Materials Science and Engineering Commons^™

Carbon Supported Octahedral Ptni Nanoparticles (Oct-Ptni/C) As A Cathode Catalyst For Proton Exchange Membrane Fuel Cells (Pemfcs) With Improved Activity And Durability, Zi-Wei Feng, Hai-Zhong Chen, Xiao Duan, Ling Tang, Yun-Kun Zhao, Long Huang

Journal of Electrochemistry

Proton exchange membrane fuel cells (PEMFCs) are considered as a promising renewable power source. However, the massive commercial application of PEMFCs has been greatly hindered by their high expense and less-satisfied performance mainly due to the sluggish oxygen reduction reaction (ORR) kinetics even on state-of-the-art Pt catalyst. Octahedral PtNi nanoparticles (oct-PtNi NPs) with excellent ORR activity in a half-cell have been widely studied, while their performance in membrane electrode assembly (MEA) has much less reported. Herein, we investigated the MEA performance using the carbon supported oct-PtNi NPs (oct-PtNi/C) as the cathode catalyst. Under the mild acid washing condition, the surface …

Development Status And Existing Problems Of Ion-Solvation Membranes For Electrolysis Of Water, Zheng-Yuan Zhou, Yu-Tao Sun, Zheng-Bang Liu, Chuan-Zheng Wang, Yong-Nan Zhou, Xi Luo, Tian-Chi Zhou, Jin-Li Qiao

Journal of Electrochemistry

Ion-solvaing membranes (ISMs) have received extensive attention in recent years as a key component in electrochemical energy conversion and storage devices. This article provides an overview of structural composition, performance advantages, research progress, ion conduction mechanism and existing issues of ISMs, primarily classifying them according to the matrix structure. A detailed analysis of performance enhancement methods, key performance indicators of ISMs and performance influencing factors is also presented. The article contributes to further optimizing the design and application of ion-solvation membranes, providing theoretical support for the development of fields such as hydrogen production through electrolysis of water and electrochemical energy …

The Ntp Anode For Aqueous Sodium Ion Batteries: Recent Advances And Future Perspectives, Ming-Li Wang, Xue-Ying Su, Zheng-Xiang Shan, Shu-Zhe Yang, Heng-Rui Guo, Hao Luo, Dong-Liang Chao

Journal of Electrochemistry

Aqueous sodium-ion batteries (ASIBs) have attracted great attention in aqueous batteries due to their merit of high safety. However, the constrained work potential and insufficient chemical stability of anode materials in aqueous electrolytes hinder the large-scale application of ASIBs. Sodium titanium phosphate, NaTi₂(PO₄)₃ (NTP), is considered one of the most promising anode materials for ASIBs due to its excellent electrochemical performance and tunable structure. Recently, great achievements have been made in the development of NTP, however, a comprehensive review of existing studies is still lacking. This article firstly introduces the basic properties of NTP and …

Iron-Involved Orr Electrocatalysts Under The Lens Of In-Situ/Operando Mössbauer Spectroscopy, Sumbal Farid, Jun-Hu Wang

Journal of Electrochemistry

Exploring cost-effective and efficient catalysts for oxygen reduction reaction (ORR) poses a significant challenge, especially in the pursuit of alternatives to precious metals like platinum. Significant advancements have driven electrochemists to develop efficient ORR catalysts using abundant materials, particularly iron (Fe)-based, known for their exceptional performance in ORR. While the crucial function of Fe in boosting ORR catalytic activity is recognized, the connection between material attributes and catalytic performance remains enigmatic. Understanding the dynamic processes involved in oxygen electrocatalysis is paramount for designing precious-metals-free ORR electrocatalysts. Mössbauer spectroscopy stands out as a powerful technique for deciphering the structural characteristics of …

Biomineralization Of Low Temperature Plasma(Ltp) Modified Polymeric Biomaterials And Scaffolds, John Patrick Bradford

ETDs from 2020-2029

Bio-integration, specifically osseo-integration of bone implants and scaffolds, are vital for the success of implants and bone tissue engineering (BTE). Calcification can be defined as the deposition of calcium compounds as either calcium phosphate(CaP) minerals consisting of hydroxyapatite(HAP) or CaP salts. The significance of the variety of phases of CaP is that mature bone matrix is composed of 65% CaP mineral. Many investigators have attempted to model the natural matrix by producing materials containing calcium phosphate in both amorphous CaP or in the more crystalline HAP form, with biomaterials (both synthetic and biological). Biomimetic CaP formation is a sign of …

Assessing The Student Awareness To Age Friendly Design: The Case Of Ain Shams University- Architecture Students, Shorouk Saleh Ali Kabel, Samah Mohamed Elsayed Atteia Elkhateb, Rowaida M. O. Mohamed Rashed, Wesam M. El-Bardisy

HBRC Journal

With Egypt’s rapid urbanization and projected demographic shift, where individuals aged 60 and above are expected to constitute more than 15% of the population by 2050, addressing the needs of older adults in urban design has become increasingly urgent. Despite global recognition of the importance of age-friendly design, its integration into Egyptian architectural education remains limited, particularly concerning accessibility, safety, and inclusivity.

This study evaluates the level of awareness of Age-Friendly Design (AFD) principles among architecture students at Ain Shams University using a mixed-methods approach. Quantitative data were collected through an online questionnaire assessing students’ familiarity with the concept, while …

Performance-Based Seismic Design And Retrofitting Via Drift And Strain Criteria, Tharwat A. Sakr, Hanaa E. Abd-El-Mottaleb, Shrouk S. Kamel

HBRC Journal

In recent decades, the demand for seismic code updates has significantly increased. Performance-based seismic design (PBSD) is a modern approach to earthquake-resistant building construction. By using this technique, the designers can establish performance targets that satisfy the owner. Most codes rely on strength design that utilizes a design response spectrum, highlighting serviceability without addressing performance levels. In this paper, an appraisal for the incorporation of PBSD into the Egyptian Code is proposed using nonlinear static and dynamic analysis. At first, response spectrum charts for 72, 475, and 2475 years return periods (RP) were developed based on the Egyptian seismicity information. …

Place Personality And User Behaviour: Insights From Cairo’S Streets, Sara Sabahy, Zeina Elzein, Doaa Abouelmagd

HBRC Journal

A place’s personality is beyond the sum of its characteristics. It’s how people perceive it on a human level, hoping for a better understanding and seeking connection. This study aims to understand how people connect with public spaces to enhance the quality of urban life.

A place’s personality extends beyond its physical attributes—it reflects how people emotionally perceive and connect with it. This study investigates the relationship between the perceived personality of urban streets and users’ behaviour to enhance the quality of urban life in Cairo. Focusing on Downtown Cairo and New Cairo, it addresses a gap in destination personality …

Spectroscopic Investigations On Polyvinylidene Fluoride Nanofibers, Parinaz Amaniabdolmalaki, Jui Vitthal Kharade, Alexandro Trevino, Lydia Morales, Karen Lozano, Victoria Padilla, Karen S. Martirosyan, Horacio Vasquez, Mircea Chipara

Physics & Astronomy Faculty Publications

The production of polyvinylidene fluoride nanofibers by force-spinning from polymer solutions was confirmed by electron microscopy. The structural and phase characteristics of the resulting nanofiber mats were examined using Fourier Transform Infrared Spectroscopy in Attenuated Total Reflectance mode, Raman spectroscopy, and X-ray Diffraction. Results from all these techniques consistently indicated that both the powder and the mats of polyvinylidene fluoride predominantly contain the α phase, with a small admixture of the β phase. Within experimental errors, no other phases were noticed both in the powder and in the as-obtained mats. The ratios of the areas of the Raman lines at …

Reproducible Semantic Data Management Workflow For Materials Data Science: Generating Knowledge Graphs With Robust Fairifcation Pipelines, Kyle R. Henrikson, Van D. Tran, Meredith Francis, Isabella Giammattei, Quynh D. Tran, Laura S. Bruckman, Erika I. Barcelos, Roger H. French

Student Scholarship

Combining data from multiple sources is crucial for efficient knowledge aggregation in materials data science. FAIR data from ontology and Linked Data principles enable this. Semantic data management streamlines data exchange and aggregation, ensuring information is available and extractable. FAIRLinked and GraphDB provide solutions for consolidating, hosting, and extracting meaningful insight from multimodal data.

Rheology-Guided Spinnability In Emulsion Forcespinning Of Water-In-Oil Nanofibers: Influence Of Surfactants And Internal Phase Concentration, Saptasree Bose, Alexandra Salinas, Evelyn Torres, Jose Ramirez, Elizabeth Gamez, Michelle A. Calabrese, Karen Lozano, Victoria Padilla

Mechanical Engineering Faculty Publications

This study explores the emulsion Forcespinning (FS) approach for fabricating nanofibers with a hydrophilic phase encapsulated within a hydrophobic polymer matrix. Key factors influencing fiber production and morphology, including the concentration of the internal water phase and the presence of ionic and nonionic surfactants, were systematically investigated. Additionally, the centrifugal spinnability of the emulsions was assessed using environmentally controlled dripping-onto-substrate (DoS) rheometry, correlating the observed extensional flow behavior and emulsion extensibility with fiber spinnability. The nanofibers were characterized by scanning electron microscopy (SEM), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and Fourier transform infrared (FTIR) spectroscopy. These findings offer critical …

Areosense, Josephine Turney

Williams Honors College, Honors Research Projects

The AeroSense growing system is designed to make indoor aeroponic gardening easy and accessible for everyone. By combining sensors, automation, and AI, the system can monitor and adjust humidity, lighting, and nutrient levels to help plants thrive without requiring expert knowledge. The goal is to create a self-regulating garden that takes the guesswork out of growing fresh herbs and vegetables at home. The project involves building a working aeroponic prototype equipped with misters, pumps, and environmental sensors, all managed by a Raspberry Pi. Using computer vision and machine learning, AeroSense will be able to assess plant health and respond automatically …

Effect Of Ionic Strength On Gelation Time And Strength Of Amps-Based Polymer Gels, Maryam Sharifi Paroushi, Xuyang Tian, Baojun Bai, Thomas P. Schuman, Yin Zhang, Mingzhen Wei

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Polymer gel treatment has been widely applied for improving sweep efficiency and controlling excessive water and gas production. Their performance depends on gelation time and final gel strength. In most studies, brine salinity is used to describe the effect of formation water on gel behavior. However, changing salinity also changes ionic strength and ion composition at the same time. Because of this coupling, it is difficult to identify the mechanisms controlling gelation, which has led to inconsistent trends in the literature. Increasing salinity has been reported to either slow or accelerate gelation and to weaken or strengthen gels depending on …

Data Set, R Scripts And Script Outputs For Manuscript: Manufacturing Systems: Characteristics And Dynamics, Alan J. Fitzmorris

Graduate Research Data

This file repository contains fifteen computer-generated datasets, two naturally occurring datasets, nineteen shipbuilding shop datasets, and sixty-one concrete plant datasets.  Each data set contains subdirectories associated with various aspects of the data analysis, including stationarity analysis, dynamic system analysis, and complexity analysis.  In each case, applicable R scripts are included.  The text file entitled “Directory_and_File_Names” depicts the directory structure and associated file names for a total of 225 directories encompassing 8008 files.

Effect Of Wall Movement On Porosity Formation In Ductile Iron Castings Under Varying Processing Parameters, Shamsul Alam

College of Graduate Studies: Theses & Dissertations

Shrinkage porosity is a major defect that significantly impairs the mechanical properties and overall performance of ductile iron castings. Although graphite formation during solidification induces volumetric expansion, this expansion alone is insufficient to fully compensate for the shrinkage occurring throughout solidification. During the solidification and cooling of ductile iron, multiple phase transformations occur, resulting in dynamic volume changes that exert pressure on mold walls and internal cavities. These pressures can deform mold walls and casting surfaces, leading to defects such as swell and porosity, while also influencing shrinkage formation. This study aims to analyze the mechanisms of porosity formation and …

Viscoelastic Behavior Of Magnetically Filled Pdms Elastomers: Influence Of Filler Loading And Particle Type, Madison Procyk

College of Graduate Studies: Theses & Dissertations

Magnetorheological elastomers (MREs) offer a promising pathway for soft, magnetically actuated drug‑delivery systems, yet material‑selection guidelines remain unclear due to limited comparative data across particle chemistries, size scales, and concentrations. This study systematically evaluates how magnetic filler type (carbonyl iron and magnetite) and particle size (micro vs. nano), at two weight percentages – 40 wt% and 50 wt% – in Sylgard 184 PDMS influence the viscoelastic behavior of MREs intended for compliant biomedical actuation. Eight particle formulations were prepared through sieving, controlled mixing, vacuum degassing, and isotropic curing, producing nineteen total specimens (16 with filler particles and 3 without). Dynamic …

Effects Of Composition, Nodularity, Pouring Temperature, Inoculation, And Mold Strength On Wall-Movement In Sgi Castings During Solidification And Cooling, Noah Brack

College of Graduate Studies: Theses & Dissertations

The iron-carbon casting alloy known as spheroidal graphite iron (SGI), nodular graphite iron, or ductile iron (DI) experiences complex volume changes during its solidification and cooling as graphite nodules and austenite form. These volume changes result in forces on the mold cavity walls and can deform the mold walls in cases when mold walls lack the strength to resist the deformation. This wall movement can cause the formation of casting defects such as swell, warped part geometry, and shrinkage porosity. Though this phenomenon has been studied in the past, it remains difficult to predict casting wall movement with existing data. …

Dietary Intake Of Micro- And Nanoplastics: Potential Adverse Gi Effects On Microbiome, Inflammation, And Neoplasia, Michael Saadeh, Gordon Hong, Sana Rabeeah, Priyata Dutta, Edward C. Oldfield, Iv, David A. Johnson

Department of Medicine Faculty Publications

Micro- and nanoplastics (MNPs) are pervasive in food-contact environments and the human diet, positioning the gastrointestinal (GI) tract as the primary portal of entry and a plausible site of early biological effects. Human exposure is supported by detection of microplastics in stool and colon tissue, and emerging clinical studies report associations between fecal microplastic burden and GI disease states, including inflammatory bowel disease (IBD) and colorectal cancer (CRC). Preclinical studies provide mechanistic plausibility, reporting that ingested MNPs can modulate microbial ecology, alter mucus membrane integrity, increase intestinal permeability through changes in cellular tight junction biology, and induce inflammatory gene expression. …

Effect Of Elemental Additions On The Microstructure, Macrostructure, And Mechanical Properties Of Gray Iron, August E. Rautmann

College of Graduate Studies: Theses & Dissertations

Gray iron is composed primarily of an iron matrix and flake graphite, with the higher percentage of volume taken up by the iron matrix. The iron matrix is the transformation product of austenite, and this prior austenite structure is understood to affect the final grain structure. Grain structure affects the properties of a metal, with a finer structure recognized as beneficial for most properties. Thus, the refinement of austenite structure has potential in improving the material properties of gray iron. This study aims to advance the limited knowledge about the control of austenite grain size via elemental additions. Building off …

Direct Ink Writing Of Shear Exfoliated Two-Dimensional Nanomaterial- Elastomeric Multifunctional Nanocomposite, Md Abdur Rahman Bin Abdus Salam, Asif Hasan Ridoy, A K M Abirul Haque, Muhammad Shahbaz Rafique, Md Arafat Hossain, Md Shahriar Forhad, Matthew G. Boebinger, Farid Ahmed, Karen Lozano, Ali Ashraf

Manufacturing & Industrial Engineering Faculty Publications

Direct ink writing (DIW) of polymer nanocomposites with high loadings of two-dimensional (2D) nanofillers (graphene and hexagonal boron nitride (hBN)) is challenging because of potential clogging, use of hazardous solvents, and agglomeration. Here, in this work, a shear exfoliation and sieving method to prepare DIW ink with high loading of nanofillers produced from low-cost bulk layered materials such as graphite and bulk hBN powder for successful DIW printing without the use of any solvents, binders, or plasticizers. The single-step exfoliation technique resulted in a composite with substantial layer reduction along the c-axis, as confirmed by SEM, TEM, XRD, and Raman …

Detecting And Repairing Conflicting Constraints In Co-Trained Physics-Informed Neural Networks For Composite Curing Processes, Cooper J. Evans

Dissertations, Master's Theses and Master's Reports

Composite materials have become a critical component of modern manufacturing, especially in the automotive and aerospace industries. The curing process for these composites has been modeled using a variety of partial differential equations representing the heat transfer and composite curing kinetics. Optimizing the applied temperature profile is critical for maximizing the efficiency and capacity of composite part manufacturers. Constraints must be placed on the inputs and outputs of the model, including but not limited to, the applied temperature profile, part temperature, and final degree of cure. Conflicting sets of constraints are easy to unknowingly impose due to the highly coupled …

Elevated Temperature Flexure Behavior Of Continuous Carbon Fiber Reinforced Zrb2–Zrsi2 Ultrahigh Temperature Ceramic Matrix Composites, Jacob Stacy, Aaron Ginsparg, Jason Lonergan, Jeremy Watts, Gregory Hilmas

Materials Science and Engineering Faculty Research & Creative Works

Ultrahigh temperature ceramic matrix composites (UHTCMCs) were fabricated from unidirectional prepreg tapes consisting of a matrix of ZrB₂ with 5, 10, and 15 vol.% ZrSi₂ additions and continuous polyacrylonitrile carbon fibers and were densified at 1600°C in a hot press. The relative matrix densities ranged from 88% to 93% with interlayer spacings of ∼72 µm and fiber volume fractions between 30% and 36%. Phenolic resin additions were utilized to react with ZrSi₂ acting as a transient sintering aid to form ZrC and SiC phases. Elastic moduli of the UHTCMCs decreased with increasing temperature during 4-pt flexure testing. …

Quantitative Grain Structure And Texture Analysis Of Hot-Pressed Zrb2 Via 3d Ebsd, Randi Swanson, Michael Chapman, Yue Zhou, Ashley Hilmas, Lisa Rueschhoff, Michael Uchic, William Fahrenholtz, Scott J. Mccormack

Materials Science and Engineering Faculty Research & Creative Works

Understanding and controlling the grain structure of ZrB₂ is critical for optimizing its mechanical and thermal performance in high-temperature applications. Fully dense ZrB₂, densified by hot pressing at 2150˚C and 32 MPa, was analyzed in three dimensions using electron backscattered diffraction, electron and optical microscopy, and mechanical polishing serial sectioning. Grain size followed a gamma distribution, with extreme deviations observed only in the largest 0.1% of grains. Large grains exhibited plate-like morphologies, with the shortest-to-longest axis ratio converging to ∼0.4 as grain volume increased. This work revealed a crystallographically controlled growth mechanism orthogonal to [0001] that is …

The Effects Of Mold Flux Contamination On Oxide Scale Formation And Hydro-Descaling Efficiency During Steel Processing, Tochukwu Princewill Ojiako, Richard Osei, Mario Buchely, Haiming Wen, Simon Lekakh, Ronald O'Malley

Materials Science and Engineering Faculty Research & Creative Works

Oxide scale formation during thin-slab continuous casting has a complex structure, which is influenced by mold flux contamination, that modifies interfacial reactions during solidification, subsequent reheating, and descaling. While individual aspects of the oxidation behavior of carbon steel have been previously examined, the synergetic effects of mold flux contamination during continuous casting and subsequent reheating on scale modification and the efficiency of hydraulic descaling remain inadequately studied. This study quantitatively examines the effect of flux composition on oxide scale evolution, adhesion, and hydraulic removal in low-carbon steel under simulated industrial conditions. Slab samples with as-cast, cleaned, and flux-coated surfaces were …

Simulated Lunar Gravity Testing Of A Magnetic And Electrostatic System For Beneficiating Lunar Regolith, Blake A. Coffman, Gabriel Porter, Lindsay Manteufel, Mitchell Cottrell, Jeffrey D. Smith, David J. Bayless, William Shonberg, Frank D. Han, Fateme Rezaei, Kirby Runyon

Materials Science and Engineering Faculty Research & Creative Works

We present the design and testing of a lunar regolith beneficiation device that utilizes magnetic and electrostatic separation methods to concentrate desired minerals by removing unwanted material, such as the mineral anorthite, from bulk lunar regolith. The beneficiated materials would have value for downstream in-situ resource utilization (ISRU) processes such as metal extraction, oxygen extraction, and metal oxide additive manufacturing processes. The apparatus uses a dual-strength magnet system with N52 and N42 neodymium magnets to separate particles by magnetic susceptibility. The electrostatic separation system, which acts like a sieve, sorts the regolith simulant by particle size using a single-phase 50% …

High Temperature Diffraction From Aerodynamically Levitated Materials, Chris J. Benmore, Stephen K. Wilke, David Lipke, Richard Weber

Materials Science and Engineering Faculty Research & Creative Works

Aerodynamic levitation combined with laser beam heating has become an established technique for studying the structure of materials at ultra-high temperatures and under non-equilibrium conditions. This article briefly highlights some recent technical and scientific advancements in understanding the relationships between a material's behavior and its structure, investigated using diffraction methods. It focuses on three evolving frontiers: sophisticated sample environments for accessing metastable states and reactive chemistries, high-flux photon and neutron probes to reveal atomic structure, and advanced computational modeling frameworks. Free from contamination, containerless processing (levitation) can minimize heterogeneous nucleation at the interface, enabling access to deeply supercooled melts or …

A Combined Stochastic And Physical Framework For Alloys And Metal Casting Processes Modeling, Simon N. Lekakh, Oleg Neroslavsky

Materials Science and Engineering Faculty Research & Creative Works

High temperature metal casting processes have dualistic nature and conceptually consist of two parts of distinct processes: the first type is deterministic, strictly obeying the physical law, while the second type is stochastic. Therefore, the metal casting processes are not precisely predictable, and deterministic considerations cannot provide exact outcomes. To solve this problem, the combined stochastic and deterministic framework was suggested. The local processes were described using deterministic models for several parameter arrangements, while the distribution of these arrangements on macro level was calculated using stochastic approaches. The approach was used for cast alloy design, investment casting process optimization, and …

Thermal Transformations And Mechanical Properties Of All-D-Metal Mn2fecu Heusler-Type Shape Memory Alloy, Choji J. Daches, Joseph W. Newkirk, Mario Buchely

Materials Science and Engineering Faculty Research & Creative Works

All-d-metal Heusler alloys are emerging functional materials in which magnetic ordering, lattice distortion, and mechanical behavior are strongly coupled through d–d electronic interactions. This study systematically investigates the structural, thermal, magnetic, and mechanical properties of Mn₂FeCu synthesized within a Heusler-type compositional framework. SEM/EDS revealed a dual-phase FCC-based microstructure consisting of Mn–Fe–rich and Mn–Cu–rich domains, while XRD confirmed FCC symmetry with compositional partitioning rather than full L2₁ ordering. Differential scanning calorimetry identified partial melting of the Cu-rich phase near ~ 900 °C. Dilatometry showed a thermoelastic FCC → FCT transformation at ~ 770–780 °C with a recoverable strain of ~ 0.067%. …

Comparative Evaluation Of Gating Systems In Femnal Castings, K. Balasubramanian, Laura Bartlett, M. Xu

Materials Science and Engineering Faculty Research & Creative Works

To understand the efficiency of gating systems, four systems, namely AFS styled pressurized system, AFS styled non-pressurized system, naturally pressurized system with a side riser and a naturally pressurized system with a top riser, were studied. The naturally pressurized systems were provided with overflows which collected the incoming metal swirl while the pressurized and non-pressurized systems had runner wells. Parameters like velocity of metal flow, air entrapment, microporosity and Niyama criterion were considered, and a design was developed with a common pouring basin using solidification software. Two molds were 3D printed using carbonitride sand, and steel of composition Fe-29Mn-8.2Al-0.91C-0.88Si-0.49Mo was …

Design Of Novel Gating Systems For Steel Castings, K. Balasubramanian, Laura Bartlett, M. Xu

Materials Science and Engineering Faculty Research & Creative Works

Gating systems play an important role in determining the quality and mechanical properties of castings. To understand the efficiency of gating systems, four systems, namely pressurized system, non-pressurized system, naturally pressurized system with a side riser and a naturally pressurized system with a top riser, were studied. The naturally pressurized systems were provided with overflows which collected the incoming metal swirl. Parameters like velocity of metal flow, air entrapment, microporosity and Niyama criterion were considered, and a design was developed with a common pouring basin. 8630 alloy was poured into two molds using a teapot ladle. The inclusion analysis revealed …