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Full-Text Articles in Mechanical Engineering

A Novel Self-Assembled Cobalt-Free Perovskite Composite Cathode With Triple-Conduction For Intermediate Proton-Conducting Solid Oxide Fuel Cells, Hua Tong, Min Fu, Yang Yang, Fanglin Chen, Zetian Tao Sep 2022

A Novel Self-Assembled Cobalt-Free Perovskite Composite Cathode With Triple-Conduction For Intermediate Proton-Conducting Solid Oxide Fuel Cells, Hua Tong, Min Fu, Yang Yang, Fanglin Chen, Zetian Tao

Faculty Publications

A traditional composite cathode for proton-conducting solid oxide fuel cells (H-SOFCs) is typically obtained by mixing cathode materials and proton conducting electrolyte of BaCe0.7Y0.2Zr0.1O3–δ (BZCY), providing chemical and thermal compatibility with the electrolyte. Here, a series of triple-conducing and cobalt-free iron-based perovskites as cathodes for H-SOFCs is reported. Specifically, BaCexFe1–xO3–δ (x = 0.36, 0.43, and 0.50) shows various contents of two single phase perovskites with an in situ heterojunction structure as well as triple conductivity by tailoring the Ce/Fe ratios. The cell performance with the optimized BaCe0.36 …


Effects Of Radiation Reabsorption On The Laminar Flame Speed And No Emission During Aviation Kerosene Combustion At Elevated Pressures, Shu Zheng, Hao Liu, Qing Li, Jiajian Zhu, Mingbo Sun, Bo Zhou, Ran Sui, Qiang Lu Sep 2022

Effects Of Radiation Reabsorption On The Laminar Flame Speed And No Emission During Aviation Kerosene Combustion At Elevated Pressures, Shu Zheng, Hao Liu, Qing Li, Jiajian Zhu, Mingbo Sun, Bo Zhou, Ran Sui, Qiang Lu

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Increasing attention has been paid on combustion stability and pollution emission of aviation kerosene due to the emerging interests on supersonic combustion scramjets. Whereas the vitiation component H2O introduced by hydrogen-fueled heaters in high-enthalpy vitiated air during ground experiments has a considerable influence on kerosene combustion, especially through its radiation effect, which needs to be further investigated. In this paper, the radiation reabsorption effects on laminar flame speeds and NO emissions during RP-3/H2O/O2/N2 combustion was assessed numerically over a wide range of equivalence ratio and pressure (ϕ = 0.7–1.4 and P = 1–15 atm) using detailed chemical and radiation models. …


Spatially Guided Construction Of Multilayered Epidermal Models Recapturing Structural Hierarchy And Cell–Cell Junctions, Haiwei Zhai, Xiaowei Jin, Grayson Minnick, Jordan Rosenbohm, Mohammed Abdul Haleem Hafiz, Ruiguo Yang, Fanben Meng Sep 2022

Spatially Guided Construction Of Multilayered Epidermal Models Recapturing Structural Hierarchy And Cell–Cell Junctions, Haiwei Zhai, Xiaowei Jin, Grayson Minnick, Jordan Rosenbohm, Mohammed Abdul Haleem Hafiz, Ruiguo Yang, Fanben Meng

Department of Mechanical and Materials Engineering: Faculty Publications

A current challenge in 3D bioprinting of skin equivalents is to recreate the distinct basal and suprabasal layers and promote their direct interactions. Such a structural arrangement is essential to establish 3D stratified epidermis disease models, such as for the autoimmune skin disease pemphigus vulgaris (PV), which targets the cell– cell junctions at the interface of the basal and suprabasal layers. Inspired by epithelial regeneration in wound healing, a method that combines 3D bioprinting and spatially guided self-reorganization of keratinocytes is developed to recapture the fine structural hierarchy that lies in the deep layers of the epidermis.Herein, keratinocyteladen fibrin hydrogels …


Thermodynamic Limits Of Atmospheric Water Harvesting, Akshay K. Rao, Andrew J. Fix, Yun Chi Yang, David M. Warsinger Sep 2022

Thermodynamic Limits Of Atmospheric Water Harvesting, Akshay K. Rao, Andrew J. Fix, Yun Chi Yang, David M. Warsinger

School of Mechanical Engineering Faculty Publications

Atmospheric water harvesting (AWH) is a rapidly emerging approach for decentralized water production, but current technology is limited by trade-offs between energy consumption and yield. The field lacks a common basis to compare different AWH technologies and a robust understanding of the performance impacts of water recovery, desorption humidity (for sorbent systems), and realistic component-level efficiencies. By devising a set of unifying assumptions and consistent parameters across technologies, we provide the first fair thermodynamic comparison over a broad range of environmental conditions. Using 2nd law analysis, or least work, we study the maximum efficiency for common open system AWH methods …


Experimentally Measured Lumbar Skin Strains During Activities Of Daily Living, Andrew Gibbons, Paul Mcmullin, Darian Emmett, Ulrike H. Mitchell, David T. Fullwood, Anton E. Bowden Sep 2022

Experimentally Measured Lumbar Skin Strains During Activities Of Daily Living, Andrew Gibbons, Paul Mcmullin, Darian Emmett, Ulrike H. Mitchell, David T. Fullwood, Anton E. Bowden

Student Works

Introduction: When mechanical stimulation of the skin, post-surgery, is kept at a minimum, the risk for hypertrophic scarring is reduced. Therefore, surgeons have utilized different tools for optimal scar outcomes such as cutting along or perpendicular to the Langers lines or collagen fiber orientation1,2. However, biomechanical strains induced in the skin during activities of daily living (ADL) are the primary mechanism for suture opening, and increased awareness of these strains may provide informative insights to both pre-operative incision planning, as well as post-operative counseling with the patient regarding specific activities that may lead to wound re-opening.

Methods: Data …


Atherogenic Potential Of Microgravity Hemodynamics In The Carotid Bifurcation: A Numerical Investigation, Philippe Sucosky, Varun Vinayak Kalaiarasan, Graham B. Quasebarth, Patricia Strack, Jason A. Shar Sep 2022

Atherogenic Potential Of Microgravity Hemodynamics In The Carotid Bifurcation: A Numerical Investigation, Philippe Sucosky, Varun Vinayak Kalaiarasan, Graham B. Quasebarth, Patricia Strack, Jason A. Shar

Open Access Publishing Fund Collection

Long-duration spaceflight poses multiple hazards to human health, including physiological changes associated with microgravity. The hemodynamic adaptations occurring upon entry into weightlessness have been associated with retrograde stagnant flow conditions and thromboembolic events in the venous vasculature but the impact of microgravity on cerebral arterial hemodynamics and function remains poorly understood. The objective of this study was to quantify the effects of microgravity on hemodynamics and wall shear stress (WSS) characteristics in 16 carotid bifurcation geometries reconstructed from ultrasonography images using computational fluid dynamics modeling. Microgravity resulted in a significant 21% increase in flow stasis index, a 22–23% decrease in …


Overview Of Arbitrarily High-Order Adjoint Sensitivity And Uncertainty Quantification Methodology For Large-Scale Systems, Dan Gabriel Cacuci Sep 2022

Overview Of Arbitrarily High-Order Adjoint Sensitivity And Uncertainty Quantification Methodology For Large-Scale Systems, Dan Gabriel Cacuci

Faculty Publications

This work reviews from a unified viewpoint the concepts underlying the “nth-Order Comprehensive Adjoint Sensitivity Analysis Methodology for Response-Coupled Forward/Adjoint Linear Systems” (nth-CASAM-L) and the “nth-Order Comprehensive Adjoint Sensitivity Analysis Methodology for Nonlinear Systems” (nth-CASAM-N) methodologies. The practical application of the nth-CASAM-L methodology is illustrated for an OECD/NEA reactor physics benchmark, while the practical application of the nth-CASAM-N methodology is illustrated for a nonlinear model of reactor dynamics that exhibits periodic and chaotic oscillations. As illustrated both by the general theory and by the examples reviewed in this work, both the nth-CASAM-L and nth-CASAM-N methodologies overcome the curse of dimensionality …


Influence Of Nano-Sized Sic On The Laser Powder Bed Fusion Of Molybdenum, Nathan E. Ellsworth, Ryan A. Kemnitz, Cayla C. Eckley, Brianna M. Sexton, Cynthia T. Bowers, Joshua R. Machacek, Larry W. Burggraf Sep 2022

Influence Of Nano-Sized Sic On The Laser Powder Bed Fusion Of Molybdenum, Nathan E. Ellsworth, Ryan A. Kemnitz, Cayla C. Eckley, Brianna M. Sexton, Cynthia T. Bowers, Joshua R. Machacek, Larry W. Burggraf

Faculty Publications

Consolidation of pure molybdenum through laser powder bed fusion and other additive manufacturing techniques is complicated by a high melting temperature, thermal conductivity and ductile-to-brittle transition temperature. Nano-sized SiC particles (0.1 wt%) were homogeneously mixed with molybdenum powder and the printing characteristics, chemical composition, microstructure, mechanical properties were compared to pure molybdenum for scan speeds of 100, 200, 400, and 800 mm/s. The addition of SiC improved the optically determined density and flexural strength at 400 mm/s by 92% and 80%, respectively. The oxygen content was reduced by an average of 52% over the four scan speeds analyzed. Two mechanisms …


Microgrid Energy Management During High-Stress Operation, Thomas Price, Gordon Parker, Gail Vaucher, Robert Jane, Morris Berman Sep 2022

Microgrid Energy Management During High-Stress Operation, Thomas Price, Gordon Parker, Gail Vaucher, Robert Jane, Morris Berman

Michigan Tech Publications, Part 1

We consider the energy management of an isolated microgrid powered by photovoltaics (PV) and fuel-based generation with limited energy storage. The grid may need to shed load or energy when operating in stressed conditions, such as when nighttime electrical loads occur or if there is little energy storage capacity. An energy management system (EMS) can prevent load and energy shedding during stress conditions while minimizing fuel consumption. This is important when the loads are high priority and fuel is in short supply, such as in disaster relief and military applications. One example is a low-power, provisional microgrid deployed temporarily to …


Technoeconomic Analysis Of Changing Pv Array Convective Cooling Through Changing Array Spacing, Matthew Prilliman, Sarah E. Smith, Brooke Stanislawski, Janine M.F. Keith, Timothy J. Silverman, Marc Calaf, Raul Bayoan Cal Sep 2022

Technoeconomic Analysis Of Changing Pv Array Convective Cooling Through Changing Array Spacing, Matthew Prilliman, Sarah E. Smith, Brooke Stanislawski, Janine M.F. Keith, Timothy J. Silverman, Marc Calaf, Raul Bayoan Cal

Mechanical and Materials Engineering Faculty Publications and Presentations

Accuracy in photovoltaic (PV) module temperature modeling is crucial to achieving precision in energy performance yield calculations and subsequent economic evaluations of PV projects. While there have been numerous approaches to PV temperature modeling based on both the steady-state and transient thermal assumptions, there have been few attempts to account for changing convective cooling on PV module surfaces resulting from changes in the PV system layout. Changes in system row spacing, in particular, can have a meaningful impact on module electrical efficiency and subsequent economic performance, even when considering additional costs from the changes in row spacing. Using a heat …


Advances In High-Order Sensitivity Analysis For Uncertainty Quantification And Reduction In Nuclear Energy Systems, Dan Gabriel Cacuci Sep 2022

Advances In High-Order Sensitivity Analysis For Uncertainty Quantification And Reduction In Nuclear Energy Systems, Dan Gabriel Cacuci

Faculty Publications

No abstract provided.


Micro-Triboelectric Generator For Zero-Power Shock Detection, Mohammad Alzgool, Mohammad Mousavi, Benyamin Davaji, Shahrzad Towfighian Sep 2022

Micro-Triboelectric Generator For Zero-Power Shock Detection, Mohammad Alzgool, Mohammad Mousavi, Benyamin Davaji, Shahrzad Towfighian

Mechanical Engineering Faculty Scholarship

This work shows zero-power shock sensing for the combination of a micro-triboelectric generator and MEMS electrostatic actuator system where the mechanical shock to the generator causes it to produce volt- age, this voltage is used to actuate a Micro-Electro-Mechanical-system (MEMS) switch. For the first time, we present the fabrication process of a Triboelectric-Nano-Generator (TENG) with MEMS technology. The MEMS-TENG has a suspended 1.5mm × 1.5mm plate separated by 2 μm from the substrate. The generator is a triboelectric transducer made of a suspended Al micro-plate above a polyimide (PI) thin layer that is covered by another Al layer in the …


Identifying Fibre Orientations For Fracture Process Zone Characterization In Scaled Centre-Notched Quasi-Isotropic Carbon/Epoxy Laminates With A Convolutional Neural Network, Xiaodong Xu, Aser Abbas, Juhyeong Lee Sep 2022

Identifying Fibre Orientations For Fracture Process Zone Characterization In Scaled Centre-Notched Quasi-Isotropic Carbon/Epoxy Laminates With A Convolutional Neural Network, Xiaodong Xu, Aser Abbas, Juhyeong Lee

Mechanical and Aerospace Engineering Faculty Publications

This paper presents a novel X-ray Computed Tomography (CT) image analysis method to characterize the Fracture Process Zone (FPZ) in scaled centre-notched quasi-isotropic carbon/epoxy laminates. A total of 61 CT images of a small specimen were used to fine-tune a pre-trained Convolutional Neural Network (CNN) (i.e., VGG16) to classify fibre orientations. The proposed CNN model achieves a 100% accuracy when tested on the CT images of the same scale as the training set. However, the accuracy drops to a maximum of 84% when tested on unlabelled images of the specimens having larger scales potentially due to their lower resolutions. Another …


Tunable Filtration Of Particles During Dip-Coating, Connor Copeland Sep 2022

Tunable Filtration Of Particles During Dip-Coating, Connor Copeland

All Theses

When a solid substrate is withdrawn from a liquid bath a thin coating is deposited whose thickness is given by the Landau-Levich-Derjaguin (LLD) law. We perform an experimental study of dip coating of particle suspensions showing that particles of a given size can become entrained in the meniscus by the competition between viscous and surface tension forces. This is called capillary filtration and can be used as a tunable dynamic filter. For single particle suspensions, filtration can be in terms of either clumps or single particles, with the relevant entrainment points depending upon the rheology of the working fluid, either …


Developing Scaling Laws To Predict Compressive Mechanical Properties And Determine Geometrical Parameters Of Modified Bcc Lattice Structures, Hasanain Abdulhadi, Abdalsalam Fadeel, Tahseen A. Alwattar, Ahsan Mian Sep 2022

Developing Scaling Laws To Predict Compressive Mechanical Properties And Determine Geometrical Parameters Of Modified Bcc Lattice Structures, Hasanain Abdulhadi, Abdalsalam Fadeel, Tahseen A. Alwattar, Ahsan Mian

Mechanical and Materials Engineering Faculty Publications

The objective of this study is to develop generalized empirical closed-form equations to predict the compressive mechanical properties and determine geometrical parameters. To achieve that, 117 models are built and analyzed using ABAQUS/CAE 2016 to provide two types of reliable data: one for lattice mechanical properties based on finite element method and the other for geometrical parameters using the measurements of ABAQUS diagnostic tool. All the models are created by modifying the basic feature of body-centered cubic lattice structure based on a range of strut angles, a set of relative densities, and two design sets. Also, the influence of lattice …


Development Of Method To Characterize Adhesion Of Electrically Conductive Adhesive For Flexible Electronics, Joshua Corbin Sep 2022

Development Of Method To Characterize Adhesion Of Electrically Conductive Adhesive For Flexible Electronics, Joshua Corbin

Summer Community of Scholars Posters (RCEU and HCR Combined Programs)

No abstract provided.


Turning Of Carbon Fiber Reinforced Polymer (Cfrp) Composites: Process Modeling And Optimization Using Taguchi Analysis And Multi-Objective Genetic Algorithm, S. M. Abdur Rob, Anil K. Srivastava Sep 2022

Turning Of Carbon Fiber Reinforced Polymer (Cfrp) Composites: Process Modeling And Optimization Using Taguchi Analysis And Multi-Objective Genetic Algorithm, S. M. Abdur Rob, Anil K. Srivastava

Manufacturing & Industrial Engineering Faculty Publications

Carbon Fiber Reinforced Polymer (CFRP) composites have been widely used in aerospace, automotive, nuclear, and biomedical industries due to their high strength-to-weight ratio, corrosion resistance, durability, and excellent thermo-mechanical properties in non-oxidative atmospheres. Machining of CFRP composites has always been a challenge for manufacturers. In this research, a comparative study was performed between the optimal machining parameters of coated and uncoated carbide inserts obtained from the Multi-Objective Genetic Algorithm during turning of CFRP composites. It was found that coated carbide inserts provide lower tool wear and surface roughness, but higher cutting forces compared to those of uncoated carbide inserts …


Automated Posture Positioning For High Precision 3d Scanning Of A Freeform Design Using Bayesian Optimization, Zhaohui Geng, Bopaya Bidanda Sep 2022

Automated Posture Positioning For High Precision 3d Scanning Of A Freeform Design Using Bayesian Optimization, Zhaohui Geng, Bopaya Bidanda

Manufacturing & Industrial Engineering Faculty Publications

Three-dimensional scanning is widely used for the dimension measurements of physical objects with freeform designs. The output point cloud is flexible enough to provide a detailed geometric description for these objects. However, geometric accuracy and precision are still debatable for this scanning process. Uncertainties are ubiquitous in geometric measurement due to many physical factors. One potential factor is the object’s posture in the scanning region. The posture of target positioning on the scanning platform could influence the normal of the scanning points, which could further affect the measurement variances. This paper first investigates the geometric and spatial factors that could …


Minimax Registration For Point Cloud Alignment, Zhaohui Geng, Mauro Garcia, Bopaya Bidanda Sep 2022

Minimax Registration For Point Cloud Alignment, Zhaohui Geng, Mauro Garcia, Bopaya Bidanda

Manufacturing & Industrial Engineering Faculty Publications

The alignment, or rigid registration, of three-dimensional (3D) point clouds plays an important role in many applications, such as robotics and computer vision. Recently, with the improvement in high precision and automated 3D scanners, the registration algorithm has become critical in a manufacturing setting for tolerance analysis, quality inspection, or reverse engineering purposes. Most of the currently developed registration algorithms focus on aligning the point clouds by minimizing the average squared deviations. However, in manufacturing practices, especially those involving the assembly of multiple parts, an envelope principle is widely used, which is based on minimax criteria. Our present work …


Additive Manufacturing Of Molybdenum For High Temperature Structural Applications, Megan L. Bustin Sep 2022

Additive Manufacturing Of Molybdenum For High Temperature Structural Applications, Megan L. Bustin

Theses and Dissertations

This research considered additive manufactured (AM) molybdenum (Mo) and the effect of three variables on microstructure, mechanical properties, and the relationship between the two. Test temperature, laser speed, and shield gas or build atmosphere were varied, and samples tested and analyzed using a three-point bending test, chemical composition, and optical and scanning electron microscopy. The relationship among variables and results using a Design of Experiments was limited compared to the inclusion of every tested sample. Most effects were expected: samples tested at room temperature were brittle without statistical significance; increasing laser speed resulted in decreased ductility and strain, smaller grain …


Effects Of Rotor-Airframe Interaction On The Aeromechanics And Wake Of A Quadcopter In Forward Flight, Denis-Gabriel Caprace, Andrew Ning, Philippe Chatelain, Grégoire Winckelmans Sep 2022

Effects Of Rotor-Airframe Interaction On The Aeromechanics And Wake Of A Quadcopter In Forward Flight, Denis-Gabriel Caprace, Andrew Ning, Philippe Chatelain, Grégoire Winckelmans

Faculty Publications

From small drones to large Urban Air Mobility vehicles, the market of vertical take-off and landing (VTOL) aircraft is currently booming. Modern VTOL designs feature a variety of configurations involving rotors, lifting surfaces and bluff bodies. The resulting aerodynamics are highly impacted by the interactions between those components and their wakes. This has consequences on the aircraft performance and on the downstream wake. Studying the effects of those interactions through CFD can inform the development of cheaper numerical models. In this work, we focus on the interaction between rotors and bluff bodies based on the example of a generic quadcopter …


Sensitivity Analysis, Uncertainty Quantification And Predictive Modeling Of Nuclear Energy Systems, Dan Gabriel Cacuci Sep 2022

Sensitivity Analysis, Uncertainty Quantification And Predictive Modeling Of Nuclear Energy Systems, Dan Gabriel Cacuci

Faculty Publications

No abstract provided.


Developing A Self-Navigating Robot To Map Disaster Regions, Lily Compher Sep 2022

Developing A Self-Navigating Robot To Map Disaster Regions, Lily Compher

Summer Community of Scholars Posters (RCEU and HCR Combined Programs)

No abstract provided.


Ultrafast Laser Ablation Of Inconel 718 For Surface Improvement, Sampson Canacoo, Enrique Contreras Lopez, Oscar Coronel, Farid Ahmed, Jianzhi Li, Anil K. Srivastava Sep 2022

Ultrafast Laser Ablation Of Inconel 718 For Surface Improvement, Sampson Canacoo, Enrique Contreras Lopez, Oscar Coronel, Farid Ahmed, Jianzhi Li, Anil K. Srivastava

Manufacturing & Industrial Engineering Faculty Publications

Inconel 718 is considered difficult to machine because of its ability to maintain its properties at high temperatures. The low thermal conductivity of the alloy causes accelerated tool deterioration when machining. Selective laser melting (SLM) additive manufacturing introduces a possibility of eliminating these difficulties, and producing complex shapes with this difficult-to-machine material. However, high surface roughness and porosity usually occur at the surface of components produced through additive manufacturing. In this study, the surfaces of Inconel 718 samples produced through selective laser melting were treated using laser ablation. The process parameters for the laser ablation process were analyzed in …


Identifying Population Hollowing Out Regions And Their Dynamic Characteristics Across Central China, Bin Guo, Yi Bian, Lin Pei, Xiaowei Zhu, Dingming Zhang, Wencai Zhang, Xianan Guo, Qiuji Chen Sep 2022

Identifying Population Hollowing Out Regions And Their Dynamic Characteristics Across Central China, Bin Guo, Yi Bian, Lin Pei, Xiaowei Zhu, Dingming Zhang, Wencai Zhang, Xianan Guo, Qiuji Chen

Mechanical and Materials Engineering Faculty Publications and Presentations

Continuous urbanization and industrialization lead to plenty of rural residents migrating to cities for a living, which seriously accelerated the population hollowing issues. This generated series of social issues, including residential estate idle and numerous vigorous laborers migrating from undeveloped rural areas to wealthy cities and towns. Quantitatively determining the population hollowing characteristic is the priority task of realizing rural revitalization. However, the traditional field investigation methods have obvious deficiencies in describing socio-economic phenomena, especially population hollowing, due to weak efficiency and low accuracy. Here, this paper conceives a novel scheme for representing population hollowing levels and exploring the spatiotemporal …


Tactics Ideation Experiment Data, Thomas L. Ashworth, Carl D. Sorensen Sep 2022

Tactics Ideation Experiment Data, Thomas L. Ashworth, Carl D. Sorensen

ScholarsArchive Data

This data includes the template worksheets, as well as filled worksheets that include ideas written by the participants in a research experiment. This experiment tested the effectiveness of a novel tactics ideation method (i.e., Random Prompts method) to a modified Brainwriting method. Transcribed copies of this data are also included.

Accompanying the data are experiment briefing presentations, Python code for rapid evaluation of the data (the evaluation methods themselves were also developed by the authors), a spreadsheet file with evaluation data (this is a necessary input to the code), and organizational trees (for team idea sets) associated with the evaluation …


In-Situ Measurements Of Temperature And Emissivity During Msw Combustion Using Spectral Analysis And Multispectral Imaging Processing, Shu Zheng, Weiguang Cai, Ran Sui, Zixue Luo, Qiang Lu Sep 2022

In-Situ Measurements Of Temperature And Emissivity During Msw Combustion Using Spectral Analysis And Multispectral Imaging Processing, Shu Zheng, Weiguang Cai, Ran Sui, Zixue Luo, Qiang Lu

Mechanical and Aerospace Engineering Faculty Research & Creative Works

By using a novel multispectral imaging technology, the 2-D distributions of flame temperature and emissivity were measured in a 16 MW incinerator to co-fire municipal solid waste (MSW) and municipal sludge. A way to establish the relationship between the multispectral flame images and the temperature was proposed by combing the Newton iteration method and Hottel emissivity model. The results showed that the measured temperatures at different locations varied by 31.25% with a fixed steam evaporation rate, and 11.76% with different steam evaporation rates at a given port. The temperatures and emissivities decreased at upper locations due to the lower local …


Improved Additive Manufacturing Of Silicon Carbide Parts Via Pressureless Electric Field-Assisted Sintering, Adam Bratten, Ruoyu Chen, Joshua Rittenhouse, Ming-Chuan Leu, Haiming Wen Sep 2022

Improved Additive Manufacturing Of Silicon Carbide Parts Via Pressureless Electric Field-Assisted Sintering, Adam Bratten, Ruoyu Chen, Joshua Rittenhouse, Ming-Chuan Leu, Haiming Wen

Mechanical and Aerospace Engineering Faculty Research & Creative Works

High solids loading silicon carbide (SiC)-based aqueous slurries containing only.5 wt. % organic additives were utilized to create specimens of various geometries via an extrusion-based additive manufacturing (AM) technique. Pressure less electric field-assisted sintering was performed to densify each specimen without deformation. The combination of these techniques produced parts with >98% relative density despite containing only 5 wt.% oxide sintering additives. After sintering, specimens contained only the α-SiC and yttrium aluminum perovskite phases. This suggests the evolution of a nonequilibrium yttrium aluminate phase, as well as transformation from β-SiC to α-SiC. The fabrication method presented in this work has advantages …


Tuning The Thermodynamic, Optical, And Rheological Properties Of Thermoresponsive Polymer Solutions Via Silica Nanoparticle Shape And Concentration, Christopher A P Neal, Valeria León, Michelle C. Quan, Nondumiso O. Chibambo, Michelle A. Calabrese Sep 2022

Tuning The Thermodynamic, Optical, And Rheological Properties Of Thermoresponsive Polymer Solutions Via Silica Nanoparticle Shape And Concentration, Christopher A P Neal, Valeria León, Michelle C. Quan, Nondumiso O. Chibambo, Michelle A. Calabrese

Mechanical Engineering Faculty Publications

Hypothesis

The shape and quantity of hydrophilic silica nanoparticles (NPs) can be used to tune the microstructure, rheology, and stability of phase-separating polymer solutions. In thermoresponsive polymer systems, silica nanospheres are well-studied whereas anisotropic NPs have little literature precedent. Here, we hypothesize that NP shape and concentration lower the onset of rheological and turbidimetric separation of aqueous poly(N-isopropyl acrylamide) (PNIPAM) solutions.

Experiments

Differential scanning calorimetry (DSC), Fourier-transform infrared spectroscopy (FTIR), turbidimetry, and oscillatory rheology are utilized to examine interactions between NPs, PNIPAM, and water and to track changes in phase separation and mechanical properties due to NP concentration and shape. …


Modeling Of Two-Dimensional And Biological Materials Towards Diverse Nano-Systems Applications, Jatin Kashyap Aug 2022

Modeling Of Two-Dimensional And Biological Materials Towards Diverse Nano-Systems Applications, Jatin Kashyap

Dissertations

This dissertation studies the demonstration of materials ranging from two-dimensional (2D) materials to small bio-molecules using various atomistic/molecular and sub-atomic particles (electron, hole, excitons) modeling techniques for multi-domain applications. Three categories of materials/systems are investigated as follows: 2D materials, biological materials, and complexes of 2D and biological materials.

The first problem demonstrates wrinkles' ubiquitous presence in two-dimensional materials significantly alters their properties. It is observed that water molecules, sourced from ambient humidity or transfer method, can get diffused in between Graphene and the substrate during the Graphene growth. The water diffusion causes/assists wrinkle formation in Graphene, which influences its properties. …