Chemical Engineering Commons^™

Removal Of Methylene Blue By Adsorption Of Water Hyacinth Derived Active Carbon Embedded With Cobalt Nanoparticles, Hany A. Elazab, A. O. Okasha, M. A. Radwan, M. A. Sadek, Amin Firouzi, Tamer T. El-Idreesy

Chemical and Biochemical Engineering Faculty Research & Creative Works

In this research, active carbon-based catalyst synthesis and characterization were tested for potential catalysts to be used in dye removal of methylene blue (MB). Water hyacinth is one of the major problems that is facing humankind and especially here in Egypt. One of the implications of industrial activities is environmental pollution. Dyes used in the production of textiles, paper, and clothes are one of the major pollutants. The waste of those dyes discharged into water supplies without treatment or with ineffective treatment harmfully impacts the environment. In this research, the treatment is implemented using active carbon-based catalysts using embedded nanoparticles. …

Scale Model Equations And Optimization For Annular Flow Of Non-Newtonian Fluids Between Eccentric And Rotating Cylinders, Wei Zhang, Pooya Khodaparast, Amin Mehrabian Dr., Amir Shojaei

Progress in Scale Modeling, an International Journal

A broad range of engineering applications involves helical flow of non-Newtonian fluids between two eccentric cylinders. These applications often require estimation of the frictional pressure losses along the axes of the cylinders. Laboratory flow loops are commonly used to study the flow characteristics at smaller scales of investigation. This study uses the laws of similarity and dimensional analysis to obtain a set of scaling equations between the laboratory and prototype scales of the described annular flow. These equations are derived for four types of fluid rheology including Newtonian, power-law, Bingham-plastic, and yield power-law.

Results are expressed through a set of …

Numerical Investigation On The Effect Of Spectral Radiative Heat Transfer Within An Ablative Material, Raghava S. C. Davuluri, Rui Fu, Kaveh A. Tagavi, Alexandre Martin

Mechanical Engineering Faculty Publications

The spectral radiative heat flux could impact the material response. In order to evaluate it, a coupling scheme between KATS - MR and P1 approximation model of radiation transfer equation (RTE) is constructed and used. A Band model is developed that divides the spectral domain into small bands of unequal widths. Two verification studies are conducted: one by comparing the simulation computed by the Band model with pure conduction results and the other by comparing with similar models of RTE. The comparative results from the verification studies indicate that the Band model is computationally efficient and can be used to …

Effect Of Glycol Based Coolant Pollution On Pem Fuel Cells Stack And Recovery Measures, Cong-Yi Zhu, Xiao-Hui Li, Quan-Quan Gan

Journal of Electrochemistry

As the heat conduction medium of fuel cell cooling system, coolant is very important for the thermal management of fuel cell stack. In practical application, coolant leakage into the stack often occurs. Due to the randomness of fault location of components, the location of coolant leakage is uncertain, which may occur on the cathode side or anode side of some or all single cells. The main effects of coolant pollution on fuel cell stack are as follows: the output of open circuit voltage decreases sharply, the consistency of single cells voltage decreases and so on, which seriously affects the normal …

Copper Nanoparticles In-Situ Anchored On Nitrogen-Doped Carbon For High-Efficiency Oxygen Reduction Reaction Electrocatalyst, Hui-Fang Yuan, Yue Zhang, Xing-Wu Zhai, Li-Bing Hu, Gui-Xian Ge, Gang Wang, Feng Yu, Bin Dai

Journal of Electrochemistry

Compared with noble metal platinum (Pt)-based catalysts, inexpensive non-noble metal electrocatalysts have attracted extensive attention for oxygen reduction reaction (ORR). Herein, chitosan as a kind of biomass resource rich in nitrogen and carbon was used to prepare nitrogen-doped carbon (N-C) and N-C in-situ anchored by copper nanoparticles (Cu/N-C). The as-obtained N-C and Cu/N-C nanoparticles were successfully used as non-noble eletrocatalysts tested for ORR. Compared with the N-C, the Cu/N-C showed the high surface area of 607.3 m ²·g^-1 with the mean pore size of 2.5 nm and the pore volume of 0.40 cm³·g^{-1 …}

Structure Analysis Of Pemfc Cathode Catalyst Layer, Rui-Qing Wang, Sheng Sui

Journal of Electrochemistry

The sluggish oxygen reduction reaction (ORR) on the cathode of the proton exchange membrane fuel cell (PEMFC) has always been one of the key factors limiting its commercialization. The optimization of the cathode catalytic layer structure plays an important role in improving fuel cell performance and reducing production costs. In this paper, two different catalysts (platinum nanoparticles (Pt-NPs) and platinum nanowires (Pt-NWs)) were prepared by using catalyst coated substrate (CCS) method. By constructing a double-layer catalytic layer structure, we analyzed the effect of different catalytic layer structures by performing a single cell test. The results showed that the dense platinum …

Formation And Morphological Evolution Of Nanoporous Anodized Iron Oxide Films, Jin-Wei Cao, Nan Gao, Zhao-Qing Gao, Chen Wang, Sheng-Yan Shang, Yun-Peng Wang, Hai-Tao Ma

Journal of Electrochemistry

The preparation of iron oxide films with nanoporous structure by anodization has attracted much attention for its potential applications. However, the formation mechanism of porous structure during anodization is still unclear. In this paper, the composition of anodic current during the formation of nanoporous anodized iron oxide film was analyzed in combination with the current density-potential response (I-V curve) and the derivation of Faraday’s law. The results showed that the anodic current consisted of an ionic current (leading to the migration of ions to form oxide) and an electronic current (leading to the oxygen evolution), and the …

Development Of Asphalt-Resin-Paraffin Deposits Solvent, Gulmira Todjiyeva, F Badriddinova, M Tursunov, H Kadirov, E Cherkasova

Technical science and innovation

A solvent which is a mixture of aromatic hydrocarbons of the C₉ fraction and aliphatic alcohols in a 1:1 ratio, a nonionic surfactant in an amount of 1 - 3% by weight has been developed. It leads to an increase in the dissolving and washing capabilities of the solvent for more than 2 times in relation to paraffin-type AS. The ability of the chemical composition, which is a solvent composition, to have a depressant-dispersing effect in relation to paraffin-type AS has been determined.

Despite a large number of studies devoted to the development of technologies for the removal of …

Methods Of Improving Complex Cleaning Of Sand Plugs In Khodjaobad Underground Gas Wells, Abdulaziz Murodov, Muhriddin Muydinov, Saidaziz Khabibullaev, Aziz Abidov

Technical science and innovation

The purpose of the study is to develop recommendations for improving the methods of cleaning complex sand plugs in wells of underground gas storage. To organize the correct and efficient use of underground gas storage, the bottom of wells must be kept clean. The article develops recommendations on the use of optimal methods for cleaning wells from complex sand jams on the example of Khujabad UGS. In addition, recommendations were developed for the operation of production wells in the horizons of the XX-XXI-XXII underground gas storage of Khujabad

Research Of New Fireproof Supplied Polymer Composites Based On Epoxy Resin For Metal Structures, Kuvondiq Murtazaev, F.N. Nurkulov, D.N. Mukhiddinov, M.T. Аbdirova

Technical science and innovation

In the article proposes new compositions based on fire retardant expanded polymer composites of epoxy resin ED-20 and phosphorus-containing oligomers, catalysts, aluminum hydroxide and nitrogen-containing compounds.

The obtained sample of fire retardant expanded polymer composites based on epoxy resin, as well as the initial substances, were investigated by IR spectroscopy (Nicolet 5700), thermogravimetric analysis (TG) (SDT Q600) of physical and chemical properties and determination of fire retardant efficiency according to GOST R 53295-2009.

Infrared spectroscopy has been used to determine the bends and epoxy groups that characterize composites, as well as to determine the frequencies of phosphorus, nitrogen, and metal-containing …

A Proper Framework For Studying Noise From Jets With Non-Compact Sources, Woutijn J. Baars, Nathan E. Murray, Charles E. Tinney

Faculty and Student Publications

A quantitative assessment of the acoustic source field produced by a laboratory-scale heated jet with a gas dynamic Mach number of 1.55 and an acoustic Mach number of 2.41 is performed using arrays of microphones that are traversed across the axial and radial plane of the jet's acoustic field. The nozzle contour comprises a method of characteristics shape so that shock-related noise is minimal and the dominant sound production mechanism is from Mach waves. The spatial topography of the overall sound pressure level is shown to be dominated by a distinct lobe residing on the principal acoustic emission path, which …

Uncertainty Of The Ultrasonic Method For Determining The Strength Of Concrete, Ortagoli Sharipovich Hakimov, Zamira Khudoyberdiyevna Ernazarova

Chemical Technology, Control and Management

The issues of measuring the strength of concrete by the method of surface sounding by ultrasound are considered. A measurement model and formulas for estimating the total standard measurement uncertainty, information about the standards used, measurement tools and methods, and environmental parameters are given. Information about the estimation of uncertainty in the form of "eight steps", such as: measurement task; mathematical model of measurement; analysis of input values; observation results; correlations; uncertainty budget; expanded uncertainty; measurement result. It has been established that the uncertainty of type B of the ultrasonic method for determining the strength of concrete is much less …

Mathematical Modeling Of Processes Of Diagnostics Of Technical And Technological Objects, Azizbek Nodirbekovich Yusupbekov, Khurshid Salim Ugli Turayev

Chemical Technology, Control and Management

The work is an introduction to the technical diagnostics of technical (or technological) objects. It discloses the basic concepts and definitions of the reliability of dynamic systems as objects of diagnostic reference knowledge and their diagnosis. Structural schemes of diagnosing objects with individual and combined channels of influence are analyzed. Questions of rational construction of base of reference knowledge are stated.

A Novel Dental Re-Mineralizing Blend Of Hydroxyethyl-Cellulose And Cellulose Nanofibers Oral Film Loaded With Nepheline Apatite Glass: Preparation, Characterization And In Vitro Evaluation Of Re-Mineralizing Effect, Dalia Y. Zaki, Engie M. Safwat, Shaymaa M. Nagi, Haidy N. Salem, Tamer M. Hamdy, Lamiaa M. Moharam, Mohammad L. Hassan, E. M.A. Hamzawy

Chemical and Biochemical Engineering Faculty Research & Creative Works

The present investigation aimed to prepare and evaluate an innovated re-mineralizing oral films made from a blend of hydroxyethyl-cellulose (HEC) and cellulose nanofibers (CNF), loaded with nepheline fluorapatite glass powder. Evaluation of film thickness, folding endurance, disintegration time, surface pH, ions release, together with SEM were carried out. In vitro re-mineralizing effect of the prepared film on demineralized teeth was examined. Results revealed the uniformity in thickness of films, folding endurance more than 300, and the disintegration times more than 24 hrs. The pH values were nearly neutral and high concentrations of calcium and fluoride ions were released. SEM showed …

Virtual Analyzers For Increasing The Intelligence Of Industrial Process Control Systems, Umidjon Abdimajotovich Ruziev Phd, Marufjon Kobuljanovich Shodiev

Chemical Technology, Control and Management

It is shown that the development and implementation of virtual analyzers of the quality of the final industrial products is an effective tool for increasing the efficiency of industrial production. The methodology and stages of development of virtual analyzers for predicting the quality of products, monitoring non-measurable or difficult-to-measure parameters of continuous and periodic technological processes are considered, and issues of supporting and adapting a virtual analyzer during its operation without restructuring are also considered.

Developing Advanced Process Control System For Manufacturing Processes Using Virtual Analyzer, Elyor Erkinovich Samadov

Chemical Technology, Control and Management

This research reflects outlines the main potential features of Advanced Process Control (APC) systems for improved control of technological processes and production. It is shown developing APC systems using a virtualized analyzer (VA) is a very effective technique to increase the efficiency of industrial production. This research reflects the main steps of generating VA as part of the APC system and also describes the key features of each step-in terms of analyzer synthesis.

Design Lifecycle Management Of Technological Processes, Yusuf Shodiyevich Avazov

Chemical Technology, Control and Management

The issues of life cycle management of design processes of complex technological processes are considered. An analysis of works devoted to the automated design of technological processes and industries, product life cycle management, and the use of predominant modeling in design is presented. A structure for the implementation of the design of technological processes is proposed and it’s components are described. An algorithm is proposed to reduce the life cycle of the design of a technological process. The sequence of selection of the most optimal project options with the help of the proposed algorithm is described. It is shown that …

Predictive Analysis And Synthesis, Modeling And Control Of Complex Technological Processes And Systems, Zhahongir Sherboyevich Bekqulov

Chemical Technology, Control and Management

Consider the theoretical underpinnings of practically predictive analysis and synthesis, modeling and automatic control of complex chemical technological processes and systems, and the evolution of advanced (or advanced) APC (Advanced Process Control) control of technological processes and industries. The current state of industrial automation systems and the characteristics of their deployment are highlighted. The features of each stage of the analysis and synthesis of APC - advanced process control for complex dynamic objects are disclosed. The real situation and features of the implementation of industrial automation systems of industrial enterprises are reflected.

New Transformer Changer Static Characteristics Measuring Angle Silences Difference, Sultan Faizullayevich Аmirov, Nurulla Raxmatullayevich Yuldashev

Chemical Technology, Control and Management

Presented the specific features of the new transformer converter, which measures the difference in angular displacement, and examines the nonlinearity levels of static characteristics, sensitivity and static characteristics. Studies have shown that in a new measuring device, where one of the two moving parts consists of a magnetic conductor made in the form of an Archimedean spiral made of ferromagnetic material, the balance of the magnetic bridge changes not only depending on the angle of rotation of it’s shoulder resistances. the current is disturbed by the change in the magnitude of the combined air gap depending on the angle of …

Quality Control Of Combustion Of Gaseous Fuel In Furnaces, Azamat Toirovich Rajabov

Chemical Technology, Control and Management

The issues of research and development of systems for monitoring the availability and quality of the process of fuel combustion in industrial furnaces are interpreted. The perspective of using new elements in control systems - communication sensors for the presence and quality in gas-burning installations and furnaces are shown. A method has been developed to control the optimal aeration coefficient based on the extreme of the total integral amplitude-frequency characteristic of the flame conductivity pulsations, which makes it possible to control the quality characteristics of gas-burner devices and control the ratio of the components of the combustible mixture with high …

Algorithm For Calculating The Parameters Of A Multi-Position Electromagnetic Linear Mechatronic Module, Nazarov Khayriddin Nuritdinovich, Matyokubov Nurbek Rustamovich, Temurbek Omonboyevich Rakhimov

Chemical Technology, Control and Management

Currently, in the world in the field of science, engineering and technology, including in mechatronics and robotics, the creation of multi-coordinate mechatronic systems that perform power and control functions is becoming of paramount importance, this is due to a number of important positive qualities of the systems, such as simplicity and compactness of the design, the possibility of obtaining significant efforts, high accuracy and stability of the establishment of fixed positions, ease of control and high reliability. This article presents the calculation of the parameters of multi-position mechatronic modules based on linear execution elements. In the construction of this model, …

Regular Algorithms For Adaptive Identification Of Linear Non-Stationary Systems, H.Z. Igamberdiyev, H.I. Sotvoldiev, U.F Mamirov

Chemical Technology, Control and Management

The article deals with the formation of regular algorithms for adaptive parametric spline identification of linear non-stationary systems. Analyzed the issues of constructing adaptive identification of continuous linear non-stationary systems with monotonic and sign-constant parameters. In this case, in a non-stationary system, the entire observation interval is in some way divided into sub-intervals. Identification is carried out at each of the parameter constancy intervals, while the parameter matrix is re-evaluated for the next interval. The input data of the system are determined with an error depending on the error of approximating the state of the system by splines and approximating …

Review—Concentration Measurements In Molten Chloride Salts Using Electrochemical Methods, Tyler Williams, Rankin Shum, Devin Rappleye

Faculty Publications

The electrochemical measurement of concentration in molten chloride salts is a valuable tool for the control of existing and potential industrial processes, recycling of precious materials and energy production. The electrochemical techniques commonly used to measure concentration and each techniques’ associated theory are discussed. Practices which improve measurement accuracy and precision are set forth. Exceptionally accurate and precise measurements published in the literature are evaluated based on their performance in specified concentration ranges. The strengths and weaknesses of the most accurate measurements are briefly explored. Chronopotentiometry (CP) and square wave voltammetry (SWV) are accurate and precise with low concentration measurements. …

Adsorption Of Organic Iodides On Reduced Silver Functionalized Silica Aerogel, Siqi Tang

Dissertations - ALL

In the nuclear waste reprocessing, radioactive iodine is released in both organic and inorganic forms into off-gas streams. Due to its properties of long half-life and accumulation in human bodies, the radioactive iodine is required to be removed by the Environmental Protection Agency (EPA) and Nuclear Regulatory Commission (NRC). In this presented work, the removal of organic iodides is studied particularly. Unlike that of inorganic iodine, the organic iodides were not well studied because of the low concentrations and the corresponding technical difficulties. Most of the studies on the organic iodides are semi-quantified, focusing on the performances of the adsorption …

Aging Study Of Silver-Exchanged Mordenite And Silver-Functionalized Silica Aerogel In Dry Air, Humid Air, No And No2, Seungrag Choi

Dissertations - ALL

Iodine-129 (129I) is one of the volatile radioactive species in the off-gas streams generated from the spent nuclear fuel reprocessing system, and it is essential to remove 129I vapor because 129I has a long half-life (1.6 x 107 years) and can be fatal to the human body if released to the environment. Radioactive iodine vapor can be effectively captured by silver containing adsorbents such as silver exchanged mordenite (Ag0Z) and silver functionalized silica aerogel (Ag0-aerogel) used in this study. However, the aging impact of off-gas streams on the adsorbents is one of major issues in the removal of radioactive iodine …

Rational Design Of Supported Metal Catalysts For Carbonyl Reduction During Biomass Upgrading, Xin Gao

Dissertations - ALL

Ketone hydrogenation:A model system of carbonyl (ketone) hydrogenation, acetone hydrogenation over supported Pt catalysts in the gas-phase fixed bed reactor was investigated to understand both the mechanism and rate controlling steps in a fundamental level. The experiments and outcomes include the detailed macro- and micro-kinetic analysis of hydrogenation of acetone. The apparent reaction orders of hydrogen and acetone, apparent activation energies, and observed kinetic isotope effects over a large range of temperatures and concentrations (compound partial pressures) are reported in this document. Generally speaking, the ketone hydrogenation over metal surfaces in vapor phase comply with the mechanism that hydrogen atoms …

Substrate Delivery Of Embedded Liposomes, Srivatsan Kidambi, Stephen L. Hayward

Department of Chemical and Biomolecular Engineering: Faculty Publications

This invention relates to compositions useful for localized and sustained release of therapeutic agents, and more particularly to functionalized liposomes embedded in a poly electrolyte multilayer. Methods of preparing the compositions, methods of treating diseases, devices, and pharmaceutical compositions comprising the compositions are also provided.

Real-Time Monitoring Of Cell Death Progress Using Capacitance Spectroscopy, Suyang Wu

Electronic Theses and Dissertations

Biologics, including the monoclonal antibody (mAb), has experienced rapid development in the last decade. However, the price of biologics is often prohibitively high because of the low process efficiency. Delaying the inevitable cell death improves the productivity of upstream bioprocessing, whose success relies on monitoring the cell death onset that indicates the timing for preventive actions.

This study proposes to develop a real-time monitoring model that quantifies the dying cell percentage in lab-scale bioreactors using capacitance spectroscopy. The capacitance spectroscopy contains cell death-related information due to various physical properties changes during the cell death process, e.g., cytoplasmic conductivity change. The …

Development Of Polymeric Cxcr4 Targeting Carriers For Sirna Delivery To Treat Acute Kidney Injury, Weimin Tang

Theses & Dissertations

Acute kidney injury (AKI) is a major kidney disease that is characterized by a sudden loss of renal function which manifests by a decrease in urine output and an increase in serum creatinine. AKI is a global healthcare burden associated with high morbidity, mortality, and increasing cost. Currently there are no effective pharmacological treatments available. Apoptosis induced by p53 has been demonstrated as an important pathological mechanism for the development of AKI. Meanwhile, CXCR4/SDF-1 axis has been associated with the inflammation during AKI, and CXCR4 is overexpressed on injured tubules. This dissertation hypothesized that polycations with CXCR4 targeting ability could …

Interfacial Engineering And Photoelectrochemistry Of Patterned Metal/Semiconductor Heterostructures, Che Tan

McKelvey School of Engineering Graduate Student Theses & Dissertations

Photoelectrochemical (PEC) cells enable the conversion of solar energy into storable fuels, which is critical in overcoming the intermittent nature of this largest renewable source. However, the majority of semiconductors used as photoelectrodes in these cells have low conversion efficiencies and/or stabilities. Silicon (Si) is an attractive semiconductor material for photoelectrodes, but the development of efficient Si-based photoanodes is challenging due to their instability in alkaline solutions. Thus, one focus of this dissertation is the design and fabrication of highly stable nickel (Ni)-patterned Si photoanodes through interfacial engineering of the barrier heights. Recently, hot carriers in plasmonic metal nanostructures have …