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Full-Text Articles in Mechanical Engineering

Topology Optimization Of Internal Cooling Channels In Turbulent Flows, Shinjan Ghosh Dec 2021

Topology Optimization Of Internal Cooling Channels In Turbulent Flows, Shinjan Ghosh

Electronic Theses and Dissertations, 2020-2023

Topology optimization, introduced by Bendsoe and Sigmund in 1988 has been a topic of research in the structural mechanics field for several decades. This technique is commonly used to optimize system performance of structural components with minimum material usage by varying the distribution of materials in a given domain. Fluid dynamic topology optimization, a relatively new research topic uses a method of adding or subtracting materials to a given flow domain to obtain an optimal flow-path for a given objective function. While the structural TO creates a solid structure by introducing holes into the domain, fluid TO introduces solid into …


Autonomous Guidance Of Unmanned Combat Air Vehicles In Basic Fighter Maneuvering, Jeffery G. Dean Dec 2021

Autonomous Guidance Of Unmanned Combat Air Vehicles In Basic Fighter Maneuvering, Jeffery G. Dean

Mechanical and Aerospace Engineering Dissertations - Archive

Basic fighter maneuvering, or BFM, is the dynamic engagement of two or more aircraft in close-range air combat. The relatively recent introduction of advanced unmanned combat air vehicles (UCAVs) has opened the possibility for automated systems to be players in this arena of air-to-air combat, which has thus far been limited to manned aircraft. In order to design an unmanned system that could fight and win a BFM engagement, the system must include an advanced system for guidance. This dissertation leverages techniques from gain scheduling and incorporates adjustable aimpoint guidance, in order to address the capability for UCAVs to execute …


2d Layered Sip As Anisotropic Nonlinear Optical Material, Huseyin Sar, Jie Gao, Xiaodong Yang Dec 2021

2d Layered Sip As Anisotropic Nonlinear Optical Material, Huseyin Sar, Jie Gao, Xiaodong Yang

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Two-dimensional (2D) material of silicon phosphide (SiP) has recently been shown as a promising optical material with large band gap, fast photoresponse and strong anisotropy. However, the nonlinear optical properties of 2D SiP have not been investigated yet. Here, the thickness-dependent in-plane anisotropic third-harmonic generation (THG) from the mechanically exfoliated 2D layered SiP flakes is reported. The crystal orientation of the SiP flake is determined by the angle-resolved polarized Raman spectroscopy. The angular dependence of the THG emission with respect to the incident linear polarization is found to be strongly anisotropic with the two-fold polarization dependence pattern. Furthermore, the effect …


Frequency Domain Measurements Of Melt Pool Recoil Force Using Modal Analysis, Tristan Cullom, Cody Lough, Nicholas Altese, Douglas A. Bristow, Robert G. Landers, Ben Brown, For Full List Of Authors, See Publisher's Website. Dec 2021

Frequency Domain Measurements Of Melt Pool Recoil Force Using Modal Analysis, Tristan Cullom, Cody Lough, Nicholas Altese, Douglas A. Bristow, Robert G. Landers, Ben Brown, For Full List Of Authors, See Publisher's Website.

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Recoil pressure is a critical factor affecting the melt pool dynamics during Laser Powder Bed Fusion (LPBF) processes. Recoil pressure depresses the melt pool. When the recoil pressure is low, thermal conduction and capillary forces may be inadequate to provide proper fusion between layers. However, excessive recoil pressure can produce a keyhole inside the melt pool, which is associated with gas porosity. Direct recoil pressure measurements are challenging because it is localized over an area proportionate to the laser spot size producing a force in the mN range. This paper reports a vibration-based approach to quantify the recoil force exerted …


Anisotropy In Impact Toughness Of Powder Bed Fused Aisi 304l Stainless Steel, Sreekar Karnati, Atoosa Khiabhani, Aaron Flood, Frank W. Liou, Joseph William Newkirk Dec 2021

Anisotropy In Impact Toughness Of Powder Bed Fused Aisi 304l Stainless Steel, Sreekar Karnati, Atoosa Khiabhani, Aaron Flood, Frank W. Liou, Joseph William Newkirk

Mechanical and Aerospace Engineering Faculty Research & Creative Works

The current effort involved investigation into the anisotropy of AISI 304L fabricated through laser powder bed fusion. Charpy V‐notch specimens made from material fabricated at three different build orientations were tested and analyzed. A statistically significant difference among the toughness values indicates the presence of anisotropy within the additively manufactured material. While the lowest toughness was found in vertically built specimens, the horizontal specimens were found to exhibit the highest toughness. From the fracture surfaces, an atypical mode of failure was observed. Exclusive crack propagation along the interlayer track boundaries was observed. The toughness variation correlated with the ease of …


Natural Van Der Waals Heterostructure Cylindrite With Highly Anisotropic Optical Responses, Arindam Dasgupta, Jie Gao, Xiaodong Yang Dec 2021

Natural Van Der Waals Heterostructure Cylindrite With Highly Anisotropic Optical Responses, Arindam Dasgupta, Jie Gao, Xiaodong Yang

Mechanical and Aerospace Engineering Faculty Research & Creative Works

The mechanical exfoliation of naturally occurring layered materials has emerged as an easy and effective method for achieving ultrathin van der Waals (vdW) heterostructures with well-defined lattice orientations of the constituent two-dimensional (2D) material layers. Cylindrite is one such naturally occurring vdW heterostructure, where the superlattice is composed of alternating stacks of SnS2-like and PbS-like layers. Although the constituent 2D lattices are isotropic, inhomogeneous strain occurring from local atomic alignment for forcing the commensuration makes the cylindrite superlattice structurally anisotropic. Here, we demonstrate the highly anisotropic optical responses of cylindrite thin flakes induced by the anisotropic crystal structure, including angle-resolved …


Polarization-Dependent Optical Responses In Natural 2d Layered Mineral Teallite, Ravi P. N. Tripathi, Xiaodong Yang, Jie Gao Dec 2021

Polarization-Dependent Optical Responses In Natural 2d Layered Mineral Teallite, Ravi P. N. Tripathi, Xiaodong Yang, Jie Gao

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Multi-element layered materials enable the use of stoichiometric variation to engineer their optical responses at subwavelength scale. In this regard, naturally occurring van der Waals minerals allow us to harness a wide range of chemical compositions, crystal structures and lattice symmetries for layered materials under atomically thin limit. Recently, one type of naturally occurring sulfide mineral, ternary teallite has attained significant interest in the context of thermoelectric, optoelectronic, and photovoltaic applications, but understanding of light-matter interactions in such ternary teallite crystals is scarcely available. Herein, polarization-dependent linear and nonlinear optical responses in mechanically exfoliated teallite crystals are investigated including anisotropic …


Impact Of Surface And Pore Characteristics On Fatigue Life Of Laser Powder Bed Fusion Ti–6al–4v Alloy Described By Neural Network Models, Seunghyun Moon, Ruimin Ma, Ross Attardo, Charles Tomonto, Mark Nordin, Paul Wheelock, Michael Glavicic, Maxwell Layman, Richard Billo, Tengfei Luo Dec 2021

Impact Of Surface And Pore Characteristics On Fatigue Life Of Laser Powder Bed Fusion Ti–6al–4v Alloy Described By Neural Network Models, Seunghyun Moon, Ruimin Ma, Ross Attardo, Charles Tomonto, Mark Nordin, Paul Wheelock, Michael Glavicic, Maxwell Layman, Richard Billo, Tengfei Luo

Mechanical and Aerospace Engineering Faculty Research & Creative Works

In this study, the effects of surface roughness and pore characteristics on fatigue lives of laser powder bed fusion (LPBF) Ti–6Al–4V parts were investigated. The 197 fatigue bars were printed using the same laser power but with varied scanning speeds. These actions led to variations in the geometries of microscale pores, and such variations were characterized using micro-computed tomography. To generate differences in surface roughness in fatigue bars, half of the samples were grit-blasted and the other half were machined. Fatigue behaviors were analyzed with respect to surface roughness and statistics of the pores. For the grit-blasted samples, the contour …


Using Dynamic In Vivo Kinematics For Subject-Specific Calibration Of Knee Ligament Parameters, Stephen Nelson Dec 2021

Using Dynamic In Vivo Kinematics For Subject-Specific Calibration Of Knee Ligament Parameters, Stephen Nelson

Boise State University Theses and Dissertations

In vivo clinical studies are the optimal way to investigate the biomechanical outcomes of new prosthetic devices. This particular style of testing can be difficult and, in certain cases, unethical to perform. The testing of unproven devices, surgical techniques, and materials put patients at risk from unanticipated outcomes in how these devices respond to the in vivo environment and patient-specific loading conditions. Biomechanical computational models were developed to provide validation to new devices prior to clinical testing. Computational models for use in optimizing knee prosthetics frequently include ligament representations, but these representations have inherent uncertainty due to wide intersubject variation …


Synthesis And Assessment Of Sustainable Fuels For Transportation And Space Exploration, Katerina Chagoya Dec 2021

Synthesis And Assessment Of Sustainable Fuels For Transportation And Space Exploration, Katerina Chagoya

Electronic Theses and Dissertations, 2020-2023

As global energy sources transition towards renewable energy, the demand for sustainable fuels has never been greater. The sheer scale of this transition will require numerous solutions to accommodate for the diverse and complex situations worldwide. This dissertation will discuss 3 studies: the utilization of CO2 waste gas to produce fuels sustainably, characterizing biofuels for efficient use in automobiles, and developing a solid, emissonless fuel intended for spaceflight but also applicable on Earth. The hydrogenation of CO2 into value-added molecules could reduce greenhouse gas emissions if waste stream CO2 were captured for conversion. We found that atomic vacancies induced in …


Anomaly Detection And Failure Prediction In Gas Turbines, Vipul Goyal Dec 2021

Anomaly Detection And Failure Prediction In Gas Turbines, Vipul Goyal

Electronic Theses and Dissertations, 2020-2023

This study is based on time-series data taken from the combined cycle heavy-duty utility gas turbines. For analysis, first, a multi-stage vector autoregressive model is constructed for the nominal operation of powerplant assuming sparsity in the association among variables, and this model is used as a basis for anomaly detection and prediction. This prediction is compared with the time-series data of the powerplant test data containing anomalies. Granger causality networks, which are based on the associations between the time series streams, can be learned as an important implication from the vector autoregressive modelling. This method suffers from the disadvantage that …


Tailoring Of The Left Ventricular Assist Device Cannula Implantation Using Coupled Multi-Scale Multi-Objective Patient Specific Optimization., Abubakar Dankano Dec 2021

Tailoring Of The Left Ventricular Assist Device Cannula Implantation Using Coupled Multi-Scale Multi-Objective Patient Specific Optimization., Abubakar Dankano

Electronic Theses and Dissertations, 2020-2023

Despite advancements in device design and anti-coagulation treatments, there are numerous adverse events that may occur following implantation of LVADs. The most devastating involves the embolization of thrombus into the brain causing a stroke, with incidence of up to 14-47% over a 6–12-month period. This study aims to elucidate ways to reduce this risk by surgical maneuvers guided by a multi-scale computational fluid dynamics analysis wrapped around a multi-objective shape optimization scheme which optimizes the anastomosis location of the VAD outflow graft (OG) along the ascending aorta to minimize the incidence of thrombi reaching the cerebral vessels and reduce particle …


Characteristic Of The Dynamics Of Disorder In Crystalline And Amorphous Materials, Amir Behbahanian Dec 2021

Characteristic Of The Dynamics Of Disorder In Crystalline And Amorphous Materials, Amir Behbahanian

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

This work provides the evidence to apply simulation methods that are applicable to systems with structural randomness to simulate crystalline materials at high temperatures. My work not only open the avenue to expand the simulation capability of materials but also provides insight to the physics of vibrations of atoms under different temperature and for different types of materials. I have also evaluated the reliability of Molecular Dynamics simulations at the frequency level and found that theses types of simulations, despite the previous belief, are reliable at low temperatures but up to a measurable frequency. In addition, the result of my …


Collective Motion In Pelotons And Fish Schools: Observation And Modeling, Syed Rafid Rahman Dec 2021

Collective Motion In Pelotons And Fish Schools: Observation And Modeling, Syed Rafid Rahman

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

In recent years there has been a sharp increase in deriving inspiration from nature for engineering applications. However there has been lack of high-resolution data from which insights into collective behavior can be drawn and models can be validated. In this imaging based thesis, data from high-speed, overhead cameras, and GPS tracking are used to collect position and sensory data for large groups of 40 or more members. These data helps us understand how different members (fish, cyclists) of a group interact with each other in collective motion. The focus of this work is to find how individual behavior leads …


Polyvinyl Chloride Gels: Theoretical Modeling Of Their Actuation Mechanism And Characterization Of Their Properties, Zachary Frank Dec 2021

Polyvinyl Chloride Gels: Theoretical Modeling Of Their Actuation Mechanism And Characterization Of Their Properties, Zachary Frank

UNLV Theses, Dissertations, Professional Papers, and Capstones

Polyvinyl chloride (PVC) gels are an electroactive polymer smart material which has been considered in a variety of actuator applications. Their large deformation, fast response rates, optical transparency, and soft nature has made them a key area of interest in fields ranging from soft robotics to optics. PVC gels are made from PVC mixed with large quantities of plasticizer, such as dibutyl adipate (DBA). When a voltage is applied, the gel experiences an “anodophilic” deformation (in which it moves preferentially towards the anode). This unique characteristic is the result of a charge buildup near the anode surface, which creates electromechanical …


Computational Sodium Heat Pipe Simulation In Three Dimensions For Transient Nuclear Reactor Analysis With Variable Surface Heat Flux, Valerie Jean Lawdensky Dec 2021

Computational Sodium Heat Pipe Simulation In Three Dimensions For Transient Nuclear Reactor Analysis With Variable Surface Heat Flux, Valerie Jean Lawdensky

UNLV Theses, Dissertations, Professional Papers, and Capstones

Heat pipes are used to transfer heat through phase change in a liquid/vapor contained in a metal tube. They are passive devices that require no pumps to circulate the fluid and can transfer heat far more efficiently than a solid copper rod of the same diameter. They are commonly used in laptop computers where copper heat pipes filled with water take heat away from the CPU and transfer the heat to air through a heat exchanger. Heat pipes were also used in the Kilopower nuclear reactor where higher temperatures required sodium as the working fluid with stainless steel tubes. Computer …


Turbulence Modeling Of Shock Boundary Layer Interaction In Hypersonic Flows, Sogol Pirbastami Dec 2021

Turbulence Modeling Of Shock Boundary Layer Interaction In Hypersonic Flows, Sogol Pirbastami

UNLV Theses, Dissertations, Professional Papers, and Capstones

Over the past few years, renewed interest in hypersonic research has significantly increased. Some of the most challenging obstacles in hypersonic vehicles design are associated with the shock wave turbulent boundary layer interactions (STBLI). This can cause a severe jump in pressure along with aerothermodynamic loads, which might result in structural damages or engine unstarts of hypersonic vehicles. Understanding the complex characteristics of these flows requires comprehensive physical experiments and detailed CFD turbulence modeling. In this dissertation, CFD simulations of STBLI using different turbulent modeling based on a set of experiments of hypersonic flow over a large hollow cylinder flare …


Modeling The Mechanical Behavior And Shock Propagation Of Metallic And Nanocomposite Materials, Pouya Shojaeishahmirzadi Dec 2021

Modeling The Mechanical Behavior And Shock Propagation Of Metallic And Nanocomposite Materials, Pouya Shojaeishahmirzadi

UNLV Theses, Dissertations, Professional Papers, and Capstones

Evaluating the materials properties under different loading conditions is critical in various industries. Compared to quasi-static loading, predicting the behavior of structures under dynamic loads is more challenging. In this work, we will address multiple problems with strain rates varying from quasi-static to hypervelocity conditions. Computer simulation is increasingly used in the design and evaluation phases to improve the efficiency, cost-effectiveness, and flexibility. However, verification and validation of each simulation is necessary. Experiments are performed in all topics and the computational models are validated by comparing with the experiments. One of the most common types of connections in structures is …


Automated Mini-Tubular Ceramic Production, Hunter Brooks, Daniel Freeman, Leo Taranta-Slack Dec 2021

Automated Mini-Tubular Ceramic Production, Hunter Brooks, Daniel Freeman, Leo Taranta-Slack

Mechanical Engineering

Researchers at Lawrence Livermore National Laboratory need a way to increase the rate of manufacturing of mini-tubular ceramics to be used in testing particulate air filters. This document outlines our process from researching and writing an initial scope of work all the way to fabricating and testing a final prototype. This journey takes us through the background research, ideation process and selection of a final design. We also detail the desired engineering specifications and our concept selection process. We dedicate a significant portion of this report to discussion of our final design. We delve into how it was manufactured as …


Gaf Fiberglass Mat Slitter Blade Sharpener, Mark D. Breaux, Bradley M. Smith, Esteban Carrillo, Carlos Espinoza Dec 2021

Gaf Fiberglass Mat Slitter Blade Sharpener, Mark D. Breaux, Bradley M. Smith, Esteban Carrillo, Carlos Espinoza

Mechanical Engineering

This document contains an overview for the offline slitter blade sharpening system created for GAF to sharpen their current cutting tools in a timely and safe manner without hindering the timeline and production of their assembly line. This design was developed by four undergraduate students at from Cal Poly, San Luis Obispo. This document first investigates background information of any patents, current sharpening device, sharpening safety standards, or literature review that may be useful in a sharpening mechanism device. This document also contains our design concept prototype, which consists of three main features, the use of a top guard for …


Produce Sorting Aid, Annica Navarro, Jessie Boucher, Natalie Roberts, Teng Lee Dec 2021

Produce Sorting Aid, Annica Navarro, Jessie Boucher, Natalie Roberts, Teng Lee

Mechanical Engineering

This Final Design Review (FDR) document intends to define the details of the Produce Sorting Aid senior project–selected by four mechanical engineering students, working under the team name Team W24. The Alameda County Community Foodbank (ACCFB) sorts bulk produce into bags or boxes for distribution to people in need of food. However, the current process is not ergonomic, time efficient, or safe for the volunteers at the ACCFB. The scope of the senior project is to design a mechanism that is ergonomic, time efficient, and safe for the volunteers to lift heavy produce and distribute the produce into bags ready …


Estimating Smart Wi-Fi Thermostat-Enabled Thermal Comfort Control Savings For Any Residence, Abdulelah D. Alhamayani, Qiancheng Sun, Kevin Hallinan Dec 2021

Estimating Smart Wi-Fi Thermostat-Enabled Thermal Comfort Control Savings For Any Residence, Abdulelah D. Alhamayani, Qiancheng Sun, Kevin Hallinan

Mechanical and Aerospace Engineering Faculty Publications

Nowadays, most indoor cooling control strategies are based solely on the dry-bulb temperature, which is not close to a guarantee of thermal comfort of occupants. Prior research has shown cooling energy savings from use of a thermal comfort control methodology ranging from 10 to 85%. The present research advances prior research to enable thermal comfort control in residential buildings using a smart Wi-Fi thermostat. "Fanger's Predicted Mean Vote model" is used to define thermal comfort. A machine learning model leveraging historical smart Wi-Fi thermostat data and outdoor temperature is trained to predict indoor temperature. A Long Short-Term-Memory neural network algorithm …


Synthesize And Characterization Of Aluminum- Tungsten Carbide Nanocomposite, Shuvendu Das Dec 2021

Synthesize And Characterization Of Aluminum- Tungsten Carbide Nanocomposite, Shuvendu Das

Theses and Dissertations

This research focuses on developing metal matrix composite reinforced by polymer-derived ceramic fibers. The force-spun AMT nanofibers were heat treated into tungsten carbide and then mixed with aluminum powder using cold pressing and sintering to produce the composites. The basic mechanical properties of this composite are investigated by density measurement, hardness and compression testing. SEM, EDS and XRD were used to test the morphology of tungsten carbide fibers. EDS identified a near-perfect W-C ratio in tungsten carbide fibers 1000 °C. Tungsten Carbide fibers were crushed using ball milling technique. Tungsten carbide nanofibers powder had a variety of particle size. Results …


Post-Processing And Characterization Of Additive Manufactured Carbon Fiber Reinforced Semi-Crystalline Polymers, Patricia Revolinsky Dec 2021

Post-Processing And Characterization Of Additive Manufactured Carbon Fiber Reinforced Semi-Crystalline Polymers, Patricia Revolinsky

Mechanical & Aerospace Engineering Theses & Dissertations

The aim of this work is to study the effect of post-processing on additive manufactured (AM) continuous carbon fiber reinforced plastics (CFRPs) performance. As-printed AM CFRPs do not perform as well as conventionally manufactured CFRPs with the same composition. Possible improvements to AM CFRP performance include annealing and applying uniaxial pressure with elevated temperature. Samples were subjected to pressure and temperature treatments and annealing at a constant temperature. Treated materials were subjected to three-point bending tests, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM) to characterize and assess sample performance. Results were assessed for flexural strength, …


How To Recognize And Control Interfacial Phenomena That Hinder The Advancement Of Clean Energy Technologies, Corey Michael Efaw Dec 2021

How To Recognize And Control Interfacial Phenomena That Hinder The Advancement Of Clean Energy Technologies, Corey Michael Efaw

Boise State University Theses and Dissertations

Nuclear energy and electrochemical energy storage, such as batteries, are key parts to the clean energy transition of critical infrastructure. This work aims to define, monitor, and modify interfacial layers that would improve the utility of materials in harsh environments seen in nuclear and energy storage applications. First, the studying of zirconium alloys, which is used as nuclear cladding, was done to better understand the degradation mechanisms within an extreme environment. High-resolution characterization techniques were used to correlate corrosion mechanisms to equivalent circuit models from novel in-pile electrochemical impedance spectroscopy sensors. Advancement in this sensor technology could provide further insight …


Developing A Prototype Energy Harvesting Device For Powering Wireless Onboard Condition Monitoring Sensor Modules For Railway Service, Martin Amaro Jr. Dec 2021

Developing A Prototype Energy Harvesting Device For Powering Wireless Onboard Condition Monitoring Sensor Modules For Railway Service, Martin Amaro Jr.

Theses and Dissertations

An energy harvesting system is being developed to power a wireless bearing health monitoring device. In contrast to other monitoring systems, this wireless monitoring device is a low-powered onboard solution. Powered by a 3.7-Volt lithium-ion battery, the device can continuously function for several months on a single charge. By implementing an energy harvesting system, the life of the battery can be increased reducing the overall maintenance, electronic waste, and time needed to replace the batteries. The harvesting system uses thermoelectric generators to convert the heat generated in the bearings into electricity. The system is composed of aluminum heat sinks, a …


Synthesis And Characterization Of Copper Oxide Nanofibers, Shishir Barai Dec 2021

Synthesis And Characterization Of Copper Oxide Nanofibers, Shishir Barai

Theses and Dissertations

The aim of this study was to develop polymer-derived Copper (II) Oxide (CuO) nanofibers through centrifugal spinning technique and subsequent calcining. To obtain the force spun pre-ceramic copper acetate nanofibers, 15% wt, 25% wt, 35% wt, 50% wt% copper acetate (active material) and poly (vinyl) alcohol ( PVA) solutions was prepared with deionized water (DI) as solvent and spun at 7500 rpm in a FibeRio Cyclone. Thermogravimetric analysis (TGA) was implemented to determine the thermal degradation behavior of the pre-ceramic nanofibers. These nanofibers were then calcined at three different temperatures (500, 600 and 700°C) to produce CuO nanofibers. The microstructure, …


Assessing The Effectiveness And Efficacy Of Wireless Onboard Condition Monitoring Modules In Identifying Defects In Railroad Rolling Stock, Lee R. Cantu Dec 2021

Assessing The Effectiveness And Efficacy Of Wireless Onboard Condition Monitoring Modules In Identifying Defects In Railroad Rolling Stock, Lee R. Cantu

Theses and Dissertations

Many industries have begun shifting into the Internet of Things (IoT) in the 21st century. To help ease this transition for the rail industry, The University Transportation Center for Railway Safety (UTCRS) has partnered with Hum Industrial Technology, Inc. (HUM) to help complete the development of a Wireless Onboard Condition Monitoring system named the ‘Boomerang™’. This product allows customers to schedule proactive maintenance on their railcars to replace defective wheels and/or bearings, saving them time, money and potentially preventing costly catastrophic derailments. The UTCRS research team has established thresholds to determine defective bearings utilizing thermal and mechanical sensors.

The effectiveness …


Synthesis And Characterization Of Centrifugally Spun Molybdenum-Based Nanomaterials For Lithium-Ion Batteries, Ramiro Gonzalez Jr. Dec 2021

Synthesis And Characterization Of Centrifugally Spun Molybdenum-Based Nanomaterials For Lithium-Ion Batteries, Ramiro Gonzalez Jr.

Theses and Dissertations

The work presented in this thesis focuses on the processing and development of transition metal compound composite fibers as anode materials for rechargeable lithium-ion batteries (LIBs). Among the transition metal compounds, molybdenum compounds have risen as promising candidates of advanced electrode materials, in view of their natural abundance, virtuous mechanical/thermal stability, rich chemistry, high theoretical specific capacity, and multiple oxidation states of Mo. The current work reports synthesize MoO2/C and MoO3/C composite fibers drawn from centrifugal spun ammonium molybdate/PAN precursor fibers, followed by a thermal treatment stabilizing in air and calcination under argon atmosphere. The weight ratios of (MoOx, 2 …


Selective Laser Melting Of Titanium Diboride: A Study Of The Energy Density Effects, Lazaro Lopez Mendez Dec 2021

Selective Laser Melting Of Titanium Diboride: A Study Of The Energy Density Effects, Lazaro Lopez Mendez

Theses and Dissertations

Natural titanium diboride (TiB2) has been reported the 5th hardest material on earth. Due to its superior properties, such as high density, high elastic modulus, and high compressive strength, TiB2 becomes one of the most suitable ceramic reinforcements for applications with severe friction and heavy loading conditions. This study is intended to produce TiB2 using 3D additive manufacture (AM) technology, and then to understand the tribological property of the AM fabricated TiB2 specimens. In this study, a laser additive alloying (LAA) process was developed based on a Renishaw AM laser system. One mm thick samples were prepared using the LAA …