Chemical Engineering Commons^™

Genetically Linked Litho- And Organo-Facies In Meter-Scale Cycles Of Lacustrine Deposits Within The Permian Lucaogou Formation In The Bogda Mountains, Northwest China: Implications For Paleoenvironment And Organic Matter Origin, Xin Zhan, Wan Yang, Qiao Feng, Zhao Wen Zhan, Sile Wei, Yujiao Zhang, Hongquan Kang, Tao Cheng, Hongyan Zhao, Wenjie Cai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

A close correlation between lithofacies and organofacies in meter-scale high-order cycles composed of lacustrine sediments enables comparison and refinement of lithofacies-defined cyclostratigraphy. Four lithofacies and four organofacies have been identified in fluctuating profundal high-order cycles in the lower-Permian Lucaogou Formation, southern Bogda Mountains, NW China. The four lithofacies include interbedded and interlaminated coarse siltstone and very fine sandstone, black shale, wackestone and dolostone, and calcareous and dolomitic shales. Four distinctive organofacies have been identified, on the basis of geochemical composition of organic matter and specific biomarker proxies related to organic matter types, rather than to depositional conditions and thermal maturity. …

Nanofluid-Assisted Enhanced Sealing Security For Efficient Geological Hydrogen Storage In Saudi Arabian Basalt, Muhammad Ali, Nurudeen Yekeen, Sarmad Al-Anssari, Aliakbar Hassanpouryouzband, Alireza Keshavarz, Hussein Hoteit

Research outputs 2022 to 2026

The modification of hydrophobic rock surfaces to the water-wet state via nanofluid treatment has shown promise in enhancing their geological storage capabilities and the efficiency of carbon dioxide (CO2) and hydrogen (H2) containment. Despite this, the specific influence of silica (SiO2) nanoparticles on the interactions between H2, brine, and rock within basaltic formations remains underexplored. The present study focuses on the effect of SiO2 nanoparticles on the wettability of Saudi Arabian basalt (SAB) under downhole conditions (323 K and pressures ranging from 1 to 20 MPa) by using the tilted plate technique to measure the contact angles between H2/brine and …

Hydrogen Wettability Of Saudi Arabian Basalt: Implications For H2 Geo-Storage, Muhammad Ali, Nurudeen Yekeen, Mujahid Ali, Amer Alanazi, Muhammad Shahzad Kamal, Alireza Keshavarz, Hussein Hoteit

Research outputs 2022 to 2026

The large-scale subsurface storage of hydrogen is a crucial element of the hydrogen economy value chain and is an essential process for achieving the successful replacement of carbon-based fuels. The wettability of the rock-H2-brine system, as quantified by contact angle measurement, has been the focus of most recent research due to its impacts on fluid flow, H2 migration and recovery efficiency during underground hydrogen storage (UHS). However, the reported contact angle data sets are quite inconsistent, and there are relatively few literature reports regarding the contact angles of H2/brine on Saudi Arabian basalt (SAB) compared to the contact angle data …

A Novel Hybrid Enhanced Oil Recovery Technique To Enhance Oil Production From Oil-Wet Carbonate Reservoirs By Combining Electrical Heating With Nanofluid Flooding, Farida Amrouche, Martin J. Blunt, Stefan Iglauer, Farid Aiouache, Michael Short

Research outputs 2022 to 2026

Enhanced Oil Recovery provides a promising technique to maximise fossil fuel recovery from existing resources, and when used in conjunction with Carbon Capture and Storage/Utilisation provides a way to support a transition to alternative cleaner fuels. A hybrid Enhanced Oil Recovery method by a combination of electrical heating and nanofluid flooding was applied to oil-wet carbonate reservoirs and assessed in terms of the oil production, zeta potential, contact angle, pellet compaction, interfacial tension, and pH values. The hybrid technique consisted of a combination of direct current (up to 30 V) and iron oxide (Fe2O3) or magnesium oxide (MgO) nanofluids. Both …

Sub-Rapid Solidification Microstructure Characteristics And Control Mechanisms Of Twin-Roll Cast Aluminum Alloys: A Review, Xian Wu, Zhi Ping Guan, Hong Yu Yang, Bai Xin Dong, Lai Chang Zhang, Jia Meng, Chang Jie Luo, Cheng Gang Wang, Kuang Cao, Jian Qiao, Shi Li Shu, Jie Kang, Ming Zhu, Feng Qiu, Qi Chuan Jiang

Research outputs 2022 to 2026

Rapid growth in industrial sectors such as automotive and shipbuilding has highlighted the significance of strip casting technology to produce lightweight alloys, particularly aluminum alloys widely used in both industrial production and daily life. Twin-roll casting (TRC), as an economically and environmentally friendly method for slab/strip production and processing, has attracted significant interest from researchers. However, the development of TRC aluminum alloys faces many challenges due to limited understanding of microstructural characteristics and control mechanisms. To further enhance comprehension of TRC aluminum alloys, this article reviews the influencing parameters, control methods, and existing issues related to TRC sub-rapid solidification (SRS) …

Evaluation Of The Mechanical Properties Of Pla Material Used For 3d Printing Solar E-Hub Component, Md Helal Uddin, Mohammad Nur-E-Alam, Abreeza Manap, Boon Kar Yap, Md Rokonuzzaman

Research outputs 2022 to 2026

The advent of additive manufacturing (AM) technologies revolutionized design and production processes across various industries. In renewable energy, AM enabled new possibilities for optimizing solar e-hub (solar energy harvesting module) configurations, enhancing efficiency and performance. This study examined critical considerations such as material selection, durability, and cost-effectiveness in solar hub development. This fast-prototyping technique was controlled by computer-aided design (CAD) software like CREO Parametric 7.0 and Creality Slicer 4.8. Experimental results indicated that PLA (Polylactic acid) materials exhibited superior strength, with an impact energy of 4.8 Joules. The deformation study revealed that the maximum load of 22 MPa aligned with …

Microplastics And Dye Removal From Textile Wastewater Using Mil-53 (Fe) Metal-Organic Framework-Based Ultrafiltration Membranes, Javad Farahbakhsh, Mohadeseh Najafi, Mitra Golgoli, Abdul Hannan Asif, Mehdi Khiadani, Amir Razmjou, Masoumeh Zargar

Research outputs 2022 to 2026

Microplastics (MPs) and other organic matters in textile wastewater have posed a formidable challenge for treatment processes, particularly in the primary stages such as ultrafiltration (UF). UF plays a crucial role in preventing the entry of pollutants into subsequent treatment steps. However, the performance efficiency of UF membranes is compromised by the potential fouling of membrane pores by MPs, dyes and other organic pollutants such as bovine serum albumin (BSA). This study focuses on enhancing UF membrane performance, specifically its antifouling properties, through the development of high-performance membranes using MIL-53(Fe) metal-organic framework (MOF) particles (noted as MIL-53 here). Various concentrations …

Analysis Of The Thermal Aging Kinetics Of Tallow, Chicken Oil, Lard, And Sheep Oil, Yun-Chuan Hsieh, Hao Ouyang, Yulin Zhang, Donyau Chiang, Fuqian Yang, Hsin-Lung Chen, Sanboh Lee

Chemical and Materials Engineering Faculty Publications

Understanding the thermal aging kinetics of animal oils is of vital importance in the storage and applications of animal oils. In this work, we use four different techniques, including UV-Vis spectrometry, viscometry, impedance spectroscopy, and acid–base titration, to study the thermal aging kinetics of tallow, chicken oil, lard, and sheep oil in the temperature range from 120 ◦C to 180 ◦C. The evolutions of the UV-Vis absorbance, dynamic viscosity, electric impedance, and acid titration are discussed with the defect kinetics. The evolutions of the color centers, defects for dynamic viscosity, and electric dipoles follow second-order, first-order, and zero-order kinetics, respectively. …

A New Air-Assisted Flare Tip Design For Managing Gas Flare Emissions (Cfd Analysis), Ahmed A. Maaroof, Joseph D. Smith, Mohammed H.S. Zangana

Chemical and Biochemical Engineering Faculty Research & Creative Works

Recently, flares have been considered as a major source of air pollution from the petroleum refining industry. The United Nations has instigated an international effort related to the management of flare emissions to reduce the global warming impact related to flaring. Eliminating or removing the need for gas flares is difficult because these devices are generally used as safety devices to allow the combustion of flammable gases in a controlled fashion which supports safe operation. However, reducing flaring is generally possible using well-designed, efficiently operated flare equipment. In general, flare performance can be enhanced following the API-521 methodology and using …

Antibiotic-Loaded Dendrimer Hydrogels In Periodontal Bone Regeneration: An In Vitro Release Feasibility Study, Nicholas Yesbeck, Da Huang, Caroline Carrico, Parthasarathy Madurantakam, Hu Yang

Chemical and Biochemical Engineering Faculty Research & Creative Works

The prescription of a course of oral antibiotics following bone grafting procedures is a common practice in clinical periodontics to reduce surgical site infections. The goal of this study is to characterize the release profile of antibiotics via local delivery using dendrimer hydrogels (DH) and to analyze the effect of two different particulate bone allografts on the release of the antibiotics in vitro. DH were synthesized from Poly amidoamine (PAMAM) dendrimer G5 and polyethylene glycol diacrylate, and cefazolin was chosen as the antibiotic. The antibiotic-loaded samples were bathed in PBS and incubated at 37 °C; aliquots were taken (1 h, …

Growth And Faceting Of Tungsten And Oxides In Scandate Cathode Particles During In Situ Heating In The Scanning Electron Microscope, Huanhuan Bai, Thomas John Balk

Chemical and Materials Engineering Faculty Publications

Tungsten-based scandate dispenser cathodes are promising next-generation thermionic electron sources for vacuum electron devices, due to their excellent emission performance at tempera- tures lower than those required for conventional cathodes. There has been a significant recent effort to understand scandate cathode performance and to characterize the tungsten and other materials on the emitting surface, primarily via the study of cathodes before and after emission testing. Moreover, these scandate cathodes have typically been characterized at room temperature only. In situ obser- vations of scandate cathodes is challenging, as these devices are thermionic emitters that operate in a high-vacuum environment, and because …

Effects Of External Pressure On Cycling Performance Of Silicon-Based Lithium-Ion Battery: Modelling And Experimental Validation, Kai Zhang, Yinan He, Junwu Zhou, Xinyang Wang, Yong Li, Fuqian Yang

Chemical and Materials Engineering Faculty Publications

Controlling the stress state of electrodes during electrochemical cycling can have a positive effect on the cycling performance of lithium-ion battery. In this work, we study the cycling performance of silicon-based lithium-ion half cells under the action of pressure in a range of 0.1 to 0.4 MPa. The cycling performance of the silicon-based lithium-ion half cells increases first with increasing the pressure to 0.2 MPa and then decreases with further increasing the pressure. The analysis of the surface morphologies of cycled electrodes reveals that applying a pressure of 0.2 MPa leads to the formation of fine electrode surface with the …

Electrified Membrane For Water Treatment And Resource Recovery: Advancing Multiscale Strategies In Gas-Involving Reactions, Jianan Gao

Dissertations

Multifunctional, modular, and scalable water treatment technologies that operate without chemical additives are crucial for addressing global water pollution challenges. While traditional membrane-based separation processes are crucial for ensuring clean water supplies, they primarily focus on pollutant removal rather than on the upcycling of pollutants into valuable resources. Electrified membrane filtration presents a robust alternative, utilizing minimal or no chemical additives and harnessing electrical power to directly reduce contaminants or produce reactive oxidants or reductants on-site.

This dissertation is dedicated to the development of innovative electrochemically reactive membranes designed to address three major challenges: (1) the engineering of electrocatalysts with …

Microwave Catalysis-Enabled Membrane Processes For Microbial Inactivation, Fangzhou Liu

Dissertations

The COVID-19 pandemic has highlighted the urgent need for advanced technologies to combat virus transmission. Traditional membrane filtration technologies primarily serve as physical barriers, capturing pollutants but failing to inactivate microbial agents such as bacteria and viruses. These membranes typically target larger particles but are ineffective against sub-micrometer viral particles. Thus, there's a critical demand for membrane filtration processes that combine robust filtration with antifouling and reaction -enabled functions for efficient pathogen disinfection. This research explores a novel microwave-assisted membrane filtration process incorporating catalytic reactions to enhance microbial disinfection and prevent membrane fouling, offering a groundbreaking solution to global challenges …

Collision Dynamics Of Compound Droplets In Microchannels: A Combined Numerical And Data-Driven Study, S M Abdullah Al Mamun

Dissertations

Understanding and predicting the hydrodynamic interactions of micron-scale droplets is crucial in a wide range of industrial and real-life applications, including microfluidics, pharmaceutics, drug delivery, food science, and enhanced oil recovery. These multi-phase and multi-scale phenomena are further complicated by the presence of core droplets of an immiscible fluid within shell droplets, known as compound droplets. The collisions and interactions of droplets in emulsions are influenced by various physical and geometric parameters, leading to distinct rheological and dynamic responses. This research employs numerical methods for a systematic parametric study of both simple and compound droplet pair collisions under confined shear …

Mathematical Modelling Of The Solar Drying Of Apricot, Sarvar Rejabov, Botir Shukurillayevich Usmonov, Asqar Artikov, Komil Usmanov

Chemical Technology, Control and Management

Agricultural products provide significant growth in export earnings for many countries and provide food globally. Fruits and vegetables are perishable foods due to their high moisture content. Therefore, most agricultural products require post-harvest processing such as drying to extend the shelf life of fruits and vegetables and maintain nutrient quality. Solar drying is widely used for this purpose. Ambient temperature, humidity and solar radiation affect the drying time and quality of agricultural products, especially apricots, in solar dryers. The experiments were carried out in the same place (Tashkent, Uzbekistan) and in the same time interval. When the mass of apricots …

Experimental Study Of The Ultrasonic Extraction Process Of Plant Raw Materials, Azamat Bakir Ogli Usenov, Doston Ishmuxammat Ogli Samandarov, Qobil Akmal Ogli Mukhiddinov, Jasur Esirgapovich Safarov Dcs

Chemical Technology, Control and Management

In-depth scientific research is being conducted around the world aimed at developing the scientific and methodological foundations of energy-saving extractors, processing medicinal plants, increasing the efficiency of modern technologies, processes and equipment for obtaining high-quality pharmaceutical raw materials rich in biologically active substances. Energy-saving extractors, developed in conjunction with the extraction process of medicinal plants, are introduced into the industry using scientifically proven technology. At the global level, special attention is paid to the creation of intelligent designs of innovative extraction plants that operate using ultrasonic waves, allowing the extraction of medicinal components of plants.

Clustering Algorithm Based On Similarity Of Objects, Akhram Khasanovich Nishanov, Alisher Tulkunovich Tursunov, Fayzullo Farhod O'G'Li Ollamberganov

Chemical Technology, Control and Management

The article discusses the problem of drug clustering. Initially, k classes are randomly formed and the resulting training sample is preprocessed, then the similarity between objects of each class is assessed based on the proximity function and the criterion for assessing the contribution of objects to the formation of their own class. It is usually expressed as a percentage and represents the degree of mutual similarity of objects of each class. In the next steps of the algorithm, first one object is taken from the first class and by adding it to all k classes, the contribution of this object …

Capacitive Sensors With Ultra-Small Capacitance For Smart Measurement And Control Systems, Rustam Baratov, Farrux Jabbor O'G'Li Ko'charov

Chemical Technology, Control and Management

This article discusses methods of low capacitance measurement of capacitive sensors. The results of the study of the amplitude-frequency (AF) and phase-frequency (PF) response of measurement circuits of capacitive sensors for low capacitances measurement, consisting of RC - differentiating elements are presented. The input and output parameters of the differentiating circuit and the complex transfer function are analyzed. The research results show that low capacitances measurement by measuring the rectangular pulses duration is the most effective measurement method.

Synthesis Of A Control System For A Non-Stationary Dynamic Plant Based On A Regulator-Predictor, Isamiddin Hakimovich Siddikov, Begovot Sheraliyevich Ibragimov

Chemical Technology, Control and Management

The paper considers the issues of synthesizing a predictor controller as part of a control system for a non-stationary dynamic plant with a predictive model. Technological processes in industry, in essence, have non-stationarity properties, the parameters of which can change during the execution of technological operations. To control such nonstationary dynamic control plants, controllers built on the basis of predictive models have found wide application. The article is devoted to the issue of studying automatic control systems of a non-stationary dynamic plant with a base regulator-predictor. To synthesize a regulator - predictor, it is proposed to use a predictive model …

Developing Decision-Making Models And Algorithms To Help Prevent Emergencies, Mizaakbar Xakkulmirzayevich Hudayberdiyev, Oybek Zokirovich Koraboshev

Chemical Technology, Control and Management

The article is devoted to the solution of the scientific issue of decision-making support for the prevention and elimination of the consequences of emergency situations. The relevance of this issue is related to the need to develop a theoretical basis for optimizing the risk of adverse effects on human health and the environment in connection with emergency situations, and a predictive model for the development of emergency situations and their prevention or elimination of their consequences. The optimization of the importance measure of signs for predicting the values of the factors of fire conditions has been carried out. In addition, …

Investigation Of The Parameters Of Semicylindrical Capacitive Sensor, Erkin Uljaev, Elyor Faxriddinovich Khudoyberdiev, Shohrukh Nurali O‘G‘Li Narzullayev

Chemical Technology, Control and Management

This study introduces a semicylindrical capacitive sensor, featuring an internal dielectric insulator, designed to measure moisture levels in bulk and other materials while in motion. The research employs numerical analysis to explore the sensor's capacitance variation and evaluate its performance. The change in capacitance of the semicylindrical capacitive sensor in the picofarad range is easily converted into a change in the frequency of the generator, which is implemented on an operational amplifier with feedback. The generator circuit is quite compact, and its output can be connected directly to the discrete input of a microcontroller without a matching element. Using the …

Review Of Fuzzy Models And Fuzzy Methods For Analysis Of Information In Conditions Of Emotional Decision Making, Latafat Gardashova, Royal Shirinov, Diana Boqdanova

Chemical Technology, Control and Management

In the modern world, decision-making often takes place in an environment of uncertainty and under the significant influence of emotional factors, which requires the use of special methods for analyzing information. This study is devoted to an overview of fuzzy models and methods that allow such factors to be taken into account when making decisions. In particular, the approaches based on fuzzy logic, fuzzy cognitive maps and fuzzy clustering methods that provide flexibility and adaptability in conditions of uncertainty are considered. The study analyzes examples of the application of these methods in various fields, including risk management, medical diagnostics and …

Optimization Of Bioethanol Production Using An Enzymatic Hydrolysis Process With Green Algae (Chaetomorpha) As The Raw Material, Teuku Maimun, Mirna Rahmah Lubis, Muhammad Aldi Zein, Wahed Febbry Andriansyah Ali

Makara Journal of Technology

Bioethanol is an alternative fuel derived from biological feedstock used to decrease the reliance on fossil fuels because of increasing energy consumption associated with population growth and increased use of oil fuels. Bioethanol production has been widely conducted using several types of algae, but the optimal conditions for the hydrolysis and fermentation processes are not explained in more detail. Therefore, this study focuses on determining the optimal conditions for hydrolysis and fermentation to maximize the bioethanol yield. This study uses optimization based on the hydrolysis time, temperature, and pH to increase the reducing sugar content using high-performance liquid chromatography in …

Addressing Strain And Porosity Changes Of Battery Electrodes Due To Reversible Expansion Through Dem Simulations, Hunter Teel, Taylor R. Garrick, Srikant Srinivasan, Fengkun Wang, Yangbing Zeng, Sirivatch Shimpalee

Faculty Publications

In this work, discrete element method (DEM) simulations were used to probe changes in electrode porosity, electrode strain, and the resultant pressure changes for composite electrodes comprised of active material and binder particles. Through the results acquired by these simulations, three cases that are representative of two limiting cases for electrode operation, and one case for realistic electrode face pressure during operation were captured and the implications on design and performance are discussed. Predicting changes in the porosity is a unique insight that is difficult if not impossible to capture experimentally but is important for predicting changes in electrochemical performance …

Rate Law For Photoelectrochemical Water Splitting Over Cuo, Bo-Yuan Gao, Wen-Hua Leng

Journal of Electrochemistry

Photocatalytic splitting of water over p-type semiconductors is a promising strategy for production of hydrogen. However, the determination of rate law is rarely reported. To this purpose, copper oxide (CuO) is selected as a model photocathode in this study, and the photogenerated surface charge density, interfacial charge transfer rate constant and their relation to the water reduction rate (in terms of photocurrent) were investigated by a combination of (photo)electrochemical techniques. The results showed that the charge transfer rate constant is exponential-dependent on the surface charge density, and that the photocurrent equals to the product of the charge transfer rate constant …

Winning Works From Journal Of Electrochemistry: The 2Nd Xiamen University Short Video Abstract Contest For Science And Technology Journal Papers, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Recent Advances On Ruthenium-Based Electrocatalysts For Lithium-Oxygen Batteries, Yu-Zhe Wang, Zhuo-Liang Jiang, Bo Wen, Yao-Hui Huang, Fu-Jun Li

Journal of Electrochemistry

Rechargeable lithium-oxygen (Li-O₂) batteries have attracted wide attention due to their high energy density. However, the sluggish cathode kinetics results in high overvoltage and poor cycling performance. Ruthenium (Ru)-based electrocatalysts have been demonstrated to be promising cathode catalysts to promote oxygen evolution reaction (OER). It facilitates decomposition of lithium peroxide (Li₂O₂) by adjusting Li₂O₂ morphologies, which is due to the strong interaction between Ru-based catalyst and superoxide anion (O₂^–) intermediate. In this review, the design strategies of Ru-based electrocatalysts are introduced to enhance their OER catalytic kinetics in …

Numerical Analysis Of Explosion Characteristics Of Vent Gas From 18650 Lifepo4 Batteries With Different States Of Charge, Shi-Lin Wang, Xu Gong, Li-Na Liu, Yi-Tong Li, Chen-Yu Zhang, Le-Jun Xu, Xu-Ning Feng, Huai-Bin Wang

Journal of Electrochemistry

The combustion and explosion characteristics of lithium-ion battery vent gas is a key factor in determining the fire hazard of lithium-ion batteries. Investigating the combustion and explosion hazards of lithium-ion batteries vent gas can provide guidance for rescue and protection in explosion accidents in energy storage stations and new energy vehicles, thereby promoting the application and development of lithium-ion batteries. Based on this understanding and combined with previous research on gas production from lithium-ion batteries, this article conducted a study on the combustion and explosion risks of vent gas from thermal runaway of 18650 LFP batteries with different states of …

Winning Results Of The 2Nd Xiamen University Short Video Abstract Contest For Science And Technology Papers, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.