Biogeochemistry Commons^™

Late Pleistocene Climate And Proboscidean Paleoecology In North America: Insights From Stable Isotope Compositions Of Skeletal Remains, Jessica Z. Metcalfe

Electronic Thesis and Dissertation Repository

This thesis uses the carbon, nitrogen, and oxygen isotope compositions of mammoth (Mammuthus) and mastodon (Mammut) skeletal remains to reconstruct paleoclimate and paleoecology in Late Pleistocene North America. Analytical methods, sampling strategies, environmental adaptations and seasonal behaviors of proboscideans were investigated.

Reliable and reproducible results are crucial for a study of this nature. A persistent methodological problem in the isotope analysis of structural carbonate in bioapatite was solved by reacting bioapatite under “sealed vessel” conditions.

Growth rate determinations are critical for designing sampling strategies and interpreting results. Histological and isotopic measurements demonstrated variations in enamel growth …

Using Equal‐Area Quadratic Splines To Compute Depth‐ Weighted Averages Of Soil Chemical Parameters, Chris E. Johnson, Jeremy Tamargo

Chris E Johnson

No abstract provided.

Using Equal‐Area Quadratic Splines To Compute Depth‐ Weighted Averages Of Soil Chemical Parameters, Chris E. Johnson, Jeremy Tamargo

Civil and Environmental Engineering

No abstract provided.

Determination Of Caffeine As A Marker For Septic Tank Contamination Of Wilgreen Lake, Rosemary Onjiko, Susan Godbey, Walter S. Borowski, Darrin Smith, Lori Wilson

EKU Faculty and Staff Scholarship

Wilgreen Lake in Richmond, Kentucky, has been listed by both the state and the Environmental Protection Agency as an “impaired” lake due to excess nutrients, which may be in part contributed by domestic septic systems. Caffeine can be used as an anthropogenic marker to estimate the contribution of septic tank effluent to the lake. We have modified existing analytical methods to produce a viable method for the determination of caffeine in environmental water samples and applied the method to water samples collected from Wilgreen Lake. The modified method allows determination of caffeine in a concentration range of 75 to 10,000 …

A High-Resolution Temperature Record From Lakes Of The Lofoten Islands, Northwestern Norway Based On A New Uk37 Temperature Calibration From In Situ Measurements, Xiaohui Huang

Masters Theses 1911 - February 2014

Water filters and sediment trap samples were collected weekly from late May to early September 2009 from four lakes of the Lofoten archipelago, northwestern Norway, and were used to explore the applicability of the alkenone unsaturation index (UK37) for temperature reconstruction in limnic systems in the area. For the first time, we observed the occurrence of long-chain alkenones (LCAs) within the water columns of lakes in this region. Water filters from two of the four studied lakes contained measurable concentrations of alkenones that were restricted to spring turnover and disappeared with the onset of summer stratification. These results indicate that …

A Multi-Proxy Approach To Assessing Isolation Basin Stratigraphy From The Lofoten Islands, Norway, Nicholas L. Balascio, Zhaohui Zhang, Raymond S. Bradley, Bianca B. Perren, Svein-Olaf Dahl, Jostein Bakke

Raymond S Bradley

This study takes a comprehensive approach to characterizing the isolation sequence of Heimerdalsvatnet, a coastal lake in the Lofoten Islands, northern Norway. We use established methods and explore new techniques to assess changes in marine influence. Bathymetric and sub-bottom profiles were acquired to examine basin-wide sedimentation and a 5.8 m sediment core spanning the last 7800 cal yr BP was analyzed. We measured magnetic susceptibility, bulk organic matter properties, molecular biomarkers, diatom assemblages, and elemental profiles acquired by scanning X-ray fluorescence. These characteristics of the sediment reflect detailed changes in salinity and water column conditions as the lake was progressively …

Climate-Mediated Nitrogen And Carbon Dynamics In A Tropical Watershed, Ashley P. Ballantyne, P. A. Baker, S. C. Fritz, B. Poulter

Ecosystem and Conservation Sciences Faculty Publications

Climate variability affects the capacity of the biosphere to assimilate and store important elements, such as nitrogen and carbon. Here we present biogeochemical evidence from the sediments of tropical Lake Titicaca indicating that large hydrologic changes in response to global glacial cycles during the Quaternary were accompanied by major shifts in ecosystem state. During prolonged glacial intervals, lake level was high and the lake was in a stable nitrogen-limited state. In contrast, during warm dry interglacials lake level fell and rates of nitrogen concentrations increased by a factor of 4–12, resulting in a fivefold to 24-fold increase in organic carbon …

Iron Oxide And Calcite Associated With Leptothrix Sp. Biofilms Within An Estavelle In The Upper Floridan Aquifer, Lee J. Florea, Chasity L. Stinson, Josh Brewer, Rick Fowler, B Joe Kearns, Anthony M. Greco

International Journal of Speleology

In Thornton’s Cave, an estavelle in west-central Florida, SEM, EDS, and XRD data reveal biofilms that are predominantly comprised of FeOOH-encrusted hollow sheaths that are overgrown and intercalated with calcite. Fragments of this crystalline biofilm adhere to the walls and ceiling as water levels vary within the cave. Those on the wall have a ‘cornflake’ appearance and those affixed to the ceiling hang as fibrous membranes. PCR of DNA in the active biofilm, combined with morphologic data from the tubes in SEM micrographs, point to Leptothrix sp., a common Fe-oxidizing bacteria, as the primary organism in the biofilm. Recent discoveries …

Seasonal Changes In The Sinking Particulate Flux And In The Nitrogen Cycle Within The Euphotic And Twilight Zones Of The Cariaco Basin, Venezuela, Enrique Montes-Herrera

USF Tampa Graduate Theses and Dissertations

This study explored the effects of seasonal variability on the geochemistry of sinking pthesiss and on the nitrogen cycle of the Cariaco Basin. Pthesis fluxes were measured at the base of the euphotic zone (the depth of 1% of photosynthetically active radiation - PAR) with drifting sediment traps during months of upwelling and non-upwelling regimes from March 2007 to November 2009. Flux estimates were analyzed in the context of seasonal variations in sea surface temperature, primary productivity, and chlorophyll a concentrations using data generated by the CARIACO Time-series Program as well as satellite data. Additionally, nine years (1996-2000 and 2004-2007) …

Spatial And Interannual Variability Of Dissolved Organic Matter In The Kolyma River, East Siberia, Observed Using Satellite Imagery, Claire G. Griffin, Karen E. Frey, John Rogan, Robert M. Holmes

Geography

The Kolyma River basin in northeastern Siberia, the sixth largest river basin draining to the Arctic Ocean, contains vast reserves of carbon in Pleistocene-aged permafrost soils. Permafrost degradation, as a result of climate change, may cause shifts in riverine biogeochemistry as this old source of organic matter is exposed. Satellite remote sensing offers an opportunity to complement and extrapolate field sampling of dissolved organic matter in this expansive and remote region. We develop empirically based algorithms that estimate chromophoric dissolved organic matter (CDOM) and dissolved organic carbon (DOC) in the Kolyma River and its major tributaries in the vicinity of …

Investigating The Influence Of Organic Acids On Uraninite Solubility And Uranyl Sorption Onto Kaolinite, Michelle L. Barger

Dissertations

Within anoxic near surface aqueous settings where U0_2(S) may be released an opportunity to encounter and complex with organic acids may occur. Reactions between U0_2(S) and ligands may promote the solubility and mobility of uranium. Organic ligands investigated in the dissolution work include citric acid, NTA and EDTA. Exposure to the ligands had little effect on U0_2(S) solubility. The log activity of U0_2(S) hydrolysis under reduced conditions was -6.56. Under all measured conditions of ligand concentration, the data consistently show an increase in uranium concentration to a median log U activity of -4.89. The observed solubility …

Early Season Depletion Of Dissolved Iron In The Ross Sea Polynya: Implications For Iron Dynamics On The Antarctic Continental Shelf, Peter N. Sedwick, C. M. Marsay, B. M. Sohst, A. M. Aguilar-Islas, M. C. Lohan, M. C. Long, K. R. Arrigo, R. B. Dunbar, M. A. Saito, W. O. Smith, G. R. Ditullio

OES Faculty Publications

The Ross Sea polynya is among the most productive regions in the Southern Ocean and may constitute a significant oceanic CO₂sink. Based on results from several field studies, this region has been considered seasonally iron limited, whereby a "winter reserve" of dissolved iron (dFe) is progressively depleted during the growing season to low concentrations (~ 0.1 nM) that limit phytoplankton growth in the austral summer (December-February). Here we report new iron data for the Ross Sea polynya during austral summer 2005-2006 (27 December-22 January) and the following austral spring 2006 (16 November-3 December). The summer 2005-2006 data show …

Fossil And Contemporary Aerosol Particulate Organic Carbon In The Eastern United States: Implications For Deposition And Inputs To Watersheds, Andrew S. Wozniak, James E. Bauer, Rebecca M. Dickhut

Chemistry & Biochemistry Faculty Publications

Atmospheric particulate matter samples were collected from mid-Atlantic and northeastern U. S. (Virginia and New York, respectively) sites to assess the fossil versus contemporary sources contributing to aerosol organic carbon (OC) and the implications for its deposition to watersheds. Mean particulate matter total OC (TOC) deposition rates (wet + dry deposition) were calculated to be 1.6 and 2.4 mg C m^-2 d^-1 for the Virginia and New York sites, respectively. Wet deposition of particulate TOC was determined to be the dominant depositional mode, accounting for >65% (Virginia) and >80% (New York) of total aerosol TOC deposition. Isotopic mass …

Engineering Our Climate: A Critical Review Of The Geoengineering Response To Climate Change, Gary Huff

The Journal of Undergraduate Research

Various responses to greenhouse gas induced climate change have been proposed within the literature. While the most desirable response is to dramatically reduce greenhouse gas emissions, technological and financial obstacles make it difficult to realize the reductions necessary to solve the climate change problem. Several geoengineering schemes have been proposed that would compensate for increased greenhouse gas concentrations by reducing the solar energy absorbed by Earth. The most notable of these shortwave climate engineering schemes involves injection of sulfur aerosols into the stratosphere in order to disperse incoming radiation. This paper examines the geoengineering responses to climate change and demonstrates …

Biodegradation Of Bisphenol-A And 17b-Estradiol In Soil Mesocosms Under Alternating Aerobic/Anoxic/Anaerobic Conditions, Won-Seok Kim

USF Tampa Graduate Theses and Dissertations

Soil-aquifer treatment (SAT) has been proposed as a method for reusing treated municipal wastewater. SAT is characterized by alternating cycles of aerobic and anaerobic conditions in the subsurface, in response to alternating cycles of flooding and drainage of a surface impoundment. It is not yet known how these alternating redox conditions affect the removal of potentially harmful endocrine-disrupting compounds (EDCs) from treated effluent.

The overall objective of my doctoral research is to determine the fate of EDCs in alternating aerobic/anoxic/anaerobic conditions under simulated SAT conditions. To assess the fate of EDCs in simulated SAT conditions, I first had to develop …

Reduction Of Iron (Iii) And Humic Substances Plays A Major Role In Anaerobic Respiration In An Arctic Peat Soil, David A. Lipson, Mony Jha, Ted K. Raab, Walter C. Oechel

Ted K. Raab

Arctic peat soils contain vast reserves of organic C and are largely anaerobic. However, anaerobic respiration, particularly the role of Fe(III) and humic substances as electron acceptors, is not well understood in such ecosystems. We investigated these processes in a drained thaw lake basin on the Arctic coastal plain near Barrow, Alaska. We measured concentrations of soluble Fe and other potential electron acceptors, described the microbial community, and performed experiments in the laboratory and field to measure net rates of Fe(III) reduction and the relationship of this process to C cycling. In most areas within the basin, aerobic conditions existed …

The Distribution And Comparative Biogeochemistry Of Silver With Other Selected Trace Metals In Coastal Waters Near Massachusetts, Usa, Christian F. Krahforst

Graduate Doctoral Dissertations

Water samples and hydrologic data were collected during 1994-1996 in New England coastal waters near Massachusetts, USA to examine the distribution of silver and other trace metals (Cu, Pb, Cd, Zn, and Fe) in the coastal systems of Massachusetts and Cape Cod Bays. These investigations were designed to test the hypothesis that silver could serve as a tracer of dispersion of municipal wastewater in Boston Harbor into Massachusetts and Cape Cod Bays and estimate the relative contribution of wastewater discharge to the overall silver budget of the Massachusetts Bays system. Silver concentrations in both particulate and filtered (<0.4 µm) fractions averaged 103 and 117 pmol kg-1 for Boston Harbor, 34 and 10 pmol kg-1 in western Massachusetts Bay, and 11 and 7 pmol kg-1 in the central portion of Massachusetts Bay, respectively. Average Ag concentrations in southern Gulf of Maine coastal waters were 10 and 2 pmol kg-1 for filtered and particulate fractions, respectively. While nearly half of the silver existed in particulate form in Boston Harbor, nearly 80% of the silver in Massachusetts and Cape Cod Bays occurred in the filterable fraction. Coastal water surveys revealed non-conservative Ag behavior and probably the result of incomplete mixing of three or more water masses with unique Ag signatures (e.g., Merrimack River, Boston Harbor, surface and intermediate Gulf of Maine waters). Quasi-steady state mass balance approaches estimate most of the silver entering into the Massachusetts Bays system during the study period was the result of municipal wastewater discharge to Boston Harbor (84-93%).

Multivariate analyses …

Carbon Isotopic Fractionation Across A Late Cambrian Carbonate Platform: A Regional Response To The Spice Event As Recorded In The Great Basin, Jonathan Lloyd Baker

UNLV Theses, Dissertations, Professional Papers, and Capstones

Geochemical models have suggested that the late Cambrian was characterized by a greenhouse climate with high pCO2. Furthermore, stableisotope analyses within the Great Basin have documented a large carbonate isotope (δ13Ccarb) excursion, known as the Steptoean Positive Carbon Isotope Excursion (SPICE). This event has been documented globally, and is interpreted as having resulted from enhanced organic carbon burial. Unless the size of carbon reservoirs in the Cambrian ocean was significantly different from those of the Cenozoic, this forcing should have resulted in a comparable carbon-isotope excursion in organic matter (δ13Corg). It is also predicted that increased organic carbon burial would …

Phosphorus Export From A Restored Wetland Ecosystem In Response To Natural And Experimental Hydrologic Fluctuations, Marcelo Ardón, Shaena Montanari, Jennifer L. Morse, Martin W. Doyle, Emily S. Bernhardt

Environmental Science and Management Faculty Publications and Presentations

Wetland restoration is a commonly used approach to reduce nutrient loading to freshwater and coastal ecosystems, with many wetland restoration efforts occurring in former agricultural fields. Restored wetlands are expected to be effective at retaining or removing both nitrogen and phosphorus (P), yet restoring wetland hydrology to former agricultural fields can lead to the release of legacy fertilizer P. Here, we examined P cycling and export following rewetting of the Timberlake Restoration Project, a 440 ha restored riverine wetland complex in the coastal plain of North Carolina. We also compared P cycling within the restored wetland to two minimally disturbed …

Phosphorus Uptake In Rhodomonas Salina (Wislouch) And Its Effect On Allocation And Elimination In Acartia Tonsa (Dana), Danna Palladino

OES Theses and Dissertations

Phosphorus is a key element in important biochemical compounds, such as RNA and phospholipids, and can become limiting in a variety of marine systems. The uptake of phosphorus into biochemical fractions (protein, low molecular weight (LMW) compounds, lipid, polysaccharide and nucleic acid) in Acartia tonsa fed ³³P -labeled Rhodomonas salina was examined. R. salina was cultured on two variations of one media that in one case contained phosphorus in balance and the other out of balance with relation to other standard f/2 components. The P-balanced (PB) media had a N:P ratio of 24.5, which is higher than that found …