Materials Science and Engineering Commons^™

Electrocatalytic Nitric Oxide Reduction To Yield Ammonia Over Fe3C Nanocrystals, Sen Lin, Lang Zhang, Tong Hou, Jun-Yang Ding, Zi-Mo Peng, Yi-Fan Liu, Xi-Jun Liu

Journal of Electrochemistry

Nitric oxide (NO), which generally originates from vehicle exhaust and industrial flue gases, is one of the most serious air pollutants. In this case, the electrochemical NO reduction reaction (NORR) not only removes the atmospheric pollutant NO but also produces valuable NH₃. Hence, through the synthesis and modification of Fe₃C nanocrystal catalysts, the as-obtained optimal sample of Fe₃C/C-900 was adopted as NORR catalyst at ambient conditions. As a result, the Fe₃C/C-900 catalyst showed an NH₃ Faraday efficiency of 76.5% and an NH₃ yield rate of 177.5 μmol·h^–1·cm^{–2 …}

Ordering Degree Regulation Of Pt2Nico Intermetallics For Efficient Oxygen Reduction Reaction, Chen-Hao Zhang, Han-Yu Hua, Jun-Hao Yang, Qian Zhang, Chang Yang, De-Li Wang

Journal of Electrochemistry

Alloying transition metals with Pt is an effective strategy for optimizing Pt-based catalysts toward the oxygen reduction reaction (ORR). Atomic ordered intermetallic compounds (IMC) provide unique electronic and geometrical effects as well as stronger intermetallic interactions due to the ordered arrangement of metal atoms, thus exhibiting superior electrocatalytic activity and durability. However, quantitatively analyzing the ordering degree of IMC and exploring the correlation between the ordering degree and ORR activity remains extremely challenging. Herein, a series of ternary Pt₂NiCo intermetallic catalysts (o-Pt₂NiCo) with different ordering degree were synthesized by annealing temperature modulation. Among them, the o-Pt …

Performance Of Co2/H2O Co-Electrolysis In A Flat-Tube Solid Oxide Electrolysis Cell Stack Under Air-Free Environment, Xiao-Hui Zhong, Fei Wang, An-Qi Wu, Bei-Bei Han, Jian-Xin Wang, Wan-Bing Guan

Journal of Electrochemistry

This work investigates the transient performance and stability of CO₂/H₂O co-electrolysis in an air-free environment using a flat-tube solid oxide electrolysis cell (SOEC) stack. The results show that the transient behavior of the stack with and without blowing gas in the air electrode is almost the same. With a current density of 0.67 A·cm⁻²@750 °C, the stack operated for over 200 h under co-electrolysis conditions with no air blowing, and the voltage drop rate of the stack was approximately 0.203%/100 hours. Microstructure analysis reveals significant loss of Ni particles and formation of an insulating …

Variation Of Membrane Electrode Assembly Catalyst Layer In Unitized Regenerative Fuel Cell, Yollanda Nurcholifah, Dedi Rohendi, Edy Herianto Majlan, Nirwan Syarif, Addy Rachmat, Dwi Hawa Yulianti, Nyimas Febrika S

Journal of Electrochemistry

A unitized regenerative fuel cell (URFC) is a device that may function reversibly as either a fuel cell (FC) or water electrolysis (WE). An important component of this device is the Membrane electrode assembly (MEA). Therefore, this study aimed to compare the performance outcomes of MEA using electrodes with single and three catalyst layers. This study measured Electrochemical Surface Area (ECSA), Electrochemical Impedance Spectroscopy (EIS), X-ray Diffraction analysis (XRD), and X-ray Fluorescence (XRF). Furthermore, the round-trip efficiency (RTE) of the MEA, as well as the performance in FC and WE mode, was measured. In comparison, The ECSA values of Pt-Ru/C …

Performance Of Quasi-Isotropic Gf/Pet Laminates In Impact And Compression After Impact Loading, Yubo Ma, Shuoyan Niu

Research & Creative Achievement Day

The impact resistance and residual compression strength of two types of glass fiber/ polyethylene terephthalate composites are investigated in this research project. The first materials are glass fiber/ polyethylene terephthalate glycol (GF/PRTG) and the second material is glass fiber/ amorphous polyethylene terephthalate (GF/PETa). Both matrix materials are ductile thermoplastic polymers. The ductility of the matrix is expected to improve the impact resistance of the composites. The advantage of the first material is higher ductility and improved fire resistance, and the advantage of the second material is high bonding strength with the reinforcing fiber glass. Both matrixes and low cost engineered …

Panel Impact And Compressing Strength Testing, Michael A. Dietz, Wyatt N. Laborde

Research & Creative Achievement Day

Intro/Purpose: This project was conducted to investigate how a material's compressive strength is affected after being impacted while supported on three sides. This has broader implications, helping us understand how military equipment, such as battleships, have their compressive strength affected when impacted by projectiles like bullets, shrapnel, or other objects.

Methodology: This test was conducted using panels made of multiple layers of fiberglass pressed together to form a solid sheet. We then cut these sheets into multiple panels. These panels were rectangular, with a tab coming off three sides. The three tabs simulated a wall supporting the material …

Durafold Premium: Composite Folding Table, Regan G. Harvey, Hendrik J. Welti, Parker D. Buth, Stadler J. Lucas, Grace Eischens

Research & Creative Achievement Day

Current folding table designs are made to be lightweight, but the table surface made of high density polyethylene (HDPE) can break and is not repairable. Our team designed the DuraFold Premium as an alternative to the traditional folding tables. The table surface and legs use a sandwich construction consisting of top and bottom face sheets made with carbon and glass reinforcing fibers in an epoxy resin system. In between the two face sheets is a honeycomb core material. This approach results in the DuraFold Premium being extremely durable while remaining lightweight. Over the past academic year, our team has been …

Carbon Club Carrier: A Lightweight Motorized Golf Pushcart, Tanner J. Conniff, Eric M. Courneya, Alex Hilo, Max R. Kauphusman, Luis M. Rodriguez

Research & Creative Achievement Day

The Carbon Club Carrier is a lightweight, motorized golf pushcart designed to enhance convenience and ease of use for golfers. Traditional golf push carts can be cumbersome and require significant effort to maneuver across varying terrain. Our design integrates a carbon fiber frame for durability and weight reduction, coupled with an electric push-assist motor to reduce strain on the user. The use of carbon fiber composite materials ensures a strong yet lightweight structure, optimizing portability and performance. The push-assist motor system is designed to provide variable-speed assistance, allowing golfers to move their clubs effortlessly across the course. The carrier is …

A Novel Fixture Development To Characterize Compression After Impact Damage Of Unidirectional Thermoplastic Composite Laminates, Matt K. Ficker, Dominic L. Perez, Noah Misukanis, Luke E. Poglayen, Jacob Kosmoski

Research & Creative Achievement Day

Impact testing of unidirectional thermoplastic composite materials is a challenge due to the Mode I shear of the primary tows on the impact side. Thermoplastic composite products manufactured using laminate stacking are bonded together with films of polymer on both sides of oriented fiber in typically a cross-ply or quasi-isotropic stack. The resulting failure from the distortion field imposed by a hemispherical tup is debonding along the interface between layer 1 and layer 2 oriented in the layer 1 direction from impact site to edge of panel. This failure mode results when the sample is too small relative to the …

Evaluation Of Chloride Diffusion In Concrete Using Bulk Diffusion Test And Scanning Electron Microscopy, Payton Davis

Doctoral Dissertations and Master's Theses

Reinforced concrete is one of the most widely used construction materials in the world with many bridges and other major infrastructure consisting of such structural elements. A primary concern impacting the durability of concrete is chloride penetration in aggressive environments such as marine or coastal areas. In such environments, chloride ions can penetrate into the pores of concrete leading to the corrosion of embedded steel reinforcement which compromises the structural integrity of concrete. To investigate the issue, a comprehensive experimental program was designed and implemented which involved the preparation and testing of 31 different concrete mixes, each incorporating varying proportions …

Advanced Manufacturing Of Multifunctional Shape Memory Polymer Composites And Self-Healing Systems, John B. Konlan

LSU Doctoral Dissertations

The need for multifunctional light weight structures for engineering applications is on the rise. Multifunctional composites are desired because of their ability to combine multiple functionalities into one structure. The advantages of a high strength-to-weight ratio of multifunctional composites make them desirable and suitable for use in energy-efficient applications. Shape-memory polymers (SMPs) have attracted interest over the past several decades because of their multifunctional nature. They have found use in many applications such as aerospace, satellites, automobiles, textiles, and biomedical devices, where lightweight and multifunctionality are key. The self-healing nature of most SMPs makes them suitable for use in lightweight …

Bioactivity And Mechanical Performance Of Centrifugally Spun Poly(D,L-Lactide)/Poly(3-Hydroxybutyrate) Submicrometric Fibers Containing Zinc Oxide And Hydroxyapatite Nanostructures, Victoria Padilla-Gainza, Heriberto Rodríguez-Tobías, Karen Lozano, Cristobal Rodriguez, Robert Gilkerson, Antonio Ledezma-Pérez, Narcedalia Anaya-Barbosa, Graciela Morales

Mechanical Engineering Faculty Publications

This study investigates the morphological, thermal, mechanical, and bioactive properties of centrifugally spun fibrous composites made from poly(D,L-lactide)/poly(3-hydroxybutyrate) (PLA/PHB) blends with zinc oxide (ZnO) and hydroxyapatite (Hap) nanoparticles. A 75/25 PLA/PHB weight ratio was chosen to balance mechanical and thermal properties. The precursor solution viscosities ranged from 0.25 to 0.50 Pa s, increasing with nanoparticle incorporation probably due to polymer-nanoparticle interactions. SEM revealed a uniform fibrous morphology, with diameters of 1.21 for PLA/PHB, 2.65 for PLA/ZnO/Hap, and 1.80 μm for PLA/PHB/ZnO/Hap. TGA showed two-step degradation for PLA/PHB fibers, while PLA/PHB/ZnO/Hap degraded in a single step at 249°C, leaving a residue …

Impact Of Repeated Washing Cycles On Surface Integrity And Mechanical Properties Of Glass Bottles, Siwat Patamakam Mr., Thitisilp Kijchavengkul, Siriyupa Netramai, Gong Yaijam

Journal of Applied Packaging Research

Glass bottles are a top choice in the global beverage industry, but their inherent brittleness poses challenges in maintaining durability. This study focused on investigating the impact of numbers of washing processes from reusing on the surface quality and mechanical properties of glass bottles after each washing cycle. Contact angle technique was used to determine surface quality of glass bottles. It was found that mechanical integrity, as reflected in internal pressure resistance values, and surface quality of glass bottles exhibited an exponential decline with each washing cycle. Furthermore, a predictive model (R² = 0.8882) was developed to estimate its …

Numerical Simulation Of Heat Transfer In Self-Propagating High-Temperature Synthesis (Shs)-Based Calcination Of Limestone, Sayee Srikarah Volaity, Shubham Agrawal, Srinivas Kilambi, Patrick Phelan, Aditya Kumar, Narayanan Neithalath

Materials Science and Engineering Faculty Research & Creative Works

Calcination of limestone, a high temperature (∼900 °C) process that emits 44 % of the mass of limestone as CO₂, is a critical process in the production of many industrially important materials. To soften the CO₂-related impacts of traditional calcination, and to enable ultrafast synthesis of lime, a novel approach based on self-propagating high-temperature synthesis (SHS) has been put forward. SHS uses exothermic heat released by the combustion of fuel intermixed with the reactants to advance the reaction, and hence requires the provision of lower external temperatures. This study introduces a microstructure-guided modeling approach to understand …

Compositionally Complex Diborides: Competing Solubility During Sintering And Properties, Laura Silvestroni, Carlo Baldisserri, Jacopo Matteo Tabaglio, Nicola Gilli, Jeremy Watts, Steven M.I. Smith, Gregory E. Hilmas, William G. Fahrenholtz

Materials Science and Engineering Faculty Research & Creative Works

An ultra-high temperature ceramic based on ZrB2, TiB2, and SiC was hot pressed to full density at 1850 °C. Addition of 5 vol% of different metal-compounds, in the form of HfC, VC, NbC or CrB2, increased the densification temperature to 1910 °C. The resulting compositionally complex ceramics had homogeneous microstructures with boride grains exhibiting core-shell features. The shell was a solid solution containing variable amounts of the three metals. Notably, TiB2 remained as a discrete phase in the reference material and in the presence of the V- and Cr- based additions, whilst it dissolved into the main ZrB2-based grains for …

Effects Of Wetting Events On Mass Timber Surface Microbial Communities And Voc Emissions: Implications For Building Operation And Occupant Well-Being, Gwynne Á. Mhuireach, Susan Collins, Leslie Dietz, Patrick Finn Horve, Aurélie Laguerre, Dale Northcutt, Jason Stenson, Kevin Van Den Wymelenberg, Elliott Gall, Mark Fretz

Mechanical and Materials Engineering Faculty Publications and Presentations

IntroductionHumans have used wood as a construction material throughout history. Currently, mass timber products, such as cross-laminated timber (CLT), are becoming more popular as a structural material, since they are renewable and have a lower carbon footprint than concrete or steel. Nonetheless, some building types, such as healthcare, veterinary, and food manufacturing, avoid using structural mass timber due to concerns about microbial growth in the event of wetting. One solution is to use protective coatings on mass timber products to increase moisture resistance, although the coatings themselves may generate concerns about volatile organic compound (VOC) emissions. Natural uncoated wood also …

Atomistic Simulations Of Shape Memory Behavior And Negative Poisson's Ratio Effect Of Liquid Crystal Elastomers, Nanang Mahardika

Student Research Symposium

• LCEs are suitable materials for soft robotics application because it is programmable, responsive to various stimuli and has flexibility.

2024, A Landmark Year For Climate Change And Global Carbon Capture, Utilization, And Storage: Annual Progress Review, Shangli Shi, Yun Hang Hu

Michigan Tech Publications

This annual review outlines the progress of carbon capture, utilization, and storage (CCUS) technologies in 2024. As human-induced CO2 emissions continued to rise, the year presented critical challenges. Notably, 2024 was the hottest year on record and the first in which global temperatures exceeded preindustrial levels by more than 1.5°C, driving intensified efforts to advance CCUS. Scientific interest in CCUS grew significantly, with the annual number of related publications increasing by 11.4% compared to 2023, reaching 53,970. The total number of operational commercial CCUS facilities also expanded, rising by 16.3% to a total of 50. In the political area, governments …

Fabrication Of Ultra High-Temperature Compact Heat Exchanger By Extrusion-Based Ceramic Additive Manufacturing, Abid Hasan Rafi, David W. Lipke, Jeremy Lee Watts, Greg Hilmas, Ming-Chuan Leu

Miners Solving for Tomorrow Research Conference

No abstract provided.

Physical Characterization Of Copper Anode Slimes, Carter Glynn, Michael S. Moats

Miners Solving for Tomorrow Research Conference

No abstract provided.

Sustainable Solutions To Eutrophication: The Role Of Glass Fertilizers, Lucas Greiner, Charmayne Lonergan

Miners Solving for Tomorrow Research Conference

No abstract provided.

Additive Manufacturing Of Thermoplastic Composites, Matik Heskin, K. Chandrashekhara, Richard Billo, Ming-Chuan Leu, Thomas P. Schuman

Miners Solving for Tomorrow Research Conference

No abstract provided.

Microstructural Evolution Of High-Entropy Carbide Ceramics, Elizabeth Pritchett, William Fahrenholtz, Greg Hilmas, Steven Smith

Miners Solving for Tomorrow Research Conference

No abstract provided.

Polymerization Methods For Vinyl Phosphonate Monomers: Challenges And Perspectives, Sara Mccauley

Miners Solving for Tomorrow Research Conference

No abstract provided.

Preliminary Assessment Of Non-Volatile Particulate Matter And Gaseous Emissions From A Premixed Pre-Vaporized Combustor Designed For Civil Supersonic Transport, Ugochukwu Ewuzie, Godwin Ifeanyi Ogbuehi, Steven Achterberg, Monday Uchenna Okoronkwo, Philip D. Whitefield

Miners Solving for Tomorrow Research Conference

No abstract provided.

Innovative Design Methodology For Durable Open-Graded Friction Course Asphalt Mixtures, Anas Abualia

LSU Doctoral Dissertations

Open-graded friction course (OGFC) is a thin asphalt mixture surface layer with a high percentage of coarse aggregates and high interconnected air voids, which provides improved skid resistance, visibility, and decreased pavement-tire noise. However, construction personnel at DOTD reported that conventional OGFC mixtures have short service life (raveling distress). Further, their structural contribution to the pavement structure is commonly neglected and designed only for functionality purposes.

The objective of this study was to develop a rational mix design methodology to improve the durability of OGFC asphalt mixtures. Specific objectives are to: (1) conduct a rheological and chemical characterization of polymer-, …

Underlying Mechanisms Of The Effect Of Microfines Of Manufactured Sand On Non-Linear Structural Build-Up Of Cement Paste, Jiang Zhu, Jiaping Liu, Kamal H. Khayat, Xin Cheng, Wei Zhao, Zhen Li, Xin Shu, Yongbo Huang

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The rheological properties of cement-based materials made with manufactured sand vary with the content and physio-chemical properties of microfines in the sand. However, the evaluation of rheological properties regarding the structural build-up at early-age hydration remains challenging for the cementitious materials prepared with different manufactured sands, due to complicated underlying structuration mechanisms. This paper studies the effect of disparate microfines of different manufactured sands on the non-linear growth of static yield stress of cement pastes at rest. The paste mixtures were prepared with 0.40 and 0.275 water-to-cement mass ratio (W/C) and had a fixed mini-slump flow of 240 ± 5 …

L.G. Twidwell Fifty-Six Years Of Research A Summary, Larry G. Twidwell

Metallurgical & Materials Engineering

Larry G. Twidwell, D.Sc. is Emeritus Professor in the Department of Metallurgical and Materials Engineering at Montana Technological University. He has fifty-six years of experience in teaching and directing research in Metallurgical and Materials Engineering at Montana Tech. Twidwell and his graduate students and coworkers have conducted research emphasizing extractive metallurgy and the application of extractive metallurgical engineering to the treatment of metallurgical wastes, process waters and byproducts. Four books, seventy-seven M.Sc. theses, one-hundred-thirty refereed publications and one hundred-eight national and international presentations have resulted from their research efforts. Twidwell has received several outstanding teacher/researcher awards during his tenure at …

Computational Modeling Of Astrophysical Systems, Leleya Iris Stallard

Spring Showcase for Research and Creative Inquiry

This research project focuses on the computational modeling of astrophysical systems using Femap with NX Nastran. The goal was to simulate and analyze the vibrational behavior and structural deformation of celestial bodies under different material compositions and collision conditions. Materials such as iron, granite, titanium, and models for white dwarf stars were used to investigate how varying physical properties affect the systems' dynamic responses. Both isotropic and anisotropic models were created to represent realistic astrophysical materials. Through static and modal analyses, the study explored how internal structure and material stiffness influence the reaction of celestial objects to applied forces and …

Josephson Junctions: Fabrication And Applications For The Axion Dark Matter Experiment, Jonah M. Sachs

Senior Honors Papers / Undergraduate Theses

The observation of axions could revolutionize the world of physics. Through microwave frequency cavity readout of the photons associated with these axions, the ADMX project at WashU utilizes multiple different forms of the Josephson junction (JJ), a superconductive circuit element. The physics behind the JJ are essential to understanding its operation for resonant cavity readout in addition to parametric amplification. Parametric amplifiers produced using JJs can approach the signal-to-noise ratio set by quantum mechanics, and prove essential for the amplification chain used by the ADMX experiment for axionic detection. The limits of these amplifiers are set by the noise tuning …