Chemical Engineering Commons^™

Experimental Data Supporting Co2 Enhanced Oil Recovery And Storage Potential In The Bakken Petroleum System (Bps), University Of North Dakota. Energy And Environmental Research Center

EERC Brochures and Fact Sheets

Fact sheet on CO₂ enhanced oil recovery (EOR) in the Bakken petroleum system. Highlights experimental data concerning CO₂’s role in oil recovery in the region.

A Focused Review On Recycling And Hydrolysis Techniques Of Polyethylene Terephthalate, Hossein Abedsoltan

Chemical and Biochemical Engineering Faculty Research & Creative Works

Polyethylene terephthalate (PET) is used in textile and packaging industries. The main source of PET production is fossil fuels with limited capacity. Also, PET products are single use that transform into high volumes of wastes, causing ecosystem problems. Recycling is proposed to confront this challenge. The four major PET recycling techniques are mechanical, chemical, pyrolysis, and enzymatic. Mechanical, pyrolysis, and enzymatic techniques have constrained capabilities to manage PET waste. Chemical recycling is the potential path to expanding recycling PET waste with possibility of upcycling and addressing dirty waste streams. Several chemical methods are introduced and discussed in literature. The five …

Syne1 Mutation Is Associated With Increased Tumor Mutation Burden And Immune Cell Infiltration In Ovarian Cancer, Laura M. Harbin, Nan Lin, Frederick R. Ueland, Jill M. Kolesar

Markey Cancer Center Faculty Publications

SYNE1, a nuclear envelope protein critical for cellular structure and signaling, is downregulated in numerous malignancies. SYNE1 alterations are found in 10% of gynecologic malignancies and 5% of epithelial ovarian cancers. Previous studies demonstrated an association between SYNE1 mutation, increased tumor mutation burden (TMB), and immunotherapy response. This study evaluates the SYNE1 mutation frequency, association with TMB, and downstream effects of SYNE1 mutation in ovarian cancer. Genetic information, including whole-exome sequencing, RNA analysis, and somatic tumor testing, was obtained for consenting ovarian cancer patients at an academic medical center. Mutation frequencies were compared between the institutional cohort and The Cancer …

Upgrading Biomass To Bio-Oil: Catalytic Hydrodeoxygenation And Pyrolysis Of Vanillin And Anisole Biomass Model Compounds, Ahmad J. Yaghi

Theses

The purpose of this project is to investigate capacity of selected formulations of catalysts toward the hydrodeoxygenation (HDO) of biomass model compounds in the gas phase with the underlying aim to produce hydrocarbon cuts that can be directly used as transportation fuels. The first part of this project is to devoted to illustrate procedures for the synthesis of potent (HDO) catalysts. Synthesized catalysts encompass nickel (Ni), cobalt (Co) and palladium (Pd) supported on zeolite, cerium oxide (CeO₂) or alumina (Al₂O₃). Various characterization techniques such as X-ray Diffraction (XRD), Temperature Programmed Reduction (TPR) were deployed …

Bacterial Motion And Spread In Porous Environments, Yasser Almoteri

Dissertations

Micro-swimmers are ubiquitous in nature from soil and water to mammalian bodies and even many technological processes. Common known examples are microbes such as bacteria, micro-algae and micro-plankton, cells such as spermatozoa and organisms such as nematodes. These swimmers live and have evolved in multiplex environments and complex flows in the presence of other swimmers and types, inert particles and fibers, interfaces and non-trivial confinements and more. Understanding the locomotion and interactions of these individual micro-swimmers in such impure viscous fluids is crucial to understanding the emergent dynamics of such complex systems, and to further enabling us to control and …

Synergistic Effect Of Air Sparging In Separation Via Nano-Carbon Immobilized Membrane Distillation Process And Optimization, Mitun Chandra Bhoumick

Dissertations

Membrane distillation (MD) has gained significant popularity as a separation and purification technique in diverse domains, such as saline/brackish water treatment, organic recovery, and wastewater treatment. The objective of this research is to advance MD by developing a novel air sparged membrane distillation in treating saline water, recovering solvents, and achieving preconcentration. To optimize the flux and selectivity in membrane distillation, the study also employed a response surface method based on a central composite rotatable design.

In this study, a novel air-sparged membrane distillation (ASMD) is introduced for the treatment of saline water, utilizing a nanocarbon immobilized membrane. The performance …

Use Of Neural Networks In Intelligent Measurement Tools, N.R Yusupbekov, Y.Sh. Avazov, Umidjon Ruziev Phd

Chemical Technology, Control and Management

The paper presents algorithms for processing the measurement signal with the possibilities of adaptation, learning and decision making. A comparative analysis of the methods of intellectual processing of measurement data is carried out. A model of a measuring instrument for determining the structure of a neural network has been developed. The problem of error reduction due to measurement noise filtering with the use of neural networks is considered. The structure of the neural network has been developed for intelligent processing of the measurement signal and ensuring the implementation of the functions of reconfiguration, calibration, self-diagnosis and self-control. A neural network …

Algorithms For Synthesis Of Adaptive Control Systems Based On The Neural Network Approach, Jasur Sevinov, Oxunjon Boborayimov, Sh.M. Abdishukurov

Chemical Technology, Control and Management

Here are algorithms for the synthesis of adaptive control systems based on the neural network approach presented. The issues of choice of architectures of neural networks that produce parametric identification of the object regulation. Adaptative neural networks that reproduce the optimal parameters of implemented controllers, methods of forming training samples for their training are considered. The other question of using the theory of artificial neural networks for approximating the functional of the controller's tuning parameters are determined. Structures of synthesized neural networks of parametric identification of objects with self-alignment in an open loop ACS are proposed. Algorithms made it possible …

Results Of The Study Of The Pumpkin Drying Process, Jasur Esirgapovich Safarov, Shahnoza Abduvakhitovna Sultanova, Andrey Svyatoslavovich Ponasenko, Gani Toshkhujaevich Dadaev

Chemical Technology, Control and Management

The article presents the results of the study of the pumpkin drying process, comparisons with different drying models are carried out. A mathematical model for numerical analysis has been developed. Pumpkin drying rates are calculated and various drying models are investigated. 5 different drying models were used to verify the accuracy of experimental data and search for the most suitable model. The experimental data obtained for the drying air temperature of 45 °C, 55 °C and 65 °C were applied to various drying models.

Systematic Analysis Of Methods Of Control Of Dynamic Objects In Conditions Of Non-Measurable Disturbances, Mamirov Farkhodovich Uktam, Buronov Mamurjon Ugli Bunyod

Chemical Technology, Control and Management

The article presents a systematic analysis of control methods of dynamic objects under non-measurable disturbances. It is important to study all the factors affecting the control object in order to increase the efficiency of the control system. Due to the immeasurable nature of disturbances affecting control objects, it is shown that they cause negative effects and increase the complexity of control systems in this case. In the control of dynamic objects of this type, the possibilities of control by indirect measurement of disturbances or by estimation of object position and disturbances have been explored. The use cases, shortcomings and achievements …

Development Of The Computer Model Of The Waste Water Treatment Process Using Ion-Exchange Resins In The Matlab Program, Jaloliddin Abdurazzakovich Eshbobaev, Bakhodir Tajiddinovich Khamidov, Adham Tilovovich Norkobilov, Orifjon Sharipovich Kodirov

Chemical Technology, Control and Management

In this work, a mathematical model of industrial wastewater treatment technology was formed. First, wastewater treatment technologies were analyzed and the technology of ion-exchange resin treatment was selected. A water purification device using ion-exchange resins was made, and tested on the Kungrad soda plant and the results were obtained. According to these results, it was determined that the cleaning coefficient of the device is up to 98-99%. In this article, a mathematical model of a wastewater treatment device using ion-exchange resins was developed using the stoichiometric matrix method. After the mathematical model of the process was found, a graph of …

The Morphology Analysis Of Soil In Remote Sensing Image Processing, Mirzayan Mirzaaxmedovich Kamilov, Mirzaakbar Xakkulmirzayevich Hudayberdiev, Bobomurod Mamitjonovich Tojiboev

Chemical Technology, Control and Management

This article analyzed various techniques used in satellite image processing to analyze soil morphology. Analysis of soil morphology using satellite imagery plays a crucial role in soil science research, Land Management, and environmental monitoring. It provides an economical and efficient means of studying large-scale soil variability, providing information on land sustainable use, resource management and soil conservation decisions.

Computer Training Systems For Training Engineering Personnel For Control Industrial Enterprises, Yusuf Shodiyevich Avazov, Kamola Rustamovna Abdullaeva

Chemical Technology, Control and Management

A principle has been proposed for constructing computer simulators for improving the qualifications of process control operators at industrial enterprises and for training students of higher educational institutions. The capabilities of a computer simulator that can be used as a digital assistant are revealed. Their architecture for building digital simulators is proposed. From the architecture it is clear that the computer simulator consists of two systems. The training process management system and the server of the computerized simulator are combined into a digital simulator. Simulators in this category provide student operators with the opportunity to develop skills in self-control of …

Obtaining Sweet Molasses By The Method Of Hydromechanical And Enzymatic Processing Of Grain, Sadritdin Maxamatdinovich Turabdjanov, Kamoliddin Ahmadjonovich Mahmudov, Bexzod Alisherovich Kasimov, Kasun Dissanayake Kumara

Chemical Technology, Control and Management

Methods of hydrolysis of grains to starch under the influence of hydrodynamic and enzymatic processes are logically based. Polysaccharides derived from starchy grains are known and popular in the food industry for their thickening and stabilizing properties. To date, studies that allow for a deeper understanding of the mechanism of interaction of polysaccharide-containing products with their main components, the effect on the set of rheological, organoleptic, physico-chemical properties of food products that determine their functions are relevant.

Mathematical Model Of An Industrial Robot Built On The Basis Of Linear Motion Mechatron Modules, Matyokubov Nurbek Rustamovich, Rakhimov Temurbek Omonboyevich

Chemical Technology, Control and Management

The use of Industry 4.0 technologies in modern production serves to increase production efficiency. Robots and robotic complexes with innovative intelligent control are widely used in industrial production. However, studying their mechanical part, linear motion mechatronic modules and control system is a complex object. The variety and complexity of control methods and operating modes negatively affects the operator's working time and production productivity. In such cases, it is necessary to improve control methods and develop technologies used in industry, including robots and robotic manipulators, which allow to perform short movements with high accuracy and speed. In the article, the mathematical …

Application Of Evolutionary Algorithms For Optimization Of Operation Modes Of Regional Electric Power Systems, Isamiddin Khakimovich Siddikov, Oksana Vitalevna Porubay

Chemical Technology, Control and Management

The paper presents the possibilities of using evolutionary algorithms to solve the problem of optimizing the operation modes of electric power facilities in the presence of constraints in the form of inequalities and equalities. The limits of constraints have a variable character, depending on the generated and consumed energy. Existing methods used for the optimization of modes are based on general principles and approaches to optimization, which usually adapt to the specifics of the problem. In electric power facilities, optimization problems have some peculiarities, among which is the presence of multiple constraints applied to both independent and dependent variables. Many …

Challenges In Optimization For The Performance On Sustainability Dimensions In Reverse Logistics Social Responsibility, Sumarsono Sudarto, Katsuhiko Takahashi, Mochammad Dewo

Makara Journal of Technology

Reverse logistics social responsibility is preferred as the most acceptable solution for addressing the challenges in stakeholders’ debate regarding social responsibility in supply chains because it involves as many actors as possible in the supply chain to perform social responsibility to achieve sustainability. This paper explores the challenges in achieving optimal policies in sustainability dimensions for collection and recycling facilities in reverse logistics. Sustainability dimensions include economic, environmental, and social aspects. The reverse logistics is modeled on System Dynamics, and a simplified statistical analysis using a contour chart is employed in numerical experiments. Results show a narrow area of optimal …

Investigating The Rheological Behavior Of A Simple Yield Stress Fluid Under Shear Flows, Francesco Accetta

Theses

Many soft materials display unique and complex rheological behavior characterized by a transition from a solid-like to a fluid-like state upon the application of a force that exceeds the threshold to flow, known as the yield stress. Yield stress fluids are found in a wide range of commonly encountered materials including microgels, emulsions, and foams, and have been widely studied by rheologists over the last several decades. Carbopol is a popular polymeric microgel system as it displays simple, non-thixotropic rheological behavior and is typically seen as an ideal yield stress fluid. Previous research has demonstrated the reproducible behavior of shear …

Optimization Of A Bioreactor, Ali Alshami

AI Assignment Library

The primary objective of this assignimentis to learn to work effectively as a team, and to design an experiment where optimization is essential.

Bacterial Extraction And Concentration From Blood Through Filtration Processes, Ryan L. Wood, Rebecca Prymak, Evelyn Welling, Alayna Bedwell, Jordan T. Wood, Damian E. Teasley, Magdalena Crofts, Hope Callister Anderson, Clifton M. Anderson, W Cameron Beard, Jacob Stepan, Alexandra Carter, William G. Pitt

Faculty Publications

Blood stream infections (BSIs) are challenging to rapidly and precisely diagnose. Current clinical diagnostic methods for BSI identification require culturing the blood sample for many hours prior to identifying the bacteria and possible antibiotic resistance. Removing the culturing step from the bacterial identification process of a BSI provides a significant reduction in the processing time, but shifts the rate-limiting step from the growth time to the concentration procedure, since CFU levels in clinical blood samples can be as low as 10 CFU/mL in blood. This study developed a novel whole blood filtration method to concentrate bacteria from a BSI without …

Synthesis And Evaluation Of Organic Additives For Copper Electroplating Of Interconnects, Yue-Hui Zhai, Yi-Xiao Peng, Yan Hong, Yuan-Ming Chen, Guo-Yun Zhou, Wei He, Peng-Ju Wang, Xian-Ming Chen, Chong Wang

Journal of Electrochemistry

Copper interconnects are essential to the functionality, performance, power efficiency, reliability, and fabrication yield of electronic devices. They are widely found in chips, packaging substrates and printed circuit boards, and are often produced by copper electroplating in an acidic aqueous solution. Organic additives play a decisive role in regulating copper deposition to fill microgrooves, and micro-vias to form fine lines and interlayer interconnects. Generally, an additive package consists of three components (brightener, suppressor, and leveler), which have a synergistic effect of super-filling on electroplating copper when the concentration ratio is appropriate. Many works of literature have discussed the mechanism of …

Transferrin-Targeted Liposomes In Glioblastoma Therapy: A Review, Paul Kawak, Nour M Al Sawaftah, William G. Pitt, Ghaleb A. Husseini

Faculty Publications

Glioblastoma (GBM) is a highly aggressive brain tumor, and its treatment is further complicated by the high selectivity of the blood–brain barrier (BBB). The scientific community is urgently seeking innovative and effective therapeutic solutions. Liposomes are a promising new tool that has shown potential in addressing the limitations of chemotherapy, such as poor bioavailability and toxicity to healthy cells. However, passive targeting strategies based solely on the physicochemical properties of liposomes have proven ineffective due to a lack of tissue specificity. Accordingly, the upregulation of transferrin receptors (TfRs) in brain tissue has led to the development of TfR-targeted anticancer therapeutics. …

Hydrodynamic Voltammetry Of Fe2+/3+ In Aqueous Deep Eutectic Solvents Towards Redox Flow Batteries, Desiree Mae Prado, Xiaochen Shen, Robert Savinell, Clemens Burda

Faculty Scholarship

Deep eutectic solvents (DESs) have recently attracted much attention as potential green electrolyte solvents for redox flow batteries. DESs are considered not only as environmentally sustainable but also economically attractive electrolytes because they can be resourced from biological feedstock (alcohols, urea, choline) and are earth-abundant and of low toxicity. Despite these advantages, DESs still have limitations in important aspects such as reactant and ion transport, which is inhibited due to hydrogen-bonding-induced viscosity. Thus, improving the transport properties of redox species in DESs is essential. In addition, we explore the quantitative addition of water to ethaline (a 1:2 choline chloride: ethylene …

Recommended Separation Distances For 1.3 Ammunition And Explosives, Clint Guymon, Ming Liu, Josephine Covino

Faculty Publications

Separation Distances are used throughout the world to protect people and assets from the potential hazardous effects from propellants, explosives, and pyrotechnics. The current separation distances for Hazard Division (HD) 1.3 substances and articles used in the United States, in some cases, may not adequately protect against the effects from heat flux and debris when those substances and articles are ignited in a confined structure. Multiple tests in such a confined scenario with HD 1.3 substances have shown that the heat flux and debris hazards could result in injury at distances beyond the current specified explosives safety separation distance (ESSD). …

The Fabrication Of Nearly Monodisperse Chiral And Achiral Plasmonic Nanostructures And Their Applications, Macayla J. Caso

LSU Doctoral Dissertations

An object is chiral when it holds no lines of symmetry. This quality naturally occurs in chemistry and biology. When an object is chiral it has a unique handedness and objects of opposite chirality are called enantiomers. The importance of handedness was brought to light in the 1960’s when a racemic mixture of thalidomide enantiomers was given to pregnant women. One enantiomer was able to treat morning sickness while the other caused severe birth defects. This case brought to light how enantiomers have unique properties from each other even though they are similar materials. With this knowledge chiral nanomaterials must …

Retracted: Fabrication And Characterization Of Wood Fiber Reinforced Polymer Composites, Firoz Ahmed, Omar Faroque, Saif Hasan, Khan Rajib Hossain, Rezaul Karim Sheikh

Al-Bahir

Wood-polymer composites (WPCs) combine the properties of wood and polymers. Creating composites involves adding plant or wood fibers as fillers to a polymer matrix. This study used mahogany and mango wood sawdust as reinforcement materials, while high-density polyethylene (HDPE) and polyvinyl chloride (PVC) were used as matrices. The investigated data in this study comprises four different (10, 20, 30, and 40) weight percentages (wt%) of mahogany and mango sawdust paired with corresponding wt% (90, 80, 70, and60) of HDPE and PVC matrices. The extrusion method produced composites with different amounts of sawdust and polymer matrices. Wood polymer composites were characterized …

Ph Gradients In Spatially Non-Uniform Ac Electric Fields Around The Charging Frequency; A Study Of Two Different Geometries And Electrode Passivation, Azade Tahmasebi, Sanaz Habibi, Jeana Collins, Ran An, Esmaeil Dehdashti, Adrienne Minerick

Michigan Tech Publications

Dielectrophoresis (DEP), a precision nonlinear electrokinetic tool utilized within microfluidic devices, can induce bioparticle polarization that manifests as motion in the electric field; this phenomenon has been leveraged for phenotypic cellular and biomolecular detection, making DEP invaluable for diagnostic applications. As device operation times lengthen, reproducibility and precision decrease, which has been postulated to be caused by ion gradients within the supporting electrolyte medium. This research focuses on characterizing pH gradients above, at, and below the electrode charging frequency (0.2–1.4 times charging frequency) in an aqueous electrolyte solution in order to extend the parameter space for which microdevice-imposed artifacts on …

Simultaneous Multistep Transformer Architecture For Model Predictive Control, Junho Park, Mohammad Reza Babaei, Samuel Arce Munoz, Ashwin N. Venkat, John Hedengren

Faculty Publications

Transformer neural networks have revolutionized natural language processing by effectively addressing the vanishing gradient problem. This study focuses on applying Transformer models to time-series forecasting and customizing them for a simultaneous multistep-ahead prediction model in surrogate model predictive control (MPC). The proposed method showcases improved control performance and computational efficiency compared to LSTM-based MPC and one-step-ahead prediction models using both LSTM and Transformer networks. The study introduces three key contributions: (1) a new MPC system based on a Transformer time-series architecture, (2) a training method enabling multistep-ahead prediction for time-series machine learning models, and (3) validation of the enhanced time …

Engineering Multifunctional Adhesive Hydrogel Patches For Biomedical Applications, Aishik Chakraborty, Shana Alexander, Wei Luo, Narisse Al-Salam, Mia Van Oirschot, Sudhir H. Ranganath, Subrata Chakrabarti, Arghya Paul

Chemical and Biochemical Engineering Publications

Traditional patches, such as sticking plaster or acrylic adhesives used for over a hundred years, lack functionality. To address this issue of poor functionality, adhesive hydrogel patches have emerged as an efficient bioactive multifunctional alternative. Hydrogels are three-dimensional, water-swellable, and polymeric materials closely resembling the native tissue architecture. The physicochemical properties of hydrogels can be modified easily, allowing them to be suitable for various biomedical applications. Moreover, adhesive properties can be imparted to hydrogels through physicochemical manipulations, making them ideal candidates for supplementing or replacing traditional sticking plaster. As a result, sticky hydrogel patches are widely used for transdermal drug …

Determination Of A Surrogate For Plutonium Electrorefining, Greg Chipman, Bryant Johnson, Suhee Choi, Chao Zhang, Michael Simpson, Devin Rappleye

Faculty Publications

Conducting research experiments on plutonium electrorefining is difficult due to the significant hazards and regulations associated with nuclear materials. Finding a surrogate for plutonium electrorefining studies would enable more fundamental research to be conducted. Potential surrogates were first identified by determining the physical properties required to conduct electrorefining at the same conditions commonly used in plutonium electrorefining, a molten metal and molten CaCl₂ at 1123 K. Ce-CeCl₃, In-InCl₃, and Pb-PbCl₂ were the only potential surrogates identified using these constraints. Sn-SnCl₂ was also tested at these same conditions. More potential surrogates were identified by …