Chemical Engineering Commons^™

Oxidative Cleavage Of Oleic Acid At High Temperature Under Autogenous Pressure, Nichkamon Suwannit

Chulalongkorn University Theses and Dissertations (Chula ETD)

The oxidative cleavage of oleic acid to produce azelaic acid and nonanoic acid, both of which are high-value chemicals and essential precursors in the pharmaceutical and plastic industries, was investigated. The objectives of this study were to examine the influence of temperature on reaction mechanisms, product formation, and reaction efficiency, as well as to optimize the reaction conditions for potential industrial applications. The research utilized hydrogen peroxide (H2O2) as the oxidizing agent, tungsten oxide (WO3) as the catalyst, and tert-butanol as a co-solvent under self-generated autogenous pressure conditions. The temperature range studied was 80 to 160°C, aiming to evaluate the …

Uv-Enhanced Catalytic Oxidative Cleavage Of Oleic Acid., Trinnasit Wittayakullertsin

Chulalongkorn University Theses and Dissertations (Chula ETD)

Oleic acid, a key component of plant oils such as palm oil, is a versatile feedstock for producing high-value bio-based chemicals. Utilizing its potential aligns with Thailand's objective of promoting sustainability as a premier palm oil producer. The conventional oxidative cleavage of oleic acid typically requires extreme conditions, including high temperatures, and ozone, which are expensive and harmful to the environment. This research provides an innovative method for utilizing ultraviolet (UV) radiation to increase oxidative cleavage at low temperatures (below 80°C). It employs hydrogen peroxide (H2O2) as an oxidizing agent and tungsten trioxide (WO3) as a catalyst to generate hydroxyl …

Ultrafine Fully Vulcanized Natural Rubber Modified By Grafting With Methyl Methacrylate Monomer As Toughening Modifiers For Polylactic Acid, Panyawutthi Rimdusit

Chulalongkorn University Theses and Dissertations (Chula ETD)

This work focused on toughening polylactic acid (PLA) with an abundant and sustainable bio-based filler from natural rubber. Deproteinized natural rubber (DPNR) was modified by grafting with methyl methacrylate monomer (MMA) and further crosslinked via e-beam irradiation and spray drying to achieve ultrafine fully vulcanized powdered natural rubber grafted with polymethylmethacrylate (UFPNR-g-PMMA) to solves in the challenges of incompatibility between the DPNR and PLA. Interestingly, UFPNR-g-PMMA showed no agglomeration between rubber particles compared to that of neat UFPNR which showed partial agglomeration after irradiation crosslinking. The flexural toughness shows a significant improvement (351%) to 11280 ± 1522 kJ/m3 compared to …

Development Of Silica-Based Support Material From Sugarcane Bagasse Ash For Synthesis Of Carbon Nanotubes, Maturada Assawagetmanee

Chulalongkorn University Theses and Dissertations (Chula ETD)

Sugarcane bagasse ash (SCBA), an abundant agricultural residue, is converted into high-value silica powder through a novel route involving calcination and acid leaching. This transformative process not only valorizes waste biomass but also yields silica nanoparticles with tailored microstructural properties suitable for application in carbon nanotube (CNT) production. The resultant silica powder was utilized as a catalyst support impregnated with Fe nanocatalyst for synthesizing CNTs from benzene. The effective route with a process sequence of 1 M HCl acid leaching followed by calcination could provide silica powder with a specific surface area of 12.29 m2/g, which could accommodate Fe nanocatalyst …

Parametrization Of Fluid Models For Electrical Breakdown Of Nitrogen At Atmospheric Pressure, Shirshak K. Dhali

Electrical & Computer Engineering Faculty Publications

In the transient phase of an atmospheric pressure discharge, the avalanche turns into a streamer discharge with time. Hydrodynamic fluid models are frequently used to describe the formation and propagation of streamers, where charge particle transport is dominated by the creation of space charge. The required electron transport data and rate coefficients for the fluid model are parameterized using the local mean energy approximation (LMEA) and the local field approximation (LFA). In atmospheric pressure applications, the excited species produced in the electrical discharge determine the subsequent conversion chemistry. We performed the fluid model simulation of streamers in nitrogen gas at …

Development Of Tio2/Nh2-Mil-125 Nanocomposite For The Removal Of Ciprofloxacin Under Induced Solar Irradiation, Bilkis Mojisola Ajiwokewu

Theses

This research focuses on the development and application of Metal-Organic Frameworks (MOFs)-based nanocomposites for the photocatalytic removal of pharmaceutical contaminants, with a specific emphasis on ciprofloxacin (CIP). The photocatalytic degradation of CIP was investigated using as-synthesized photocatalysts of TiO₂ nanowires (TiO₂NWs), bare MOF of NH₂-MIL-125, TiO₂NW/NH₂-MIL-125 composite, and Lanthanum (La)-doped composite. Intriguingly, the TiO₂NW/NH₂-MIL-125 composite exhibited the highest efficiency, achieving a photodegradation rate of 0.0111 min-1, surpassing the independent performances of bare MOF of NH₂-MIL-125 and TiO₂NW. The observed efficiency was attributed to …

Characterization Of Antibody Repertoires Developed From Naive And Recall Responses, Nicholas C. Curtis

Dartmouth College Ph.D Dissertations

Adaptive immunity, comprised in part by the antibody repertoire, is the cornerstone of our ability to remain healthy amongst the plethora of pathogenic challenges we encounter daily. Despite the importance of understanding antibody repertoire development, much remains unknown about the composition and evolution of circulating antibodies in response to viral challenges. To better understand antibody repertoire development, we profiled the serum antibody repertoire using a combination of next-generation sequencing and serum antibody proteomics in the predominantly naïve response against SARS-CoV-2 spike and the recalled response to influenza hemagglutinin. The response to SARS-CoV-2 spike in four convalescent individuals was diverse (consisting …

Assessing The Feasibility And Mechanism Of Destructive Removal Of Per- And Polyfluoroalkyl Substances (Pfas) From Water, Kaushik Vinaykumar Londhe

Dissertations

One of the most pertinent challenges faced by the drinking water community is the widespread contamination of per- and polyfluoroalkyl substances (PFAS). These anthropogenic chemicals have been ubiquitously used in everyday products such as carpets, stain repellents, dyes, shampoos, non-stick cookware as well as in aqueous firefighting foams. PFAS are linked with adverse health effects in humans such as thyroid disease, obesity, immunological and reproductive disorders and linked to cancer in adults and low birth weight and developmental defects in infants.

Conventional water treatment technologies have proven to be largely ineffective in PFAS remediation, due to their extreme stability and …

Classification Of Oil Products According To The Nomenclature Of Goods, Kurbankul Mavlankulovych Karimkulov Profesor, Azoda Abdurahmanova

Technical science and innovation

The article analyzes types of vegetable oils. Simple methods of determining their quality using liquid gas chromatography have been developed. Recommendations for improving the classification of foreign economic activity based on commodity nomenclature were developed and recommended for customs operations. “Fats and oils of animal, vegetable or microbiological origin and products of their breakdown; prepared edible fats; waxes of animal or vegetable origin” was called. Animal fats, including pork, beef, sheep, goat, fish and oils of animals such as marine mammals are classified according to the Nomenclature of Foreign Economic Activities of the Republic of Uzbekistan in commodity headings 1501-1506 …

Advancing Polymer Sustainability Through Custom Interpenetrating Polymer Network Synthesis, Processing, And Design, Alexandra Maria Lehman-Chong

Theses and Dissertations

The need for improving polymer sustainability is as ubiquitous as the role of polymers in modern society. Interpenetrating polymer network (IPN) design flexibility offers opportunities for improved polymer sustainability while balancing desired polymer properties for various applications. This work investigates the structure-property-processing relationships of IPNs judiciously designed under the framework of the polymer life cycle. Sustainable polymer design was largely considered at the feedstock and manufacturing stages while considering overall polymer performance. Chemicals from bio-based feedstocks were used to design a full simultaneous polybenzoxazine-epoxy IPN, focusing on the effects of monomer and polymer structure on polymer properties. Processing-property relationships were …

Improvement Of Calorimetric Quality Analyzers For Substances, Makhfuza Azimovna Radjabova

Chemical Technology, Control and Management

It is noted that the development of intelligent means of measuring qualitative indices is of topical importance. Since the quality of many substances is determined by optical methods, an algorithm for spectrophotometric data processing has been developed, which consists of primary data processing (stage I) and determination of qualitative indices of liquid products (stage II). Since the task of numerical determination of colour characteristics of transmittance coefficients of liquid samples is incorrectly set, it is recommended to use regularization methods of A.N.Tikhonov to improve metrological characteristics of the device. On the basis of regularization methods for solving incorrect problems, algorithms …

Reducing Food Scarcity: The Benefits Of Urban Farming, S.A. Claudell, Emilio Mejia

Journal of Nonprofit Innovation

Urban farming can enhance the lives of communities and help reduce food scarcity. This paper presents a conceptual prototype of an efficient urban farming community that can be scaled for a single apartment building or an entire community across all global geoeconomics regions, including densely populated cities and rural, developing towns and communities. When deployed in coordination with smart crop choices, local farm support, and efficient transportation then the result isn’t just sustainability, but also increasing fresh produce accessibility, optimizing nutritional value, eliminating the use of ‘forever chemicals’, reducing transportation costs, and fostering global environmental benefits.

Imagine Doris, who is …

Modeling Of Amine-Based Co2 Capture Process, Zafar Safarovich Turakulov

Chemical Technology, Control and Management

A significant factor influencing climate change is the release of carbon dioxide (CO₂) into the atmosphere as a consequence of human activities such as the combustion of fossil fuels. Climate change can be slowed down by taking action to mitigate industrial-scale CO₂ emissions. Currently, the most advanced technology for capturing CO₂ from industrial flue gases is the post-combustion CO₂ capture based on amine absorption. However, due to the high energy penalties of existing CO₂ capture technologies and insufficient carbon markets, it is necessary to develop methods that compete with these technologies or minimize their …

Algorithms For Synthesis Of Adaptive Control Systems With A Customized Model Using The Speed Gradient Method, Jasur Sevinov, Oxunjon Boborayimov

Chemical Technology, Control and Management

Algorithms are considered for the synthesis of adaptive control systems with a customized model based on the speed gradient method. For the synthesis of adaptive control systems, the identification approach is based on obtaining estimates of the unknown parameters in the object. By calculating the speed gradient, identification algorithms with an explicit and implicit customized model were obtained as well as that in sliding modes. A joint solution is given to the interrelated problems of identifying parameters with insufficient current information. The position of an object is about assessing the state with insufficient a priori information about its parameters. This …

Life Cycle Management Of A Technological Complex For Separating Multicomponent Mixtures Under Conditions Of Uncertainty Of Parameters, Yusuf Shodievich Avazov

Chemical Technology, Control and Management

The issue of control the lifecycle of technological complexes of multicomponent mixtures is considered, taking into account the uncertainty of parameters. Among uncertainties such as parameter uncertainty, model uncertainty, choice uncertainty under variability, spatial variability uncertainty, temporal variability uncertainty, inter-site variability uncertainty, more attention is paid to input parameter uncertainty and action uncertainty. The rectification technology is schematically presented, the influence of parameter uncertainty on the technological functions of the rectification complex. The scheme analyzes the control and assessment of “uncertainty” to repeat the lifecycle of the rectification complex and make changes to the components of the rectification complex technology. …

Mathematical Models And Calculation Of Parameters Of Optoelectronic Angular Displacement Converters, Yuriy Gennadyevich Shipulin, Azimjon Khusanov

Chemical Technology, Control and Management

The article discusses promising optoelectronic converters (OP) for wide application of angular movements. A methodology and diagram for calculating OP with the transverse movement of a moving element is presented; in order to simplify the calculation, the weight range of angular movements is conventionally divided into three sub ranges. A graph is given of the dependence of the area of the photosensitive surface of a photo resistor made from a single crystal of high-resistivity p-type silicon.

Intelligent Decision Support System, Khurshid Salim Ugli Turayev

Chemical Technology, Control and Management

The article studies issues related to the development of intelligent systems located in an environment capable of perceiving this environment and acting autonomously to achieve assigned tasks. To create an intelligent process control system, it is necessary to monitor the mode to ensure high quality of finished products with minimal energy consumption at a given productivity of the entire complex. It is important to have a flow of input data to provide the system with operational information to support decision making.

The proposed intelligent control system makes it possible to analyze the results of production activities to make organizational and …

The Use Of Ultraviolet Radiation As A Means Of Destroying Microorganisms In Cherries, Jasur Safarov, Shaxnoza Sultanova, Pulatov M. Murodjon

Chemical Technology, Control and Management

The article discusses methods for extending the shelf life of cherries, having previously treated it with an ultraviolet ray. The article also presents the results obtained, which prove that the shelf life of cherries exposed to ultraviolet increases. At the same time, the article describes in detail the processing technique and presents the results of research.

Study Of Dynamic Characteristics Of The Mechanical Circuit Of The Developed Induction Inertial Vibration Transducer, Sulton Fayzullayevich Amirov, Asror Abdunabiyevich Shoimkulov

Chemical Technology, Control and Management

The article examines the dynamic characteristics of the mechanical circuit of the developed induction vibration transducer. It is found that in the investigated transducers forced oscillations occur with the frequency of the input disturbing force, the amplitude of forced oscillations does not depend on the initial conditions and time, and in forced oscillations with damping there is always a shift of the oscillation phase compared to the phase of the input disturbing force. It is shown that the induction vibration transducer reproduces the measured vibrations with small distortions only in a relatively narrow frequency region at frequencies of the input …

Improvements Of The Control System For The Technological Process Of Drying Bulk Materials, Azizbek Nodirbekovich, Dilmurod Ikromovich

Chemical Technology, Control and Management

The issues of convective drying of bulk materials as objects of monitoring, control and advanced management are presented based on the results of simulation modeling of a complex heat and mass transfer process, taking into account the drying kinetics. As a result of the work of a number of them, in the last few decades neat hypotheses were formed about moisture migration in and around dried materials, which led to the creation of accurate mathematical models of drying behavior, with successfully applied in a wide range of fields. The reasons for this are the dynamics of processes in the drying …

Application Of Quantum Algorithms In The Synthesis Of Dynamic Objects, Noilakhon Yakubova

Chemical Technology, Control and Management

Around the world, the food industry is focusing on achieving energy and resource efficiency. One of the main challenges in the field of process automation is the creation of effective control systems using intelligent technologies to improve the quality of processes and achieve the production of high-quality products with less energy and resources. Therefore, it is necessary to work with a large amount of data. Particular attention is paid to the development of computational algorithms for automated high-speed computational analysis systems for processing this data at high speed. Therefore, the article discusses the use of quantum computing methods in controlling …

System For Advanced Control Of Thermal Parameters Of Glass Furnaces, O'Tkir Xolmanov

Chemical Technology, Control and Management

The results of an analysis of the functioning of glass furnaces for melting semi-white or discolored glass as an object of automatic control and management are presented. Through experimental research, a parametric control scheme for a glass melting furnace was formed and a system for improved control of thermal glass melting processes was synthesized. The proposed system regulates the parameters of a furnace with a horseshoe-shaped flame development. Based on commercially produced instruments and automation equipment that ensure stabilization of thermal conditions of glass melting. The burner block control algorithm provides control over the performance of the gas burner, safety …

Electrochemical Performance Of Porous Ceramic Supported Tubular Solid Oxide Electrolysis Cell, Heng-Ji Wang, Wen-Guo Chen, Zhou-Yi Quan, Kai Zhao, Yi-Fei Sun, Min Chen, Ogenko Volodymyr

Journal of Electrochemistry

Solid oxide electrolysis cell (SOEC) is an efficient and clean energy conversion technology that can utilize electricity obtained from renewable resources, such as solar, wind, and geothermal energy to electrolyze water and produce hydrogen. The conversion of abundant intermittent energy to hydrogen energy would facilitate the efficient utilization of energy resources. SOEC is an all-ceramic electrochemical cell that operates in the intermediate to high temperature range of 500–750 ℃. Compared with traditional low temperature electrolysis technology (e.g., alkaline or proton exchange membrane cells operating at ~100 ℃), the high-temperature SOEC can increase the electrolysis efficiency from 80% to ~100%, providing …

An In-Situ Raman Spectroscopic Study On The Interfacial Process Of Carbonate-Based Electrolyte On Nanostructured Silver Electrode, Yu Gu, Yuan-Fei Hu, Wei-Wei Wang, En-Ming You, Shuai Tang, Jian-Jia Su, Jun Yi, Jia-Wei Yan, Zhong-Qun Tian, Bing-Wei Mao

Journal of Electrochemistry

The solid-electrolyte interphase (SEI) plays a key role in anodes for rechargeable lithium-based battery technologies. However, a thorough understanding in the mechanisms of SEI formation and evolution remains a major challenge, hindering the rapid development and wide applications of Li-based batteries. Here, we devise a borrowing surface-enhanced Raman scattering (SERS) activity strategy by utilizing a size optimized Ag nanosubstrate to in-situ monitor the formation and evolution of SEI, as well as its structure and chemistry in an ethylene carbonate-based electrolyte. To ensure a reliable in-situ SERS investigation, we designed a strict air-tight Raman cell with a three-electrode configuration. Based on …

Isolation And Characterization Of Caffeine-Degrading Bacteria From Coffee Plantation Areas In Malaysia, Elvina Clarie Dullah, Mohd Fazli Farida Asras

Makara Journal of Technology

Decaffeination by microbial degradation is currently the most optimal and low-cost approach, involving only microbial cells and/or their enzymes. The bacterium was characterized using a series of biochemical tests. Positive results were obtained from carbohydrate fermentation, citrate utilization, and catalase tests, while negative results were obtained from Voges-Proskauer (VP) and indole tests. Three different caffeine concentrations of 0.25%, 0.4%, and 2% were tested and measured through Gas Chromatography-Mass Spectrophotometry (GC-MS) analysis. The highest caffeine reduction (89.25%) was found when 0.25% caffeine was used in the media. Only a small amount of caffeine was reduced to 0.4% and 2%, with 34.78% …

Combined Risk Based Inspection And Fault Tree Analysis For Repetitive 3-Phase Line Piping Leakage At West Java Offshore Topside Facility, Dona Yuliati, Akhmad Herman Yuwono, D. Rizal Asral, Donanta Dhaneswara

Journal of Materials Exploration and Findings

Hydrocarbon releases might result in serious consequences in various aspects. In addition to the contribution to environmental pollution, repetitive leakages need high repair costs. This study aim is to minimize potential repetitive leakage for other typical 3-phase piping systems. We conducted the risk assessment by adopting Risk Based Inspection (RBI) API 581 to identify risk level, calculating piping lifetime, recommended inspection plan and mitigations. The most relevant root causes can be obtained through quantitative Fault Tree Analysis (FTA). Observation and investigation was taken from eight 3-phase piping systems that experienced repetitive leakages. It has been found that the risk level …

Nitrogen Gas Quenching Pressure Effect On Bs S155 Alloy Steel In Vacuum Furnace, Agus Mulyadi Hasanudin, Eddy Sumarno Siradj

Journal of Materials Exploration and Findings

The production of metal and alloy products requires the use of heat treatment, when during the heat treatment process, quenching is a crucial step. The quenching medium can be anything from water, a salt bath, oil, air and gas. In a vacuum furnace, pressurized gas, most frequently nitrogen (N₂) gas, serves as one of the quenching mediums. One of the drawbacks of the quenching process is the distortion and dimensional change of the parts. This paper aims to investigate the influence of nitrogen gas quenching pressure on the distortion and dimensional change of aerospace actuator gear planet parts …

Optimization Of The Building Envelope And Roof Shading To Reduce The Energy Consumption Of College Low-Rise Buildings In Indonesia, Nasruddin Nasruddin, Azimil Gani Alam, Mohammad Imroz Sohel

Makara Journal of Technology

Energy consumption in buildings is a crucial concern globally, prompting researchers to explore innovative solutions to mitigate its impact. This study investigates the optimization of building envelopes and roof shading systems of existing buildings in Indonesia to realize notable energy savings. Multiple scenarios were explored, with modifications to building envelopes and roof shading, highlighting the overall thermal transfer value as a key parameter. Using EnergyPlus simulations, the efficacy of natural ventilation in corridors and roof shading modifications was assessed in reducing energy consumption. The findings revealed that renovating existing buildings by optimization of the building envelope and roof shading by …

Robust Gasification Trial Results For A Variety Of Difficult-To-Recycle Packaging-Related Materials, Bruce A. Welt

Journal of Applied Packaging Research

Currently, recycling requires nearly absolute sorting of materials to accommodate the limited capabilities of existing recycling infrastructure. Whether a material is “recyclable” depends more on the method of recycling than the material itself. Our dependence upon sorting has limited success of recycling and has stifled our ability to achieve circular economy sustainability with plastic packaging materials. Our dependence upon sorting is rooted in our material-specific recycling processes. However, newer robust recycling processes are commercially available that reduce or eliminate the need to sort waste, and can convert mixed waste into primary feedstock chemicals, such as methanol for subsequent manufacture of …

The Role Of Interactive Spaces In Enhancing Social Interaction Of Children In Orphanage Institutions, Zainab Khalid Rashad Al Khafaji, Shamael M. W. Al Dabbagh

Al-Esraa University College Journal for Engineering Sciences

The child who moves to an environment outside his family environment, suchas orphanage institutions because of the loss of one or all of his family members, itis obvious that he feels a kind of alienation and isolation from his peers and a loss ofa sense of interaction and communication with society, so it is possible to mitigatethis feeling by promoting diversity in interactive activities within the internal spacesof the orphanage institutions and at the neighborhood level, the research problemwas represented by "the lack of clarity in the nature of knowledge aboutthe role of of interactive spaces in enhancing social interaction …