Power and Energy Commons^™

Preparation Of Nis2 Nanosheet And Its Application In Asymmetric Supercapacitor, Yuan-You Wang, Ya-Nan Liu, Dang-Qin Jin

Journal of Electrochemistry

In this work, the NiS₂ nanosheets have been synthesized using Ni(OH)₂  as a precursor through a sacrificial template method. The microstructure and chemical composition of as-prepared NiS₂ were characterized by XRD, EDS, BET, SEM and TEM techniques. The results showed that both Ni(OH)₂  and NiS₂  were composed of nanoplates. The electrochemical tests revealed that NiS₂ exhibited the high specific capacitance of 1067.3 F•g^-1 at a current density of 1 A•g^-1 and excellent rate performance. Furthermore, in order to evaluate the practical application of NiS₂, an asymmetric supercapacitor, NiS₂ as …

Electroactivities Of Pd/Fe3O4-C Catalysts For Electro-Oxidation Of Methanol, Ethanol And Propanol, Tao Zou, Qing-Feng Yi, Yuan-Yuan Zhang, Xiao-Ping Liu, Guo-Rong Xu, Hui-Dong Nie, Xiu-Lin Zhou

Journal of Electrochemistry

Development of palladium (Pd) catalysts with high electroactivity for alcohol oxidation is significant for alcohol fuel cells. In this work, Pd nanoparticles were formed by sodium borohydride (NaBH₄) reduction method and subsequently deposited on the surface of carbon supported ferriferrous oxide (Fe₃O₄/C) composites to obtain the Pd/Fe₃O₄-C catalysts with different Fe₃O₄ loadings. Their transmission electron microscopic (TEM) images show that the Pd nanoparticles were uniformly dispersed on the Fe₃O₄/C. Electroactivities of the prepared Pd/Fe₃O₄-C catalysts toward oxidations of C1-C3 …

Kinetics And Mechanism Toward Electrochemical Reductions Of Sodium Bromide And Methanol Over Iron Electrodes, Qun Liao, Shu-Feng Zhang, Wen-Hua Leng

Journal of Electrochemistry

It is of technological value and scientific interest to the electro-synthesis of ferrocene, conversion of carbon dioxide (CO₂) and organic electro-synthesis in non-aqueous solutions by investigating the kinetics and mechanism toward electrochemical reductions of sodium bromide (NaBr) and methanol over iron electrodes. However, few reports in the related researches are available. In this article, the kinetics and mechanism toward electrochemical reductions of NaBr and methanol over iron electrodes were examined in detail by carrying out the polarization curve and electrochemical impedance spectroscopic measurements. The results showed that methanol was the reactant, while Na⁺ ions were functioned only …

Effect Of Peg-Coating On Properties Of Lithium-Sulfur Battery Cathode Material Containing Carbon Fiber Conductive Agent, Jie-Cheng Tan, Yan-Hong Tian, Xue-Jun Zhang, Kai-Le Fan

Journal of Electrochemistry

The composite materials contained high modulus carbon fiber (HMCF) were successfully prepared by employing a ball-milling process based on the coating treatment of polyethylene glycol (PEG), and their structures and morphologies were characterized by scanning electron microscopy (SEM), X-ray powder diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) techniques．The influences of PEG content on sulfur cathode capacity, cycle stability and rate performance were systematically studied. It was found that by the pre-coating of PEG, the cathode exhibited the high initial discharge specific capacity of 1312.5 mAh⋅g^-1 at a current rate of 0.2C, and the reversible discharge capacity of 650 mAh⋅g …

Capacity Fading Analyses Of Lini0.5Co0.2Mn0.3O2And Lini0.5Co0.2Mn0.3O2/Lifepo4 Cathode Materials For Lithium-Ion Battery, Yi Hu, Xiang-Zhu He, Zhong-De Deng, Ling-Yong Kong, Wei-Li Shang

Journal of Electrochemistry

The LiNi _0.5Co _0.2Mn _0.3O₂/LiFePO₄ (NMC532/LFP) composite cathode material for lithium-ion battery was prepared by wet ball-milling. The capacity fading behaviors of LiNi _0.5Co _0.2Mn _0.3O₂ (NMC532) and LiNi _0.5Co _0.2Mn _0.3O₂/LiFePO₄ (NMC532/LFP) were analyzed by X-ray diffraction (XRD), scanning electron microscope (SEM), charge/discharge and electrochemical impedance spectroscopy (EIS) tests. The results indicated that the capacity retention values of NMC532/LFP were 97.80% and 86.48%, respectively, after 50 cycles and 60℃ high temperature storage. The NMC532/LFP exhibited better cycle performance and high temperature storage performance. …

Cobalt-Based Nitrogen-Doped Carbon Non-Noble Metal Catalysts For Oxygen Reduction Reaction, Meng-Xiu Jiang, Jing Zhang, Yue-Hua Li, Rong Zhang

Journal of Electrochemistry

Transition metal-nitrogen co-doped carbon catalysts have attracted significant attention because of their reasonable activity and remarkable selectivity toward oxygen reduction reaction (ORR) as cathodic reaction in fuel cells. However, the role of transition metal in the active sites of the catalysts still is uncertain. In this work, the Co_x-N_y/C-T catalysts were prepared with BP2000 as a carbon source, urea (Ur) as a nitrogen source and Co(OAc)₂•4H₂O as a metal precursor by a simple chemical method. Meanwhile, in order to optimize the ORR activity, the catalysts were synthesized with different amounts of Co …

Core-Shell Pd@Pt Ultrathin Nanowires As Durable Oxygen Reduction Electrocatalysts, Xin Wang, Yun-Jie Xiong, Liang-Liang Zou, Qing-Hong Huang, Zhi-Qing Zou, Hui Yang

Journal of Electrochemistry

This paper describes a simple CO-assisted reduction approach for the controllable synthesis of ultrathin Pd nanowires along the one-dimensional (1D) direction. Ultrathin Pt films from one to several atomic layers were successfully decorated onto ultrathin Pd nanowires by utilizing Cu UPD deposition, and followed by in-situ redox replacement reaction of UPD Cu by Pt. The core–shell structure and composition of the Pd@Pt ultrathin nanowires have been verified using transmission electron microscopy and energy dispersive X-ray spectrometry. The core–shell Pd@Pt ultrathin nanowires exhibited comparative electrocatalytic activity and improved durability for the oxygen reduction reaction in comparison with commercial Pt black. The …

Effects Of Jet Milling And Classifying Process On The Performance Of Lifepo4/C In Full Batteries, Xing-Liang Liu, Mao-Ping Yang, Wei-Wei Wang, Yong Cao

Journal of Electrochemistry

The carbon coated lithium iron phosphate (LiFePO₄/C) composite cathode material was prepared by using iron phosphate process. The effects of jet milling and classifying process on the electrochemical performance of LiFePO₄/C cathode material in full batteries were investigted. Scanning electron microscopic analyses suggested that the globose secondary particles were crustily crushed during the jet milling and classifying process, which would further result in lower tap density and carbon content. The LiFeP₄/C composite cathode materials with different physical characteristics were further tested in full batteries to evaluate the electrochemical properties. The results showed no obvious …

Engineering The Electrochemical Capacitive Properties Of Activated Carbon By Correct Selection Of Ionic-Liquid Electrolytes, Qiu-Hong Zhang, Bao-Shou Shen, Song-Lin Zuo, Xin-Yu Wei

Journal of Electrochemistry

In order to improve the electrochemical capacitive properties and to apply coconut shell activated carbon (AC) serving as electrode materials in ionic liquid (IL)-based supercapacitor (SC), the coconut shell AC material was re-activated using a steam as an activating agent in this work, forming a secondary AC (W-AC). The results showed that the specific capacitance of the W-AC electrode was much larger than that of the raw activated carbon electrode (R-AC) in 1-ethyl-3-methylimidazolium tetrafluoroborate ([EMIM]BF₄). The electrochemical techniques including cyclic voltammetry (CV), galvanostatic charge/discharge (GCD) measurement, and electrochemical impedance spectroscopy (EIS) were used to systematically study the capacitive …

Applications Of N-Methyl-N-Butyl-Pyrrolidinium Bromide And N-Methyl-N-Ethyl-Pyrrolidinium Bromide In Zn-Br Flow Batteries, Qi Zhang, Miao-Miao Zhang, Lin Meng

Journal of Electrochemistry

It is extremely important for battery performance and safety in Zn-Br flow battery to use quaternary ammonium salts as complex agents for bromine. In this work, the effects of electrolyte compositions and concentrations on the electrode reactions and battery performances were studied in the absence and presences of N-methyl-N-ethyl-pyrrolidinium bromide (MEP) or N-methyl-N-butyl-pyrrolidinium bromide (MBP). The conductivities in the electrolytes containing different constitutions and concentrations were measured by EIS method. The charge-discharge performance for the battery and the complex ability for bromine in different electrolytes were also investigated. The results showed that the electrolyte containing MBP was better than that …

Effect Of Fe2+/Fe3+Interconvertion On Reduction Behavior Of Fe3+ In Acidic Electrolytes, Jian-Xin Qin, Feng Lin, Wen-Ping Liu, Chao Chen, Meng-De Ren

Journal of Electrochemistry

The influences of ferrous/ferric (Fe²⁺/Fe³⁺) interconvertion on electrochemical reduction and electrode reaction of Fe³⁺ were investigated by using linear sweep voltammetry, potentiostatic method and cyclic voltammetry (CV) in acidic electrolytes containing chloride ion (Cl^-) and sulfate ion (SO₄^2-). It was shown that the reduction process of Fe³⁺/Fe²⁺ would take place in two independent stages: (1) the reduction of Fe³⁺ to Fe²⁺ at E=0.35V and (2) the co-precipitation of Fe²⁺ by forming Fe(OH)₂ (E≤-0.3 V) instead of Fe. The major effect of Fe^{2+ …}

Parameter Estimation Technique For Models In Pss/E Using Real-Time Data And Automation, Malavika Vasudevan Menon

LSU New Orleans Theses and Dissertations

The purpose of this thesis is to use automation to create appropriate models in PSS/E with the data from Hardware-in-Loop real-time simulations. With the increase in technology of power electronics, the use of High Voltage Direct Current Technology and Flexible Alternating Current Transmission System devices in the electrical power system have increased tremendously. Static Var Compensators are widely used and it is important to have accurate and reliable models for studies relating to power systems planning and interaction. An automation method is proposed to find the parameters of an SVC model in PSS/E with the data from the Hardware-in- loop …

Harmonics Elimination In Three Phase Cascade H-Bridge Multilevel Inverter Using Virtual Stage Pwm, Amro Quedan

Durham School of Architectural Engineering and Construction: Dissertations, Theses, and Student Research

The multilevel inverters are one of the great solutions that are proposed to satisfy the demand for high-power application and the significant integration of renewable energy. The conversion process from DC to AC must be done at high efficiency to decrease the energy loss and to ensure the electric grid power quality. The Total Harmonic Distortion (THD) is the most important feature that indicates the efficiency of the conversion process. In this research, due to the advantages of the cascade H-bridge inverter over other topologies, it has been used with the virtual stage PWM technique to investigate two different methods …

2017 Fall Engr333 Project Final Report (Section A), Trevor Nyeholt, Francis Kapesa, Justin Thalmayer, Erik Karlson, Kyle Van Veen, Kirk Brink, Steven Tarske, Brent Homan, Nathan De Haan, Paul Bootsma, Megan Anders, Philip Holmes, Melanie Fox, Noah Pirrotta, Abigail Berkompas, Ben Wellman, Halley Press, Christopher Greaves, Josh Templeman, Tim Bosch, Jake Zandstra, Hendrik Vermeulen

ENGR 333

Calvin College currently spends $836,000 annually on natural gas consumption. The engineering 333-A class was tasked with the question, "What would it take for Calvin College to save $75,000 per year on natural gas costs". The class was split into five groups (Boilers, Dorms and Dining Hall, Academic Buildings, Finance, and PE Complex) to research possible areas of savings. Through the class' research, it was determined that Calvin College has the potential savings of $87,000 a year through the reduction of natural gas usage.

2017 Fall Engr333 Project Final Report (Section B), Eric Ball, Mitchell Debruin, Raymond Kolocek, Edwin Kpodzro, Jacob Vandekieft, Nate Anderson, Brennan Steenhoek, Darbi Meyer, Derek Vermerris, Jessica Bouma, Devon Loerop, Reuben Saarloos, Richmond Amoh, Matthew Boelens, Tyson Butler, Laura Van Winkle, Alex Keizer, Kwame Ohemeng, Cameron Richman, Julie Van De Riet

ENGR 333

Currently, Calvin College spends $2.8M on electricity and natural gas. In the recent past Calvin has alleviated some of these costs by running a cogeneration system that combusts fuel and produces electricity and heat, this old system has since been removed due to age. With the old system removed Calvin is fully reliant on grid, leading to increased electricity cost. In addition to saving Calvin money, President Leroy formally signed the President’s Carbon Commitment that announced Calvin’s intent to be Carbon neutral by 2057. To meet both the cost and emissions saving needs, the objective of the energy savings project …

Co-Simulation Framework For Power Distribution System Analysis With Humans In The Loop, Victor H. Ayon

Mechanical Engineering ETDs

Recent developments in the area of power generation have led to an increased penetration of storage and distributed energy resources (DER) in power distribution systems. As a result, new and enhanced energy management systems will be necessary as the deployment of DERs, as well as the need to control loads, continues to increase in the coming years. Advanced management systems are especially important to achieve resilient power delivery during emergency situations. During a blackout for example, a section of a distribution feeder could island to operate as a microgrid to ensure critical services such as water, food, and medical care …

Impacts Of Power System-Tied Distributed Generation On The Performance Of Protection Systems, Terver T. Maor

Electrical Engineering Theses

The dispersed integration of smaller power units in the existing utility grid is the new trend. This is largely due to changes in the power generation and distribution markets. The combination of rising cost of new construction, deregulations and improved newer power equipment technologies suitable for deferred expansions make the new trend very attractive to power companies and independent investors. Until recently, other contributions to power distribution systems from such sources as standby units were considered negligible and therefore unaccounted for during the design and operation of power systems. This view has drastically changed, largely due to the increasing penetration …

2017 Fall Engr333 Seminar Preservation, Trevor Nyeholt, Erik Karlson, Cam Richman, Tyson Butler

ENGR 333

File for student presentation, given by students in the Fall 2017 class of ENGR333.

2017 Fall Engr333 Poster (Section B), Eric Ball, Mitchell Debruin, Raymond Kolocek, Edwin Kpodzro, Jacob Vandekieft, Nate Anderson, Brennan Steenhoek, Darbi Meyer, Derek Vermerris, Jessica Bouma, Devon Loerop, Reuben Saarloos, Richard Amoh, Matthew Boelens, Tyson Butler, Laura Van Winkle, Alex Keizer, Kwame Ohemeng, Cameron Richman, Julie Van De Riet

ENGR 333

Previously, Calvin College had a cogeneration system with the purpose of generating electricity and heat, through the combustion of natural gas, for Calvin’s campus. The original co-gen system was removed in 2017 due to high costs associated with maintenance and operations. Without a co-gen system, Calvin College is fully dependent on the grid. To save money and help in the President’s Carbon Commitment, PCC, the mechanical engineering students of ENGR 333 (section B) propose the implementation of a new co-gen system.

2017 Fall Engr333 Poster (Section A), Trevor Nyeholt, Francis Kapesa, Justin Thalmayer, Erik Karlson, Kyle Van Veen, Kirk Brink, Steven Tarske, Brent Homan, Nathan De Haan, Paul Bootsma, Megan Anders, Philip Holmes, Melanie Fox, Noah Pirrotta, Abigail Berkompas, Ben Wellman, Halley Press, Christopher Greaves, Josh Templeman, Tim Bosch, Jake Zandstra, Hendrik Vermeulen

ENGR 333

Calvin College uses 161,000 MMBTU of natural gas per year, which correlates to $836,000 of annual expenses. However Calvin could save as much as $240,000 on natural gas if they were as efficient as the top performer in an energy audit of similar colleges and universities in the Midwest, conducted by Sightlines Institute. The goal of this project was to see what actions could be taken to save the college $75,000 in annual natural gas costs.

Conjugated Dynamic Modeling On Vanadium Redox Flow Battery With Non-Constant Variance For Renewable Power Plant Applications, Abu Nayem Md. Asraf Siddiquee

Student Theses and Dissertations

A parametric modeling study has been carried out to assess the impact of change in operating parameters on the performance of Vanadium Redox Flow Battery (VRFB). The objective of this research is to develop a computer program to predict the dynamic behavior of VRFB combining fluid mechanics, reaction kinetics, and electric circuit. The computer program was developed using Maple 2015 and calculations were made at different operating parameters. Modeling results show that the discharging time increases from 2.2 hours to 6.7 hours when the concentration of V2+ in electrolytes increases from 1M to 3M. The operation time during the charging …

Technology Planning For Aligning Emerging Business Models And Regulatory Structures: The Case Of Electric Vehicle Charging And The Smart Grid, Kelly R. Cowan

Dissertations and Theses

Smart grid has been described as the Energy Internet: Where Energy Technology meets Information Technology. The incorporation of such technology into vast existing utility infrastructures offers many advantages, including possibilities for new smart appliances, energy management systems, better integration of renewable energy, value added services, and new business models, both for supply- and demand-side management. Smart grid also replaces aging utility technologies that are becoming increasingly unreliable, as the average ages for many critical components in utility systems now exceed their original design lives. However, while smart grid offers the promise of revolutionizing utility delivery systems, many questions remain about …

Flexible Custom Electric Skateboard, Caleb Adam Kelsay

Electrical Engineering

At Cal Poly traveling long distances only accessible by foot such as across campus or from the car park to class can be tiring and time-consuming. While not physically demanding, the trek consumes time in our tight college life schedule. To improve our time efficiency this project provides a relatively lightweight, powered solution to quickly and effectively travel long distances while maintaining full control and safety even on hills, a current limitation of traditional skateboards.

This electric skateboard includes the battery capacity to travel all around campus on a single charge with a compact and flexible skateboard design that provides …

Dc-To-Dc Buck Converter, Kyle Christopher Roman

Electrical Engineering

The growth of sustainable energy requires many components to work in harmony creating one efficient and effective system. Sustainable energy generation that produces a DC current varying in voltage requires a subsystem to convert voltage to a practical and usable value. The DC to DC Buck converter converts high DC solar generated voltage to a 12V output. This Modular -Level power electronic (MLPE) device performs as a solar charge controller for small lithium ion batteries. Fluctuating voltage levels generated by Photovoltaic cells makes the solar controller a critical part of the solar system. Regulating the DC voltage allows safe and …

Mppt Control For Solar Splash Photovoltaic Array, Kelsey Zenko

Mechanical Engineering Undergraduate Honors Theses

This thesis demonstrates the ability to model and simulate the operation of Maximum Power Point Tracking, MPPT. Moreover, the MPPT technology is contextualized within the confines of the Solar Splash competition to provide the foundation for future model development and simulation for optimal competition performance. MatLab Simulink was used to model the solar panel's operation. A MPPT algorithm was written using the perturb and observe method and was implemented in the model using a buck DC to DC converter. The performance of the model with hardware in the loop using Typhoon and dSPACE, which demonstrated how the actual hardware would …

Control Of Power Electronic Interfaces In Distributed Generation., Mohammad Mohebbi

Electronic Theses and Dissertations

Renewable energy has gained popularity as an alternative resource for electric power generation. As such, Distributed Generation (DG) is expected to open new horizons to electric power generation. Most renewable energy sources cannot be connected to the load directly. Integration of the renewable energy sources with the load has brought new challenges in terms of the system’s stability, voltage regulation and power quality issues. For example, the output power, voltage and frequency of an example wind turbine depend on the wind speed, which fluctuate over time and cannot be forecasted accurately. At the same time, the nonlinearity of residential electrical …

A Silicon Carbide Power Management Solution For High Temperature Applications, Robert Murphree

Graduate Theses and Dissertations

The increasing demand for discrete power devices capable of operating in high temperature and high voltage applications has spurred on the research of semiconductor materials with the potential of breaking through the limitations of traditional silicon. Gallium nitride (GaN) and silicon carbide (SiC), both of which are wide bandgap materials, have garnered the attention of researchers and gradually gained market share. Although these wide bandgap power devices enable more ambitious commercial applications compared to their silicon-based counterparts, reaching their potential is contingent upon developing integrated circuits (ICs) capable of operating in similar environments.

The foundation of any electrical system is …

Power Interface Design And System Stability Analysis For 400 V Dc-Powered Data Centers, Yuzhi Zhang

Graduate Theses and Dissertations

The demands of high performance cloud computation and internet services have increased in recent decades. These demands have driven the expansion of existing data centers and the construction of new data centers. The high costs of data center downtime are pushing designers to provide high reliability power supplies. Thus, there are significant research questions and challenges to design efficient and environmentally friendly data centers with address increasing energy prices and distributed energy developments.

This dissertation work aims to study and investigate the suitable technologies of power interface and system level configuration for high efficiency and reliable data centers.

A 400 …

Energy Shaping Control For Stabilization Of Interconnected Voltage Source Converters In Weakly-Connected Ac Microgrid Systems, Nadia Lenora Carmita Smith

Graduate Theses and Dissertations

With the ubiquitous installations of renewable energy resources such as solar and wind, for decentralized power applications across the United States, microgrids are being viewed as an avenue for achieving this goal. Various independent system operators and regional transmission operators such as Southwest Power Pool (SPP), Midcontinent System Operator (MISO), PJM Interconnection and Electric Reliability Council of Texas (ERCOT) manage the transmission and generation systems that host the distributed energy resources (DERs). Voltage source converters typically interconnect the DERs to the utility system and used in High voltage dc (HVDC) systems for transmitting power throughout the United States. A microgrid …

The Development Of Novel Interconnection Technologies For 3d Packaging Of Wire Bondless Silicon Carbide Power Modules, Sayan Seal

Graduate Theses and Dissertations

This dissertation advances the cause for the 3D packaging and integration of silicon carbide power modules. 3D wire bondless approaches adopted for enhancing the performance of silicon power modules were surveyed, and their merits were assessed to serve as a vision for the future of SiC power packaging. Current efforts pursuing 3D wire bondless SiC power modules were investigated, and the concept for a novel SiC power module was discussed. This highly-integrated SiC power module was assessed for feasibility, with a focus on achieving ultralow parasitic inductances in the critical switching loops. This will enable higher switching frequencies, leading to …