Materials Science and Engineering Commons^™

Parametric Analysis Of Particle Spreading With Discrete Element Method, Yuxuan Wu

Doctoral Dissertations and Master's Theses

The spreading of metallic powder on the printing platform is vital in most additive manufacturing methods, including direct laser sintering. Several processing parameters such as particle size, inter-particle friction, blade speed, and blade gap size affect the spreading process and, therefore, the final product quality. The objective of this study is to parametrically analyze the particle flow behavior and the effect of the aforementioned parameters on the spreading process using the discrete element method (DEM). To effectively address the vast parameter space within computational constraints, novel parameter sweep algorithms based on low discrepancy sequence (LDS) are utilized in conjunction with …

Fourier Transform Infrared Spectroscopy For The Measurement Of Gesn/(Si)Gesn, Solomon Opeyemi Ojo

Graduate Theses and Dissertations

Photoluminescence (PL) and Electroluminescence (EL) characterization techniques are important tools for studying the optical and electrical properties of (Si)GeSn. Light emission from these PL and EL measurements provides relevant information on material quality, bandgap energy, current density, and device efficiency. Prior to this work, the in-house PL set-up of this lab which involves the use of a commercially-obtained dispersive spectrometer was used for characterizing both GeSn thin film and fabricated devices, but these measurements were limited by issues bordering on low spectral resolution, spectral artifacts, and poor signal-to-noise ratio (SNR) thereby resulting in the possible loss of vital information and …

Dyeing Properties And Color Fastness Of Eri Silk Yarn Dyed With Soaked Red Kidneybean Water, Piyaporn Kampeerapappun, Kritsana Wongwandee, Siriluk Janon

Journal of Metals, Materials and Minerals

The purpose of this research was to study the dyeing of eri silk yarn using soaked red bean water. The optimal condition for preparing dye solutions was a ratio of 1:5 of dried red bean to water and dyeing at 100°C for 45 min. The dyeing process was conducted with and without mordants, using three different mordanting methods; pre-mordanting, meta-mordanting, and post-mordanting. The effects on silk analyzed are color fastness to washing, wet and dry rubbing, acid and alkali perspiration, and color characteristics on CIEL*a*b* color coordinates.Without mordants, the dyed silk yarn gave a rosy brown color. Each mordant caused …

Soldering Of Copper Using Graphene-Phosphoric Acid Gel, Gurudatt Puranik, Asis Sarkar, Nirankar Mishra, Sangam Chandrasekhar Gurumurthy, Shridhar Mundinamani

Journal of Metals, Materials and Minerals

Soldering is a physical process in which one metal melts and joins the other to form a strong bond,which further helps in electron conduction and increases the mechanical strength in any electronic circuits. The present work demonstrates the development of graphene-based flux comprising of 2 g of graphene and 2 ml of phosphoric acid for the residue-free, high stability, durable, and two-stepsoldering of copper wire on to the surface of the copper-based printed circuit board. The soldering fluxcan be applied to the copper, and wire can be soldered in ambient conditions using commercial solderingiron at a standard soldering temperature of …

Preparation And Properties Of Fired Clay Bricks With Added Wood Ash, Anuwat Srisuwan, Supachai Sompech, Chiawchan Saengthong, Sukhontip Thaomola, Prinya Chindraprasirt, Nonthaphong Phonphuak

Journal of Metals, Materials and Minerals

This study was designed to determine the effects of wood ash on the physical and mechanical properties of fired clay bricks. The clay bricks were fabricated with the addition of 0, 4, 8, 12, and 16% by weight of wood ash. Strength development of brick was cased byfired at 900, 1000, and 1100°C for 40 min. The experimental results demonstrated that the physical property and strength of the fired clay bricks depend on the wood ash contentand firing temperature. Higher wood ash content affected an increase in porosity and water absorption, while the bulk density of the clay brickswas reduced. …

Mechanical Characterization And Wear Behavior Of Aerospace Alloy Aa2124 And Micro B4c Reinforced Metal Composites, Fazil N, V Venkataraman, Madeva Nagaral

Journal of Metals, Materials and Minerals

In the present investigation, the mechanical and wear properties of aerospace alloy AA2124-9wt%of B4C composites were displayed. The composites containing 9wt% of micro boron carbidein AA2124 alloy were synthesized by liquid metallurgy method through stir casting. For the composites, reinforcement particles were preheated to a temperature of 400°Cand afterward added in ventures of two stages into the vortex of liquid AA2124 alloy compound to improve the wettability anddispersion. Microstructural examination was carried out by SEM and elemental investigation was finished by EDS. Mechanical and wear properties of as cast AA2124 alloy and AA214-9wt% of B4C composites were evaluated as per …

Quenched And Tempered High Strength Steel:A Review, Gadadhar Sahoo, Krishna Kumar Singh, Vinod Kumar

Journal of Metals, Materials and Minerals

Quenched and tempered steel are broadly classified as low alloy conventional grades with C contentof 0.15-0.40% and tool steels with C content as high as 2% alloyed with strong carbide forming elementssuch as Cr, V, Mo etc. in the range of 1-12%. In both the cases, steels are used in hardened/quenchedand tempered or auto tempered condition for improved toughness, strength and wear resistance. The C content and tempering temperature are optimized based on desired application. However, achieving high strength/hardness along with adequate toughness is a challenge. The chemistry designis one of the important parts of developing these grades. The judicious …

Characterization Of Tio2-Activated Carbon Onto Adsorption And Photocatalytic Propertiesand Its Application, Mark Chobchun, Pasakorn Jutakridsada, Puttiporn Thiamsinsangwon, Pornnapa Kasemsiri, Khanita Kamwilaisak, Prinya Chindaprasirt

Journal of Metals, Materials and Minerals

This study investigates the characterization of TiO2in conjunction with activated carbon(AC) on its adsorption and photocatalytic properties. TiO2in theabsence and presence of AC were preparedby the sol-gel method. TiCl4was used as a precursor to reduce using acidic solution during preparationprocess. The effects of the amount of AC on the characteristics of composites were investigated. TGA technique was used to evaluate the amount of TiO2and AC in TiO2/AC composite. The adsorptionproperties of TiO2/AC were characterized using XRD, TEM, N2adsorption/desorption, FTIR and UV - Visdiffuse reflectance spectroscopy techniques. The photocatalytic activitiesof the composites were investigated by measuring the removal of acid dye. …

The Usage Of Coal−Layered Double Oxide For Removal Of Toxic Dye Fromaqueous Solution, Pornnapa Tongchoo, Sonchai Intachai, Prakaidao Pankam, Chomponoot Suppaso, Nithima Khaorapapong

Journal of Metals, Materials and Minerals

CoAl−layered double oxide derived from calcination of CoAl−layered double hydroxide at400Cfor 120 min, delivered the change in microstructure with increasing surface area. Spinel Co3O4was the majority in the product as confirmed by X-ray diffraction, and Fourier transform infrared andUV-visible spectroscopies. The calcined product, CoAl−layered double oxide resulted in significantadsorption capacity on dye removal superior to that of CoAl−layered double hydroxide. The adsorbed amounts of the diverse dyes increased as follows: methylene blue phenolphthaleinmethyl orange orange II. The adsorption affinity between adsorbent and dyes relied on electrostatic interaction and physical adsorption.

Laser Powder Bed Fusion Of Ti6al4v Lattice Structures And Their Applications, Thywill Cephas Dzogbewu

Journal of Metals, Materials and Minerals

The study focused on producing lattice structures using rhombic and diagonal nodes and indicatingtheir logical biomedical and engineering applications. Laser powder bed fusion manufacturingtechnology a subset of additive manufacturing was used to manufacture the lattice structures with different struts geometry. Average elastic modulus value of 5.30.2 GPa was obtained for therhombic lattice structures and 5.10.1 GPa for the diagonal lattice structures. Generally, the mechanicalproperties of the lattice structures produced could be logically considered suitable for biomedical and engineering applications. The mechanical properties of the lattice structures could be fine-tunedfor a specific engineering or biomedical applications by varying the lattice properties …

Ultraviolet‐Shielding And Water Resistance Properties Of Graphene Quantum Dots/Polyvinyl Alcohol Composite-Based Film, Sutthipoj Wongrerkdee, Pichitchai Pimpang

Journal of Metals, Materials and Minerals

The Ultraviolet‐shielding (UV‐shielding) and water resistance properties of graphene quantum dots/polyvinyl alcohol (GQDs/PVA) composite-based film have been investigated. The GQDs/PVA composite-based films were fabricated with different GQDs concentrations of 0, 5, 10, 15, and 20 wt%. The optical property of GQDs was carried out by utilizing fluorescence spectroscopy. Characterizationsof GQDs/PVA composite-based films were performed byusing FT-IR spectroscopy, and UV-vis spectroscopy. It was found that GQDs exhibited the strongest excitation wavelength in the UV range. GQDs/PVA composite-based films offered an improved UV-shielding capacity when compared to PVA films and glass. Particularly, the GQDs/PVA composite-based film containing 20 wt% GQDs exhibited a …

Impact Of Boron Carbide And Graphite Dual Particulates Addition On Wear Behavior Of A356 Alloy Metal Matrix Composites, Pankaj R. Jadhav, Madeva Nagaral, Shivakumar Rachoti, Jayasheel I. Harti

Journal of Metals, Materials and Minerals

The current work gives the detailed microstructural analysis and wear behaviour of aluminiumalloy A356 based metal matrix composite. Here, boron carbide (B4C) and graphite (Gr) particulates were used as reinforcing phase to develop A356/ 4 wt% B4C, A356/ 4 wt% Gr composites along with A356/ 4 wt% Gr/ 12 wt% B4C hybrid composites. The composites were developed by conventional stir casting method to improve the wear properties. The developed composites were subjected to scanning electron microscope (SEM) formicrostructural analysis and then to DUCOM made wear test assembly to know the dry sliding wear behaviour. The wear tests were conducted for …

Effect Of Amorphous Rice Husk Silica Additionon The Structure Of Asphalt Composite, Simon Sembiring, Agus Riyanto, Rudy Situmeang, Zipora Sembiring, Nita Susanti, Iqbal Firdaus

Journal of Metals, Materials and Minerals

In this study, modified asphalt composites were produced by adding silica extracted from rice husk.The mass ratios of asphalt to silica are 1:0, 1:1.6, 1:1.8, and 1:2 and calcined at the temperature of 150C for 6 h.The structural and microstructural characteristics of asphalt composites were examinedby x-ray diffraction (XRD),Scanning Electron Microscopy/Energy Dispersive x-ray (SEM-EDX) Spectroscopy and Differential Thermal Analysis (DTA-TGA),respectively. The XRDstudy revealed that the major phases were carbon and amorphous silica. The surface morphology of asphalt without silica addition presents a cluster of larger size than the cluster of asphalt with an addition of silica. The addition of silica …

Influence Of Coconut Shell Powder Organic Reinforcement On Chemical, Microstructuraland Mechanical Properties Of Spark Plasma Sintered Ti-Ni Based Metal Matrix Composite, Peter Odetola, Abimbola Patricia Popoola, Emmanuel Ajenifuja, Olawale Popoola

Journal of Metals, Materials and Minerals

Metal matrix composites (MMCs) are currently used in place of pure alloys and polymer matrix composites because of their unique physical properties. Titanium and nickel powders were alloyed with coconut shell powder (CSP) as organic compound reinforcement to form a TiNi-based metal matrix composite (MMC) using spark plasma sintering (SPS) technique. The powders were mild-milledfor 16 h and then axially consolidated at 850C, heating rate of 100Cmin-1and 50 MPa sintering pressure. Characterizations were done using field emission scanning electron microscope (FE-SEM-EDX) and x-ray diffractometer (XRD). Elemental and structural characterizations of the composites revealed the formation of the Ti-rich eutectic phase, …

Raman Spectroscopic Investigation Of The Speciation Of Uranyl (Vi) And Thorium (Iv) Ions In Chloride-Bearing Aqueous Solutions Under Hydrothermal Conditions, Nadib Akram

Graduate Theses/Dissertations

Raman spectra were acquired for a uranyl chloride aqueous solution at temperatures ranging from 25°C to 500°C at the chloride concentration of 6M and uranium (vi) concentration of 0.05M. The measurements were taken by sealing the sample in a hydrothermal diamond anvil cell (HDAC) which enabled spectra acquisition at non-ambient conditions. The pressure inside the cell was measured by estimating the liquid-vapor homogenization temperature (T_H) and using the isochoric equation of state diagram of water. The acquired spectra were then fitted to determine the speciation distribution of the various uranyl chloride species for the mentioned concentration. The developed …

Modeling And Analysis For Unit Cell Size, Material Anisotropy And Material Imperfection Effects Of Cellular Structures Fabricated By Powder Bed Fusion Additive Manufacturing., Yan Wu

Electronic Theses and Dissertations

Cellular structures are networks of interconnected struts or walls with porosities and are widely found in many natural load-bearing structures such as plants and bones. Cellular structures offer unique functional characteristics such as high stiffness to weight ratio, tailorable heat transfer coefficient, and enhanced mechanical energy absorption, which makes them highly attractive in various engineering disciplines such as biomedical implants, electrodes, heat exchangers, and lightweight structures. There exists an abundance of literatures that have investigated various mechanical properties of various cellular structures such as Poisson’s ratio, elastic modulus, ultimate strength, yield strength, and failure characteristics. Based on the classic cellular …

Spatially Directed Functionalization By Co-Electropolymerization Of Two 3,4-Ethylenedioxythiophene Derivatives On Microelectrodes Within An Array, Benjamin J. Jones, Carol Korzeniewski, Jefferson H. Franco, Shelley D. Minteer, Ingrid Fritsch

Chemistry & Biochemistry Faculty Publications and Presentations

Electrodeposited conductive copolymer films with predictable relative properties (quantities of functional groups for further modification and capacitance) are of interest in sensors, organic electronic materials and energy applications. Potentiodynamic copolymerization of films in aqueous solutions of two different thiophene derivatives, (2,3-dihydrothieno[3,4-b]dioxin-2-yl) methanol (1) and 4-((2,3-dihydrothieno[3,4-b][1,4]dioxin-2-yl)-methoxy)-4-oxobutanoic acid (2), containing 0.02 M total monomer (0, 25, 34, 50, 66, 75, 100 mol% 2), 0.05 M sodium dodecyl sulfate, and 0.1 M LiClO4, on gold microelectrodes in an array was investigated. Decreasing monomer deposited (m) from 0 to 100 mol% 2 is attributed to a decreasing pH that inhibits electropolymerization. Molar ratios of …

Synthesis, Characterization, Spectroscopic, And Mesomorphic Studies Of New Schiff Base Ligands And Titanium, Cobalt, Nickel And Copper Metal Centers, Raj K. Gurung

Chemistry & Biochemistry Theses & Dissertations

Transition metal complexes with Schiff base ligands offer a wide application in the field of development of catalysis and material. The straightforward synthesis allowed the structural modification and helped to optimize in various application of such complexes. Titanium-containing complexes have been reported to be important for their catalytic and material applications through the coordination of a tetradentate Schiff base ligand, viz. N, N’-ethylene bis(salicylideneiminate) dianion (salen). Studies reporting the characterization of achiral titanium(IV) salen complexes are scarce due to their intricate nature. Such complexes would be comparatively less expensive and easier to prepare synthetically and thus could represent an …

Growth And Characterization Of Semiconductor Materials And Devices For Extreme Environments Applications, Abbas Sabbar

Graduate Theses and Dissertations

Numerous industries require electronics to operate reliably in harsh environments, such as extreme high temperatures (HTs), low temperature (LT), radiation rich environments, multi-extreme, etc. This dissertation is focused on two harsh environments: HT and multi-extreme.

The first study is on HT optoelectronics for future high-density power module applications. In the power modules design, galvanic isolation is required to pass through the gate control signal, reject the transient noise, and break the ground loops. The optocoupler, which consists of a lighting emitting diode (LED) and photodetector (PD), is commonly used as the solution of galvanic isolation at room temperatures. There is …

Static And Dynamical Properties Of Multiferroics, Sayed Omid Sayedaghaee

Graduate Theses and Dissertations

Since the silicon industrial revolution in the 1950s, a lot of effort was dedicated to the research and development activities focused on material and solid-state sciences. As a result, several cutting-edge technologies are emerging including the applications of functional materials in the design and enhancement of novel devices such as sensors, highly capable data storage media, actuators, transducers, and several other types of electronic tools. In the last two decades, a class of functional materials known as multiferroics has captured significant attention because of providing a huge potential for new designs due to possessing multiple ferroic order parameters at the …

Direct Solar Absorption Nanoparticle Doped Membranes For A Hybrid Membrane Distillation And Photovoltaic Cell, Alejandro Espejo Sanchez

Boise State University Theses and Dissertations

The growing demand for clean water supplies is driving the need for an innovative approach of water desalination. Developing a method for treating water with high salinities is possible with membrane distillation (MD). Additionally, MD is very attractive for pairing with solar energy due to the low temperature requirements. The integration of a membrane distillation system with a photovoltaic (PV) system will result in the co-production of electricity and clean water, thereby improving the economics of MD. Such a hybrid system will directly absorb thermal energy in the membrane for desalination while taking advantage of the spectrally selective nature of …

Effects Of Ca Doping On Structural And Optical Properties Of Pzt Nanopowders, K. H. Omran, M. Mostafa, M. S. Abd El-Sadek, O. M. Hemeda, R. Ubic

Materials Science and Engineering Faculty Publications and Presentations

The influence of the addition of calcium ions (Ca²⁺) in the Pb_(1-x)Ca_xZr_0.52Ti_0.48O₃ system (PCZT) for x = 0.05, 0.10, 0.15, 0.20, and 0.25 on the structural and optical properties was systematically studied. The compositions were synthesized through a polymerized-complex approach based on the Pechini polymeric precursor route. The solubility limit of calcium ions within the PCZT lattice is in between x = 0.10 and x = 0.15, at which a CaTiO₃ secondary phase is detected. The Goldschmidt tolerance factors, modified tolerance factors, and the effective vacancy sizes were …

Defect Evolution In High-Temperature Irradiated Nuclear Graphite, Steve Johns

Boise State University Theses and Dissertations

Graphite has historically been used as a moderator material in nuclear reactor designs dating back to the first man-made nuclear reactor to achieve criticality (Chicago Pile 1) in 1942. Additionally, graphite is a candidate material for use in the future envisioned next-generation nuclear reactors (Gen IV); specifically, the molten-salt-cooled (MSR) and very-high-temperature reactor (VHTR) concepts. Gen IV reactor concepts will introduce material challenges as temperature regimes and reactor lifetimes are anticipated to far exceed those of earlier reactors. Irradiation-induced defect evolution is a fundamental response in nuclear graphite subjected to irradiation. These defects directly influence the many property changes of …

Additive Manufacturing Of Graphene-Based Devices For Flexible Hybrid Electronics, Twinkle Pandhi

Boise State University Theses and Dissertations

In this work, I investigate and enhance the fundamental sensing properties of printed electronic nanomaterials (e.g., graphene) in real-world environments while decreasing weight, cost, and power consumption. The dissertation addresses this issue with the following foci in mind: (1) developing a straightforward and repeatable process to synthesize graphene ink which is also compatible with Inkjet-printing (IJP) and Aerosol Jet printing (AJP). (2) Tuning additive manufacturing printing (IJP and AJP) parameters to establish a repeatable manufacturing process and print high performing (graphene-based) electrodes and interconnects, compatible with the underlying substrate. (3) Investigate power dissipation and electrical breakdown in AJP printed graphene …

Design, Discovery, And Characterization Of Single Crystals Of A Topological Semimetal Using A Self-Flux Method, Sudha Krishnan

Graduate Theses/Dissertations

Realization of topological semimetals in the recent past show that ternary intermetallics can exhibit topological phases. This discovery initiated the quest for this novel research. There is a crucial need to discover new materials that manifest these phases for a better understanding of their behavior to utilize them in device technology. Also, Bi compounds have attracted much attention as candidates for topological materials and topological superconductors. In this context, synthesis and characterization of single crystals of a layered transition metal pnictide SmMnBi2, a potential Dirac topological semimetal candidate, is reported. A flux method was utilized to synthesize single crystals of …

Exploring The Variability In The Gray Scale Imaging Process Of Asphalt Samples, David Oluwawade Olatunji

Civil Engineering Undergraduate Honors Theses

Gray scale image analysis is a powerful tool for testing asphalt concrete materials. From material composition to surface properties, gray scale analysis has shown evidence as a non-invasive way to obtain information from asphalt samples. Casillas et al. used a gray scale analysis to measure the Representative Volume Element of three asphalt sample geometries to understand the minimum size at which an asphalt sample is representative of a larger homogeneous mixture [1]. While the gray scale analysis used in this experiment yielded results, there were unknown factors in the image capturing process. Particularly, not much was known about the effect …

Properties And Performance Of The Basalt-Fiber Reinforced Texture Roof Tiles, Parinya Chakartnarodom, Wichit Prakaypan, Pitcharat Ineure, Nutthita Chuankrerkkul, Edward A. Laitila, Nuntaporn Kongkajun

Michigan Tech Publications, Part 1

The mechanical and the physical properties, and the performance of texture roof tiles reinforced with the basalt fibers were observed. The samples of the basalt-fiber reinforced texture roof tiles were produced on the industrial scale by using filter pressing method. After forming, the as-molded samples were air cured and characterized based on ASTM C1185 standard for their mechanical properties and physical properties. In addition, the roof-tile installation test was also performed. The results showed that the samples of the basalt-fiber reinforced texture roof tile (BFRT) could be produced on the industrial scale by using the common setting of the forming …

Synthesis Of Novel Coo/Mnfe2o4 Heterostructured Nanoparticles And The Effects Of Variable Size And Extent Of Overgrowth On Their Magnetic Properties, Mohammad Tauhidul Islam

Graduate Theses/Dissertations

A combination of thermal decomposition and surfactant-assisted synthesis route was utilized to synthesize novel CoO/MnFe₂O₄ heterostructured nanoparticles. Four samples of varying CoO core size were synthesized with variable extent of overgrowth phase. XRD, XPS, SEM and TEM data show evidence of MnFe₂O₄ spinel phase overgrowth on CoO rock-salt structured nanoparticles. XPS and magnetic data reveal partial oxidation and formation of Co₃O₄ phase on 7 nm and 19 nm size CoO-based nanoparticles. The remaining samples having 22 nm and 34 nm dimensions show a higher percentage of FiM materials overgrowth on the …

Kinetic Monte Carlo Investigations Involving Atomic Layer Deposition Of Metal-Oxide Thinfilms, David Tyler Magness

Graduate Theses/Dissertations

Atomic Layer Deposition is a method of manufacturing thin film materials. Metal-oxides such as zinc-oxide and aluminum-oxide are particularly interesting candidates for use in microelectronic devices such as tunnel junction barriers, transistors, Schottky diodes, and more. By adopting a 3D Kinetic Monte Carlo model capable of simulating ZnO deposition, the effect of parameters including deposition temperature, chamber pressure, and composition of the initial substrate at the beginning of deposition can be investigated. This code generates two random numbers: One is used to select a chemical reaction to occur from a list of all possible reactions and the second is used …

Development Of Functional Materials And Devices On Flexible Platforms Using Additive Print Manufacturing Processes For Biomedical And Environmental Applications, Dinesh Maddipatla

Dissertations

In recent years, considerable research has been vested into the development of printed electronics (PE) to explore the best ways of fabricating electronic devices on flexible platforms using additive print manufacturing processes. PE produces flexible devices that are compatible with complex geometries, foldable applications and conformal to curved surfaces, with a promising potential for large‐area device fabrication at relatively lower manufacturing costs. This dissertation focuses majorly on the design and fabrication of novel flexible functional materials and devices for biomedical and environmental applications using additive printing processes.

Initially, a simple paper-based low cost and rapid prototypable platform with oxygen sensors …