Chemical Engineering Commons^™

Solvent Engineering Of Molybdenum Disulfide Electrocatalyst For Hydrogen Evolution., Robert Carl Spalding

Electronic Theses and Dissertations

Energy is at an exponentially growing demand, and to keep up with these demands new technologies for renewable energy have received increased attention. Hydrogen plays a vital role in water electrolysis and fuel cells, as the hydrogen evolution reaction (HER) is the main step water splitting process. Most of the current electrocatalysts for HER are dominated by platinum and other precious metals due to their low over-potential and small Tafel slope, however, they are extremely costly. For this reason, cost-effective non-precious metal catalysts must be developed. Transition metal dichalcogenides, such as molybdenum disulfide (MoS2), are abundant and have recently shown …

Multi Stage Modified Solvay Process For Co2 Capture And Reject Brine Desalination, Ameera Fares Mohammad

Dissertations

Brine management is an environmental concern, as many desalination plants need to find suitable approaches for the treatment or disposal of the large amounts of concentrated brine that are produced. Many conventional methods are used such as disposal through deep well injection, but these methods still suffer from many drawbacks. An alternative approach is to further process the brine by extracting the salts through reactions with carbon dioxide. The chemical reactions of reject brine with high alkalinity products and carbon dioxide are postulated to constitute a new, effective, economic and environmentally friendly approach. On the other hand, a major challenge …

Computational Sodium Heat Pipe Simulation In Three Dimensions For Transient Nuclear Reactor Analysis With Variable Surface Heat Flux, Valerie Jean Lawdensky

UNLV Theses, Dissertations, Professional Papers, and Capstones

Heat pipes are used to transfer heat through phase change in a liquid/vapor contained in a metal tube. They are passive devices that require no pumps to circulate the fluid and can transfer heat far more efficiently than a solid copper rod of the same diameter. They are commonly used in laptop computers where copper heat pipes filled with water take heat away from the CPU and transfer the heat to air through a heat exchanger. Heat pipes were also used in the Kilopower nuclear reactor where higher temperatures required sodium as the working fluid with stainless steel tubes. Computer …

Stochastic Modeling Of Surface Scalar-Flux Fluctuations In Turbulent Channel Flow Using One-Dimensional Turbulence, Marten Klein, Heiko Schmidt, David O. Lignell

Faculty Publications

Accurate and economical modeling of near-surface transport processes is a standing challenge for various engineering and atmospheric boundary-layer flows. In this paper, we address this challenge by utilizing an economical stochastic one-dimensional turbulence (ODT) model. ODT aims to resolve all relevant scales of a turbulent flow for a one-dimensional domain. Here ODT is applied to turbulent channel flow as stand-alone tool. The ODT domain is a wall-normal line that is aligned with the mean shear. The free model parameters are calibrated once for the turbulent velocity boundary layer at a fixed Reynolds number. After that, we use ODT to investigate …

Microplastics Fouling And Interaction With Polymeric Membranes: A Review, Mitra Golgoli, Mehdi H. Khiadani, Abdellah Shafieian, Tushar K. Sen, Y. Hartanto, M. L. Johns, Masoumeh Zargar

Research outputs 2014 to 2021

The emergence and accumulation of microplastics (MPs) in various aquatic environments have recently raised significant concerns. Wastewater treatment plants (WWTPs) have been identified as one of the major sources of MPs discharge to the environment, implying a substantial need to improve advanced techniques for more efficient removal of MPs. Polymeric membranes have been proven effective in MPs removal. However, fouling is the main drawback of membrane processes and MPs can foul the membranes due to their small size and specific surface properties. Hence, it is important to investigate the impacts of MPs on membrane fouling to develop efficient membrane-based techniques …

A Spatial Model Of Hepatic Calcium Signaling And Glucose Metabolism Under Autonomic Control Reveals Functional Consequences Of Varying Liver Innervation Patterns Across Species, Aalap Verma, Alexandra Manchel, Rahul Narayanan, Jan B. Hoek, Babatunde A Ogunnaike, Rajanikanth Vadigepalli

Department of Pathology, Anatomy, and Cell Biology Faculty Papers

Rapid breakdown of hepatic glycogen stores into glucose plays an important role during intense physical exercise to maintain systemic euglycemia. Hepatic glycogenolysis is governed by several different liver-intrinsic and systemic factors such as hepatic zonation, circulating catecholamines, hepatocellular calcium signaling, hepatic neuroanatomy, and the central nervous system (CNS). Of the factors regulating hepatic glycogenolysis, the extent of lobular innervation varies significantly between humans and rodents. While rodents display very few autonomic nerve terminals in the liver, nearly every hepatic layer in the human liver receives neural input. In the present study, we developed a multi-scale, multi-organ model of hepatic metabolism …

Cfd Simulations Of Macroscopic And Microscopic Multiphase Fluid Flow And Droplet Interaction, Aaron Harrington

LSU Master's Theses

Multiphase flow is a complex phenomenon which can be modeled on numerous different length scales, both macroscopically and microscopically. The use of a Euler-Euler model for Computation Fluid Dynamics (CFD) simulations of subcooled boiling phenomena is discussed in detail. The CFD conditions have been set up to mimic previous experimental conditions. A cylindrical vessel with subcooled liquid flow is heated along part of the axial wall of the vessel. A constant heat flux is applied to produce subcooled boiling. We discuss the development of the phase change within the vessel as well as the temperature profile, and validate the results …

Large-Scale Reality Modeling Of A University Campus Using Combined Uav And Terrestrial Photogrammetry For Historical Preservation And Practical Use, Bryce Berrett, Cory Vernon, Haley Beckstrand, Madi Pollei, Kaleb Markert, Kevin Franke, John Hedengren

Faculty Publications

Unmanned aerial vehicles (UAV) enable detailed historical preservation of large-scale infrastructure and contribute to cultural heritage preservation, improved maintenance, public relations, and development planning. Aerial and terrestrial photo data coupled with high accuracy GPS create hyper-realistic mesh and texture models, high resolution point clouds, orthophotos, and digital elevation models (DEMs) that preserve a snapshot of history. A case study is presented of the development of a hyper-realistic 3D model that spans the complex 1.7 km2 area of the Brigham Young University campus in Provo, Utah, USA and includes over 75 significant structures. The model leverages photos obtained during the historic …

Reaction Pathways Of Molecular Growth For Bay-Region Methyl-Substituted Polycyclic Aromatic Hydrocarbons During Supercritical Pyrolysis Of N-Decane, Venkata Sai Krishna Karthik Vutukuru

LSU Doctoral Dissertations

Prior to its combustion, fuel for future-highspeed aircraft will experience supercritical conditions, causing the fuel to undergo pyrolytic reactions that lead to the formation of polycyclic aromatic hydrocarbons (PAH), precursors to fuel-line solids that hinder aircraft’s safe operation. Therefore, understanding the formation pathways of PAH under supercritical conditions is important to preventing formation of these solids.

Previous work from our group has shown that n-alkanes are particularly problematic regarding solids formation and that the model fuel n-decane produces an abundance of aliphatics and one- to nine-ring aromatics—many of which are methyl-substituted. Some of these methyl-substituted PAH have their …

Computationally Driven Design Of Shape-Controlled Polymeric Nanostructures, Davindra Tulsi

USF Tampa Graduate Theses and Dissertations

In the realm of shape control involving synthetic soft materials, block copolymers are ubiquitously exploited due to their ability to spontaneously self-assemble into a plethora of morphologies. The growing need in areas such as drug delivery, lithography, and microelectronics to generate new nanostructures demands ever finer control of copolymer self-assembly. It is desirable to better control the shape and size of soft nanostructures, with minimal post processing techniques to assert stability.

While there is an abundance of literature on diblock copolymer assembly, few relationships exist for sequence-controlled copolymers. It is well known that biological macromolecules are highly sequence specific and …

Application Of Gas-Assisted Gravity Drainage (Gagd) Process For Enhancing Recovery From Unconventional Resources, Muzher Al Musabeh

LSU Doctoral Dissertations

The oil recovery with hydraulic fracturing has played an important role in hydrocarbon production and energy support last decade from unconventional resources. Characteristically, the significant production decline and low recovery factors from these reservoirs triggered the need for new EOR techniques to compensate for the decline and help sustain the production. In this study, an experimental investigation of the Gas-Assisted Gravity Drainage (GAGD) process in the presence of fractures as EOR process was conducted using Nitrogen (N2) and Carbon Dioxide (CO2) in Berea Sandstone (BSS) and Tuscaloosa Marine Shale (TMS). Core flooding and EOR experiments were used to determine the …

Aerobic Copper-Promoted Oxidative Dehydrosulfurative Carbon-Oxygen Cross-Coupling Of 3,4-Dihydropyrimidine-1: H -2-Thiones With Alcohols, Jihong Lee, Yujeong Kwon, Dong-Chan Lee, Jeong Hun Sohn

Chemistry and Biochemistry Faculty Research

An aerobic Cu-promoted oxidative dehydrosulfurative carbon-oxygen cross-coupling of 3,4-dihydropyrimidin-1H-2-thiones (DHPMs) with both aliphatic and aromatic alcohols is described. Together with the ready availability of DHPMs and both alcohols, the method furnishes facile access to biologically valuable 2-alkoxypyrimidines with rapid diversification.

Aiche Virtual Communities Of Practice – Supporting Faculty During The Covid-19 Pandemic, Christi L. Patton (Luks)

Chemical and Biochemical Engineering Faculty Research & Creative Works

In response to the COVID-19 pandemic, chemical engineering departments from around the world shifted their course offerings from in-person to online almost instantaneously. The AIChE Education Division immediately responded to this educational shift by developing five Virtual Communities of Practice (VCPs) that allowed faculty to share experiences and best practices as well as provide a network for emotional support. Community creation, methods and materials shared, and surveys related to the impact of this initiative will be discussed.

Entrepreneurially Minded Learning In The Unit Operations Laboratory Through Community Engagement In A Blended Teaching Environment, Erick S. Vasquez, Kelly Bohrer, Abraham Noe-Hays, Arthur Davis, Matthew Dewitt, Michael J. Elsass

Chemical and Materials Engineering Faculty Publications

Online and blended learning opportunities in Chemical Engineering curriculum emerged due to COVID-19. After eight weeks of in-person Unit Operations Laboratory sessions, a remote-learning open-ended final project was assigned to student teams. The assignment involved aspects related to entrepreneurial-minded learning (EML) and community-based learning (CBL). Results show correlations between self-directed learning and the EML framework. Continuous support and involvement of a community partner correlate to students' m

Inventory Control Using Fuzzy Inference System And Adaptive Neuro Fuzzy Inference System Under Uncertain Conditions, Ali Abdulmajeed Ali, Arzaq Mohammed Ali Kulaib

Hadhramout University Journal of Natural & Applied Sciences

Supply chain management plays a significant role for running business efficiently, as it integrates management of materials and information flows between supply chain parties Fuzzy Inference System (FIS) and Adaptive Neuro Fuzzy inference system (ANFIS) are expert systems widely used to deal with imprecise and vague data. In this paper FIS and ANFIS are implemented to deal with the uncertainty regarding demand, lead time and inventory level in continuous inventory control system in order to obtain the optimal order quantity and reorder point. These two models are compared with Economic Order Quantity (EOQ) model at the different service level to …

A Modified Model For Prediction Of Gas Viscosities Of Yemeni Gas Fields, Khaled Saeed Ba-Jaalah, Abbas Mohamed Al-Khudaf, Amer Badr Binmerdhah

Hadhramout University Journal of Natural & Applied Sciences

Gas viscosity is an important physical property that controls and influences the flow of gas through porous media and pipe networks. An accurate gas viscosity model is essential for use with reservoir and process simulators. The present study is concerned with the evaluation of available gas viscosity correlations. The paper also presents new models for predicting gas viscosity for Yemeni gas reservoirs. The most often used different correlations for gas viscosity were assisted for Yemeni gas samples. The limitations of these correlations have been analyzed using Yemeni field data. Calculations are made using 120 experimental data points from Yemeni gas …

Experimental Heat Transfer Investigations Of A Double Pipe U-Tube Heat Exchanger Equipped With Twisted Tape And Cut Twisted Tape Internals, Raj Kumar Nayak Maloth, Glen Cletus Dsouza, Swarna Mayee Patra

Mechanical and Materials Engineering Publications

For several decades, the use of heat exchangers for both heating and cooling applications has been established in industries ranging from process to space heating. Out of the various types of heat exchangers, U-tube heat exchangers are preferred owing to their abilities to handle larger flowrates and their simplicity in construction. U-tube exchangers are often equipped with innards of various forms which facilitate higher heat transfer rates and thermal efficiencies. Although higher heat transfer rates have been established with the addition of internals, there is a lack of coherence on the underlying complex physical phenomena such as heat transfer boundary …

Investigating Black Silicon Surface Geometry Via Parameter Modification And Low Flow Inductively Coupled Plasma Deep Reactive Ion Etching, Noah Mulherin Smith

Honors Capstones

No abstract provided.

A Conceptual Efficient Design Of Energy Recovery Systems Using A New Energy-Area Key Parameter, Ibrahim H. Alhajri, Mamdouh A. Gadalla, Hany A. Elazab

Chemical and Biochemical Engineering Faculty Research & Creative Works

Energy integration in petrochemical and refining industries is an effective concept to minimize dependence on heating and cooling utilities through networks of exchanger equipment. Pinch Analysis is very popular and successful technique to optimize heat recovery between heat sources and sinks. Yet, design of networks of exchangers is challenging and requires careful attention to energy consumption and exchanger areas. This work presents a graphical methodology to design exchanger networks taking into account both heat loads and transfer areas of exchanger units in one single information. A new parameter is introduced for design that is the ratio between the heat load …

Extracellular Matrix-Mimetic Hydrogels For Treating Neural Tissue Injury: A Focus On Fibrin, Hyaluronic Acid, And Elastin-Like Polypeptide Hydrogels, Derek W. Nelson, Ryan J. Gilbert

Chemical and Biochemical Engineering Faculty Research & Creative Works

Neurological and functional recovery is limited following central nervous system injury and severe injury to the peripheral nervous system. Extracellular matrix (ECM)-mimetic hydrogels are of particular interest as regenerative scaffolds for the injured nervous system as they provide 3D bioactive interfaces that modulate cellular response to the injury environment and provide naturally degradable scaffolding for effective tissue remodeling. In this review, three unique ECM-mimetic hydrogels used in models of neural injury are reviewed: fibrin hydrogels, which rely on a naturally occurring enzymatic gelation, hyaluronic acid hydrogels, which require chemical modification prior to chemical crosslinking, and elastin-like polypeptide (ELP) hydrogels, which …

Immobilization Of Lipase On Metal Organic Frameworks For Biodiesel Production, Reem L Husam Safwan Shoma

Theses

For the economical application of enzymatic processes in biodiesel production, lipase enzyme has to be used in immobilized form to allow easy retention and reuse. The main challenges facing the industrialization of the enzymatic process are the high mass transfer resistance, the tendency to adsorb the by-product glycerol onto the support matrix and poor operational stability. These problems can be solved by a good selection of supports of favourable surface characteristics and pore sizes. In that regard, increasing interest has recently been in Metal-Organic Frameworks (MOFs) as a new kind of porous support for enzyme immobilization. Physical adsorption, which is …

Control Of The Facial Design Process Of Innovative Developments, Yusuf Shodiyevich Avazov

Chemical Technology, Control and Management

The role and place of visual design in the process of creating an innovative development have been stated. It is shown that the tasks of the face stage of the product life cycle are devoted to systemic issues, in the center of which is the resolution of the contradiction between the desired and the achievable. The first is determined by the need to create a new system of a higher level, and the achievable is determined by the level of development of science, technology and production technology, as well as by the conditions of operation and repair. The work is …

Information Software And Devices For Energy Efficiency Management And Control, Narzullo Nuriddinovich Mirzoyev

Chemical Technology, Control and Management

The article provides information on modern methods of management and control of energy efficiency at industrial enterprises. This includes the software needed to manage and monitor energy efficiency, as well as the formation of a database. In addition, a structural diagram of an intelligent power monitoring system has been developed and its elements have been selected. Describes the principle of operation of an intelligent measuring device, its connection to the network, conversion of analog signals to digital, channels and ranges of signal transmission, metrological characteristics. The article details the capabilities and benefits of smart meters.

Control System Synthesis With Self-Adapting Regulator By Interactive Adaptation Method, Isamiddin Xakimovich Siddikov, Renata Nikolayevna Izmaylova

Chemical Technology, Control and Management

The research results on the creation of a self-adapting control system for a nonlinear dynamic object based on the theory of intelligent control using interactive adaptation methods have been presented. The lack of an accurate description and the nonlinearity of the dynamic properties of the object under study, the presence of mutual influence of cross communication channels in the control circuits, as well as the influence of various types of uncertainties associated with the lack of a priori information about the process, significantly complicate the solution of the problem of synthesis of highly efficient control systems for dynamic objects, which …

Analysis Of Water Treatment Methods For Circulating Water Supply In Industrial Plants, Djalolitdin Paxritdinovich Mukhitdinov, Nilufar Abdusomi Kizi Yunusova

Chemical Technology, Control and Management

This scientific paper deals with the problem of extracting Ca2+ and Md2+ salts from water in order to prevent the formation of scale on the heating surfaces of heat exchange equipment. The features, advantages and disadvantages of chemical, membrane and ion exchange methods of water treatment have been evaluated. It has been shown that the chemical method of water purification can be used only for the preparation of industrial water at large stations (at the same time, high residual hardness prevails in the water, the equipment has low productivity), and the membrane method requires pretreatment of water, creation of overpressure …

Algorithms For Modal Control Synthesis In Multi-Dimensional Dynamic System, Husan Zakirovich Igamberdiev, Jasur Usmonovich Sevinov, Oqila Husanovna Boyeva

Chemical Technology, Control and Management

Algorithms for the synthesis of modal control of a multidimensional dynamic system with concentrated parameters in the state space have been presented. The problems of modal control of a multidimensional dynamic system have been formulated for the case when the matrix representation of a closed system has a simple structure. The conditions for the solvability of the problem of modal control of a multidimensional dynamic system by means of output feedback have been obtained. To give numerical stability in the procedure of pseudo-circulation of matrices, it is proposed to use the concepts of regular methods in the form of scalar …

Ultrasonic Extraction Of Instant Forms Of Plant Substrates In Industrial Production, Shakhnoza Abduvaxitovna Sultanova, Jasur Safarov, Azamat Bakir O'G'Li Usenov, Doston Ishmuhammat Ogli Samandarov, Qobil Akmal Ogli Mukhiddinov

Chemical Technology, Control and Management

In recent years, both in our country and abroad, ultrasonic extraction methods have been increasingly used in industrial production, which is associated with the extraction of various substances and compounds from natural plant substrates. Domestic and foreign experience shows that this method has significant advantages over traditional methods and can significantly increase the efficiency and profitability of industrial enterprises, producing complete and functional food products.

This article discusses a brief theory of ultrasonic cavitation and the experience of extracting substrates from plants. Different results have been compared and analyzed.

Analysis Of Grain Product Drying Methods, Azizbek Nodirbekovich Yusupbekov, Dilmurod Egamberganov

Chemical Technology, Control and Management

Various drying methods and grain characteristics have been studied. The advantages and disadvantages of various grain drying methods were obtained. The use of the following methods of drying grain products is very useful for speeding up the drying process, reducing waste, achieving more flexible process management and delivering all the nutrients of dried grain and grain products to the subsequent production process. The technological approaches that increase the efficiency of high-quality production after drying grain products, the requirements for modern grain dryers have analyzed. The ways of overcoming the problem of high energy consumption in the process of drying grain …

Implementation Of Distance Learning At Universities Using The Experience Of The Honeywell Process Control Laboratory At Tashkent State Technical University, Nodirbek Rustambekovich Yusupbekov, Adilov Tulkunovich Farukh, Isakova Ismailovna Sitora

Chemical Technology, Control and Management

The experience of modernization of the Honeywell Process Control Laboratory at Tashkent State Technical University has been considered (which is equipped with upgraded equipment (simulators for simulating various technological processes, distance learning tools). As a result, the quality of the demonstration of process control mechanisms increased the availability of theoretical and practical knowledge in the field of automated control systems. They also considered the teaching methods necessary for a modern student – remote access in real time, when students pass a knowledge test, consult with teachers, etc.

Error Of Contactless Converters Of High Currents Of Monitoring And Control Systems From The Influence Of Currents Of Neighboring Buses, A.M. Plakhtiev, Gayratjon Gaziev, Y.A. Meliboev, O. Doniyorov

Chemical Technology, Control and Management

The article presents the general principles of construction of contactless ferromagnetic converters of large direct currents, the main requirements for them, and the results of the development of one of the developed wide-range magnetomodulation contactless converters of control and control systems concerning large electric power facilities. The developed converter, unlike the known ones, have a wide range of controlled currents, increased accuracy and sensitivity, a technological design, and small weight and dimensions at low material consumption and cost. The errors of contactless wide-range magnetomodulation converters from the influence of currents of neighboring buses connected by and the opposite direction are …