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Articles 601 - 630 of 14236

Full-Text Articles in Chemical Engineering

Foundations Of Artificial Intelligence In Healthcare Diagnostics: A Systematic Survey, Raghad Tariq Al-Hassani Oct 2025

Foundations Of Artificial Intelligence In Healthcare Diagnostics: A Systematic Survey, Raghad Tariq Al-Hassani

Al-Esraa University College Journal for Engineering Sciences

Artificial Intelligence (AI) is becoming the cornerstone of the future of healthcare diagnostics, that has to ability to change the healthcare diagnostic landscape in terms of diagnostic accuracy, speed, and availability. This systematic review investigates the basic methods, tools, applications, and challenges involved in the integration of AI in diagnostic medicine. It emphasizes the using of machine learning models, deep learning networks (e.g., CNNs), NLP for clinical documentation, and smart computing infrastructures, such as edge device and IoMT. They are making possible real-time, data-driven decision making that is already at human-expert-level performance or, in some cases, even better (in the …

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Secure Gif Files Based On Zuc Stream Cipher And Present Algorithm, Suhad Fakhri Hussein Oct 2025

Secure Gif Files Based On Zuc Stream Cipher And Present Algorithm, Suhad Fakhri Hussein

Al-Esraa University College Journal for Engineering Sciences

Some important security needs include authentication, confidentiality, integrity, non-repudiation, and user privacy. Many security systems include these required protections for information transmission. The encryption process is one of the most important security measures. Many secure encryption algorithms are based on different keys and key lengths to ensure a high degree of security. GIF file format is common file format that is used in several application, securing these files through transmission is imperative. In this paper, an efficient method for encryption GIF file is proposed based on using modified present algorithm, modified ZUC stream cipher, and an efficient method for key …

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Advanced Strategies And Solutions Towards More Secure And Effective Two-Factor Authentication In Networking, Zahraa Sameer Jawad Oct 2025

Advanced Strategies And Solutions Towards More Secure And Effective Two-Factor Authentication In Networking, Zahraa Sameer Jawad

Al-Esraa University College Journal for Engineering Sciences

With the rapid increase in cybersecurity threats targeting network systems, traditional two-factor authentication (2FA) methods are insufficient to address advanced attacks. Vulnerabilities such as phishing, SIM-swapping, and social engineering exploit the limitations of SMS-based and email-based 2FA. This paper examines advanced strategies and solutions for securing networked environments through robust 2FA mechanisms, focusing on approaches like elliptic curve cryptography (ECC), digital certificates, and biometric verification. This article offers a comparative review of various strategies about their effectiveness in enhancing security, while also highlighting their capacity to optimize user-friendliness and adaptability to emerging threats. Research findings promote an effective countermeasure strategy …

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Advancements In Ultrasound Technology And Iot Security: A Physics-Based Approach To Enhanced Imaging With Lightweight Encryption Algorithms, Noor Fawzi Shafiq Oct 2025

Advancements In Ultrasound Technology And Iot Security: A Physics-Based Approach To Enhanced Imaging With Lightweight Encryption Algorithms, Noor Fawzi Shafiq

Al-Esraa University College Journal for Engineering Sciences

The rapid advancements in ultrasound technology, coupled with the growing significance of IoT security, present a unique opportunity to enhance imaging systems while ensuring data integrity. This study explores the integration of physics-based principles in ultrasound imaging, focusing on how lightweight encryption algorithms can secure data transmitted from IoT devices.Ultrasound technology has evolved significantly, benefiting from improved imaging techniques and the incorporation of IoT devices. As these devices proliferate across various applications, including healthcare and industrial monitoring, the need for secure data transmission becomes paramount. This paper proposes a framework that combines advanced ultrasound imaging with robust lightweight encryption methods …

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Artificial Intelligence Approaches To Mitigating Network Congestion In Iot Systems, Aysar Hadi Oleiwi Oct 2025

Artificial Intelligence Approaches To Mitigating Network Congestion In Iot Systems, Aysar Hadi Oleiwi

Al-Esraa University College Journal for Engineering Sciences

The unprecedented explosion of Internet of Things (IOT) devices has elevated the requirements of the network infrastructures to unprecedented levels, causing severe congestion problems, especially in applications which demand low latency, high throughput, and real-time feedback. Static routing protocols, AQM, and TCP variants are some of the traditional mechanisms for congestion control that are unable to perform efficiently in dynamic and diverse IoT environments as they are reactive-based and inflexible. To this end, in this paper, we explore the promising ability of Artificial Intelligence (AI) methods such as Machine Learning (ML), Deep Learning (DL), Reinforcement Learning (RL), and their combination …

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Groundwater Quality Analyses For Irrigation Purposes In Salah Al-Din, Iraq: A Review, Noor A. Radhi, Dawood E. Sachit, Abdul-Sahib T. Al-Madhhachi Oct 2025

Groundwater Quality Analyses For Irrigation Purposes In Salah Al-Din, Iraq: A Review, Noor A. Radhi, Dawood E. Sachit, Abdul-Sahib T. Al-Madhhachi

Al-Esraa University College Journal for Engineering Sciences

The focus of this study is the effect of the physical and chemical characteristics of groundwaters on plants and agricultural crops, following the last studies on this matter. The results underscore the necessity for groundwater treatment before its utilization in irrigation for sustainable agricultural farming. It is also possible to identify which crop type can be grown in well-watered land, according to the characteristics of irrigation water and the yield of each crop. The study also introduces some ideas about irrigation water quality parameters such as Electrical conductivity (EC), Total Dissolved Solids (TDS), pH, Chloride (Cl–), Sodium (Na …

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Examining Iot-Enhanced For Current Developments In Face Image Authentication (Fia) Methods And Their Drawbacks, Marwa Jamal Hadi, Emaan Ouudha Oraby Oct 2025

Examining Iot-Enhanced For Current Developments In Face Image Authentication (Fia) Methods And Their Drawbacks, Marwa Jamal Hadi, Emaan Ouudha Oraby

Al-Esraa University College Journal for Engineering Sciences

The quick development of IoT and facial image manipulation (FIM) algorithms, as well as the growth of their user-friendly applications, highlight the pressing need for manipulation detection methods. These techniques need to demonstrate how face photos have been altered and validate their legitimacy. The scientific community has recently taken notice of the phrase “DeepFakes” and methods for detecting them. Take note of the latest methods for identifying watermark-based face image modification as well. The important thing to remember is that every one of these methods has its own set of drawbacks. This study provides a brief introduction to face image …

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Meshless Discrete Velocity Boltzmann Model For Porous Media Flow, Amandine Maidenberg Oct 2025

Meshless Discrete Velocity Boltzmann Model For Porous Media Flow, Amandine Maidenberg

Doctoral Dissertations and Master's Theses

This dissertation explores the combination of two sophisticated techniques for addressing computational fluid dynamics: the discrete velocity Boltzmann equation (DVBE) and the localized collocation meshless model with upwinding (U-LCMM). The DVBE is a high-level model that describes the foundations of transport phenomena by addressing the microscale motions of particles themselves and the effect of their aggregate behaviors on continuum principles. This equation integrates multiple scales of phenomena; while it can be used for fluid flow at Navier-Stokes scales, it can also resolve fine features that can only be described at the molecular level. This type of model is necessary for …

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Laboratory Investigation Of High-Temperature Preformed Particle Gels For Fluid Control In Granite Cores For Geothermal Applications, K. Caleb Darko, Yanbo Liu, Thomas P. Schuman, Mingzhen Wei, Baojun Bai Oct 2025

Laboratory Investigation Of High-Temperature Preformed Particle Gels For Fluid Control In Granite Cores For Geothermal Applications, K. Caleb Darko, Yanbo Liu, Thomas P. Schuman, Mingzhen Wei, Baojun Bai

Chemistry Faculty Research & Creative Works

To understand the applicability of high-temperature preformed particle gel (HT-PPG) for control of short-circuiting in enhanced geothermal systems (EGSs), core flooding experiments were conducted on fractured granite cores under varying fracture widths, gel particle sizes and swelling ratios. Key parameters such as injection pressure, water breakthrough pressure, and residual resistance factor were measured to evaluate HT-PPG performance. The gel exhibited strong injectability, entering granite fractures at pressure gradients as low as 0.656 MPa/m; HT-PPG yields a superior sealing performance by significantly reducing the permeability; and dehydration occurs during HT-PPG propagation, with a dehydration ratio ranging from 4.71% to 11.36%. This …

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Exploring The Effects Of Excipients On Complex Coacervation, Xianci Zeng, Pratik U. Joshi, Alexander Lawton, Lynn M. Manchester, Caryn Heldt, Sarah L. Perry Oct 2025

Exploring The Effects Of Excipients On Complex Coacervation, Xianci Zeng, Pratik U. Joshi, Alexander Lawton, Lynn M. Manchester, Caryn Heldt, Sarah L. Perry

Michigan Tech Publications

Complex coacervation is an associative liquid–liquid phase separation phenomenon that takes place due to the electrostatic complexation of oppositely-charged polyelectrolytes and the entropic gains associated with the release of bound counterions and rearrangement of solvent. The aqueous nature of coacervation has resulted in its broad use in systems requiring high biocompatibility. The significance of electrostatic interactions in coacervates has meant that studies investigating the phase behaviors of these systems have tended to focus on parameters such as the charge stoichiometry of the polyions, the solution pH, and the ionic strength. However, the equilibrium that exists between the polymer-rich coacervate phase …

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Electrode Engineering To Minimize Degradation In Lithium-Sulfur Batteries, Saheed Adewale Lateef Oct 2025

Electrode Engineering To Minimize Degradation In Lithium-Sulfur Batteries, Saheed Adewale Lateef

Theses and Dissertations

Lithium-Sulfur (Li-S) batteries have recently received significant attention as a potential candidate for next-generation energy storage technology. This is due to its high theoretical capacity (1675 mAh/g) which can provide theoretical energy density of 2500 Wh/kg as compared to 400 Wh/kg of the current Lithium-ion batteries. Moreover, the earth-abundant sulfur element as well as its environmental friendliness endows unique advantages on the cost and environmental impact. However, there are several roadblocks that need to be addressed for commercial adoption of Li-S batteries, such as: (i) poor conductivity of sulfur and its discharged product; (ii) solubility of lithium polysulfides and their …

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Towards Accurate First-Principles Modeling In Heterogenous Catalysis: Ethane Dehydrogenation And Hydrogenolysis Over Pt Catalysts, Mubarak Ayo Bello Oct 2025

Towards Accurate First-Principles Modeling In Heterogenous Catalysis: Ethane Dehydrogenation And Hydrogenolysis Over Pt Catalysts, Mubarak Ayo Bello

Theses and Dissertations

First-principles modeling has become central to heterogeneous catalysis research, offering mechanistic insight and guiding catalyst design, yet conventional approaches often struggle to accurately describe complex catalytic systems due to methodological uncertainties, simplified assumptions, and the structural diversity of nanoparticle catalysts. This dissertation addresses these challenges using ethane dehydrogenation (EDH) and hydrogenolysis (EH) over platinum catalysts as model systems. The first study benchmarks density functional theory (DFT) functionals against the random phase approximation (RPA) for the EDH network on Pt(111), identifying cost-effective functionals and demonstrating the efficiency of BEEF-vdW ensembles for capturing functional uncertainty. The second study (addressed in prior work) …

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Towards Accurate First-Principles Modeling In Heterogenous Catalysis: Ethane Dehydrogenation And Hydrogenolysis Over Pt Catalysts, Mubarak Ayo Bello Oct 2025

Towards Accurate First-Principles Modeling In Heterogenous Catalysis: Ethane Dehydrogenation And Hydrogenolysis Over Pt Catalysts, Mubarak Ayo Bello

Theses and Dissertations

First-principles modeling has become central to heterogeneous catalysis research, offering mechanistic insight and guiding catalyst design, yet conventional approaches often struggle to accurately describe complex catalytic systems due to methodological uncertainties, simplified assumptions, and the structural diversity of nanoparticle catalysts. This dissertation addresses these challenges using ethane dehydrogenation (EDH) and hydrogenolysis (EH) over platinum catalysts as model systems. The first study benchmarks density functional theory (DFT) functionals against the random phase approximation (RPA) for the EDH network on Pt(111), identifying cost-effective functionals and demonstrating the efficiency of BEEF-vdW ensembles for capturing functional uncertainty. The second study (addressed in prior work) …

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Soft Sensing Of Biological Oxygen Demand In Industrial Wastewater Using Machine Learning Models, Muhammad Hassnain, Sarada M.W. Lee, Muhammad Rizwan Azhar Oct 2025

Soft Sensing Of Biological Oxygen Demand In Industrial Wastewater Using Machine Learning Models, Muhammad Hassnain, Sarada M.W. Lee, Muhammad Rizwan Azhar

Research outputs 2022 to 2026

Traditional methods for determining biological oxygen demand (BOD) from industrial water resource recovery facilities (WRRFs) are time-consuming and often impractical for real-time process control. This study explores the application of machine learning (ML) and artificial intelligence (AI) models for the prediction of final effluent BOD (F-BOD) based on physicochemical and operational parameters by leveraging nineteen years of historical laboratory and instrumentation data from the WRRF of an essential oil manufacturing plant. The predictions from these models are then used to simulate the process dynamics, assessing the optimal operational boundary conditions for all input parameters at which the target (F-BOD) falls …

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Biomass Materials And Their Application In 4d Printing, Zhongda Yang, Jian Li, Yanling Guo, Yangwei Wang, Wen Zhao, Wei Zhao, Yanju Liu, Laichang Zhang Oct 2025

Biomass Materials And Their Application In 4d Printing, Zhongda Yang, Jian Li, Yanling Guo, Yangwei Wang, Wen Zhao, Wei Zhao, Yanju Liu, Laichang Zhang

Research outputs 2022 to 2026

Four-dimensional (4D) printing technology is a revolutionary development that produces structures that can adapt in response to external stimuli. However, the responsiveness and printability of smart materials with shape memory properties, which are necessary for 4D printing, remain limited. Biomass materials derived from nature have offered an effective solution due to their various excellent and unique properties. Biomass materials have been abundant in resources and low in carbon content, contributing to the then-current global green energy-saving goals, including carbon peaking and carbon neutrality. This review focused on different sources of biomass materials used in 4D printing, including plant-based, animal-based, and …

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Defective Mil-88b(Fe) Metal-Organic Frameworks: Peculiar Photocatalysts For Enhanced Degradation Of Organic Pollutants, Samira Sadeghi, Ahmad Najafidoust, Seyedeh Zahra Haeri, Masoumeh Zargar Oct 2025

Defective Mil-88b(Fe) Metal-Organic Frameworks: Peculiar Photocatalysts For Enhanced Degradation Of Organic Pollutants, Samira Sadeghi, Ahmad Najafidoust, Seyedeh Zahra Haeri, Masoumeh Zargar

Research outputs 2022 to 2026

Environmental pollution, particularly water contamination from organic compounds like synthetic dyes, poses a major global challenge. In this study, defective MIL-88B(Fe) MOFs under varying solvothermal conditions (70–150 °C) for 12 and 24 h were synthesized to enhance methylene blue (MB) and methyl orange (MO) dye degradation. The MOF synthesized at 100 °C for 24 h showed the highest efficiency, achieving 97 % and 40 % degradation of MB and MO, respectively, in 60 min due to increased porosity, surface area, and optimized crystal growth along the [100] direction. A 24-h synthesis produced well-formed particles with the highest surface area and …

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Performance Limiting Factors For Silicon Anodes In Lithium-Ion Batteries, Najmaddin Bashirzada Oct 2025

Performance Limiting Factors For Silicon Anodes In Lithium-Ion Batteries, Najmaddin Bashirzada

Theses and Dissertations

The rising global demand for high-performance and sustainable energy storage solutions has placed lithium-ion batteries (LIBs) at the forefront of technological progress. However, the energy density limits of traditional graphite anodes require the investigation of alternative materials. Silicon (Si), with its high theoretical capacity, is a promising anode material. Still, its practical use faces major challenges such as volumetric expansion, unstable solid electrolyte interphase (SEI) formation, and low conductivity. This thesis examines the electrochemical behavior and limitations of Si-based electrodes using coin cells and ex-situ three-electrode cells. A comparison of electrochemical testing methods – i.e., Galvanostatic Intermittent Titration Technique (GITT) …

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Extraction Of Aluminum From Lunar Regolith Through Molten Salt Electrolysis, Jacob N. Ortega, Todd P. Sander, Jeffrey D. Smith, Fateme Rezaei, David J. Bayless, William Schonberg, Daniel S. Stutts, Frank D. Han Oct 2025

Extraction Of Aluminum From Lunar Regolith Through Molten Salt Electrolysis, Jacob N. Ortega, Todd P. Sander, Jeffrey D. Smith, Fateme Rezaei, David J. Bayless, William Schonberg, Daniel S. Stutts, Frank D. Han

Materials Science and Engineering Faculty Research & Creative Works

This paper presents the methodology, development, and results of an end-to-end regolith-to-metal concept for producing aluminum in-situ on the lunar surface, namely, the Lunar In-Situ Aluminum Production through Molten Salt Electrolysis (LISAP-MSE) method. Using electrolytic reduction, aluminum oxide (i.e., alumina) can be reduced into aluminum and oxygen via electrolysis in a molten salt bath. A steady supply of hydrogen chloride could allow this in-situ resource utilization (ISRU) method to supply several necessary materials consumed in the electrolytic reduction step of the process to produce bulk aluminum metal, oxygen, water, and silica from anorthite abundant in lunar highland regions. In this …

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Aminated Phenolated Lignin For Effective Anionic Dye Removal For Water Remediation, David Chem, Samantha Glidewell, Fatema Tarannum, Keisha B. Walters Oct 2025

Aminated Phenolated Lignin For Effective Anionic Dye Removal For Water Remediation, David Chem, Samantha Glidewell, Fatema Tarannum, Keisha B. Walters

Chemical Engineering Faculty Publications and Presentations

Lignin, a renewable biopolymer sourced from plant cell walls, is gaining attention due to its extensive availability from natural resources, native functional groups, low cost, and biodegradability in various applications. In recent years, lignin and its derivatives have been utilized as adsorbents, flocculants, and sterilants in a broad range of applications, including wastewater treatment and sustainable packaging. The growing global demand for clean water-driven by rapid industrialization, urban expansion, and agricultural intensification-has made effective wastewater treatment a pressing environmental priority. In this effort, a dual-functionalization strategy to transform raw lignin into a high-performance adsorbent for the removal of hazardous anionic …

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Factors Influencing The Effectiveness Of Machine Learning Algorithms In Predicting Raw Wastewater Characteristics: An Analysis Based On Weekly Field Data, Hoda Khoshvaght, Ratish Ramyad Permala, Amir Razmjou, Mehdi Khiadani Oct 2025

Factors Influencing The Effectiveness Of Machine Learning Algorithms In Predicting Raw Wastewater Characteristics: An Analysis Based On Weekly Field Data, Hoda Khoshvaght, Ratish Ramyad Permala, Amir Razmjou, Mehdi Khiadani

Research outputs 2022 to 2026

Accurate prediction of raw wastewater characteristics can reduce laboratory costs, enable optimized chemical dosing, and improve the overall efficiency of wastewater treatment plant (WWTP) operations. This study evaluates machine learning (ML) models as a fast, sustainable, and cost-effective alternative for predicting Biochemical Oxygen Demand (BOD) and Ammonia Nitrogen (NH4+-N) in raw wastewater. Seven ML algorithms, including tree-based, neural, and regression approaches, were trained using standard wastewater indicators, including organic load, nutrient levels, and pH, with hyperparameters tuned via grid search cross-validation. Model performance was evaluated using correlation-based (R2) and error-based metrics (RMSE, MAE, MAPE) to ensure …

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Membrane Fouling Dynamics And Flux Optimization In The Ultrafiltration Of Chlorella Sp. Mur 269 And Dunaliella Salina Cs 744/01, Victor Okorie Mkpuma, Mohadeseh Najafi, Javad Farahbakhsh, Masoumeh Zargar, Navid Reza Moheimani, Houda Ennaceri Oct 2025

Membrane Fouling Dynamics And Flux Optimization In The Ultrafiltration Of Chlorella Sp. Mur 269 And Dunaliella Salina Cs 744/01, Victor Okorie Mkpuma, Mohadeseh Najafi, Javad Farahbakhsh, Masoumeh Zargar, Navid Reza Moheimani, Houda Ennaceri

Research outputs 2022 to 2026

Membrane filtration has emerged as a viable technique for microalgal dewatering. However, fouling constraints limit their large-scale implementation. In this research, the fouling patterns during ultrafiltration of Chlorella sp. and Dunaliella salina were investigated using both dead-end and crossflow filtration modules. Chlorella sp. filtration in the dead-end module revealed an initial flux of 72.02 L.m−2.h−1 in the first cycle, which rapidly decreased to 19.18 L.m−2.h−1 within 30 min. In the second and third cycles, the initial flux exhibited decreases of 23 % and 50 %, respectively. Chlorella sp. demonstrated lower fouling than D. salina …

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Bridging Materials And Energy Storage Mechanisms In Zn-I2 Batteries, Rong-Qi Liu, Wen-Shuo Shang, Jin-Tao Zhang Sep 2025

Bridging Materials And Energy Storage Mechanisms In Zn-I2 Batteries, Rong-Qi Liu, Wen-Shuo Shang, Jin-Tao Zhang

Journal of Electrochemistry

Zinc-iodine (Zn-I2) batteries have emerged as a compelling candidate for large-scale energy storage, driven by the growing demand for safe, cost-effective, and sustainable alternatives to conventional systems. Benefiting from the inherent advantages of aqueous electrolytes and zinc metal anodes, including high ionic conductivity, low flammability, natural abundance, and high volumetric capacity, Zn-I2 batteries offer significant potential for grid-level deployment. This review provides a comprehensive overview of recent progress in three critical domains: positive-electrode engineering, zinc anode stabilization, and in situ characterization methods. On the cathode side, anchoring iodine to conductive matrices effectively mitigates polyiodide shuttling and enhances …

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Significantly Enhanced Oxygen Reduction Reaction Activity In Co-N-C Catalysts Through Synergistic Boron Doping, Chang Lan, Jing-Sen Bai, Xin Guan, Shuo Wang, Nan-Shu Zhang, Yu-Qing Cheng, Jin-Jing Tao, Yu-Yi Chu, Mei-Ling Xiao, Chang-Peng Liu, Wei Xing Sep 2025

Significantly Enhanced Oxygen Reduction Reaction Activity In Co-N-C Catalysts Through Synergistic Boron Doping, Chang Lan, Jing-Sen Bai, Xin Guan, Shuo Wang, Nan-Shu Zhang, Yu-Qing Cheng, Jin-Jing Tao, Yu-Yi Chu, Mei-Ling Xiao, Chang-Peng Liu, Wei Xing

Journal of Electrochemistry

The weak adsorption energy of oxygen-containing intermediates on Co center leads to a considerable performance disparity between Co-N-C and costly Pt benchmark in catalyzing oxygen reduction reaction (ORR). In this work, we strategically engineer the active site structure of Co-N-C via B substitution, which is accomplished by the pyrolysis of ammonium borate. During this process, the in-situ generated NH3 gas plays a critical role in creating surface defects and boron atoms substituting nitrogen atoms in the carbon structure. The well-designed CoB1N3 active site endows Co with higher charge density and stronger adsorption energy toward oxygen species, …

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Series Reports From Professor Wei’S Group Of Chongqing University: Advancements In Electrochemical Energy Conversions (2/4): Report 2: High-Performance Water Splitting Electrocatalysts, Ling Zhang, Wang-Yang Wu, Qiu-Yue Hu, Shi-Dan Yang, Li Li, Rui-Jin Liao, Zi-Dong Wei Sep 2025

Series Reports From Professor Wei’S Group Of Chongqing University: Advancements In Electrochemical Energy Conversions (2/4): Report 2: High-Performance Water Splitting Electrocatalysts, Ling Zhang, Wang-Yang Wu, Qiu-Yue Hu, Shi-Dan Yang, Li Li, Rui-Jin Liao, Zi-Dong Wei

Journal of Electrochemistry

The unavailability of high-performance and cost-effective electrocatalysts has impeded the large-scale deployment of alkaline water electrolyzers. Professor Zidong Wei’s group has focused on resolving critical challenges in industrial alkaline electrolysis, particularly elucidating hydrogen and oxygen evolution reaction (HER/OER) mechanisms while addressing the persistent activity-stability trade-off. This review summarizes their decade-long progress in developing advanced electrodes, analyzing the origins of sluggish alkaline HER kinetics and OER stability limitations. Professor Wei proposes a unifying “12345 Principle” as an optimization framework. For HER electrocatalysts, they have identified that metal/metal oxide interfaces create synergistic “chimney effect” and “local electric field enhancement effect”, enhancing selective …

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Local Electric Fields Coupled With Cl− Fixation Strategy For Improving Seawater Oxygen Reduction Reaction Performance, Yu-Rong Liu, Miao Zhang, Yan-Hui Yu, Ya-Lin Liu, Jing Li, Xiao-Dong Shi, Zhen-Ye Kang, Dao-Xiong Wu, Peng Rao, Ying Liang, Xin-Long Tian Sep 2025

Local Electric Fields Coupled With Cl− Fixation Strategy For Improving Seawater Oxygen Reduction Reaction Performance, Yu-Rong Liu, Miao Zhang, Yan-Hui Yu, Ya-Lin Liu, Jing Li, Xiao-Dong Shi, Zhen-Ye Kang, Dao-Xiong Wu, Peng Rao, Ying Liang, Xin-Long Tian

Journal of Electrochemistry

Development of robust electrocatalyst for oxygen reduction reaction (ORR) in a seawater electrolyte is the key to realize seawater electrolyte-based zinc-air batteries (SZABs). Herein, constructing a local electric field coupled with chloride ions (Cl−) fixation strategy in dual single-atom catalysts (DSACs) was proposed, and the resultant catalyst delivered considerable ORR performance in a seawater electrolyte, with a high half-wave potential (E1/2) of 0.868 V and a good maximum power density (Pmax) of 182 mW·cm−2 in the assembled SZABs, much higher than those of the Pt/C catalyst (E1/2: 0.846 V; Pmax: 150 mW·cm−2 …

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The Effect Of Ozone Treatment On The Quality Of Biodiesel From Waste Cooking Oil, Sri Redjeki Setyawati, Singgih Wibowo Sep 2025

The Effect Of Ozone Treatment On The Quality Of Biodiesel From Waste Cooking Oil, Sri Redjeki Setyawati, Singgih Wibowo

Makara Journal of Science

This research demonstrates the successful production of biodiesel from waste cooking oil (WCO) using the transesterification method. A methoxide solution, formed by employing a base catalyst and alcohol, facilitated the conversion of triglycerides into methyl esters and glycerol as the byproduct. The conversion process yielded 74% biodiesel and 13.5% glycerol content, with the remaining proportion consisting of water and contaminants. The application of ozone (O3) aeration proved effective in reducing contaminants—such as alcohol, unreacted catalysts, food residues and water—by approximately 60%. Furthermore, Fourier transform infrared (FTIR) testing affirmed that the biodiesel product—treated with O3 aeration—maintained its original …

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Effect Of Varying Chitosan Molecular Weights On The Morphology And Physical Characteristics Of Pva/Chitosan Composite Hydrogels, Yuan Alfinsyah Sihombing, Halida Rahmi Luthfianti, William Xaveriano Waresindo, Marathur Rodhiyah, Nur’Aini Nafisah, Dian Ahmad Hapidin, Dhewa Edikresnha, Khairurrijal Khairurrijal Sep 2025

Effect Of Varying Chitosan Molecular Weights On The Morphology And Physical Characteristics Of Pva/Chitosan Composite Hydrogels, Yuan Alfinsyah Sihombing, Halida Rahmi Luthfianti, William Xaveriano Waresindo, Marathur Rodhiyah, Nur’Aini Nafisah, Dian Ahmad Hapidin, Dhewa Edikresnha, Khairurrijal Khairurrijal

Makara Journal of Science

We employed the innovative freeze–thaw method to investigate the effect of chitosan (CS) molecular weights incorporated into polyvinyl alcohol on the morphology and physical characteristics of the hydrogel. This study aimed to unravel the intricate relationships between CS molecular weight variations, CS concentration, and the number of freeze–thaw cycles (4 or 6 cycles) on hydrogel swelling degree and weight loss. Incorporating CS improved the hydrogel structure and enhanced its porosity, resulting in remarkable increases in swelling degree ranging from 2 to 6 times the initial weight. Higher molecular weight CS (310,000–375,000 Da) exhibited a lower swelling degree than medium molecular …

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Nonlinear Analytical Models Of The Seismically Isolated ``Frame-Boiler'' System With Cantilever-Type Hysteresis Dampers, Aleksandr Mikhailovich Anushchenko, Dmitrii Evgenievich Bondarev, Aleksandr Yurievich Schukin Sep 2025

Nonlinear Analytical Models Of The Seismically Isolated ``Frame-Boiler'' System With Cantilever-Type Hysteresis Dampers, Aleksandr Mikhailovich Anushchenko, Dmitrii Evgenievich Bondarev, Aleksandr Yurievich Schukin

Journal of Sustainable Construction Materials and Technologies

This study shows results of development of the ``frame-boiler'' system with hysteresis dampers analytical model. Hysteresis dampers are used as boiler antiseismic bracing. It is noted that simplified analytical models are necessary at the stage of preliminary iterative calculations, when a CAE-modeling is impractical due to significant time costs. The authors have proposed 2 options of analytical models: 2-mass model and 3-mass model. The differential equations of motion for each model are written below. The results of the calculation for seismic impacts are compared with the finite element model. It is shown that 3-mass model gives good match of results …

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Advancing Sustainable Structural Solutions: Hemp Fiber-Reinforced Polymer (Hfrp) Reinforcement Bars For Concrete Applications Through Material Selection, Simulation, And Pathways For Future Development, Thomas Cadenazzi, Busra Keles Sep 2025

Advancing Sustainable Structural Solutions: Hemp Fiber-Reinforced Polymer (Hfrp) Reinforcement Bars For Concrete Applications Through Material Selection, Simulation, And Pathways For Future Development, Thomas Cadenazzi, Busra Keles

Journal of Sustainable Construction Materials and Technologies

This paper investigates innovative Hemp Fiber-Reinforced Polymer (HFRP) rebars as a sustainable alternative to conventional Carbon Steel (CS) and Glass Fiber-Reinforced Polymer (GFRP) rebars used as reinforcement in concrete structures. The feasibility of HFRP rebars is assessed, focusing on mechanical properties and sustainability advantages. A virtual tensile test on a modeled M19 HFRP rebar, conducted using Autodesk's Fusion 360, demonstrates tensile strength comparable to CS 235 and greater environmental sustainability than GFRP, despite a slight reduction in stiffness. The study also considers the potential of graphene fiber integration to enhance mechanical properties, underscoring HFRP's adaptability. Findings suggest that HFRP rebars, …

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Effect Of Clays On The Spontaneous Imbibition Behavior Of Surfactant Solutions In Shale Oil Reservoirs, Ning Xu, Yanling Wang, Baojun Bai, Chuanbao Zhang, Shizhang Cui, Yu Zhang, Di Li, Wenjing Shi, Wenhui Ding Sep 2025

Effect Of Clays On The Spontaneous Imbibition Behavior Of Surfactant Solutions In Shale Oil Reservoirs, Ning Xu, Yanling Wang, Baojun Bai, Chuanbao Zhang, Shizhang Cui, Yu Zhang, Di Li, Wenjing Shi, Wenhui Ding

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Surfactant-enhanced spontaneous imbibition is a proven method of enhancing oil recovery from shale reservoirs. However, a significant knowledge gap concerning the impact of clay minerals on surfactant-enhanced imbibition in shale reservoirs remains. Therefore, this study first analyzed the mineral composition and pore structure of the shale reservoirs. Subsequently, three surfactants were selected for spontaneous imbibition experiments. The influence of various clay minerals on the surfactant imbibition was assessed by considering various properties of the imbibition system. The results showed that the shale pores primarily consisted of macropores (44.03%) and mesopores (43.94%). Surfactants enhance the imbibition recovery by altering the wettability …

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