Chemical Engineering Commons^™

Kinetics, Thermodynamics, And Biological Characterizations Of Hydrolysates Enzymatically Produced From Proteins Extracted From Microalgae, Hebah Al-Amodi

Theses

This thesis aims to explore the use of Zeolitic Imidazolate Framework-L (ZIF-L) as a support for immobilizing alcalase and its potency in producing protein hydrolysates. ZIF-L was synthesized at room temperature using an aqueous solution, and alcalase was immobilized through adsorption batch experiment. The successful immobilization of alcalase on ZIF-L was confirmed through Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). The maximum adsorption capacity of alcalase on ZIF-L was determined to be 672.1 ± 5.5 mg g^-1 at 40°C using an initial protein concentration of 5 mg mL-1. Adsorption equilibrium data …

The Impact Of Film Cooling On The Heat Release Within A Rotating Detonation Combustor, Shreyas Ramanagar Sridhara, Antonio Andreini, Marc D. Polanka, Myles D. Bohon

Faculty Publications

Rotating detonation combustors establish a detonation wave that continuously circulates inside a small annulus. The presence of the detonation wave and the downstream oblique shock within the small annulus coupled with high mass flow induces a high heat load to the combustor wall. Preliminary analysis shows that for higher thermal power, internal air cooling alone is not sufficient to remove the heat out of the walls to maintain them below the maximum temperature of the metal. A possible solution is to use film cooling to reduce the heat flux to the combustor walls. One issue, though, is that the introduction …

Modeling Reversible Volume Change In Automotive Battery Cells With Porous Silicon Oxide-Graphite Composite Anodes, Taylor R. Garrick, Brian J. Koch, Miguel A. Fernandez, Erin Efimoff, Hunter Teel, Matthew D. Jones, Mingjie Tu, Sirivatch Shimpalee

Faculty Publications

Automotive battery manufacturers are working to improve the individual cell and overall pack design by increasing durability, performance, and range, while reducing cost, and active material volume change is a key aspect that needs to be considered during this design process. Recently, silicon oxide-graphite composite anodes are being explored to increase total anode capacity while maintaining a tolerable amount of cell level reversible volume expansion due to the relatively lower reversible volume change of the silicon oxide compared to pure battery grade or metallurgical grade silicon. To predict the blended anode response and contribution to the overall cell volume change, …

Optimizing In-Situ Upgrading Of Heavy Crude Oil Via Catalytic Aquathermolysis Using A Novel Graphene Oxide-Copper Zinc Ferrite Nanocomposite As A Catalyst, Attia Attia, Ahmed Ashraf Soliman Eng., Mostafa Aboul-Fetouh Prof., Sayed Gomaa Prof., Tarek Aboul-Fotouh Prof.

Petroleum Engineering and Gas

Unconventional resources, such as heavy oil, are increasingly being explored and exploited due to the declining availability of conventional petroleum resources. Heavy crude oil poses challenges in production, transportation, and refining, due to its high viscosity, low API gravity, and elevated sulfur and metal content. Improving the quality of heavy oil can be achieved through the application of steam injection, which lowers the oil’s viscosity and enhances its flow. However, steam injection alone falls short of meeting the growing demand for higher-quality petroleum products. Catalytic upgrading is therefore being investigated as a viable solution to improve heavy oil quality. This …

Single Nanobubble Formation On Au Nanoelectrodes And Au@Ws2 Nanoelectrodes: Voltammetric Analysis And Electrocatalysis, Xian-Zhun Luo, Xiao-Hu Chen, Yong-Xin Li

Journal of Electrochemistry

Taking advantage of the extremely small size of the gold nanodisk electrode, the single hydrogen nanobubble generated on the surface of the nanoelectrode was studied to evaluate its hydrogen evolution performance. It was found that compared with the bare gold nanodisk electrode, the bubble formation potential of the gold nanodisk electrode modified with tungsten disulfide quantum dots (WS₂ QDs) on the surface was more positive, indicating that its hydrogen evolution activity was higher. Microdynamic model analysis shows that the average standard rate constant of the rate-determining step of the hydrogen evolution reaction of gold nanoelectrodes modified with WS_{2 …}

Journal Of Electrochemistry Is Selected To Entering Ici Journals Master List, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Goodbye With Tears! Deep Condolences To Academician Zhao-Wu Tian!, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

The Adviser Of Journal Of Electrochemistry Professor Christian Amatore Received The Chinese Government Friendship Award, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Joint Subarray Acoustic Tweezers Enable Controllable Cell Translation, Rotation, And Deformation, Liang Shen, Zhenhua Tian, Kaichun Yang, Joseph Rich, Jianping Xia, Neil Upreti, Jinxin Zhang, Chuyi Chen, Nanjing Hao, Zhichao Pei, Tony Jun Huang

Faculty Publications

Contactless microscale tweezers are highly effective tools for manipulating, patterning, and assembling bioparticles. However, current tweezers are limited in their ability to comprehensively manipulate bioparticles, providing only partial control over the six fundamental motions (three translational and three rotational motions). This study presents a joint subarray acoustic tweezers platform that leverages acoustic radiation force and viscous torque to control the six fundamental motions of single bioparticles. This breakthrough is significant as our manipulation mechanism allows for controlling the three translational and three rotational motions of single cells, as well as enabling complex manipulation that combines controlled translational and rotational motions. …

Tunable Blended Collagen I/Ii And Collagen I/Iii Hydrogels As Tissue Mimics, Paulina M. Babiak, Carly M. Battistoni, Leonard Cahya, Rithika Athreya, Jason Minnich Ii, Alyssa Panitch, Julie C. Liu

School of Chemical Engineering Faculty Publications

Collagen (Col) is commonly used as a natural biomaterial for biomedical applications. Although Col I is the most prevalent col type employed, many collagen types work together in vivo to confer function and biological activity. Thus, blending collagen types can better recapitulate many native environments. This work investigates how hydrogel properties can be tuned through blending collagen types (col I/II and col I/III) and by varying polymerization temperatures. Col I/II results in poorly developed fibril networks, which softened the gels, especially at lower polymerization temperatures. Conversely, col I/III hydrogels exhibit well-connected fibril networks with localized areas of fine fibrils and …

Topography Of The 410 And 660 Km Discontinuities Beneath The Tibetan Plateau And Adjacent Areas, Zexin Miao, Stephen S. Gao, Muchen Sun, Kelly H. Liu

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

To investigate the three-dimensional spatial distribution of subducted oceanic slab segments and their consequential effect on the thermal and hydrous composition of the mantle transition zone (MTZ) beneath the entire Tibetan Plateau, we conducted a comprehensive analysis of approximately 655,000 P-to-s receiver functions (RFs), obtained from 735 broadband seismic stations. These RFs were utilized to delineate the 410 km (d410) and 660 km (d660) seismic discontinuities, which represent the upper and lower boundaries of the MTZ, respectively. The RFs were grouped within circular bins with a radius of 1 degree and stacked to image the discontinuities. The mean apparent depths …

Spatial And Temporal Variations Of Seismic Azimuthal Anisotropy Following The 2019 Ridgecrest Earthquake Sequence In Southern California, Yan Jia, Stephen S. Gao, Kelly H. Liu

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

To investigate the spatial and temporal variations of seismic azimuthal anisotropy in the vicinity of the conjugate fault network activated by the 4 July 2019 (UTC) M6.4 foreshock and the 6 July 2019 M7.1 mainshock in Ridgecrest, California, a total of 1,470 shear wave splitting measurements were obtained from local events recorded by five seismic stations over the period of July 2019 to January 2020. The results suggest a strong asymmetry in anisotropy forming mechanisms across the NW-SE striking Eastern Little Lake Fault, which is the main fault of the area. In the area located to the northeast of the …

Atomic Layer Deposition Of Ru Nanoclusters On Ba-Laceox: A Highly Efficient Catalyst For Ammonia Synthesis Under Mild Conditions, Kaiying Wang, Baitang Jin, Xiaoqing He, Xinhua Liang

Chemical and Biochemical Engineering Faculty Research & Creative Works

Ammonia synthesis has significant implications for global energy and environmental issues, driving the need for highly active catalysts that operate under mild conditions. This study reports the successful deposition of uniform ∼1.0 nm metallic ruthenium (Ru) nanoclusters onto Ba-LaCeO_x particles via atomic layer deposition (ALD). The catalytic performance of the ALD-prepared Ru nanoclusters was assessed for ammonia synthesis and compared with two catalysts produced by conventional incipient wetness impregnation. For the ALD-prepared Ru nanoclusters, a pre-reaction H_2-reduction step induced partial encapsulation of suboxide species on Ru sites due to strong metal-support interactions, limiting Ru nanocluster sintering and …

Ir Spectral Analysis Of Broussonetia Papyrefera Plant, Umid Hamroyevich Alamov, Zaytuna Ali Qizi Qurbonaliyeva, Dostonbek Qurbonsho Ugli Shomurodov, Elmurod Abduqodirovich Egamberdiev

Technical science and innovation

in this study, a method for determining the concentration of lignin, cellulose and hemicellulose in plant materials using Fourier-transform IR spectroscopy of Broussonetia papyrefera was developed and tested. The procedure is based on the use of calibration functions that reflect the dependence of the intensity of analytical absorption lines on the concentration of lignin (1512 cm-1) and cellulose (1450 cm-1) in standard samples; indirect correlation was used for hemicellulose. The model samples were ternary mixtures composed of lignin, bacterial cellulose and hemicellulose in different proportions. The proposed method was tested on a wide range of plant biomass samples.

Study Of Technological Parameters On Catalytic Hydroisomerisation Of Aromatic Hydrocarbons Into Alkyl Naphthenic Hydrocarbons, Habibullaeva Mirzaxmatovna Ra'no, Nodira Turobjonovna Torayeva, Temurbek Z. Daminov, Murod Azimovich Eshmukhamedov

Technical science and innovation

The article presents experimental results of the catalytic hydroisomerization of aromatic hydrocarbons into alkyl naphthenic hydrocarbons. Aluminum col-molybdenum with silicon oxides has been studied as a catalytic system, which imparts acidic properties to the catalytic system and stimulates isomerization.

The dehydrogenation reaction of cyclohexane has been studied, which occurs on the active surface of one of the metal oxides to cyclohexene, then the resulting cycloolefin diffuses to the acidic active center - aluminosilicate, where skeletal isomerization occurs and then the isomerized cycloolefin again returns to the active center of the surface of the catalytic system, where it is hydrogenated to …

Nanoparticles In Drilling Fluids: A Review Of Types, Mechanisms, Applications, And Future Prospects, Vasanth Gokapai, Prasad Pothana, Kegang Ling

Petroleum Engineering Student Publications

Nanofluids have gained significant attention as a promising solution to several challenges in drilling operations. Nanoparticles, due to their exclusive properties such as high specific surface area, strong adsorption potential, and excellent thermal conductivity, offer significant potential to improve the efficiency and performance of drilling processes. Regardless of the advancements in drilling fluids and techniques that have improved borehole stability, hole cleaning, and extreme operational condition (HTHP) management, limitations still persist. This review discusses a detailed summary of existing research on the application of nanofluids in drilling, exploring their types, properties, and specific uses in areas such as fluid loss …

Hydrogen Underground Storage For Grid Electricity Storage: An Optimization Study On Techno-Economic Analysis, Yunzhi Chen, Daniel Hill, Blake Billings, John Hedengren, Kody Powell

Faculty Publications

This study performs a techno-economic analysis of hydrogen underground storage systems for grid electricity storage, evaluating their economic viability at the plant scale using dynamic optimization. It explores the feasibility of various system configurations and revenue models in the context of volatile electricity prices and the necessity for multiple revenue streams. The hypothesis tested is that large-scale hydrogen storage, despite its low round-trip efficiency, can be economically viable with the right mix of revenue streams. This study uses scenario-based analysis to assess the impacts of different system configurations, including engaging in time-shifting arbitrage, ancillary service markets and blending hydrogen with …

Efficient Phosphate Removal From Water Using Ductile Cast Iron Waste: A Response Surface Methodology Approach, Mai Hassan Dr., Nada Alkhashab Eng., Ahmed Osman Dr., Dalia A. Ali Eng

Chemical Engineering

Water scarcity is a critical issue worldwide. This study explores a novel method for addressing this issue by using ductile cast iron (DCI) solid waste as an adsorbent for phosphate ions, supporting the circular economy in water remediation. The solid waste was characterized using XRD, XRF, FTIR, and particle size distribution. Wastewater samples of different phosphate ion concentrations are prepared, and the solid waste is used as an adsorbent to adsorb phosphate ions using different adsorbent doses and process time. The removal percentage is attained through spectrophotometer analysis and experimental results are optimized to get the optimum conditions using Design …

Efficient Phosphate Removal From Water Using Ductile Cast Iron Waste: A Response Surface Methodology Approach, Mai Hassan Roushdy Dr., Nada Amr El-Khashab Eng,, Ahmed Ibrahim Osman Dr., Dalia Amer Ali Dr.

Chemical Engineering

Water scarcity is a critical issue worldwide. This study explores a novel method for addressing this issue by using ductile cast iron (DCI) solid waste as an adsorbent for phosphate ions, supporting the circular economy in water remediation. The solid waste was characterized using XRD, XRF, FTIR, and particle size distribution. Wastewater samples of different phosphate ion concentrations are prepared, and the solid waste is used as an adsorbent to adsorb phosphate ions using different adsorbent doses and process time. The removal percentage is attained through spectrophotometer analysis and experimental results are optimized to get the optimum conditions using Design …

Solubility Characterization Of Organic Molecules For Aqueous Organic Redox Flow Batteries, Anthony W. Ferrell, Harkeerith K. Vij, Seamus D. Jones

College of Engineering Summer Undergraduate Research Program

The major obstacle to renewable energy sources is a lack of long-term energy storage capabilities. Energy produced during the day dissipates, leaving insufficient electricity for at night. The goal of the project is to design an Aqueous Organic Redox Flow Battery (AORFB) to act as long-term energy storage. Work has been done using machine learning to identify suitable compounds for the batteries. In this work there was no indication as to the aqueous solubility of the molecules; this controls the device’s energy storage capabilities. We used a machine learning model to determine the aqueous solubility of slightly more than 3000 …

Carboxymethyl Cellulose-Based Preformed Particle Gels For Water Management In Oil And Gas Reservoirs, Ahmed Ben Ali, Ahmed Hamza, Abdulaziz A. Almakimi, Mohammed Saad, Ibnelwaleed A. Hussein, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Carboxymethyl cellulose (CMC) based materials have been proposed as preformed particle gels (PPGs) for reducing excessive water production in oil and gas reservoirs. Multi-sized dry particles ranging between 100 and 1180 μm have been synthesized using microwave-assisted grafting copolymerization of CMC and acrylamide (AM)/n,n''-methylene-bisacrylamide (MBA). FTIR and SEM confirmed CMC crosslinked polyacrylamide's chemical structure and morphology (CMC/CPAM). Thermo-gravimetric analysis has demonstrated the thermal stability of dry PPGs up to 309 °C. CMC/CPAM showed slightly high absorbency in brine 2 (TDS = 67.3 g/L) compared to brine 1 (TDS = 33.65 g/L), 1% NaCl, and deionized water, with swelling ratios (SR) …

Feasibility Study Of Perovskite Solid Electrolyte For Electrochemical Lithium-Ion Cells, Danyi Sun

Theses and Dissertations

To achieve a high energy density in lithium-ion batteries (LIB), replacing the graphite anode with lithium metal is essential, as it offers a theoretical capacity of 3840 mAh/g.(Q. Wang et al. 2021) However, the use of lithium metal anodes is restricted by the formation of lithium dendrites, which can cause short circuits.(Wood et al. 2016) Solid-state electrolytes present a viable alternative to conventional liquid electrolytes by potentially mitigating dendrite growth. Among these, the perovskite-type Li3/8Sr7/16Ta3/4Zr1/4O3 (LSTH) stands out due to its excellent ambient stability, although its synthesis, properties, and applications remain underexplored.(Y. Li et al. 2018) In this study, I …

Harnessing The Power Of Hollow Zein Nanoparticles For Enhanced Antifouling And Heavy Metal Removal Of Polyethersulfone Membranes, Farzan Esmali, Mohadeseh Najafi Arani, Elsie Betmoushoul, Masoumeh Zargar, Khalil Farhadi, Vahid Javan Kouzegaran, Rahim Molaei, Yaghoub Mansourpanah

Research outputs 2022 to 2026

This study explores the physicochemical characteristics of an innovative mixed matrix membrane made from polyethersulfone (PES) and hollow Zein nanoparticles (HZNs), which are derived from the corn storage protein, Zein. HZNs, with a mean diameter of 40 nm, were applied to address the challenges associated with metal and inorganic nanoparticles, such as their tendency to accumulate unevenly on the membrane surface. The membranes were fabricated by incorporating varying concentrations of HZNs into the PES casting solution through the nonsolvent phase separation method. The addition of HZNs enhanced the hydrophilicity and pure water flux of the membranes. It also modified the …

Carbon Fiber And Carbon Fiber Composites—Creating Defects For Superior Material Properties, Ashis Sutradhar Nitai, Tonny Chowdhury, Md Nafis Inam, Md Saifur Rahman, Md Ibrahim H. Mondal, M. A.H. Johir, Volker Hessel, Islam Md Rizwanul Fattah, Md Abul Kalam, Wafa Ali Suwaileh, John L. Zhou, Masoumeh Zargar, Mohammad Boshir Ahmed

Research outputs 2022 to 2026

Recent years have seen a rise in the use of carbon fiber (CF) and its composite applications in several high-tech industries, such as the design of biomedical sensor components, 3D virtual process networks in automotive and aerospace parts, and artificial materials or electrodes for energy storage batteries. Since pristine CF have limited properties, their properties are often modified through a range of technologies, such as laser surface treatment, electron-beam irradiation grafting, plasma or chemical treatments, electrophoretic deposition, carbonization, spinning-solution or melt, electrospinning, and sol–gel, to greatly improve their properties and performance. These procedures cause faulty structures to emerge in CF. …

Operational And Design Factors In Air Staging And Their Effects On Fouling From Biomass Combustion, Akram Elsebaie, Mingming Zhu, Yasir M. Al-Abdeli

Research outputs 2022 to 2026

The global transition towards a carbon-neutral economy highlights the potential of biomass as a renewable fuel source. However, the sustainability of biomass energy systems is challenged by its complex fouling behaviours during combustion. This study investigates the impact of air staging on mitigating fouling in biomass combustion. By optimising the secondary-to-total air flowrate ratio (Qs/Qt) and the positioning of secondary air, this research investigates the impact of operational and design parameters on fouling deposits in biomass combustion. A fixed-bed combustor was used for the experiments, with hardwood pellets as fuel. This study employed TGA and SEM to analyse the fouling …

Production Of Lioh·H2o From Lithium Chloride By Electrodialysis And Crystallisation, Kwang Loon Ang, Maryam Barmi, Yasaman Boroumand, Amir Razmjou, Aleksandar N. Nikoloski

Research outputs 2022 to 2026

Laboratory bench scale experiments were performed to develop a process for electrodialysis (ED) of LiCl liquor from spodumene leaching and purification to produce LiOH solution, for subsequent conversion by evaporative crystallisation to LiOH·H2O crystals as the end-product. Nafion® 117 cation-selective membranes were used in all experiments. The small electrolytic test cell achieved an average LiOH production rate of 7.5 g/h with 83 % coulombic efficiency and specific electrical consumption of 6.5 kWh/kg LiOH. In the large electrolytic test cell, a higher average LiOH production rate of 11.2 g/h was attained but at lower coulombic efficiency (62 %) and greater specific …

An Overview Of Additively Manufactured Metal Matrix Composites: Preparation, Performance, And Challenge, Liang Yu Chen, Peng Qin, Lina Zhang, Lai Chang Zhang

Research outputs 2022 to 2026

Highlight Recent progresses in additive manufacturing on metal matrix composites are reviewed. Additive manufacturing technologies for metal matrix composites are summarized. The characteristics of feedstocks and reinforcements are introduced. Mechanical property of additively manufactured metal matrix composites is reviewed. Challenges of additively manufactured metal matrix composites are discussed.

The Undergraduate Engineering Mental Health Help-Seeking Instrument (Ue-Mh-Hsi): Development And Validity Evidence, Joseph H. Hammer, Courtney J. Wright, Melanie E. Miller, Sarah A. Wilson

Chemical and Materials Engineering Faculty Publications

Background: Undergraduate engineering students experiencing distress are less likely than peers to ask for professional help. A population-specific instrument to facilitate the identification of factors that influence mental healthcare utilization could guide development and testing of interventions to increase help seeking.

Purpose: We used mixed methods guided by the Integrated Behavioral Model (IBM) to develop and evaluate the Undergraduate Engineering Mental Health Help-Seeking Instrument (UE-MH-HSI).

Method: First, we adapted existing measures of mental health help-seeking intention and mechanisms (i.e., attitudes, perceived norm: injunctive, perceived norm: descriptive, personal agency: autonomy, personal agency: capacity). Second, we coded qualitative interviews (N = 33) …

Kinetic Modeling Of Dust Grain Dynamics In Electrostatic Sieving, Aaron Berkhoff, Easton Ingram, Fateme Rezaei, Jeffrey Smith, David Bayless, William Schonberg, Daoru Han

Chemical and Biochemical Engineering Faculty Research & Creative Works

A new kinetic particle modeling framework was developed to investigate electrostatic transport of lunar regolith dust particles with applications to the concept of electrostatic sieving. the new approach is based on kinetic particle dynamics and includes major modules of sampling the particle size distribution, solving electric fields, and tracking motion of charged dust grains. a case study for a concept of electrostatic sieving was chosen to validate the new model. the simulation achieved similar performance of particle size classification as reported in the literature. the new model is computationally efficient (takes a few minutes on a PC-type laptop computer) so …

Delivery Of Tgfβ3 From Magnetically Responsive Coaxial Fibers Reduces Spinal Cord Astrocyte Reactivity In Vitro, Jessica L. Funnell, Jasper Fougere, Diana Zahn, Silvio Dutz, Ryan J. Gilbert

Chemical and Biochemical Engineering Faculty Research & Creative Works

A spinal cord injury (SCI) compresses the spinal cord, killing neurons and glia at the injury site and resulting in prolonged inflammation and scarring that prevents regeneration. Astrocytes, the main glia in the spinal cord, become reactive following SCI and contribute to adverse outcomes. The anti-inflammatory cytokine transforming growth factor beta 3 (TGFβ3) has been shown to mitigate astrocyte reactivity; however, the effects of prolonged TGFβ3 exposure on reactive astrocyte phenotype have not yet been explored. This study investigates whether magnetic core-shell electro spun fibers can be used to alter the release rate of TGFβ3 using externally applied magnetic fields, …