Direction-Tunable Nanotwins In Copper Nanowires By Laser-Assisted Electrochemical Deposition, 2013 Birck Nanotechnology Center, Purdue University
Direction-Tunable Nanotwins In Copper Nanowires By Laser-Assisted Electrochemical Deposition, Zhikun Liu, Yuefeng Wang, Yiliang Liao, Gary Cheng
Yuefeng Wang
Nanotwins can improve mechanical strength and maintain high electrical conductivity in metallic nanowires. We demonstrated a method of pulsed-laser-assisted electrodeposition, which could form dense nanotwins with tunable directions in copper nanowires of uniform sizes. Transmission electron microscopy characterization showed with a growth potential of -0.2 V, nanotwins tend to align along the longitudinal direction of the nanowires, whereas at a larger potential of -0.8 V, nanotwins of {111}/< 112 > type perpendicular to the longitudinal direction of the wire were formed. The two types of nanotwins were investigated by comparing the microstructures under different electrochemical conditions and laser irradiation energies. Two different …
A Taper To Reduce The Straight-To-Bend Transition Loss In Compact Silicon Waveguides, 2013 Purdue University - Main Campus
A Taper To Reduce The Straight-To-Bend Transition Loss In Compact Silicon Waveguides, Hao Shen, Li Fan, Jian Wang, Justin Wirth, Minghao Qi
Jian Wang
Strong confinement of light in silicon waveguides allows for sharp bends and, as a result, high-density integration. However, the mode transition loss between the straight and bent portions of a silicon waveguide begins to affect the device performance when the bending radius becomes small. In this letter, we show that a transition region with a step taper between the straight and bent portions of the waveguide can effectively reduce this transition loss. This is demonstrated by measuring the intrinsic round-trip losses of micro-racetrack resonators, where ultralow loss can be precisely characterized according to the quality (Q)-factor change. The results show …
Direct Fabrication Of Silicon Photonic Devices On A Flexible Platform And Its Application For Strain Sensing, 2013 Birck Nanotechnology Center, Purdue University
Direct Fabrication Of Silicon Photonic Devices On A Flexible Platform And Its Application For Strain Sensing, Li Fan, Leo Varghese, Yi Xuan, Jian Wang, Ben Niu, Minghao Qi
Jian Wang
We demonstrate a process to fabricate silicon photonic devices directly on a plastic film which is both flexible and transparent. This process allows the integration of complex structures on plastic films without the need of transferring from another substrate. Waveguides, grating couplers, and microring resonators are fabricated and optically characterized. An optical strain sensor is shown as an application using 5 mu m-radius microring resonators on the flexible substrate. When strain is applied, resonance wavelength shifts of the microring resonators are observed. Contributions of different effects are analyzed and evaluated. Finally, we measure the influence of residual strain and confirm …
An All-Silicon Passive Optical Diode, 2013 Birck Nanotechnology Center, Purdue University
An All-Silicon Passive Optical Diode, Li Fan, Jian Wang, Leo Varghese, Hao Shen, Ben Niu, Yi Xuan, Andrew Weiner, Minghao Qi
Jian Wang
A passive optical diode effect would be useful for on-chip optical information processing but has been difficult to achieve. Using a method based on optical nonlinearity, we demonstrate a forward-backward transmission ratio of up to 28 decibels within telecommunication wavelengths. Our device, which uses two silicon rings 5 micrometers in radius, is passive yet maintains optical nonreciprocity for a broad range of input power levels, and it performs equally well even if the backward input power is higher than the forward input. The silicon optical diode is ultracompact and is compatible with current complementary metal-oxide semiconductor processing.
Observation Of Correlation Between Route To Formation, Coherence, Noise, And Communication Performance Of Kerr Combs, 2013 Purdue University
Observation Of Correlation Between Route To Formation, Coherence, Noise, And Communication Performance Of Kerr Combs, Pei-Hsun Wang, Fahmida Ferdous, Houxun Miao, Jian Wang, Daniel Leaird, Kartik Srinivasan, Lei Chen, Vladimir Aksyuk, Andrew Weiner
Jian Wang
Microresonator optical frequency combs based on cascaded four-wave mixing are potentially attractive as a multi-wavelength source for on-chip optical communications. In this paper we compare time domain coherence, radio-frequency (RF) intensity noise, and individual line optical communications performance for combs generated from two different silicon nitride microresonators. The comb generated by one microresonator forms directly with lines spaced by a single free spectral range (FSR) and exhibits high coherence, low noise, and excellent 10 Gbit/s optical communications results. The comb generated by the second microresonator forms initially with multiple FSR line spacing, with additional lines later filling to reach single …
Spectral Line-By-Line Pulse Shaping Of On-Chip Microresonator Frequency Combs, 2013 Purdue University
Spectral Line-By-Line Pulse Shaping Of On-Chip Microresonator Frequency Combs, Fahmida Ferdous, Houxun Miao, Daniel Leaird, Kartik Srinivasan, Jian Wang, Lei Chen, Leo Tom Varghese, Andrew Weiner
Jian Wang
Recently, on-chip comb generation methods based on nonlinear optical modulation in ultrahigh-quality-factor monolithic microresonators have been demonstrated, where two pump photons are transformed into sideband photons in a four-wave-mixing process mediated by Kerr nonlinearity. Here, we investigate line-by-line pulse shaping of such combs generated in silicon nitride ring resonators. We observe two distinct paths to comb formation that exhibit strikingly different time-domain behaviours. For combs formed as a cascade of sidebands spaced by a single free spectral range that spread from the pump, we are able to compress stably to nearly bandwidth-limited pulses. This indicates high coherence across the spectra …
Multiscale Modeling Of The Hierarchical Structure Of Cellulose Nanocrystals, 2013 Purdue University
Multiscale Modeling Of The Hierarchical Structure Of Cellulose Nanocrystals, Fernando Luis Dri
Open Access Dissertations
Cellulose constitutes the most abundant renewable polymeric resource available today. It considered an almost inexhaustible source of raw material, and holds great promise in meeting increasing demands for environmentally friendly and biocompatible products. Key future applications are currently under development for the automotive, aerospace and textile industries. When cellulose fibers are subjected to acid hydrolysis, the fibers yield rod-like, highly crystalline residues called cellulose nanocrystals (CNCs). These particles show remarkable mechanical and chemical properties (e.g. Young Modulus ~200 GPa) within the range of other synthetically-developed reinforcement materials. Critical to the design of these materials are fundamental material properties, many of …
Development Of A Multiscale Atomistic Code To Investigate Self-Organized Pattern Formation Induced By Ion Irradiation, 2013 Purdue University
Development Of A Multiscale Atomistic Code To Investigate Self-Organized Pattern Formation Induced By Ion Irradiation, Zhangcan Yang
Open Access Dissertations
Various self-organized patterns including ripples and quantum dots can be induced by ion beam sputtering (IBS). For the past decades, the understanding of such phenomenon has been mainly relied on the Bradley-Harper theory that attributes the formation of self-organized patterns to the interplay between roughening by curvature dependence of erosion and smoothening by surface diffusion. Recently, the development of the crater function theory has overturned this erosion-based paradigm to a redistribution-based paradigm. The theory has proved that erosion is irrelevant and negligible in the pattern formation at low and intermediate incidence angles. Despite the success, there are still some questions …
Solar Cell Temperature Dependent Efficiency And Very High Temperature Efficiency Limits, 2013 Purdue University
Solar Cell Temperature Dependent Efficiency And Very High Temperature Efficiency Limits, John Robert Wilcox
Open Access Dissertations
Clean renewable solar energy is and will continue to be a critically important source of electrical energy. Solar energy has the potential of meeting all of the world's energy needs, and has seen substantial growth in recent years. Solar cells can convert sun light directly into electrical energy, and much progress has been made in making them less expensive and more efficient. Solar cells are often characterized and modeled at 25 °C, which is significantly lower than their peak operating temperature. In some thermal concentrating systems, solar cells operate above 300 °C. Since increasing the temperature drastically affects the terminal …
Hybrid Opto-Electrokinetic Technique For Micro/Nanomanipulation: Towards Application Of A Novel Non-Invasive Manipulation Technique In Microbiological Assay, 2013 Purdue University
Hybrid Opto-Electrokinetic Technique For Micro/Nanomanipulation: Towards Application Of A Novel Non-Invasive Manipulation Technique In Microbiological Assay, Jae-Sung Kwon
Open Access Dissertations
This dissertation explores various physical mechanisms of the Rapid Electrokinetic Patterning (REP) technique suggested for rapid and precise on-chip manipulation of colloids and fluids, and bio-compatibility of the technique for biological applications. REP is a hybrid opto-electrokinetic technique that is driven by the simultaneous application of an AC electric field and a heating source. It can not only effectively transport and manipulate a fluid but also concentrate and pattern particles suspended in the fluid through the combined effect of an electrohydrodynamic flow, electrostatic colloidal interactions and an electrothermal microfluidic flow. These capabilities make REP a promising tool which can provide …
Graphene Decorated Substrates And Their Interfacial Characteristics, 2013 Purdue University
Graphene Decorated Substrates And Their Interfacial Characteristics, Anurag Kumar
Open Access Dissertations
Carbon nanotubes and graphene have been extensively studied for their excellent properties. As research on carbon expands, two major issues face the scientific community: (i) Expanding the scale of synthesis and (ii) Integration of different carbon structures for improved functionality. While significant advancements have been made in large-scale synthesis, room for improvement remains. As the scale of production increases, issues such as time, cost and energy that may otherwise not be very significant, begin to play greater roles. Thus, in order to effectively transition from laboratory prototypes to industrial products, a synthesis method that can address these issues is strongly …
Non-Silicon Mosfets And Circuits With Atomic Layer Deposited Higher-K Dielectrics, 2013 Purdue University
Non-Silicon Mosfets And Circuits With Atomic Layer Deposited Higher-K Dielectrics, Lin Dong
Open Access Dissertations
The quest for technologies beyond 14nm node complementary metal-oxide-semiconductor (CMOS) devices has now called for research on higher-k gate dielectrics integration with high mobility channel materials such as III-V semiconductors and germanium. Ternary oxides, such as La2-xYxO3 and LaAlO3, have been considered as strong candidates due to their high dielectric constants and good thermal stability. Meanwhile, the unique abilities of delivering large area uniform thin film, excellent controlling of composition and thickness to an atomic level, which are keys to ultra-scaled devices, have made atomic layer deposition (ALD) technique an excellent choice.
In this thesis, we systematically study the atomic …
A New Angle On Microscopic Suspension Feeders Near Boundaries, 2013 University of California - Berkeley
A New Angle On Microscopic Suspension Feeders Near Boundaries, Rachel E. Pepper, Marcus Roper, Sangjin Ryu, Nobuyoshi Matsumoto, Moeto Nagai, Howard A. Stone
Department of Mechanical and Materials Engineering: Faculty Publications
Microscopic sessile suspension feeders are a critical component in aquatic ecosystems, acting as an intermediate trophic stage between bacteria and higher eukaryotic taxa. Because they live attached to boundaries, it has long been thought that recirculation of the feeding currents produced by sessile suspension feeders inhibits their ability to access fresh fluid. However, previous models for the feeding flows of these organisms assume that they feed by pushing fluid perpendicular to surfaces they live upon, whereas we observe that sessile suspension feeders often feed at an angle to these boundaries. Using experiments and calculations, we show that living suspension feeders …
Micro Solar Thermal Energy Development And Use For Mems Power Applications, 2013 Louisiana Tech University
Micro Solar Thermal Energy Development And Use For Mems Power Applications, Emmanuel Ogbonnaya
Doctoral Dissertations
Increasing focus on alternative energy sources has produced significant progress across a wide variety of research areas. One particular area of interest has been solar energy. The sun represents sustainable and renewable energy source capable of meeting present energy needs without compromising the ability of future generations to meet theirs. Energy from the sun can be utilized in multiple ways. Direct rise in modern power generation typically involves either photovoltaic systems or large-scale solar thermal energy installations. While large-scale solar thermal energy generation is well advanced, there has been comparatively little research on smaller scale thermal energy collection and application. …
Negotiating The Inclusion Of Nanoscience Content And Technology In Science Curriculum: An Examination Of Secondary Teachers' Thinking In A Professional Development Project, 2013 Portland State University
Negotiating The Inclusion Of Nanoscience Content And Technology In Science Curriculum: An Examination Of Secondary Teachers' Thinking In A Professional Development Project, Jennifer Gayle Wells
Dissertations and Theses
The Next Generation Science Standards represent a significant challenge for K-12 school reform in the United States in the science, technology, engineering and mathematics (STEM) disciplines (NSTA, 2012). One important difference between the National Science Education Standards (NRC, 1996) and the Next Generation Science Standards (Achieve, 2013) is the more extensive inclusion of nanoscale science and technology. Teacher PD is a key vehicle for implementing this STEM education reform effort (NRC, 2012; Smith, 2001).
The context of this dissertation study is Project Nanoscience and Nanotechnology Outreach (NANO), a secondary level professional development program for teachers that provides a summer workshop, …
Nanostructured Tin-Based Anodes For Lithium Ion Batteries With X-Ray Absorption Fine Structure Studies, 2013 The University of Western Ontario
Nanostructured Tin-Based Anodes For Lithium Ion Batteries With X-Ray Absorption Fine Structure Studies, Dongniu Wang
Electronic Thesis and Dissertation Repository
The practical applications of lithium ion batteries are highly dependent on the choice of electrodes, where boosting the materials innovations to design and achieve high capacity, excellent cycling performance, rate capability, low-cost and safe electrode materials provide the best solution. Based on this, tin-based anodes have gained great attention due to its high theoretical capacity, low cost and nontoxic nature to environment. Nevertheless, it undergoes significant volume variation(259%)during the operation of the battery, leading to pulverization and significant capacity fade. Thus, the practical application of tin-based anodes is still quite challenging. This thesis tackles issues related to tin-based anodes. It …
Optimization Of Gold Nanoparticles Synthesis By Stainless Steel For H2o2 And Glucose Detection, 2013 Universiti Brunei Darussalaam
Optimization Of Gold Nanoparticles Synthesis By Stainless Steel For H2o2 And Glucose Detection, T. H. Han, Mohammad Mansoob Khan Dr, J. Lee, M. H. Cho
Dr. Mohammad Mansoob Khan
The synthesis of (+)AuNPs procedure using a stainless-steel mesh was optimized. The optimal synthetic parameters were found to be one piece of stainless-steel mesh (22.5 cm2 in surface area) in 100 mL of a 1 mM precursor, precursor solution pH 4, and reaction temperature of 30°C. Under the optimal conditions, the as-synthesized (+)AuNPs were highly positively charged (+24.2 mV). Therefore, the as-synthesized (+)AuNPs act as a peroxidase mimic and provide a simple, fast, highly sensitive and selective colorimetric method for H2O2 detection with a detection limit of 0.06 mM in the linear range from 0.06 mM to 4.29 mM.
Investigation Of The Morphology Of Polypropylene-Nanoclay Nanocomposites, 2013 SelectedWorks
Investigation Of The Morphology Of Polypropylene-Nanoclay Nanocomposites, Raghavendra R. Hegde Dr
Raghavendra R Hegde Dr
The morphology development in polypropylene − nanoclay composites with different weight percentages of nanoclay additives was studied using a combination of wide-angle X-ray diffraction, small-angle X-ray scattering (SAXS), polarized optical microscopy and transmission electron microscopy. SAXS studies showed an increase in long period with increase in additive weight percentage. Thermal analysis showed that even if the clay platelets are not completely exfoliated they can act as effective nucleating agents. Studies indicated that the ultimate morphology formation is influenced by both the thermodynamics of mixing and crystallization and spherulite formation. During spherulite growth, unenclosed clay platelets were excluded at the spherulite …
Near Sputter-Threshold Gasb Nanopatterning, 2013 Birck Nanotechnology Center, Purdue University
Near Sputter-Threshold Gasb Nanopatterning, Osman El-Atwani, Sean Gonderman, Jean Paul Allain
Birck and NCN Publications
Nanopatterning at sputter-threshold energies with Ar irradiation of GaSb (100) surfaces is presented. Comparison with high-energy irradiations up to 1000 eV is conducted measuring in-situ the composition evolution over irradiation time at early stages (e. g., < 10(17) cm(-2)) and up to nanostructure saturation (e. g., similar to 10(18) cm(-2)). Low-energy irradiation is conducted for energies between 15-100 eV and a low-aspect ratio nanostructured dot formation is found. Furthermore, the role of oxide on GaSb is found to delay nanostructure formation and this is predominant at energies below 100 eV. In-situ quartz crystal microbalance measurements collect sputtered particles yielding the sputter rate at threshold energies indicating a correlation between erosion and surface composition consistent with recent theoretical models. Ion-induced segregation is also found and indicated by both compositional measurements of both the surface and the sputtered plume. (C) 2013 AIP Publishing LLC.
Giant Quasiparticle Bandgap Modulation In Graphene Nanoribbons Supported On Weakly Interacting Surfaces, 2013 Rensselaer Polytechnic Institute
Giant Quasiparticle Bandgap Modulation In Graphene Nanoribbons Supported On Weakly Interacting Surfaces, Xueping Jiang, Neerav Kharche, Paul Kohl, Timothy B. Boykin, Gerhard Klimeck, Mathieu Luisier, Pulickel M. Ajayan, Saroj K. Nayak
Birck and NCN Publications
In general, there are two major factors affecting bandgaps in nanostructures: (i) the enhanced electron-electron interactions due to confinement and (ii) the modified selfenergy of electrons due to the dielectric screening. While recent theoretical studies on graphene nanoribbons (GNRs) report on the first effect, the effect of dielectric screening from the surrounding materials such as substrates has not been thoroughly investigated. Using large-scale electronic structure calculations based on the GW approach, we show that when GNRs are deposited on substrates, bandgaps get strongly suppressed (by as much as 1 eV) even though the GNR-substrate interaction is weak.