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Articles 181 - 210 of 14230

Full-Text Articles in Chemical Engineering

Nanofluid Flooding As A Sufficient Alternative To Waterflooding For Incremental Oil Recovery From Carbonate Reservoirs, Sarmad Al-Anssari, Dhifaf Sadeq, Hassanain A. Hassan, Ahmed Hamid Al-Taie, Hasan Ali Abood, Mohammed Mahdi, Zain Ul Abedin Arain Jun 2026

Nanofluid Flooding As A Sufficient Alternative To Waterflooding For Incremental Oil Recovery From Carbonate Reservoirs, Sarmad Al-Anssari, Dhifaf Sadeq, Hassanain A. Hassan, Ahmed Hamid Al-Taie, Hasan Ali Abood, Mohammed Mahdi, Zain Ul Abedin Arain

Research outputs 2022 to 2026

Oil recovery from carbonate reservoirs is one of the critical challenges in the oil industry due to the strongly oil-wet nature, natural fractures, and the heterogeneity of carbonate rocks. Subsequently, waterflooding can only displace oil from large fractures, leaving the majority of oil trapped in the rock matrix. This work suggests that nanofluid flooding, as a predesigned flooding method, is an alternative to conventional waterflooding. Various concentrations of silica nanofluid at different nanoparticle concentrations were formulated and systematically investigated for their characteristics, stability at reservoir conditions, and their influence on wettability and oil recovery. Silica nanoparticles were sustainably synthesized from …


Glass Transition Temperature Of Plga Nanoparticles And The Application In Drug Delivery, Guangliang Liu May 2026

Glass Transition Temperature Of Plga Nanoparticles And The Application In Drug Delivery, Guangliang Liu

Dissertations

The glass transition temperature (Tg) of poly(D,L-lactic-co-glycolic acid) (PLGA) nanoparticles plays a crucial role in governing molecular mobility, diffusion, and consequently, drug release kinetics. However, the interaction among residual surfactant, drug effect, nanoscale confinement, and release medium on Tg remains insufficiently characterized. This study aims to bridge this gap by correlating the thermal behavior of PLGA nanoparticles with their drug release behavior under physiologically relevant conditions.

In the present study, PLGA nanoparticles were synthesized using both nano-emulsion and surfactant-free nano-precipitation approaches. The influence of residual surfactants - poly(vinyl alcohol) (PVA) and didodecyldimethylammonium bromide (DMAB) - was systematically …


Membrane-Engineered Nanotherapeutic Platforms For Drug Delivery: Hollow Fiber Membrane Synthesis Of Lipid Nanoparticles, Biomimetic Nanocarriers, And Nanobubbles, Zhixiang Liu May 2026

Membrane-Engineered Nanotherapeutic Platforms For Drug Delivery: Hollow Fiber Membrane Synthesis Of Lipid Nanoparticles, Biomimetic Nanocarriers, And Nanobubbles, Zhixiang Liu

Dissertations

Lipid-based nanocarriers have emerged as a cornerstone technology for RNA therapeutics, enabling effective intracellular delivery for applications ranging from vaccination to gene regulation. However, current manufacturing approaches, particularly microfluidic-based platforms, face inherent limitations in scalability, throughput, and structural tunability due to their reliance on confined channel geometries and restricted mixing architectures. Addressing these challenges requires fundamentally new strategies that decouple nanoparticle formation from traditional microscale flow constraints while maintaining precise control over physicochemical properties.

This dissertation presents a comprehensive framework for the design, engineering, and application of advanced lipid-based nanocarriers, centered on a hollow fiber membrane (HFM)—assisted nanopore-mediated assembly platform. …


Machine Learning-Driven Prediction And Mechanistic Insight Into Co2 Adsorption On Biomass-Derived Activated Carbons Using Explainable Ai (Xai), Dalia A. Ali Dr. May 2026

Machine Learning-Driven Prediction And Mechanistic Insight Into Co2 Adsorption On Biomass-Derived Activated Carbons Using Explainable Ai (Xai), Dalia A. Ali Dr.

Chemical Engineering

To improve CO2 uptake in Biomass-Derived Activated Carbon (BDAC), this study develops a multiscale hybrid digital twin framework. By integrating microscopic descriptors from Density Functional Theory and Molecular Dynamics (DFT/MD) with experimental data from 63 chemically diverse biomass precursors, a Gaussian Process Regression (GPR) model was developed using the Materń 5/2 Automatic Relevance Determination (ARD) kernel. The framework achieved high internal training accuracy (R2 = 0.968) and Root Mean Square Error (RMSE = 0.2552), while providing a realistic generalization baseline across heterogeneous precursors with a 5-fold Cross Validated (CV) R2 of 0.1567 and CV RMSE of 0.283. Explainable Artificial Intelligence …


Modulating Electronic Structure With Linearly Fused Pyrazine Units For High-Voltage And Stable Zinc-Organic Batteries Cathode, Min-Jian Zhao, Li-Bin Zhang, Jin-Tao Wang, Kun Ding, Hai-Mei Liu, Yong-Gang Wang May 2026

Modulating Electronic Structure With Linearly Fused Pyrazine Units For High-Voltage And Stable Zinc-Organic Batteries Cathode, Min-Jian Zhao, Li-Bin Zhang, Jin-Tao Wang, Kun Ding, Hai-Mei Liu, Yong-Gang Wang

Journal of Electrochemistry

High-voltage n-type organic cathode materials are critical for constructing zinc-organic batteries (ZOBs) with high energy density and long cycle life. However, the intrinsically unfavorable electronic structures and relatively high LUMO energy levels of most n-type materials often lead to sluggish kinetics, high solubility, and suboptimal discharge voltages (< 0.8 V). Here, we design a small molecule, quinoxalino[2’,3’:5,6]pyrazino[2,3-f][1,10]phenanthroline (DPQP), as a ZOB cathode by introducing locally electron-deficient motifs into the conjugated backbone of aromatic compounds. The linearly fused pyrazine units extending the pyrazine–benzene framework effectively optimize the electronic structure, thereby significantly enhancing the discharge voltage. Meanwhile, the expanded π-conjugated plane suppresses dissolution and accelerates charge-transfer kinetics. Benefiting from these features, the DPQP electrode exhibits an exceptional increase in average operating voltage from 0.61 V to 1.07 V (vs. Zn2+/Zn) at 0.1 A·g–1, with an overpotential of only 140 mV. Notably, no discernible voltage decay occurs as the current density increases, indicating rapid and highly reversible redox kinetics. Furthermore, the DPQP cathode delivers outstanding cycling stability, maintaining over 2000 h of continuous operation at 0.1 A·g–1 …


(Co,Ni,Mn,Cu,Zn)O High-Entropy Oxide Nanotubes As Efficient Bifunctional Electrocatalyst For Oxygen Evolution And Hydrazine Oxidation Reactions, Pan-Yan Chen, Wan-Wan Wu, Heng Bian, Wei-Wei Li, Xin-Sheng Zhao, Lu Wei May 2026

(Co,Ni,Mn,Cu,Zn)O High-Entropy Oxide Nanotubes As Efficient Bifunctional Electrocatalyst For Oxygen Evolution And Hydrazine Oxidation Reactions, Pan-Yan Chen, Wan-Wan Wu, Heng Bian, Wei-Wei Li, Xin-Sheng Zhao, Lu Wei

Journal of Electrochemistry

High-entropy oxides (HEOs) present significant scientific challenges in both design and synthesis due to their multielement and high-entropy nature, which involves complex combinations of multiple metal cations and oxygen anions, typically arranged in equimolar ratios to achieve structural stability. Herein, one-dimensional (Co,Ni,Mn,Cu,Zn)O high-entropy oxide nanotubes (HEO-NTs) are fabricated by means of a gradient electrospinning strategy with a tailored polyvinyl alcohol (PVA) molecular weight distribution and controlled pyrolysis. Benefiting from the HEO features and the synergistic effect of multicomponent sites, the as-synthesized (Co,Ni,Mn,Cu,Zn)O HEO-NTs exhibit exceptional bifunctional electrocatalytic activity for the oxygen evolution and hydrazine oxidation reactions (OER/HzOR). This study offers …


The Effects Of Solutes On The Growth Of Crystals In Polycrystalline Ice ​, Roberto Nieto Jr, Chinazom Onubogu, Ian Baker May 2026

The Effects Of Solutes On The Growth Of Crystals In Polycrystalline Ice ​, Roberto Nieto Jr, Chinazom Onubogu, Ian Baker

Wetterhahn Science Symposium Posters

The structure of sea ice (NaCl-doped water) differs from freshwater ice. In this project, we will be investigating how ice grows when doped with various solutes such as sodium chloride and sulfuric acid. There are two projects that were investigated. The first project consisted of finding the velocity of the ice growth of deionized water, saltwater, and water doped with sulfuric acid. The second project consisted of observing how the polycrystalline structure of ice differs between deionized water, saltwater, and water doped with sulfuric acid.


Zirconium Metal-Organic Cages: Synthetic Development Of Chromium-Functionalized Ligands, Jim P. Heller, Jonathan E. Pines, Miguel I. Gonzalez May 2026

Zirconium Metal-Organic Cages: Synthetic Development Of Chromium-Functionalized Ligands, Jim P. Heller, Jonathan E. Pines, Miguel I. Gonzalez

Wetterhahn Science Symposium Posters

Metal-organic cages (MOCs) are a class of highly porous molecules composed of inorganic clusters bridged by highly tunable organic ligands. The synthesis and development of various ligands could allow for more selective and efficient catalysts. Specifically, Chromium-based homogeneous catalysts have recently been commercialized due to their high selectivity in the production of 1-hexene and 1-octene. This project aims to synthesize reusable heterogeneous catalysts composed of chromium-functionalized zirconium MOCs deposited on mesoporous supports.

The current focus of this project is to synthesize and purify the "SNS Ligand." This ligand can coordinate to chromium via its S—N—S moiety. This project specifically focuses …


How Fe(Ii)/2-Oxoglutarate Oxygenase Chooses Chlorination Over Hydroxylation: Electric Field-Driven Ligand Exchange Governs C-Cl Formation, Simahudeen Bathir Jaber Sathik Rifayee, Midhun George Thomas, Anandhu Krishnan, Kritika Gupta, Carter Davis, Tatyana Karabencheva-Christova, Christo Z. Christov May 2026

How Fe(Ii)/2-Oxoglutarate Oxygenase Chooses Chlorination Over Hydroxylation: Electric Field-Driven Ligand Exchange Governs C-Cl Formation, Simahudeen Bathir Jaber Sathik Rifayee, Midhun George Thomas, Anandhu Krishnan, Kritika Gupta, Carter Davis, Tatyana Karabencheva-Christova, Christo Z. Christov

Michigan Tech Publications

Non-heme Fe(II)/2-oxoglutarate (2OG)-dependent halogenases catalyze highly selective C-H halogenation. BesD is a non-heme Fe(II)/2OG halogenase that performs regio- and stereoselective chlorination of the l-lysine (l-Lys) substrate. Understanding the mechanism by which halogenation is favored over canonical hydroxylation is essential for guiding enzyme engineering efforts aimed at converting hydroxylases into halogenases. Here, we combine molecular dynamics (MD) and hybrid quantum mechanics/molecular mechanics (QM/MM) calculations to elucidate the origin of chlorination selectivity in BesD and variants derived from a homologous hydroxylase. Our results indicate that, although the initial inline Cl-Fe(III)-OH intermediate is inherently predisposed toward hydroxylation, it undergoes a two-step isomerization in …


Polymer-Derived Silicon Oxycarbide (Sioc) And Silicon Carbonitride (Sicn) Ceramics For Advanced Electrochemical Energy Storage Applications, Saja Al Ajrash, Erick S. Vasquez-Guardado May 2026

Polymer-Derived Silicon Oxycarbide (Sioc) And Silicon Carbonitride (Sicn) Ceramics For Advanced Electrochemical Energy Storage Applications, Saja Al Ajrash, Erick S. Vasquez-Guardado

Chemical and Materials Engineering Faculty Publications

Preceramic polymers, especially silicon oxycarbide (SiOC) and silicon carbonitride (SiCN) ceramics, have gained significant attention due to their wide range of applications in many fields, particularly in energy storage devices beyond conventional lithium-ion batteries (LIBs). This review focuses on the synthesis, structural characteristics, and properties of SiOC and SiCN ceramics as electrodes for battery applications. Furthermore, their promising applications as electrode materials for energy storage systems are explored, along with the most recent advances in the development of such materials and their use in lithium-ion batteries (LIBs), lithium-sulfur batteries (LSBs), potassium-ion batteries (PIBs), sodium-ion batteries (SIBs), and supercapacitors. This review …


Techno-Economic Assessment And Life Cycle Analysis Of Electrocatalytic Reduction Of Co2 To Ethanol., Omotolani Elizabeth Oduyebo May 2026

Techno-Economic Assessment And Life Cycle Analysis Of Electrocatalytic Reduction Of Co2 To Ethanol., Omotolani Elizabeth Oduyebo

LSU Master's Theses

This study presents a techno-economic analysis (TEA) and life cycle assessment (LCA) of the electrocatalytic reduction of CO₂ to ethanol, a multi-carbon (C2) product with significant market value. Prior TEA studies have relied on simplified lump-sum separation cost estimates, and prior LCA studies have rarely examined the combined effect of CO₂ source and electricity supply on carbon intensity gaps that this work addresses through process-simulation-grounded analysis. An Aspen Plus process simulation was developed for an anion-exchange membrane (AEM) electrolyzer system coupled with an extractive distillation separation train using ethylene glycol as the entrainer, achieving 99.9 wt.% ethanol purity …


Nuclear Deterrence: Enhancing The Mission Through Smart Factory Predictive Solutions, Jarrod Matthew Ronquillo May 2026

Nuclear Deterrence: Enhancing The Mission Through Smart Factory Predictive Solutions, Jarrod Matthew Ronquillo

Chemical and Biological Engineering ETDs

To meet the stewardship and modernization initiatives set by the Department of Energy new technologies must enter the manufacturing facilities within the nuclear deterrent complex. Predictive solutions begin with collecting data. An equipment health monitoring device was created to streamline data collection and organization for equipment and processes. A predictive and process performance dashboard was developed for a deionized water system. The dashboard used Western Electric statistical process rules and a machine learning regression algorithm to predict when the resistivity would fall out of specification. Lastly, a remaining useful life calculation was developed for all equipment related to nuclear deterrent …


Technical Advancements In Single-Molecule Spectroscopy For High-Throughput Measurement Of Long-Time Dynamics, Quyen B. Le May 2026

Technical Advancements In Single-Molecule Spectroscopy For High-Throughput Measurement Of Long-Time Dynamics, Quyen B. Le

Chemical and Biological Engineering ETDs

Single-molecule fluorescence spectroscopy is a powerful technique for resolving transient biomolecular dynamics and quantifying free energy landscapes, kinetics, and binding interactions. However, two fundamental limitations restrict its broader application: slow, labor-intensive data acquisition and the limited observation time imposed by fluorophore photobleaching. These limitations hinder its use in drug discovery and biomedical engineering applications that require both high-throughput and access to long-time dynamics. In this work, both challenges are addressed through technical advancements. First, a simple, generalizable approach is introduced to automate data acquisition, eliminating manual intervention during experiments. This increases the acquisition rate by more than an order of …


Machine Learning Approaches For Predicting Biochemical Oxygen Demand And Ammonium Nitrogen: A Decade-Long Weekly Field Study At A Full-Scale Water Resource Recovery Facility, Hoda Khoshvaght, Ratish Ramyad Permala, Amir Razmjou, Mehdi Khiadani May 2026

Machine Learning Approaches For Predicting Biochemical Oxygen Demand And Ammonium Nitrogen: A Decade-Long Weekly Field Study At A Full-Scale Water Resource Recovery Facility, Hoda Khoshvaght, Ratish Ramyad Permala, Amir Razmjou, Mehdi Khiadani

Research outputs 2022 to 2026

Unlike previous studies that rely on high-frequency (15-min or hourly) datasets, this study is among the first to use low-frequency (weekly) data to evaluate the performance of linear and nonlinear machine learning (ML) algorithms for predicting biochemical oxygen demand (BOD) and ammonium nitrogen (NH4+-N) in the primary and secondary treatment effluents from the Subiaco Water Resource Recovery Facility (WRRF) in Western Australia. Various feature selection methods, including filters, wrappers, and embedded methods, were employed to identify the most effective approach that achieves the highest model performance while enhancing computational efficiency. The results demonstrate that a reduced set of …


Sorption And Thermal Conductivity Of Concrete Containing Aggregates Of E-Waste, Rakesh Kumar Saini, Praveen Kumar May 2026

Sorption And Thermal Conductivity Of Concrete Containing Aggregates Of E-Waste, Rakesh Kumar Saini, Praveen Kumar

Journal of Sustainable Construction Materials and Technologies

In many parts of the world, substantial energy is used to maintain comfortable temperatures in inner parts of the buildings for living and working. Construction materials with low thermal conductivity, if used in the exterior walls and façade etc. in such structures can be useful in lowering the energy demand. On the other hand, moisture ingress through sorption is a common factor contributing in degradation of concrete structures with time. Constituents of concrete may be engineered to some extent to get both the desired attributes, lower thermal conductivity and sorption than normal concrete. The rapid increase in electronic waste, or …


High-Surface-Area Ficus Leaf-Extracted Cuo-Zno-Nio Ternary Nanocomposites For Rapid Adsorption-Assisted Uv-A Degradation Of Direct Blue 15, Kafa’A H. Ali, Mohammed A. Atiya, Ahmed K. Hassan May 2026

High-Surface-Area Ficus Leaf-Extracted Cuo-Zno-Nio Ternary Nanocomposites For Rapid Adsorption-Assisted Uv-A Degradation Of Direct Blue 15, Kafa’A H. Ali, Mohammed A. Atiya, Ahmed K. Hassan

Karbala International Journal of Modern Science

Direct Blue 15 (DB15) is a long-lasting synthetic dye that pollutes water and is difficult to remove during wastewater treatment. Conventional treatments fail to remove DB15 adequately due to rapid electron-hole recombination, which necessitates photocatalysts with reduced recombination rates for effective dye removal. The study aims to synthesize and evaluate a CuO-ZnO-NiO ternary system as an integrated adsorption and UV-A photocatalysis platform for DB15 removal. Ficus leaf-extracted CuO-ZnO-NiO nanocomposites with four Cu:Zn:Ni ratios (1:1:1, 1:1:2, 1:2:1, 2:1:1) were prepared by co-precipitation, followed by extensive chemical and physical characterization and dye-removal performance measurements. The CuO-ZnO-NiO nanocomposite exhibited hexagonal zinc oxide, cubic …


Valorization Of Ductile Cast Iron Solid Waste As A High-Performance Adsorbent For Crystal Violet Removal: Characterization, Optimization, And Mechanistic Insights, Ibrahim Ibrahim Mr., Abdel Mohsen Turky Dr., Nasser Mostafa Prof., Mai H. Roushdy May 2026

Valorization Of Ductile Cast Iron Solid Waste As A High-Performance Adsorbent For Crystal Violet Removal: Characterization, Optimization, And Mechanistic Insights, Ibrahim Ibrahim Mr., Abdel Mohsen Turky Dr., Nasser Mostafa Prof., Mai H. Roushdy

Chemical Engineering

Industrial textile wastewater containing synthetic dyes cause serious environmental and health risk, whereas ductile cast iron (DCI) foundries generate over 500 000 tons of waste annually. This study utilizes DCI solid waste as an adsorbent to remove the crystal violet (CV) dye from wastewater. Techniques (XRF, XRD, BET, SEM-EDX, FTIR, TGA-DTG, zeta potential) proved that the waste contains 88.0 wt% periclase (MgO) with nanoscale, high surface area, and abundant surface hydroxyl groups. Response surface methodology showed that the most significant parameters were the adsorbent dose and time contact. The optimal conditions give 93.7% removal efficiency at initial concentration: 38.7 mg …


The Design And Optimization Of A Styrene Production Plant, Kaylee Hardenstein, Amanda Anderson May 2026

The Design And Optimization Of A Styrene Production Plant, Kaylee Hardenstein, Amanda Anderson

Honors Theses

This thesis presents the design and economic optimization of a Styrene Production Plant targeting a capacity of 100,000 tonnes/yr at a product purity of 99.8 wt%. The process relies on the dehydrogenation of ethylbenzene in a packed-bed reactor system. Downstream separation is achieved through a series of cooling, phase separation, and distillation operations to recover styrene while recycling unreacted ethylbenzene and recovering valuable byproducts.

A base case design was developed and evaluated using a process simulation software, Aspen Plus V14, and an economic analysis. Sensitivity analysis identified the styrene market price and ethylbenzene raw material cost as the dominant factors …


The Design And Manufacturing Process Of The Concealed Shelf, Mexrojiddinbek Sattorov May 2026

The Design And Manufacturing Process Of The Concealed Shelf, Mexrojiddinbek Sattorov

Honors Theses

This document contains information regarding the design and build process of the Concealed Shelf, which is a furniture product with hidden storage capability. First, the team members decided on the design of the product, followed by market analysis and manufacturing feasibility. Lean manufacturing principles were applied to improve the process efficiency and reduce waste.

Multiple prototypes were built with varying raw materials and locking mechanisms. Jigs and fixtures were handcrafted to ensure more consistent product quality. Two production runs were conducted to evaluate performance and identify areas for improvement.

The final design includes economic considerations, manufacturing layout, and continuous improvement …


Optimization And Safety Protocols For An Acetone Production Plant, Holley J. Garrison May 2026

Optimization And Safety Protocols For An Acetone Production Plant, Holley J. Garrison

Honors Theses

The proposed acetone production plant, scheduled for start-up in 2028, is capable of producing 3,750 kg/h of 99.9 wt% acetone. Using an endothermic catalytic dehydrogenation reaction, a feed of isopropyl alcohol (IPA) is reacted to produce 30,000 metric tons per year (MT/y) of acetone. Initial design and economic analysis of this process found that this plant will not be economically viable due to its Net Present Value (NPV) of -$132M. Optimization efforts prioritized reductions in raw materials and improved product recovery. Several optimizations were performed to reduce the feed rate, including switching to the low temperature catalyst, shortening the reactor …


Synthesis And Investigation Of Tungsten–Copper Oxide Composites For Enhanced Photocatalytic Applications, Janak Paudel, John Nichols May 2026

Synthesis And Investigation Of Tungsten–Copper Oxide Composites For Enhanced Photocatalytic Applications, Janak Paudel, John Nichols

Research and Creative Works Expo

No abstract provided.


Response Surface Modelling And Multi-Objective Optimisation Of Asphalt Binder And Mixture Properties Modified With Reclaimed Automotive Lubricants And Waste Glass Bottle Powder, Nura Shehu Aliyu Yaro, Jacob Adedayo Adedeji, Luvuno Nkosinathi Jele, Nasir Khan, Aliyu Usman, Jacob Olumuyiwa Ikotun May 2026

Response Surface Modelling And Multi-Objective Optimisation Of Asphalt Binder And Mixture Properties Modified With Reclaimed Automotive Lubricants And Waste Glass Bottle Powder, Nura Shehu Aliyu Yaro, Jacob Adedayo Adedeji, Luvuno Nkosinathi Jele, Nasir Khan, Aliyu Usman, Jacob Olumuyiwa Ikotun

Journal of Sustainable Construction Materials and Technologies

Large volumes of reclaimed automotive lubricant (RAL) and waste glass bottle powder (WGBP) are disposed of inappropriately, causing serious environmental concerns. Furthermore, the paradigm shift towards sustainability in the pavement industry has prompted academics to investigate alternatives to conventional materials. As a result, one possible approach is to use these waste products as alternative materials in the asphalt pavement sector. This study investigated the combined use of RAL and WGBP as complementary modifiers, extending beyond the conventional single-modifier approaches reported in previous studies. Thus, in this study, response surface methodology (RSM) was utilised to optimise and predict the synergistic effects …


Optimization And Dynamic Control Of Acetone Production From Isopropyl Alcohol, Thomas W. Wasson May 2026

Optimization And Dynamic Control Of Acetone Production From Isopropyl Alcohol, Thomas W. Wasson

Honors Theses

This paper investigates the optimization and dynamic control of acetone production via catalytic dehydrogenation of isopropyl alcohol. Optimization was conducted using steady-state Aspen Plus modeling with product specifications of 30,000 metric tons per year of 99.9% pure acetone by weight. Dynamic modeling of the feed preparation and reaction portions of the process was conducted in Aspen Plus Dynamic. Through optimization efforts the primary economic factor, net present value (NPV), was increased from $(126.6) million to $(83.2) million, representing a $43.4 million increase. This was primarily accomplished through a switch to low temperature catalyst, optimization of reactor dimensions, pressurization of key …


Study Of Pv Panel Degradation Under Extreme Weathering Within Uae Climate Conditions, Maitha Abdulla Almheiri May 2026

Study Of Pv Panel Degradation Under Extreme Weathering Within Uae Climate Conditions, Maitha Abdulla Almheiri

Thesis/ Dissertation Defenses

The thesis studies monocrystalline and polycrystalline photovoltaic modules under desert operating conditions. The study uses long term outdoor exposure at the UAEU Falaj Hazza campus. Dust deposition, strong temperature variation, and high irradiance shape field performance at the site. The work sets three objectives. Track performance degradation over time. Identify dominant loss mechanisms. Define maintenance strategies supported by experimental data and field observations. The experimental plan uses two module groups. A reference group receives daily cleaning. A test group stays uncleaned across several weeks of exposure. A monitoring system records electrical outputs such as current, voltage, and power. The same …


Design Of Air-Entrained Concrete For Airport Pavements Through Local Aggregate Utilization: Performance Optimization And Economic Analysis, Li Wentao, Rizwan Qadir, Arslan Mushtaq, Hilal Khan, Kamran Jillani May 2026

Design Of Air-Entrained Concrete For Airport Pavements Through Local Aggregate Utilization: Performance Optimization And Economic Analysis, Li Wentao, Rizwan Qadir, Arslan Mushtaq, Hilal Khan, Kamran Jillani

Journal of Sustainable Construction Materials and Technologies

Airport pavement construction in developing countries faces critical challenges balancing international performance standards with economic constraints, while limited research exists on optimizing air-entrained concrete mixes using locally sourced materials for cost-effective solutions. This study investigated the development of economical air-entrained concrete mix designs for airport pavements utilizing Pakistani aggregates and systematic cement content optimization. Comprehensive experimental evaluation included material characterization through petrographic analysis, alkali-aggregate reactivity assessment via accelerated mortar bar testing, and mechanical property development across cement contents from 360-450 kg/m3. Air entrainment was achieved through controlled admixture dosing while maintaining target slump of 50mm. Results demonstrated that locally sourced …


Molybdenum-Doped Zinc Oxide Nanocomposite For Sustainable Photoelectrocatalytic Degradation Of Dyes And Antimicrobial Activity, Samar A. Salim May 2026

Molybdenum-Doped Zinc Oxide Nanocomposite For Sustainable Photoelectrocatalytic Degradation Of Dyes And Antimicrobial Activity, Samar A. Salim

Nanotechnology Research Centre

Mo-doped ZnO nanocomposite was synthesized by using auto-combustion method. X-ray diffraction patterns of prepared nanocomposite indicated effective construction of crystalline Mo/ZnO NCs with co-existence of MoO2 and ZnO in required weight ratio. XRD results revealed also that ZnO crystallite size decreased as Mo-doping concentration increased. The direct band gap reduced from 3.309 eV of (MZ-0) to 3.258 eV of (MZ-5), demonstrating a negative correlation with Mo-doping levels. The electrocatalytic activity of Mo/ZnO NCs was assessed by their capability to degrade Indigo Carmine (IC) and Murexide (ME) dyes, and their antibacterial properties were also evaluated. The electrocatalytic (EC) degradation efficiencies for …


Bridging Reaction Engineering And Polymers Design: Solvent Effects In Continuous Flow Copolymerization, Leila Ba May 2026

Bridging Reaction Engineering And Polymers Design: Solvent Effects In Continuous Flow Copolymerization, Leila Ba

Department of Chemical and Biomolecular Engineering: Dissertations, Theses, and Student Research

Poly(glycidyl methacrylate-co-methyl methacrylate) [poly(GMA-co-MMA)] is a promising functional copolymer for photoresist applications due to its reactive epoxy groups and tunable physicochemical properties. This thesis is focused on this polymer and integrates theoretical solubility prediction, thermodynamic modeling, and continuous-flow synthesis to establish quantitative structure–process–property relationships for their use in microelectronic-grade solvents.

Solubility behavior in dimethyl sulfoxide (DMSO), propylene glycol monomethyl ether (PGME), and propylene glycol monomethyl ether acetate (PGMEA) was investigated using the Hildebrand and Hansen models, Hoy group-contribution method, Polymer Genome machine-learning platform, and Flory–Huggins thermodynamic analysis of Gibbs free energy of mixing. Experimental saturation solubility measurements at 25 °C …


Turning Down The Heat: Fine-Tuning Tempo-Modified Nanocellulose And Emim-Ac Ionic Liquid Membranes For Kidney Dialysis, Olivia Reid May 2026

Turning Down The Heat: Fine-Tuning Tempo-Modified Nanocellulose And Emim-Ac Ionic Liquid Membranes For Kidney Dialysis, Olivia Reid

Chemical Engineering Undergraduate Honors Theses

TEMPO modified nanocellulose membranes are utilized across various laboratory and industrial applications from protein purification to advancements in kidney dialysis. This study investigates the effect of varying coagulation temperatures on the morphology and transport properties of these membranes to enhance their performance for targeted filtration. It was hypothesized that higher temperatures would accelerate the solvent-nonsolvent exchange during phase inversion, resulting in larger pore structures. Conversely, lower temperatures were expected to slow solvent diffusion, yielding smaller, more uniform pores. The membranes[JH1]  were synthesized using 2,2,6,6-tetramethylpiperidinyl-1-oxyl (TEMPO) to improve selectivity and antifouling characteristics. Scanning electron microscopy (SEM) served as the primary …


Strengthening Kidney Dialysis One Membrane At A Time: Enhancing Tempo-Oxidized Nanocellulose And Ionic Liquid Membrane Strength Through The Variation Of Cosolvents, Bailey M. Butler May 2026

Strengthening Kidney Dialysis One Membrane At A Time: Enhancing Tempo-Oxidized Nanocellulose And Ionic Liquid Membrane Strength Through The Variation Of Cosolvents, Bailey M. Butler

Chemical Engineering Undergraduate Honors Theses

Chronic kidney disease occurs when the kidneys lose the ability to effectively filter the blood, which causes waste build up. End-stage kidney disease (ESKD) is the most severe case of kidney disease and requires either dialysis or a kidney transplant. Hemodialysis, the most common form of dialysis, is an extremely time-intensive and physically burdensome process that is currently limited by membrane performance. The polysulfone (PSf) membranes that are widely used for dialysis today have many limitations, including fouling, toxin rejection, and essential protein loss. Recently, new membranes made from TEMPO-Oxidized nanocellulose dissolved in 1-ethyl-3-methylimidazolium acetate (EMIM-Ac) have shown promising characteristics, …


Shooting For The Stars: Stem Outreach Strategies Between 2nd And 7th Grade, Paige Miller May 2026

Shooting For The Stars: Stem Outreach Strategies Between 2nd And 7th Grade, Paige Miller

Chemical Engineering Undergraduate Honors Theses

Engineering and planetary science outreach programs are increasingly important as industries and research organizations face growing demand for STEM professionals. Despite the importance of these fields, many students receive little exposure to engineering careers during their early educational experiences. This honors thesis examines the effectiveness of interactive STEM outreach presentations designed for elementary and middle school students. Specifically, this study evaluates outreach activities centered on chemical engineering applications and the NASA M2M CO₂ regeneration project for Martian environments.

Two student age groups participated in this study: 2nd grade students at Butterfield Elementary School and 7th grade students at Woodland Junior …