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Full-Text Articles in Power and Energy
Deciphering The Role Of Binder Reaction Exothermicity In Thermal Runaway Of Lithium-Ion Cells, Wen Wen, Jing-Hong Zhou, Hao-Tian Lu, Xing-Gui Zhou
Deciphering The Role Of Binder Reaction Exothermicity In Thermal Runaway Of Lithium-Ion Cells, Wen Wen, Jing-Hong Zhou, Hao-Tian Lu, Xing-Gui Zhou
Journal of Electrochemistry
Thermal safety associated with lithium-ion cells as power sources remains a critical industry concern. A comprehensive understanding of how internal exothermic side reactions contribute to temperature rise is fundamental for accurately analyzing thermal runaway processes and predicting the thermal safety of lithium-ion cells. While various side-reactions, such as decomposition of solid electrolyte interphase layer, reaction between anode materials and electrolyte, reaction between cathode materials and electrolyte, and electrolyte decomposition, have been identified as heat generation sources in previous studies, the quantification of these reactions remains insufficiently standardized. Particularly, the impact of heat generation from binder decomposition (most commonly polyvinylidene difluoride) …
Research Progress On Thermal Management Of Lithium-Ion Batteries, Hong-Da Li, Qiu-Wan Shen, Zhao-Yang Zhang, Xin-Yue Zhao, Yuan Wei, Shi-An Li
Research Progress On Thermal Management Of Lithium-Ion Batteries, Hong-Da Li, Qiu-Wan Shen, Zhao-Yang Zhang, Xin-Yue Zhao, Yuan Wei, Shi-An Li
Journal of Electrochemistry
Nowadays, new energy technologies are developing rapidly, energy storage systems are widely used, and lithium-ion batteries occupy a dominant position among them. Therefore, it is also very important to ensure their performance, safety and service life through thermal management technology. In this paper, the causes of thermal runaway of lithium batteries are reviewed firstly, and three commonly used thermal management technologies, namely, air cooling, liquid cooling and phase change material cooling, are compared according to relevant literature in recent years. Air cooling technology has been widely studied because of its simple structure and low cost, but its temperature control effect …
Causes And Prevention Of Thermal Runaway In Lithium-Ion Batteries — A U.S. Utility Perspective, Shaun Lavin, Kwabena Kyeremeh, Elias Nemeh, David Beyerle, Chad Alkire, Samuel Kelty, Lakshmi Srinivasan, Stephanie Shaw, Erin Minear, Haresh Kamath, Dan Ionel, Aron Patrick
Causes And Prevention Of Thermal Runaway In Lithium-Ion Batteries — A U.S. Utility Perspective, Shaun Lavin, Kwabena Kyeremeh, Elias Nemeh, David Beyerle, Chad Alkire, Samuel Kelty, Lakshmi Srinivasan, Stephanie Shaw, Erin Minear, Haresh Kamath, Dan Ionel, Aron Patrick
Power and Energy Institute of Kentucky Faculty Publications
Lithium-ion batteries are a critically important technology for maintaining grid reliability with the integration of variable intermittent renewable energy resources. However, lithium-ion batteries also pose significant human safety and infrastructure hazards due to the inherent risk of thermal runaway, fire, and explosion, which should be understood, mitigated, and managed. While battery manufacturers have primary responsibility for the design, manufacturing, and software which are necessary to keep battery storage systems safe, electric utilities also have an important role in understanding these risks and adopting best practices to mitigate them. This paper provides background on utility-scale battery deployment, an overview of a …
Aging Characteristics Of Lithium-Ion Battery Under Fast Charging Based On Electrochemical-Thermal-Mechanical Coupling Model, Dong-Xu Zuo, Pei-Chao Li
Aging Characteristics Of Lithium-Ion Battery Under Fast Charging Based On Electrochemical-Thermal-Mechanical Coupling Model, Dong-Xu Zuo, Pei-Chao Li
Journal of Electrochemistry
The aging characteristics of lithium-ion battery (LIB) under fast charging is investigated based on an electrochemical-thermal-mechanical (ETM) coupling model. Firstly, the ETM coupling model is established by COMSOL Multiphysics. Subsequently, a long cycle test was conducted to explore the aging characteristics of LIB. Specifically, the effects of charging (C) rate and cycle number on battery aging are analyzed in terms of nonuniform distribution of solid electrolyte interface (SEI), SEI formation, thermal stability and stress characteristics. The results indicate that the increases in C rate and cycling led to an increase in the degree of nonuniform distribution of SEI, and thus …
In Situ Diffuse Reflectance Spectroelectrochemistry Of Cathode Materials In Lithium-Ion Batteries, Lu-Lu Chen, Hao-Ran Li, Wei-Yi Liu, Wei Wang
In Situ Diffuse Reflectance Spectroelectrochemistry Of Cathode Materials In Lithium-Ion Batteries, Lu-Lu Chen, Hao-Ran Li, Wei-Yi Liu, Wei Wang
Journal of Electrochemistry
Developing in situ spectroelectrochemistry methods, which can provide detailed information about species transformation during electrochemical reactions, is very important for studying electrode reaction mechanisms and improving battery performance. Studying real-time changes in the surface of electrode materials during normal operation can be an effective way to assess and optimize the practical performance of electrode materials, thus, in situ and in operando characterization techniques are particularly important. However, batteries are hard to be studied by in situ characterization measurements due to their hermetically sealed shells, and there is still much room for battery characterizations. In this work, a specially designed battery …
Application Of Artificial Intelligence To Lithium-Ion Battery Research And Development, Zhen-Wei Zhu, Jing-Yi Qiu, Li Wang, Gao-Ping Cao, Xiang-Ming He, Jing Wang, Hao Zhang
Application Of Artificial Intelligence To Lithium-Ion Battery Research And Development, Zhen-Wei Zhu, Jing-Yi Qiu, Li Wang, Gao-Ping Cao, Xiang-Ming He, Jing Wang, Hao Zhang
Journal of Electrochemistry
Lithium-ion batteries (LIBs) have become one of the best solutions to the energy storage issue in modern society. However, the battery materials and device development are both complex, and involve multivariable problems. Traditional trial-and-error approach, which relies on researchers to conduct experiments, has encountered bottlenecks in the improvement of the battery performance. Artificial intelligence (AI) is the most potential technology to deal with this issue due to its powerful high-speed and capabilities of processing massive data. In particular, the capability of machine learning (ML) algorithms in assessing multidimensional data variables and discovering patterns in the sets are expected to assist …
Preparation And Performance Investigation Of Li-Sgo Doped Semi-Ipns Porous Single Ion Conducting Polymer Electrolyte, Yun-Feng Zhang, Jia-Ming Dong, Chang Tan, Shi-Kang Huo, Jia-Ying Wang, Yang He, Ya-Ying Wang
Preparation And Performance Investigation Of Li-Sgo Doped Semi-Ipns Porous Single Ion Conducting Polymer Electrolyte, Yun-Feng Zhang, Jia-Ming Dong, Chang Tan, Shi-Kang Huo, Jia-Ying Wang, Yang He, Ya-Ying Wang
Journal of Electrochemistry
Herein, the lithiated sulfonated graphene oxide (Li-SGO) was successfully prepared via three steps by sulfonation of graphene oxide with 3-merraptnpropylt rimethnxysilane, oxidation of thiol into sulfonate with hydrogen peroxide and lithiation of sulfonate with aqueous lithium hydroxide. The as-prepared Li-SGO was then introduced into the semi-interpenetrating networks of single ion conducting polymer electrolyte (Li-SGO-FPAS) and poly vinylidenefluoride-hexafluoro propylene (PVDF-HFP) binder by in-situ polymerization to fabricate the porous single ion conducting polymer electrolyte membrane (Li-SGO-po-FPAS) generated from the poor compatibility between aromatic Li-SGO-FPAS and aliphatic PVDF-HFP binder. The key properties such as morphology, porosity, solvent uptake, mechanical …
Influence Of Resveratrol On Performance Of Long-Term Storage’S Lithium-Ion Battery Electrolyte, Lei Zhang, Xu-Ping Zhang, Si-Wei Zhang, Quan-Chao Zhuang
Influence Of Resveratrol On Performance Of Long-Term Storage’S Lithium-Ion Battery Electrolyte, Lei Zhang, Xu-Ping Zhang, Si-Wei Zhang, Quan-Chao Zhuang
Journal of Electrochemistry
Electrolyte of lithium-ion battery usually goes through processes of filling, transportation and storage from the completion of manufacture to the use. Understanding the influence of long-term storage process on performance of lithium-ion battery electrolyte is of theoretical significance for production of lithium-ion battery. Scanning electron microscope (SEM) images showed that the solid electrolyte interface (SEI) film formed on the surface of the graphite electrode was thicker in the base electrolyte after 6 months of storage. The charge/discharge test results showed that the reversible cycle capacity and cycle stability (capacity retention rate) of graphite electrode decreased significantly after 6 months of …
A Review Of Electrochemical Energy Storage Researches In The Past 22 Years, Yu-Sheng Yang
A Review Of Electrochemical Energy Storage Researches In The Past 22 Years, Yu-Sheng Yang
Journal of Electrochemistry
In this paper, research activities from my groups in the field of electrochemical energy storage are reviewed for the past 22 years, which is divided into three sections. The first section describes the researches related to high specific energy and high specific power energy storage devices, including lithium sulfur batteriies (sulfur composite cathode material, lithium sulfur battery fabrication, lithium boron alloy as lithium sulfur battery anodes, and sulfur lithium-ion battery new system), supercapacitors (super activated carbon, capacitive carbon prepared from phenolic resin, carbon nanotube array parasitic pseudo-capacitive energy storage materials, necessary properties of capacitive carbons, nickel hydroxide xerogels pseudo-capacitive energy …
Lithium-Ion Battery And Beyond: Oxygen Vacancy Creation In Tungsten Trioxide And Surface Modification Of Lithium Metal, Rajesh Pathak
Lithium-Ion Battery And Beyond: Oxygen Vacancy Creation In Tungsten Trioxide And Surface Modification Of Lithium Metal, Rajesh Pathak
Electronic Theses and Dissertations
The graphite-based anode material has a low theoretical specific capacity of 371 mAh g-1. The transitional metal oxides (TMOs) are considered a better choice owing to their relatively higher specific capacity. Among TMOs, tungsten trioxide (WO3) is considered promising due to a higher specific capacity of 693 mAh g-1, low cost, mechanically stable, and eco-friendly. It has been a challenge to utilize the TMOs as anode materials as they suffer from poor electronic conductivity and large electrode volume expansion during discharge/charge cycles. In our first project, we demonstrate a unique self-recovery of capacity in reduced WO3 by the incorporation of …
Cvd Preparation And Application Of 3d Graphene In Electrochemical Energy Storage, Yong-Kang Xia, Ming-Yuan Gu, Hong-Guan Yang, Xin-Zhi Yu, Bing-An Lu
Cvd Preparation And Application Of 3d Graphene In Electrochemical Energy Storage, Yong-Kang Xia, Ming-Yuan Gu, Hong-Guan Yang, Xin-Zhi Yu, Bing-An Lu
Journal of Electrochemistry
Three-dimensional (3D) graphene combinations with the excellent intrinsic properties of graphene and the 3D micro/nano porous structures provide a graphene foam with high specific surface area, excellent mechanical strength and fast electron and mass transports. The 3D graphene foam and its composite nanomaterials are widely used in the fields of nano-electronics, energy storage, chemical and biological sensing. The 3D graphene foam prepared by chemical vapor deposition (CVD) method is of high purity and crystallinity. In this review, a brief overview in the CVD preparations of 3D graphene and properties of CVD prepared 3D graphene based nanomaterials in electrochemical energy storage …
Synthesis And Electrochemical Properties Of Nickel-Rich Cathode Material Lini0.6Co0.2Mn0.2O2 With High Initial Coulombic Efficiency, Xiao-Yun Guan, Chao-Yu Hong, Jian-Ping Zhu, Wei-Li Wang, Yi-Xiao Li, Yong Yang
Synthesis And Electrochemical Properties Of Nickel-Rich Cathode Material Lini0.6Co0.2Mn0.2O2 With High Initial Coulombic Efficiency, Xiao-Yun Guan, Chao-Yu Hong, Jian-Ping Zhu, Wei-Li Wang, Yi-Xiao Li, Yong Yang
Journal of Electrochemistry
Nickel-rich cathode materials LiNi0.6Co0.2Mn0.2O2(NCM622)were synthesized by a co-precipitation-solid state sintering method at different temperatures. The structure, morphology and electrochemical performance of the as-prepared materials were investigated by X-ray powder diffraction (XRD) /Rietveld refinement, scanning electron microscope (SEM) and electrochemical experiments. It is found that NCM622 calcined at 800 ℃ showed the lowest degree of cation disorder (~1.97%) with a high initial Coulombic effiency of 92.2% and the capacity retention of 81.4% after 100 cycles.
Research Progress In Cycle Stability Of Silicon Based Li-Ion Battery Anodes, Ze-Liang Guo, Hui Wu
Research Progress In Cycle Stability Of Silicon Based Li-Ion Battery Anodes, Ze-Liang Guo, Hui Wu
Journal of Electrochemistry
Silicon(Si), with the highest specific capacity currently known, is a promising anode material for Li-ion battery. However, in the charging and discharging process, with Li atoms inserting into and breaking out of the Si crystal lattices, the Si anode undergoes enormous volume expansion and contraction, ending in pulverization. The fact that the specific capacity of bulk Si anodes drop quickly is a challenging problem. In this review, we summarize recent progresses in Si anode. We concern about the nanostructure of silicon, cooperation of silicon with other additives and macrostructure design of anodes. We discuss strengths and shortcomings of different methods, …
Preparation And Enhanced Rate Capability Of Spinel Limn1.9Al0.1O3.95F0.05, Jun-Yan Hu, Meng-Meng Wang, Hong-Tao Liu
Preparation And Enhanced Rate Capability Of Spinel Limn1.9Al0.1O3.95F0.05, Jun-Yan Hu, Meng-Meng Wang, Hong-Tao Liu
Journal of Electrochemistry
Spinel LiMn1.9Al0.1O3.95F0.05 cathode materials with good crystallinity were synthesized by a sol-gel process followed with a high-temperature solid reaction. The effects of partial substitution of Al for Mn, and F for O on the structure and the electrochemical performance were investigated. The results showed that LiMn1.9Al0.1O3.95F0.05 exhibited the same crystalline state as LiMn2O4, but much better electrochemical stability at higher rate cycling. As a result, LiMn1.9Al0.1O3.95F0.05 could maintain stable electrochemical lithium storage even suffering from …
Synthesis And Electrochemical Performance Of Mn3O4/Graphene Composites, Shan-Shan Yang, Qian Zhang, Xiong-Gui Lin, Ming-Sen Zheng, Quan-Feng Dong
Synthesis And Electrochemical Performance Of Mn3O4/Graphene Composites, Shan-Shan Yang, Qian Zhang, Xiong-Gui Lin, Ming-Sen Zheng, Quan-Feng Dong
Journal of Electrochemistry
The Mn3O4/Graphene composites were synthesized by hydrothermal method with the in-situ redox reaction of graphene oxide (GO) and manganese acetate (Mn(Ac)2). The phase structures and morphologies of the materials were characterized by XRD, SEM and TEM. The XPS and IR techniques were used for studying the residual function groups of reduced graphene oxide (RGO). The electrochemical performances of the hybrids were tested in a coin cell. Results showed that the composites prepared with the addition of ammonia water (RM-A) have better performance. The graphenes in RM-A were better-reduced and the Mn3O4 …
Syntheses And Electrochemical Performances Of Li4Ti5O12 Anode Materials For Lithium Ion Battery, Yong-Long Zhang, Xue-Bu Hu, Yao-Qiong Wang, Dong-Hai Huang
Syntheses And Electrochemical Performances Of Li4Ti5O12 Anode Materials For Lithium Ion Battery, Yong-Long Zhang, Xue-Bu Hu, Yao-Qiong Wang, Dong-Hai Huang
Journal of Electrochemistry
Series of spinel lithium titanate (Li4Ti5O12) materials were synthesized by one-step solid-state reaction using lithium acetate and TiO2 as raw materials under different temperatures (750/800/850 °C) and atmospheres (N2/air). The as-prepared Li4Ti5O12 materials were investigated by thermogravimetric analysis, X-ray diffraction, scanning electron microscopy, cyclic voltammotry and charge-discharge test to analyze their crystal structures, microstructures and electrochemical performances. The results show that the Li4Ti5O12（L-800N）material obtained at 800 °C under nitrogen atmosphere exhibited better electrochemical performance and smaller particle size. The initial …
Effect Of Al-Doping In Li-Rich Material Li1.2Mn0.543Co0.078Ni0.155Al0.030O2 For Lithium-Ion Batteries, Xiao-Xi Jin, Yi-Xiao Li, Yong Yang, Zhou-Cheng Wang
Effect Of Al-Doping In Li-Rich Material Li1.2Mn0.543Co0.078Ni0.155Al0.030O2 For Lithium-Ion Batteries, Xiao-Xi Jin, Yi-Xiao Li, Yong Yang, Zhou-Cheng Wang
Journal of Electrochemistry
The Al-doped 0.5Li2MnO3·0.5Li(Mn0.4Co0.2Ni0.4)O2 compounds were successfully synthesized as cathode materials for lithium-ion batteries. The pristine and Al-doped materials were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), inductively coupled plasma-atomic emission spectrometry (ICP-AES) and laser Raman spectroscopy. The results indicated that all the prepared materials were indexed as a hexagonal structure with R-3m space group, and Al element had been introduced into lattice. When cycled at 180 mA·g-1 (1 C-rate), the capacity retention of 4% (by mole) Al-doped 0.5Li2MnO3·0.5Li(Mn0.4Co0.2Ni …
Synthesis And Electrochemical Properties Of Lico1-XMgXMno4 And Lico1-XAlXMno4 (X= 0, 0.02, 0.05, 0.1) As Positive Materials For Lithium-Ion Batteries, Mei-Ling You, Qing-Song Tong, Xiu-Hua Li, Min Lin, Xing-Kang Huang, Yong Yang
Synthesis And Electrochemical Properties Of Lico1-XMgXMno4 And Lico1-XAlXMno4 (X= 0, 0.02, 0.05, 0.1) As Positive Materials For Lithium-Ion Batteries, Mei-Ling You, Qing-Song Tong, Xiu-Hua Li, Min Lin, Xing-Kang Huang, Yong Yang
Journal of Electrochemistry
The Al-doped and Mg-doped LiCoMnO4 materials were synthesized through solid-state reaction. The effects of doping amounts of Mg and Al on the initial capacities, discharge plateaus, and cycle performances were investigated. The morphologies and structures of the as-prepared materials were studied by scanning electron microscopy and powder X-ray diffraction. The results indicate that the as-prepared samples were composed of uniform, well-crystallized particles. The pristine LiCoMnO4 possessed an initial capacity of 87.0 mAh·g-1, while LiCo0.98Mg0.02MnO4 and LiCo0.98Al0.02MnO4 delivered 91.3 and 93.6 mAh·g-1, respectively. The proper …
Hydrothermal Synthesis Of Pure Li4Ti5O12 And Its Electrochemical Performance, Wen-Jun Xie, Yu-Shi He, Hong Wang, Xiao-Zhen Liao, Zi-Feng Ma
Hydrothermal Synthesis Of Pure Li4Ti5O12 And Its Electrochemical Performance, Wen-Jun Xie, Yu-Shi He, Hong Wang, Xiao-Zhen Liao, Zi-Feng Ma
Journal of Electrochemistry
Spinel Li4Ti5O12 was prepared by hydrothermal method using commercial anatase (TiO2) and lithium hydroxide (LiOH) as raw materials. The effects of the LiOH concentration of lithium hydroxide, hydrothermal reaction time and calcination temperature on the structure and electrochemical performance of Li4Ti5O12 were investigated. The formation process of Li4Ti5O12 was also proposed. The micro-structure and morphology wereas characterized by XRD, SEM, TEM techniques, and the electrochemical performance was analyzed by galvanostatic charge-discharge test. The results show that the pure phase spinel Li4Ti …
Synthesis And Electrochemical Performance Of Si/C Composite Modified By Pani, Guang-Hui Zhang, Pei-Kang Shen, Ge Sang, Ren-Jin Xiong
Synthesis And Electrochemical Performance Of Si/C Composite Modified By Pani, Guang-Hui Zhang, Pei-Kang Shen, Ge Sang, Ren-Jin Xiong
Journal of Electrochemistry
Silicon/carbon (Si/C) composite materials were prepared through high-energy ball milling and high-temperature solid-phase method, and then coated with thin polyaniline (PAni) film by oxidation. The microstructure and component of the composites were characterized by SEM, XRD, IR, TG, and the electrochemical performance was investigated by cyclic voltammetry (CV) and galvanostatic charge-discharge tests. The results showed that the surface of PAni/Si/G/C composite was coating with complete lamellar structure of PAni film. Its reversible capacity was 784 mAh·g-1 and 690 mAh·g-1 could be maintained after 50th charge-discharge cycles.
Properties Of Carbon Coated Tin Negative Electrode For Lithium-Ion Battery, Gui-Chang Liu, Xiao-Xiao Shen, Li-Da Wang
Properties Of Carbon Coated Tin Negative Electrode For Lithium-Ion Battery, Gui-Chang Liu, Xiao-Xiao Shen, Li-Da Wang
Journal of Electrochemistry
Carbon coated tin power was prepared by decomposing glucose applying a hydrothermal method, and was further used as the active material for negative electrode of lithium secondary battery. Charge-discharge tests show that the carbon coated tin electrode with the addition of 5 wt.% acetylene black as a conductive agent could obtain an initial discharge capacity of 967 mAh·g-1 and a discharge capacity of 362 mAh·g-1 after 50 cycles, which is much higher than that of tin electrode (166 mAh·g-1 after 50 cycles). The coated carbon hinders the agglomeration of tin powder, reduces the irreversible capacity loss of …
Preparation And Modification Of Li4Ti5O12 As Anode Materials For Lithium-Ion Batteries, Jin-Long Liu, Zhou-Guang Lu, Yang Ren, Ya-Jie Zhu, Shan-Shan Hu, Zhong Peng, Dong Qian, You-Gen Tang
Preparation And Modification Of Li4Ti5O12 As Anode Materials For Lithium-Ion Batteries, Jin-Long Liu, Zhou-Guang Lu, Yang Ren, Ya-Jie Zhu, Shan-Shan Hu, Zhong Peng, Dong Qian, You-Gen Tang
Journal of Electrochemistry
Anode Material Li4Ti5O12 for lithium-ion batteries was successfully prepared using half-solid-state method. Furthermore, carbon coating modification of Li4Ti5O12 was also carried out. The phase structure and morphology were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and high resolution transmission electron microscopy (HRTEM). The electrochemical properties were investigated by constant current discharge-charge tests, cyclic voltammetry and electrochemical impedance techniques. The results indicated that the electrochemical performance of Li4Ti5O12 without modification declined seriously due to the aggregation of Li4Ti …
Synthesis And Electrochemical Characterization Of Li3V2(Po4)3/C Cathode Material By Ball-Milling Assisted Microwave Method, Zhi-Yuan Tang, Wen-Feng Mao, Ji Yan, Wei Yuan, Xin-He Zhang
Synthesis And Electrochemical Characterization Of Li3V2(Po4)3/C Cathode Material By Ball-Milling Assisted Microwave Method, Zhi-Yuan Tang, Wen-Feng Mao, Ji Yan, Wei Yuan, Xin-He Zhang
Journal of Electrochemistry
The cathode materials of Li3V2(PO4)3/C were successfully synthesized by ball-milling assisted microwave method and the microwave irradiation time was also optimized. It is found that the Li3V2(PO4)3/C material obtained at a microwave power of 640 W for 18 min showed the best electrochemical performance with the initial reversible capacity of 101.3 mAh·g-1 and the remained 100.8 mAh·g-1 at 5C rate after 300 cycles. This excellent electrochemical capability may be resulted from good crystallinity, smaller and uniform particle size of the material, showing …
Preparation And Electrochemical Performance Of Tio2/Gns Nanocomposite As Anode Materials For Lithium-Ion Batteries, Lin-Lin Qin, Huan Zhang, Xiao-Jing Liu, Jian-Hui Xu, Yi-Ning Shi, Ming-Sen Zheng, Quan-Feng Dong
Preparation And Electrochemical Performance Of Tio2/Gns Nanocomposite As Anode Materials For Lithium-Ion Batteries, Lin-Lin Qin, Huan Zhang, Xiao-Jing Liu, Jian-Hui Xu, Yi-Ning Shi, Ming-Sen Zheng, Quan-Feng Dong
Journal of Electrochemistry
The honeycomb-like porous TiO2/graphenes (TiO2/GNs) nanocomposite was prepared by a reflux method. SEM and TEM results showed that nanosized anatase TiO2 (about 5~10 nm) were dispersed uniformly on the surface of the GNs. The TiO2/GNs composite showed excellent rate and cycling performance: A stable charge capacity of 169.5 mAh·g-1 was obtained at 30C, and can restore to 241.7 mAh·g-1 while current went back to 1C. The stable charge capacity of TiO2/GNs nanocomposite electrode up to 201.9 mAh·g-1 was achieved at 10C in the first cycle, and could be …
Preparation And Application Of Nano-Nio As Anode In Lithium-Ion Batteries, Cheng-Dong Bai, Jia-Jia Chen, Qi Zhang, Ming-Sen Zheng, Quan-Feng Dong
Preparation And Application Of Nano-Nio As Anode In Lithium-Ion Batteries, Cheng-Dong Bai, Jia-Jia Chen, Qi Zhang, Ming-Sen Zheng, Quan-Feng Dong
Journal of Electrochemistry
In this work, the nano-NiO material was prepared by hydrothermal method. The surface morphologies and electrochemical properties of nano-NiO material were investigated. The special nano-NiO material with porous surface assembling honeycombs(100-200nm) was obtained by using surface active agents. The discharge capacity of nano-NiO electrode up to 2385.7 mAh/g was achieved at current density of 0.1A/g in the first circle,while 1100mAh/g could be maintained after 100 circles. At current density of 2.0A/g, the discharge capacity of 600 mAh/g was obtained. And when the current density was reduced to 0.1A/g, the discharge capacity was restored to 1050 mAh/g. The nano-NiO electrode exhibited …
Research Progress In Orthosilicates As Cathode Materials For Li-Ion Batteries, Dong-Ping Lv, Lin Wang, Yong Yang
Research Progress In Orthosilicates As Cathode Materials For Li-Ion Batteries, Dong-Ping Lv, Lin Wang, Yong Yang
Journal of Electrochemistry
Rechargeable Li-ion batteries fulfilling high-energy density, high safety, environmental friendliness, and low cost are demanded urgently for energy storage systems. Besides the structure stability arising from the strong Si-O covalent bond, environmental benignancy and low cost from the characteristics of Fe, Mn, Si elementals, orthosilicates (Li2MSiO4) show promising prospect to meet the demand of high-energy density for its two available Li+ per formula unit. Motivated by these significant advantages, Li2MSiO4 have been intensively investigated in the past few years. In the present work, we gave a review on the progress of orthosilicate research …
Preparation And Electrochemical Properties Of Sn Thin Film As Anode Materials For Lithium-Ion Batteries, Hong-Mei Bai, Zhan-Liang Tao, Fang-Yi Cheng, Jun Chen
Preparation And Electrochemical Properties Of Sn Thin Film As Anode Materials For Lithium-Ion Batteries, Hong-Mei Bai, Zhan-Liang Tao, Fang-Yi Cheng, Jun Chen
Journal of Electrochemistry
Sn thin films as the anode materials of Li-ion batteries were prepared by vacuum-evaporation method on the copper foam substrate. The phase structure,surface morphology and electrochemical property of the as-prepared films were characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM), and galvanostatic cycling. The results showed that three-dimensional structure of copper foam substrate enhanced the adhesion strength between the active material and the substrate, under the same substrate temperature, the particles became bigger with the increasing of evaporation time, while their electrochemical property decreased, under the same evaporation time, the particles didn′t changed obviously with the increasing of substrate temperature,while their cycle …
Research Of Explosion Mechanism Of Lithium-Ion Battery, Yu-Hong Chen, Zhi-Yuan Tang, Yan-Bing He, Qiang Liu
Research Of Explosion Mechanism Of Lithium-Ion Battery, Yu-Hong Chen, Zhi-Yuan Tang, Yan-Bing He, Qiang Liu
Journal of Electrochemistry
The heat character of Lithium-ion battery materials and explosion mechanism of Lithium-ion cells under the overcharge,short-circuit and other abuse behavior are tested by C80 calorimeter, DSC and charge-discharge instrument.SEI reactions, LixC6/electrolyte and LixC6/PVDF reactions take place at the anodes. Electrolyte and solvent reactions happen after 178℃ and Li1-xCo1/3Ni1/3Mn1/3O2 decomposes after 230℃. The batteries explode at 150℃ oven test or 1.5C, 5.5 V overcharge and do not explode at short-circuit.
The Study On Lithiated Titanium Composite Oxides As Negative Electrode For Lithium-Ion Battery, Xiao-Yan Yang, Shou-Nan Hua, Shu-Yong Zhang
The Study On Lithiated Titanium Composite Oxides As Negative Electrode For Lithium-Ion Battery, Xiao-Yan Yang, Shou-Nan Hua, Shu-Yong Zhang
Journal of Electrochemistry
Lithiated titanium composite oxides Li4Ti5O12 were prepared from Li2CO3 and TiO2. The XRD results of this composite oxides indicated that the compound had a spinel structure. The electrochemical behavior of lithiated titanium composite oxides was examined. The results showed that this material had an excellent cyclic capability and reversibility for lithium insertion, and had high specific capacity: the initial discharge capacity was 300 mAh·g-1 , and the reversible capacity was 100 mAh·g-1 . The discharge plateau (about 1.5 V) and the charge plateau (about 1.6 V) were very …
Synthesis Of LiXCoo2 And Its Behaviour In Rechargeable Lithium Battery, Mingfeng Guo, Ruimin Yang, Zebo Zhang, Jincao Ye
Synthesis Of LiXCoo2 And Its Behaviour In Rechargeable Lithium Battery, Mingfeng Guo, Ruimin Yang, Zebo Zhang, Jincao Ye
Journal of Electrochemistry
The Variations of crystal lattice parameters of LixCoO2 during charge anddischarge have been st ud ied by XRD and AAR spectroscopy. It was found that the LixCoO2 crystalvolume expanded during charge and contracted during discharge. The crystal lattice structure was broken because of the formation of Co3O4 when deeply charge.The variation of lattice parameter C0 value in cycling process was similar to that in charge process.The variation of 006 peak was the mostsensitive in every case. In case of preheating for 20 hours at 700℃ before operating high temperature, the …