Materials Science and Engineering Commons^™

Core-Shell Copper And Nickel Nanofoam: Uniform Electroplating And Properties, Hassan Zbib, David Bahr

The Summer Undergraduate Research Fellowship (SURF) Symposium

Characterizing materials on the nanoscale is a key factor to enhance nanotechnology in diverse applications, ranging from electronics to energy fields. However, controlling the structure of the material at the nanoscale or mimicking the nanoscale features of a structure that already exists requires linking processing conditions to the nanostructure. This work focuses on solids that show porous patterns at the nano-micro scale; these are often called cellular solids and classified into two categories: honeycombs and foams. This study focuses on nanofoams; with ligament dimensions in the sub-micron scale. Electrospinning has been developed to produce nanofoam structures of polymers with controlled …

Structure-Force Field Generator For Molecular Dynamics Simulations, Carlos M. Patiño, Lorena Alzate, Alejandro Strachan

The Summer Undergraduate Research Fellowship (SURF) Symposium

Atomistic and molecular simulations have become an important research field due to the progress made in computer performance and the necessity of new and improved materials. Despite this, first principle simulations of large molecules are still not possible because the high computational time and resources required. Other methods, such as molecular dynamics, allow the simplification of calculations by defining energy terms to describe multiple atom interactions without compromising accuracy significantly. A group of these energy terms is called a force field, and each force field has its own descriptions and parameters. The objective of this project was to develop a …

Cylindrical Shell Based Phase Transforming Cellular Materials: Designing A Recoverable Energy Dissipating Material, Gordon F. Jarrold, David Restrepo, Nilesh Mankame, Pablo Zavattieri

The Summer Undergraduate Research Fellowship (SURF) Symposium

Energy dissipating materials are used in a variety of impact events to protect more important parts of a system; one example of this is a football player’s helmet protecting a brain. A major drawback to classic energy dissipating materials however is that they dissipate energy through plastic deformation, meaning that after a single use, permanent deformations will prevent the material from being reusable to the same capacity as initially. We have designed a 1D cellular material in which geometric phase transformations in cylindrical shell elements are the primary energy dissipating mechanism, allowing for recoverability after use while keeping high energy …

Effect Of Particle Interactions On Powder Flow Behavior, Ivana A. Penagos, Carolina P. Mora, Teresa Carvajal

The Summer Undergraduate Research Fellowship (SURF) Symposium

The study of powder flow behavior is essential for the development of processing technologies in many industries. In fact, powders have a major function in diverse types of manufacturing, such as pharmaceuticals, foods, chemicals, materials, minerals and cosmetics. This leads to an increasing demand for the development of reliable methods to assess powder flow problems in industry. This research intends to provide a general insight into how surface interactions and particle properties may alter powder flowability. The materials used for this study were lactose, starch, milk powder, cocoa and chocolate. These vary in their interparticle forces as well as on …

Atomistic Simulations Of Novel Nanoscale Semiconductor Devices: Resistance Switches And Two-Dimensional Transistors, Joseph P. Anderson, Mahbubul Islam, David Guzman, Alejandro Strachan

The Summer Undergraduate Research Fellowship (SURF) Symposium

As transistors get smaller, we are achieving record levels of memory density. However, there is a limit to how small transistors can be made before their functionality breaks down. Thus alternatives to traditional transistor technology are needed. The two such technologies we examined are: resistance switching devices, which reversibly grow metal filaments through a dielectric, and two-dimensional transistors, which are capable of breaking through the scalability limit of traditional transistors. In order to design resistance switching devices which create filaments with some level of consistency, the dynamics of the filament formation need to be explored. Herein we model this process …

Study Of Persistent Slip Bands Formed By Low Cycle Fatigue On Nickel-Based Superalloys At Room Temperature, Anjola Uprety, Sae Matsunaga, Michael S. Titus Dr., Michael D. Sangid Dr., Alberto W. Mello Dr.

The Summer Undergraduate Research Fellowship (SURF) Symposium

The ability of Ni-based superalloys to withstand temperatures in excess of 1100⁰C makes them useful for applications in the hottest components in jet engines, gas turbines, and thrust engines. Increasing the efficiency of these gas turbine engines helps to reduce the fossil fuel consumption and the production of greenhouse gasses. A common mode of failure in these Ni-based superalloys is low cycle fatigue, in which narrow regions of high dislocation density, which are known as persistent slip bands (PSBs), can develop and lead to crack initiation. A detailed understanding of the formation and structure of PSBs has eluded …

Comparison Of Pm-Hip To Cast Alloy 625 For Nuclear Applications, Alexander L. Bullens, Keyou Mao, Janelle P. Wharry, Esteban Bautista

The Summer Undergraduate Research Fellowship (SURF) Symposium

PM-HIP, or Powder Metallurgy and Hot Isostatic Pressing, metals have been a low cost alternative to forged and cast structural metals within various industries. The nuclear industry has recently developed interest in PM-HIP alloys, but further research needs to be done to quantify their mechanical properties and characterize the microstructure. Specifically, we must understand the mechanical and microstructural evolution of PM-HIP materials after long-term operation at the elevated temperatures that PM-HIP components will experience in service. We focus on Ni-base alloy Inconel 625, and compare the PM-HIP version to the cast version. Our methodology consists of annealing samples to various …

Improving Methods Of Doping On Black Phosphorus, Yuqin Duan, Adam Charnas, Jingkai Qin, Peide Ye

The Summer Undergraduate Research Fellowship (SURF) Symposium

Black phosphorus (BP) is a 2D semiconducting material with high carrier mobility. It is usually p-type due to oxidation states near its valence band. Although achieved through other growth methods, n-type doping has not yet been accomplished through the modern chemical vapor transport (CVT) growth method. To address this issue, small amounts of tellurium were added to Red Phosphorus to act as a dopant during the CVT growth process in addition to tin(Sn) and tin(IV) iodide, which facilitate growth. The chemicals are heated up to 600°C and precisely cooled in a 21-hour process, during which BP crystals should form. After …

Residual Stress Measurements On The Tig Weld Joint Of 57fe15cr25ni Austenitic Steel For Structural Material Applications By Means X-Ray Diffraction Techniques, Parikin Parikin, Agus Hadi Ismoyo, Riza Iskandar, Arbi Dimyati

Makara Journal of Technology

Measurements of residual stress on the 57Fe25Cr15Ni steel plate with no-filler TIG-welding process were carried out. This work was conducted to determine the nature of weld ability in synthesized steel. The bulks were formed in a dimension of 30x20x7 mm3 to ease data retrieval. Results show that the largest residual stress occurred in the weld metal area, amounting to 82.40 MPa with lattice stretching of 0.18%. Conversely, the values decreased to 65.92 MPa and a stretch of 0.14% in the HAZ area. This residual stress is a tensile stress that can reduce the mechanical strength of the material since it …

Personality Trait Based Intervention For Workplace Accident Prevention, Yassierli Yassierli, Nurhayati Nurhayati, Marisa Anatasia, Shamsul Bahri

Makara Journal of Technology

Previous research has suggested that some traits may be useful as the predictors of risk behaviours behaviors. Therefore, personality traits seem to play a role in accident involvement. The purpose of this study is was to explore the relationship between the personality traits based on the Big Five Inventory (BFI) and worker accident experiences in order to elaborate personality traits based intervention for workplace accident prevention. A cross cross-sectional study was conducted among 173 workers in a cement company using a set of questionnaires consisting of respondents’ characteristics, BFI, and self-reported accident experience. The correlations were computed using Goodman Kruskal’s …

Urban Drainage Management And Flood Control Improvement Using The Duflow Case Study: Aur Sub Catchment, Palembang, South Sumatra, Indonesia, Charlotte De Fraiture, Robiyanto Hendro Susanto, F.X. Suryadi, Harrini Mutiara Hapsari Wahyu

Makara Journal of Technology

Urban flooding often times staggers the livelihood in an urban area, which most likely happens in the lowland urban area. Therefore, the existing urban drainage system should be improved in order to tackle the upcoming urban flooding events, which are more than likely to be more devastating than those in the previous years. The research location is in Palembang, Sumatra, Indonesia, where 30% of its urban part is a lowland area. The selected Aur Sub Catchment is located in Silaberanti. The main objective of this research is to improve the current drainage system in order to achieve the optimal design …

Ethanol Purification Using Activated Natural Zeolite, Chandra Wahyu Purnomo, Nelliza Putri, Indra Perdana, Hirofumi Hinode

Makara Journal of Technology

Bio ethanol is one of the potential fuels in the future. However, ethanol in water mixture has an azeotropic concentration of 95.6 wt. %, which makes it difficult to purify further. The common method of purification is by using an azeotropic distillation column, which requires an intensive energy and an addition of specific solvent. In this study, ethanol purification is done using an adsorption column packed with zeolite Raschig rings. The natural zeolite ring was modified beforehand using the NaOH solution to enhance the material’s water adsorption performance. The ethanol purity can reach more than 99% with the modified zeolite …

An Efficient Palladium-Thiourea Catalysed Heck Cross-Coupling Reaction For Molecular Electronic Interest, Wan M. Khairul, Mohd Shahrul Shahmi Md Shariff, Rafizah Rahamathullah, Adibah Izzati Daud, Mustaffa Shamsuddin, Siti Kamilah Che Soh

Makara Journal of Technology

The synthesis and utilization of C-C bonds formation are concerned about the key steps for the building of several conducting molecular electronics involving many asymmetric catalysts approached, which is an essential task that most researchers would ignore in preparing these materials to enhance the production yield of cross-coupling materials. Despite the enormous progress, there still remains a great demand for economic and practicable cross-coupling processes involving ultra-low catalyst loadings with high turnover numbers due to the employment of conventional metal catalyst. Thus, there has been an excessive interest to cultivate non-phosphine palladium catalysts for excellent achievement of activity, stability, and …

A Study On Dielectric Properties Of The Cellulose Derivative-Nh4br-Glycerol- Based The Solid Polymer Electrolyte System, Nur Muhitul Jalilah Rasali, Saifful Kamaluddin Muzakir, Ahmad Salihin Samsudin

Makara Journal of Technology

The characterization of biopolymer-based solid polymer electrolytes (SPEs) has been carried out in this present work. Cellulose derivative was chosen due to its superior physical attributes. In this work, NH4Br-doped glycerol plasticized carboxyl methylcellulose-based SPEs were successfully prepared via the solution casting method. The conductivity and dielectric properties of the prepared films were investigated using the impedance analysis which presented ~1.91×10-3 Scm-1 (with addition of 6 wt% of glycerol). In addition, the studied SPE system shows a non-Debye behaviour without a single relaxation time. The findings of the research indicate that the complexes of NH4Br and glycerol in the cellulose …

Physical And Mechanical Properties Of Palm Kernel Oil-Based Polyester Polyurethane/Multi-Walled Carbon Nanotube Composites, Khairul Anuar Mat Amin, Muhammad Alif Zailani, Nurul Nabilah Zulkifli, Khairiah Haji Badri

Makara Journal of Technology

In this study, polyurethane (PU) films from palm kernel oil-based polyester (PKO-p) incorporated multi-walled carbon nanotubes (MWNTs) are prepared via a evaporative casting method. Nanoparticle fluid dispersions containing 0.02%, 0.03%, and 0.05% wt. of MWNTs are added into PKO-p based resin and mixed by digital probe sonicator for 30 min followed by mixing with isocyanate to produce PU-MWNTs composite films. The mechanical properties, swelling, water vapour transmission rate (WVTR) and conductivity of the PU-MWNTs composite films are examined. Results show that the toughness (T) or flexibility, the tensile strength (TS), and Young’s modulus (YM) values of PU-MWNTs composite films increase …

Spectroscopic Contrast Of Diarylethene Molecules On Octanethiol Monolayer, Arramel Arramel, Tibor Kudernac, Nathalie Katsonis, Bernard Lucas Feringa, Bart Jan Van Wees

Makara Journal of Technology

We present a systematic scanning tunneling microscopy (STM) study of bias-dependent imaging of disulfur diarylethene (2S-DE) molecules on octanethiol (C8) monolayer at room temperature. In a rigid confinement of the C8 matrix, we did not observe any significant variation in the appearance of the 2S-DE. On the contrary, a reversal in the apparent height of the 2S-DE was present when the molecule was situated on a gold vacancy island. We attributed this finding to the presence of a new electronic state that became accessible for a tunneling event. In addition, the C8 surface structure underwent a reversible phase transformation from …

Viscoelastic Analysis And Fatigue Characterization Of Bituminous Materials In Two Length Scales Under The Influence Of Aging, Santosh Reddy Kommidi

Department of Civil and Environmental Engineering: Dissertations, Theses, and Student Research

Fatigue cracking in asphalt concrete (AC) is of immense importance to pavement design and analysis because it is one of the most important forms of distress that can lead to structural failure in pavement. Once started, these types of cracks can be combined with other environmental factors leading to detrimental effects such as faster rates of pavement deterioration and shortened pavement life and functionality.

Currently AASHTO TP101, also known as linear amplitude sweep (LAS) specification, is being widely used to evaluate the ability of an asphalt binder to resist fatigue. The LAS method, although mechanistic in its approach, has certain …

Usage Of Fomblin Y To Improve Water Repellence Of Surface Coatings, Shawn Pj Kirby, Jeffrey Alston, Andrew Guenthner

STAR Program Research Presentations

Fluoro-Decyl POSS (FDP) has shown strong potential as a water repellant surface coating. Additionally, Fomblin is a solvent believed to have the ability to control the crystallization of POSS compounds on surfaces. Controlling the crystallization is key to improving water repelling abilities of surfaces. Thus, dip coating FDP and Fomblin onto surfaces is being investigated for water repulsion, mechanical stability, and deposition feasibility. Relative water repelling abilities of different coatings were determined by measuring contact angle of surfaces with water. Coatings with and without POSS and Fomblin were compared. It was shown that the surfaces treated with both POSS and …

Usage Of Fomblin Y To Improve Water Repellence Of Surface Coatings, Shawn Pj Kirby, Jeffrey Alston, Andrew Guenthner

STAR Program Research Presentations

Fluoro-Decyl POSS (FDP) has shown strong potential as a water repellant surface coating. Additionally, Fomblin is a solvent believed to have the ability to control the crystallization of POSS compounds on surfaces. Controlling the crystallization is key to improving water repelling abilities of surfaces. Thus, dip coating FDP and Fomblin onto surfaces is being investigated for water repulsion, mechanical stability, and deposition feasibility. First, temperature dependence of solubility of Fluoro-Decyl POSS in Fomblin was tested using Dynamic Light Scattering. Relative water repelling abilities of different coatings were determined by measuring contact angle of surfaces with water. Coatings with and without …

Comparative Solubility Of Poss Compounds In Fomblin Y, Shawn Pj Kirby, Jeffrey Alston, Andrew Guenthner

STAR Program Research Presentations

Fluoro-Decyl POSS (FDP) has shown strong potential as a water repellant surface coating. Additionally, Fomblin is a solvent believed to have the ability to control the crystallization of POSS compounds on surfaces. Controlling the crystallization is key to improving water repelling abilities of surfaces. Thus, dip coating FDP and Fomblin onto surfaces is being investigated for water repulsion, mechanical stability, and deposition feasibility. However, in order for this to be successful, POSS must be soluble in Fomblin. Temperature dependence of solubility of Fluoro-Hexyl, Fluoro-Octyl, Fluoro-Decyl POSS in Fomblin was tested using Dynamic Light Scattering. The values were compared, and it …

Lb3d: A Parallel Implementation Of The Lattice-Boltzmann Method For Simulation Of Interacting Amphiphilic Fluids, S. Schmieschek, L. Shamardin, S. Frijters, T. Krüger, U. D. Schiller, J. Harting, P. V. Coveney

Publications

We introduce the lattice-Boltzmann code LB3D, version 7.1. Building on a parallel program and supporting tools which have enabled research utilising high performance computing resources for nearly two decades, LB3D version 7 provides a subset of the research code functionality as an open source project. Here, we describe the theoretical basis of the algorithm as well as computational aspects of the implementation. The software package is validated against simulations of meso-phases resulting from self-assembly in ternary fluid mixtures comprising immiscible and amphiphilic components such as water–oil–surfactant systems. The impact of the surfactant species on the dynamics of spinodal decomposition are …

Deformation Behavior Of Al/A-Si Core-Shell Nanostructures, Robert Andrew Fleming

Graduate Theses and Dissertations

Al/a-Si core-shell nanostructures (CSNs), consisting of a hemispherical Al core surrounded by a hard shell of a-Si, have been shown to display unusual mechanical behavior in response to compression loading. Most notably, these nanostructures exhibit substantial deformation recovery, even when loaded much beyond the elastic limit. Nanoindentation measurements revealed a unique mechanical response characterized by discontinuous signatures in the load-displacement data. In conjunction with the indentation signatures, nearly complete deformation recovery is observed. This behavior is attributed to dislocation nucleation and annihilation events enabled by the 3-dimensional confinement of the Al core. As the core confinement is reduced, either through …

Mitigation And Evaluation Of Alkali-Silica Reaction (Asr) And Freezing And Thawing In Concrete Transportation Structures, Richard Albert Deschenes Jr.

Graduate Theses and Dissertations

An evaluation of alkali-silica reaction (ASR) and freezing and thawing (F/T) in concrete transportation structures is presented along with mitigation methods for slowing the rate of deterioration in concrete. A combination of field and laboratory testing confirms ASR deterioration is exacerbated by exposure to F/T. Laboratory testing indicates an aggregate previously deemed inert to ASR, caused ASR deterioration in several concrete pavement and transportation structures. Existing standard test methods deem this aggregate safe for use in concrete. A modified test method shows the concrete can deteriorate rapidly when subjected to cycles of conditions promoting ASR and F/T. Several structures containing …

Optimization Of Concrete Mixtures For Use In Structural Elements, Waleed Almutairi

Graduate Theses and Dissertations

Portland cement is an essential ingredient in concrete. The use of cement is to enhance the strength as well as other hardened properties of concrete mixtures. Determining the accurate amount of cement is important because the required strength may not be achieved if not enough cement is used. By contrast, when using too much cement, concrete cracking may occur that leads to reducing durability. Researchers at the University of Arkansas (UA) have shown that many bridge decks achieve their 28 day design strength of 4000 psi by 7 days of age. Bridge decks having high strength may experience cracking, which …

Nanosilica Based 3d Printed Scaffold Facilitate Osteoblast Mineral Formation, Tugba Cebe

Material Science and Engineering Theses - Archive

Bone has the ability to heal fractures so long as the size of the fracture is sufficiently small. If the defect is large or of critical size, a filling material or graft will be needed to help bone union. Among all the available methods to address this medical condition, the common drawback of grafts is that they are limited in supply since a biological site or organism is needed to harvest the biological graft. As a new approach, researchers have been working with bioceramics and biopolymers for their use in bone tissue engineering. In this work, chitosan was modified with …

Processing Beta-Tricalcium Phosphate And 45s5 Bioglass Mixtures For Osteogenic Bone Tissue Scaffolds, Phillip Zachary James

Material Science and Engineering Theses - Archive

A 30% 45S5 Bioglass and 70% -tricalcium phosphate ceramic mixture, which was previously shown to be osteogenic [1], was sintered and the process was investigated as a strengthening mechanism. Samples were sintered for dwell times of 1,2, and 4 hrs at 500°C to avoid crystallization of the 45S5 Bioglass. Two different binders were used, 2% gelatin in deionized water and 2% laponite with 2% oleic acidin deionized water. The mixture was also robocasted as a slurry to evaluate the manufacturing process. Mechanical compression testing shows that the laponite with oleic acid binder acted as a sintering aid leading to a …

Investigation Of Microstructure Effects On Hardness And Oxidation Resistance Of New Generation Ceramic Coatings, Minghui Zhang

Material Science and Engineering Dissertations - Archive

This work was motivated by the demand for a new generation of materials capable for harsh environment applications, and focused on developing a better understanding of the effects of elemental composition and microstructure on the mechanical and thermal properties of coatings. The knowledge gained from this work can be used to design protective coatings with tailored properties for harsh environment applications in the future. High resolution transmission electron microscopy (HRTEM) and electron diffraction have been mainly employed in the microstructure studies of the new generation ceramics, with the assistance of other materials characterization techniques, such as x-ray diffraction (XRD), x-ray …

Phase Separation In Ti-6al-4v Alloys With Boron Additions For Biomedical Applications: Scanning Kelvin Probe Force Microscopy Investigation Of Microgalvanic Couples And Corrosion Initiation, P. H. Davis, K. Robles, K. Livingston, S. Johns, V. A. Ravi, E. Graugnard, M. F. Hurley

Materials Science and Engineering Faculty Publications and Presentations

To investigate the effect of boron additions on the corrosion behavior of Ti-6Al-4V for potential use in biomedical implants and devices, cast samples of Ti-6Al-4V were alloyed with 0.01% to 1.09% boron by weight and subjected to hot isostatic pressing. Subsequent analysis via scanning Kelvin probe force microscopy and scanning electron microscopy/energy-dispersive spectroscopy revealed the presence of both alpha (α) and beta (β) phase titanium, enriched in aluminum and vanadium, respectively. At all concentrations, boron additions affected the grain structure and were dispersed throughout both phases, but above the solubility limit, needle-like TiB structures also formed. …

Cellulose Reinforced Thermoplastic Composites By In-Situ Ring-Opening Polymerization, Shahab Kashani Rahimi

Dissertations

Over the past two decades, the increasing concern about the negative environmental impacts of synthetic materials has led to rising interests in utilizing renewable natural resources to develop polymer materials with comparable properties and performance to their synthetic counterparts. One of the major fields of interest is polymer composites where the replacement of synthetic fibers with bio renewable natural fibers is of great potential. However, the processing difficulties, in terms of fiber dispersion and thermal stability have limited the application of cellulosic fibers to polymers with low processing temperatures which are mostly hydrophobic polymers. As a result, the true reinforcing …

Membranes For Food And Bioproduct Processing, Alexandru Marius Avram

Graduate Theses and Dissertations

Modified membranes for process intensification in biomass hydrolysis

Production of biofuels and chemicals from lignocellulosic biomass is one of the leading candidates for replacement of petroleum based fuels and chemicals. However, conversion of lignocellulosic biomass into fuels and chemicals is not cost effective compared to the production of fuels and chemicals from crude oil reserves. Some novel and economically feasible approaches involve the use of ionic liquids as solvents or co-solvents, since these show improved solvation capability of cellulose over simple aqueous systems. Membranes offer unique opportunities for process intensification which involves fractionation of the resulting biomass hydrolysate leading to …