Geochemistry Commons^™

Hydrothermal Carbonization Of Biomass Wastes: Sustainability And Geochemistry, Michael A. Kruge, Teresa A. Centeno, Alvaro Amado-Fierro, José Manuel González-Lafuente, Ruben Forjan-Castro, José Luis Gallego

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Introduction. To reduce the stream of solid waste going to landfills, innovative means for beneficial use are essential. The diversity and volume of organic wastes pose singular problems and opportunities for recovery and circularity. Common processes for organics include conversion to biofuels and carbonization to biochar, typically done by torrefaction (dry pyrolysis). Research on biochar explores its potential as pollutant adsorbent, agricultural or polluted soil amendment, biofuel (directly or as feedstock), and for carbon sequestration (Ighalo et al., 2022; Cavali et al., 2023). Recently, other processes at lower temperatures such as hydrothermal carbonization (HTC) offer new possibilities (Seshadri et al., …

Polygonal Faults In The Austin Chalk: Invariance Of Scale From Mud Cracks To Polygons With Implications Of Structural, Geomorphic And Isotopic Data On Polygonal Fault Geometry And Origin., Kun Shang

Earth Sciences Theses and Dissertations

The Cretaceous Austin Chalk contains large numbers of fractures and normal faults whose orientations have been attributed to either regional stresses (e.g., the Balcones fault trend) or, by analogy with the mudrocks, to polygonal faulting resulting from compaction. In this study, we present geomorphic data, field study, and stable isotope data to support that the majority of these faults in North Texas are polygonal. Field-measured fault orientations suggest randomly distributed fault strikes, indicating a polygonal fault structure. Using geomorphologic data (topographic and DEM data) on stream orientations suggests that the polygonal fault patterns are best reflected in the headwater (1st …

Thames River Subwatershed Soil, Sediment, Water Data, Justin B. Richardson, Mark J. Butler

Data and Datasets

Trace element and nutrient data are for riparian soils, suspended sediments, eddy bottom sediments, and river water collected between 2019 and 2020 in the Thames River watershed of Connecticut, USA. Trace elements and nutrients were measured using EPA 3050B digestion method and analyzed by ICP-OES or ICP-MS.

A Typological And Chemical Analysis Of Roman Oil Lamps From Poggio Del Molino, Brandon Tejo

Dissertations, Theses, and Capstone Projects

Terracotta lamps, known to the Romans as lucernae, are small, handheld, often decorated objects which provided ancient people light. To modern researchers, they serve as tools for dating stratigraphy and iconographic studies. Beyond their immediately apparent aesthetic and symbolic value, the chemical compositions of the clay of these lamps reflect their origin. This study complements archaeological typologies with chemometric analyses to describe 16 Late Republican and Imperial Roman lamps recovered from the villa at Poggio del Molino (PdM), Tuscany. These finds were recovered from the 2021 and 2022 PdM excavations. The combined approach of typology with X-ray Diffraction (XRD) …

Untangling The Nature And Timescales Of Magmatic Processes Driving Eruptions At Quiescent Volcanoes: Examples From Momotombo, Nicaragua, And Cumbre Vieja, Canary Islands, Samantha Tramontano

Dissertations, Theses, and Capstone Projects

Across all scales of human relationships (i.e. person-to-person, country-to-country, etc.), qualms can take the form of long-standing wars, quick and intense bouts, or petty exchanges. While our understanding of human behavior is ever increasing, reactions and behaviors of self and others may still come as a surprise. Expressions of disagreement can occur suddenly or following years to centuries of accumulated grievances. The solid earth is also a system that behaves (like human emotion) predictably at times and unpredictably at other times. Some volcanoes, a tangible surface expression of solid earth processes, exhibit precursory signals prior to eruption (e.g. the bulging …

Understanding The Connection Between Gypsum Blooms And Human Health At The Salton Sea, Isabel Ichiyama

Undergraduate Honors Theses

The Salton Sea is a closed hypersaline lake in Southern California that has been receiving little input over the past few decades, leading to desiccation that is rapidly increasing every year. This large-scale evaporation of the sea has led to increased dissolved solutes, high salinity, and gypsum blooms. Gypsum blooms, the precipitation of gypsum (CaSO42H2O) in the sea, have been a prominent facet of the sea and their distribution is well known. However, much of their chemistry and potential health hazards are still undetermined. Potential health effects from gypsum salt, an atmospheric dust particle present at the sea, have known …

Investigation Of The Sheep Creek Carbonatites, Ravalli County, Montana, Sarah Risedorf

Graduate Theses & Non-Theses

Carbonatite-related REE-Nb mineralization in southern Ravalli County, Montana was first discovered in the late 1950s and early 1960s. Over 30 discontinuous carbonatite bodies occur in a ~ 10 km² area centered on Sheep Creek, a tributary to the headwaters of the West Fork of the Bitterroot River (WFBR). The deposits are contained in a belt that extends to the southeast into the Mineral Hill district of Lemhi County, Idaho. Country rocks include a deformed and metamorphosed bimodal igneous suite of diabase and A-type granite, both dated to 1.37 Ga by previous workers. These rocks are locally metamorphosed to amphibolite …

Differentiating Biotic Vs. Abiotic Co2 In The Formation Of Pedogenic Carbonate In Agriculture And Natural Dryland Soils, Valeria Isabel Molina

Open Access Theses & Dissertations

Drylands, characterized by low and sporadic precipitation, require irrigation for crop growth. However, irrigation practices can lead to salt accumulation in soil due to high evaporation rates and reduced leaching. In addition to loading salts to soil, irrigation promotes the accumulation of secondary calcite. In natural systems, the formation of pedogenic carbonate (secondary calcite, CaCO3) is critical, impacting the soil properties hydrologically and biogeochemically, and modifying the global carbon cycle over geological time, albeit at a lower rate. In agricultural sites, irrigation water supplies HCO3- and Ca2+, accelerating the rates of CaCO3 formation and releasing abiotic CO2. This study investigated …

The Impact Of Glacial Proximity On The Elemental Composition Of Leachate Derived From Sediment Weathering, Karoline Ford

Theses/Capstones/Creative Projects

This study assesses chemical weathering trends as they relate to glacial retreat. The chemical environment of surfaces exposed to the atmosphere differs significantly from beneath a glacier. As a glacier melts, changes to the biogeochemical processes generate environmental gradients. This study analyzed chemical weathering signals at different distances from a glacial front by comparing the elemental composition of leachate derived from sediments in southeastern Greenland. Samples from proglacial, nonglacial, and moraine locations were weathered in a laboratory setting, and ion chromatography was used to determine the elemental composition of the products. Divergent trends in leachate composition were observed as distance …

Geochemical Analysis And Numerical Modeling Of Central And East Tennessee Mississippi Valley-Type Ore Districts: Constraints On Ore Genesis, Jackson Price Copeland

Geosciences Undergraduate Honors Theses

A simple two-way stochastic mixing model is presented for analysis of the lead (Pb) isotope compositions of the North American Mississippi Valley-Type (MVT) districts of East Tennessee, Central Tennessee, and Central Kentucky. Four distinct mixing scenarios were run to critically evaluate the stochastic model and examine different hypotheses regarding the genesis of Central Tennessee and Central Kentucky MVT deposits. Additionally, Pb isotope analysis was conducted on sphalerite samples from the Central and East Tennessee MVT districts. Model and sampling results suggest that Central Tennessee and Central Kentucky ores likely formed by mixing of three fluids. In contrast to conclusions from …

Modeled Uranium Series Disequilibria In A Heterogeneous Mantle Underlying Iceland, Dana Andersen

Honors Theses, University of Nebraska-Lincoln

Regional lithologic heterogeneities in Earth’s mantle may significantly contribute to variations in magma productivity and crustal generation. Such heterogeneities may be a key factor in the anomalously high rates of magmatism and thickened crust of Iceland, which are not fully explained by the presence of a mantle plume. However, the exact lithologic composition of the mantle underlying Iceland is largely unknown. Recent trace element modeling has suggested a two-component melt source beneath Iceland, consisting of a typical upper mantle peridotite mixing with one of several compositions of pyroxenitic material. This study further investigates these potential melt sources by calculating U-series …

Isotopic Insights Into Water Of Condensation, Cross-Formation Water Flow, And Natural Hydrocarbon Migration In Sedimentary Basins, Lisa J. Molofsky

Open Access Theses & Dissertations

This dissertation applies geochemical tools to track the movement, transformation, and behavior of water and gases in hydrocarbon-bearing sedimentary basins. During petroleum exploration and production, hydrocarbons are generated at the surface along with other fluids naturally present in the formation, such as formation water. In addition, where hydraulic fracturing is used to stimulate shale gas and oil production, a percentage of the injected fracturing fluid also returns to the surface. Understanding the origin and movement of these water sources, as well as targeted and non-targeted hydrocarbon gases is critical to evaluating reservoir performance and properly managing fluids at the surface. …

Impacts Of Preferential Flow On Tc-99and Np-237 Vadose Transport In Soils At The Savannah River Site, Josh Parris

All Theses

Since the 1950s, the United States has produced approximately 90,000 metric tons of spent nuclear fuel (SNF) (Office of Nuclear Energy, 2022); however, no long-term storage solutions are available. Technecium-99 and neptunium-237, two fission products found in SNF, readily form highly mobile species in oxidizing conditions (Hu, 2008; Bondietti, 1979) and have respective half-lives of 2.13 x 10⁵ and 2.14 x10⁶ years (Hu, 2010). Considering these characteristics, ⁹⁹Tc and ²³⁷Np are two risk-driving isotopes found in SNF storage. The process of macropore-facilitated preferential flow, transport through cracks within a soil matrix, has been recognized to increase …

Quantifying Heterogeneity Along A Hillslope Using Seismic Refraction, Structure From Motion, And X-Ray Fluorescence In The Piedmont, South Carolina, Leah Topping

All Theses

The critical zone (CZ) is the life sustaining outer layer of the earth that spans from the top of unweathered bedrock to the tops of the trees. This dynamic zone is always evolving because a variety of chemical, physical, and biological processes transform bedrock into regolith, creating a spatially heterogeneous CZ architecture. This study aims to investigate the relationships between regolith thickness, seismic velocities, and chemical profiles as a function of slope position and it is hypothesized bedrock composition, fracture density, and foliation are the key factors controlling the physical heterogeneity in the top 1-2 meters of the CZ. To …

Evaluating Bulk Carbon And Nitrogen Isotope Compositions Of Acidic Hydrothermal Sediments On Earth– Implications For Mars Astrobiology, Chance Sturrup

Masters Theses

Carbon isotopes have been widely used as unique biosignatures because biologic processes commonly result in distinctive negative delta ¹³C values (-35 to -10 ‰) within organic material on Earth. However, the bulk delta ¹³C analysis in Gale crater sediments on Mars revealed a wider range of values, from -25 to +56 ‰ (Franz et al., 2020), which suggests a more complex origin. To determine if bulk isotope analysis can be successfully used to detect a microbial signature in a martian analog environment, we analyzed concentrations and isotope compositions of C within hydrothermal sediments in Iceland (Námafjall, Krýsuvík, Hveragerdi) …

Comparing Igneous Geochemical Data From Hawaii And Southern California Via Machine Learning, Miro Manestar

MS in Computer Science Project Reports

Bi-plots are commonly used in geochemical analyses. However, their use can become cumbersome in the case of multi-variate analyses. Therefore, this thesis explores the application of unsupervised machine learning techniques, specifically PCA and K-Means, to analyze large geochemical data sets from two distinct regions, Hawaii and the \acrfull{prb} in Southern California. The IBM Foundational Methodology for Data Science was utilized to ensure proper data preparation and analysis. PCA provided dimensionality reduction, revealing which features correlated most strongly with variances within the data. K-Means clustering allowed for deeper interpretation of the data. The analysis yielded valuable insights into the composition and …

The Phosphorus Puzzle: Why Metal Phosphites Could Be The Missing Piece, Eleanor Boyle, Thomas J. Leyden Iii

Symposium of Student Scholars

It is well understood that phosphorylation of organic molecules is a keystone mechanism toward developing early cell function. However, the source of phosphorous in prebiotic chemistry is under debate. Phosphate minerals were abundant on the early Earth, but they are highly insoluble. In comparison, metal phosphites are significantly more soluble. While they may not have been preserved in the geological record, there are several plausible pathways for their formation under prebiotic conditions. We hypothesize that metal phosphites were a major source of phosphorus. To test our hypothesis, we synthesized and characterized metal phosphites, containing the most abundant cations on the …

Concept Validation: Collecting Composite Samples To Understand The Presence Of Per- And Polyfluoroalkyl Substances (Pfas) In Michigan Forested Areas, Nicole Renee Sanabria

Masters Theses

This research discusses the results of a state-wide study conducted by The Michigan Department of Environment, Great Lakes, and Energy to assess the presence of PFAS in shallow soils of state-owned forested areas in Michigan utilizing a composite sampling method. One sample collected from each of Michigan’s 83 counties reveals the presence of PFAS in all but one sample, with total PFAS concentrations ranging from non-detect to 2.016 μg/kg (dry weight). PFOS is generally detected at the highest concentrations, ranging from non-detect to 0.88 μg/kg, followed by PFBA, with concentrations ranging from non-detect to 0.69 μg/kg, and PFOA, with concentrations …

The Fate Of Carbonate Rocks During Hypervelocity Impacts: Case Studies From Three Impact Structures On Earth, Nicolas D. Garroni

Electronic Thesis and Dissertation Repository

Approximately 28% of all hypervelocity impact structures discovered on Earth exist in a carbonate-dominated target sequence. Despite decades of research, how carbonate rocks and minerals react to shock metamorphism is still poorly understood. In this contribution, three impact structures on Earth were studied to determine the effects of shock metamorphism on carbonate minerals: Chicxulub, Crooked Creek and Jebel Waqf as Suwwan.

At Chicxulub, carbonates from the impact-melt bearing breccia of drill core, M0077A were characterized petrographically and geochemically. Calcite was the only carbonate mineral present and is abundant throughout the impact breccia in five distinct varieties: limestone clasts …

Assessing Ecosystem Health Through Contaminants In The Tijuana River National Estuarine Research Reserve, Nancy Torres

Theses

Although the Tijuana River Estuary (TRE) remains the largest, most-intact coastal wetland in Southern California, it has a history of major changes, much of this related to its location immediately north of the US / Mexico Border. One of the primary challenges is cross-border flows from the rapidly growing city of Tijuana, Baja California, Mexico, and the delivery of wastewater, debris, and sediment to sensitive coastal wetland ecosystems. There is a need to more fully investigate these environmental changes to assess the ecosystem health of the Tijuana River Estuary over time, especially related to pollution impacts. This can inform an …