Materials Science and Engineering Commons^™

The Impact Of Solution Ionic Strength, Hardness, And Ph On The Sorption Efficiency Of Polychlorinated Biphenyls In Magnetic Nanocomposite Microparticle (Mnm) Gels, Angela M. Gutierrez, Thomas D. Dziubla, J. Zach Hilt

Chemical and Materials Engineering Faculty Publications

Environmental conditions of groundwater and surface water greatly vary as a function of location. Factors such as ionic strength, water hardness, and solution pH can change the physical and chemical properties of the nanocomposites used in remediation and the pollutants of interest. In this work, magnetic nanocomposite microparticle (MNM) gels are used as sorbents for remediation of PCB 126 as model organic contaminant. Three MNM systems are used: curcumin multiacrylate MNMs (CMA MNMs), quercetin multiacrylate MNMs (QMA MNMs), and polyethylene glycol-400-dimethacrylate MNMs (PEG MNMs). The effect of ionic strength, water hardness, and pH were studied on the sorption efficiency of …

Mechanical Characterization Of Additively Manufactured Alloys Compared To Their Wrought Counterparts, Laith A. Alqawasmi

Mechanical Engineering ETDs

Additive manufacturing is a method of manufacturing based on building parts layer by layer, allowing for more control over shape of the product, therefore reducing machining costs, reducing material waste, faster production times and the ability to build complex engineering design that other manufacturing technologies won’t be able to produce. This research is on the tensile and indentation testing (following ASME standards) of 3D printed Ti-6Al-4V and Inconel 718 built by powder-based direct energy deposition technology. Ti-6Al-4V is an attractive material for the aerospace and aviation industry, and Inconel 718, a nickel-chromium based superalloy, is an attractive material for usage …

Modifying Barium Hexaferrite Magnets By Adding Sol-Gel Synthesized Cobalt Ferrite Phase, Thanida Charoensuk, Wannisa Thongsamrit, Anuchit Hunyek, Komkrich Chokprasombat, Pongsakorn Jantaratana, Chitnarong Sirisathitkul

Karbala International Journal of Modern Science

Combining various types of ferrites brings about magnetic properties desirable for different applications. This study aims to modify barium hexaferrite (BaFe₁₂O₁₉) by physically mixing it with cobalt ferrite (CoFe₂O₄). BaFe₁₂O₁₉/CoFe₂O₄ magnets were produced by ball-milling and pressing sol-gel-derived ferrite powders. The ferrite composites showed variations in magnetic properties from BaFe₁₂O₁₉ magnets with a saturation magnetization of 69.46 emu/g and a maximum energy product of 0.4529 MGOe. For the BaFe₁₂O₁₉:CoFe₂O₄ weight ratio of 4:1, both satura-tion …

Femtotesla Magnetometry And Nanoscale Imaging With Color Centers In Diamond, Yaser Silani

Optical Science and Engineering ETDs

Intriguing photophysical properties of color centers in diamond make them ideal candidates for many applications from imaging and sensing to quantum networking. In the first part of this work, we have studied the silicon vacancy (SiV) centers in diamond for nanoscale imaging applications. We showed that these centers are promising fluorophores for Stimulated Emission Depletion (STED) microscopy, owing to their photostable, near-infrared emission and favorable photophysical properties. In the second part, we built a femtotesla Radio-Frequency (RF) magnetometer based on the diamond nitrogen vacancy (NV) centers and magnetic flux concentrators. We used this sensor to remotely detect Nuclear Quadrupole Resonance …

A High-Strength Precipitation Hardened Cobalt-Free High-Entropy Alloy, Matthew Luebbe, Jiaqi Duan, Fan Zhang, Jonathan Poplawsky, Hans Pommeranke, Maalavan Arivu, Andrew Hoffman, Mario F. Buchely, Haiming Wen

Materials Science and Engineering Faculty Research & Creative Works

Recent Studies on Precipitation-Hardened High-Entropy Alloys (HEAs) Demonstrate their High Strength and Thermal Stability, Making Them Promising Materials for High-Temperature Structural Applications Such as Nuclear Reactors. However, Many Existing HEAs Contain Cobalt (Co), Which is Unsuitable for Nuclear Applications Because of the Long-Term Activation Issue of Co. Co is Also Expensive and Considered a Critical Material for Other Applications. Therefore, It is Desired to Exclude Co from the Composition. a Co-Free (Fe_0.3Ni_0.3Mn_0.3Cr_0.1)88Ti₄Al₈ HEA Was Developed and Studied in This Work. in Contrast to Previous Co-Free HEAs, This Alloy is …

A High-Strength Precipitation Hardened Cobalt-Free High-Entropy Alloy, Matthew Luebbe, Jiaqi Duan, Fan Zhang, Jonathan Poplawsky, Hans Pommeranke, Maalavan Arivu, Andrew Hoffman, Mario Buchely, Haiming Wen

Materials Science and Engineering Faculty Research & Creative Works

Recent studies on precipitation-hardened high-entropy alloys (HEAs) demonstrate their high strength and thermal stability, making them promising materials for high-temperature structural applications such as nuclear reactors. However, many existing HEAs contain cobalt (Co), which is unsuitable for nuclear applications because of the long-term activation issue of Co. Co is also expensive and considered a critical material for other applications. Therefore, it is desired to exclude Co from the composition. a Co-free (Fe0.3Ni0.3Mn0.3Cr0.1)88Ti4Al8 HEA was developed and studied in this work. in contrast to previous Co-free HEAs, this alloy is close to Equi atomic in its composition and promises a more …

Development Of Novel Electrodes And Electrolytes For Safer Aqueous Ammonium Ion Batteries With Enhanced Performance., Shelton Farai Kuchena

LSU Doctoral Dissertations

The Lithium-ion battery (LIBs) system has dominated the battery market because of its superior energy and power density. Problems related to LIBs such as safety, scarcity of cobalt and lithium have led researchers to explore alternative battery systems. NH₄⁺ ion is a nonmetal charge carrier with lower molar mass (18 mol g^-1) and smaller hydrated ionic size (3.31 Å) which results in excellent electrochemical properties. Furthermore, NH₄⁺ ion has a tetrahedral structure that has no preferred orientation as compared to spherical metal ions giving a different intercalation chemistry based on hydrogen bonding. These properties …

Corrosion Case Study On Automobile, Grace Ajayi, Xinran Pan, Geethu Sasikala, Marshall S. Yang

Chemistry Publications

No abstract provided.

Deposition, Material Characterization, And Mechanical Testing Of Cr Containing Diamond-Like Carbon Films, Nicholas Anderson

LSU Master's Theses

A series of amorphous hydrogenated chromium containing diamond-like carbon films were deposited on 316 stainless steel substrates with a chromium interlayer through inductively coupled plasma assisted direct current magnetron sputtering. Details on the deposition process of these films are discussed. The film is characterized using scanning electron microscopy, X-ray photoelectron spectroscopy, X-ray diffraction, energy dispersive spectroscopy, and transmission electron microscopy. The coating hardness and indentation modulus is measured by instrumented nanoindentation. The coefficient of friction and the upper bound of the coating wear coefficient is measured using the pin-on-disk method. The fracture toughness of the diamond-like carbon film and a …

Beirut Arab University - Faculty Of Engineering - Newsletter Issue 0, Faculty Of Engineering, Beirut Arab University

Engineering Newsletters

No abstract provided.

Timeline - History Of The Metallurgy / Mineral Processing Programs (1900-2022), Jerome Downey, Larry G. Twidwell

Metallurgy

No abstract provided.

History Of The Metallurgy / Mineral Processing Programs (1900-2022), Jerome Downey, Larry G. Twidwell

Metallurgy

No abstract provided.

Treatment Of Arsenic-Bearing Minerals And Fixation Of Recovered Arsenic Products: An Updated Review, Larry G. Twidwell

Metallurgy

Mineral processing and extractive metallurgical operations have created and are creating appreciable arsenic bearing wastewater and waste solid products that have to be handled, treated for recycle, or treated for environmentally safe disposal. At present there are intense research and operational activities being conducted to provide the best viable processing procedures to ensure that the mineral processing and extractive metallurgical industries are profitable and environmentally secure. The focus of this presentation is on the element arsenic, even though many other deleterious elements may also be present in ores and concentrates. Numerous base metal resources contain arsenic bearing minerals, especially resources …

Entre Punzones Y Percutores Reconstrucción De Tecnología Ósea De Los Selk'nam (Tierra Del Fuego), Rachel Dietz

Independent Study Project (ISP) Collection

Esta investigación se enfoca en el estudio, reconstrucción y uso de la tecnología ósea empleada por las sociedades cazadoras-recolectoras-pedestres que ocuparon el litoral Atlántico de Tierra del Fuego, durante el Holoceno, específicamente se enfoca en la tecnología utilizada por los Selk´nam del Norte de Tierra del Fuego. La tecnología ósea fue una parte importante de su cultura y dos tipos fueron elegidos para investigar: percutores blandos y punzones huecos. Los percutores blandos fueron confeccionados sobre huesos de guanaco, un recurso importante para las sociedades cazadoras-recolectoras.

Los percutores blandos fueron usados para la formatización de artefactos líticos a través de la …

Flexible Materials And Applications For Wearable Sensors, Brock Ferrari

Senior Honors Theses

This literature review aimed to address the limitations of rigid wearable sensors in the medical community by investigating the development of flexible materials for remote health monitoring. A keyword search was conducted on Google Scholar, PubMed, and the Jerry Falwell Library, which yielded 9,102 articles. After applying filtering techniques, the results were narrowed down to 21 articles, which were categorized into "Present Market Conditions," "Flexible Materials for Medical Use," "Applications for Wearable Sensors," and "Potential Use Cases." Discussions were held on prominent materials such as substrate, nanocomposite, and liquid metal materials, exploring their potential applications for chemical and physical sensing, …

Impact Resistance Of Hybrid Metal-Organic Frameworks/Carbon Fibers Composites, Derek Isaac Espinosa Ramirez

Doctoral Dissertations and Master's Theses

The increase in the use of carbon fiber-reinforced polymers (CFRPs) composites in the aerospace industry generated the need of improving the properties and capabilities of these composites by adding nano-reinforcements to the carbon fibers, also called hybrid fiber reinforced polymer composites. In this study, the energy absorption due to impact at low speed will be tested and simulated in four configurations of CFRPs utilizing the same [0/90]_S layout throughout them.

The carbon fiber configurations used during this study are de-sized, acid-activated, metal-organic frameworks (MOF), and carbon nanotubes (CNTs). Nickel (II) Nitrate, Methylimidazole, and Methanol were used to grow the …

Additive Manufacturing For Phase Change Thermal Energy Storage And Management, Thomas B. Freeman

Doctoral Dissertations and Master's Theses

Phase change materials can enhance the performance of energy systems by time shifting or reducing peak thermal loads. Certain electronic devices such as batteries, laser systems, or electric vehicle power electronics are highly transient and require pulse heat dissipation. Heat sinks, or thermal management devices made of a phase change material can absorb large heat spikes while maintaining a constant temperature. Additive manufacturing techniques hold tremendous potential to enable co-optimization of material properties and device geometry, while potentially reducing material waste and manufacturing time. Recently, a few efforts have emerged that employ additive manufacturing techniques to integrate a phase change …

Understanding The Role Thin Film Interfaces Play In Solar Cell Performance And Stability, Mirra M. Rasmussen, Laura S. Bruckman, Ina T. Martin

Student Scholarship

As more efficient and cost-effective photovoltaic (PV) architectures are developed, solar becomes an ever more competitive and viable replacement for fossil fuels. Full grid electrification necessitates the development of efficient, reliable, cost-effective technologies - and there is room for many different kinds of PV in this expanding market. The practical challenges and constraints of terawatt PV production have brought scalability and durability into sharp scientific focus. From a materials perspective, there are commonalities in the materials questions and challenges across different PV technologies. Whereas most PV technology is referred to by the absorber layer - e.g. silicon, or perovskite solar …

Advanced Materials For High Performance Lithium-Sulfur Batteries, Jian Yang

Dissertations

With the advantages of high capacity and low cost, lithium-sulfur batteries (LSBs) have been considered as one of the most promising candidates for next-generation batteries. However, the wide adoption of LSBs to the commercial markets is limited due to the fast capacity decay and low utilization of sulfur. To address these issues, advanced cathodes with high electronic conductivity and strong affinity to elemental sulfur and lithium polysulfides, which are intermediate products during the charge/discharge process, have been developed in this program. Carbon aerogels (RFCs) with controllable porous architectures have been fabricated through adjusting the process parameters and used as the …

Targeting Lncrna Ddit4-As1 Sensitizes Triple Negative Breast Cancer To Chemotherapy Via Suppressing Of Autophagy, Ting Jiang, Jiaojiao Zhu, Shilong Jiang, Zonglin Chen, Ping Xu, Rong Gong, Changxin Zhong, Yueying Cheng, Xinyuan Sun, Wenjun Yi, Jinming Yang, Wenhu Zhou, Yan Cheng

Markey Cancer Center Faculty Publications

In this study, it is found that the lncRNA, DNA damage inducible transcript 4 antisense RNA1 (DDIT4-AS1), is highly expressed in triple-negative breast cancer (TNBC) cell lines and tissues due to H3K27 acetylation in the promoter region, and promotes the proliferation, migration, and invasion of TNBC cells via activating autophagy. Mechanistically, it is shown that DDIT4-AS1 induces autophagy by stabilizing DDIT4 mRNA via recruiting the RNA binding protein AUF1 and promoting the interaction between DDIT4 mRNA and AUF1, thereby inhibiting mTOR signaling pathway. Furthermore, silencing of DDIT4-AS1 enhances the sensitivity of TNBC cells to chemotherapeutic agents such as paclitaxel both …

Hydrothermal Liquefaction Of Saccharina Latissima For The Production Of Biofuel, Mayokun A. Oke

Mechanical Engineering Theses

We performed hydrothermal liquefaction of brown macroalga (Saccharina latissima) in the presence of homogenous and heterogenous catalysts such as KOH, Na₂CO₃, Pd/C, HZSM-5, Ce/HZSM-5, and Ni/SiO₂-Al₂O₃ in hot compressed water, to investigate their effects on product yield and composition in the biocrude. To investigate hydrocarbon production, we used methanol as co-solvent (methanol-to-water 1/4 vol.%) and as the only liquefaction solvent. We carried out the experiments in a batch reactor at 330^oC and 120-130 bar, and varying temperature, algae-to-water ratio, residence time, and pretreatment method. The biocrude yields …

A Comprehensive Study On Non-Proprietary Ultra-High-Performance Concrete Containing Supplementary Cementitious Materials, Seyedsaleh Mousavinezhad, Gregory J. Gonzales, William K. Toledo, Judith M. Garcia, Craig M. Newston, Srinivas Allena

Civil and Environmental Engineering Faculty Publications

Ultra-high performance concrete (UHPC) is a novel cement-based material with exceptional mechanical and durability properties. Silica fume, the primary supplementary cementitious material (SCM) in UHPC, is expensive in North America, so it is often substituted with inexpensive class F fly ash. However, future availability of fly ash is uncertain as the energy industry moves toward renewable energy, which creates an urgent need to find cost-effective and environmentally friendly alternatives to fly ash. This study investigated replacing cement, fly ash, and silica fume in UHPC mixtures with ground granulated blast-furnace slag (GGBFS), metakaolin, and a natural pozzolan (pumicite). To identify acceptable …

Adsorption Of Water Vapour On The Microstructure And Stability Of Cu-Zn Bimetallic Coordination Polymer, Bukunola K. Oguntade, Gareth M. Watkins

Tanzania Journal of Science

A current challenge in the design of synthesis lies in the incorporation of two or more transition metals into a coordination polymer. The most widely used approach has been to incorporate a second metal as a generally innocent (coordinatively saturated) part of a linear linker as in the case of multifunctional carboxylated porphyrins (MCPs). The empirical method has been used to obtain many other types of MCPs; however, the selective, direct replacement of one transition metal within a monometallic coordination polymer via controlled stoichiometry has not generally led to maintained structural fidelity. In this present work, three pyromellitic acid complexes …

Peak And Differential Temperature Determination Of Drilled Shafts, Amanda A. Lewis

USF Tampa Graduate Theses and Dissertations

The term “mass concrete” characterizes a specific concrete condition that typically requires unique considerations to mitigate extreme temperature effects on a structure. Mass concrete has historically been defined by the physical dimensions of a “mass”-ive concrete element with the intent of identifying when differential temperatures may induce early-onset cracking, leading to reduced service life. More recently, in addition to differential temperature considerations, extreme upper temperature limits have been imposed by the American Concrete Institute to prevent long-term concrete degradation. Studies dating back to 2007 show shafts as small as 48 inches in diameter can exceed both differential and peak temperature …

Physics-Based Crystal Plasticity Model For Predicting Microstructure Evolution And Dislocation Densities, Juyoung Jeong

LSU Doctoral Dissertations

This work presents three different studies investigating plastic deformation mechanisms in metals and alloys using crystal plasticity finite element (CPFE) modeling. The first study presents a new nonlocal crystal plasticity model for face-centered cubic single crystals under heterogeneous inelastic deformation. The model incorporates generalized constitutive relations that incorporate the thermally activated and drag mechanisms to cover different kinetics of viscoplastic flow in metals and describes the plastic flow and yielding of single-crystals using dislocation densities. The model is compared to micropillar compression experiments for copper single crystals and clarifies the complex microstructural evolution of dislocation densities in metals. The second …

Recent Research Progresses Of Solid-State Lithium-Sulfur Batteries, Yu Luo, Ru-Qin Ma, Zheng-Liang Gong, Yong Yang

Journal of Electrochemistry

All solid-state lithium-sulfur batteries (ASSLSBs) are considered to be one of the most promising next-generation energy storage systems, due to the promises of high energy density and safety. Although the use of solid-state electrolytes could effectively suppress the "shuttle effect" and self-discharge of the conventional liquid lithium-sulfur (Li-S) battery, the commercialization of ASSLSBs has been seriously hampered by the electrolyte degradation, electrode/electrolyte interfacial deterioration, electrochemo-mechanical failure, lithium dendrite growth and electrode pulverization, etc. This paper provides a comprehensive review of recent research progresses on the solid-state electrolytes, sulfur-containing composite cathodes, lithium metal and lithium alloy anodes, and electrode/electrolyte interfaces in …

Bimetallic Compound Catalysts With Multiple Active Centers For Accelerated Polysulfide Conversion In Li-S Batteries, Wu-Xing Hua, Jing-Yi Xia, Zhong-Hao Hu, Huan Li, Wei Lv, Quan-Hong Yang

Journal of Electrochemistry

Practical applications of lithium-sulfur (Li-S) batteries are hindered mainly by the low sulfur utilization and severe capacity fading derived from the polysulfide shuttling. Catalysis is an effective remedy to those problems by promoting the conversion of polysulfides to reduce their accumulation in the electrolyte, which needs the catalyst to have efficient adsorption ability to soluble polysulfides and high activity for their conversion. In this work, we have proposed a bimetallic compound of NiCo₂S₄ anchored onto sulfur-doped graphene (NCS@SG) to fabricate a catalytic interlayer for Li-S batteries. Compared to CoS, the NiCo₂S₄ demonstrated much higher …

Preface To The Special Issue On Lithium-Sulfur Batteries, Jia-Jia Chen, Ren-Jie Chen, Zhong Jin

Journal of Electrochemistry

No abstract provided.

A Review On Solid-State Li-S Battery: From The Conversion Mechanism Of Sulfur To Engineering Design, Huan-Huan Jia, Chen-Ji Hu, Yi-Xiao Zhang, Li-Wei Chen

Journal of Electrochemistry

Lithium-sulfur (Li-S) batteries attract sustained attention because of their ultrahigh theoretical energy density of 2567 Wh·kg^–1 and the actual value over 600 Wh·kg^–1. Solid-state Li-S batteries (SSLSBs) emerge in the recent two decades because of the enhanced safety when compared to the liquid system. As for the SSLSBs, except for the difference in the conversion mechanism induced by the cathode materials themselves, the physical-chemical property of solid electrolytes (SEs) also significantly affects their electrochemical behaviors. On account of various reported Li-S batteries, the advantages and disadvantages in performance and the failure mechanism are discussed in this review. …

Coni-Based Bimetal-Organic Framework Derived Carbon Composites Multifunctionally Modified Separators For Lithium-Sulfur Batteries, Yan-Jie Wang, Hong-Yu Cheng, Ji-Yue Hou, Wen-Hao Yang, Rong-Wei Huang, Zhi-Cong Ni, Zi-Yi Zhu, Ying Wang, Ke-Yi Wei, Yi-Yong Zhang, Xue Li

Journal of Electrochemistry

The commercial application of lithium-sulfur batteries (LSB) is still limited by the irreversible capacity fading caused by the shuttle of lithium polysulfides (LIPS). To address this issue, a bimetal (nickel, cobalt)-organic framework (MOF) derived carbon, (Ni, Co)/C, was prepared to modify the separator. The multifunctionally modified separator effectively captures LIPS, ensuring the stability and reversibility of sulfur fixation, while providing catalytic activity and improving ionic conductivity. The cobalt metal has a larger coordination number, more pore structure distribution, larger specific surface area, more surface C=O, and smaller particle size to achieve a large and rapid chemical sulfur fixation. The high …