in the context of new technologies for catalyst development. The purpose of this work was to recombinantly produce a 45- amino acid long metal binding peptide that is useful for nanoparticle synthesis. Using splicing by overlap extension PCR, a synthetic gene containing the fusion of the metal binding peptide with Green Fluorescent Protein (GFPUV) was constructed. The metal binding peptide, fused to reporter protein GFPUV, was expressed using high cell density fermentation. Palladium nanoparticles of an average diameter of 1.18 0.45 nm were synthesized by using the crude cell extract containing the …

Electrochemical Behavior Of Dense Electrodes For Impedancemetric Nox Sensors, Nabamita Pal

Doctoral Dissertations

NOx (NO and NO2) exhaust gas sensors for diesel powered vehicles have traditionally consisted of porous platinum (Pt) electrodes along with a dense ZrO2 based electrolyte. Advancement in diesel engine technology results in lower NOx emissions. Although Pt is chemically and mechanically tolerant to the extreme exhaust gas environment, it is also a strong catalyst for oxygen reduction, which can interfere with the detection of NOx at concentrations below 100 ppm. Countering this behavior can add to the complexity and cost of the conventional NO x sensor design. Recent studies have shown that dense electrodes are less prone to heterogeneous …

Feasibility Analysis Of Recycled-Paper Fueled Agricultural Desalination Process: Design Of Recycling And Desalination Processes, Sean M. Street

Chemical Engineering Undergraduate Honors Theses

While recycled-paper-briquettes have lower BTU ratings than wood, and fresh water is typically a low cost to agricultural entities, situations exist where economic and/or environmental factors may allow a recycled-paper-fueled desalination process to be viable for some specific agricultural entities. This document begins with a discussion of how water is priced throughout India before analyzing trends in the Maize futures market. By tying the two together, an opportunity is created for solution which the remainder of the document presents. Paper waste in India makes-up 50% of its solid waste country-wide; however, only a quarter of that waste is recycled - …

Life Cycle Assessment Of Sweet Sorghum As Feedstock For Second-Generation Biofuel Production, Karla Morrissey

Chemical Engineering Undergraduate Honors Theses

There exist few life cycle assessments (LCAs) in the literature that focus on the second-generation biofuel production from sweet sorghum, a non-food-source feedstock that offers several advantages in terms of farming requirements compared to corn or sugarcane. The objective of this LCA study was to evaluate biofuels produced from sweet sorghum to determine the potential environmental benefits of producing sweet sorghum biofuel compared to conventional fossil fuels. The biofuel production process used for this study differed from other LCAs in that, in parallel to stalk juice extraction and fermentation, residual bagasse and vinasse was pyrolyzed and upgraded to a diesel …

Tailings Dust Emissions, Emily Degner, Sam Horn, Zakary Galligan, Ryan Bernard, Julie Jameson, Josh Mueller, Natalie Tucker, Joe Griffin

Chemical Engineering Undergraduate Honors Theses

Fugitive dust emissions from the storage and handling of mine tailings presents environmental and safety concerns, which must be addressed to promote the land sustainability and the health and safety of individuals around a tailings storage facility (TSF). The investigated dust control methods were agglomeration, binder slurry injection, and topical spray.

The Dust Busters determined that pelletizing was the most practical method of agglomeration. In order to produce durable pellets from the mine tailings, which consist primarily of silica, a binder must be added. A variety of binders were considered including magnesium and calcium chloride, bentonite, barite, cement, vinyl polymers, …

Novel Iii-V Alloys For Unassisted Water Splitting., Alejandro Martinez-Garcia

Electronic Theses and Dissertations

Direct conversion of solar energy to fuels by photoelectrochemical (PEC) water splitting has been identified as a promising route for sustainable power generation and storage. However, semiconductor materials with suitable opto-electronic properties have yet to be identified. In this dissertation, band gap engineering of III-V alloys, tuning the light sensitivity of GaP and GaN nitride through alloying Sb, is investigated for developing new semiconductor alloys with appropriate opto-electronic properties and their performance with overall water photoelectrolysis. In addition to III-V materials, copper oxide (Cu₂O) electrode was investigated for p-type semiconductor material. The new III-V alloy anodes were studied …

Data Driven Discovery Of Materials Properties., Fadoua Khmaissia

Electronic Theses and Dissertations

The high pace of nowadays industrial evolution is creating an urgent need to design new cost efficient materials that can satisfy both current and future demands. However, with the increase of structural and functional complexity of materials, the ability to rationally design new materials with a precise set of properties has become increasingly challenging. This basic observation has triggered the idea of applying machine learning techniques in the field, which was further encouraged by the launch of the Materials Genome Initiative (MGI) by the US government since 2011. In this work, we present a novel approach to apply machine learning …

Effect Of High Cationic Flocculant On Anaerobic Digestion Of Municipal Wastewater., Prathap D. John

Electronic Theses and Dissertations

Anaerobic digestion (AD) of municipal sludge is a widely used stabilization process at municipal wastewater treatment plants. It is highly effective in reducing sludge volume and produces methane gas which is used as fuel in the wastewater plant. Following digestion sludge is sent to a centrifuge to separate the solids from the liquids. Louisville MSD adds flocculent to material in the centrifuge to better coagulate the solids, thereby aiding in separation of the solids from the liquids. The potential for further AD, COD reduction, and methane generation of the liquid effluent from the centrifuge was unknown, particularly in regards to …

Technical Feasibility Of Selectively Separating Rare Earth Elements By Vapor Phase Extraction And Condensation, Katie Lyons

Graduate Theses & Non-Theses

Experiments were performed to evaluate the technical feasibility of selectively separating selected rare earth halides (bromides and chlorides) using a volatilization and condensation technique. Initially, optimum chloridizing and bromidizing roast parameters were secured in studies performed on reagent grade rare earth oxide samples and subsequently confirmed in tests performed on mineral ore and concentrate samples. The volatilization and condensation experiments were performed by placing the subject rare earth halide samples in an argon-purged multiple-zone tube furnace wherein the temperature profile was controlled to establish separate vaporization and condensation regions. Following each experiment, condensate and solid residue samples were analyzed to …

In-House Fabrication Of Temperature Sensitive Paint For Turbine Cooling Research, Mayur D. Patel, Mark A. Ricklick

Beyond: Undergraduate Research Journal

The Temperature Sensitive Paint (TSP) is a widely used method in measuring and visualizing flow separation and heat transfer. Compared to the cost and time consumption needed for methods such as pitot tubes, temperature sensitive paint is a cheaper alternative. Due to high usage in College of Engineering research projects, it was determined that in house fabrication of temperature sensitive paint would reduce time and cost limitations. For initial stages, literature research was performed to determine the recipe of intensity based TSP with luminophore and polymer binder that operated optimum at temperatures from 0-100°C. Europium III thenoyltrifluoroacetonate was determined to …

Synthesis, Characterization, And Activity Of Co/Fe Alumina/Silica Supported Ft Catalysts And The Study Of Promoter Effect Of Ruthenium, Sunday Azubike Esumike

Doctoral Dissertations

The alumina and hybrid alumina-silica FT catalyst were prepared by one-step solgel/oil-drop methods using metal-nitrate-solutions (method-I), and nanoparticle-metaloxides (method-2). The nanoparticle-metal-oxides did not participate in solubility equilibria in contrast to metal nitrate in method-1 causing no metal ion seepage; therefore, method-2 yields higher XRF metal loading efficiency than method-1. The thermal analysis confirmed that the metal loading by method-1 and method-2 involved two different pathways. Method-1 involves solubility equilibria in the conversion of metal-nitrate to metal- hydroxide and finally to metal-oxide, while in method-2 nanoparticle-metal-oxide remained intact during sol-gel-oil-drop and calcination steps.

The alumina supported catalysts were dominated by γ-alumina …

Enhanced Energy Storage And Conversion Applications By Porous Carbon And Atomic Layer Deposition, Yomna H. Abdelmoaty

Theses and Dissertations

The design and synthesis of porous materials attracted great attention recently because of their potential use in many fields like clean energy and environmental protection. Herein, we introduced new synthetic approaches for the preparation for porous carbons and organic polymers for selective CO₂ and iodine capture application. Regarding CO₂ capture application, Two new

series of porous carbons (PYDCs) and (TRI-Ps) were synthesized by thermally activating Pyrazole and Triazolo Pyridine monomers respectively using KOH as a catalyst, which leads to porous carbon. PYDCs exhibit high surface area according to Brunauer–Emmett–Tellertheory (SA_BET = 1266–2013 m² g⁻¹), …

Optimising The Performance Of Cement-Based Batteries, Aimee Byrne, Shane Barry, Niall Holmes Dr., Brian Norton

Articles

The development of a battery using different cement-based electrolytes to provide a low but potentially sustainable source of electricity is described. The current, voltage, and lifespan of batteries produced using different electrolyte additives, copper plate cathodes, and (usually) aluminium plate anodes were compared to identify the optimum design, components, and proportions to increase power output and longevity. Parameters examined include water/cement ratio, anode to cathode surface area ratio, electrode material, electrode spacing, and the effect of sand, aggregate, salts, carbon black, silica fume, and sodium silicate on the electrolyte. The results indicate that the greatest and longest lasting power can …

Using Better Solvents To Functionalize Glass With Chlorotrimethylsilane, Jonathan Cookston

Summer Community of Scholars Posters (RCEU and HCR Combined Programs)

No abstract provided.

The Effects Of Carboxylic Acids In Aluminum Anodizing, Abby E. Koczera

Honors Theses and Capstones

Hard-anodized alumina coatings were formed in sulfuric acid at low temperature and high current density in the presence of carboxylic acid additives. Citric acid, trimesic acid, mellitic acid and ethylenediaminetetraacetic acid (EDTA) were utilized in varying concentrations. The additives were chosen for their capacity to form complexes with tri-valent aluminum and hence impart chemical stability to the coatings. The coatings were sealed in boiling water, and corrosion resistance was observed in a high pH solution of potassium hydroxide. The coatings were examined using scanning electron microscopy (SEM) to assess coating thickness and pore dimensions. Thicker coatings were produced when the …

Controlled Humidity Chambers To Maintain Red Roses’ Freshness And Improve Their Shelf Life, Rima Vasudevan

Williams Honors College, Honors Research Projects

Floriculture is the third largest agricultural crop in the United States of America. Flowers are usually transported in pots of mud or with the roots still submerged in water to increase their shelf life and ensure freshness during long hours of transport. This not only increases the weight of the transport materials but also makes the process expensive.

The research conducted provides the first stages of an alternative packaging material that can lower the weight of transport materials and maintain the freshness of the flowers. The experiments conducted in this work support the hypothesis that using controlled high (>60%) …

Role Of Salt On Coating Failure, Kyle Krause

Williams Honors College, Honors Research Projects

It is important to understand the role of salt in the coating failure because it may influence the coating degradation mechanism that is related to coating performance. This project will study the role of salt on two types of organic coatings under two different immersion environment. The environment selected was 3.5% by weight sodium chloride solution and deionized (DI) water. The two coatings were Neorez 1080 (a waterborne polyurethane) and Joncryl 587-AC (a solvent borne polyurethane). Each coating was tested in each environment using electrochemical impedance spectroscopy (EIS) measurement which presented a total of four data sets. The equivalent circuit …

Corrosion Resistance Of Silane Coatings On Aluminum And Magnesium Alloys, John Demopoulos

Williams Honors College, Honors Research Projects

The purpose of this project was to increase the corrosion resistance of aluminum and magnesium alloys by coating the coupons with a silane on the surface. Four different silanes: 3-aminopropyltriethoxysilane (APTES), Bis(triethoxysilylpropyl)amine (Bis), (Heptadecafluoro-1,1,2,2-tetrahydrodecyl)trichlorosilane (FTS), and (Heptadecafluoro-1,1,2,2-tetrahydrodecyl)triethoxysilane (non Cl FTS) will be used and compared to see which silane would give the best corrosion resistance. Each silane solution was coated on the coupons by using a solution method in which the coupon was submerged for 24 hours and then thermally cured for another 24 hours. Once the coating was applied, the water contact angle and the thickness of the coating …

Chemical Modification Of Crumb Rubber To Increase Its Bonding With Concrete, Mary T. Mccannon, Kendall J. Sweitzer

Williams Honors College, Honors Research Projects

The hydrophilicity of crumb rubber was increased with wet chemical modification and added to concrete to increase its adhesion with concrete, consequently the compressive strength relative to that of concrete with untreated rubber. Other modification methods were tested on crumb rubber and rubber sheets to yield an increase in hydrophilicity. Certain tests were less reliable for powder testing or tedious and time consuming and concrete materials and rubber may not be homogeneous.

For wet chemical modification, several approaches were attempted. First, crumb rubber was soaked in 5% sodium hydroxide, 5% potassium permanganate and saturated sodium bisulfite, tested for hydrophilicity using …

Titanium Nanoparticles Synthesized Via Hydrothermal Reaction, Kyle W. Hodge

Williams Honors College, Honors Research Projects

The main goal of this project was to determine if increasing the time and temperature of a hydrothermally reacted titanium nanotube would increase the size of the nanotubes. Five experiments were conducted while varying the time and temperature of the reaction: 120°C for 24 hours, 120°C for 48 hours, 150°C for 24 hours, 180°C for 24 hours, and 180°C for 48 hours. Following the synthesis of all of these samples x-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive spectroscopy (EDS) analyses were performed. The XRD analysis revealed anatase titanium nanoparticles formed in the 120°C and 150°C samples, this could …

Controlling Properties Of Agglomerates For Chemical Processes, Joseph A. Halt

Dissertations, Master's Theses and Master's Reports

Iron ore pellets are hard spheres made from powdered ore and binders. Pellets are used to make iron, mainly in blast furnaces. Around the time that the pelletizing process was developed, starch was proposed as a binder because it’s viscous, adheres well to iron oxides, does not contaminate pellets and is relatively cheap. In practice, however, starch leads to weak pellets with rough surfaces – these increase the amount of dust generated within process equipment and during pellet shipping and handling. Thus, even though the usual binder (bentonite clay) contaminates pellets, pelletizers prefer it to starch or other organics.

This …

Enzymatically Active Microspheres For Self-Propelled Colloidal Engines, Jungeun Park

Dissertations and Theses

Micro- and nano-motors have attracted numerous attentions from various scientific areas due to their potential applications. Most studies on self-propelled colloidal engines have exploited catalytic decomposition of hydrogen peroxide to drive the motor. Since the hydrogen peroxide is caustic, it is not suitable to use in biological applications, encouraging people to develop “greener” fuels. The aim of this research is to study a new transduction mechanism for self-propulsion not tied to hydrogen peroxide, and which can in particular be used with biological molecules as fuels. In this study, we focus on making particles with enzymatic activity which can effectively decompose …

Ionic Liquids Tethered To Activated Carbon For Capture Of Airborne Toxins, Devin Peck

Dissertations and Theses

Ionic liquids (ILs) were investigated for functionalization of activated carbon (AC) adsorbents for the filtration of warfare toxins. Preliminary steps were taken by testing absorption capacity of neat ILs and tethering ionic liquids to the surface of AC. AC is known to have good adsorption ability for warfare agents. Functionalizing the AC with ILs could enhance the capture ability significantly. ILs have been found to be good absorbents for a variety of gaseous species. The absorption selectivity and capacity can be tuned by changing the anion-cation pair. By tethering ILs to AC, the beneficial properties of gas absorption from ILs …

Electrochemical Oxidation Of Antibiotic, Antihistamine, Analgesic And Cns Stimulant Pharmaceuticals, Md Mosaddek Hossen

Chemical and Biological Engineering ETDs

Electrochemical oxidation is a common method for the degradation of chemicals by applying potential at a definite value. In this research, ‘cyclic voltammetry’ experiments were conducted to find out the oxidation potential for 8 different pharmaceuticals. Mainly, 3 different pH solutions (pH 6.0, 7.5, 9.0) and 9 different concentrations (1, 2, 5, 10, 20, 50, 100, 200, 500 µM) were studied for each of the pharmaceuticals in this experiments. Acetaminophen, Ibuprofen, Naproxen Sodium, Caffeine showed oxidation peak at 0.34-0.79V, 1.37- 1.39V, 0.94-1.01V, 1.44-1.55V respectively at different pH and concentrations. Antibiotic and antihistamine pharmaceuticals i.e. Erythromycin Hydrate, Triclosan, Sulfanilamide, Diphenhydramine Hydrochloride …

Design, Construction, And Preliminary Testing Of A Square Cross-Sectional Mixing Chamber, Holly Holmes-Smith

Chemical Engineering Undergraduate Honors Theses

Throughout the US, large quantities of chlorine are produced and transported by rail. In the past, train accidents led to deadly accidental releases and the need for mass evacuation. However, moving people unnecessarily may cause pandemonium or danger to health for sensitive members of the public. In these past cases, the models used for evacuation distances did not accurately predict the impact of the chlorine release, but these models did not take into account the reactivity of chlorine. Because chlorine is a highly reactive gas, it is absorbed into the surrounding environment which reduced the amount of chlorine in the …

Chlorpyrifos Removal For Wastewater Reuse, Indran Kamalanathan

Chemical Engineering Undergraduate Honors Theses

Approximately 1.2 billion people around the world live in areas of physical water scarcity. This could increase to half of the world’s population by 2030 and could displace 24 to 700 million people unless steps are taken to ensure adequate water supply.¹ Water scarcity is an escalating issue within the United States, specifically in Western inland states with arid climates. This scarcity is encouraging communities to investigate tertiary level municipal wastewater treatment, allowing for reuse of wastewater. Unfortunately, wastewater contains numerous contaminants that are not regulated by the Environmental Protection Agency (EPA) under the Safe Drinking Water Act (SDWA). …

Haul Truck Tires Recycling, Omkar Bhave

Chemical Engineering Undergraduate Honors Theses

The disposal of large Off-the-Road (OTR) tires is an increasingly important concern. These tires can weigh up to 8,450 pounds with an overall diameter and width of approximately 140.7 inches and 45.1 inches respectively. OTR tires are used for mining vehicles such as haul trucks, wheel loaders, backhoes, graders, and trenchers.[1] These new tires cost between $38,000 and $50,000 each, depending on multiple factors including oil prices and the cyclical nature of the industry. Haul trucks contain six tires per vehicle, and mines replace these tires around every 9-12 months.[2] Statistics regarding discarded OTR tires are not provided by the …

Numerical Simulation On The Combustion Characteristic Of Iron Ore Sintering With Flue Gas Recirculation, Gan Wang, Zhi Wen, Guofeng Lou, Ruifeng Dou, Xunliang Liu, Fuyong Su, Sizong Zhang

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

Molecular Dynamics Studies Of The Adsorption Behavior Of Methyl 3-((2-Mercaptophenyl)Imino)Butanoate As Corrosion Inhibitors On Copper Surface, Jianlin Sun, Sang Xiong, Xudong Yan, Yang Xu

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

Continuous Ligand-Assisted Elution Chromatography Applied To Separation Of Rare Earth Elements, Jeremy A. Weinstock, David M. Harvey, N.-H. Linda Wang

The Summer Undergraduate Research Fellowship (SURF) Symposium

Rare earth elements (REEs) are metals used to make many valuable products such as magnets and electronics. Following their extraction from larger materials, REEs are to be separated into their individual components as high purity is required for product manufacture. Purification is very difficult because most (15/17) of the REEs are lanthanides (Ln’s) and Ln ions have the same valence and similar atomic radii. The current industrial process for purifying REEs involves using toxic solvents to perform a series of liquid-liquid extractions. Ling and Wang (2015) proposed a ligand-assisted batch chromatography process to purify Ln’s. The latter approach is a …