Chemical Engineering Commons^™

Thin-Film Block Copolymers (Bcps) Self-Assembly As Versatile Patterning Scheme For Functional Nanomaterials, Le Zhang

LSU Master's Theses

Nanopattern generation is required for building various structural entities in every production process that involves nanostructures. Advancing nanopatterning technologies play an important role in developing and broadening the current nanopatterning technologies to meet up with the ever-demanding requirements in the realm of smaller feature sizes, smoother line-edge roughness (LER) and facile pattern transfer in pursuit of faster computer processors, better electrocatalysts and more compact and intelligent sensors, etc. Conventionally, patterning needs are heavily relied on photolithography, a technique that dominate chip-making industry for more than 50 years. However conventional photolithography is bounded by inherent resolution limits and difficult to be …

Highly Thiolated Poly (Beta-Amino Ester) Nanoparticles For Acute Redox Applications, Andrew L. Lakes, David A. Puleo, J. Zach Hilt, Thomas D. Dziubla

Chemical and Materials Engineering Faculty Publications

Disulfides are used extensively in reversible cross-linking because of the ease of reduction into click-reactive thiols. However, the free-radical scavenging properties upon reduction are often under-considered. The free thiols produced upon reduction of this disulfide material mimic the cellular reducing chemistry (glutathione) that serves as a buffer against acute oxidative stress. A nanoparticle formulation producing biologically relevant concentrations of thiols may not only provide ample chemical conjugation sites, but potentially be useful against severe acute oxidative stress exposure, such as in targeted radioprotection. In this work, we describe the synthesis and characterization of highly thiolated poly (β-amino ester) (PBAE) nanoparticles …

Au@H-Al2o3 Analogic Yolk–Shell Nanocatalyst For Highly Selective Synthesis Of Biomass-Derived D-Xylonic Acid Via Regulation Of Structure Effects, Jiliang Ma, Zewei Liu, Junlong Song, Linxin Zhong, Dequan Xiao, Hongxia Xi, Xuehui Li, Runcang Sun, Xinwen Peng

Chemistry and Chemical Engineering Faculty Publications

Selective oxidation of biomass-based monosaccharides into value-added sugar acids is highly desired, but limited success of producing D-xylonic acid has been achieved. Herein, we report an efficient catalyst system, viz., Au nanoparticles anchored on the inner walls of hollow Al₂O₃ nanospheres (Au@h- Al₂O₃), which could catalyze the selective oxidation of D-xylose into D-xylonic acid under base-free conditions. The mesoporous Al₂O₃ shell as the adsorbent first adsorbed D-xylose. Then, the interface of Au nanoparticles and Al₂O₃ as active sites spontaneously dissociated O₂, and …

Well-Failure Analysis Of The Devil’S Basin In Musselshell County, Mt., Alexander Koerner

Graduate Theses & Non-Theses

Central Montana’s Devil’s Basin is the home of the first wildcat well in Montana. However, numerous operators have failed to recover economic oil reserves in the nearly 100- year history of the play. Analysis of the geologic conditions within the Devil’s Basin leads to a modern understanding of the charge, reservoir, and trap potentials of the greater Devil’s Basin petroleum play. Primary focus within the play is the Heath and Tyler Formations. Evaluation of previous exploration guides the end narrative of recommendations to direct future production in the Devil’s Basin.

A representative geologic model describing the southeastern portion of the …

Molecular Dynamics Studies On Nanoscale Confined Liquids, Alper Celebi

Mechanical Engineering Research Theses and Dissertations

Liquid transport in nanochannels have been attracting great interests, especially for last two decades, owing to its potential applicability in various fields including biochemistry, medical science and engineering. For exploring and generating new ideas in the field of nanofluidics, molecular simulation techniques have become an ideal way due to the experimental challenges impeding the field of nanofluidics in fabrication and measurements.

In this dissertation, we perform molecular dynamics simulations to investigate liquid transport behavior in nanoscale channels. The expanse of this dissertation concerns several fundamental topics in nanoscale liquid transport phenomena such as liquid properties in nanoscale confinements, interfacial flows …

Three-Way Catalysts In Passive Selective Catalytic Reduction Systems, Calvin Thomas

Theses and Dissertations

Conventional gasoline-powered engines operate with a stoichiometric air-fuel ratio (AFR), but greater fuel economy is achieved in lean burn engines by increasing the AFR. The primary drawback to these engines is the nitrogen oxide (NOX) emissions, which cannot be reduced over a conventional three-way catalyst (TWC). Passive selective catalytic reduction (SCR) is a promising approach for the control of NOX emissions in lean burn systems. By periodically decreasing the AFR to fuel-rich levels, ammonia (NH3) can be produced over a TWC and stored on a downstream SCR catalyst for the reduction of NOX during normal lean operation. While passive SCR …

Local Deformation And Texture Of Cold-Rolled Aa6061 Aluminum Alloy, Diaoyu Zhou, Wenwen Du, Xiyu Wen, Junwei Qiao, Wei Liang, Fuqian Yang

Chemical and Materials Engineering Faculty Publications

Using cold rolling, we plastically deform AA6061 sheets at room temperature and investigate the variations of the microstructures, textures and local deformation of the cold-rolled AA6061 sheets as functions of thickness reduction (Δt/t₀, t₀ and t are the thicknesses of the AA6061 sheet before and after the cold rolling, respectively). The volume fraction of total deformation texture is relatively independent of the thickness reduction for Δt/t₀ ≤ 30%, and becomes an approximately linearly increasing function of the thickness reduction for Δt/t₀ > 30%. Increasing the thickness reduction causes the increase of the Vickers hardness of the …

The Aromatization Of Propene Via Nano-Size Hzsm-5, Wayne Seames, Swapnil Fegade, Inna Sakodynskaya, Darrin Muggli, Brian Tande, Alena Kubatova, Evguenii Kozliak

Chemistry Faculty Publications

Zeolite (ZSM) catalysts are known to convert small-size alkenes, e.g., propene, into aromatic hydrocarbons, specifically benzene, toluene and xylenes (BTX), with both high efficiency and specificity. The efficiency of conventional and hierarchical nano-size ZSM-5 for propene aromatization was compared in this study using a Design of Experiments (DOE) approach combined with detailed product analysis. Contrary to our expectations, the former showed a significantly greater BTX yield than the latter. Analysis of the obtained data by DOE and additional experiments with soybean oil cracking using both catalyst types indicated that a reason for the observed reduced activity of nano-scale zeolites may …

Interface Model Of Pem Fuel Cell Membrane Steady-Dtate Behavior, Russell L. Edwards, Ayodeji Demuren

Mechanical & Aerospace Engineering Faculty Publications

Modeling works which simulate the proton-exchange membrane fuel cell with the computational fluid dynamics approach involve the simultaneous solution of multiple, interconnected physics equations for fluid flows, heat transport, electrochemical reactions, and both protonic and electronic conduction. Modeling efforts vary by how they treat the physics within and adjacent to the membrane-electrode assembly (MEA). Certain approaches treat the MEA not as part of the computational domain, but rather an interface connecting the anode and cathode computational domains. These approaches may lack the ability to consistently model catalyst layer losses and MEA ohmic resistance. This work presents an upgraded interface formulation …

Development Of A Simple Lab-Scale Vacuum Assisted Resin Transfer Molding (Vartm) Process, Donald A. Klosterman

Chemical and Materials Engineering Faculty Publications

The goal of the current study was to develop and demonstrate a simple and quick lab-scale VARTM process for the purpose of making flat panels for subsequent characterization, for example in new materials development efforts. This process was not intended to be optimized for final production, rather it served as the quickest way to make lab-scale composite panels using VARTM while maintaining all the salient features of typical VARTM processes used in larger scale manufacturing. There is a wide variety of ways to implement VARTM, as well as a diverse list of potential materials and supplies from which to choose. …

Thermochemical Conversion Of Biomass: Detailed Gasification And Near-Burner Co-Firing Measurements, Jacob B. Beutler

Theses and Dissertations

An increasing emphasis on mitigating global climate change (global warming) over the last few decades has created interest in a broad range of sustainable or alternative energy systems to replace fossil fuel combustion. Biomass, when harvested responsibly, is a renewable fuel with many uses in replacing fossil fuels. Cofiring biomass with coal in traditional large-scale coal power plants represents one of the lowest risk, least costly, near-term methods of CO₂ mitigation. Simultaneously, it is one of the most efficient and inexpensive uses of biomass. Alternatively, biomass can be transformed into useful products through gasification to produce clean syngas for …

Ultra-Thin Coating And Three-Dimensional Electrode Structures To Boosted Thick Electrode Lithium-Ion Battery Performance, Jie Li, Yan Gao, Xinhua Liang, Jonghyun Park

Chemical and Biochemical Engineering Faculty Research & Creative Works

This paper reports a multiscale controlled three‐dimensional (3D) electrode structure to boost the battery performance for thick electrode batteries with LiMn_1.5Ni_0.5O₄ as cathode material, which exhibits a high areal capacity (3.5 mAh/cm²) along with a high specific capacity (130 mAh/g). This excellent battery performance is achieved by a new concept of cell electrode fabrication, which simultaneously controls the electrode structure in a multiscale manner to address the key challenges of the material. Particles with ultrathin conformal coating layers are prepared through atomic layer deposition followed by a nanoscale‐controlled, thermal diffusion doping. The particles …

Electrochemical Hydrogenation Of Acetone To Produce Isopropanol Using A Polymer Electrolyte Membrane Reactor, Chen Li, Ashanti M. Sallee, Xiaoyu Zhang, Sandeep Kumar

Civil & Environmental Engineering Faculty Publications

Electrochemical hydrogenation (ECH) of acetone is a relatively new method to produce isopropanol. It provides an alternative way of upgrading bio-fuels with less energy consumption and chemical waste as compared to conventional methods. In this paper, Polymer Electrolyte Membrane Fuel Cell (PEMFC) hardware was used as an electrochemical reactor to hydrogenate acetone to produce isopropanol and diisopropyl ether as a byproduct. High current efficiency (59.7%) and selectivity (>90%) were achieved, while ECH was carried out in mild conditions (65 degrees C and atmospheric pressure). Various operating parameters were evaluated to determine their effects on the yield of acetone and …

Characterization And Evaluation Of Cordless Nailer Performance For Liquid And Gaseous Fuels, Mark Carioscio

Master's Theses (2009 -)

The Paslode Cordless XP Framing Nailer is a combustion-powered nail gun that operates using a fuel blend of a propylene and 1-butene. This tool is designed to drive nails using a piston driven by a combustion reaction. The current fuel blend is able to fire approximately 1200 shots per fuel cartridge and match the energy output of pneumatic, corded nailers on the market. This thesis is written with the intent to gain a better understanding of the operation of the tool and how its performance varies when the fuel source is altered. A bizonal combustion model was created to simulate …

Nanoflower-Like Bi2moo6/Ag3po4 In Water Treatment, Xavier Morgan-Lange, Jaeyun Moon, Kaleab Ayalew

McNair Poster Presentations

• Environmental issues continue to intensify causing natural resources such as clean water to become increasingly scarce while demand only continues to grow. • Some of the most effective measures taken appear to be bioremediation tactics and their synthetic counterparts. • A critical area of interest are semi-conducting photocatalytic nanomaterials that take advantage of the photo-electric effect and use the introduction of ultra violet (UV) and visible light to induce oxidation and reduction reaction in p-type semiconductors. This results in the decomposition of certain pollutants and/or deactivates certain microbes in water. • These materials have the potential to operate using …

The Flow Reactor Technology As A Modern Synthetic Tool For Preparation Of Pd/Fe3o4 Nanoparticles As A High Efficient Magnetic Catalyst For Co Oxidation, Hany A. Elazab

Chemical Engineering

No abstract provided.

Cysteine As An Eco-Friendly Corrosion Inhibitor, Hany A. Elazab Dr

Chemical Engineering

In this paper, the aim was finding the most efficient corrosion inhibitor for mild steel placed in a 0.5M Sulfuric acid. The comparison was implemented between Cysteine (an eco-friendly corrosion inhibitor) and 4 different Ions-Cysteine Inhibitors (Copper- Cysteine, Nickel-Cysteine, Iron-Cysteine, and Cobalt-Cysteine). The solutions were prepared and evaluated while placed with a working electrode of mild steel with a copper rod attached to its end. To determine the best eco-friendly corrosion inhibitors two experiments were implemented: Electrochemical Impedance Spectra, and Linear Polarization. By the end of the experiment it was found that Copper- Cysteine was the most efficient eco-friendly corrosion …

A Nonlinear Systems Framework For Cyberattack Prevention For Chemical Process Control Systems, Helen Durand

Chemical Engineering and Materials Science Faculty Research Publications

Recent cyberattacks against industrial control systems highlight the criticality of preventing future attacks from disrupting plants economically or, more critically, from impacting plant safety. This work develops a nonlinear systems framework for understanding cyberattack-resilience of process and control designs and indicates through an analysis of three control designs how control laws can be inspected for this property. A chemical process example illustrates that control approaches intended for cyberattack prevention which seem intuitive are not cyberattack-resilient unless they meet the requirements of a nonlinear systems description of this property.

Suitability Of Active And Intelligent Packaging For Local And Organic Food – A Case Study In Southern Finland, Sara Paunonen, Marja Pitkänen, Mika Vähä-Nissi, Ville Leminen, Mika Kainusalmi

Journal of Applied Packaging Research

This study explores the suitability of innovative packaging for local and organic food. Attitudes and opinions in local and organic food chains in Southern Finland were collected via eighteen semi-structural interviews. The respondents were small-scale producers and processors of fish, meat, berries, and mushrooms, wholesalers, retailers, and institutional kitchens. The aim of this study was to understand factors promoting and preventing the penetration of innovative packaging solutions into the organic and local food market. A clear majority (89%) of respondents considered active and intelligent solutions to be equally suitable for local and organic food as for conventional food. However, less …

Measuring Up: Engineering Stronger And Faster Cardiomyocytes, Kaitlyn Mcentire, Dr. Alonzo Cook

Journal of Undergraduate Research

If a heartbeat connotes life, then cardiomyocytes are the life givers. When heart disease results in cardiomyocyte death, however, these life-giving, beating cells are unable to reproduce, and portions of the heart irreversibly die. Despite modern technology and developments in heart disease treatment and prevention, heart disease remains the number one cause of death in America. With an inability to meet an ever-increasing demand for heart transplants, any potential alternative must be pursued.

Differentiation Of Kidney Progenitors Using Induced Pluripotent Stem Cells And Conditioned Media Of Renal Cortical Tubular Epithelial Cells, Steven Passey, Dr. Alonzo Cook

Journal of Undergraduate Research

According to the National Kidney Foundation, 26 million American adults have kidney disease, 47,000 Americans died from kidney disease in 2013, and over 100,000 people await kidney transplants. Current treatment of kidney failure includes dialysis and kidney transplant. Unfortunately, those undergoing dialysis may experience fatigue and other complications. In addition, there is a vast shortage of available kidneys for transplant.

Equilibration Of Chloride Ions In Concrete Bridge Decks After Rehabilitation Using Hydro-Demolition And Concrete Overlay, Elizabeth Newbill, Dr. Spencer Guthrie

Journal of Undergraduate Research

In cold regions like northern Utah, harsh winters can lead to decreases in the service life of concrete bridge decks. Chloride-based deicing salts, which are commonly used to remove snow and ice from the surface of concrete bridge decks during winter months, are of particular concern. Even in uncracked concrete, chloride ions can diffuse into the bridge deck and eventually lead to corrosion of the embedded reinforcing steel. When chlorides corrode the steel, expansive rust forms, which causes cracks to form in the deck. These cracks allow for greater chloride ingress, accelerating the corrosion and deterioration processes within the bridge …

Hips Turbulent Flow Modeling For High Schmidt Number Flow A Novel Approach To An Old Problem, Joshua Frei, Dr. David Lignell

Journal of Undergraduate Research

The whorls and vortices of smoke plumes, churning waterfalls, and crashing waves have a captivating sense of mystery about them. This chaotic, seemingly random fluid motion is known as turbulent flow, and it is ubiquitous both in day-to-day life and in engineering problems. Despite the many advances in technology, much of turbulence remains a mystery. It has been called the most important unsolved problem in physics [1].

Hierarchal Parcel Swapping (Hips) A Comprehensive Multiscale Subgrid Model For Turbulent Reacting Flow, Justin Ward, Dr. David Lignell

Journal of Undergraduate Research

The purpose of this project is to address the unmet need for a comprehensive, multiscale, regime- and fuel-independent turbulent reacting model by using a novel, physics-based strategy called Hierarchal Parcel Swapping (HiPS). Turbulent flow has been called the most important unsolved problem of classical physics. Modeling turbulent flow is extremely important due to the fact that nearly all flows in the real world are turbulent. Though the exact details of turbulent flow are not of great importance to an engineer, the effect turbulence has on chemical reactions and the overall chemical properties is vital. The solution to the turbulence problem …

Hand-Powered Washing Machine For The Developing World, Chris Bailey, Sean Larson, Megan Peffer, Sarah Ann Skousen, Judith Westwood, Dr. Randy Lewis

Journal of Undergraduate Research

Many countries still hand wash all their clothing. The community of the Uros Islands in Peru is no exception. Our goal was to develop a hand powered washing machine that will be useful to and improve the quality of life of the Uru people. The washing machine must be built out of materials that are inexpensive and readily available to the community. It must also be simple enough for the people to perform any necessary repairs. Furthermore, the final washing machine system could be implemented any developing area with similar needs.

Engineering Metal-Ligand Interface For Selective Electrochemical Carbon Dioxide Reduction, Yuxin Fang

LSU Doctoral Dissertations

Unsustainable exploitation of fossil fuel and its massive greenhouse gas emission necessitates the development in alternative energy sources. Chemical fuels (CH₃OH or C₂H₅OH) outperform other choices, such as batteries for their high energy densities, which is key to portability. Electrochemical reduction of CO₂is capable of producing a wide range of valuable fuels (Syngas, formic acid, methane and methanol, etc.). Converting CO₂into carbon-based fuels further closes the carbon neutral cycle, which contributes to the effort in reducing global CO₂emission. Integration of organic ligands with transition metals shows great potential …

Rapid Biosensor Screening Blood And Urine, Rebecca Whitney Bills, Dr. Bradley Bundy

Journal of Undergraduate Research

Endocrine Disrupting Chemicals (EDCs) have led to worldwide health problems, including cancers, developmental disorders, and reproductive disorders. A recent study estimates that annual health and economic costs caused by EDCs in the European Union is $200 Billion and that the costs are even greater in the US (1). This is largely due to the extensive number of undetected Endocrine Disrupting Chemicals (EDCs) that we come into contact with on a daily basis. EDCs have been found in dietary, environmental, and household chemicals. Despite this only a handful of EDCs have been characterized. The purpose of this project is to optimize …

Investigating The Agricultural Applications Of Acryl Amide Based Hydrogel, Hany A. Elazab Dr

Chemical Engineering

Hydrogel is classified as one of the most effective materials due to its widely used applications either in tissue or agriculture engineering. This scientific research aims to investigate the potential applications of hydrogels in the field of desert agriculture in dry places. In this research hydrogel was prepared under several conditions in order to evaluate and optimize the conditions. The research included optimiz-ing several factors including cross-linking agent, water temperatures and pH. The potential agricultural applications of hydrogel were also investigated.

Self-Cleaning Nanocomposite Membranes With Phosphorene-Based Pore Fillers For Water Treatment, Joyner Eke, Katherine Elder, Isabel Escobar

Chemical and Materials Engineering Faculty Publications

Phosphorene is a two-dimensional material exfoliated from bulk phosphorus and it possesses a band gap. Specifically, relevant to the field of membrane science, the band gap of phosphorene provides it with potential photocatalytic properties, which could be explored in making reactive membranes that can self-clean. The goal of this study was to develop an innovative and robust membrane that is able to control and reverse fouling with minimal changes in membrane performance. To this end, for the first time, membranes have been embedded with phosphorene. Membrane modification was verified by the presence of phosphorus on membranes, along with changes in …

Creation Of Non-Electric Cooling System For Food Preservation In Peru, Eleanor Ott, Dr. Randy Lewis

Journal of Undergraduate Research

Food preservation is an issue in third-world countries around the world where electricity and monetary means are not present to maintain a modern refrigerator. The short shelf life of unrefrigerated food items creates waste, requires time and energy with frequent trips to buy food, and lowers quality of life. Multiple solutions for this problem have been devised which are principally applicable in Asia and Africa. Implementation of these solutions has increased shelf-life of perishable foods and eliminated the need for daily trips to the market for food. A natural consequence has been increased profits, more educational opportunities for women, and …