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Evidence Of Coal Conversion In The Majuba Underground Coal Gasification Pilot Plant, South Africa, L.S. Mokhahlane, N.J. Wagner, D. Vermeulen 2022 University of the Witwatersrand, School of Chemical and Metallurgical Engineering, 1 Jan Smuts Avenue, Braamfontein, Johannesburg, 2000, South Africa

Evidence Of Coal Conversion In The Majuba Underground Coal Gasification Pilot Plant, South Africa, L.S. Mokhahlane, N.J. Wagner, D. Vermeulen

Coal Combustion and Gasification Products Journal Archive

Underground coal gasification (UCG) is a coal conversion method that permits coal resources to be exploited in situ using high-temperature conversion reactions. An understanding of the chemical, mineralogical, and petrographic properties of the coal, and resultant unburned carbon, degasified coal, and ash (minerals) in the UCG gasification zone, is fundamental to determining conversion rates, gas composition, and environmental and groundwater risk assessments. This study aims to provide a mineralogical and petrographic characterization of UCG residues obtained from the Eskom Majuba UCG pilot plant site in South Africa. Samples were selected from a verification borehole (VH3) drilled at the site following …


Low-Density And High-Strength Fracking Proppant Made By High Alumina Fly Ash, Shuqiang Ding, Jinder Jow 2022 National Institute of Clean-and-Low-Carbon Energy

Low-Density And High-Strength Fracking Proppant Made By High Alumina Fly Ash, Shuqiang Ding, Jinder Jow

Coal Combustion and Gasification Products Journal Archive

High-alumina fly ash is defined to have alumina (Al2O3) content of no less than 40%, according to the Chinese power industry standard DL/T 2297. Specification for resource utilization categorization of fly ash from coal-fired power plant (Standard No. DL/T 2297-2021), and is considered a valuable raw material to replace bauxite for making aluminum, refractory materials, and fracking proppants, etc. A low-density and high-strength proppant, conventionally made with bauxite, has been successfully made by high-alumina fly ash and commercially used in the market. This new high-alumina f ly-ash–derived proppant has some advantages compared with the bauxite-derived proppant: (1) lower raw material …


Techno-Economic Feasibility Of Electrifying Food Markets In Nigeria With Biogas Hybrid Mini-Grids, Demi Temitope Ogunwo 2022 California Polytechnic University, Humboldt

Techno-Economic Feasibility Of Electrifying Food Markets In Nigeria With Biogas Hybrid Mini-Grids, Demi Temitope Ogunwo

Cal Poly Humboldt theses and projects

This thesis explored the feasibility of electrifying a food market in an urban city in Nigeria with a hybrid biogas-powered mini-grid. Under the Energizing Economies Initiative of the Rural Electrification Agency of Nigeria, nine markets in the country currently receive constant access to electricity via hybrid mini-grid systems. As a majority of these systems are diesel-solar-battery systems, this thesis explored the use of biogas generators as a substitute for diesel generators in hybrid mini-grids for food markets. A fruit and vegetable market in Ketu, Lagos was used as a case study for the research. The research for this thesis was …


Assessment Of Aged Woodchip Bioreactor Physical And Hydraulic Properties, Shelby Duncan 2022 South Dakota State University

Assessment Of Aged Woodchip Bioreactor Physical And Hydraulic Properties, Shelby Duncan

Electronic Theses and Dissertations

Denitrifying woodchip bioreactors are a critical tool for mitigating nitrate loading to downstream water bodies. The properties of the woodchip are a key factor in the design of the bioreactor which are usually designed to optimize that retention time of the water being treated. Retention time is affected by active flow volume, porosity, and flow rate. As a bioreactor ages, the carbon material will break down and, in some cases, sedimentation will occur within the bioreactor. Both processes will affect the porosity and hydraulic performance of the bioreactor. When flow through the bioreactor is significantly different than the original design, …


Energy And Economic Modeling Of Stillage Dewatering Processes In Kentucky Bourbon Distilleries, William Brennan 2022 University of Kentucky

Energy And Economic Modeling Of Stillage Dewatering Processes In Kentucky Bourbon Distilleries, William Brennan

Theses and Dissertations--Mechanical and Aerospace Engineering

Stillage is a byproduct of alcohol distillation and must be managed in all distilleries to sustain operations. In the United States, fuel ethanol plants typically convert all stillage into Dried Distillers’ Grains with Solubles (DDGS). This process and its variations are well known. Typical stillage management approaches are not well known, however, for the Kentucky bourbon industry. A survey of stillage management approaches in operational bourbon distilleries was conducted. Process modeling was performed to evaluate the energy and economic considerations of the available stillage dewatering methods for a 7 Million Original Proof Gallon (MMOPG) distillery. Monte Carlo simulations were performed …


The Response Of Beef Cattle To Disturbances From Unmanned Aerial Vehicles (Uavs), Gabriel Abdulai 2022 University of Kentucky

The Response Of Beef Cattle To Disturbances From Unmanned Aerial Vehicles (Uavs), Gabriel Abdulai

Theses and Dissertations--Biosystems and Agricultural Engineering

Unmanned aerial vehicles (UAVs) are increasingly becoming common in animal agriculture. However, research regarding the impact of UAV disturbance on animal wellbeing is lacking or limited. The goal of this study was to investigate the effect of UAV flights on beef cattle by measuring cattle heart and movement rate when introduced to single or multiple UAV flights. A total of 16 -18 crossbred beef heifers were introduced to different flights patterns at between 5 and 9 m above ground level (AGL) at approximately 1 to 2 m/s horizontal velocity for 4 weeks with flights repeated 3 days per week. Results …


Lignin Valorization Via Reductive Depolymerization Using Promoted Nickel Catalysts And Sub- And Supercritical Methanol, Julia Parker 2022 University of Kentucky

Lignin Valorization Via Reductive Depolymerization Using Promoted Nickel Catalysts And Sub- And Supercritical Methanol, Julia Parker

Theses and Dissertations--Biosystems and Agricultural Engineering

While lignin has been regarded as the most promising renewable feedstock for the sustainable manufacture of aromatic compounds, lignin valorization is necessary to improve the economic viability of biorefineries. Reductive catalytic fractionation (RCF), which combines delignification and lignin depolymerization into a single stage while maintaining the structure and integrity of the cellulose component, has evolved as an effective method for processing biomass. The ability of Cu and Fe to promote the performance of a 20% Ni/alumina catalyst when converting native lignin to alkylphenols by RCF in sub- and supercritical methanol was tested. The effectiveness of lignin extraction as measured by …


Implications To Tap And Stream Water Chemistry Due To Variations In Sampling Locations And Watershed Land Use, Dayana Rodriguez 2022 University of Kentucky

Implications To Tap And Stream Water Chemistry Due To Variations In Sampling Locations And Watershed Land Use, Dayana Rodriguez

Theses and Dissertations--Biosystems and Agricultural Engineering

The Kentucky River Basin, which is in the Eastern Kentucky Coal Field region, is a rural region with sparse population distribution and a history of water quality impairments. The long history of mining activity in the Commonwealth has not only left a mark on the area’s economy, but it has also shaped the environment. Changes in land use from forested areas to surface mining have been shown to significantly change water chemistry and hydrology. To date, there is limited information regarding the potential exposure and introduction of heavy metals and sulfate entering rural water treatment plants, resulting in a notable …


Classifying And Mapping Aquatic Vegetation In Heterogeneous Stream Ecosystems Using Visible And Multispectral Uav Imagery, Rozalia Agioutanti 2022 University of Kentucky

Classifying And Mapping Aquatic Vegetation In Heterogeneous Stream Ecosystems Using Visible And Multispectral Uav Imagery, Rozalia Agioutanti

Theses and Dissertations--Biosystems and Agricultural Engineering

The need for assessment and management of aquatic vegetation in stream ecosystems is recognized given the importance in impacting water quality, hydrodynamics, and aquatic biota. However, existing approaches to monitor are laborious and its currently not feasible to track spatial and temporal differences at broad scales. The objective of this study was therefore to map and classify aquatic vegetation of a shallow stream with heterogenous mixtures of emergent and submerged aquatic vegetation. Data was collected in the Camden Creek watershed within the Inner Bluegrass Region of central Kentucky. The use of unmanned aerial vehicles (UAVs) was employed and both visible …


Exploration Of Lignin-Based Superabsorbent Polymers (Hydrogels) For Soil Water Management And As A Carrier For Delivering Rhizobium Spp., Toby Adjuik 2022 University of Kentucky

Exploration Of Lignin-Based Superabsorbent Polymers (Hydrogels) For Soil Water Management And As A Carrier For Delivering Rhizobium Spp., Toby Adjuik

Theses and Dissertations--Biosystems and Agricultural Engineering

Superabsorbent polymers (hydrogels) as soil amendments may improve soil hydraulic properties and act as carrier materials beneficial to soil microorganisms. Researchers have mostly explored synthetic hydrogels which may not be environmentally sustainable. This dissertation focused on the development and application of lignin-based hydrogels as sustainable soil amendments. This dissertation also explores the development of pedotransfer transfer functions (PTFs) for predicting saturated hydraulic conductivity using statistical and machine learning methods with a publicly available large data set. A lignin-based hydrogel was synthesized, and its impact on soil water retention was determined in silt loam and loamy fine sand soils. Hydrogel treatment …


Assessing Machine Learning Utility In Predicting Hydrologic And Nitrate Dynamics In Karst Agroecosystems, Timothy McGill 2022 University of Kentucky

Assessing Machine Learning Utility In Predicting Hydrologic And Nitrate Dynamics In Karst Agroecosystems, Timothy Mcgill

Theses and Dissertations--Biosystems and Agricultural Engineering

Seasonal hypoxia in the Gulf of Mexico and harmful algal blooms experienced in many inland freshwater bodies is partially driven due to excessive nitrogen loading seen from agricultural watersheds. Within the Mississippi/Atchafalaya River Basin, many areas are underlain with karst features, and efforts to reduce nitrogen contributions from these areas have had varying success, due to lacking a complete understanding of nutrient dynamics in karst agricultural systems. To improve the understanding of nitrogen cycling in these systems, 35 months of high resolution in situ water quality and atmospheric data were collected and fed into a two-hidden layer extreme learning machine …


Above-Ground Biomass Estimation In Oat Breeding Nurseries Using Uav-Based Multispectral Data, Rakshya Dhakal 2022 South Dakota State University

Above-Ground Biomass Estimation In Oat Breeding Nurseries Using Uav-Based Multispectral Data, Rakshya Dhakal

Electronic Theses and Dissertations

Conventional methods of phenotyping for above-ground biomass under field conditions are time consuming, costly, and labor intensive. Unmanned Aerial Vehicles (UAV) offer a rapid and non-destructive approach for collecting high temporal and spatial resolution imagery of multiple field plots. Vegetation indices (VIs) can be derived from those imagery and have been used broadly for high-throughput biomass estimation, however, they suffer from spectrum saturation issues at high canopy density. In addition, VIs only reflect the canopy spectral information and fail to incorporate the 3-dimensional (3D) canopy structure and architecture information. It also ignores the spatial relationship of pixels to each other …


Managing Water Quantity And Quality With Subsurface Drainage In Eastern South Dakota, Morghan Hurst 2022 South Dakota State University

Managing Water Quantity And Quality With Subsurface Drainage In Eastern South Dakota, Morghan Hurst

Electronic Theses and Dissertations

Moisture extremes (excess and deficit) impact crop loss and water quality. Due to excessively wet springs and dry summers, crop damage can occur within the same county or field within the same year. To determine the magnitude of this problem in eastern South Dakota, indemnified crop insurance data for drought and excessive moisture claims were assessed for the years 1991-2020 for the occurrence of both excess moisture and drought in four counties in eastern South Dakota. Results show that there is greater than a 70% chance of the moisture extremes happening in the same year, making subsurface drainage, controlled drainage, …


Nondestructive Multivariate Classification Of Codling Moth Infested Apples Using Machine Learning And Sensor Fusion, Nader Ekramirad 2022 University of Kentucky

Nondestructive Multivariate Classification Of Codling Moth Infested Apples Using Machine Learning And Sensor Fusion, Nader Ekramirad

Theses and Dissertations--Biosystems and Agricultural Engineering

Apple is the number one on the list of the most consumed fruits in the United States. The increasing market demand for high quality apples and the need for fast, and effective quality evaluation techniques have prompted research into the development of nondestructive evaluation methods. Codling moth (CM), Cydia pomonella L. (Lepidoptera: Tortricidae), is the most devastating pest of apples. Therefore, this dissertation is focused on the development of nondestructive methods for the detection and classification of CM-infested apples. The objective one in this study was aimed to identify and characterize the source of detectable vibro-acoustic signals coming from CM-infested …


Cradle-To-Grave Life Cycle Assessment Of Production And Consumption Of Pulses In The United States, Prathamesh A. Bandekar, Ben Putman, Greg Thoma, Marty Matlock 2022 University of Arkansas, Fayetteville

Cradle-To-Grave Life Cycle Assessment Of Production And Consumption Of Pulses In The United States, Prathamesh A. Bandekar, Ben Putman, Greg Thoma, Marty Matlock

Biological and Agricultural Engineering Faculty Publications and Presentations

Environmental impact associated with production and consumption of pulses in the United States was evaluated using life cycle assessment (LCA). The system boundary was set to cradle-to-grave with a functional unit of 60 g (dry basis) of pulses consumed in a US household. Varieties of pulses modeled in the study included field pea (Pisum sativum), lentil (Lens culinaris), chickpea (Cicer arietinum), and dry bean. Three methods of cooking pulses at the consumer stage tested in the study were cooking in open vessel on electric cooking range (OVC), cooking in stovetop pressure cooker on electric cooking range (SPC), and cooking in …


Ammonia Cycling And Emerging Particulate Matter Pollutants Under Arable Land-Use Management: A Modelling Approach, Vivien Pohl 2022 Technological University Dublin

Ammonia Cycling And Emerging Particulate Matter Pollutants Under Arable Land-Use Management: A Modelling Approach, Vivien Pohl

Doctoral

Air quality monitoring in Ireland is under the jurisdiction of the Environmental Protection Agency in compliance with the Gothenburg Protocol, EU/national legislation, and the National Clean Air Strategy. Particulate Matter (PM) has been acknowledged as a key atmospheric pollutant, with serious public health impacts and no safe threshold of exposure in place to-date. Ammonia (NH3) emissions are linked to the secondary production of PM through atmospheric reactions occurring with acidic atmospheric components such as sulfuric acid, nitric acid, and hydrochloric acid. These reactions result in the formation of ammonium sulfate, ammonium nitrate and ammonium chloride, among others. More than 95% …


Comparison Of Stationary And Mobile Canopy Sensing Systems For Irrigation Management Of Maize And Soybean In Nebraska, Sandeep Bhatti, Derek M. Heeren, Susan A. O’Shaughnessy, Steven R. Evett, Mitchell S Maguire, Suresh Pradhyun Kashyap, Christopher M. U. Neale 2022 University of Nebraska-Lincoln

Comparison Of Stationary And Mobile Canopy Sensing Systems For Irrigation Management Of Maize And Soybean In Nebraska, Sandeep Bhatti, Derek M. Heeren, Susan A. O’Shaughnessy, Steven R. Evett, Mitchell S Maguire, Suresh Pradhyun Kashyap, Christopher M. U. Neale

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Accurate knowledge of plant and field characteristics is crucial for irrigation management. Irrigation can potentially be better managed by utilizing data collected from various sensors installed on different platforms. The accuracy and repeatability of each data source are important considerations when selecting a sensing system suitable for irrigation management. The objective of this study was to compare data from multispectral (red and near-infrared bands) and thermal (long wave thermal infrared band) sensors mounted on different platforms to investigate their comparative usability and accuracy. The different sensor platforms included stationary posts fixed on the ground, the lateral of a center pivot …


Inspiring Young Students To Pursue Engineering, Tami M. Brown-Brandl, Brian Steward 2022 University of Nebraska-Lincoln

Inspiring Young Students To Pursue Engineering, Tami M. Brown-Brandl, Brian Steward

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Imagine elementary school students understanding inputs and outputs, choosing appropriate sensors, and programming an autonomous robot. Imagine middle school students learning about PID control and creating advanced programs for sensor-based decision making. Imagine high school students using CAD to design drive trains, manufacturing parts with CNC machine tools, using finite element analysis to adjust the design, ordering custom components from a machine shop, using image processing for target recognition, and applying path planning and motion control. We have witnessed all of these skills. They happened outside of traditional classrooms, and they were all student-driven.

Yes, it’s true, and it’s amazing. …


Recovering And Upgrading Kraft Lignin For Application In Flexible Polyurethane Foam, Peng Quan 2022 Michigan Technological University

Recovering And Upgrading Kraft Lignin For Application In Flexible Polyurethane Foam, Peng Quan

Dissertations, Master's Theses and Master's Reports

Lignin is the second abundant natural polymer and has been highlighted as a potential substitute for fossil-based raw materials. However, the inherent molecular heterogeneity and the complex recovery processes result in the challenge of controlling the molecular properties and value-added applications of lignin in large scale. To address those issues, a novel acid-liquefaction process was developed in this study to recover Kraft lignin with improved molecular homogeneity directly from black liquor.

In the first study, the liquefaction parameters were screened based on yield and molecular weight properties of the recovered lignin. Then, the recovered lignin samples were used to replace …


Resistome And Mobilome In Surface Runoff From Manured Soil As Affected By Setback Distance, Noelle Mware, Maria C. Hall, Selvakumar Rajendran, John E. Gilley, Amy Schmidt, Shannon Bartelt-Hunt, Yifan Zhang, Xu Li 2022 University of Nebraska - Lincoln

Resistome And Mobilome In Surface Runoff From Manured Soil As Affected By Setback Distance, Noelle Mware, Maria C. Hall, Selvakumar Rajendran, John E. Gilley, Amy Schmidt, Shannon Bartelt-Hunt, Yifan Zhang, Xu Li

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Land application of livestock manure introduces antibiotic resistance genes (ARGs) and mobile genetic elements (MGEs) into the soil environment. The objectives of this study were to examine the changes of resistome and mobilome in runoff and soil as a function of setback distance, i.e., the distance between manured soil and surface water, and to quantify the contributions of manure and background soil to the ARGs and MGEs in surface runoff. The resistome and mobilome in runoff and soil from a field-scale plot study were characterized using a high throughput quantitative polymerase chain reaction (HT-qPCR) array. It was estimated that a …


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