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Articles 3751 - 3780 of 14260

Full-Text Articles in Chemical Engineering

Preparation Of Nanoemulsion Using Lipase-Synthesized Glucose Monooleate Through Low Energy Technique, Muhammad Fakhrurazi Ahmad Fadzil Feb 2021

Preparation Of Nanoemulsion Using Lipase-Synthesized Glucose Monooleate Through Low Energy Technique, Muhammad Fakhrurazi Ahmad Fadzil

Student Works (2020-2029)

In this study, glucose monooleate (GluO) was synthesized and compared to its counterpart i.e. Tween-80 (Tw-80) and Span-80 (Sp-80) to investigate the influence of the different hydrophilic head structure of the surfactants on emulsification property. Utilizing sugar molecules like glucose as the hydrophilic head group of surfactants is of interest as it has a high potential to be used as a targeted delivery agent. The main objective of this study is to investigate the capability of lipase synthesized GluO in the formation of O/W nanoemulsion in four different types of vegetable oils that are sunflower oil, olive oil, palm oil, …

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Editors’ Choice-Power-Generating Electrochemical Co2 Scrubbing From Air Enabling Practical Aemfc Application, Yiwei Zheng, Garrett Huang, Mrinmay Mandal, John R. Varcoe, Paul A. Kohl, William E. Mustain Feb 2021

Editors’ Choice-Power-Generating Electrochemical Co2 Scrubbing From Air Enabling Practical Aemfc Application, Yiwei Zheng, Garrett Huang, Mrinmay Mandal, John R. Varcoe, Paul A. Kohl, William E. Mustain

Faculty Publications

Anion exchange membrane fuel cells (AEMFCs) have been widely touted as a low-cost alternative to existing proton exchange membrane fuel cells. However, AEMFCs operating on air suffer from a severe performance penalty caused by carbonation from exposure to CO2. Many approaches to removing CO2 from the cathode inlet would consume valuable energy and complicate the systems-level balance-of-plant. Therefore, this work focuses on an electrochemical solution where CO2 removal would still generate power, but not expose an entire AEMFC stack to carbonation conditions. Such a system consists of two AEMFCs in series. The first AEMFC, which acts as an anion exchange …

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The Concept Of Constructing Set-Theoretic Models Of Structures Of Intelligent Multi-Axis Mechatronic Robot Modules, Nazarov Khayriddin Nuritdinovich, Matyokubov Nurbek Rrustamovich, Temurbek Omonboyevich Rakhimov, Pulatov Rustambek Alisher Ugli Feb 2021

The Concept Of Constructing Set-Theoretic Models Of Structures Of Intelligent Multi-Axis Mechatronic Robot Modules, Nazarov Khayriddin Nuritdinovich, Matyokubov Nurbek Rrustamovich, Temurbek Omonboyevich Rakhimov, Pulatov Rustambek Alisher Ugli

Bulletin of TUIT: Management and Communication Technologies

The article discusses the features and areas of application of multi-axis electromagnetic mechatronic modules in modules of mechatronic and robotic systems that allow not only to increase productivity and improve the quality of manufactured products, but also by replacing heavy, monotonous and sometimes associated with a risk to human health, manual labor with a machine to release a person for creative constructive work. The generalized structure of a multi-axis mechatronic module is presented; multiple theoretical models of construction principles for the study of electromagnetic mechatronic modules of robots and robotic systems are constructed. In this case, the main attention is …

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In Vitro Evaluation Of Novel Titania-Containing Borate Bioactive Glass Scaffolds, Romina Shafaghi, Omar Rodriguez, Anthony W. Wren, Loraine Chiu, Emil H. Schemitsch, Paul Zalzal, Stephen D. Waldman, Marcello Papini, Mark R. Towler Feb 2021

In Vitro Evaluation Of Novel Titania-Containing Borate Bioactive Glass Scaffolds, Romina Shafaghi, Omar Rodriguez, Anthony W. Wren, Loraine Chiu, Emil H. Schemitsch, Paul Zalzal, Stephen D. Waldman, Marcello Papini, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

Titanium-containing borate bioactive glass scaffolds (0, 5, 15, and 20 mol %, identified as BRT0, BRT1, BRT3, and BRT4) with a microstructure similar to that of human trabecular bone were prepared and evaluated in vitro for potential bone loss applications in revision total knee arthroplasty (rTKA). Methyl thiazolyl tetrazolium (MTT) cell viability assays of scaffold ion release extracts revealed that BRT0 scaffolds (0 mol % titanium) inhibited cell proliferation and activity at day 14. At day 30, all scaffold extracts decreased cell proliferation and activity significantly. However, live/dead cell assay results demonstrated that degradation products from all the scaffolds had …

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Lignin-Zein Composite: Synthesis, Three-Dimensional Printing, And Microbial Degradation, Jin Gyun Lee, Yusheng Guo, Jorge A. Belgodere, Ahmed Al Harraq, Aubry A. Hymel, Amber J. Pete, Kalliat T. Valsaraj, Michael G. Benton, Mary G. Miller, Jangwook P. Jung, Bhuvnesh Bharti Feb 2021

Lignin-Zein Composite: Synthesis, Three-Dimensional Printing, And Microbial Degradation, Jin Gyun Lee, Yusheng Guo, Jorge A. Belgodere, Ahmed Al Harraq, Aubry A. Hymel, Amber J. Pete, Kalliat T. Valsaraj, Michael G. Benton, Mary G. Miller, Jangwook P. Jung, Bhuvnesh Bharti

Chemical and Biochemical Engineering Faculty Research & Creative Works

Worldwide use and disposal of plastics have reached a dramatic saturation point, polluting lands, oceans, and air across the globe. Responding to such a challenge requires, among other environmental remediation measures, the manufacture of alternative sustainable plastics. Recent studies in the area have enabled the development of degradable plastics; however, the rate and conditions required for the degradation of such materials remains under scrutiny. Here, we introduce a new class of fully plant-based, rapidly degradable lignin and zein composite blend that can be transformed into macroscopic structures using extrusion three-dimensional (3D) printing. Corn-derived zein forms the polymeric solution, while insoluble …

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Characterization And Oil Recovery Enhancement By A Polymeric Nanogel Combined With Surfactant For Sandstone Reservoirs, Mustafa Mohammed Almahfood, Baojun Bai Feb 2021

Characterization And Oil Recovery Enhancement By A Polymeric Nanogel Combined With Surfactant For Sandstone Reservoirs, Mustafa Mohammed Almahfood, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The characterization and enhanced oil recovery mechanisms of a nanosized polymeric cross-linked gel are presented herein. A negatively charged nanogel was synthesized using a typical free radical suspension polymerization process by employing 2-acrylamido 2-methyl propane sulfonic acid monomer. The synthesized nanogel showed a narrow size distribution with one peak pointing to a predominant homogeneous droplet size. The charged nanogels were also able to adsorb at the oil-water interfaces to reduce interfacial tension and stabilize oil-in-water emulsions, which ultimately improved the recovered oil from hydrocarbon reservoirs. In addition, a fixed concentration of negatively charged surfactant (sodium dodecyl sulfate or SDS) was …

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Bone Cement As A Local Chemotherapeutic Drug Delivery Carrier In Orthopedic Oncology: A Review, Sunjeev S. Phull, Alireza Rahimnejad Yazdi, Michelle Ghert, Mark R. Towler Feb 2021

Bone Cement As A Local Chemotherapeutic Drug Delivery Carrier In Orthopedic Oncology: A Review, Sunjeev S. Phull, Alireza Rahimnejad Yazdi, Michelle Ghert, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

Metastatic bone lesions are common among patients with advanced cancers. While chemotherapy and radiotherapy may be prescribed immediately after diagnosis, the majority of severe metastatic bone lesions are treated by reconstructive surgery, which, in some cases, is followed by postoperative radiotherapy or chemotherapy. However, despite recent advancements in orthopedic surgery, patients undergoing reconstruction still have the risk of developing severe complications such as tumor recurrence and reconstruction failure. This has led to the introduction and evaluation of poly (methyl methacrylate) and inorganic bone cements as local carriers for chemotherapeutic drugs (usually, antineoplastic drugs (ANPDs)). The present work is a critical …

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Mixed Matrix Membranes For Sustainable Electrical Energy-Saving Applications, Hossein Riasat Harami, Farid Amirkhani, Hossein Abedsoltan, Mohammad Younas, Mashallah Rezakazemi, Mahdi Sheikh, Saeed Shirazian Feb 2021

Mixed Matrix Membranes For Sustainable Electrical Energy-Saving Applications, Hossein Riasat Harami, Farid Amirkhani, Hossein Abedsoltan, Mohammad Younas, Mashallah Rezakazemi, Mahdi Sheikh, Saeed Shirazian

Chemical and Biochemical Engineering Faculty Research & Creative Works

This work presents a technical investigation and review of the development of mixed matrix membranes (MMMs) employed in different applications to save electrical energy. The MMMs design has been recently adjusted and improved to restore more energy bulks. The important factors to control the performance of the MMMs are the penetrant type, membrane matrix, and polymer-filler interface interactions. This study reviews the current methods to deal with dielectric MMMs and smart nanomembranes for energy saving. These methods include ferroelectric membrane fabrication, dielectric permittivity, conductive dopants, construction of nanocomposites with modified surfaces, and the usage of combined effects. Most chemists and …

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Effect Of Membrane Properties On The Carbonation Of Anion Exchange Membrane Fuel Cells, Yiwei Zheng, Lyzmarie Nicole Irizarry, Noor Ui Hassan, Eric R. Williams, Morgan Stefik, Jacob M. Lamanna, Daniel S. Hussey, Mustain E William Jan 2021

Effect Of Membrane Properties On The Carbonation Of Anion Exchange Membrane Fuel Cells, Yiwei Zheng, Lyzmarie Nicole Irizarry, Noor Ui Hassan, Eric R. Williams, Morgan Stefik, Jacob M. Lamanna, Daniel S. Hussey, Mustain E William

Faculty Publications

Anion exchange membrane fuel cells (AEMFC) are potentially very low-cost replacements for proton exchange membrane fuel cells. However, AEMFCs suffer from one very serious drawback: significant performance loss when CO2 is present in the reacting oxidant gas (e.g., air) due to carbonation. Although the chemical mechanisms for how carbonation leads to voltage loss in operating AEMFCs are known, the way those mechanisms are affected by the properties of the anion exchange membrane (AEM) has not been elucidated. Therefore, this work studies AEMFC carbonation using numerous high-functioning AEMs from the literature and it was found that the ionic conductivity of the …

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Investigating The Performance Of Hydroponic Nutrient Solutions As Potential Draw Solutions For Fertilizer Drawn Forward Osmosis, Mohamed Bassiouny Abu Qersh Jan 2021

Investigating The Performance Of Hydroponic Nutrient Solutions As Potential Draw Solutions For Fertilizer Drawn Forward Osmosis, Mohamed Bassiouny Abu Qersh

Theses and Dissertations

This research project aims at investigating the performance of hydroponic nutrient solutions as draw solutions for desalination using the fertilizer drawn forward osmosis (FDFO) process. Six different lettuce and leafy greens hydroponic nutrient stock solutions were prepared according to the literature and used in this study and tested on a bench-scale forward osmosis unit as draw solutions for the process. The feed solutions for the process was de-ionized water mixed with Sodium Chloride in different concentrations to represent different salinities of brackish groundwater. The draw efficiency of each solution was measured based on water flux, reverse solute flux, water recovery, …

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Data-Driven Tools Guided By First-Principles For Scale Modeling, Sadegh Poozesh Jan 2021

Data-Driven Tools Guided By First-Principles For Scale Modeling, Sadegh Poozesh

Progress in Scale Modeling, an International Journal

For decades, traditional scale-modeling techniques have been relying on first-principles models (FPMs). FPMs have been used to find non-dimensional numbers (PIs) and identify normalized underlying forces and energies behind the phenomenon in focus. The two main challenges with FPM-based PIs extraction are finding the relevant PIs and proper correlations between PIs. The emergence and surge of data-driven modeling (DDM) provide a new opportunity to leverage experimental data in model development across scales/plants. In this paper, first, the two mentioned issues in PIs development will be elaborated to reveal the gap, and second, a new insight into scale modeling and similarity …

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Radiation‐Induced Oral Mucositis Hamster Model Using A Linear Accelerator Enhances Clinical Relevance Of Preclinical Studies For Treatment Strategy Investigation, Carolyn T. Jordan, Emily M. Bradford, Dennis C. Cheek, Mahesh R. Kudrimoti, Craig S. Miller, Molly H. Smith, J. Zach Hilt, Thomas D. Dziubla Jan 2021

Radiation‐Induced Oral Mucositis Hamster Model Using A Linear Accelerator Enhances Clinical Relevance Of Preclinical Studies For Treatment Strategy Investigation, Carolyn T. Jordan, Emily M. Bradford, Dennis C. Cheek, Mahesh R. Kudrimoti, Craig S. Miller, Molly H. Smith, J. Zach Hilt, Thomas D. Dziubla

Radiation Medicine Faculty Publications

Translational animal models for oral mucositis (OM) are necessary to simulate and assess the bioclinical effects and response in humans. These models should simulate high levels of radiation exposure that leads to oxidative stress and inflammatory‐initiated tissue changes. Hamster models have been extensively studied to observe pathological effects of radiation exposure and help in the development of effective treatments. To successfully evaluate the potential for treatment regimens with consistency and relevance, a radiation‐induced OM hamster model was developed using a clinical linear accelerator utilized by cancer patients daily. The dose exposure to the isolated, everted cheek pouch of a hamster, …

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Assessment Of Heavy Metal Concentration In Soils Around Geita The Gold Mine, Tanzania, Mariam G. Mgendi, Mkabwa L. K Manoko, W.J.S. Mwegoha, C. Southway C. Southway Jan 2021

Assessment Of Heavy Metal Concentration In Soils Around Geita The Gold Mine, Tanzania, Mariam G. Mgendi, Mkabwa L. K Manoko, W.J.S. Mwegoha, C. Southway C. Southway

Journal of Humanities and Social Sciences

Health issues related to gold mining cannot be underestimated. Gold mining produce acid mine drainage (AMD), which in turn releases heavy metals into the nearby environment, hence causing environmental pollution. Heavy metals are naturally very toxic, thus pose a great health concern especially when their concentration exceeds the recommended permissible limits. In this study, concentrations of five heavy metals—including Pb, Ni, Cr, Cu and Zn—were assessed in the soil around Geita Gold Mine (GGM). A total of 17 sampling sites were established from which the soil samples were collected at 0-15cm and 15-30cm soil depth. The concentration of both total …

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Fluorination Of Al₂O₃ Coating For Lithium-Ion Battery, Xinhua Liang, Han Yu Jan 2021

Fluorination Of Al₂O₃ Coating For Lithium-Ion Battery, Xinhua Liang, Han Yu

Chemical and Biochemical Engineering Faculty Research & Creative Works

Improving the performance of cathodes by using surface coatings has proven to be an effective method for improving the stability of Li-ion batteries (LIBs), while a high quality film satisfying all requirements of electrochemical inertia, chemical stability, and lithium ion conductivity has not been found. A composite film composed of AI2O3 and AIF3 layers was coated on the surface of Li-rich NMC based electrodes by atomic layer deposition (ALD). The electrochemical characterization results indicated that the coating with 1 cycle of AIF3 ALD on 5 cycles of AI2O3 ALD (1 A1 F3-5AI2O …

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Coating Compositions And Methods For Using The Same, Fateme Rezaei, Thomas P. Schuman, Glenn Morrison Jan 2021

Coating Compositions And Methods For Using The Same, Fateme Rezaei, Thomas P. Schuman, Glenn Morrison

Chemical and Biochemical Engineering Faculty Research & Creative Works

Coating compositions and methods for using the same are disclosed. The coating compositions can include an aminosilica adsorbent. The coating compositions can adsorb CO2.

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New Mechanism Insight For The Hydrogenation Of Co/Co2 Gas Mixtures To Hydrocarbons Over Iron-Based Catalyst, Sandeep Badoga, Michela Martinelli, Muthu Kumaran Gnanamani, Young Koh, Wilson D. Shafer Jan 2021

New Mechanism Insight For The Hydrogenation Of Co/Co2 Gas Mixtures To Hydrocarbons Over Iron-Based Catalyst, Sandeep Badoga, Michela Martinelli, Muthu Kumaran Gnanamani, Young Koh, Wilson D. Shafer

Center for Applied Energy Research Faculty and Staff Publications

Iron-based catalysts are the most suitable candidates for converting CO2 or CO2-rich syngas to hydrocarbons. However, several issues about the mechanism of CO2 hydrogenation are still unclear. In this work, we investigated the performance of an iron-based catalyst with H2/CO2, H2/CO/N2 and H2/CO/13CO2/N2 gas mixtures at the same process conditions (T = 270°C, P = 175 psi and SV = 3 NL/h/gcat). The CO2 hydrogenation rate was much lower than that observed for CO hydrogenation. 13CO2 …

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Computational Study Of Helical And Helix-Hinge-Helix Conformations Of An Anti-Microbial Peptide In Solution By Molecular Dynamics And Vibrational Analysis, Faramarz Joodaki, Lenore M. Martin, Michael L. Greenfield Jan 2021

Computational Study Of Helical And Helix-Hinge-Helix Conformations Of An Anti-Microbial Peptide In Solution By Molecular Dynamics And Vibrational Analysis, Faramarz Joodaki, Lenore M. Martin, Michael L. Greenfield

Chemical, Biomolecular, and Materials Engineering Faculty Publications

Many classical antimicrobial peptides adopt an amphipathic helical structure at a water-membrane interface. Prior studies led to the hypothesis that a hinge near the middle of a helical peptide plays an important role in facilitating peptide-membrane interactions.Here, dynamics and vibrations of a designed hybrid antimicrobial peptide LM7-2 in solution were simulated to investigate its hinge formation.Molecular dynamics simulation results on the basis of the CHARMM36 force field showed that the $\alpha$-helix LM7-2 bent around two or three residues near the middle of the peptide, stayed in a helix-hinge-helix conformation for a short period of time, and then returned to a …

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3d-Printed Microfluidic Droplet Generator With Hydrophilic And Hydrophobic Polymers, Chandler A. Warr, Hunter S. Hinnen, Saroya Avery, Rebecca J. Cate, Gregory P. Nordin, William G. Pitt Jan 2021

3d-Printed Microfluidic Droplet Generator With Hydrophilic And Hydrophobic Polymers, Chandler A. Warr, Hunter S. Hinnen, Saroya Avery, Rebecca J. Cate, Gregory P. Nordin, William G. Pitt

Faculty Publications

Droplet generation has been widely used in conventional two-dimensional (2D) microfluidic devices, and has recently begun to be explored for 3D-printed droplet generators. A major challenge for 3D-printed devices is preventing water-in-oil droplets from sticking to the interior surfaces of the droplet generator when the device is not made from hydrophobic materials. In this study, two approaches were investigated and shown to successfully form droplets in 3D-printed microfluidic devices. First, several printing resin candidates were tested to evaluate their suitability for droplet formation and material properties. We determined that a hexanediol diacrylate/lauryl acrylate (HDDA/LA) resin forms a solid polymer that …

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3d-Printed Microfluidic Droplet Generator With Hydrophilic And Hydrophobic Polymers, Chandler A. Warr, Hunter S. Hinnen, Saroya Avery, Rebecca J. Cate, Gregory P. Nordin, William G. Pitt Jan 2021

3d-Printed Microfluidic Droplet Generator With Hydrophilic And Hydrophobic Polymers, Chandler A. Warr, Hunter S. Hinnen, Saroya Avery, Rebecca J. Cate, Gregory P. Nordin, William G. Pitt

Faculty Publications

Droplet generation has been widely used in conventional two-dimensional (2D) microfluidic devices, and has recently begun to be explored for 3D-printed droplet generators. A major challenge for 3D-printed devices is preventing water-in-oil droplets from sticking to the interior surfaces of the droplet generator when the device is not made from hydrophobic materials. In this study, two approaches were investigated and shown to successfully form droplets in 3D-printed microfluidic devices. First, several printing resin candidates were tested to evaluate their suitability for droplet formation and material properties. We determined that a hexanediol diacrylate/lauryl acrylate (HDDA/LA) resin forms a solid polymer that …

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Isolation And Purification Of Glycoglycerolipids To Induce Apoptosis In Breast Cancer Cells, Muhammad Raisul Abedin, Sutapa Barua Jan 2021

Isolation And Purification Of Glycoglycerolipids To Induce Apoptosis In Breast Cancer Cells, Muhammad Raisul Abedin, Sutapa Barua

Chemical and Biochemical Engineering Faculty Research & Creative Works

Monogalactosyldiacylglycerol (MGDG) is the most abundant type of glycoglycerolipid found in the plant cell membrane and mostly in the chloroplast thylakoid membrane. The amphiphilic nature of MGDG is attractive in pharmaceutical fields for interaction with other biological molecules and hence exerting therapeutic anti-cancer, anti-viral, and anti-inflammatory activities. In this study, we investigated the therapeutic efficacy of cyanobacteria derived MGDG to inhibit breast cancer cell growth. MGDG was extracted from a cyanobacteria Synechocystis sp. PCC 6803 followed by a subsequent fractionation by column chromatographic technique. The purity and molecular structure of MGDG were analyzed by nuclear magnetic resonance (NMR) spectroscopy analysis. …

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Modelling And Analysis Of Performance For Biogas Fuelled Gas Engine Using Matlab, Indran Kunusilin Jan 2021

Modelling And Analysis Of Performance For Biogas Fuelled Gas Engine Using Matlab, Indran Kunusilin

Student Works (2020-2029)

A wide-ranging performance evaluation of a multi-cylinder gas engine operating wit biogas as a fuel were studied based on its performance parameters such as effective power, torque, SFC, MEP and Thermal Efficiency and its HRR analysis with the aid of modeling software, MATLAB. The analysis and performance study were used based on the thermodynamic model of an Otto cycle, which is based on the gas engines used. Parameters such as cylinder pressure with domain of crank angle and heat addition model (using Wiebe function ) were studied to model the and analyze the HRR .Besides that , the contributing factors …

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The 3-O-Sulfation Of Heparan Sulfate Modulates Protein Binding And Lyase Degradation, Pradeep Chopra, Apoorva Joshi, Jiandong Wu, Weigang Lu, Tejabhiram Yadavalli, Margreet A. Wolfert, Deepak Shukla, Joseph Zaia, Geert Jan Boons Jan 2021

The 3-O-Sulfation Of Heparan Sulfate Modulates Protein Binding And Lyase Degradation, Pradeep Chopra, Apoorva Joshi, Jiandong Wu, Weigang Lu, Tejabhiram Yadavalli, Margreet A. Wolfert, Deepak Shukla, Joseph Zaia, Geert Jan Boons

Chemical and Biochemical Engineering Faculty Research & Creative Works

Humans Express Seven Heparan Sulfate (HS) 3-O-Sulfotransferases that Differ in Substrate Specificity and Tissue Expression. Although Genetic Studies Have Indicated that 3-O-Sulfated HS Modulates Many Biological Processes, Ligand Requirements for Proteins Engaging with HS Modified by 3-O-Sulfate (3-OS) Have Been Difficult to Determine. in Particular, the Context in Which the 3-OS Group Needs to Be Presented for Binding is Largely Unknown. We Describe Herein a Modular Synthetic Approach that Can Provide Structurally Diverse HS Oligosaccharides with and Without 3-OS. the Methodology Was Employed to Prepare 27 Hexasaccharides that Were Printed as a Glycan Microarray to Examine Ligand Requirements of a …

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A Microscale Approach To Investigate Breast Cancer Cellular Communication And Migration, Sharif Mohammad Mizanur Rahman Jan 2021

A Microscale Approach To Investigate Breast Cancer Cellular Communication And Migration, Sharif Mohammad Mizanur Rahman

LSU Doctoral Dissertations

Metastatic breast cancer significantly decreases patient survival, with the majority of deaths caused by secondary metastasis. Cancer metastasis is a multi-step process that starts with the detachment of a cancer cell from the primary tumor and ends with establishing a secondary tumor at a distal location. This work's focus was to use an interdisciplinary microscale approach to study how cancer cells respond to neighboring cells and how they migrate in response to chemical gradients. Two distinct devices, a microfluidic device, and a 3D-printed plate insert, were developed to perform co-culture studies to elucidate the impact of ASCs on cancer cell …

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Stabilizing Liquid Drops In Nonequilibrium Shapes By The Interfacial Crosslinking Of Nanoparticles, Mohd A. Kahn, Martin F. Haase Jan 2021

Stabilizing Liquid Drops In Nonequilibrium Shapes By The Interfacial Crosslinking Of Nanoparticles, Mohd A. Kahn, Martin F. Haase

Henry M. Rowan College of Engineering Departmental Research

Droplets are spherical due to the principle of interfacial energy minimization. Here, we show that nonequilibrium droplet shapes can be stabilized via the interfacial self-assembly and crosslinking of nanoparticles. This principle allows for the stability of practically infinitely long liquid tubules and monodisperse cylindrical droplets. Droplets of oil-in-water are elongated via gravitational or hydrodynamic forces at a reduced interfacial tension. Silica nanoparticles self-assemble and cross-link on the interface triggered by the synergistic surface modification with hexyltrimethylammonium- and trivalent lanthanum-cations. The droplet length dependence is described by a scaling relationship and the rate of nanoparticle deposition on the droplets is estimated. …

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Study On Engine Performance And Exhaust Pollutant Using Isobutanol - Calophyllum Inophyllum Biodiesel - Diesel Ternary Blends In A Diesel Engine, Mohd Azham Mohd Alwi Jan 2021

Study On Engine Performance And Exhaust Pollutant Using Isobutanol - Calophyllum Inophyllum Biodiesel - Diesel Ternary Blends In A Diesel Engine, Mohd Azham Mohd Alwi

Student Works (2020-2029)

Renewable energy sources such as biodiesel and bio-alcohol are desirable and are alternative to meet energy demand and control emission, from renewable sources such as ethanol, methanol, butanol, and pentanol. Biodiesel has a notable interest in offering many advantages with few disadvantages and needs to be extended for comprehensive use. Applying greater alcohols such as butanol with biodiesel in fuel blends is a beneficial technic to enhance the fuel characteristics and use biodiesel and alcohol efficiently. Isobutanol is an organic compound that has very low volatility, higher-chain alcohols have energy densities close to gasoline. It is not as volatile or …

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Removal Of Selected Organic Pollutants In Landfill Leachate Using Natural Coagulant From Dillenia Indica Seed Extract, Aziz Ahmed Jan 2021

Removal Of Selected Organic Pollutants In Landfill Leachate Using Natural Coagulant From Dillenia Indica Seed Extract, Aziz Ahmed

Student Works (2020-2029)

This study is aimed to identify and characterise novel green coagulant from Dillenia indica seed extracts for the removal of selected persistent organic pollutants (POPs) in landfill leachate using coagulation-flocculation process. The removal efficacy of D. indica seed extracts was compared with commercially available coagulants namely Locust Bean Gum (LBG) and alum. Additionally, it focused on the optimisation of the variables of the coagulation-flocculation process such as coagulants dosage, pH and mixing speed for POPs removal. The functional groups, morphological behaviour and surface area of the dried flocs and samples were analysed using Fourier transform infrared (FTIR), Scanning Electron Microscopy …

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A Water Quality And Contaminant Source Assessment Of Arbuckle Creek In Fayette County, West Virginia, Sarah Ashby Simonton Jan 2021

A Water Quality And Contaminant Source Assessment Of Arbuckle Creek In Fayette County, West Virginia, Sarah Ashby Simonton

Theses, Dissertations and Capstones

Arbuckle Creek, located in Minden, West Virginia, is a stream that runs through Oak Hill, WV and is characterized by the presence of the Oak Hill Wastewater Treatment Plant and the history of the contamination of polychlorinated biphenyl (PCBs) from the copious amount of contamination from the Shaffer Equipment Site and the pollution from mining completed in the area throughout the 1900’s. In order to assess the reaches of the current water quality, samples were collected and assessed for benthic macroinvertebrates, water parameters, benthic algae, and habitat. This was accomplished using the West Virginia Department of Environmental Protection (WVDEP) agency’s …

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“Greener” Chemical Modification Of Cellulose Nanocrystals Via Oxa-Michael Addition With N-Benzylmaleimide, Mohammad Jahid Hasan, Ashley E. Johnson, Esteban E. Ureña-Benavides Jan 2021

“Greener” Chemical Modification Of Cellulose Nanocrystals Via Oxa-Michael Addition With N-Benzylmaleimide, Mohammad Jahid Hasan, Ashley E. Johnson, Esteban E. Ureña-Benavides

Faculty and Student Publications

Surface modification of cellulose nanocrystals (CNCs) was conducted by an oxa-Michael addition of primary hydroxyl groups on the CNC surface with N-Benzylmaleimide (BnM). Six principles of green chemistry were used to obtain the hydrophobized CNC. Two catalytic approaches were used, a self-catalyzed reaction where alkyl sulfuric acid on the surface of the CNC was the catalyst, and a base-catalyzed approach using triethylamine (TEA). DMSO was chosen as reaction solvent due to its low cost, low toxicity and ability to disperse native CNC compared to other polar diprotic solvents. NMR and FTIR studies confirmed the successful modification of CNCs in both …

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Effects Of Resin Chemistries On The Selective Removal Of Industrially Relevant Metal Ions Using Wafer-Enhanced Electrodeionization, Humeyra B. Ulusoy Erol, Christa N. Hestekin, Jamie A. Hestekin Jan 2021

Effects Of Resin Chemistries On The Selective Removal Of Industrially Relevant Metal Ions Using Wafer-Enhanced Electrodeionization, Humeyra B. Ulusoy Erol, Christa N. Hestekin, Jamie A. Hestekin

Chemical Engineering Faculty Publications and Presentations

Wafer-enhanced electrodeionization (WE-EDI) is an electrically driven separations technology that occurs under the influence of an applied electric field and heavily depends on ion exchange resin chemistry. Unlike filtration processes, WE-EDI can be used to selectively remove ions even from high concentration systems. Because every excess ion transported increases the operating costs, the selective separation offered by WE-EDI can provide a more energy-efficient and cost-effective process, especially for highly concentrated salt solutions. This work reports the performance comparison of four commonly used cation exchange resins (Amberlite IR120 Na+, Amberlite IRP 69, Dowex MAC 3 H+, and …

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Surface And Interfacial Phenomena Between Soil And Oil, Md Firoz Ahmed Jan 2021

Surface And Interfacial Phenomena Between Soil And Oil, Md Firoz Ahmed

Electronic Theses and Dissertations

Crude oil and motor oil spills on land have severe environmental consequences that pose threats to both humans and natural resources. It is particularly important to know the flow behavior of oils to protect terrestrial ecosystems from this kind of damage. The spreading kinetics, contact angle (CA), and droplet baseline studies of crude oil and motor oils were investigated over several realistic soil-based matrices composed of topsoil (silt-dominant), sand, clay, and moisture. It was found that with an increase in moisture content (MC), the spreading area decreased, and initial spreading time increased for all given oil. The initial CA generally …

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