Chemical Engineering Commons^™

Would Self-Supported Fracture Contribute To The Hydrocarbon Production In Shale Reservoir Besides Proppant-Supported Fracture, Y. Sun, G. Li, S. Zeng, J. Wu, J. Liu, M. Xu, C. Dai, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

During hydraulic fracturing in deep shale gas reservoirs, it is difficult to pump proppants long distances, and self-supported fractures are formed at the far and upper ends of the fractures. The self-supported fracture could hold the fracture space by its surface structure again fracture closure. However, it faces various aspects of impairment during shale gas reservoir development, which affect its conductivity. Among the impairment, long-term production results in a decline of bottom hole pressure, which will compact the fracture space, and self-supported fractures without proppant are more sensitive than those with proppant. In this paper, we conducted a series of …

Functionalized Microfiltration Membranes For Aerosol Capture To Chloro-Organic Degradation, Rollie George Mills

Theses and Dissertations--Chemical and Materials Engineering

The environmental remediation of water and air sources is a challenging field, due to widespread contamination, pollutant variety, and efficiency of existing treatment options. Remediation of certain pollutants, such as per- and polyfluorinated chemicals (PFAS), polychlorinated biphenyls (PCBs), volatile organic compounds (VOCs), and viral aerosols, has shown promise via adsorptive, degradative, or filtration-based processes, each with their respective advantages and limitations. Membrane technology is one option that has exhibited considerable pollutant removal from environmental sources via reverse osmosis (RO) filtration, but is limited by low permeabilities and lack of pollutant detoxification. With the support of NIEHS and NSF, the functionalization …

Molecular Understanding And Design Of Deep Eutectic Solvents And Proteins Using Computer Simulations And Machine Learning, Usman Lame Abbas

Theses and Dissertations--Chemical and Materials Engineering

Hydrophobic deep eutectic solvents (DESs) have emerged as excellent extractants. A major challenge is the lack of an efficient tool to discover DES candidates. Currently, the search relies heavily on the researchers’ intuition or a trial-and-error process, which leads to a low success rate or bypassing of promising candidates. DES performance depends on the heterogeneous hydrogen bond environment formed by multiple hydrogen bond donors and acceptors. Understanding this heterogeneous hydrogen bond environment can help develop principles for designing high performance DESs for extraction and other separation applications. This work investigates the structure and dynamics of hydrogen bonds in hydrophobic DESs …

Exploring The Effect Of Casting Solution Composition, Additives, And Casting Conditions On The Morphology And Separation Performance Of Pvdf Membranes, Rachel Kaplan

Theses and Dissertations--Chemical and Materials Engineering

Global water scarcity and quality concerns in the past decade have led to a looming global water crisis. Polymeric membranes have emerged as a potential solution due to their modularity, operational reliability, and wide range of contaminant removal. Polyvinylidene fluoride (PVDF) is often selected as a membrane material for its enhanced chemical resistance, thermal stability, and mechanical strength. However, these membranes often require more complex fabrication methods or support materials to achieve optimum performance. Flat-sheet unsupported PVDF membranes were fabricated via nonsolvent induced phase separation. The influence of solvent, polymer composition, pore forming additives, and casting conditions were explored with …

Development Of Glutathione-Responsive Disulfide-Containing Poly(Beta-Amino Esters) With Varied Hydrophilicity And Acrylate Functionality, Anastasiia Aronova

Theses and Dissertations--Chemical and Materials Engineering

Smart biomaterials are becoming promising for therapeutic deliveries due to their ability to respond to changes in the environment. Redox-responsive hydrogels are a promising type of smart polymer that can swell and degrade according to cellular oxidative stress levels. Glutathione, abundant in cells, is crucial in redox-responsive biomaterials, serving as a key reactive molecule. This study explored the degradation kinetics of glutathione-responsive poly(β-amino ester) (PBAE) polymers created through a single-step Michael addition. We examined how disulfide content influences the degradation kinetics of these PBAE networks. Additionally, we investigated how the hydrophilicity and functionality of acrylate affect the degradation of disulfide-containing …

Sustained Release Systems For Endometrial Cancer, Claire E. Rowlands

Theses and Dissertations--Chemical and Materials Engineering

Endometrial cancer (EC) is the sixth most common cancer in women worldwide and is the most common cancer of female reproductive organs. From 2007-2016 there has been a global rise in incidence of EC of 1.3 %. Typically, EC is treated with surgery, but at later stages surgery is less effective requiring chemotherapy and/or radiation therapy. These treatment options are less effective than surgery and there are very few FDA approved chemotherapies for EC. The minuscule number of effective treatment options as well as an increase in incidence shows the need for creating improved treatments for EC. There has been …

Fiber Assisted Re-Assembly Preformed Particle Gel For Conformance Control, Zhe Sun

Masters Theses

"In Enhanced Oil Recovery technology today, gel treatments have been implemented as a cost-effective method to improve the oil sweep efficiency in reservoirs by plugging the high permeability zones. This study presents a novel gel composition to be used in conformance control in order to improve oil recovery for mature oilfields.

The product is a fiber-assist re-assembly preformed particle gel which could be generalized to the preformed particle gels (PPG). The product developed in this study could be injected into the reservoir act as a conformance control agent by plugging water thief zones and channels in the beginning process. Due …

Fe-Ni-Cu-Pge Sulfide Transport Mechanisms And Carbon-Sulfur Interactions In Lower Crustal Magmatic Settings: A Study From The Valmaggia Ultramafic Pipe, Ivrea-Verbano Zone, Italy, Shelby Leann Clark

Masters Theses

"Constraining the processes that control the transport and deposition of sulfides in the deep lithosphere is an important step in expanding ore deposit exploration search space to include exhumed lower crustal rocks. The ultramafic sulfide ore-bearing Valmaggia pipe in the Ivrea-Verbano Zone of NW Italy, an exhumed cross section of the overlying lower continental crust and subcontinental lithospheric mantle, gives critical insight into metallogenic processes in lower crustal settings. The ~300 m wide metasomatized pipe hosts Fe-Ni-Cu-(PGE±Co±Au) sulfide mineralization that is commonly associated with locally abundant carbonates and hydrous silicates (phlogopite, amphibole). Previous studies suggested that sulfides were physically transported …

Impacts Of Key Degradation Byproducts On Amine Scrubbing For Post-Combustion Carbon Capture, Thomas Jorgensen

Theses and Dissertations--Chemistry

The increasing atmospheric CO₂ concentration causes significant concern about global warming and its environmental impact. Industrial sectors, including power generation, transportation, and production factories, contribute most of the anthropogenic sources of CO₂ emissions. Researchers search for methods to mitigate these CO₂ emissions without compromising the benefits of industrial processes, including CO₂ capture, utilization, and sequestration (CCUS). Post-combustion carbon capture (PCCC) by amine scrubbing is the most technology ready CCUS, with various pilot-scale projects worldwide showing small-scale to fully operational plants. While researchers have made significant progress in amine scrubbing, they strive to improve the efficiency and …

Effects Of Electron Beam Irradiation On Crmnv And Crmntiv High Entropy Alloys: Nano-Mechanical, Structural, And Thermodynamic Perspectives, N. A. Sultana, Y. S. Mohammed, S. J. Pendleton, J. Vennekate, G. Ciovati, X. Li, H. Baumgart, A. A. Elmustafa

Mechanical & Aerospace Engineering Faculty Publications

Beam exit windows are crucial components of any particle accelerator as they provide an interface between the beamline vacuum and target material at atmospheric media. For high beam power machines, special materials and designs are required to withstand high radiation and mechanical loads, while minimizing energy loss during transition and maximizing window lifetime. This research investigates the impact of electron beam exposure to bulk CrMnV and CrMnTiV high entropy alloys (HEAs) with the primary goal of identifying suitable candidate materials for the design of robust and durable exit window settings. The selection criteria include intrinsic characteristics, power dissipation, and mechanical …

Engineering Mussel Foot Protein 5 (Mfp5) For Enhanced Adhesive Performance In Tendon And Bone Repair, Ziyue Zhu

McKelvey School of Engineering Graduate Student Theses & Dissertations

This study explores the development of Mussel Foot Protein 5 (MFP5) bioadhesives to improve tendon-to-tendon and tendon-to-bone adhesive outcomes. MFP5, known for its underwater adhesive properties, was synthesized using recombinant techniques and optimized through coacervation and cross-linking. Adhesion tests demonstrated the superior performance of the optimized MFP5 adhesive on the tendon and bone samples. Improved protein concentration testing and purification methods enhanced MFP5 yield and consistency. Future research will focus on further standardization, exploring alternative purification methods, and evaluating the adhesive's performance in animal models. This study lays a foundation for developing robust MFP5-based bioadhesives, potentially revolutionizing surgical repair techniques …

In Vitro Assessment Of The Anti-Biofilm Effectiveness Of Copper And Zinc Enhanced Borate Bioactive Glass Using Processed Microscopic Images, Sarah Fakher, David J. Westenberg

Biological Sciences Faculty Research & Creative Works

The escalating burden of nosocomial infections presents a formidable challenge to healthcare systems worldwide, leading to increased morbidity, prolonged hospital stays, and elevated healthcare costs. These infections are often resistant to conventional antibiotic therapies due to their association with biofilms which contribute to the persistence and resistance of pathogens. In addressing the challenge of biofilm-associated nosocomial infections, borate bioactive glasses (BBGs) have emerged as promising biomaterials. Doping these glasses with antimicrobial metals could potentially harness their antibacterial properties to prevent biofilm formation. This study undertakes a rigorous evaluation of the anti-biofilm efficacy of copper and zinc-doped BBGs by employing processed …

A Concept Of Producing Aluminum In-Situ On The Moon Through Molten Salt Electrolysis, Jacob N. Ortega, Jeffrey Smith, Fateme Rezaei, David Bayless, William Schonberg, Daniel Stutts, Daoru Han

Materials Science and Engineering Faculty Research & Creative Works

This paper presents a concept of producing aluminum in-situ on the lunar surface, namely, the Lunar In-Situ Aluminum Production through Molten Salt Electrolysis (LISAP-MSE) method developed at Missouri University of Science and Technology. This paper aims to demonstrate the use of electro-deoxidation to reduce aluminum oxide (i.e., alumina) into aluminum and oxygen gas via electrolysis in a molten salt bath for the production of aluminum on the Moon. It is shown that with a steady supply of hydrogen chloride, this in-situ resource utilization (ISRU) method could supply several necessary materials consumed in the electro-deoxidation process except hydrogen chloride to produce …

Descriptive Statistical Analysis Of Experimental Data For Wettability Alteration With Smart Water Flooding In Carbonate Reservoirs, Muhammad Ali Buriro, Mingzhen Wei, Baojun Bai, Ya Yao

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Smart water flooding is a promising eco-friendly method for enhancing oil recovery in carbonate reservoirs. the optimal salinity and ionic composition of the injected water play a critical role in the success of this method. This study advances the field by employing machine learning and data analytics to streamline the determination of these critical parameters, which are traditionally reliant on time-intensive laboratory work. the primary objectives are to utilize data analytics to examine how smart water flooding influences wettability modification, identify key parameter ranges that notably alter the contact angle, and formulate guidelines and screening criteria for successful lab design. …

Progress Of Lisap-Mse: A Concept Of Producing Aluminum In-Situ On The Moon Through Molten Salt Electrolysis, Jacob N. Ortega, David Bayless, Daniel Stutts, Daoru Han, Todd P. Sander, Jeffrey Smith, Fateme Rezaei, William Schonberg

Mechanical and Aerospace Engineering Faculty Research & Creative Works

This paper presents a concept of producing aluminum in-situ on the lunar surface, namely, the Lunar In-Situ Aluminum Production through Molten Salt Electrolysis (LISAP-MSE) method developed at Missouri University of Science and Technology. This paper aims to demonstrate the use of electro-deoxidation to reduce aluminum oxide (i.e., alumina) into aluminum and oxygen gas via electrolysis in a molten salt bath for the production of aluminum on the Moon. It is shown that with a steady supply of hydrogen chloride, this in-situ resource utilization (ISRU) method could supply several necessary materials consumed in the electro-deoxidation process except hydrogen chloride to produce …

Method For Continuous Fabrication Of Multi-Functional Nanogels, Hu Yang, Da Huang

Patents

Nanogels and methods of synthesizing and using these nanogels are provided. The nanogels are formed by mixing a building block (e.g., polymer), crosslinker, preferably a target (e.g., biomedical compound or molecule), and a solvent in a multi-inlet vortex mixer, so as to cause the polymer and crosslinker to react and form a chemically crosslinked polymer network. In embodiments including a target, the target will be interspersed in and among that network and can be physically embedded and/or chemically bound therein.

Development Of Tio2/Nh2-Mil-125 Nanocomposite For The Removal Of Ciprofloxacin Under Induced Solar Irradiation, Bilkis Mojisola Ajiwokewu

Theses

This research focuses on the development and application of Metal-Organic Frameworks (MOFs)-based nanocomposites for the photocatalytic removal of pharmaceutical contaminants, with a specific emphasis on ciprofloxacin (CIP). The photocatalytic degradation of CIP was investigated using as-synthesized photocatalysts of TiO₂ nanowires (TiO₂NWs), bare MOF of NH₂-MIL-125, TiO₂NW/NH₂-MIL-125 composite, and Lanthanum (La)-doped composite. Intriguingly, the TiO₂NW/NH₂-MIL-125 composite exhibited the highest efficiency, achieving a photodegradation rate of 0.0111 min-1, surpassing the independent performances of bare MOF of NH₂-MIL-125 and TiO₂NW. The observed efficiency was attributed to …

A Critical Review Of Capillary Pressure Behavior And Characterization In Fractional-Wet Reservoirs, Yihang Xiao, Zhenjiang You, Lei Wang, Zhengtong Du

Research outputs 2022 to 2026

Fractional wettability is common in oil and gas reservoirs, resulting in complex fluid distribution and transport phenomena. A precise understanding of capillary pressure behavior and characterization in fractional-wet reservoirs, including the two-phase flow mechanisms within pores and relationship between capillary pressure and saturation in porous media, is significant to enhanced oil recovery strategies. In this paper, an in-depth review of the two-phase flow mechanisms in fractional-wet pores and capillary entry pressures in various displacement processes was conducted. Furthermore, the effects of oil-wet proportion and contact angle on capillary pressure characterization were summarized, highlighting the emergence of similar capillary pressure curves …

Assessing The Impact Of Geochemical Mechanism And Interpolation Factor Selection On The Precision Of Low-Salinity Waterflooding Modelling: A Comparative Study, Malek Jalilian, Sedigheh Mahdavi, Peyman Pourafshary, Zheinjiang You, Amir H. Mohammadi

Research outputs 2022 to 2026

The efficacy of low salinity waterflooding (LSWF) as an enhanced oil recovery (EOR) method in carbonate formations has been well established; however, its geochemical modelling in such reservoirs remains insufficiently explored. This study aims to bridge this gap by conducting a comparative analysis of three well-recognised geochemical mechanisms including fines migration, rock dissolution/precipitation, and multi-ion exchange (MIE). Our research encompasses two parts: experimental and modelling. First, we conducted four coreflooding experiments to study the effect of LSWF on oil recovery in core scale as well as on rock wettability by measuring the contact angle of the crude oil-brine-rock system. In …

Gradient Microstructures And Mechanical Properties Of Ti–6al–4v Alloy Induced By Laser Surface Quenching, Enqing Wang, Jinpeng Tuo, Fengqi Hou, Dongjie Li, Yuanhang Li, Lvhao Zheng, Kai Zhang, Longlong Dong, Yi Yang, Hao Wang, Aijun Huang, Lai Chang Zhang

Research outputs 2022 to 2026

Laser surface quenching (LSQ) was employed to fabricate gradient microstructures in a Ti–6Al–4V alloy. The influence of the LSQ parameters on the surface morphology, the depth of the LSQ layer, gradient microstructure, and microhardness were investigated. The results showed that as the laser energy density increases, the surface roughness and thickness of the heat-affected zone (HAZ) increase. From the internal matrix to the surface, the microstructure in the HAZ changes from the equiaxed structure to the mixt structure, martensitic structure, Widmanstätten structure, and then the oxide layer. The size of the β grains gradually decreases as the distance from the …

The Phase Behaviour And Stability Of An Environmentally Friendly Oil-In-Water Emulsion Produced Using Balanites Aegyptiaca Oil And Green Emulsifiers, Sami A.M. Yagoub, Swee P. Yeap, Nurudeen P. Yekeen, Mohammed A. Ayoub

Research outputs 2022 to 2026

Due to environmental concerns about extensively using chemical emulsifiers and hydrocarbon oil in emulsion systems formation, recent research has shifted to using natural emulsifiers and oil. This study produced green emulsion using Balanites aegyptiaca oil and various bio-emulsifiers (such as sodium alginate, carboxymethylcellulose, guar gum, and Saponin). Phase behavior and stability of the emulsion were tested at different NaCl concentrations over one month of ageing. The emulsion was also produced using Balanites aegyptiaca oil and synthetic emulsifiers (Tween 80 and Triton X-100). The critical micelle concentrations of emulsifiers were determined and used as the fixed concentration for the green emulsion …

Advancing Natural Hydrogen Exploration: Headspace Gas Analysis In Water-Logged Environments, Krista Davies, Lionel Esteban, Alireza Keshavarz, Stefan Iglauer

Research outputs 2022 to 2026

Natural hydrogen has gained prominence as a potential contributor to the low-carbon energy landscape; however, exploration techniques are still evolving. Current methods primarily rely on dry soil gas studies or gas vent measurements. Because gas vents are scarce and groundwater inhibits hydrogen gas flux from the soil, other field detection techniques are necessary. This research paper presents a novel approach for advancing natural hydrogen exploration through the analysis of headspace gas of agitated groundwater extracted from dedicated shallow boreholes to better estimate the hydrogen gas flux and its variations with time. Several shallow boreholes were drilled in Western Australia on …

A Bi-Functional Air Electrode Developed From A Dual-Mof Strategy For High-Performance Zinc-Air Batteries, Yasir Arafat, Muhammad Rizwan Azhar, Yijun Zhong, Xiaomin Xu, Moses O. Tadé, Zongping Shao

Research outputs 2022 to 2026

A durable, high-performing and cost-effective bi-functional catalyst toward oxygen reduction/evolution reactions (ORR/OER) is the key towards the practical application of Zn-air batteries (ZABs). Here, we report a new concept of combining pristine and carbonized MOFs for developing a bifunctional electrocatalyst for ZABs, where the pristine MOF acts as a support for the OER catalysts and the carbonized MOF acts as the ORR catalyst and enhances the electronic conductivity. By electroless NiP-plating over the surface of the Fe-containing 3D MOF (MIL-100), the catalyst shows superior activity for the OER, delivering a current density of 10 mA cm⁻² at an overpotential …

Green Synthesis Of Nanomaterials For Smart Biopolymer Packaging: Challenges And Outlooks, Shima Jafarzadeh, Majid Nooshkam, Masoumeh Zargar, Farhad Garavand, Sabyasachi Ghosh, Milad Hadidi, Mehrdad Forough

Research outputs 2022 to 2026

There are several physical and chemical methods for synthesizing nanomaterials, while the most appropriate techniques involve using green chemistry and eco-friendly material. Recently, green synthesized materials for different applications have gained attention as a result of their environmental friendliness and cost-effectiveness. Applying green synthesized nanoparticles (NPS) in food packaging has been extensively investigated. Biopolymers require filler to enhance the optical, barrier, thermal, antimicrobial, and mechanical properties of packaging. Biopolymer packaging incorporated with green synthesized NPs is expected to simultaneously enhance performance while reducing environmental damage. The current review article focuses on biopolymer films with bio (green)-synthesized nanomaterials and their effectiveness …

Magnetic Separation Of Lunar Regolith Simulants With Applications To In Situ Resource Utilization On The Moon, Peter Bachle, Jeffrey Smith, Fateme Rezaei, David Bayless, William Schonberg, Daoru Han

Materials Science and Engineering Faculty Research & Creative Works

The development of in situ resource utilization (ISRU) for metal extraction is imperative as a steppingstone for habitation construction in lunar and non-terrestrial environments. Separation of minerals by chemical composition is important to optimize metal and oxygen liberation from lunar ore. to this effect, devices capable of separating aluminum bearing minerals from iron-bearing minerals from the lunar regolith simulants have been developed. Twenty-eight different simulants have been used in this study. a dual-belt separator was designed to reduce middlings. Para-magnetic minerals were reliably separated using a neodymium N52-magnet-separator system. Effective separation of aluminum-bearing minerals from iron-bearing minerals was greater than …

Beneficiation Of Lunar Regolith Simulants Through Electrostatic Sieving And Magnetic Separation, Peter Bachle, Jeffrey Smith, Fateme Rezaei, David Bayless, William Schonberg, Daoru Han

Materials Science and Engineering Faculty Research & Creative Works

In the light of future development of lunar structures, in-situ feldspar beneficiation is imperative for metal extraction. This research incorporates the tandem use of electrostatic sieving and magnetic separation for collecting a specific size range and mineral composition from lunar soil that optimizes subsequent chemical processing. While earlier works focused on silt-sized particles, this work expands that range up to medium-grained sand with a greater variety of potential lunar regolith compositions. This work shows that a 2.5 kV, 7 Hz to 30Hz frequency, single-phase square wave can lift silt and fine sand for collection. This lifting is successful directly from …

Kinetic Modeling Of Electrostatic Sieving For Lunar Regolith Beneficiation: Case Studies, Easton Ingram, Emmanuela Amen Eze, Jeffrey Smith, Fateme Rezaei, David Bayless, William Schonberg, Daoru Han

Materials Science and Engineering Faculty Research & Creative Works

A new kinetic particle modeling framework was developed to investigate electrostatic transport of lunar regolith particles with applications to the concept of electrostatic sieving. The new approach is based on kinetic particle dynamics and includes major modules of sampling the particle size distribution, solving electric fields, and tracking motion of charged dust grains. Case studies for a concept of electrostatic sieving were chosen to validate the new model. The simulation achieved similar yields reported in previous works, which served as validation of the model. The new model is computationally efficient and could serve as a design, analysis, and optimization tool.

Evaluation Of Novel Preformed Particle Gel System For Conformance Control In Mature Oil Reservoirs, Abdulaziz Almakimi, Ahmed Ben Ali, Ibnelwaleed A. Hussein, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

To address challenges associated with excessive water production in mature oil reservoirs, this study introduces a carboxymethyl cellulose (CMC)-based material as a novel preformed particle gel (PPG) designed to plug excessive water pathways and redistribute the subsequent injected water toward unswept zones. Through microwave-assisted grafting copolymerization of CMC with acrylamide (AM), we successfully generated multi-sized dry particles within the range of 250–800 µm. Comprehensive analyses, including Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM), have confirmed the chemical composition and morphology of the resulting carboxymethyl cellulose-grafted crosslinked polyacrylamide (CMC/PAMBA). Swelling kinetics and rheology tests were conducted to confirm the …

Kinetic Modeling Of Electrostatic Sieving For Lunar Regolith Beneficiation: Case Studies, Easton Ingram, Emmanuela Amen Eze, Jeffrey Smith, Fateme Rezaei, David Bayless, William Schonberg, Daoru Han

Materials Science and Engineering Faculty Research & Creative Works

A new kinetic particle modeling framework was developed to investigate electrostatic transport of lunar regolith particles with applications to the concept of electrostatic sieving. the new approach is based on kinetic particle dynamics and includes major modules of sampling the particle size distribution, solving electric fields, and tracking motion of charged dust grains. Case studies for a concept of electrostatic sieving were chosen to validate the new model. the simulation achieved similar yields reported in previous works, which served as validation of the model. the new model is computationally efficient and could serve as a design, analysis, and optimization tool.

Triphlapan: Predicting Hla Molecules Binding Peptides Based On Triple Coding Matrix And Transfer Learning, Meng Wang, Chuqi Lei, Jianxin Wang, Yaohang Li, Min Li

Computer Science Faculty Publications

Human leukocyte antigen (HLA) recognizes foreign threats and triggers immune responses by presenting peptides to T cells. Computationally modeling the binding patterns between peptide and HLA is very important for the development of tumor vaccines. However, it is still a big challenge to accurately predict HLA molecules binding peptides. In this paper, we develop a new model TripHLApan for predicting HLA molecules binding peptides by integrating triple coding matrix, BiGRU + Attention models, and transfer learning strategy. We have found the main interaction site regions between HLA molecules and peptides, as well as the correlation between HLA encoding and binding …