Chemical Engineering Commons^™

Electrochemical Characterization Of Bromine Reduction To Tribromide In Individual Nitrobenzene-In-Water Emulsion Droplets, Liang Chang, Allen J. Bard

Faculty Scholarship

We report an electrochemical study of bromine reduction to tribromide in a single nitrobenzene (NB) droplet during a single collision event. The feasibility of this study is based on the favorable distribution of Br2 in NB rather than in water, which was demonstrated by voltammetry at the NB/water interface. The NB-in-water emulsions containing the ionic liquids trihexyltetradecylphosphonium bis(trifluoromethylsulfonyl)amide (ILPA) as the supporting electrolyte and sodium dodecyl sulfate (SDS) as the surfactant were prepared by a high-power ultrasonication. Its single droplet as an attoliter reactor, colliding on a 25 μm Pt UME, was monitored by chronoamperometry. The spike-type current transients of …

Transition Metal-Doped Rare-Earth Oxysulfide Catalysts For High Temperature Dry Reforming Of Methane, Changyi Jiang

LSU Doctoral Dissertations

Carbon dioxide reforming of methane is a catalytic reaction utilizing two kinds of greenhouse gases and converting them into a useful industrial gas stream, “syngas”. However, sulfur poisoning and coke formation are two major challenges for this reaction. In this study, we have synthesized and examined several Ce-La and Ce-Zr oxides, with different transition metal additives. A rapid screening technique was developed to measure reforming and coking rates at low partial pressures. It is a good indicator of catalyst behavior at higher conversions and partial pressures. Following the rapid screening, select catalysts were examined at longer times on stream. Those …

Peptide-Modified Chondroitin Sulfate Reduces Coefficient Of Friction At Articular Cartilage Surface, Celina Twitchell, Tanaya Walimbe, Julie C. Liu, Alyssa Panitch

School of Chemical Engineering Faculty Publications

Osteoarthritis is a debilitating disease that results in pain and joint stiffness. Currently, steroidal and nonsteroidal anti-inflammatory drugs and supplements aimed at restoring lubrication to the affected joint are the most successful with respect to improving patient comfort. Due to the success in lubricating therapies, there exists a keen interest to develop better therapies that mimic how lubrication occurs naturally in the joint. Here we describe the results obtained using a chondroitin sulfate chain to which is conjugated peptides that bind to either hyaluronic acid (found in high concentrations in the synovial fluid) or collagen type II (present on the …

Investigation Of Tracer-Surfactant-Foam Processes In Shallow Subsurface Environmental Remediation: History-Matching And Performance Prediction, Hazem Fleifel

LSU Master's Theses

In-situ subsurface remediation has been widely used as an efficient means of cleaning up non-aqueous phase liquid (NAPL) from contaminated soils and aquifer. The use of tracer, surfactant, and foam are often considered to keep track of the propagation of injected fluids in the medium, dissolve and mobilize contaminants trapped by capillary forces, and overcome the level of heterogeneity and improve displacement and sweep efficiencies.

This study shows an actual remediation process to reduce NAPL within a military base in South Korea, by injecting tracer and surfactant solutions together for a duration of 10 days. The site consists of 5 …

Dissolved Organic Matter-Capped Silver Nanoparticles For Electrochemical Aggregation Sensing Of Atrazine In Aqueous Systems, Ziad Khalifa, Moustafa Zahran Dr, Magdy Zahran Prof, Magdi Abdel Azzem Prof

Chemical Engineering

An electrochemical sensor based on silver nanoparticles (AgNPs) was developed by immobilizing dissolved organic matter (DOM) to interact with AgNPs on a glassy carbon electrode (GC), forming a DOM/AgNP/GC composite. AgNPs have been fabricated and characterized using ultraviolet−visible spectroscopy, fluorescence spectroscopy, and transmission electron microscopy. The immobilization efficiency and stability of the DOM/AgNP/GC composite have been optimized through studying the effects of electrode material type, immobilization technique, sticking duration, supporting electrolyte, and pH using square wave anodic stripping voltammetry. The detection of atrazine (Atz), a common herbicide, in aqueous systems has a great significance because of its toxicity to humans …

Microfluidic Study Of The Electrocoalescence Of Aqueous Droplets In Crude Oil, Thomas Leary, Mohsen Yeganeh, Charles Maldarelli

Publications and Research

In electrocoalescence, an electric field is applied to a dispersion of conducting water droplets in a poorly conducting oil to force the droplets to merge in the direction of the field. Electrocoalescence is used in petroleum refining to separate water from crude oil and in droplet-based microfluidics to combine droplets of water in oil and to break emulsions. Using a microfluidic design to generate a two-dimensional (2D) emulsion, we demonstrate that electrocoalescence in an opaque crude oil can be visualized with optical microscopy and studied on an individual droplet basis in a chamber whose height is small enough to make …

Fabrication Of Perovskite Solar Cells At Uah, Natalie Mann

Research Horizons Day Posters

No abstract provided.

Enhancing Chemical Sensing With Seira And Silicon Carbide Gratings, Autumn Bruncz, Thomas Folland, Joshua Caldwell, Marko Tadjer

Research Horizons Day Posters

No abstract provided.

Dlvo Interactions Of Janus Ellipsoids With A Planar Surface, Kailian Davis

Research Horizons Day Posters

No abstract provided.

Hybrid Monomers & Resins For High-Performance Thermosetting Polymers, Thermoplastics, & Additive Manufacturing, Alexander William Bassett

Theses and Dissertations

Vinyl ester and epoxy resins are used to produce thermosetting polymeric materials for a variety of commercial and military applications due to their relatively high moduli (2-3 GPa at 25 deg C), glass transition temperatures (Tgs) (greater than or equal to 120 deg C), and adequate fracture toughness (G1C approx. 200-250 J m-2). Most commercially available vinyl ester and epoxy resins are typically cured via traditional manufacturing techniques such as resin transfer molding and thermal curing. However, additive manufacturing (AM) has gained significant traction as a favorable manufacturing technique over traditional methods due to the ability to create customizable parts …

Co2 Mass Transfer Enhancement Of Aqueous Amine Solvents By Particle Additives, Leland R. Widger, Guojie Qi, Kun Liu, Jonathan Bryant, Cameron A. Lippert, Kunlei Liu

Center for Applied Energy Research Faculty Patents

The present invention relates to methods for improving carbon capture by providing particles within an amine solvent. The particles provide for increased turbulence at the interface between the counter-flowing gas and solvent, which allows for increased amine and carbamate salt diffusion between the liquid film and bulk.

The Use Of Succinonitrile As An Electrolyte Additive For Composite-Fiber Membranes In Lithium-Ion Batteries, Jahaziel Villarreal, Roberto Orrostieta Chavez, Sujay A. Chopade, Timothy P. Lodge, Mataz Alcoutlabi

Mechanical Engineering Faculty Publications

In the present work, the effect of temperature and additives on the ionic conductivity of mixed organic/ionic liquid electrolytes (MOILEs) was investigated by conducting galvanostatic charge/discharge and ionic conductivity experiments. The mixed electrolyte is based on the ionic liquid (IL) (EMI/TFSI/LiTFSI) and organic solvents EC/DMC (1:1 v/v). The effect of electrolyte type on the electrochemical performance of a LiCoO₂ cathode and a SnO₂/C composite anode in lithium anode (or cathode) half-cells was also investigated. The results demonstrated that the addition of 5 wt.% succinonitrile (SN) resulted in enhanced ionic conductivity of a 60% EMI-TFSI 40% EC/DMC MOILE …

Three-Phase Hydrodynamic Simulation And Experimental Validation Of An Upflow Anaerobic Sludge Blanket Reactor, Camila D' Bastiani, Jéferson Luis Alba, Gabriel Tomazzoni Mazzarotto, Severino Rodrigues De Farias Neto, Anthony Reynolds, David Kennedy, Lademir Luiz Beal

Articles

This research focuses on performing multiphase solid/liquid/gas CFD simulations of a UASB reactor in order to obtain a validated model that provides a clearer understanding of the hydrodynamic behaviour of the three phases in UASB reactors. Eulerian–Eulerian, laminar, three-dimensional, multiphase simulations are carried out using Fluent 16.2. The liquid phase velocity and flow profile are validated through PIV experiments. A liquid mean velocity difference of 8.45% is found between the experimental and numerical results, thus validating the CFD model. Shadowgraphy is applied successfully to validate the biogas phase velocity and bubble size. Based on the hydrodynamic analysis results, the reactor …

Coating Topologically Complex Electrospun Fibers With Nanothin Silk Fibroin Enhances Neurite Outgrowth In Vitro, Alexis M. Ziemba, Tanner D. Fink, Mary Clare Crochiere, Devan L. Puhl, Samichya Sapkota, Ryan J. Gilbert, R. Helen Zha

Chemical and Biochemical Engineering Faculty Research & Creative Works

Electro spun poly-l-lactic acid (PLLA) fibers are commonly used for tissue engineering applications because of their uniform morphology, and their efficacy can be further enhanced via surface modification. In this study, we aimed to increase neurite outgrowth along electro spun fibers by coating with silk fibroin (SF), a bioinert protein derived from Bombyx mori cocoon threads, shown to be neuro compatible. Aligned PLLA fibers were electro spun with smooth, pitted, and devoted surface nano topographies and coated with SF by immersion in coating solution for either 12 or 24 h. Specifically, thin-film coatings of SF were generated by leveraging the …

Re-Crosslinking Particle Gel For Co₂ Conformance Control And Co₂ Leakage Blocking, Yifu Long, Baojun Bai, Thomas P. Schuman

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The present invention generally relates to the composition of particle gels for CO₂-EOR and CO₂ storage. More particularly, CO₂ resistant particle gels are provided that can re-crosslink at subterranean conditions. These particle gels can be deployed to improve the conformance of CO₂ flooding, CO₂ huff-puff, or Water-Alternative-Gas (WAG). The applications may also involve CO₂ storage, such as the blocking of CO₂ leakage and similar CO₂ processing.

Integrity Testing Of Gas Permeable Silicone Filters, Maggie M. Baker, Thomas P. Humann, Kevin J. Yerina

Biomedical Engineering

This report investigates the most reasonable, cost efficient, and reliable ways to integrity test a filter made from a permeable silicone membrane for future biomedical and pharmaceutical applications. The goal of the project was to create a fixture that a pharmaceutical company can use to quickly and reliably test the integrity of the filter. A variety of methods are outlined to test the integrity of the filter, after a series of quantitative tests, a single method was established that meet the requirements most thoroughly. The method that was determined to be most effective involves a series of components including a …

Critical Review Of Asphaltene Properties And Factors Impacting Its Stability In Crude Oil, Sherif Fakher, Mohamed Ahdaya, Mukhtar Elturki, Abdulmohsin Imqam

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Asphaltene is a component of crude oil that has been reported to cause severe problems during production and transportation of the oil from the reservoir. It is a solid component of the oil that has different structures and molecular makeup which makes it one of the most complex components of the oil. This research provides a detailed review of asphaltene properties, characteristics, and previous studies to construct a guideline to asphaltene and its impact on oil recovery. The research begins with an explanation of the main components of crude oil and their relation to asphaltene. The method by which asphaltene …

Insights Into The Applications Of Waste Materials In The Oil And Gas Industry: State Of The Art Review, Availability, Cost Analysis, And Classification, Abo Taleb T. Al-Hameedi, Husam H. Alkinani, Hussein W. Albazzaz, Shari Dunn-Norman, Mohammed M. Alkhamis

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

This study investigates different types of waste materials and their applicability in the oil and gas industry as well as analyzing various applications of these waste materials in the petroleum industry. This study also explores the availability of these waste materials by performing a statistical analysis in a good number of countries worldwide. The statistical study was performed starting with a study on which countries generate waste the most overall, followed by examining multiple countries and investigating their top three most available waste. The results showed that the USA is the leading country in terms of municipal solid waste generation …

A Data Analysis Of Immiscible Carbon Dioxide Injection Applications For Enhanced Oil Recovery Based On An Updated Database, Sherif Fakher, Abdulmohsin Imqam

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Carbon dioxide (CO₂) injection is an enhanced oil recovery technique used worldwide to increase oil recovery from hydrocarbon reservoirs. Immiscible CO₂ injection involves injecting the CO₂ into the reservoir at a pressure below which it will become miscible in the oil. Even though immiscible CO₂ injection has been applied extensively, very little research has been conducted to provide a comprehensive understanding of the mechanism and the applications of immiscible CO₂ injection. This research performs an in-depth data analysis is performed based on more than 200 experiments and 20 field tests from more than 40 …

Evaluation Of Diode Laser Application On Chemical Analysis And Surface Microhardness Of White Spots Enamel Lesions With Two Remineralizing Agents, Lamiaa Mahmoud Moharam, Doaa Mohamed Sadony, Shaymaa Mohamed Nagi

Chemical and Biochemical Engineering Faculty Research & Creative Works

Background: To investigate the effect of diode laser application and two commercial remineralizing agents on the remineralization and surface microhardness of white spot enamel lesions. Material and Methods: Sixty specimens were prepared then equally divided into six groups (n=10/group), according to the diode laser and the two commercial remineralizing agents applied to demineralized enamel surfaces (APF gel and sodium fluoride NaF mousse) with or without diode Laser application as follows; Group A; control, Group B; diode Laser application, Group C; APF gel application, Group D; NaF mousse application, Group E; APF gel application + diode Laser, Group F; NaF mousse …

Mixed Culture Polyhydroxyalkanaotes (Pha) Production Using Crude Glycerol As Carbon Source, Mohamad Fauzi Ainil Hawa

Student Works (2020-2029)

Polyhydroxyalkanoates (PHA) is a biopolymer that has the prospect of becoming a preferred renewable and environmentally friendly resource with various applications including in manufacturing and medicine. Intensive studies have been carried out to find the most practical and economical method for PHA production because current commercial production of PHA is stringent and extremely costly. The aim of this study is to enrich PHA-accumulators with high PHA production capabilities by evaluating the stability of the enrichment process and by observing the effect of organic loading rate (OLR) on the production potential. In this study, PHA-accumulators were cultivated using activated sludge with …

Rapid Self-Assembly Of Polymer Nanoparticles For Synergistic Codelivery Of Paclitaxel And Lapatinib Via Flash Nanoprecipitation, Shani L. Levit, Hu Yang, Christina Tang

Chemical and Biochemical Engineering Faculty Research & Creative Works

Taxol, a formulation of paclitaxel (PTX), is one of the most widely used anticancer drugs, particularly for treating recurring ovarian carcinomas following surgery. Clinically, PTX is used in combination with other drugs such as lapatinib (LAP) to increase treatment efficacy. Delivering drug combinations with nanoparticles has the potential to improve chemotherapy outcomes. In this study, we use Flash NanoPrecipitation, a rapid, scalable process to encapsulate weakly hydrophobic drugs (logP < 6) PTX and LAP into polymer nanoparticles with a coordination complex of tannic acid and iron formed during the mixing process. We determine the formulation parameters required to achieve uniform nanoparticles and evaluate the drug release in vitro. The size of the resulting nanoparticles was stable at pH 7.4, facilitating sustained drug release via first-order Fickian diffusion. Encapsulating either PTX or LAP into nanoparticles increases drug potency (as indicated by the decrease in IC-50 concentration); we observe a 1500-fold increase in PTX potency and a six-fold increase in LAP potency. When PTX and LAP are co-loaded in the same nanoparticle, they have a synergistic effect that is greater than treating with two single-drug-loaded nanoparticles as the combination index is 0.23 compared to 0.40, respectively.

Recent Progress In The Mechanistic Understanding Of Co2 Reduction On Copper, Matthew M Sartin, Wei Chen, Fan He, Yan-Xia Chen

Journal of Electrochemistry

In this review, we present the major developments in the understanding of the mechanisms of the electrochemical reduction of CO₂ from a historical perspective. Most of the work discussed in this review was carried out at copper electrodes, as this is the only material at which hydrocarbons are produced in reasonable quantities. The emphasis focuses on the differentiation of mechanisms for the generation of C1 and C2 products as well as factors and methods for controlling the product selectivity of CO₂ reduction. We have highlighted ambiguities, assumptions, and important methodologies, such as differential electrochemical mass spectrometry and electrochemical …

Neuro-Fuzzy Modeling For Predictive Control Systems With Complex Technological Processes And Production, Yusupbekov Nodirbek, Shukhrat Gulyamov, Malika Doshchanova

Chemical Technology, Control and Management

The paper implements a modification of a fuzzy neural network, which is suitable for predictive control purposes. Adaptation of a multidimensional programmable controller based on a neural algorithm for the back propagation of forecasting errors is proposed, as well as neural parametric identification of a fuzzy mathematical model of complex technological processes and production based on experimental data and expert estimates.

Preparations Of Nickel-Iron Hydroxide/Sulfide And Their Electrocatalytic Performances For Overall Water Splitting, Hang-Shuo Lu, Xiao-Bo He, Feng-Xiang Yin, Guo-Ru Li

Journal of Electrochemistry

The Ni-Fe/Ti oxygen evolution electrode was prepared by electrodeposition on a titanium mesh substrate. Then, the as prepared Ni-Fe/Ti electrode was used to derive the Ni-Fe-S/Ti hydrogen evolution electrode through solid phase sulfuration. The effects of the molar ratio of Ni²⁺ to Fe³⁺ in the electrolyte and the amount of thiourea on the structures and electrochemical performances of Ni-Fe/Ti and Ni-Fe-S/Ti electrodes were investigated. The results show that the oxygen evolution performance of Ni-Fe/Ti electrode was first increased and then decreased with the increase of nickel ion content in the electrolyte. The Ni9Fe1/Ti electrode exhibited the best oxygen …

Precise Measuring Cells For Quantitative And Qualitative Measurement, A.A. Begunov, B.M. Akhmedov, R.A. Ibragimov

Chemical Technology, Control and Management

The main provisions considered in assessing the accuracy of methods and measurement results are considered. It is shown that in the experimental assessment of various accuracy indicators, and also when analyzing the content of components in various gaseous media, the sorption-gravimetric measurement method is widely used, methods for measuring the mass of the sorbent and possible sources of error of this technique. Methods of measuring the mass of gas using specific surface areas, including taking into account the contact of gas with a solid material, and also, the amount of adsorbed gas and its pressure, temperature, type and size of …

Features Of Hydration Process, Structure Formation And Curing Processes Of Mono And Polymineral Cement In The Presence Of Additives Of Solid Waste Of Soda Production, Nargis Shamadinova, Gulnora Abdukadirovna Tokhtakhunova Phd, Temur Azimovich Atakuziev, Shakhnoza Saidanvarovna Rakhimjanova

Chemical Technology, Control and Management

The influence of the additive of solid waste of soda production (SWSP) on the content of -C₂S and C₃S in cement studied. It was found that SWSP affects the density of the aluminum-containing minerals C₃A and C₄AF, in addition, in the presence of gypsum, their plasticizing properties improved. The introduction of SWSP additives during grinding of clinker intensifies the grinding process and made it possible to obtain a more plastic cement. It was proved that SWSP with CaCl₂ content can be used as an additive to concrete and cement mortars - …

Controlling And Forecasting The Reliability Of Integrated Circuits Of Radio Systems Transmitting Information, Abdulaziz M. Nazarov Prof, Dilmurod A. Davronbekov Prof.

Chemical Technology, Control and Management

The issues of forecasting the reliability of integrated circuits, which are the main element base of modern radio engineering information transmission systems, are considered. Methods of parametric and functional control are described to determine the correspondence of the static and dynamic parameters of microcircuits to the required values. A combined method for determining the operating parameters of microcircuits is also described. The advantage of this method in addition to the two above methods is indicated that it combines the function of controlling the operation of the entire control system. Two approaches for predicting reliability are given, as well as mathematical …

Investigating The Solution Properties Of Population Model Of Cross-Diffusion Model With Double Nonlinearity And With Variable Density, Dildora Kabilovna Muhamediyeva

Chemical Technology, Control and Management

The models of two competing populations with double nonlinear diffusion and three types of functional dependencies are considered. The first dependence corresponds to the Malthusian type, the second to the Verhühlst type (logistic population), and the third to Olli-type populations. A common element of this kind of description is the presence of a linear source. Nonlinear sinks are also present in descriptions of populations of the Verhulst and Ollie type. Suitable initial approximations for a rapidly converging iterative process are proposed. Based on a self-similar analysis and comparison of the solutions of the Cauchy problem in the domain for an …

Steady Algorithms For Synthesis Of Multidimensional Controlling Systems With Incomplete Information About The Object State, Uktam Farkhodovich Mamirov

Chemical Technology, Control and Management

In this paper, questions of forming and creation of steady synthesis algorithms of multidimensional controlling systems at incomplete information on object status are considered. It is shown that the matrix of feedback coupling on a status at the complete information is not determined. The different algorithms of steady calculation of a matrix pseudo-inverse to the matrix of outputs using these or those decomposition of matrixes are analyzed. Algorithms of iterative specification of a required solution of "skeletal" decomposition are given. The given expressions allow synthesizing the simplified computing procedures of synthesis of multidimensional controlling systems at incomplete information on object …