Mechanical Engineering Commons^™

Improvement Of Mechanical And Corrosion Properties Of Weld In Stainless Steel In Crude Oil Tank By Using Nano-Fillers, Ali Abdulzahra Shanshoon

Al-Esraa University College Journal for Engineering Sciences

The aim of this study is to investigate the corrosion behavior and mechanical properties of welded steel exposed to gases emitted from crude oil reservoirs. In this study, two types of nanoparticles were used as fillers during welding to improve corrosion and mechanical properties. TiO₂ and SiO₂ nanoparticles were mixed with soldering oil in four mass concentrations of 0, 1, 2.5 and 5% by ultrasonic bath method and used as filler during the welding process. In order to prepare the samples, plain carbon steel with a thickness of 3 mm was used and they were welded together by …

Effect Of Heat Treatments On The Corrosion Resistance Of A Trip Steel And Its Evaluation By Non-Destructive Testing, Karla Ivette Vega-Nava, Ariosto Medina-Flores, Marco Antonio Espinosa-Medina, José Sergio Pacheco-Cedeño, Héctor Guillermo Carreón-Garcidueñas, Francisco Fernando Curiel-López, Jose Jaime Taha-Tijerina

Mechanical Engineering Faculty Publications

The development of advanced high-strength steels (AHSS) for the automotive industry requires optimizing the balance between mechanical properties and durability in aggressive environments. This study investigates the effects of two heat treatment routes on the microstructure and corrosion resistance of a transformation-induced plasticity (TRIP) steel (Fe-0.2C-1.75Mn-0.5Si-1Al). Route A includes a full austenitizing step at 1000 °C prior to intercritical annealing, whereas Route B omits this step and begins directly with intercritical annealing at 800 °C. Microstructural characterization (SEM/XRD), electrochemical assays, and eddy current tests were employed. The results revealed that Route A yields a homogeneous microstructure with 12.7% retained austenite, …

Capturing Sclera Anisotropy Using Direct Collagen Fiber Models: Linking Microstructure To Macroscopic Mechanical Properties, Fengting Ji, Xuehuan He, Frederick Sebastian, Mohammad R. Islam, Hannah Schilpp, Bingrui Wang, Yi Hua, Rouzbeh Amini, Ian A. Sigal

Mechanical Engineering Faculty Publications

Collagen fibers are essential to the mechanical behavior of soft tissues, including sclera. Conventional models often represent these fibers statistically, potentially missing crucial aspects of their role in tissue behavior. In this study, we expand on a direct fiber modeling approach that we recently presented based on explicitly representing the sclera long, interwoven fiber bundles. Specifically, our goal was to capture specimen-specific 3D fiber architecture and anisotropic mechanics of four ovine sclera samples (superior from Eye-1, temporal and superior from Eye-2, and temporal from Eye-3), each tested under five conditions: equi-biaxial (1:1) and four non-equi-biaxial (1:0.75, 0.75:1, 1:0.5, and 0.5:1). …

Microstructural And Mechanical Characterization Of Aa6082 /Sic/Al2o3 Hybrid Nano Composite Fabricated By Ultrasonic Assisted Stir Casting, Anasmon Koderi Valappil

Theses

The utilization of aluminium alloys has increased rapidly in past decades due to the increasing demand for lightweight and high-performance materials. Among the popular aluminium alloys, AA6082 is widely favoured for its excellent combination of strength, corrosion resistance, and machinability. Most previous work, however, has concentrated on either on micro scale reinforcement or on single ceramic particles, leaving very few experimental studies on the use of hybrid nano reinforcement in AA6082. Therefore, to further enhance its mechanical properties without compromising its inherent advantages, hybrid metal matrix composites were developed using various nano particulates as reinforcements. In this current study, AA6082-based …

Material Extrusion 3d Printing Of Metal Alloy: Material, Methods And Application., Sihan Zhang

Electronic Theses and Dissertations

Material extrusion (MEX) additive manufacturing presents a promising pathway for producing metal components with complex geometries while avoiding the safety hazards associated with loose powder handling in conventional metal additive manufacturing processes. This dissertation investigates the development and optimization of MEX processes for aluminum alloys, addressing critical challenges in feedstock formulation, printing parameter optimization, and post-processing strategies. Three distinct approaches were explored to advance the capabilities of aluminum MEX: filament-based processing of 6061 aluminum, paste-based extrusion of 6061 aluminum, and development of a novel aluminum-magnesium-tin alloy system for space manufacturing applications. The filament-based approach successfully demonstrated the production of 6061 …

Corrosion Behavior Of Mgtizn And Mg4tizn Alloys After Ball Milling And Subsequent Spark Plasma Sintering, Alexander Helmer, Rahul Agrawal, Manoj Mugale, Tushar Borkar, Rajeev Gupta

Mechanical Engineering Faculty Publications

Magnesium-containing multi-principal element alloys (MPEAs) are promising for lightweight applications due to their low density, high specific strength, and biocompatibility. This study examines two Mg-Ti-Zn alloy compositions, equal molar MgTiZn (TZ) and Mg4TiZn (4TZ), synthesized via ball milling followed by spark plasma sintering, focusing on their microstructures and corrosion behaviors. X-ray diffraction and transmission electron microscopy revealed the formation of intermetallic phases, including Ti2Zn and Mg21Zn25 in TZ, while 4TZ exhibited a predominantly Mg-rich phase. Potentiodynamic polarization and immersion tests in 0.1 M NaCl solution showed that both alloys had good corrosion resistance, with values of 3.65 +/- 0.65 mu …

Microstructure And Defects Of Aa6061 In The Laser Powder Bed Fusion Additive Manufacturing, Sivaji Karna

Theses and Dissertations

AA6061 is a widely used aluminum alloy known for its excellent thermal conductivity, strength, and corrosion resistance. However, its application in Laser Powder Bed Fusion (LPBF) additive manufacturing is restricted by solidification cracking and porosity. This study examines defect formation, microstructural evolution, and precipitate behavior in AA6061 processed under various LPBF conditions, including room temperature and heated substrates (500°C), as well as pulsed wave laser configurations. Microstructural characterization was conducted using optical microscopy, scanning electron microscopy (SEM) with energy dispersive X-ray spectroscopy (EDS) and electron backscatter diffraction (EBSD), and transmission electron microscopy (TEM).

A maximum relative density of 99.17% was …

Experimental Characterisation Of Laser Cladding Of Crniw And Crnifealzr Powders On H13 Tool Steel And Optimisation Of Process Parameters, Martin Vinoth S

Theses and Dissertations

In this work, laser cladding on H13 steel substrate with two different powder compositions CrNiW and CrNiFeAlZr has been carried out. The laser power, powder feed rate, and scanning speed were varied and the clad dimensions, aspect ratio, and dilution percentage were measured. The microhardness found in the CrNiW clad is 834 ± 20 HV0.5, which is higher than that of the CrNiFeAlZr clad (780 ± 20 HV0.5) as well as the substrate (548 ± 20 HV0.5).

The X-ray Diffraction (XRD) patterns identified the common phase creation of Ni3C and Fe3C for CrNiFeAlZr and CrNiW coatings, while the oxide formation …

Open Accessarticle Crystal Plasticity Modeling Of Dislocation Density Evolution In Cellular Dislocation Structures, Md Mahabubur Rohoman, Caizhi Zhou

Faculty Publications

The complex thermal cycles during the solidification process in metal additive manufacturing (AM) lead to the formation of high-density dislocation networks, organizing into submicron-scale cellular structures. These ultrafine structures are recognized as crucial for enhancing the mechanical properties of AM metals. In this study, we investigate the evolution of dislocation density within these cellular structures under plastic deformation and its impact on mechanical response using dislocation density-based crystal plasticity finite element (CPFE) modeling. The model incorporates the evolution of both statistically stored dislocation (SSD) and geometrically necessary dislocation (GND). Our simulations reveal that the yield and flow stresses of dislocation …

A Comprehensive Study Of Cooling Rate Effects On Diffusion, Microstructural Evolution, And Characterization Of Aluminum Alloys, Atiqur Rahman, Sriram Praneeth Isanaka, Frank Liou

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Cooling Rate (CR) definitively influences the microstructure of metallic parts manufactured through various processes. Factors including cooling medium, surface area, thermal conductivity, and temperature control can influence both predicted and unforeseen impacts that then influence the results of mechanical properties. This comprehensive study explores the impact of CRs in diffusion, microstructural development, and the characterization of aluminum alloys and the influence of various manufacturing processes and post-process treatments, and it studies analytical models that can predict their effects. It examines a broad range of CRs encountered in diverse manufacturing methods, such as laser powder bed fusion (LPBF), directed energy deposition …

Effect Of Alloying Additions On Austenite Refinement In Nickel-Alloyed Ductile Cast Irons, Adnan Adib Aahamed

College of Graduate Studies: Theses & Dissertations

The benefits associated with the application of ductile irons are significantly attributed to the control of microstructures, with refinement of austenitic matrix during solidification playing a significant role. Nickel alloyed ductile irons are attractive due to their potential for high ductility and suitability for potential high-temperature applications with stable austenitic microstructure. Refinement of austenite grain structure is thus important to enhance the mechanical properties of the alloyed ductile iron. This research investigates the impact of in-mold additions of different alloying elements on the austenite morphology and grain refinement of nickel-alloyed ductile iron along with the associated mechanical properties. A hypoeutectic …

Implementation Of Miniature Tensile Specimens In Mechanical Properties Assessment Of Directed Energy Deposited Ti-6al-4v: As-Built And Heat Treated, Saeid Alipour, Sung Heng Wu, Frank Liou, Arezoo Emdadi

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Within the last two decades, additive manufacturing (AM), a. k.a. 3D printing, has provided promising solutions for producing near-net-shape components with intricate geometries. From the material perspective, titanium alloys, one of humankind's most essential structural materials, are being considered the first candidate for AMed parts due to their unique characteristics in strength-weight-corrosion combinations. However, measuring the mechanical properties of designed geometry remains a challenge due to the ineffectiveness of conventional standard tensile specimens in assessing the site-specific and intricate geometries. In AM, the current approach often consists of evaluating standard-sized samples with the assumption that components with complex geometries possess …

Rheology Of Alumina Suspensions Subjected To Alternating Current Electric Fields For Freeze-Casting, Sivakumar Chithamallu, Ruksana Baby, Jacob L. Jones, Dipankar Ghosh

Mechanical & Aerospace Engineering Faculty Publications

Alternating current (AC) electric field can extrinsically tune freeze‐cast microstructure, originating from field‐induced increase in viscosity of ceramic suspensions. However, the changes that occur in a ceramic suspension and rheological behavior, ultimately affecting freeze‐cast microstructure, are not well understood. Moreover, the effects of AC electrokinetic forces and temperature on viscosity need to be decoupled. The viscosity and temperature of ceramic suspensions subjected to AC field and direct heating were measured, revealing that the increase in viscosity is due to AC dielectrophoretic forces rather than field‐induced heating of suspension. The shear thinning behavior of suspensions characterized using a power‐law model reveals …

Assessing Porosity Limit In Freeze-Cast Sintered Lithium Titanate (Li₄Ti₅O₁₂) Materials, Rohan Parai, Dipankar Ghosh

Mechanical & Aerospace Engineering Faculty Publications

This study aims to assess the lower limit of porosity that can be achieved in freeze-cast sintered lithium titanate (LTO) materials while maintaining the characteristic pore directionality. LTO materials were fabricated with solid loading varying in the range of 30–37 vol.%. Sucrose and cationic dispersant were used to vary viscosity and total solute concentration in the aqueous LTO suspensions. Two series of suspension compositions were selected for freeze-casting. In one series, aqueous suspensions were prepared by mixing deionized (DI) water, sucrose, and LTO powder, while in the other series, aqueous suspensions were prepared by mixing DI water, sucrose, cationic dispersant …

Intrinsic Manipulation Of Microstructure And Strength Of Ice-Templated Lithium Titanate, Rohan Parai

Mechanical & Aerospace Engineering Theses & Dissertations

This dissertation focuses on developing a fabrication landscape first time ever for directionally porous lithium titanate (LTO) materials using ice-templating technique. Ice-templating, a promising fabrication technique for porous ceramics, enables the formation of sintered structures with anisotropic pores that are aligned to improve mechanical stability of materials.

The work presented in this dissertation addresses advancements in tuning the porosity, strength, and microstructural characteristics of ice-templated LTO materials through adjustments of intrinsic variables, including sucrose as a water-soluble additive, variations in freezing front velocity, solute concentration, and solid loading. First, this study demonstrated that adding sucrose in LTO suspensions increased the …

Study On The Tribological Properties Of Din 16mncr5 Steel After Duplex Gas-Nitriding And Pack Boriding, Rafael Carrera Espinoza, Melvyn Alvarez-Vera, Marc Wettlaufer, Manuel Kerl, Stefan Barth, Pablo Moreno Garibaldi, Juan Carlos Díaz Guillen, Héctor Manuel Hernández García, Rita Muñoz Arroyo, Javier A. Ortega

Mechanical Engineering Faculty Publications

DIN 16MnCr5 is commonly used in mechanical engineering contact applications such as gears, joint parts, shafts, gear wheels, camshafts, bolts, pins, and cardan joints, among others. This study examined the microstructural and mechanical properties and tribological behavior of different surface treatments applied to DIN 16MnCr5 steel. The samples were hardened at 870 °C for 15 min and then quenched in water. The surface conditions evaluated were as follows: quenched and tempered DIN 16MnCr5 steel samples without surface treatments (control group), quenched and tempered DIN 16MnCr5 steel samples with gas-nitriding at 560 °C for 6 h, quenched and tempered DIN 16MnCr5 …

Mechanical Properties And Microstructure Of Multi-Materials Fabricated Through A Combination Of Lpbf And Ded Additive Manufacturing Techniques, Christopher J. Bettencourt

All Graduate Theses and Dissertations, Fall 2023 to Present

This research explores the use of different metals combined through 3D-printing to enhance the performance of materials, with a focus on making heat exchangers more cost-effective for renewable energy. The goal is to replace a costly high-temperature alloy with a more affordable low-temperature alloy, using metal additive manufacturing for its benefits such as less material waste, faster production, reduced weight, and the ability to print entire assemblies in one go. The study delves into a unique combination of two 3D-printing techniques, Directed Energy Deposition and Laser Powder-Bed Fusion, to create a multi-material composed of stainless steel 316L and a nickel-based …

Fabrication Of Smooth Sac305 Thin Film Via Magnetron Sputtering, M. Ojha, A. A. Elmustafa

Mechanical & Aerospace Engineering Faculty Publications

SAC305 (96.5 wt% Sn, 3 wt% Ag, 0.5 wt%Cu) solder is increasingly becoming popular due to its reliability good characteristics and performance in addition to the environmental concerns and regulations that restrict the use of lead in nano/microelectronic products. In nano/microelectronics, manufacturing smooth solder coatings free of defects such as voids and cracks, which can compromise joint reliability is crucial. Magnetron sputtering offers a high degree of control over film thickness and composition, resulting in films with excellent uniformity and adhesion. Despite these advantages, fabricating continuous and robust SAC305 films using magnetron sputtering remains a difficult task with limited research …

Stable Energy-Efficient Macro-Scale Partial Flow-Boiling Operations Using Microstructured Surfaces And Ultrasonics, Divya Kamlesh Pandya

Dissertations, Master's Theses and Master's Reports

Controlled but explosive growth in vaporization rates is made feasible by ultrasonic acoustothermal heating of the microlayers associated with micro-scale nucleating bubbles within the microstructured boiling surface/region of a millimeter-scale single-channel heat exchanger (HX) – part of a typically multi-channel heat-sink. The experiments illustrate the achievement of a remarkably high stable heat flux (10 – 80 W/cm²) for a partial flow-boiling-based cooling approach and exceptional efficiency through active/passive enhancement in the vaporization rates into the heterogeneously nucleated micro-bubbles (through acoustothermal heating of their microlayers) and their removal rates (typically within the passive microstructured region of boiling). A controlled …

The Effect Of Parameters In Cryogenic Treatment On Mechanical Properties Of Tool Steel: A Review, Ronaldus Caesariano Ekaputra, Myrna Ariati Mochtar

Journal of Materials Exploration and Findings

Tool steel is classified as special alloy steel which proposed as dies or mold materials as their high mechanical properties and dimensional stability. In order to improve tool steel’s mechanical properties, heat treatment process, especially, cryogenic treatment is conducted. Cryogenic treatment is done by exposing tool steel material at sub-zero liquid/gas media after heated at austenite temperature. This process significantly affects the martensite phase transformation increase and avoids retained austenite emersion. In particular, the higher martensite volume fraction, the higher hardness and wear resistance value of tool steel. It had been proven that adjusting critical process parameters of cryogenic treatment …

Synergistic Strategies In Sinter-Based Material Extrusion (Mex) 3d Printing Of Copper: Process Development, Product Design, Predictive Maps And Models., Kameswara Pavan Kumar Ajjarapu

Electronic Theses and Dissertations

3D printing pure copper with high electrical conductivity and exceptional density has long been challenging. While laser-based additive manufacturing technologies suffered due to copper's highly reflective nature towards laser beams, parts printed via binder-assisted technologies failed to reach over 90% IACS (International Annealed Copper Standard), electrical conductivity. Although promising techniques such as binder jetting, filament, and pellet-based 3D printing that can print copper exist, they however still face difficulties in achieving both high sintered densities and electrical conductivity values. This is due to a lack of comprehensive understanding of property evolution from green to sintered states and the strategies that …

Microstructural Characterization Of The Transition In Ss316l And In625 Bimetallic Fabricated Using Hybrid Additive Manufacturing, Christopher J. Bettencourt, Nadia Kouraytem

Mechanical and Aerospace Engineering Faculty Publications

Nearly all energy technologies utilize heat exchangers and recuperators within the power cycle. To further improve the cost-effectiveness of recuperators, costly high temperature Inconel 625 superalloy was substituted with a more affordable Stainless Steel 316L to be used at the low-temperature side of the heat exchanger. Bimetallic samples for analysis and examination were fabricated by combining Laser Powder-bed Fusion and Directed Energy Deposition. Two transition strategies for joining to the laser powder-bed fusion steel were explored, namely, a direct transition and an intermediate layer of 50% nickel powder mixed with 50% steel powder through Directed Energy Deposition. The microstructure and …

High Magnification Surface Topography Based Digital Image Correlation (Dic) For Identifying Damage Accumulation And Crack Growth In Polycrystalline Nickel, Arash Valiollahi

Mechanical and Aerospace Engineering Dissertations - Archive

Damage index parameters that have been formulated to identify damage localization in plastically deformed materials typically require all six stress or strain components. Recently, simulations through Crystal Plasticity Finite Element Method (CPFEM) have been widely used to extract damage initiation parameters. However, these models are rarely verified due to the challenges in measuring the out-of-plane deformation/strain experimentally. A damage index combining the effective plastic strain and surface roughness change is investigated for identifying damage accumulation sites and predicting crack propagation path in polycrystalline pure Nickel. A novel Digital Image Correlation (DIC) technique is developed to measure both in-plane and out-of-plane …

Lap Joint On St.37 Steel Plate With Friction Welding Clamping Method, Widia Setiawan, Nugroho Santoso, Wiyadi Wiyadi, Muhammad Sulistiyo Aji, Rachmat Alamin, Achsan Tarmudi

Journal of Mechanical Engineering Science and Technology (JMEST)

Friction stir (FW) welding is a relatively fresh method that was created and has been continually refined and adapted to industrial applications due to its benefits. This approach for solid-state joining entails connecting the components at a temperature below their melting point and then heating them up. Clamp joint applications are widely used using external heating and hitting with high strength, but the clamped joints with the FW method are rarely done. The research studied the characteristic of clamped joints at various plate thicknesses using the FW method. In this study, 30 specimens were used in the form of a …

Twin-Solute, Twin-Dislocation And Twin-Twin Interactions In Magnesium, Materials Yue, Jian Wang, Jian-Feng Nie

Department of Mechanical and Materials Engineering: Faculty Publications

Magnesium alloys have received considerable research interest due to their lightweight, high specific strength and excellent castability. However, their plastic deformation is more complicated compared to cubic materials, primarily because their low-symmetry hexagonal closepacked (hcp) crystal structure. Deformation twinning is a crucial plastic deformation mechanism in magnesium, and twins can affect the evolution of microstructure by interacting with other lattice defects, thereby affecting the mechanical properties. This paper provides a review of the interactions between deformation twins and lattice defects, such as solute atoms, dislocations and twins, in magnesium and its alloys. This review starts with interactions between twin boundaries …

A Direct Fiber Approach To Model Sclera Collagen Architecture And Biomechanics, Fengting Ji, Manik Bansal, Bingrui Wang, Yi Hua, Mohammad R. Islam, Felix Matuschke, Markus Axer, Ian A. Sigal

Mechanical Engineering Faculty Publications

Sclera collagen fiber microstructure and mechanical behavior are central to eye physiology and pathology. They are also complex, and are therefore often studied using modeling. Most models of sclera, however, have been built within a conventional continuum framework. In this framework, collagen fibers are incorporated as statistical distributions of fiber characteristics such as the orientation of a family of fibers. The conventional continuum approach, while proven successful for describing the macroscale behavior of the sclera, does not account for the sclera fibers are long, interwoven and interact with one another. Hence, by not considering these potentially crucial characteristics, …

A High-Strength Precipitation Hardened Cobalt-Free High-Entropy Alloy, Matthew Luebbe, Jiaqi Duan, Fan Zhang, Jonathan Poplawsky, Hans Pommeranke, Maalavan Arivu, Andrew Hoffman, Mario Buchely, Haiming Wen

Materials Science and Engineering Faculty Research & Creative Works

Recent studies on precipitation-hardened high-entropy alloys (HEAs) demonstrate their high strength and thermal stability, making them promising materials for high-temperature structural applications such as nuclear reactors. However, many existing HEAs contain cobalt (Co), which is unsuitable for nuclear applications because of the long-term activation issue of Co. Co is also expensive and considered a critical material for other applications. Therefore, it is desired to exclude Co from the composition. a Co-free (Fe0.3Ni0.3Mn0.3Cr0.1)88Ti4Al8 HEA was developed and studied in this work. in contrast to previous Co-free HEAs, this alloy is close to Equi atomic in its composition and promises a more …

Crystalline–Amorphous Nanostructures: Microstructure, Property And Modelling, Binqiang Wei, Lin Li, Lin Shao, Jian Wang

Department of Mechanical and Materials Engineering: Faculty Publications

Crystalline metals generally exhibit good deformability but low strength and poor irradiation tolerance. Amorphous materials in general display poor deformability but high strength and good irradiation tolerance. Interestingly, refining characteristic size can enhance the flow strength of crystalline metals and the deformability of amorphous materials. Thus, crystalline–amorphous nanostructures can exhibit an enhanced strength and an improved plastic flow stability. In addition, high-density interfaces can trap radiation-induced defects and accommodate free volume fluctuation. In this article, we review crystalline–amorphous nanocomposites with characteristic microstructures including nanolaminates, core–shell microstructures, and crystalline/amorphous-based dual-phase nanocomposites. The focus is put on synthesis of characteristic microstructures, deformation …

Material Property Dependence Of Nanoparticle Silicon Carbide Alloying In Additively Manufactured Molybdenum, Andrew P. Mason

Theses and Dissertations

The structural performance of additively manufactured Mo printed by LPBF can be significantly improved by nanoparticle alloying. Previous AFIT studies of SiC nanoparticle addition conducted by Ellsworth (2022) et al. demonstrated increased powder consolidation, leading to reduced porosity, increased microhardness, and a shift in atomic defect concentrations. The addition of defected SiC particles is proposed to reduce in situ oxidation by acting as a sacrificial oxidizing agent and contributing to the formation of Mo disilicide secondary phases. This study investigated the relationship between laser powder bed fusion Mo microscale and nanoscale properties with varying SiC particle size while maintaining a …

Synthesizing Ti–Ni Alloy Composite Coating On Ti–6al–4v Surface From Laser Surface Modification, Yitao Chen, Joseph William Newkirk, Frank W. Liou

Materials Science and Engineering Faculty Research & Creative Works

In This Work, a Ni-Alloy Deloro-22 Was Laser-Deposited on a Ti–6Al–4V Bar Substrate with Multiple Sets of Laser Processing Parameters. the Purpose Was to Apply Laser Surface Modification to Synthesize Different Combinations of Ductile TiNi and Hard Ti₂Ni Intermetallic Phases on the Surface of Ti–6Al–4V in Order to Obtain Adjustable Surface Properties. Scanning Electron Microscopy, Energy Dispersion Spectroscopy, and X-Ray Diffraction Were Applied to Reveal the Deposited Surface Microstructure and Phase. the Effect of Processing Parameters on the Resultant Compositions of TiNi and Ti₂Ni Was Discussed. the Hardness of the Deposition Was Evaluated, and Comparisons with …