Materials Science and Engineering Commons^™

Machine Learning-Driven Process Analysis And Optimization In Solid-State Welding And Fusion-Based Additive Manufacturing, Radif Uddin Ahmed

Master's Theses

In the modern era of advanced manufacturing, optimizing process parameters is pivotal in ensuring the quality and reliability of sophisticated component fabrication. This study presents a novel, data-driven approach to parameter optimization in two cutting-edge manufacturing techniques: Friction Stir Welding (FSW) and Laser Powder Bed Fusion (LPBF). By leveraging machine learning methodologies, this research addresses the critical challenge of efficiently determining optimal process parameters, a task traditionally relying on time-consuming and resource-intensive trial-and-error methods. This study will lead to a robust data-driven framework for process analysis of more advanced manufacturing techniques like the Additive Friction Stir Deposition (AFSD) process. Friction …

Biocorrosion Analysis Via Multiscale Time Series Analysis, Victor Hugo Mendoza Vejar, Eliseo Hernandez Martinez, Hector Puebla

Annual Symposium on Biomathematics and Ecology Education and Research

No abstract provided.

Biofabrication Of Tissue Constructs Using Protein-In-Polysaccharide Bioinks For Muscle Regeneration, Harshavardhan B

Theses and Dissertations

Myocardial infarction (MI) and volumetric muscle loss (VML) are debilitating conditions that severely affect patient quality of life and challenge healthcare systems, particularly in diagnosis and treatment. Conventional therapies often result in long recovery periods with limited functional restoration. Advances in regenerative medicine, especially extrusion-based 3D bioprinting, offer promising potential to improve the regeneration of complex tissues by precisely depositing cells and biomaterials layer-by-layer to create tailored tissue constructs.

A critical challenge in muscle tissue regeneration is developing protein-polysaccharide bioinks that closely mimic the native muscle tissue microenvironment. In this study, two protein-inpolysaccharide bioinks (alginate-fibrinogen and methylcellulose-gelatin-alginate) were developed to …

Quantifying Chemomechanical Weakening In Muscovite Mica With A Simple Micromechanical Model, Jordan J. Sickle, William M. Mook, Frank W. Delrio, Anastasia G. Ilgen, Wendelin Wright, Karin A. Dahmen

Faculty Journal Articles

In response to gradual nanoindentation, the surface of muscovite mica deforms by sudden stochastic nanometer-scale displacement bursts. Here, the statistics of these displacement events are interpreted using a statistical model previously used to model earthquakes to understand how chemically reactive environments alter the surface properties of this material. We show that the statistics of nanoindentation displacement bursts in muscovite mica are tuned by chemomechanical weakening in a manner similar to how the statistics of model events are tuned by a mechanical weakening parameter that describes how easily system-spanning cracks can be nucleated. Because the predictions of this model are independent …

Anti-Corrosion Performance Of Magnesium Potassium Phosphate Cement Coating On Steel Reinforcement: The Effect Of Boric Acid, Fan Zhang, Jihui Qin, Kangyi Cai, John J. Myers, Hongyan Ma

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

It has recently been found that magnesium potassium phosphate cement (MKPC) paste coating applied on the surface of steel reinforcement can effectively retard the onset of corrosion and suppress corrosion reactions. However, the fast-setting nature of MKPC—which is a merit in repair—can be problematic in a practical engineering process of coating the steel reinforcement with MKPC paste. To address this problem, boric acid (H₃BO₃) was added as a retarder in an MKPC formulation to prolong the setting time. This work investigated the impact of boric acid (at 5% by weight of MgO) on the anti-corrosion performance …

Metal Additive Manufacturing Of Damage-Controlled Elements For Structural Protection Of Steel Members, Hamdy Farhoud, Islam Mantawy

Henry M. Rowan College of Engineering Departmental Research

This paper develops hybrid steel members by integrating additively manufactured, ultra-lightweight, damage-controlled elements (DCEs) into hot-rolled structural steel members. This approach relies on segmenting a structural member into distinct sections; one or two segments are enlarged to be capacity protected; however, another end or middle DCE segment is optimized to emulate the conventional member’s strength and stiffness. A small-scale DCE was topologically optimized and then additively manufactured using a powder bed fusion technique through a direct metal laser sintering process of 17-4PH stainless steel and then was experimentally tested to study the buckling behavior under compression. The experimental testing of …

Refining Chlorosulfonation Methods For The Synthesis Of A Perfluoroalkyl Arylsulfonimide (Pfsi) Monomer, Ainsley P. Foster, Benjamin Varney, Hua Mei

Science University Research Symposium (SURS)

Proton-exchange membrane (PEM) fuel cells are sources of energy that are clean, quiet, and highly responsive to changes in power needs, making them promising for use in automobiles and other portable power devices. The electrolyte of a PEM cell–the layer responsible for conductivity–is a polymer membrane, commonly consisting of perfluoroalkyl sulfonic acid (PFSA) polymers. Perfluoroalkyl arylsulfonimide (PFSI) polymers are expected to improve the efficiency of PEM fuel cells through optimal stability and proton conductivity. The trifluovinylether (TFVE) aryl perfluorosulfonamide monomer is a new PFSI monomer proposed to fulfill these benefits once polymerized. A six-step synthesis route was initially designed to …

The Effect Of Organic Semiconductor Electron Affinity On Preventing Parasitic Oxidation Reactions Limiting Performance Of N-Type Organic Electrochemical Transistors, Maryam Alsufyani, Benjamin Moss, Claudia E. Tait, William K. Myers, Maryam Shahi, Katherine Stewart, Xiaolei Zhao, Reem B. Rashid, Dilara Meli, Ruiheng Wu, Bryan D. Paulsen, Karl J. Thorley, Yuanbao Lin, Craig Combe, Charlie Kniebe-Evans, Sahika Inal, Sang Young Jeong, Han Young Woo, Grant Ritchie, Ji-Seon Kim, Jonathan Rivnay, Alexandra F. Paterson, James R. Durrant, Iain Mcculloch

Chemical and Materials Engineering Faculty Publications

A key challenge in the development of organic mixed ionic-electronic conducting materials (OMIEC) for high performance electrochemical transistors is their stable performance in ambient. When operating in aqueous electrolyte, potential reactions of the electrochemically injected electrons with air and water could hinder their persistence, leading to a reduction in charge transport. Here, the impact of deepening the LUMO energy level of a series of electron-transporting semiconducting polymers is evaluated, and subsequently rendering the most common oxidation processes of electron polarons thermodynamically unfavorable, on organic electrochemical transistors (OECTs) performance. Employing time resolved spectroelectrochemistry with three analogous polymers having varying electron affinities …

Synthesis And Properties Of (Hf,Mo,Ti,W,Zr)B2–(Hf,Mo,Ti,W,Zr)C Dual Phase Ceramics, S. Filipović, S. M. Smith, G. Hilmas, W. Fahrenholtz, N. Obradović, S. Curtarolo

Materials Science and Engineering Faculty Research & Creative Works

Dense, dual phase (Hf,Mo,Ti,W,Zr)B₂–(Hf,Mo,Ti,W,Zr)C ceramics were synthesized with varying contents of Mo and W. The final (Hf_0.317Mo_0.025Ti_0.317W_0.025Zr_0.317)C–(Hf_0.317Mo_0.025Ti_0.317W_0.025Zr_0.317)B₂ was a nominally pure, dual phase ceramic, while compositions with higher amounts of Mo and W contained multiple phases. The final microstructures had submicron grains due to pinning effects. Vickers hardness values were up to 48.6 ± 2.2 GPa for an applied load of 0.49 N for the ceramic with optimized composition and densification. The solubility limits for Mo and …

Atmosphere Effects In Laser Powder Bed Fusion: A Review, Ben Brown, Cody Lough, Davis Wilson, Joseph Newkirk, Frank Liou

Materials Science and Engineering Faculty Research & Creative Works

The use of components fabricated by laser powder bed fusion (LPBF) requires the development of processing parameters that can produce high-quality material. Manipulating the most commonly identified critical build parameters (e.g., laser power, laser scan speed, and layer thickness) on LPBF equipment can generate acceptable parts for established materials and moderately intricate part geometries. The need to fabricate increasingly complex parts from unique materials drives the limited research into LPBF process control using underutilized parameters, such as atmosphere composition and pressure. As presented in this review, manipulating atmosphere composition and pressure in laser beam welding has been shown to expand …

Investigating The Effect Of Microwave Pretreatment On Bastnasite Grinding For Comminution Energy Reduction And Rare Earth Recovery, Kaveh Asgari, Qingqing Huang, Rick Q. Honaker, Edward Sabolsky

Chemical and Materials Engineering Faculty Publications

This study explored the impact of microwave pretreatment on the grinding efficiency of bastnaesite ore using a stirred mill. Bastnaesite ore was prepared using a staged crushing and sieving process, followed by microwave pretreatment in a specially designed microwave furnace system. Representative samples of the crushed ore underwent stirred mill grinding, with power draw measurements recorded and adjusted to reflect only the specific energy input required for grinding. Particle size distribution was analyzed periodically using laser particle size analysis. In addition, a Box–Behnken design was used to statistically assess the effects of various parameters on the results, ensuring a robust …

Liquid Crystalline Collagen Assemblies As Substrates For Directed Alignment Of Human Schwann Cells, Homa Ghaiedi, Luis Carlos Pinzon-Herrera, Saja Alshafeay, Leonard Harris, Jorge Almodovar, Karthik Nayani

Chemical Engineering Faculty Publications and Presentations

Collagen is a key component of the extracellular matrix (ECM) and well-oriented domains of collagen are important for mimicking the local cell environment in vitro. While there has been significant attention directed towards the alignment of collagen, formation of large-scale oriented domains remains a key challenge. Type I collagen self-assembles to form liquid crystalline (LC) mesophases in acidic conditions at concentrations above 100 mg mL−1. The LC mesophase provides an efficient platform for large-scale alignment and patterning of collagen coated substrates. However, there still exist challenges related to solubilizing and processing of collagen at such high concentrations in order …

Insulator-To-Metal Transition And Isotropic Gigantic Magnetoresistance In Layered Magnetic Semiconductors, Gokul Acharya, Bimal Neupane, Chia-Hsiu Hsu, Xian P. Yang, David Graf, Eun Sang Choi, Krishna Pandey, Md Rafique Un Nabi, Santosh Karki Chhetri, Rabindra Basnet, Sumaya Rahman, Jian Wang, Zhengxin Hu, Bo Da, Hugh O.H. Churchill, Guoqing Chang, M. Zahid Hasan, Yuanxi Wang, Jin Hu

Physics Faculty Publications and Presentations

Magnetotransport, the response of electrical conduction to external magnetic field, acts as an important tool to reveal fundamental concepts behind exotic phenomena and plays a key role in enabling spintronic applications. Magnetotransport is generally sensitive to magnetic field orientations. In contrast, efficient and isotropic modulation of electronic transport, which is useful in technology applications such as omnidirectional sensing, is rarely seen, especially for pristine crystals. Here a strategy is proposed to realize extremely strong modulation of electron conduction by magnetic field which is independent of field direction. GdPS, a layered antiferromagnetic semiconductor with resistivity anisotropies, supports a field-driven insulator-to-metal transition …

Size And Shape Dependence Of Hydrogen-Induced Phase Transformation And Sorption Hysteresis In Palladium Nanoparticles, Xingsheng Sun, Rong Jin

Chemical and Materials Engineering Faculty Publications

Phase transitions of metals in hydrogen (H) environments are critically import- ant for applications in energy storage, catalysis, and sensing. Nanostructured metallic particles can lead to faster charging and discharging kinetics, increased lifespan, and enhanced catalytic activities. However, establishing a direct causal link between nanoparticle structure and function remains challenging. In this work, we establish a computational framework to explore the atomic config- uration of a metal-hydrogen system when in equilibrium with a H environ- ment. This approach combines Diffusive Molecular Dynamics with an itera- tion strategy, aiming to minimize the system’s free energy and ensure uniform chemical potential across …

Engineering The Coherent Phonon Transport In Polar Ferromagnetic Oxide Superlattices, In Hyeok Choi, Seung Gyo Jeong, Do-Gyeom Jeong, Ambrose Seo, Woo Seok Choi, Jong Seok Lee

Chemical and Materials Engineering Faculty Publications

Artificial superlattices composed of perovskite oxides serves as an essential platform for engineering coherent phonon transport by redefining the lattice periodicity, which strongly influences the lattice-coupled phase transitions in charge and spin degrees of freedom. However, previous methods of manipulating phonons have been limited to controlling the periodicity of superlattice, rather than utilizing complex mutual interactions that are prominent in transition metal oxides. In this study on oxide superlattices composed of ferromagnetic metallic SrRuO3 and quantum paraelectric SrTiO3 , phonon modulation by controlling the geometry of superlattice in atomic-scale precision is realized, demonstrating the coherent phonon engineering using structural and …

Development Of Multifunctional Wood Composites With Integrated Phase Change Materials For Enhanced Thermal Management, Self-Healing, And Sustainability., Emmanuel Igbokwe

LSU Master's Theses

Abstract

This study focused on incorporating self-healing, flame retardancy, and energy harvesting capabilities into the wood composite to contribute to more sustainable and energy-efficient building practices. Oriented strand board has been widely used as sheath for roofing or dry walls in residential buildings. Residential buildings account for a large portion of energy consumption. Therefore, an oriented strand board with energy harvesting capability is highly desired. Additionally, flame retardancy and damage self-healing and end-of-life recycling are also critical features for buildings.

In this study, we prepared a novel oriented strand board by constructing sandwich structures. The face sheets of the sandwich …

Lithicone-Protected Lithium Metal Anodes For Lithium Metal Batteries With Nickel-Rich Cathode Materials, Ridwan A. Ahmed, Kevin V. Carballo, Krishna P. Koirala, Qian Zhao, Peiyuan Gao, Ju-Myung Kim, Cassidy S. Anderson, Xiangbo Meng, Chongmin Wang, Ji-Guang Zhang, Wu Xu

Mechanical Engineering Faculty Publications and Presentations

The high energy density advantage of lithium (Li) metal batteries (LMBs) makes them increasingly desirable; however, problems such as strong reactivity and dendrite growth of Li metal anode limit their practical uses. In this work, a novel Li-containing glycerol (LiGL) or lithicone protection layer on a 50 μm thick Li metal anode is employed for improving the performance of LMBs. This LiGL layer was accurately deposited via a molecular layer deposition (MLD) process at 150°C, using lithium tert-butoxide and glycerol as precursors. The as-formed LiGL coating layer is highly tunable in its thickness by simply adjusting MLD cycles and shows …

Implementation Of Mash Surrogate Test Vehicles For Sign Supports, Breakaway Poles, And Work Zone Traffic Control Devices, Mahfuza Rahman Doreen

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

This describes the development of two surrogate test vehicles, or "bogie vehicles," for performing compliance testing of breakaway devices found on the roadside according to the American Association of State Highway and Transportation Officials (AASHTO) Manual for Assessing Safety Hardware (MASH). Historically, surrogate vehicle testing and approval of roadside structures was not permitted, because critical vehicle behaviors could not be emulated using the existing or modified rigid frame structures. Therefore, Project NCHRP 22-55 was funded to develop two reusable bogie vehicles to emulate the MASH 1100C small car and 2270P pickup truck. This thesis describes the background data collection, initial …

Treatment Methods Of Unstable Expansive Soil Slope Excavation In Overlying Rock Layer In Alpine Region, Shi Xiaobo, Cui Guangyan, Mou Chao, Wen Ye, Xie Feng, Fu Xiaoyang

Journal of China & Foreign Highway

To deeply study the treatment method for instability of highway cutting slope under the condition of expansive soil overlying rock layer in an alpine region，the comprehensive treatment method of unstable slope under this bad geology was put forward based on the unstable slope project of Zhangbei‒Shangyi Expressway.The governance protection structure consisted of a rigid protection system，drainage system，thermal insulation system，flexible protection system，and waterproof system.The rigid protection system was an anti-slide pile setting at the height of 1/3 of the first grade slope，of which parameters were calculated by cutting the slope of the rock layer in the unstable area to reduce the …

Treatment And Measurement Of Water Inrush During Highway Tunnel Construction, Wang C Haojie, Feng Zhihua, Fan Haobo

Journal of China & Foreign Highway

As a special geological condition of highway tunnels，water inrush will cause difficulties in engineering construction technology and management.Unnecessary disputes and management difficulties will emerge when different construction units hold different views about the treatment measures of water inrush，which leads to distributed provisions in the specification and a long treatment period.In view of key problems about the water inrush during highway tunnel construction，including water inrush treatment concept，investigation and estimation，measurement and pricing，and on-site confirmation，this paper systematically sorted out the current regulations and other guiding documents and investigated the treatment methods of tunnel water inrush and reverse slope pumping in China ’s highway …

Review Of Evaluation Methods For Mixing Workability Of Asphalt Mixture, Dong Fuqiang, Zu Yuanzhe, Yu Xin, Chen Bei, Liu Lin

Journal of China & Foreign Highway

To clarify the evaluation methods an d research status of mixing workability of asphalt mixture， by consulting relevant research literature in China and abroad and analyzing different evaluation methods，indexes，and research findings of the workability of asphalt mixture，the applicability and evaluation effects of different workability evaluation methods were systematically summarized，and the comparative analysis and comprehensive review were made on the main influencing factors of the mixing workability.The results show that in most evaluation methods for the mixing workability of asphalt mixture，corresponding indexes are constructed to quantitatively evaluate the workability by quantifying the resistance or energy consumption in the mixing process.Besides，in some …

Research Review Of Biomass Ash As Concrete Admixture, Ma Bicong, Liang Jian, Weng Yiling

Journal of China & Foreign Highway

In order to provide a comprehensive overview of research progress in the use of biomass ash as concrete admixture，the physical and chemical properties，mechanism of action，factors affecting the production process of biomass ash，and the effects of biomass ash incorporation on the working properties，mechanical properties，and durability of concrete were studied.The results show that biomass ash has a smaller density and a larger specific surface area than traditional mineral admixture，and the total amount of active components，namely SiO2 + Al2O3 + Fe2O3 （SAF） in most biomass ashes exceeds the requirements of class F volcanic ash （≥70%）.Incorporating biomass ash can effectively improve the mechanical properties …

Compaction Characteristics Of Granular Material And Its Structural Mechanical Behavior Considering Orthotropy, Huang You, Zhang Yunbao, Liu Zhaohui, Pan Yu, Liu Zebin, Fang Ronghai

Journal of China & Foreign Highway

The orthotropy of granular materials is closely related to the compaction process and has a significant impact on the mechanical behavior of pavement structures.In this study，in order to study the effect of the compaction process on the orthotropy of granular materials，different compaction methods and compaction energies were employed to compact granular materials for pavement into specimens，and improved dynamic resilient mechanical tests were conducted.Orthotropic coefficients （α2） of typical granular materials were obtained，and the finite element method was used to conduct mechanical analysis of asphalt pavement structures considering the orthotropy of granular materials.The results show that the dry density of specimens by …

Effect Of Basalt Fiber On Strength Of Cement‑Stabilized Macadam Base, Shu Hongbo, Tang Zhengguang, Zhang Yanhong, Bu Xilian, Liang Dong

Journal of China & Foreign Highway

To study the performance of basalt fiber in improving the poor angularity of the crushed cobble base，based on the orthogonal test，this paper determined that the optimal dosage of basalt fiber in the cement-stabilized crushed cobble was 1 kg/m3 （15 mm） + 2 kg/m3 （25 mm）.Besides，unconfined compressive strength and splitting strength tests were carried out on mixtures under three working conditions including the cement-stabilized crushed cobble，cement-stabilized crushed cobble with the optimal dosage of basalt fiber，and cement-stabilized macadam （limestone machine-crushed stone ）.The results show that influenced by the aggregate angularity，the strength of the cement-stabilized macadam （limestone machine-crushed stone ） mixture is better …

Design And Simulation Of Anti‑Collision System On Independent Pile With External Composite, Liao Yuanyuan, Liu Yu, Zhu Lu, Fang Hai, Zhang Jinrui, Han Juan

Journal of China & Foreign Highway

The precise calculation of the ship-bridge collision force is necessary for the assessment of the structural safety of the bridge and the design of an effective anti-collision system.Taking the ship-bridge issue in Furong Bridge in Xiangtan City，this paper compared the collision forces from different angles and in different locations calculated through the finite element software Ansys/LS-DYNA with the results calculated through the empirical formula，thereby determining the fortification collision forces of the bridge piers.Based on the weak anti-collision ability of the bridge double-limb thin-walled pier，the paper designed and implemented a new anti-collision system combined with composite and concrete-filled steel independent piles.The …

Intelligent Recognition Technology Of Highway Cracks Based On Semantic Segmentation, Gao Liang, Rao Faqiang, Yang Zhongmin, Dai Zongsheng, Sun Hao

Journal of China & Foreign Highway

Real-time detection and timely treatment of highway cracks are crucially fundamental for vehicle safety.Rapid identification and comparison of cracks is a new method for monitoring the development and changes of geological disasters especially when they induce cracks.Therefore，this study proposed an intelligent recognition method of highway cracks based on semantic segmentation，establishing a model with dataset，neural network，calculation parameters，and evaluation indicators to rapidly identify the cracks.The results show that，firstly，when the neural network Attention U-net built in this study semantically segments highway cracks，the binary cross loss function value and accuracy rate reach 0.008 7 and 0.998 4，respectively.Secondly，compared with traditional algorithms，the semantic segmentation method shows …

Lessons Learned From 60 Years Of Pavement Trials In Continental Climate Regions Of Canada And Future Perspective, Wang Di, Li Jingxiao, Ren Xueyuan, Zhang Fan, Yuan Dongdong

Journal of China & Foreign Highway

During the early 1960 s，Canadian road authorities began using stiffer asphalt to address the issue of early rutting in the wheel track zone of asphalt pavements，which was caused by the growing traffic volumes.Pavements constructed with stiffer asphalt commonly exhibit evenly spaced transverse cracks due to the significant internal stresses caused by low temperatures and the inadequate resistance of the asphalt to cracking under such conditions.Research conducted on asphalt pavements with cracks caused by low temperatures has verified the significant impact of asphalt ’s consistency，temperature sensitivity，phase uniformity，and durability.In order to tackle the difficulties presented by the utilization of modified asphalt in …

Method Of Solving Initial Construction Cable Force Of Completed Cable‑Stayed Bridge, Xu Yufeng, Chen Si, Xie Yunfei, Zhu Mengyang

Journal of China & Foreign Highway

To solve the initial construction cable forces of a completed cable-stayed bridge，a method that combines unstressed cable length and forward-iteration is proposed.Firstly，the unstressed length of each cable is calculated according to the completed bridge state.Then，the initial cable forces are obtained by using the unstressed cable length for the forward analysis.The initial construction cable forces are adjusted by difference iteration.Finally，the initial construction cable forces are fine-tuned according to the deformation of the pylon deformation to obtain the bridge completion state that satisfies the deviation requirements.The proposed method is employed in a cable-stayed bridge with a known completion state to calculate the …

Experimental Study On Influence Of Stress Ratio On Fatigue Life Of High Strength Steel Wire, Zeng Yi, Yan Donghuang, Xu Hongsheng, Yang Ying

Journal of China & Foreign Highway

To clarify the influence of stress ratio on the fatigue life of high strength steel wire and verify the applicability of the fracture mechanics model to evaluate the fatigue life of steel wire，based on the assumption of equating wire corrosion pits to notches，fatigue tests were carried out on steel wire samples with different prefabricated notch depths at different stress ratios，and a fatigue life empirical equation considering the stress ratio effect was established.The results show that the fatigue life of the steel wire samples is significantly influenced by the stress ratio，which decreases with the increase in the stress ratio.The increase in …

Influence Of High Temperature On Large Cantilever Construction Control Of Wide Extradosed Cable‑Stayed Bridge, Zhu Haojie, Zhang Xiedong, Li Yong, Lin Yuan, Wu Di

Journal of China & Foreign Highway

In order to investigate the influence of temperature gradient on the construction of wide extradosed cable-stayed bridges in the large cantilever construction stage at high temperatures，the solar radiation and thermal boundary conditions of wide equal-height box girder were theoretically calculated，and the thermal analysis finite element model of the wide equal-height box girder was established by Abaqus.The cross-section temperature of the box girder was measured by intelligent string sensors and an infrared thermometer.The temperature gradient and its distribution of wide equal-height box girder from sunrise to sunset on a certain day in summer were calculated.The finite element model of the construction …