Other Chemical Engineering Commons^™

Modified Anodic Stripping Voltammetry For In Situ Analysis Of Liquid Metal Composition In Molten Salt Electrorefining Systems, James H. Manner

Reviews, Analyses, and Instructional Studies in Electrochemistry (RAISE)

The development of in-situ analytical techniques for high-temperature molten salt systems is critical for advancing electrorefining in nuclear fuel recycling and metallurgical purification. This study proposes Modified Anodic Stripping Voltammetry (MASV), using a “dip-and-strip” approach where a tungsten electrode captures molten Sn–Ni alloy before stripping in LiCl–KCl–CaCl₂ at 415 °C. OCP results showed rapid loss of the metal layer due to poor wetting, and stripping peaks gave compositions inconsistent with the alloy, likely reflecting Sn/Sn²⁺ and Sn²⁺/Sn⁴⁺ redox processes. These results highlight interfacial limitations and the need for improved electrode materials and surface modification.

Comsol Simulation Of Pipeline Corrosion With Cathodic Protection, Ethan Scalzo

Williams Honors College, Honors Research Projects

Cathodic protection (CP) is a widely used technique to mitigate corrosion in buried steel pipelines. This study uses COMSOL Multiphysics to model and analyze the performance of both sacrificial anode and impressed current systems in a simulated 3D environment. The model solves for pipeline potential, current density, and corrosion rate within a surrounding soil domain to assess protection coverage across the pipeline. Simulations were conducted to evaluate the influence of electrode and electrolyte properties on CP effectiveness. The study demonstrates that COMSOL Multiphysics is an effective tool for modeling CP systems, offering insights that align with established industry practices. While …

Materials And Interfaces For Electrocatalytic Hydrogen Production And Utilization., Alexander Jiya Gupta

Electronic Theses and Dissertations

Mass industrialization over the last few centuries has created a global economy which is dependent upon fossil fuels to satisfy an exponentially increasing demand for energy. Aside from the possible depletion of this finite resource, the combustion of fossil fuels releases greenhouse gases into the atmosphere which cause the global temperature to rise – a phenomenon which has already begun to create geologic and geopolitical instability and shows no signs of abatement. One proposed method to rid humanity of its dependence on fossil fuels is to use green hydrogen as an energy carrier. In this scheme, excess electricity from a …

The Study Of Copper Corrosion Mechanisms Using Electrochemical Experimental Techniques., Evan Grimm

Electronic Theses and Dissertations

The purpose of this study was to discover and thoroughly explain the corrosion mechanisms of copper in saltwater, tap water and deionized water, and to apply these methods and findings when testing the corrosion mechanisms of other materials. The experimental procedure consisted of measuring the open circuit potential, electrochemical impedance spectroscopy, linear sweep voltammetry, and Tafel analysis.

The copper was found to corrode at a greater rate in saltwater, followed by tap water then deionized water, with a larger difference between saltwater and tap water than between tap water and deionized water. Each reaction was found to be both kinetically …

Biomass-Derived Electrode Materials And Sustainable Processes For Supercapacitors, Katelyn M. Shell

Theses and Dissertations

Biomass is one of the most abundant natural resources and has been used as a source of energy for thousands of years. Biomass as a precursor for energy storage materials is still relatively novel and faces several obstacles before becoming commonly used in today’s electrical devices. Currently, energy storage devices, such as batteries, capacitors, and supercapacitors, utilize petroleum-derived graphitic carbons for anodes, generating a need for more sustainable materials. Biomass, as a carbon-rich source for electrode materials, presents a viable and economically feasible alternative due to the prevalent lignocellulosic compounds: lignin, cellulose, and hemicellulose. Preliminary studies on the solid residues …

Vanadium Redox Flow Batteries: Design And Experimentation, Matthew George

Williams Honors College, Honors Research Projects

Vanadium flow batteries (VFB) are a type of battery that has potential as a grid-scale energy storage solution. An original design for a lab-scale VFB is presented herein, along with a procedure for electrolyte preparation from V₂O₅ using oxalic acid. The flow cell is constructed from Delrin, Teflon, Kynar, Santoprene, Nafion, graphite plate, and porous carbon. Two diaphragm pumps along with polyethylene, PVC, and Santoprene tubing are used. The active area is 58 cm². The battery was charged using a DC power supply at a constant current of 4 A with corresponding initial voltage of …

High Temperature Electrochemical Engineering And Clean Energy Systems, Brenda L. Garcia-Diaz, Luke Olson, Michael Martinez-Rodriguez, Roderick Fuentes, Hector Colon-Mercado, Josh Gray

Journal of the South Carolina Academy of Science

Global power demand is projected to more than double by 2050 and meeting this increased power demand will require maintaining or increasing power output from all existing energy sources while adding a large amount of new capacity. The power sources that have the greatest opportunity to fulfill this demand gap over this time period are clean energy sources including solar and nuclear power. One of the areas of expertise that SRNL has been applying to help with a variety of clean energy technologies is in high temperature electrochemistry. Savannah River National Laboratory (SRNL) in collaboration with industrial and university partners …

Electrochemical Detection Of Antioxidants, Garrett Thompson

Honors Theses and Capstones

No abstract provided.

Simulation Of Polarization Curves For Oxygen Reduction Reaction In 0.5 M H2So4 At A Rotating Ring Disk Electrode, Qingbo Dong, Shriram Santhanagopalan, Ralph E. White

Faculty Publications

A cylindrical two-dimensional model based on the Nernst–Planck equations, the Navier–Stokes equation, and the continuity equation is used to simulate the oxygen reduction reaction in 0.5MH₂SO₄ at a rotating ring disk electrode. Concentration distributions and a potential profile are obtained as a function of the axial and radial distances from the center of the electrode surface. Polarization curves are simulated to interpret experimental results by studying various reaction mechanisms, i.e., the four-electron-transfer reduction of oxygen, the two-electron-transfer reduction of oxygen, a combination of the above two reactions, mechanisms with reduction of peroxide to water, and/or the heterogeneous …

Fuel Cells, Frederick J. Munster Jr.

Maine Collection

Fuel Cells

by Frederick J. Munster Jr.

Edited by: Mr. Christopher Carroll

Maine Department of Economic Development, Augusta, Maine, 1998.

Contents: Hydrogen / Hydrogen Safety / Electrolysis / Electrolyzers / History of Fuel Cells / How Fuel Cells Operate / Fuel Cell Types / Fuel Cell Electrochemistry / Power Systems / Fuel Cells in Transportation / Hydrogen Powered Internal Combustion Engines / Home, Garden, Education and Industry / For More Information / Glossary / References