Chemical Engineering Commons^™

Size Distribution, Elemental Composition And Morphology Of Nanoparticles Separated From Respirable Coal Mine Dust, Shoeleh Assemi, Lei Pan, Xuming Wang, Titilayo Akinseye, Jan D. Miller

Michigan Tech Publications, Part 1

Nanoparticles, defined as particles with one dimension below 100 nm, contribute little to the total mass concentration in respirable coal mine dust (RCMD) toxicological studies, but they could have a considerable part in the adverse health effects by RCMD inhalation. It has been shown that inhaled nanoparticles can penetrate deep into the lung and could plausibly contribute to acute and chronic pulmonary diseases by triggering oxidative stress formation and inducing inflammation. RCMD nanoparticles from samples collected in an underground mine in the United States were analyzed by a particle separation technique, field-flow fractionation (FFF), for size, morphology, and elemental composition. …

Preparation, Cure, And Characterization Of Cyanate Ester-Epoxy Blends Containing Reactive Flame Retardants, Mustafa Mukhtar, Donald A. Klosterman

Chemical and Materials Engineering Faculty Publications

Cyanate ester resins are sometimes mixed with lower cost epoxy monomers to modify cost, toughness, and processing capabilities. Despite the high performance of these thermosetting polymers, flame retardancy remains an issue. This study examined blends of three different commercial cyanate ester monomers (LVT-100, LECy, and XU-71787.02) and diglycidyl ether of bisphenol A (DGEBA) at 50/50 wt% of each type. The blends were successfully reacted with two reactive flame retardants (FR): 9,10-dihydro-9-ox-9-phosphaphenanthrene-10-oxide (DOPO) and poly(m-phenylene methylphosphonate) (PMP) at phosphorus contents ranging from 0 to 3 wt%. The curing behavior of EP/CE blends was investigated using differential scanning calorimetry (DSC). It was …

Heterogeneous Microstructure And Mechanical Behaviour Of Al-8.3fe-1.3v-1.8si Alloy Produced By Laser Powder Bed Fusion, S. J. Yu, P. Wang, H. C. Li, R. Setchi, M. W. Wu, Z. Y. Liu, Z. W. Chen, S. Waqar, Lai-Chang Zhang

Research outputs 2022 to 2026

The relationship between processing parameters, microstructure, and mechanical properties of Al-8.3Fe-1.3V-1.8Si alloy processed by laser powder bed fusion is seldom studied. Therefore, fully dense alloys with two parameters were selected to investigate this key issue. The results show that the alloy with low power and scanning speed (S200) shows fan-shell-shaped melt pools and laser tracks while another (S350) shows a deeper and wider melt pool. Both alloys obtain a heterogeneous microstructure without a secondary phase in melt pool (MP) and a nano-sized phase in melt pool boundary (MPB). The difference between solid-solution strengthening and Orowan strengthening in MP and MPB …

The Production Of Encapsulated Holy Basil Oil Powder Via Different Scales Of Spray Drying Process., Chanakarn Chungmarisakul

Chulalongkorn University Theses and Dissertations (Chula ETD)

The spray drying process is widely utilized in food manufacturing and pharmaceuticals for products like seasoning powder, milk powder, and medicine. This research investigates the scale-up of the spray drying process from laboratory to commercial scale with maintaining the product characteristic. A key aspect of the study is the encapsulation technique applied to prolong the release of essential oils from holy basil, encapsulating the essential substances (liquid, suspension, or emulsion) in nanoparticle form with hot air flow. The study utilizes the Aspen program, incorporating mass and energy balance calculations for simulation. The results, assuming similar particle size, water evaporation per …

Effects Of Confinement On Ionic Liquids And Deep Eutectic Solvents For The Design Of Catalytic Systems, Electrochemical Devices, And Separations, Andrew Drake

Theses and Dissertations--Chemical and Materials Engineering

Confinement of ionic liquids (ILs) and deep eutectic solvents (DESs) within mesoporous materials such as silica helps to control the local environment within the pores for applications such as catalysis, electrochemistry, and absorption. Silica thin films with 2.5 and 8 nm pores and micron-sized silica particles with pore diameters of 5.4 and 9 nm were synthesized to study the effect of nanoconfinement on ILs 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF₆]), 1-butyl-3-methylimidazolium chloride ([BMIM][Cl]), and DESs reline and ethaline (choline chloride and urea or ethylene glycol). Silica thin films with vertically aligned, well ordered, and accessible pores were synthesized via the evaporation-induced …

Attrition Study Of Copper-Supplemented Iron-Based Oxygen Carrier For Chemical Looping Combustion, Neng Huang

Theses and Dissertations--Mechanical and Aerospace Engineering

Chemical looping combustion (CLC) is a promising technology that can mitigate the carbon emissions for power generation. The cost of oxygen carriers (OCs) impedes the scale up of CLC. Compared to synthetic iron-based OCs, red mud (RM), an abundant iron-based solid waste from industry, is a cost-effective choice due to its intrinsic inclusion of both inert and catalytic phases that are crucial for CLC. It was anticipated that the addition of copper oxide to RM using a mechanical mixing method that can be easily scaled up would enhance both reactivity and oxygen transport capacity (OTC), and the heat of reaction …

Impact Of Spallation And Internal Radiation On Fibrous Ablative Materials, Raghava Sai Chaitanya Davuluri

Theses and Dissertations--Mechanical and Aerospace Engineering

Space vehicles are equipped with Thermal Protection Systems (TPS) that encounter high heat rates and protect the payload while entering a planetary atmosphere. For most missions that interest NASA, ablative materials are used as TPS. These materials undergo several mass and energy transfer mechanisms to absorb intense heat. The size and construction of the TPS are based on the composition of the planetary atmosphere and the impact of various ablative mechanisms on the flow field and the material. Therefore, it is essential to quantify the rates of different ablative phenomena to model TPS accurately. In this work, the impact of …

Microalgae Immobilization With Filamentous Fungi: Process Development For Sustainable Food Systems, Suvro Talukdar

Theses and Dissertations--Biosystems and Agricultural Engineering

Demand for sustainable food sources has increased because of the rapid growth of the world's population.  In this study, microalgae cells of Haematococcus pluvialis were immobilized using the edible fungal strain Aspergillus awamori for potential food applications. The study investigated the impact of fungal loading, pellet geometry, and initial microalgae cell concentration on the immobilization performance and product characteristics. It was found that higher fungal loading and larger fungal pellets contributed to increased immobilization performance while increased initial microalgae concentration inhibited the process. Larger fungal pellets had decreased biomass density, which led to decreased surface concentration of immobilized microalgae but …

Direct Recycling Of Lithium-Ion Battery Materials Using Physical Separation Methods., Tinuade Ololade Folayan

Dissertations, Master's Theses and Master's Reports

The increased demand for Lithium-ion batteries for Electric vehicles has influenced worldwide interest in the research and development of methods for recycling end-of-life Lithium-ion batteries. Direct recycling method has gained more attention in recent times as a method that is low-cost with the ability to recover all Lithium-ion battery materials without changing the chemical and structural properties of the recycled materials.

A lithium-ion battery contains a complex mixture of materials with significantly different physical properties. This work develops physical separation techniques as Direct recycling methods to recycle individual battery components without damaging the functional integrity of the recycled materials. In …

Solid-State Shear Pulverization: A Comprehensive Study On Polymer Processing Technology From A Systematic Innovation Perspective, Tyler A. Will

Master’s Theses

Solid-state shear pulverization (SSSP) is a continuous and scalable processing technique that imposes mechanochemical changes in polymer-based materials. It has been shown to impart beneficial properties onto homopolymers or create copolymers and composites through continuous fragmentation and fusion. The unique technology employs cold temperature to keep the polymer in the solid state. This thesis investigates industrial polymer processing in the context of real-world applications. This thesis analyzes SSSP using an organized methodology called systematic innovation (SI). SI facilitates problem solving by assisting engineers in conducting root cause analysis around a material and studying the physical setup of the equipment.

This …

Temperature-Dependent Diffusion In Block Copolymer Organogels, Ridwana Bashar

Master’s Theses

Organogels are often considered for transport-based applications such as transdermal drug delivery vehicles and gel actuators due to their unique properties. Recent consideration of styrenic block copolymer based organogels’ application in transdermal drug delivery requires an extensive investigation of drug diffusion behavior through these gels to assess their applicability. Temperature is a major influencing parameter on diffusion. The goal of this research is to better understand the impact of temperature on diffusion in styrenic triblock copolymer organogels. To accomplish this goal, we focused on three specific objectives: (i) accurately measure the diffusivities of a solute – AOT reverse micelles – …

Running Shoe Pedometer, Benjamin Kasper

Williams Honors College, Honors Research Projects

Running shoe pedometer aims to solve the issue of worn out running shoes. It can be difficult to know just how many miles you have run in your shoes and when a new pair is needed. Running in old shoes and worn out shoes is heavily linked to injury. My proposed project is a device that is powered by the compressive forces on the shoes soles that counts the number of steps the wearer takes using a microcontroller. Then, when the shoe reaches milestone that indicate it has been used 75% 90% and 100% of its expected life, it will …

Enhancing Control Room Operator Decision Making: An Application Of Dynamic Influence Diagrams In Formaldehyde Manufacturing, Joseph Mietkiewicz, Anders L. Madsen

Articles

Intoday’s rapidly evolving industrial landscape, control room operators must grapple with an ever-growing array of tasks and respon sibilities. One major challenge facing these operators is the potential for task overload, which can lead to decision fatigue and increased reliance on cognitive biases. To address this issue, we propose the use of dynamic influence diagrams (DID) as the core of our decision support system. By monitoring the process over time and identifying anomalies, DIDs can recommend the most effective course of action based on a probabilistic assessment of future outcomes. Instead of letting the operator choose or search for the …

Development, Validation And Implementation Of Multiple Radioactive Particle Tracking Technique, Mehul S. Vesvikar, Thaar M. Aljuwaya, Mahmoud M. Taha, Muthanna H. Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

Computer Automated Radioactive Particle Tracking (CARPT) technique has been successfully utilized to measure the velocity profiles and mixing parameters in different multiphase flow systems where a single radioactive tracer is used to track the tagged phase. However, many industrial processes use a wide range of particles with different physical properties where solid particles could vary in size, shape and density. For application in such systems, the capability of current single tracer CARPT can be advanced to track more than one particle simultaneously. Tracking multiple particles will thus enable to track the motion of particles of different size shape and density, …

3d-Printed Boron Nitride Catalytic Monoliths For Oxidative Dehydrogenation Of Propane, Theodore Agbi, Wei Shang Lo, Khaled Baamran, Taekyung Ryu, Christine Cheung, Fateme Rezaei, Ive Hermans

Chemical and Biochemical Engineering Faculty Research & Creative Works

Boron-containing materials are efficient catalysts for the oxidative dehydrogenation of propane to propylene, proceeding via radical intermediates. The radical mechanism is initiated by the solid surface and propagated in the gas phase. It has been hypothesized that the propylene selectivity could be increased by enhancing the gas-phase contributions by favoring the formation of iso- over n-propyl radical intermediates. Indeed, whereas n-propyl radicals can be converted to both propylene and ethylene, iso-propyl radicals yield exclusively propylene. In this contribution, we explore 3D printing to structure the hexagonal boron nitride (hBN) heterogeneous catalyst with high void space. 3D-printed hBN monoliths were found …

Reactive Oxygen Species (Ros)-Responsive Size-Reducible Nanoassemblies For Deeper Atherosclerotic Plaque Penetration And Enhanced Macrophage-Targeted Drug Delivery, Jianhua He, Wenli Zhang, Xiaoju Zhou, Fengfei Xu, Jiahui Zou, Qiqi Zhang, Yi Zhao, Hongliang He, Hu Yang, Jianping Liu

Chemical and Biochemical Engineering Faculty Research & Creative Works

Nanoparticle-Based therapeutics represent potential strategies for treating atherosclerosis; however, the complex plaque microenvironment poses a barrier for nanoparticles to target the dysfunctional cells. Here, we report reactive oxygen species (ROS)-responsive and size-reducible nano assemblies, formed by multivalent host-guest interactions between β-cyclodextrins (β-CD)-anchored discoidal recombinant high-density lipoprotein (NP3ST) and hyaluronic acid-ferrocene (HA-Fc) conjugates. the HA-Fc/NP3ST nano assemblies have extended blood circulation time, specifically accumulate in atherosclerotic plaque mediated by the HA receptors CD44 highly expressed in injured endothelium, rapidly disassemble in response to excess ROS in the intimal and release smaller NP3ST, allowing for further plaque penetration, macrophage-targeted cholesterol efflux and …

Hygroscopic Tandem Differential Mobility Analyzer (Htdma) Design And Testing For Aerosol Hygroscopic Behavior Studies, Ziheng Zeng

Honors Theses

Most particles in the atmosphere take up water when exposed to increasing relative humidity (RH), and this behavior is described and quantized by a hygroscopicity parameter, kappa. Hygroscopic Tandem Differential Mobility Analysis (HTDMA) can be used to measure the physicochemical properties of aerosol particles and study phenomena that lead to size changes in submicron aerosol particles. Specifically, HTDMA measures how aerosol particles of different initial dry sizes grow or shrink when exposed to changing RH. HTDMA uses two differential mobility analyzers (DMAs) and a humidification system to make these measurements. One DMA selects a narrow size range of dry aerosol …

Development Of A Solution Synthesis Of Poly(Sebacic Anhydride) With The Activating Agent 4-Toluenesulfonyl Chloride: Understanding The Effect Of Different Bases On The Reaction Products, Patricia Poley

Honors Theses

The overall goal of this honors thesis was to develop a solution synthesis of Poly(Sebacic Anhydride) with the activating agent 4-toluenesulfonyl chloride and understand the effects of varying temperature, bases, and the addition order of reagents on the reaction.

Polyanhydrides are a class of hydrophobic, degradable polymers used in controlled drug delivery for 30 years. They are synthesized through three general methods: melt polycondensation, solution polycondensation, and ring-opening polymerization. Of these three methods, solution polycondensation typically results in products with lower molecular weight. Previous work in the Vogel lab identified two new ways to synthesize anhydrides using solution polycondensation reactions …

Interdependence Of Salt Concentration And Filler Particles On Crystallinity And Mechanical Behavior Of Peo-Litfsi Electrolytes For Lithium-Ion Batteries, Valeria Perez

Master's Theses

Developing composite polymer electrolytes is crucial for enhancing the safety, energy density, and performance of lithium-ion batteries. While it is widely accepted that introducing filler particles in PEO-based electrolytes can reduce crystallinity and enhance ionic conductivity, this conventional understanding applies primarily to electrolytes with high lithium salt concentrations. The hypothesis of this investigation is that the crystallinity change induced by LLZTO ceramic particles in PEO-LiTFSI electrolytes is contingent on the EO:Li molar ratio. This hypothesis is interrogated by measuring changes in crystallinity, spherulite morphology, and stiffness of composite polymer electrolytes with two different EO:Li molar ratios using differential scanning calorimetry, …

Exploring Ph Gradient Phenomena In Non-Linear Electrokinetic Microfluidic Devices, Azade Tahmasebi

Dissertations, Master's Theses and Master's Reports

Electrokinetic microfluidics is a versatile technology utilized within lab on a chip (LOC) devices for diagnostic and analytical applications; advantages include reduced resource demands, flexibility, and simplicity of use. Dielectrophoresis (DEP) is a precision nonlinear electrokinetic tool utilized within microfluidic microdevices to induce polarization and control bioparticle motions for applications that range from hemoglobin separations to cancer cell isolation and detection. Despite promising results, undesired side phenomena can occur in electrokinetic systems which impede reproducibility and accuracy. These unfavorable phenomena have not been comprehensively explored in the literature. Prior preliminary research suggests the fundamental phenomena originate from microelectrodes utilized in …

Batch And Fixed-Bed Adsorption Of Ciprofloxacin Using Magnetic Biochar From Macadamia Nutshell, Sakonsupa Damdib

Chulalongkorn University Theses and Dissertations (Chula ETD)

In this research, the utilization of macadamia nutshell as a potential adsorbent for ciprofloxacin (CIP) removal was investigated. The distinctive features of macadamia nutshell, characterized by its lignocellulosic composition and hardness, make it suitable as a precursor for synthesizing magnetic biochar, aimed at CIP adsorption in both batch and fixed-bed column processes. The influence of temperature activation and carbonization temperature on the properties of the resulting biochar was examined. Macadamia nutshell impregnated with a 0.10 M iron nitrate solution and carbonized under a nitrogen atmosphere at 800°C (MB-BI-800) exhibited the highest micropore and mesopore volumes, with values of 0.14 and …

Verification Of Oil Recovery Mechanism Through Alteration Of Relative Permeability Curve And Analytical Measurements, Tina Tharn

Chulalongkorn University Theses and Dissertations (Chula ETD)

In the petroleum production industry, there are several methods that can be utilized to increase oil recovery. These methods are so-called Enhanced Oil Recovery (EOR). Nowadays, Low Salinity Water Flooding (LSWF) is one of the considerable of those techniques due to its cost and simplicity. However, understanding its main oil recovery mechanism is still limited. Therefore, the investigation of oil mechanism provided by LSWF would help refine its application to oilfields. In this study, the Johnson–Bossler–Naumann (JBN) approach is employed to examine relative permeability curves during LSWF in different rock formations including clean sandstone (SS), shaly-sandstone (SHS), and dolostone (DL). …

ผลของแกรฟีนควอนตัมดอทต่อการเจริญเติบโตและฤทธิ์ต้านอนุมูลอิสระของต้นถั่วเขียวและต้นอ่อนทานตะวัน, วราวุธ คงแสงชัย

Chulalongkorn University Theses and Dissertations (Chula ETD)

แกรฟีนควอนตัมดอท (Graphene Quantum Dots) จัดเป็นวัสดุนาโนที่มีคุณสมบัติเชิงแสงที่เป็นเอกลักษณ์จากผลของการกักกันเชิงควอนตัม อีกทั้งยังมีความเข้ากันได้กับเซลล์ของสิ่งมีชีวิตค่อนข้างสูง รวมทั้งความเป็นพิษต่อเซลล์ของสิ่งมีชีวิตที่ต่ำ สำหรับงานวิจัยนี้เป็นการศึกษาผลของการเติม GQDs ที่มีต่อการเจริญเติบโตและฤทธิ์ต้านอนุมูลอิสระ ซึ่งเมล็ดต้นกล้าที่ใช้ในการศึกษา คือ เมล็ดถั่วเขียวและเมล็ดต้นอ่อนทานตะวัน โดยจะติดตามการเจริญเติบโตในลักษณะเทคนิคต่างๆของการเติม GQDs 3 เทคนิควิธีการ ได้แก่ 1.) การแช่เมล็ดด้วย GQDs ที่ความเข้มข้นต่างๆ 2.) การเติม GQDs ให้กับต้นกล้าในลักษณะการใส่ปุ๋ยที่ความเข้มข้นต่างๆ และ 3.) การกระทำทั้งเทคนิควิธีการที่ 1 และ 2 ร่วมกันในช่วงความเข้มข้น 0 - 0.3 mg/mL ของ GQDs พบว่าต้นกล้าถั่วเขียวที่ความเข้มข้น 0.3 mg/mL ด้วยเทคนิควิธีการเติม GQDs ให้กับต้นกล้าในลักษณะการใส่ปุ๋ยมีฤทธิ์ต้านอนุมูลอิสระมากที่สุดถึง 33.67% เมื่อเทียบกับต้นกล้า control แต่สำหรับต้นกล้าต้นอ่อนทานตะวันนั้นจะพบว่าที่ความเข้มข้น 0.3 mg/mL เทคนิควิธีร่วมกันทั้ง 2 วิธีการจะให้ฤทธิ์ต้านอนุมูลอิสระมากที่สุด 38.24% เมื่อเทียบกับต้นกล้า control

Combustion Characteristics Of Methane, Ethane, Propane, And Butane Blends Under Conditions Relevant Of A Dual-Fuel Diesel And Natural Gas Engine, Christopher Joseph Ulishney

Graduate Theses, Dissertations, and Problem Reports (ETD)

As natural gas production infrastructure is already in place in most of the world and will continue expanding for the foreseeable future, natural gas is an alternative to traditional liquid petroleum fuels in heavy-duty engines. Dedicated natural gas or dual-fuel diesel-natural gas heavy-duty engines are alternatives to diesel-only power generation equipment. One challenge is the large variation in the natural gas composition available for such applications, which is known to significantly affect engine’s combustion characteristics and the emissions composition. As the literature on dual-fuel combustion under low load engine operating conditions that use more realistic natural gas mixtures (i.e., mixtures …

Modeling And Simulation Of A Process That Converts Ethane To Ethylene And Ethylene To Low Density Polyethylene, Ernest Bosire Mokaya

Graduate Theses, Dissertations, and Problem Reports (ETD)

Ethylene is a critical feedstock and a major building block in the petrochemical industry that is used in synthesizing important products like polyethylene, ethanol, ethylene oxide, ethylene dichloride and ethylbenzene. With increasing demand of plastics, production of ethylene and subsequently polyethylene has increased globally. This thesis conducts the modeling and simulation of an integrated process that utilizes ethane as the primary feedstock to produce ethylene and the subsequent polymerization of ethylene to low-density polyethylene (LDPE). The process combines two different processes into one integrated process: (1) conversion of ethane to ethylene and (2) conversion of ethylene to LDPE. First, a …

Applying Thermal And Microwave Heating For Natural Gas Conversion To Value-Added Chemicals Over Zeolite-Supported Catalysts, Ashley Marie Caiola

Graduate Theses, Dissertations, and Problem Reports (ETD)

The world’s demand for natural gas has been consistently growing over the past few decades. Natural gas is considered a potential alternative to oil and coal because of its ability to burn cleaner. Although not completely emission-free, it has dominated the energy industry by providing a continuous supply of cheap fuel. Currently, natural gas makes up 41% of North American energy production. The conversion of natural gas to value-added chemicals typically involves the indirect production of synthesis gas (syngas) as an intermediate before the production of the desired product. Steam reforming and partial oxidation are two of the most common …

Synthesis Of Quasi-Freestanding Graphene Films Using Radical Species Formed In Cold Plasmas, Michael A. Mathews Jr.

Graduate Theses, Dissertations, and Problem Reports (ETD)

For over a decade, the Stinespring laboratory has investigated scalable, plasma assisted synthesis (PAS) methods for the growth of graphene films on silicon carbide (SiC). These typically utilized CF₄-based inductively coupled plasma (ICP) with reactive ion etching (RIE) to selectively etch silicon from the SiC lattice. This yielded a halogenated carbon-rich surface layer which was then annealed to produce the graphene layers. The thickness of the films was controlled by the plasma parameters, and overall, the process was readily scalable to the diameter of the SiC wafer.

The PAS process reproducibly yielded two- to three-layer thick graphene films …

Leveraging Artificial Intelligence And Geomechanical Data For Accurate Shear Stress Prediction In Co2 Sequestration Within Saline Aquifers (Smart Proxy Modeling), Munirah Alawadh

Graduate Theses, Dissertations, and Problem Reports (ETD)

This research builds upon the success of a previous project that used a Smart Proxy Model (SPM) to predict pressure and saturation in Carbon Capture and Storage (CCS) operations into saline aquifers. The Smart Proxy Model is a data-driven machine learning model that can replicate the output of a sophisticated numerical simulation model for each time step in a short amount of time, using Artificial Intelligence (AI) and large volumes of subsurface data. This study aims to develop the Smart Proxy Model further by incorporating geomechanical datadriven techniques to predict shear stress by using a neural network, specifically through supervised …

Ambient Ammonia Synthesis Via Microwave-Catalytic Materials And Plasma Chemistry, Siobhan Brown

Graduate Theses, Dissertations, and Problem Reports (ETD)

Ammonia is critical to supporting human life on earth because of its use as fertilizer. The Haber-Bosch process to produce ammonia has been practiced for over 100 years. This process operates at high pressure and temperature to overcome the thermodynamic and kinetic limitations of the ammonia synthesis reaction thus researchers have tried to overcome it for decades. At present this process represents 1% of global energy usage and 2.5% of global CO₂ emissions. The proposed chemical looping ammonia synthesis approach seeks to reduce the environmental impact of this critical process and to elucidate microwave-catalytic principles.

This research aims to …

Optimal Design And Operation Of Integrated Hydrogen Generation And Utilization Plants, Ijiwole Solomon Ijiyinka

Graduate Theses, Dissertations, and Problem Reports (ETD)

There are considerable efforts worldwide for reducing the use of fossil fuel for energy production. While renewable energy sources are being increasingly used, fossil fuel still contribute about 80% of the energy used worldwide. As a result, the level of CO₂ is still increasing fast in the atmosphere currently exceeding about 410 parts per million (ppm). For reducing CO₂ build up in the atmosphere, various approaches are being investigated. For the electric power generation sector, two key approaches are post-combustion CO₂ capture and use of hydrogen as a fuel for power generation. These two solutions can also …