Power and Energy Commons^™

Novel Composites Between Nano-Structured Nickel Sulfides And Three-Dimensional Graphene For High Performance Supercapacitors, Xiaomin Wang, Huanglin Dou, Zhen Tian, Jiujun Zhang

Journal of Electrochemistry

In this paper, a three-dimensional graphene (3DG) network grown on nickel foam was employed as a template for synthesizing graphene-based composite materials of supercapacitor electrode. The composites (crystal Ni₃S₂ nanorods on the surface of 3DG (abbreviated as Ni₃S₂/3DG)) were obtained through a one-step hydrothermal reaction. The morphological and structural evolution of the Ni₃S₂/3DG composites were investigated by SEM, TEM, XRD and Raman spectroscopy. Detailed electrochemical characterization showed that the Ni₃S₂/3DG-coated electrodes exhibited both a specific capacitance as high as 1825 F·g^-1 at 5 mV·s …

Designing Pt-Skin Of Pt-Based Bimetallic Electrocatalysts For Oxygen Reduction Reaction, Binwei Zhang, Yunxiao Wang, Yanfei Xu, Huakun Liu, Shixue Dou

Journal of Electrochemistry

In the past decade, great advancement has been made in the development of nanocatalysts for energy conversion and storage. Pt-skin of Pt-based bimetallic has shown a great potential in the tuning the electronic structures of electrocatalytically active materials toward oxygen reduction reaction. Here, we offer a brief overview of the recent research on the design and preparation of catalysts. Our focus is paid on the systematic studies of preparation and performance of Pt-skin catalysts towards oxygen reduction reaction.

Recent Progress In Template-Assisted Synthesis Of Nitrogen-Doped Porous Carbons For Oxygen Electroreduction, Wenhan Niu, Ligui Li, Shaowei Chen

Journal of Electrochemistry

Nitrogen (N)-doped porous carbons are potential alternatives to precious metal catalysts for oxygen reduction reaction (ORR) at the cathodes of proton exchange membrane fuel cells and metal-air batteries. Template-assisted synthesis has been used extensively as a robust and versatile method in the preparation of such carbon catalysts, where the ORR activity has been found to be dependent on various structural parameters, such as the concentrations and molecular configurations of the dopants, and the porosity, surface accessibility and electrical conductivity of the carbon materials. In this review, we summarize recent progress in this area of research focusing on the design, preparation …

Comparative Studies Of Fe, Ni, Co And Their Bimetallic Nanoparticles For Electrochemical Water Oxidation, Maduraiveeran Govindhan, Brennan Mao, Aicheng Chen

Journal of Electrochemistry

The design of efficient, durable, and earth-abundant electrocatalysts via environmentally compatible strategies for the oxygen evolution reaction (OER) is a vital for energy conversion processes. Herein we report a facile approach for the fabrication of low-cost and earth abundant metal catalysts, including iron (Fe), nickel (Ni), cobalt (Co), CoNi, and CoFe nanoparticles (NPs) on titanium (Ti) substrates through a one-step electrochemical deposition. Field-emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD) spectrocopy, X-ray photoelectron spectroscopy (XPS), and electrochemical techniques were employed to characterize these nanoparticles. Our electrochemical results revealed that among the five synthesized nanomaterials, the …

Impact Of Nafion Loading And Anion Adsorption On The Synthesis Of Pt Monolayer Core-Shell Catalysts, Lijun Yang, Dustin Banham, Elod Gyenge, Siyu Ye

Journal of Electrochemistry

Carbon supported palladium (Pd) nanoparticles were used as a model core material for the synthesis of platinum (Pt) monolayer core-shell catalysts using rotating disk electrode method and a copper (Cu) under potential deposition technique. The impact of Nafion on the synthesis process was revealed by electrochemical testing with various Nafion contents. The existence of Nafion influenced the Cu under potential deposition, galvanic replacement and eventually the oxygen reduction reaction activity of the core-shell catalyst. However, as long as the Nafion content was less than 5 wt% in the test film, adding Nafion could help to bind catalyst onto the surface …

Comparison Of Oxygen Reduction Reaction Activity Of Pt-Alloy Nanocubes, Yongan Tang, Lin Dai, Shouzhong Zou

Journal of Electrochemistry

Alloying Pt with the first row non-noble transition metals has been demonstrated to increase the catalytic activity toward oxygen reduction reaction (ORR), which is the cathode reaction of the proton exchange membrane fuel cells (PEMFCs) and metal-air batteries. However, how much the ORR activity improvement comes from the alloying elements remains controversial. In this paper, the nanocubes of PtMn, PtFe, PtCo, and PtNi with the similar size and composition were prepared and their ORR activities were explored, in order to investigate the effects of alloying elements on the catalytic activity. The use of cubic shape particles minimizes the contribution to …

Electrodeposition Of Ruo2 Layers On Tio2 Nanotube Array Toward Co2 Electroreduction, Bei Jiang, Lina Zhang, Xianxian Qin, Wenbin Cai

Journal of Electrochemistry

RuO₂/TiO₂ composite materials have multitude of electrocatalytic applications including but not limited to CO₂ reduction reaction (CO₂RR). RuO₂/TiO₂ electrodes were previously prepared by repetitive coating and thermal decomposition (TD) of a Ru(III) precursor solution on Ti substrate. In this work, electrochemical potential cycling is applied to deposit amorphous RuO₂ (α-RuO₂) layers onto TiO₂ nanotube array (TNA) (RuO₂^CV/TNA) preformed on Ti foil. SEM, GIXRD, and voltammetry are applied to characterize the structures of the resulting RuO₂^CV/TNA. Ru loading on the RuO_{2 …}

5g-Ucda Multi Antenna-To-Logical Cell Circular Fifo Mapping Strategy For High-Speed Train Wireless Communications, Subharthi Banerjee

Department of Electrical and Computer Engineering: Dissertations, Theses, and Student Research

2020 is the target year for the roll out of fifth generation wireless communication methodologies. The commercial vendors have characterized 5G as a collection of disruptive set of technologies to provide high throughput, low latency communication supporting a variety of services, i.e., machine to machine communication to next generation base stations and vehicle-to-vehicle communication to radio-over-fiber and high mobility channels. High-speed train wireless communication channels as a subset of high mobility channels have their clear advantages and disadvantages considering other vehicular channels. The speed of high-speed trains is going to reach 500km/hr and with Hyperloop it may reach 1000km/hr. LTE …

Optimal Control For Wind Turbine System Via State-Space Method, Mudhafar Lazam Shanoob

Theses and Dissertations

Renewable energy is becoming a fascinating research interest in future energy production because it is green and does not pollute nature. Wind energy is an excellent example of renewable resources that are evolving. Throughout the history of humanity, wind energy has been used. In ancient time, it was used to grind seeds, sailing etc. Nowadays, wind energy has been used to generate electrical power. Researchers have done a lot of research about using a wind source to generate electricity. As wind flow is not reliable, there is a challenge to get stable electricity out of this varying wind. This problem …

Design And Experiments Of A Sic Power Mosfet-Based Bidirectional Switching Power Pole (Bspp), Hussain Khthear Sayed Subhii

Theses and Dissertations

This research presents the design and experiments of a SiC power MOSFET-based bidirectional switching power pole (BSPP) by benefiting from the advantages of SiC power MOSFETs: high-speed switching, high power density, high operating temperatures, and low power losses. The main goal of this research is to design a printed circuit board (PCB) prototype with a minimum parasitic inductance to improve the switching transient performance of the SiC MOSFETs for the BSPP application. The effects of the parasitic inductance of the PCB power traces were investigated, for the BSPP application, based on the experimental, simulation, and theoretical analyses. The PCB prototypes …

Hand Cranked Generator For Mobile Devices, Kyle Brown, Monique Butoto, Stephen Cain, Steven Corio, Brock Stevenson

Thinking Matters Symposium Archive

It’s estimated that over 90% of American adults own cell phones while over 70% of the United States land area belongs to rural counties. It is a challenge to charge mobile devices in these remote and rural areas given the lack of access to power sources. This lack of power in remote destinations limits the general use of mobile devices for outdoor enthusiasts, as well as a survival means for all who need access to a portable power generation device, especially in emergency situations. There are other portable generators currently available on the market, but our project wanted to take …

5‐Minute Power Ouptut Data For A 1.72kwp Pv System With Weather Variables, Lacour Ayompe, Aidan Duffy, Kevin O'Farrell

Other resources

This dataset contains 5-minute power (AC and DC) power output date from a 1.72kWp PV system located in Dublin in 2009-10 together with input weather variables and system parameters. Details below.

Geographical site: FOCAS Institute building roof top, Dublin Institute of Technology, Kevin Street, Dublin 2, Ireland.

Situation: Latitude 53.4degN Longitude -6degE

Time zone GMT

Installation date: 4th April 2008

PV array orientation: Tilt 53deg Azimuth 0deg

Near shadings: No shadings

Building height: Approximately 12 m

PV array capacity: 1.72 kWp

Collection period: 4^th April 2009 – 3^rd April 2010

The data acquisition system consisted of a Sunny …

Centralized Control For Dc Microgrid Using Finite State Machine, Mahmoud Saleh, Yusef Esa, Ahmed Mohamed

Publications and Research

In this paper, an autonomous communication-based centralized control for DC microgrids (MG) has been developed and implemented. The proposed controller enables smooth transition between various operating modes. Finite state machine (FSM) has been used to mathematically describe the various operating modes (states), and events that may lead to mode changes (transitions). Therefore, the developed centralized controller aims at optimizing the performance of MG during all possible operational scenarios, while maintaining its reliability and stability. Results of selected cases have been presented. These results show stable transition between modes, verifying the validity and applicability of the proposed controller.

Deposition Of Silicon Thin Films By Ion Beam Assisted Deposition, Tejaswini Miryala

Electrical & Computer Engineering Theses & Dissertations

With the depletion of non-renewable energy sources owing to increasing demands, we need to develop renewable energy sources, which can replace them with cleaner energy sources. The solar industry is one of these renewable energies. In spite of having very high potential, harvesting solar energy has been a challenge due to the cost of solar cells. Silicon dominates the photovoltaic industry, but even this technology can accommodate great improvements. This can be done notably by finding low cost deposition techniques for the silicon. The main aim of this thesis is to form high-quality nanocrystalline silicon thin films with the help …

Modification Of Deposition Process Parameters For Uniform Indium Layer Deposition, Isaac Butt

Electrical & Computer Engineering Theses & Dissertations

The need for more efficient light to energy converting cells has long been a subject of research and development. With abundant availability of solar energy that the earth receives, the photovoltaic industry has sought materials that could serve the purpose of great energy conversion. The photovoltaic industry is mainly dominated by Silicon owing to its abundant availability, reliability and economic cost. However, due to limitations on efficiency improvements, some focus has shifted toward III-V based solar cells with a great potential for attaining higher efficiency and multi-junction applications. However, the cost of the III-V materials is extremely high due to …

A Study Of The Sensitivity Of Energy Conversion Efficiency To Load Variation In Class-E Resonant Power Inverter, Richard Samuel Jennings

Electrical & Computer Engineering Theses & Dissertations

In this thesis the sensitivity of energy conversion efficiency (ECE) and output power of a class-E resonant inverter under variable resistive and inductive load assignments is examined for wireless power transfer (WPT) applications. By performing simulation and mathematical analysis, it was found that the on-resistance of the switching device has minor effect on the design’s efficiency. Additional comparisons between the simulation and mathematical analysis show reasonable output power and ECE load variation performance for the design, but with unique load impedances where zero voltage switching (ZVS) and zero derivative switching (ZDS) are achieved. These comparisons also expose inaccurate mathematical assumptions. …

Study Of A High-Efficient Wide-Bandgap Dc-Dc Power Converter For Solar Power Integration, Yashwanth Bezawada

Electrical & Computer Engineering Theses & Dissertations

This research focuses on the design and analysis of a Boost cascaded Buck-Boost (BoCBB) power converter with super high efficiency in electric power conversion. The BoCBB power converter is based on emerging wide-bandgap silicon-carbide (SiC) MOSFETs and Schottky diodes, which have only 1/6 times of power loss in traditional silicon power semiconductor devices. The BoCBB power converter can be widely applied in solar harvesting for the National Aeronautics and Space Administration (NASA), military bases and electric utilities, as well as high-power DC motor drives for the electric vehicles, robotics, and manufacturing and product lines.

This research analyzed the topology and …

Investigation Of Low Cost Substrate Approaches For Iii-V Solar Cells, Marlene Lydia Lichty

Electrical & Computer Engineering Theses & Dissertations

With the need for cleaner energy sources, which can displace fossil fuel, the solar cell industry is of particular interest due to the abundancy of the Sun. Silicon currently dominates terrestrial applications, but efficiency improvements have saturated. III-V based solar cells have reported the highest efficiencies, however, high costs due to substrates and fabrication processes have limited these devices to specialty applications, such as space. In order to reduce the cost associated with fabricating III-V semiconductor substrate material, two different approaches were taken in this work with a particular focus on making III-Vs more applicable outside of specialty applications, including …

Building Energy Model Calibration For Retrofit Decision Making, Nicolas R. Johnson

Dissertations and Theses

Accommodating the continued increase in energy demand in the face of global climate change has been a worldwide concern. With buildings in the US consuming nearly 40% of national energy, a concerted effort must be given to reduce building energy consumption. As new buildings continue to improve their efficiency through more restrictive energy codes, the other 76.9 billion square feet of current building stock falls further behind. The rate at which current buildings are being retrofit is not enough and better tools are needed to access the benefits of retrofits and the uncertainties associated with them. This study proposes a …

Predicting Solar Performance In A Contingency Environment To Meet Net-Zero Facility Power, Anthony D. Williams

Theses and Dissertations

The U.S. government is involved in contingency operations all over the world and these operations require operational support and sustainment in these locations; this includes the reliable delivery of power to base infrastructure. The traditional means of delivering this support requirement in austere environments has been the use of diesel-power generation that has an extensive logistical and economic tail. The research sought out contingency solar applications that may be implemented and operated to offset the facility demand loads in the location to achieve net-zero power. This research explores the technical feasibility of a deployable photovoltaic microgrid to deliver power to …

Power-Aware Datacenter Networking And Optimization, Qing Yi

Dissertations and Theses

Present-day datacenter networks (DCNs) are designed to achieve full bisection bandwidth in order to provide high network throughput and server agility. However, the average utilization of typical DCN infrastructure is below 10% for significant time intervals. As a result, energy is wasted during these periods. In this thesis we analyze traffic behavior of datacenter networks using traces as well as simulated models. Based on the insight developed, we present techniques to reduce energy waste by making energy use scale linearly with load. The solutions developed are analyzed via simulations, formal analysis, and prototyping. The impact of our work is significant …

Energy Harvesting From Exercise Machines: Buck-Boost Converter Design, Andrew E. Forster

Master's Theses

This report details the design and implementation of a switching DC-DC converter for use in the Energy Harvesting From Exercise Machines (EHFEM) project. It uses a four-switch, buck-boost topology to regulate the wide, 5-60 V output of an elliptical machine to 36 V, suitable as input for a microinverter to reclaim the energy for the electrical grid. Successful implementation reduces heat emissions from electrical energy originally wasted as heat, and facilitates a financial and environmental benefit from reduced net energy consumption.

Off Grid Solar Array, Courtney Elliott

Electrical Engineering

No abstract provided.

The Problem Of The Anode Electrolyte In H-Type Electrolytic Cell For Electrochemical Reduction Of Carbon Dioxide, Rui Zhang, Wei-Xin Lv, Li-Xu Lei

Journal of Electrochemistry

Electrochemical reduction of carbon dioxide (CO₂) was studied in the H-type electrolytic cell. It was found that the voltage between the cathode and the anode would increase during the long time electrolysis process, for this reason the electrolytic process would be unsustainable. After the experimental investigations carried out by constant potential electrolysis, constant current electrolysis, pH test and KHCO₃ concentration analysis of anode electrolyte before and after the electrolysis, the increase in cell voltage might be caused by the following process: H⁺, that was generated from the anodic oxygen evolution reaction, reacted with HCO_{3 …}

Effects Of Flame Retardant On The Rate Capability And Safety Performances Of The Soft-Package 5ah Lithium Ion Battery, Yan-Zhuo Lv, Xiao-He Wang, Yi-Ming Qin, Zhen-Bo Wang, Ke Ke

Journal of Electrochemistry

The 5 Ah soft packed lithium ion batteries with LiNi _0.4Co_0.2Mn_0.4 O₂ as the positive electrode material and the organic electrolytes with different amounts of fire retardants as the electrolyte solution were prepared. The effects of the fire retardant amount (5 %,10 %,20 %) of the fire retardants on the rate performances, short-circuit characteristics and overcharged behaviors of the 5 Ah soft packed lithium ion battery were investigated by electrochemical methods. The results indicated that the best rate performances were obtained by adding 5 vol.% of the fire retardants in the electrolyte solution when the …

Application Of Composite Ionic Liquid In Electro-Oxidation Activation Of A C-H Bond, Zi-Ying Chen, Qian-Qian Wu, Jian-Qing Zhang, Ying-Hong Zhu, Chun-An Ma

Journal of Electrochemistry

In this paper, the ionic liquid/carbon nanotube composite material was prepared through modifying the ionic liquid 1-ethyl-3-methylimidazolium acetate to multi-walled carbon nanotubes. The electro-oxidation properties of p-methoxy toluene (p-MT) were studied using the composite as an electrolyte. The effects of scanning speed, temperature and substrate concentration were studied by cyclic voltammetry and chronoamperometry. The electrochemical kinetics of p-MT in this system was also studied. The results showed that the electrochemical oxidation of p-MT in the composite electrolyte solution was irreversible. The process was mainly controlled by diffusion, and the diffusion coefficient (D) was 7.69×10-10 cm²·s^-1. Increasing …

Electrochemical Nucleation Of Invar Alloy On Glassy Carbon Electrode, Xian-Jie Huang, Hui Yan, Shuai-Shuai Huang, Fang-Zu Yang, Zhong-Qun Tian, Shao-Min Zhou

Journal of Electrochemistry

The linear sweep voltammetry, cyclic voltammetry and potential step methods were used to study the electrodeposition mechanism of Invar nickel-iron alloy (the mass fraction of nickel was 32~36%) on glassy carbon electrode surface in the weak acidic bath. The results demonstrate that the electrodeposition is was a diffusion controlled irreversible electrode process in this system. The Scharifker-Hill (SH) theory theoritic model (SH) were was used employed to fitting the experimental data and the result shows that the codeposition of Invar alloy on glassy carbon electrode surface conformed to the diffusion controlled three-dimensional instantaneous nucleation mechanism. The kinetic parameters were obtained …

Electrochemical Synthesis Of Porous Polyaniline Electrodes Using Hkust-1 As A Template And Their Electrochemical Supercapacitor Property, Qiong Luan, Chun-Feng Xue, Hong-Ye Zhu, Fu-Juan Yang, Xu-Li Ma, Xiao-Gang Hao

Journal of Electrochemistry

Excellent electrode plays vital important role in the performance of supercapacitors. Polyaniline (PANI) with good conductivity is often used to prepare electrode. However, its available surface is limited and results in a poor supercapacitance in many cases. It is desirable to fabricate an electrode containing electroactive PANI with high surface area deriving from its porous structure. Here, the metal-organic framework (MOF) material with high surface area was selected as a hard template for synthesizing porous PANI. Microporous PANI composite electrodes (Micro-PANI/CC) were fabricated by depositing aniline on to carbon cloth (CC) pre-coated with MOF material of HKUST-1 using a unipolar …

Sn-Doped Α-Fe2O3 Photocatalyst Containing Oxygen Vacancy For Water-Splitting, Zu-Hua Wang, Dong-Fang Niu, Hui-Cheng Li, Rong-Bin Du, Heng Xu, Xin-Sheng Zhang

Journal of Electrochemistry

The α-Fe₂O₃ nanoparticles containing oxygen vacancies were synthesized in atmospheric N₂ by dip-dropping method without a high vacuum employed before annealing. The influences of annealing atmosphere and Sn-doping on the photocatalytic performance of α-Fe₂O₃ nanoparticles were studied by annealing the photocatalyst in N₂ or air and adding SnCl₄ to the precursor directly. The results showed that the current density of Sn-doping α-Fe₂O₃ annealed in N₂ at 550 °C and 1.23 V (vs. RHE) was 35 times greater than that of pristine α-Fe₂O₃ annealed in …

Preparation And Electrochemical Properties Of Attapulgite-Supported Nitrogen-Doped Carbon@Nico2O4 Composites For Supercapacitors, Hui Wan, Zong-Rong Ying, Xin-Dong Liu, Jian-Jian Lu, Wen-Wen Zhang

Journal of Electrochemistry

In this work, the attapulgite-supported nitrogen-doped carbon (ANC) was prepared by in-situ chemically polymerizing polyaniline coating upon attapulgite, followed by high temperature heat treatment, and then NiCo₂O₄was reacted onto the surface of ANC by a combination of hydrothermal reaction and calcination to synthesize ANC@NiCo₂O₄ composites. The chemical composition and morphology of the samples were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and N₂ adsorption/desorption. The electrochemical properties were evaluated by means of constant current charge discharge (GCD) and cyclic voltammetry (CV). …