Biogeochemistry Commons^™

Facilitate Visualization And Distribution Of Nasa's Environmental Science Data Through Open Standards And Open Source Software For Geospatial, Yaxing Wei, Zhaoying (Angie) Wei, Suresh Santhanavannan

Free and Open Source Software for Geospatial (FOSS4G) Conference Proceedings

This paper introduces the utilization of open standards and open source software for visualization and distribution of geospatial environmental science data at the Oak Ridge National Laboratory Distributed Active Archive Center (ORNL DAAC). The ORNL DAAC is one of the NASA Earth Observing System Data and Information System (EOSDIS) data centers. A big challenge for the ORNL DAAC (https://daac.ornl.gov) is to efficiently manage over a thousand heterogeneous environmental data, collected through field campaigns, aircraft/satellite observations, and model simulations. ORNL DAAC also has to provide tools to easily find, visualize, and access the heterogeneous data. To address ...

Nitrogen And Carbon Isotopic Dynamics Of Subarctic Soils And Plants In Southern Yukon Territory And Its Implications For Paleoecological And Paleodietary Studies, Farnoush Tahmesabi, Fred J. Longstaffe, Grant Zazula, Bruce Bennett

Earth Sciences Publications

We examine here the carbon and nitrogen isotopic compositions of bulk soils (8 topsoil and 7 subsoils, including two soil profiles) and five different plant parts of 79 C₃ plants from two main functional groups: herbs and shrubs/subshrubs, from 18 different locations in grasslands of southern Yukon Territory, Canada (eastern shoreline of Kluane Lake and Whitehorse area). The Kluane Lake region in particular has been identified previously as an analogue for Late Pleistocene eastern Beringia. All topsoils have higher average total nitrogen δ¹⁵N and organic carbon δ¹³C than plants from the same sites with ...

Methylmercury Production In Two Northern Fen Peatlands, Mikhail J. Mack

Electronic Thesis and Dissertation Repository

Northern peatlands provide conditions favourable for sulphate reducing bacteria, microorganisms responsible for producing methylmercury, an aquatic pollutant. An expected climate driven shift from moss- to sedge-dominance may alter mercury biogeochemistry. Observations from a moss-dominated poor fen and sedge-dominated intermediate fen were used to compare methylmercury to assess if contrasting plant communities, nutrients status and/or hydrologic regime control production. Chapter 2 compared porewater methylmercury and ancillary chemistry across two Northern Ontario fens. The lower water table, greater dissolved organic carbon, and lower pH in the poor fen resulted in 3.1 times greater methylmercury. Chapter 3, riparian zones in intermediate ...

Xzlamalraab_Clorg (2017).Pdf, Jaime Zlamal, Ted K. Raab, Robert A. Edwards, Mark Little, David A. Lipson

Ted K. Raab

Influence Of Common Bean (Phaseolus Vulgaris) Grown In Elevated Co2 On Apatite Dissolution, Brian Matthew Morra

Electronic Theses and Dissertations

Elevated concentrations of atmospheric CO₂ brought about by human activity creates changes in plant morphology, growth rate and exudate production. Our study sought to understand the effect of these changes on soil mineral weathering using plants grown under two conditions, ambient CO₂ (400ppm) and elevated CO₂ (1000ppm). Phaseolus vulgaris (common beans) were grown in flow-through microcosms consisting of a mixture of quartz and apatite sands. Plant growth was sustained by a nutrient solution devoid of calcium (Ca) and phosphorous (P). Using Atomic Adsorption Spectroscopy and colorimetry, Ca and P content of the leachate and plant tissue served ...

The Effects Of Urbanization On Nitrogen Processing In Urban Streams, Peter Francissen, Dr. Kevin Geedey, Dr. Michael Reisner

Celebration of Learning

Urban stream syndrome is described as the deterioration of stream health in an urbanized watershed and is associated with the loss of ecosystem services, which in turn degrades downstream environments. One key symptom of the urban stream syndrome is reduced processing of inorganic nitrogen. Previous research suggests that as urbanization increases and water quality decreases, the uptake length (Sw) of inorganic N increases. This indicates that the stream is increasing the export of N downstream compared to in situ incorporation of N into the ecosystem. We measured uptake length (Sw) of NO3, using a pulse addition method, along 9 different ...

Summer Precipitation Occurrence Effect On Two Passerine Species In Thule, Greenland, Sara E. Baugh

Celebration of Learning

Climate change is occurring at a faster rate in the Arctic than the rest of the globe, causing temperature rises at twice the rate of the global average and increased summer precipitation in the form of rain. These precipitation events are predicted to affect migratory bird species that breed throughout the Arctic. Increased occurrence of heavy rainstorms indirectly affect bird populations by impacting distribution and abundance of food supply, and directly by increasing mortality rates of juveniles. Studies conducted on bird species throughout the low Arctic regions; have shown that it is not the total precipitation of a breeding season ...

Determining Sources Of Nitrate In The Semi-Arid Rio Grande Using Nitrogen And Oxygen Isotopes, Diego Alberto Sanchez Hernandez

Masters Theses

The Rio Grande, a semi-arid river in the American Southwest, is a major source of surface water for agriculture and drinking supplies in New Mexico and Texas. In addition to increasing salinity, considerable increases of NO₃^- [nitrate] have been observed in the semi-arid portion of the Rio Grande. It is possible that elevated water salinity inhibits denitrification on irrigated fields and, thus, fails to mediate excess nutrient load from anthropogenic activities. Therefore, two major goals of this project were to 1) characterize and quantify major NO₃^- sources, and 2) assess whether elevated water salinity affects microbial denitrification. In ...

Influence Of Algae On Soil Saturated Hydraulic Conductivity: An In Situ Treatment Option For Reducing Infiltration Beneath Unlined Algae Cultivation Ponds, Molly Brianne Pattullo

Masters Theses

Commercial production of algal biofuels is currently limited by high capital costs, including the cost of installation and maintenance of plastic pond liners, which mitigate seepage of cultivation fluids and control the release of salts and nutrients into the subsurface beneath outdoor algae cultivation ponds. However, studies of animal waste settling lagoons show that underlying soils ranging from sands to clay loams can exhibit reduced hydraulic conductivity within days to weeks after construction, reducing the need for plastic liners. The mechanisms of the hydraulic conductivity reductions, or “soil sealing”, are physical rearrangement of soil particles, buildup of fines, and the ...

Catalyzed Synthesis Of Zinc Clays By Prebiotic Central Metabolites, Marcelo I. Guzman, Ruixin Zhou, Kaustuv Basu, Hyman Hartman, Christopher J. Matocha, S. Kelly Sears, Hajatollah Vali

Chemistry Faculty Publications

How primordial metabolic networks such as the reverse tricarboxylic acid (rTCA) cycle and clay mineral catalysts coevolved remains a mystery in the puzzle to understand the origin of life. While prebiotic reactions from the rTCA cycle were accomplished via photochemistry on semiconductor minerals, the synthesis of clays was demonstrated at low temperature and ambient pressure catalyzed by oxalate. Herein, the crystallization of clay minerals is catalyzed by succinate, an example of a photoproduced intermediate from central metabolism. The experiments connect the synthesis of sauconite, a model for clay minerals, to prebiotic photochemistry. We report the temperature, pH, and concentration dependence ...

A Model Archive For A Coupled Hydrodynamic-Sediment Transport-Biogeochemistry Model For The Rhône River Sub-Aqueous Delta, France, Julia Moriarty, Courtney K. Harris, Katja Fennel, Kehui Xu, Christophe Rabouille, Marjorie A.M. Friedrichs

Data

This dataset includes model input, code, and output used in the publication Moriarty et al. (2017, Biogeosciences), which used a coupled hydrodynamic-sediment transport-biogeochemical model to investigate the roles of resuspension, diffusion and biogeochemical processes on oxygen dynamics on the Rhône River sub-aqueous delta, France. Model development for this project focused on coupling the sediment transport and water-column biogeochemistry modules in the Regional Ocean Modeling System (ROMS) by incorporating a seabed biogeochemistry module into the ROMS framework. As described in Moriarty et al. (2017, Biogeosciences), the coupled model can account for diffusion of nutrients across the seabed-water-column interface; storage of particulate ...

Multiple Metabolisms Constrain The Anaerobic Nitrite Budget In The Eastern Tropical South Pacific, Andrew R. Babbin, Brian D. Peters, Calvin W. Mordy, Brittany Widner, Karen L. Casciotti, Bess B. Ward

OEAS Faculty Publications

The Eastern Tropical South Pacific is one of the three major oxygen deficient zones (ODZs) in the global ocean and is responsible for approximately one third of marine water column nitrogen loss. It is the best studied of the ODZs and, like the others, features a broad nitrite maximum across the low oxygen layer. How the microbial processes that produce and consume nitrite in anoxic waters interact to sustain this feature is unknown. Here we used ¹⁵N-tracer experiments to disentangle five of the biologically mediated processes that control the nitrite pool, including a high-resolution profile of nitrogen loss rates ...

Assessing The Potential To Decrease The Gulf Of Mexico Hypoxic Zone With Midwest Us Perennial Cellulosic Feedstock Production, Andy Vanloocke, Tracy E. Twine, Christopher J. Kucharik, Carl J. Bernacchi

Andy VanLoocke

The goal of this research was to determine the changes in streamflow, dissolved inorganic nitrogen (DIN) leaching and export to the Gulf of Mexico associated with a range of large-scale dedicated perennial cellulosic bioenergy production scenarios within in the Mississippi–Atchafalaya River Basin (MARB). To achieve this goal, we used Agro-IBIS, a vegetation model capable of simulating the biogeochemistry of row crops, miscanthus and switchgrass, coupled with THMB, a hydrology model capable of simulating streamflow and DIN export. Simulations were conducted at varying fertilizer application rates (0–200 kg N ha -1) and fractional replacement (5–25%) of current row ...

Candidate Perennial Bioenergy Grasses Have A Higher Albedo Than Annual Row Crops, Jesse N. Miller, Andy Vanloocke, Nuria Gomez-Casanovas, Carl J. Bernacchi

Andy VanLoocke

The production of perennial cellulosic feedstocks for bioenergy presents the potential to diversify regional economies and the national energy supply, while also serving as climate ‘regulators’ due to a number of biogeochemical and biogeophysical differences relative to row crops. Numerous observational and model-based approaches have investigated biogeochemical trade-offs, such as increased carbon sequestration and increased water use, associated with growing cellulosic feedstocks. A less understood aspect is the biogeophysical changes associated with the difference in albedo (a), which could alter the local energy balance and cause local to regional cooling several times larger than that associated with offsetting carbon. Here ...

Analysis Of Microbial Diversity In Disturbed Soil, Tyler G. Sanda

Honors Research Projects

This paper uses the composition and abundance of microbial species to analyze soil recovery in disturbed land. Surface mining disturbs ecological communities throughout the world. As organizations seek to reclaim these disturbed lands, a proper analysis of recovery is needed. In previous studies, recovery of disturbed land was limited to surface examinations, which do not characterize the possible unseen devastating effects of the subsoil. Soil microorganisms are extremely sensitive to environmental changes such as strip mining. It is proposed that these microorganisms may serve as better indicators of recovery post disturbance. Our analysis indicates microbial recovery, however it may not ...

Using High-Resolution Glider Data And Biogeochemical Modeling To Investigate Phytoplankton Variability In The Ross Sea, Daniel Edward Kaufman

Dissertations, Theses, and Masters Projects

As Earth’s climate changes, polar environments experience a disproportionate share of extreme shifts. Because the Ross Sea shelf has the highest annual productivity of any Antarctic continental shelf, this region is of particular interest when striving to characterize current and future changes in Antarctic systems. However, understanding of mesoscale variability of biogeochemical patterns in the Ross Sea and how this variability affects assemblage dynamics is incomplete. Furthermore, it is unknown how the Ross Sea may respond to projected warming, reduced summer sea ice concentrations, and shallower mixed layers during the next century. To investigate these dynamics and explore their ...

Calcium Carbonate Prenucleation Clusters: Towards Unification Of Classical And Non-Classical Nucleation Theory, Jonathan Avaro

Theses

The aim of this PhD was to develop analytical methods to characterize the physical and chemical characteristics of calcium carbonate prenucleation clusters and their role in the mineral nucleation process. A novel sample environment was developed to allow fast in situ and ex situ kinetic experiments when coupled to synchrotron and neutron radiation techniques. The results obtained through these experiments support findings from previous computer simulations and define the impact of pH and saturation state on the very early stages of calcium carbonate mineral formation via non-classical nucleation processes.

Terrestrial Versus Aquatic Carbon Fluxes In An Agricultural Coastal Floodplain, Jackie Roslyn Webb

Theses

In ecosystems at the terrestrial-aquatic interface, the carbon cycle is intricately connected between these two components. However, these terrestrial-aquatic carbon subsidies are often neglected in carbon budgets. This dissertation addresses the role of the aquatic pathway in the carbon budget of a “model” ecosystem representing a well constrained catchment. By combining terrestrial and aquatic methodologies, the study revealed important findings on the drivers of aquatic carbon fluxes and the relative contribution of this pathway to offsetting the land carbon sink. This study demonstrated that an interdisciplinary approach to terrestrial-aquatic ecosystems propels our understanding of carbon cycling in these systems.

The Influence Of Submarine Groundwater Discharge On Carbon, Nutrient And Greenhouse Gases Dynamics In Coastal Waters, Mahmood Sadat-Noori

Theses

This thesis documents the use of mass balance modelling combined with a multi-tracer approach, to quantify, interpret and manage coastal groundwater discharge. The dynamic characteristics of groundwater discharge requires intensive and multifaceted sampling strategies to constrain its effects on surface water quality. This thesis highlights that dissolved carbon, greenhouse gases and nutrient export from estuaries are strongly coupled to groundwater discharge therefore, should not be neglected in coastal carbon and nutrient budget studies. Results presented here indicate that even small volumetric groundwater discharge fluxes occurring on large scales play a major role in the hydrology and biogeochemistry of coastal ecosystems.

Effects Of Silvopasture Establishment On Aqueous And Gaseous Soil N Losses At The University Of New Hampshire Organic Dairy Research Farm, Kathryn Ann Slebodnik

Honors Theses and Capstones

The expansion of local agriculture in the New England region is putting increased pressure on farmers to expand their arable land base. While clear-cutting is a traditional method of converting forested land to agriculture, it is known for having adverse ecological impacts. To minimize these impacts, farmers can create a silvopasture which incorporates a portion of the original forest canopy into pastures or crop fields. This study evaluates the impact of land-use changes for agriculture on soil nitrogen (N) retention. In particular, this study investigates the differences in soil N turnover, gaseous loss, and aqueous loss among an established forest ...