Other Chemical Engineering Commons^™

Modeling Of Amine-Based Co2 Capture Process, Zafar Safarovich Turakulov

Chemical Technology, Control and Management

A significant factor influencing climate change is the release of carbon dioxide (CO₂) into the atmosphere as a consequence of human activities such as the combustion of fossil fuels. Climate change can be slowed down by taking action to mitigate industrial-scale CO₂ emissions. Currently, the most advanced technology for capturing CO₂ from industrial flue gases is the post-combustion CO₂ capture based on amine absorption. However, due to the high energy penalties of existing CO₂ capture technologies and insufficient carbon markets, it is necessary to develop methods that compete with these technologies or minimize their …

Gold Thin Film Electrodes For High Sensitivity & Selectivity Electrochemical Detection Of Arsenite In Water, Tybur Q. Casuse Driovínto

Civil Engineering ETDs

This is partial fulfillment of a dissertation defense on electrochemical detection of Arsenic (As) in water using gold (Au) nanofilms as sensing electrodes. The maximum contaminant level of Arsenic in drinking water is set at 10 g L^-1 by the WHO and USEPA. Electrochemical detection by linear stripping voltammetry has comparable detection limits to more expensive laboratory-based methods but with added benefits of being portable and manufacturable. The work has developed sputtered and crystallographically oriented nanofilms for detection of trace As (III). Ultraflat Au(111) oriented thin films, Au(UTF), were compared to single crystal model electrodes to identify the impacts …

Exploration Of The Sludge Biodiesel Pathway, Zachary Christman

Department of Agronomy and Horticulture: Dissertations, Theses, and Student Research

Wastewater sludge is an overlooked source of fat, oil, and grease (FOG) that could be converted into biodiesel. The United States produces about 8 million tons of sludge per year. The disposal cost for this amount of sludge is about 2 billion dollars. The widespread availability and low cost of sludge compared to other biodiesel raw materials make it an economical choice for a renewable fuel. Using sludge as a raw material can produce 25 to 30 mg per gram of fatty acid methyl ester (FAME); the main component of biodiesel. Sludge biodiesel has the potential of transforming a portion …

Household Income And Air Pollution At Public Schools In The United States, Katyland Facas, Kristina Wagstrom

Honors Scholar Theses

Poor air quality at schools may negatively impact students’ academic performance.1 2 3 In this study we look at the relationship between ambient, outdoor air quality and student socioeconomic status at United States public schools. We used free and reduced lunch eligibility, as part of the USDA’s National School Lunch Program, as an indicator of household income. We focus on nitrogen dioxide (NO2), ozone (O3), and particulate matter smaller than 2.5 microns (PM2.5). We used ambient pollutant concentration estimates at census block group resolution (Kim et al.) as the outdoor air pollution concentration at each school.4 We found a positive …

Production Of Engineered Carbons From Secondary Waste Streams For Environmental Applications, Ghazaleh Chegini

Electronic Thesis and Dissertation Repository

Pyrolysis and activation were used in this thesis to produce biochar and activated carbon from industrial digestate and hydrochar materials. In the first part of thesis, digestate derived biochars were obtained by varying the pyrolysis heating rate (10, 80, 100, 200, >1000 °C·min^-1) and temperature (300 to 600 °C) to modify their soil-related characteristics (i.e., nutrient leachability, carbon stability, and heavy metal adsorptive capacity). The biochar produced at a temperature of 500 °C and heating rate of 10 °C·min^-1 was also activated under using CO₂ at 800 °C with different holding times (0.5-2 h). Results indicated …

Optimization Of Nitrate Removal From Aqueous Solution By Acid-Activated Rice Straw Supported Nano Zero-Valent Iron Using Response Surface Methodology, Dalia A. Ali Eng, Nagwa Mahmoud Al-Mansi Prof, Mohamed Amin Sadek Prof., Ahmad Wafiq Abolnasr Dr.

Chemical Engineering

Rice straw is one of the most common agricultural wastes due to its large production amounts. Energy valorization of rice straw is a technology used for nitrate removal as the produced ashes used to generate the adsorbent by means of an alkali dissolution followed by acid precipitation. The novelty of the proposed process is that the production of the nano zero-valent iron supported acid-activated rice straw (AARS-nZVI) adsorbent is carried out without the energy valorization process but, through an acid activation for rice straw followed by precipitation of nZVI particles on its surface. The new adsorbent synthesis, characterization and application …

Pollution Prevention Via Recovery Of Cerium (Iv) Oxide In Optics Company, Eugene Park, William Gallagher, Sydor Optics, Flint Creek Resources

Articles

Pollution prevention methods were applied at an optics manufacturer in an effort to improve recovery of a valuable polishing component, cerium oxide (ceria), 77% of which was lost to dragout and sewer discharge. Centrifugation and microfiltratiion were evaluated to develop a process that would increase recovery of used ceria, which would then be sent back to the ceria supplier for reclamation and reuse. Full-scale implementation included a high-speed centrifuge that operates continuously with a microfiltration system through recirculation in a single process tank. Sydor Optics has improved ceria recovery from 23% to 48%, saving thousands of dollars annually.

Process Water Recycling, Adrian Barron, Josiah Snider, Kyle Serpe

Scholar Week 2016 - present

The Millipore Sigma-Kankakee Site uses high volumes of water for many operations. One operation utilizes approximately 3600 L of water per batch every couple days and more than 3.8MM liters of water per year. The water is utilized as a component of the buffer washes used in the extraction process for cholesterol that involves various other components such as silica and ions such as sodium, sulfur, and phosphate. The washes that go through the process involve these components and large amounts of water that are then drained out of the facility. This volume is roughly 7% of the site's total …

Effects Of Drinking Water Treatment Processes On Removal Of Algal Matter And Subsequent Water Quality, Ziming Zhao

Electronic Thesis and Dissertation Repository

Seasonal algal blooms in drinking water sources have increased significantly over the recent past as a result of increased temperature and nutrient loading in surface water due to agricultural and surface runoff. More than 95% of algal cells can be removed by coagulation and flocculation processes. However, algal organic matter (AOM) is not removed well during coagulation, thus causes several operational challenges in drinking water treatment. This research was conducted to investigate the effectiveness of coagulation, granular activated carbon adsorption, and filtration processes on AOM removal and to evaluate disinfection by-products formation potential with/without UV irradiation.

Initially, coagulation performance for …

Desarrollo De Un Esquema De Gestión Hídrica En El Sistema Acuífero Sap 3.1 Apoyado De La Tipificación De Suelos Y El Modelo Conceptual De Thöt, Maria Camila Soriano Espinosa, Camilo José Rodríguez Carvajal

Ingeniería Ambiental y Sanitaria

El presente proyecto tiene como objetivo principal desarrollar un esquema de gestión hídrica (EGH) en el sistema acuífero SAP 3.1, provincia llanos orientales, con base en la tipificación de suelos y el modelo conceptual de Tӧth, partiendo de que las aguas subterráneas se consideran una fuente alternativa de abastecimiento por su mejor calidad y el bajo costo de manejo en comparación al agua superficial, y teniendo en cuenta que el Departamento del Meta conoce la riqueza hídrica que está en su jurisdicción, no cuenta con una regulación adecuada en pro de una gestión hídrica a nivel subterráneo. La metodología empleada …

Wastewater Treatment Fatty Acids For Biodiesel Production, Zachary Christman

Department of Agronomy and Horticulture: Dissertations, Theses, and Student Research

Wastewater scum is the thick oily substance that floats on top of the primary and secondary tanks within a wastewater treatment plant. Scum has a 30% to 60% lipid content making it an excellent resource for the biodiesel industry. Also the use of scum would reduce the cost of current management practices such as landfill disposal or incineration. In this article there is an overview of lipid byproducts currently being produced at wastewater treatment plants today. This is followed by a presentation showing a full length process for turning wastewater scum into biodiesel raw material.

How Moisture Content Levels And Packing Density In Soil Affect Crude Oil Spreads, Shaylin N. Williams

Venture: The University of Mississippi Undergraduate Research Journal

Crude oil spills are one of the most destructive disasters that can occur, and they are extremely difficult to recover from. Many studies focus on what can be done to clean these crude oil spills, but more research should be focused on means of prevention. Currently, very little is known about how the moisture content levels and the packing efficiency of soil can affect an oil spill. These two factors alone can offer a variety of information to environmental agencies, manufacturers, and refineries. Through utilization of a chemical engineering lab, a recording mechanism, and ImagePro software, data was collected and …

Removal And Reuse Of Phosphorus As A Fertilizer From Cafo Runoff, Hannah Young

Chemical Engineering Undergraduate Honors Theses

Eutrophication is the process in which nutrient saturated waters promote algal blooms on the surface of the water. This limits the amount of dissolved oxygen content in the water, effectively limiting the range of species that can survive in a body of water. Concentrated animal feeding operations (CAFO) can contribute to this issue. The animals in a CAFO produce large amounts of nutrient-rich waste streams that can enter natural waterways if not properly managed and increase the problem of eutrophication. The ability to treat these waste streams and recover the excess nutrients would allow for not only the reduction of …

Removal And Reuse Of Phosphorus As A Fertilizer From Cafo Runoff, Kristin Moore

Chemical Engineering Undergraduate Honors Theses

Eutrophication is the process in which nutrient saturated waters promote algal blooms on the surface of the water. This limits the amount of dissolved oxygen content in the water, effectively limiting the range of species that can survive in a body of water. Concentrated animal feeding operations (CAFO) can contribute to this issue. The animals in a CAFO produce large amounts of nutrient-rich waste streams that can enter natural waterways if not properly managed and increase the problem of eutrophication. The ability to treat these waste streams and recover the excess nutrients would allow for not only the reduction of …

Effect Of Coagulant Recycling On Chemically Enhanced Primary Treatment Performance, Tulip Chakraborty

Electronic Thesis and Dissertation Repository

Chemically enhanced primary treatment (CEPT) process is a promising method for carbon redirection and improving the performance and efficiency of wastewater treatment processes. CEPT is employed to precipitate colloidal and suspended matter from wastewater; however, this requires a significant amount of coagulant and produces large volumes of sludge. Coagulant recovery (CR) from the precipitated sludge has the potential to reduce sludge quantities, associated costs for disposal of sludge, cost of dosing fresh coagulant by regenerating and purifying the coagulant before reuse. This research was conducted to understand the feasibility and implications of CR in municipal wastewater.

In order to evaluate …

Analysis And Control Of Aluminum Concentration In Groundwater: Mathematical Modelling And Laboratory Study, Daria Popugaeva

Electronic Thesis and Dissertation Repository

The remediation of metal-contaminated natural water bodies is prioritized due to metals toxicity, non-biodegradable properties, and accumulative behaviours leading to the increased incidence of adverse health effects. Current investigation is driven by the existing problem of elevated aluminum concentrations in the groundwater of Khibiny alkaline massif (Kola Peninsula). The prohibitive aluminum level exceeding the accepted standard of 0.20 mg L⁻¹ is described as a serious health concern when the groundwater used for the local water supply. The results of comprehensive field data analysis based on chemometric methods applied to the available monitoring data including 12 groundwater quality parameters are …

Prevention Of Harmful Algal Blooms By The Mitigation Of Phosphorus Nutrient Loading Via Filtration By Steel Wool And Activated Carbon, Ronald Simpson, Sara Kidd, Samantha Zidd

Williams Honors College, Honors Research Projects

Harmful Algal Blooms (HABs) are a devastating ecological and economic consequence of the abundance of nutrient-rich agricultural runoff entering aquatic ecosystems (Baker et al. 2014). Bio-available phosphorus from synthetic fertilizers is one of the major nutrients contributing to this global issue. Previous studies indicated that dissolved phosphorus can be removed from an aqueous environment when passed through a composite mixture of granular steel wool particles and activated carbon (Erickson, Gulliver, and Weiss, 2007). In this project, we conducted experiments using higher quality concentration measurements to determine what grades of steel wool (SW-0000, SW-000, SW-00) and types of activated carbon (granulated …

Call For Abstracts - Resrb 2019, July 8-9, Wrocław, Poland, Wojciech M. Budzianowski

Wojciech Budzianowski

No abstract provided.

Impact Of Trace Element Ions And Fe2+ On Anaerobic Food Waste Digestion, Andisheh Yazdanpanah

Electronic Thesis and Dissertation Repository

In Canada, about $31 billion worth of food is wasted annually. This amount of food waste (FW) ends up in landfills where it is naturally broken down by bacteria and releases methane to the atmosphere, a powerful greenhouse gas (GHG) which is 21 times more harmful to the environment than carbon dioxide (CO₂). This process can also be done in a controlled environment at wastewater treatment plants, in a process known as anaerobic digestion (AD). Diverting food waste from landfills to wastewater treatment facilities allows for the capture of the methane, which can be used as an energy …

Corrosion Scale Characteristics And Lead Oxide Dissolution In Chloraminated Water, Daoping Guo

Electronic Thesis and Dissertation Repository

The presence of lead in drinking water is a common issue for utilities where lead pipes are used as service lines in drinking water distribution systems. Dissolved lead concentrations have been linked to the destabilization of stratified lead corrosion scales formed at the inner walls of lead pipe used as drinking water service lines. To develop a framework for lead dissolution control, it is necessary to fully describe the characteristics of the surface layer of the lead corrosion scale in direct contact with drinking water. In the first part of this thesis, a thorough lead corrosion scale characterization is carried …

Desalination Concentrate Disposal: Ecological Effects And Sustainable Solutions, Ryan Hanley

Global Honors Theses

Freshwater availability is a growing global concern, and desalination is often presented as the solution, but from this important technology comes issues of toxic waste. Ecosystems are delicate areas that contain species adapted to that specific location, and any chemical or physical changes can disrupt the fitness of species. The concentrate byproduct waste from desalination plants is toxic to species if the concentrate is not compatible with the receiving water body. A critical review of scientific articles, industry-leading books, conversations with industry experts, and information from the American Membrane Technology Association conference was used to analyze the current knowledge. Species …

Removal Of Carbamazepine From Drinking Water, Jordan Alex Gadberry, Adam Johnson, Juan Rodriguez, Paola Marrero-Rivera, Tom Krumpolc, Zach Wiese

Chemical Engineering Undergraduate Honors Theses

Due to the increasing prevalence of prescription medication over the past few decades, pharmaceuticals have accumulated in various water sources. This has become a public health concern because many pharmaceuticals have limited research on the effects of chronic low-level exposure. According to the World’s Health Organization (WHO), traces of pharmaceuticals products have been reported in different water sources such as surface waters, wastewater, groundwater, and drinking water.^[1] One pharmaceutical of interest that has been detected in water sources is carbamazepine. Carbamazepine (CBZ) is a common pharmaceutical prescribed for the treatment of seizure disorders, neuropathic pain, and various psychological disorders. …

Direct Potable Reuse Of Wastewater, Dakota Rusk, Molly Churchwell, Lauren Clark, Sabrina Castle, Boyce Bethel, Aaron Henry

Chemical Engineering Undergraduate Honors Theses

Water is essential to our societies and mankind. Currently, 844 million people across the globe lack access to potable water. By 2025, it is projected that half of the world population will be in a region of water stress. The water crisis is often thought of as a problem limited to places that have always struggled to have clean water, but it is now affecting new areas such as the southwest United States. With increasing population demands and drought, the feasibility of direct potable reuse (DPR) of wastewater is being considered. According to an EPA report in 2017, there are …

Direct Potable Reuse Of Wastewater, Aaron Henry, Molly Churchwell, Lauren Clark, Boyce Bethel, Dakota Rusk, Sabrina Castle

Chemical Engineering Undergraduate Honors Theses

Water is essential to our societies and mankind. Currently, 844 million people across the globe lack access to potable water. By 2025, it is projected that half of the world population will be in a region of water stress.5 The water crisis is often thought of as a problem limited to places that have always struggled to have clean water, but it is now affecting new areas such as the southwest United States. With increasing population demands and drought, the feasibility of direct potable reuse (DPR) of wastewater is being considered. According to an EPA report in 2017, there are …

Direct Potable Reuse Of Wastewater, Lauren Clark

Chemical Engineering Undergraduate Honors Theses

Water is essential to our societies and mankind. Currently, 844 million people across the globe lack access to potable water. By 2025, it is projected that half of the world population will be in a region of water stress.⁵ The water crisis is often thought of as a problem limited to places that have always struggled to have clean water, but it is now affecting new areas such as the southwest United States. With increasing population demands and drought, the feasibility of direct potable reuse (DPR) of wastewater is being considered. According to an EPA report in 2017, there …

Direct Potable Reuse Of Wastewater, Boyce Bethel

Chemical Engineering Undergraduate Honors Theses

Water is essential to our societies and mankind. Currently, 844 million people across the globe lack access to potable water. By 2025, it is projected that half of the world population will be in a region of water stress.⁵ The water crisis is often thought of as a problem limited to places that have always struggled to have clean water, but it is now affecting new areas such as the southwest United States. With increasing population demands and drought, the feasibility of direct potable reuse (DPR) of wastewater is being considered. According to an EPA report in 2017, there …

Direct Potable Reuse Of Wastewater, Molly Churchwell

Chemical Engineering Undergraduate Honors Theses

Water is essential to our societies and mankind. Currently, 844 million people across the globe lack access to potable water. By 2025, it is projected that half of the world population will be in a region of water stress.5 The water crisis is often thought of as a problem limited to places that have always struggled to have clean water, but it is now affecting new areas such as the southwest United States. With increasing population demands and drought, the feasibility of direct potable reuse (DPR) of wastewater is being considered. According to an EPA report in 2017, there are …

Direct Potable Reuse Of Wastewater, Sabrina Castle

Chemical Engineering Undergraduate Honors Theses

Water is essential to our societies and mankind. Currently, 844 million people across the globe lack access to potable water. By 2025, it is projected that half of the world population will be in a region of water stress.5 The water crisis is often thought of as a problem limited to places that have always struggled to have clean water, but it is now affecting new areas such as the southwest United States. With increasing population demands and drought, the feasibility of direct potable reuse (DPR) of wastewater is being considered. According to an EPA report in 2017, there are …

Adaption Of Catechol And Reversible Addition-Fragmentation Chain-Transfer (Raft) Chemistries For Water-Based Applications, Olabode Oyeneye

Electronic Thesis and Dissertation Repository

Incorporating the binding chemistry of catechol functionality with RAFT chemistry offers a facile and simplified approach for developing a suite of new 2D and 3D hybrid materials with tailored morphologies. Leveraging both chemistries by synthesizing catechol-end functionalized RAFT agents and catechol-containing monomeric species for RAFT (co)polymerization, this dissertation examined a new series of advanced materials that were designed for water-based applications including model flocculants, thermoresponsive hydrogels, adsorbents and underwater adhesives.

To prepare the RAFT agents, novel trithiocarbonates with several catechol end R groups (as postpolymerization anchors) were synthesized that differ in their carbonyl α-substituents (Dopa-CTAs). These materials were evaluated for …

Fabrication And Modification Of Titania Nanotube Arrays For Harvesting Solar Energy And Drug Delivery Applications, Ahmed El Ruby Abdel Rahman Mohamed

Electronic Thesis and Dissertation Repository

The fast diminishing of fossil fuels in the near future, as well as the global warming caused by increasing greenhouse gases have motivated the urgent quest to develop advanced materials as cost-effective photoanodes for solar light harvesting and many other photocatalytic applications. Recently, titania nanotube arrays (TNTAs) fabricated by anodization process has attracted great interest due to their excellent properties such as: high surface area, vertically oriented, highly organized, one-dimensional, nanotubular structure, photoactivity, chemical stability and biocompatibility. This unique combination of excellent properties makes TNTAs an excellent photoanode for solar light harvesting. However, the relatively wide band gap energy of …