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Articles 1321 - 1350 of 14041

Full-Text Articles in Chemical Engineering

Investigation Of Ethane Dehydrogenation And Hydrogenolysis On Pt(111), Pt(211) And Pt(100): Bayesian Quantification And Correction Of Dft-Based Enthalpic And Entropic Uncertainties, Mubarak Bello Jul 2024

Investigation Of Ethane Dehydrogenation And Hydrogenolysis On Pt(111), Pt(211) And Pt(100): Bayesian Quantification And Correction Of Dft-Based Enthalpic And Entropic Uncertainties, Mubarak Bello

Theses and Dissertations

Computational investigations of heterogeneously catalyzed reactions using density functional theory (DFT) are often inaccurate, largely due to uncertainties in the choice of DFT functional (enthalpic uncertainty) and approximations for modeling adsorbate movement along the catalyst surface (entropic uncertainty). This work illustrates that both uncertainties are significant in the investigation of the ethane dehydrogenation (EDH) and hydrogenolysis on Pt catalysts by considering the complete deconstruction of ethane on Pt(111), Pt(211), and Pt(100) using microkinetic modeling (MKM). Hence, this work uses both non-calibrated and Bayesian calibrated MKMs to quantify and correct inaccuracies in macroscopic properties due to both uncertainties. A Bayesian approach …


Exploring Shape Dependency Of Catalysts For Chemical Reactions, Kaveh Shariati Jul 2024

Exploring Shape Dependency Of Catalysts For Chemical Reactions, Kaveh Shariati

Theses and Dissertations

Recent advancements in the synthesis of nanoparticles, particularly one-dimensional (1D) nanoparticles, have significantly enhanced the catalytic activity of various processes by enabling precise control over their morphologies and exposing unique crystallographic facets. The shape of nanoparticles is closely linked to their chemical, physical, electrical, optical, magnetic, and catalytic properties. This dissertation investigates the impact of 1D nanoparticle catalysts on two distinct and well-known chemical reactions. In the first part of the study, we explore the catalytic activity and selectivity of silver catalysts in the ethylene epoxidation reaction, which are intrinsically linked to their faceting. Silver nanowire catalysts representing Ag(100) and …


Carbon-Based Nanocomposite Membranes For Membrane Distillation: Progress, Problems And Future Prospects, Chhabilal Regmi, Yuwaraj K. Kshetri, S. Ranil Wickramasinghe Jul 2024

Carbon-Based Nanocomposite Membranes For Membrane Distillation: Progress, Problems And Future Prospects, Chhabilal Regmi, Yuwaraj K. Kshetri, S. Ranil Wickramasinghe

Chemical Engineering Faculty Publications and Presentations

The development of an ideal membrane for membrane distillation (MD) is of the utmost importance. Enhancing the efficiency of MD by adding nanoparticles to or onto a membrane’s surface has drawn considerable attention from the scientific community. It is crucial to thoroughly examine state-of-the-art nanomaterials-enabled MD membranes with desirable properties, as they greatly enhance the efficiency and reliability of the MD process. This, in turn, opens up opportunities for achieving a sustainable water–energy–environment nexus. By introducing carbon-based nanomaterials into the membrane’s structure, the membrane gains excellent separation abilities, resistance to various feed waters, and a longer lifespan. Additionally, the use …


Simulation Of A Passive Osmosis-Integrated Electrolyzer For Seawater Electrolysis, Masoomeh Ghasemi Jul 2024

Simulation Of A Passive Osmosis-Integrated Electrolyzer For Seawater Electrolysis, Masoomeh Ghasemi

Theses and Dissertations

Efforts to develop direct seawater electrolysis technology have been ongoing due to the need for pure water in electrolysis and the abundance of seawater. However, progress has been hampered by several issues, including competition with the chlorine evolution reaction, higher membrane resistance, corrosion of electrodes, and scaling from multivalent cations [1]. To avoid these issues, our project has proposed a new reactor that integrates passive osmosis (extracting fresh water from seawater) with electrolysis. In this thesis, we will discuss the operation of the osmosis-integrated electrolyzer and show theoretical predictions of the osmotic pressure differential and water flux/velocity profiles under different …


Applications Of Catalytic Ammonia Chemistry: From Low-Pressure Ammonia Synthesis To The Decomposition Of Tritiated Ammonia As A By-Product Of Magnetically Confined Nuclear Fusion, Jennifer Kules Naglic Jul 2024

Applications Of Catalytic Ammonia Chemistry: From Low-Pressure Ammonia Synthesis To The Decomposition Of Tritiated Ammonia As A By-Product Of Magnetically Confined Nuclear Fusion, Jennifer Kules Naglic

Theses and Dissertations

Ammonia is the 2nd most produced chemical in the world with vital importance for its use in fertilizer as the global population has grown in accordance with the industrialization of NH3. While 80% of NH3 produced goes to fertilizer, it has gained attention recently as a hydrogen storage and transportation vessel. Industrially, NH3 is produced at high temperatures and pressures which in turn require high electrical input. Turning to a green NH3 cycle with low temperature and pressure membrane reactors for both NH3 synthesis and decomposition would allow for much lower energy input as well as a renewable energy to …


High–Strength Porous Tinbzrtafe Alloys Fabricated By Sintering Of Nanocomposite Powder Precursor With Space Holder Technique, Yuhua Li, Yuxin He, Rong Zhao, Libin Niu, Juxin Qu, Lai Chang Zhang Jul 2024

High–Strength Porous Tinbzrtafe Alloys Fabricated By Sintering Of Nanocomposite Powder Precursor With Space Holder Technique, Yuhua Li, Yuxin He, Rong Zhao, Libin Niu, Juxin Qu, Lai Chang Zhang

Research outputs 2022 to 2026

Although introducing high porosity in biomedical Ti alloys can reduce their elastic modulus and promote new bone ingrowth, relieving the stress–shielding effect and implant failure, this also causes a decline in the alloys’ mechanical strength. In this work, a new preparation method for the high–strength and high–porosity Ti65Nb23.33Zr5Ta1.67Fe5 (TNZTF, at.%) alloy was suggested by sintering nanocomposite powder precursor in combination with the use of a space holder technique, in which NH4HCO3 is adopted to achieve a porous structure. The highly porous TNZTF alloy possesses a homogeneous fine–grained microstructure consisting of equiaxed α–Ti and a small amount of FeTi2, the latter …


Dynamic Metabolic Flux Analysis Amidst Data Variability: Sphingolipid Biosynthesis Case Study In Arabidopsis Thaliana Cell Cultures, Abraham Boluwatife Osinuga Jul 2024

Dynamic Metabolic Flux Analysis Amidst Data Variability: Sphingolipid Biosynthesis Case Study In Arabidopsis Thaliana Cell Cultures, Abraham Boluwatife Osinuga

Department of Chemical and Biomolecular Engineering: Dissertations, Theses, and Student Research

Sphingolipids are pivotal for plant development and stress responses. Growing interest has been directed towards fully comprehending the regulatory mechanisms of the sphingolipid pathway. In this study, we explore its de novo biosynthesis and homeostasis in Arabidopsis thaliana cell cultures, shedding light on fundamental metabolic mechanisms. Employing 15N isotope labeling and quantitative dynamic modeling approach, we obtained data with notable variations and developed a regularized and constraint-based Dynamic Metabolic Flux Analysis (r-DMFA) framework to predict metabolic shifts due to enzymatic changes. Our analysis revealed key enzymes such as sphingoid-base hydroxylase (SBH) and long-chain-base kinase …


Optimizing The Expression Of Polyethylene Terephtalate Hydrolase-Encoding Synthetic Gene In Escherichia Coli Arctic Express (De3), Jocelyn Nataniel, Maria Ulfah, Dini Achnafani, Niknik Nurhayati, Gabriela Christy Sabbathini, Sri Rezeki Wulandari, Abinawanto Abinawanto, Is Helianti Jun 2024

Optimizing The Expression Of Polyethylene Terephtalate Hydrolase-Encoding Synthetic Gene In Escherichia Coli Arctic Express (De3), Jocelyn Nataniel, Maria Ulfah, Dini Achnafani, Niknik Nurhayati, Gabriela Christy Sabbathini, Sri Rezeki Wulandari, Abinawanto Abinawanto, Is Helianti

Makara Journal of Science

The waste of polyethylene terephthalate (PET) plastic waste in Indonesia is a pressing concern due to its slow degradation and potential environmental damage. One promising solution is to utilize polyethylene terephthalate hydrolase from Ideonella sakaiensis (IsPETase), an enzyme that specifically degrades PET. However, inducing the expression of IsPETase synthetic gene in Escherichia coli BL21 (DE3) has been challenging because much of it remains insoluble. This study aimed to express IsPETase in E. coli Arctic Express (DE3) and optimize the conditions to enhance its production. First, pET22b(+)pelB-IsPETase was inserted into E. coli Arctic Express (DE3). The …


Preparation Of Β-Ni (Oh)2 Nanosheet–Modified Glassy Carbon For Pseudocapacitors, Muhammad Buchari Setia Putra, Aliyah Aliyah, Afiten Rahmin Sanjaya, Respati Kevin Pramadewandaru, Hoeil Chung, Tribidasari Anggraningrum Ivandini Jun 2024

Preparation Of Β-Ni (Oh)2 Nanosheet–Modified Glassy Carbon For Pseudocapacitors, Muhammad Buchari Setia Putra, Aliyah Aliyah, Afiten Rahmin Sanjaya, Respati Kevin Pramadewandaru, Hoeil Chung, Tribidasari Anggraningrum Ivandini

Makara Journal of Science

β-Nickel hydroxide (Ni(OH)2) nanosheet–modified glassy carbon for pseudocapacitors was successfully prepared. The nanosheets were synthesized via a conventional growth seeding method combined with hydrothermal treatment. Transmission electron microscopy (TEM) characterization indicated the hexagonal structure of the nanosheets of around 15 nm in size, and X-ray diffraction (XRD) pattern confirmed the β-phase lattice crystal. These nanosheets used to modify the glassy carbon surface, increased the electroactive surface area by around 15 times. Furthermore, electrochemical investigation of the modified glassy carbon revealed an excellent performance and a specific capacitance of 628.01 F g−1 at a 1 A g−1 …


Ultrasonic Flow Meter Calibration Via The Internet Using An Analog-To-Digital Converter, Aliev Ravshan, A.U. Djalilov Jun 2024

Ultrasonic Flow Meter Calibration Via The Internet Using An Analog-To-Digital Converter, Aliev Ravshan, A.U. Djalilov

Chemical Technology, Control and Management

The purpose of scientific research work is remote control of improving the metrological properties of the water flow measuring device. Therefore, the Arduino platform with an additional ESP8266 NodeMcu v3 and analog-to-digital converter, module was installed in the scientific article for automatic calibration/checking of ultrasonic flow meters used in irrigation networks. The module is integrated into a 32-bit microcontroller with low power consumption. The ESP8266 NodeMcu v3 module operates at 80 and 160 MHz clock frequencies, supports real-time operating system (RTOS), built-in Wi-Fi, and has a microstrip antenna on board. Through this, the data exchange between the computing equipment and …


Environmental Monitoring And Control System Of Greenhouse Based On Internet Of Things Technology, Ru Jiang, Nadirbek Yusupbekov Jun 2024

Environmental Monitoring And Control System Of Greenhouse Based On Internet Of Things Technology, Ru Jiang, Nadirbek Yusupbekov

Chemical Technology, Control and Management

Greenhouse is an important application scene of modern agriculture. In this paper, a set of greenhouse environmental monitoring, facility remote control and production management system is designed and implemented based on Internet of Things technology for the development needs of modern agriculture in greenhouse. The system selects STM32F407 control board as the main controller to realize real-time monitoring of greenhouse environmental parameters including temperature and humidity, soil nutrients, soil pH and other greenhouse environmental information, and can adjust greenhouse environmental parameters by controlling the irrigation system, roller shutters, fans, shading curtains and other facilities in the greenhouse. The main controller …


Structural And Parametric Identification Of Recycling Systems, Khusan Igamberdiev, Madina Mirxalilovma Fozilova Jun 2024

Structural And Parametric Identification Of Recycling Systems, Khusan Igamberdiev, Madina Mirxalilovma Fozilova

Chemical Technology, Control and Management

The issue of identifying recirculation systems with a specific control loop, in which information and control information about various technological processes circulate, is being considered. A methodology for identifying recirculation systems has been developed, based on algorithms for structural identification of the model based on the results of assessing the sensitivity of the optimum of control parameters and a fuzzy inference algorithm based on production rules that contribute to solving the problem of parametric identification.


Research Of The Fuzzy Control System For Adjusting Thread Tension During The Warping Process, To'xtamurod Hayitmurodovich Avezov, Zokhid Ergashboyevich Iskandarov Jun 2024

Research Of The Fuzzy Control System For Adjusting Thread Tension During The Warping Process, To'xtamurod Hayitmurodovich Avezov, Zokhid Ergashboyevich Iskandarov

Chemical Technology, Control and Management

The paper considered issues of research into a fuzzy control system for the warping process. During the warping process, the reasons that cause defects in the final finished product have been studied, firstly (remove this word) which are thread breakage, thread tangling, the formation of loops on or under the belt, hanging loose threads and similar factors. To study the warping process, its mathematical model is constructed. Kinematic parameters of stationary movement corresponding to the equilibrium mode were determined by solving the nonlinear functional matrix - equation of movement. The process of breakage the warp of the threads under oscillation …


Research Of A New Technological Flowsheet Parameters For Uranium Mining From Technogenic Uranium Ores, Nazarov Jamol, G.M. Allaberganova, H.L. Pulatov, A.M. Muzafarov Jun 2024

Research Of A New Technological Flowsheet Parameters For Uranium Mining From Technogenic Uranium Ores, Nazarov Jamol, G.M. Allaberganova, H.L. Pulatov, A.M. Muzafarov

Chemical Technology, Control and Management

This paper presents the results of a study of the parameters of a new technological scheme for the extraction of uranium from technogenic uranium ores. The results of the analytical determination of the concentration of parent - 238U and daughter radionuclides - 234U , 230Th , 226Ra , 222Rn , 218Pa , 214Pb , etc. are presented . in the studied technogenic uranium ores. The principal scheme of the new uranium extraction technology from technogenic uranium ores is presented. The use of the classifier in a new scheme for separating granules of technogenic …


Assessment Of Metrological Errors Of Recognition Metrics In The Intelligent Control And Regulation System Of The Cotton Harvesting Machine, Erkin Uljaev, Utkirjon Murodillaevich Ubaydullaev, Azizjon Abdulla Ugli Abdulhamidov Jun 2024

Assessment Of Metrological Errors Of Recognition Metrics In The Intelligent Control And Regulation System Of The Cotton Harvesting Machine, Erkin Uljaev, Utkirjon Murodillaevich Ubaydullaev, Azizjon Abdulla Ugli Abdulhamidov

Chemical Technology, Control and Management

This article presents a method for assessing the error of metrics of an intelligent system for monitoring and regulating the width of the working gap of the harvesting apparatus of a cotton picker. To assess the error, the calculation of the average value of the standard deviation of metrics, absolute systematic and random errors, as well as absolute and relative total errors are used. The results of these calculations will allow us to determine the accuracy of the recognition system and opportunities for its improvement.


Synthesis Of An Adaptive Neuro-Fuzzy Control System For Steam Generator Temperature, Isomiddin Xakimovich Siddikov, Dilnoza Maxamadjanovna Umurzakova Jun 2024

Synthesis Of An Adaptive Neuro-Fuzzy Control System For Steam Generator Temperature, Isomiddin Xakimovich Siddikov, Dilnoza Maxamadjanovna Umurzakova

Chemical Technology, Control and Management

This paper is devoted to the modeling and synthesis of an adaptive neuro-fuzzy control system for steam generator temperature. Temperature control systems play an important role in industry because accurate and stable control is a prerequisite for the efficient operation of steam systems. Traditional control methods based on mathematical models and fixed parameter controllers may have limitations in providing optimal performance and adapting to changing operating conditions. The paper proposes a synthesized system combining fuzzy logic and adaptation methods to achieve more accurate and stable temperature control. A detailed structural diagram of the system, modeling, and tuning methods are presented. …


Decision-Making Algorithms For Drilling Instrument Control Systems, Fuzayl Fozil Ugli Odilov Jun 2024

Decision-Making Algorithms For Drilling Instrument Control Systems, Fuzayl Fozil Ugli Odilov

Chemical Technology, Control and Management

The control of the movement of the drilling tool and the structure of the well are considered. An effective control algorithm for drilling systems that provides control of well trajectory parameters is analyzed. In technological processes, it is necessary to control several parameters or several systems at the same time. It is considered necessary to create decision-making algorithms for the formation of managerial effects for the control system of such technological processes. The controlled oriented type of the bottom of the drill string was analyzed. Work was carried out on the decision-making algorithm for the processing of control effects. The …


Algorithms And Models For Synthesis Of Elements Of Digital Information Systems, Odil Abdujalilovich Jumaev, M.T. Ismoilov, V.B. Pulatov, G.X. Rashidov Jun 2024

Algorithms And Models For Synthesis Of Elements Of Digital Information Systems, Odil Abdujalilovich Jumaev, M.T. Ismoilov, V.B. Pulatov, G.X. Rashidov

Chemical Technology, Control and Management

The development of algorithms for noise-tolerant and high-speed measurement systems involves an integrated approach that encompasses methods of data processing and transmission, as well as mechanisms for rapid response to changes. This paper presents the key principles and techniques used in such technologies. The information systems are thoroughly analyzed, including the use of signal processing techniques and their identification, filtering using various statistical techniques to determine signal parameters and the development of algorithms to analyze and classify signals. Critical aspects of the system such as performance, reliability, security and scalability are also evaluated. The paper discusses information system structures and …


Manufacturing Of Aligned Electrospun Nanofiber Yarns For Their Enhanced Mechanical And Piezoelectric Properties, Adaugo Mary-Frances Enuka Jun 2024

Manufacturing Of Aligned Electrospun Nanofiber Yarns For Their Enhanced Mechanical And Piezoelectric Properties, Adaugo Mary-Frances Enuka

Theses and Dissertations

Electrospinning is a widely used technique for producing nanofibers with diverse applications. This method uses polymer solutions and strong electric fields to generate nano-sized fibers with unique properties. This study presents a novel manufacturing approach that enables the production of electrospun poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) nanofiber yarns using an automated parallel track system and an adjustable roll-to-roll collector. This research examines the impact of an automated post-drawing system on the polymer chain orientation, crystallinity, tensile strength, morphology, and piezoelectric properties of PVDF-HFP nanofiber yarn. The results reveal that the post-drawing process significantly improves molecular alignment, increases tensile strength, and enhances the …


Investigating The Feasibility And Mechanisms Of Cold Spray Deposition Of Polymer-Based Powders On Fiber-Reinforced Composite Substrates, Nicholas Beau Mennie Jun 2024

Investigating The Feasibility And Mechanisms Of Cold Spray Deposition Of Polymer-Based Powders On Fiber-Reinforced Composite Substrates, Nicholas Beau Mennie

Theses and Dissertations

Fiber-reinforced composites have become important structural components in industries such as aerospace and energy due to their high mechanical strength and relatively light structural weight. However, during operation, these materials can be prone to impact damage and disintegration. Effective protection via metalization and repair of composites would, therefore, reduce the cost and time for replacement parts. Polymer-based cold spray, while a relatively new technique, can be utilized to metalize and possibly repair composite materials subjected to impact-induced damage. In this work, studies involving polymers and composite cold spray were performed to enable the process of safeguarding, enhancing, or repairing various …


Copper-Based Electrocatalysts For Electrochemical Reduction Of Co2 To C2 Products, Monsuru Olatunji Dauda Jun 2024

Copper-Based Electrocatalysts For Electrochemical Reduction Of Co2 To C2 Products, Monsuru Olatunji Dauda

LSU Master's Theses

The electrochemical reduction of CO2 using copper-based electrocatalysts has emerged as a promising approach for sustainable chemical production, offering a pathway to mitigate the rising atmospheric CO2 levels while generating valuable fuels and chemicals. However, the selectivity and efficiency of copper-based catalysts towards specific C2 products remain a major challenge, hindering their commercial viability. This thesis focuses on the development, characterization, and mechanistic understanding of three promising electrocatalyst systems for multi-carbon product generation from CO2 reduction: copper-phosphide (Cu-P), copper-tin (Cu-Sn), and copper selenide (Cu2Se). A comprehensive investigation of the electrocatalysts was conducted using advanced …


Activity Descriptors As Tools For Designing Highly Efficient Electrocatalysts For Water Splitting, Aya Gomaa Jun 2024

Activity Descriptors As Tools For Designing Highly Efficient Electrocatalysts For Water Splitting, Aya Gomaa

Theses and Dissertations

There is an uprising urge to design efficient, active, and durable catalysts to achieve sustainable hydrogen production. The unambiguity of which material should be used pushed the scientific community to devote enormous efforts in exploring different elements with different ratios on trial and error bases. However, the bridge between the theoretical calculation and the experiments introduced a new realm of designing efficient catalysts by introducing the concept of activity descriptors. In the first part of the thesis, the ability to convert waste stainless steel (SS) 316L meshes into highly efficient and durable oxygen evolution reaction (OER) catalysts is demonstrated. The …


Department Chairs As Change Agents: A Virtual Cross-Institutional Professional Development Model For Chairs, Cinzia Cervato, Stephanie Peterson, Carrie Ann Johnson, Canan Bilen-Green, Carla Koretsky, Adrienne Minerick, Gul Okudan Kremer Jun 2024

Department Chairs As Change Agents: A Virtual Cross-Institutional Professional Development Model For Chairs, Cinzia Cervato, Stephanie Peterson, Carrie Ann Johnson, Canan Bilen-Green, Carla Koretsky, Adrienne Minerick, Gul Okudan Kremer

Michigan Tech Publications

Department chairs are crucial in impacting departmental climate, conveying expectations, and providing merit assessments. Therefore, they have the most influence in retaining highly qualified faculty. Most department chairs come from the faculty ranks and lack formal training in key management, communication, and administrative skills, including performance reviews, resource allocation and budgeting, legal and compliance issues, promotion and tenure determinations, conflict resolution, and the inclusive management of people with diverse identities. Recognizing the critical role of department chairs and the evident gap in their training, we developed a series of chair workshops to provide ongoing professional development for department chairs across …


Electrochemical Identification Of Metal Chlorides In Eutectic Licl-Kcl Without Prior Knowledge Of Analyte Identities, Tyler Williams, Jason Torrie, Mark Schvaneveldt, Ranon Fuller, Greg Chipman, Devin Rappleye Jun 2024

Electrochemical Identification Of Metal Chlorides In Eutectic Licl-Kcl Without Prior Knowledge Of Analyte Identities, Tyler Williams, Jason Torrie, Mark Schvaneveldt, Ranon Fuller, Greg Chipman, Devin Rappleye

Faculty Publications

The identities of unknown analytes within four eutectic LiCl-KCl melts were determined using electrochemical methods, simulating the uncertainty of electrochemically probing an electrorefiner salt bath or molten salt nuclear reactor. With a variety of electrochemical methods (e.g. cyclic voltammetry, chronopotentiometry, and square-wave voltammetry), and electroanalytical techniques (e.g. semi-differentiation), every analyte was positively identified, although one false positive occurred because of an unexpected chemical interaction. This study highlights some remaining challenges for the use of electrochemical sensors in nuclear material control and accountability in molten salts: (1) quantification of analytes without the use of calibration curves (e.g. error in property values, …


Chemical Herding As A Multiplicative Factor For Top-Down Manipulation Of Colloids, Mark N. Mcdonald, Douglas R. Tree, Cameron K. Peterson Jun 2024

Chemical Herding As A Multiplicative Factor For Top-Down Manipulation Of Colloids, Mark N. Mcdonald, Douglas R. Tree, Cameron K. Peterson

Faculty Publications

Colloidal particles can create reconfigurable nanomaterials, with applications such as color-changing, self-repairing, and self-regulating materials and reconfigurable drug delivery systems. However, top-down methods for manipulating colloids are limited in the scale they can control. We consider here a new method for using chemical reactions to multiply the effects of existing top-down colloidal manipulation methods to arrange large numbers of colloids with single-particle precision, which we refer to as chemical herding. Using simulation-based methods, we show that if a set of chemically active colloids (herders) can be steered using external forces (i.e., electrophoretic, dielectrophoretic, magnetic, or optical forces), then a larger …


Emergent Magnetism And Hyperthermia In Phase- And Size-Tunable Iron Oxide Nanostructures, K Mudiyanselage Tharindu Supun Bandara Attanayake Jun 2024

Emergent Magnetism And Hyperthermia In Phase- And Size-Tunable Iron Oxide Nanostructures, K Mudiyanselage Tharindu Supun Bandara Attanayake

USF Tampa Graduate Theses and Dissertations

Iron oxide nanoparticles (IONPs) hold immense potential across diverse fields, from spintronics, magnetic hyperthermia to drug delivery, biodetection, and magnetic resonance imaging. Unlocking these applications hinges on our ability to tailor the magnetic properties of IONPs, and this dissertation presents novel and powerful approaches for enhancing magnetic and hyperthermic responses of multiphase iron oxide nanostructures. This is achieved by manipulating their phase volume fraction, size, and shape with a focus on the magnetic tunability of nanostructures via strategic control over structural and environmental parameters. The aforementioned has been achieved by the following three key approaches: (i) phase-tunability of iron oxide …


Method For Separating Individual Cathode-Active Materials From Li-Ion Batteries, Lei Pan, Tinuade Ololade Folayan, Jeffrey S. Spangenberger, Bryant J. Polzin Jun 2024

Method For Separating Individual Cathode-Active Materials From Li-Ion Batteries, Lei Pan, Tinuade Ololade Folayan, Jeffrey S. Spangenberger, Bryant J. Polzin

Michigan Tech Patents

Method of separating individual cathode active materials from a mixture of cathode active materials by froth flotation has been developed. They are based on using appropriate chemical reagents that selectively hydrophobize individual cathode active materials to be recovered, so that they can be collected by air bubbles used in flotation and separated from other mixtures. The chemical reagents are amphiphilic molecules with specialized head groups have a strong affinity to metal elements on surfaces of cathode materials. This method enables a separation of individual cathode active material from a mixture of cathode active materials.


Operation Of A Packed Bed Reactor For Hyrdogenation, Austin Joseph Urfer Jun 2024

Operation Of A Packed Bed Reactor For Hyrdogenation, Austin Joseph Urfer

Graduate Theses - Chemical Engineering

The primary goals of this research were to develop an efficient standard operating procedure for undergraduate students and researchers performing reactions within a packed bed reactor and to determine the optimal operating conditions for phenethylamine formation from mandelonitrile hydrogenation. With the current laboratory packed bed reactor system, undergraduates can conduct gas-liquid phase reactions at a maximum temperature of 95℃ and a maximum pressure of 100 psi. The versatile system setup can be modified for unit operations laboratory instruction or future researchers analyzing heterogeneous catalysis reactions. The developed standard operating procedure provides detailed instructions on packing the reactor with a solid …


Creation And Fill Of An Eocene Incision On A Leeward Margin Of An Isolated Carbonate Platform, Northeast Sirte Basin, Libya, Muneer Abdalla, Wan Yang, Abdlsaid Ibrahem, Salah Hassan, Alzobeere Bogzil Jun 2024

Creation And Fill Of An Eocene Incision On A Leeward Margin Of An Isolated Carbonate Platform, Northeast Sirte Basin, Libya, Muneer Abdalla, Wan Yang, Abdlsaid Ibrahem, Salah Hassan, Alzobeere Bogzil

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The recognition of incised valleys and the reconstruction of their filling history are significant for defining unconformity surfaces and their stratigraphic framework, particularly when detailed petrographic data are missing. However, little of such research is published so far on the characterization and factors influencing the development of incised valleys using three-dimensional seismic and well data. Thus, this work aims to examine and analyze the geometry and factors controlling the formation and sediments filling of an eocene incised valley in a sequence stratigraphic frame using an integration of three-dimensional seismic and well data from ne sirte basin, libya. The eocene incised …


Assessing Global Engagement Interventions To Advance Global Engineering Competence For Engineering Formation, Scott Schneider, Erick S. Vasquez-Guardado, Corinne Mowrey, Michael Moulton, Homero Murzi, Matthew A. Witenstein Jun 2024

Assessing Global Engagement Interventions To Advance Global Engineering Competence For Engineering Formation, Scott Schneider, Erick S. Vasquez-Guardado, Corinne Mowrey, Michael Moulton, Homero Murzi, Matthew A. Witenstein

Chemical and Materials Engineering Faculty Publications

This paper summarizes the work performed during the first year of a collaborative Research Initiation in Engineering Formation (RIEF) project focused on assessing the formation of a global learner mindset in engineering students through the use of different types of global engagement interventions without extended international travel. During this year the global engagement interventions have been developed, piloted, and assessed using the Global Engagement Survey (GES) and Global Engineering Competency Scale (GECS) instruments in a pre and post format. The assessment results helped the research team update the interventions and refine the assessment strategy, including the addition of new qualitative …