Power and Energy Commons^™

When Does Global Search Pay For Itself? A Measured Exploration Cost And Energy Break-Even Analysis Of A Metaheuristic Search Controller In Solar Energy Systems, Mohamed Ali Muammar Ezgour

Communications of the IIMA

Autonomous energy systems increasingly delegate the choice of operating point to embedded search algorithms, trading a fast local optimizer that can settle on a wrong point against a slower global search that guarantees the right one at a measurable cost. This paper reframes maximum power point tracking under partial shading as that decision and measures its economics on a fixed photovoltaic plant in MATLAB/Simulink. A Hippopotamus Optimization global search handed over to incremental conductance is compared with incremental conductance alone across seventeen initial duty cycles and thirty random seeds. The hybrid reached the global peak in all thirty seeds, whereas …

Neural Network Driven By Electrochemical Performance Data For Predicting The Discharge Termination Time Of Seawater Electrolyte-Based Metal-Air Batteries, Peng-Peng Shen, Yi-Chi Pan, Yu-Rong Liu, Lu-Dan Zhang, Ning Niu, Guan-Jun Wang, De-Kun Yang, Xin-Long Tian, Peng Rao

Journal of Electrochemistry

Seawater electrolyte-based metal-air batteries exhibit great promise for marine energy supply systems. However, conventional statistical analysis methods, though applicable to seawater metal-air battery lifetime prediction, have inherent limitations of insufficient prediction accuracy and large error. Herein, a deep time-series regression framework based on InceptionTime and incorporating prior-biased attention pooling is proposed to construct a nonlinear mapping between electrochemical performance sequences and the discharge termination time of catalysts. Specifically, chronoamperometric profiles are employed to extract long-term stability features, while prior knowledge derived from linear sweep voltammetry is introduced to strengthen the attention weighting over critical potential regions. Under a nested leave-one-catalyst-out …

Microwave-Assisted Synthesis Of Core-Shell Structured Pd@Pdptcufe Recessed Truncated Octahedral Nanocrystals For Multifunctional Electrocatalysis, De-Zhong Hu, Wen-Dan Jiang, Wei Keat Ng, Jun Yang, Xiong-Wu Kang

Journal of Electrochemistry

Developing cost-efficient and durable multifunctional electrocatalysts of hydrogen evolution reaction, oxygen reduction reaction and oxygen evolution reaction is crucial for improving energy conversion efficiency in electrolytic water splitting electrolyzer and advancing rechargeable zinc-air batteries. Polyhedral shaped nanocrystals with well-defined crystal facets represent a type of model catalysts that enables the exploration of structure-activity relationships. However, it is still very challenging to prepare alloy nanocrystals with multiple metal components due to their complicated redox potentials and mixing enthalpy. Herein, we report a rapid microwave-assisted polyol reduction method for syntheses of core-shell Pd@PdPtCu, Pd@PdPtCuNi, Pd@PdPtCuCo and Pd@PdPtCuZn octahedral nanocrystals, and recessed truncated-octahedral …

Techno-Economic Analysis Of Implementing Carbon Capture And Storage (Ccs) At The Punagaya 2×100 Mw Coal Power Plant, Ricky Andreas Kristianto Siringoringo, Rahma Muthia, Widodo Wahyu Purwanto

Journal of Materials Exploration and Findings

The increase in greenhouse gases due to the combustion of fossil fuels is one of the major drivers of global warming and consequently drives the development of low-carbon technologies such as Carbon Capture and Storage (CCS). The aim of this study is to evaluate the technical and economical feasibility of the implementation of CCS technology in the Punagaya Subcritical Coal-Fired Power Plant (CFPP) 2×100 MW as a part of the energy transition strategy towards Net Zero Emissions (NZE) 2060. The simulation was carried out using Aspen HYSYS software, including coal combustion, CO₂ capture through MDEA-PZ solvent, dehydration, transportation, and storage …

Flexible Power Point Tracking For Active Frequency Regulation In Grid-Connected Photovoltaic Power Plants, Castor K. Haule, Sophia D. Kigodi, Emmanuel S. Matee, Francis Mwasilu

Tanzania Journal of Science

The increasing penetration of photovoltaic (PV) systems into modern power grids necessitates advanced control strategies capable of supporting grid stability. Traditional PV systems rely on Maximum Power Point Tracking (MPPT) to maximize energy extraction, limiting their ability to participate in grid-support functions such as frequency regulation or power curtailment. This paper presents a flexible power point tracking (FPPT) control strategy that enables PV systems to operate at arbitrary points along the power–voltage (P–V) curve. A multi-mode power management scheme is proposed, integrating conventional Perturb and Observe (P&O) MPPT with FPPT, allowing the system to switch dynamically between energy maximization and …

Modeling And Simulation Of Solar Battery Charge Controller Using Adaptive Particle Swarm Optimization Mppt Algorithm, Mustafa Sacid Endiz, Göksel Gökkus

Mathematical Modelling and Numerical Simulation with Applications

Implementing an effective Maximum Power Point Tracking method is crucial for optimizing solar energy harvesting against environmental fluctuations like solar radiation and temperature. This paper introduces a novel approach for modeling and simulating a solar battery charge controller, using a modified Particle Swarm Optimization algorithm. The power stage of the system is based on a SEPIC converter, which is employed to manage the power conversion and improve the energy transfer to the battery. The developed circuit model is evaluated under various radiation levels at a constant temperature, as well as under different temperature levels at a constant radiation. Simulations are …

Dynamic Reconstruction Engineering Of Anti-Corrosion Ni-Based Anodes For Alkaline Seawater Electrolysis, Yi-Gang Zhang, Wen-Wen Xu, Tian-Yu Zhang, Zhi-Yi Lu

Journal of Electrochemistry

Green hydrogen production via alkaline seawater electrolysis offers an environmentally sustainable and potentially cost-effective route to address both energy and climate challenges. Achieving long-term anode stability under complex ionic environments and industrial current densities remains a central bottleneck. Specifically, Ni-based anodes exhibit intense surface reconstruction during the oxygen evolution reaction, necessitating dynamic anti-corrosion strategies. This mini review systematically summarizes reconstruction engineering approaches to develop anti-corrosion Ni-based anodes of alkaline seawater electrolysis across increasingly complex ionic environments from simulated seawater to real seawater: (i) Cl^– dominated; (ii) Cl^– with co-existing oxyanions, and (iii) Cl^–  with co-existing Br^{– …}

Preparation And Performance Study Of In-Situ Self-Assembled Biphasic Smmn2O5-Nimn2O4 Composite Cathode, Neng-Chu Xia, Yu Zhou, Qin Wang, Jia-You Zhang, Chun Yu, Yang Zhang, Wan-Bing Guan, Jian-Xin Wang

Journal of Electrochemistry

Mullite-structured oxides exhibit excellent oxygen reduction reaction activity, possess a low thermal expansion coefficient due to their unique crystal structure, and can eliminate the need for a barrier layer and simplify the preparation process as they contain no alkaline earth elements. Thus, they hold great promise as novel cathode materials for solid oxide fuel cells. In this work, a mullite-spinel-structured SmMn₂O₅-NiMn₂O₄ (SMO-NMO) composite cathode was one-step synthesized via a solid-liquid composite route, and its in-situ self-assembly enabled good compatibility with the electrolyte without any barrier layer. Characterization results showed that the SMO:NMO = …

Policy Reflections On Promoting Strategic Oriented Basic Research In China: Insights From The U. S. Department Of Energy’S Basic Research Funding System, You Yu, Yun Liu, Wenneng Zhou

Bulletin of Chinese Academy of Sciences (Chinese Version)

Strategy-oriented basic research is a key pathway to driving major original breakthroughs at the frontiers of science, serving national strategic needs, and securing a leading position in global science and technology. It is also a vital pillar for achieving high-level self-reliance and self-strengthening in science and technology and enhancing the capacity for original innovation. Faced with the urgent need to build a science and technology powerhouse and achieve breakthroughs in key core technologies, China has gradually improved its organizational framework for advancing strategy-oriented basic research and has established a solid foundation for policy support and resource allocation. Nevertheless, when measured …

Li+/Na+ Hybrid Ion Conduction Mechanism In The Superionic Conductor Li3–XNaXZr2Si2Po12, Yi-Hong Wu, Xia Xie, Lei Zhu, Mu-Ran Yu, Guo-Tai Zhang, Jun-Chao Chen, Shu-Ying Sun, You-Wei Wang, Wei-Ping Tang

Journal of Electrochemistry

Hybrid ion conductors that transport multiple ionic conductive species provide a useful platform for understanding how mixed-ion transport governs ionic conductivity within a single phase. However, the controlled introduction of multiple mobile ions into solid-state electrolytes and a mechanistic understanding of their migration within the framework remain challenging. Herein, a skeleton-retained Li⁺↔Na⁺ cationic exchange was used to simultaneously induce Li⁺ and Na⁺ cations into the NASICON-type framework of Li_3–xNa_xZr₂Si₂PO₁₂ (0 < x < 3). We show that the interpenetration of NaO₆ and NaO₈ coordination polyhedra significantly influences the ionic conductivity of hybrid ion conductors. Computational …

Distribution And Transport Of Lithium Ions At Interfaces Between Graphite And Carboxymethyl Celluloses, Zi-Jun Huang, Zhen-Ying Zheng, Hua-Wei Cao, Jian Wang, Qing-Feng Zhang, Sheng-Li Chen

Journal of Electrochemistry

Carboxymethyl cellulose (CMC) is a water-processable binder widely used for graphite anodes. However, a microscopic understanding of why the identity of CMC counterions (Li⁺/Na⁺/K⁺) strongly affects electrode performance remains limited. Here, molecular dynamics (MD) simulations are used to track Li⁺ transport accessibility across electrolyte/CMC/graphite three-phase interfaces, comparing pure CMC-Li, CMC-Na, CMC-K, and mixed-counterion CMC binders. We find that CMC-Li sustains a continuous Li⁺ transport pathway from the electrolyte through the binder phase toward graphite. In contrast, in CMC-Na and CMC-K, Na⁺/K⁺ ions preferentially enrich at the graphite/binder interface, forming …

Distinct Co2 Electroreduction Behaviors Over Planar And Non-Planar Cobalt Molecular Catalysts, Ru Jia, Cheng-Biao Zhu, Zi-Mo Zhang, Tuo Wang, Kai-Cong Yang, Guang-Zhe Wang, Yang Hu, Ting-Ting Zhang, Zhen-Wei Wei, Li Xiao, Gong-Wei Wang, Lin Zhuang

Journal of Electrochemistry

Molecular catalysts serve as ideal platforms for studying electrocatalytic reaction mechanisms. While current research mainly focuses on modulating central metals or surrounding ligands, the influence of molecular spatial configuration remains largely unexplored. Herein, we synthesized two cobalt complexes with similar ligand environments but distinct spatial geometries, a planar cobalt hexaazamacrocyclic complex (CoHAM) and a non-planar acyclic Co(phen)₂Cl₂, and evaluated their performance in CO₂ reduction reaction (CO₂RR). The planar CoHAM exhibited dramatically superior CO₂RR performance compared to the non-planar Co(phen)₂Cl₂. Through a series of combined analyses using in-situ …

Optimal Design And Techno-Economic And Environmental Analysis Of A Hybrid Solar Pv-Battery-Generator System For Off-Grid Telecom Towers And Rural Households: Case Of Misughaa Village In Tanzania, Ibrahim Mwammenywa, Martha Mwaikenda

Tanzania Journal of Engineering and Technology (TJET)

Telecommunication services are pivotal for the socio-economic development of communities, regions, and countries. Extensive and reliable telecom infrastructure enables populations to leverage development opportunities and bridge the urban-rural divide. However, extending these services to rural areas often necessitates the deployment of telecommunication towers in locations lacking national grid access. Consequently, service providers typically rely on diesel generators (DG) for power, which introduces significant challenges. These challenges include a high operational expenditure (OPEX), rendering telecom services unaffordable for rural communities, and substantial environmental pollution from greenhouse gas (GHG) emissions. This study aims to present an optimal design, encompassing sizing and economic …

Voltage Profile Enhancement In Iliceto Shield Wire Scheme For Rural Electrification: Case Study Of Chalinze-Mbwewe Transmission Line In Tanzania, Ebeneza Chaula, Ibrahim Mwammenywa, Santos Kihwele

Tanzania Journal of Engineering and Technology (TJET)

Rural electrification faces challenges due to significant voltage drops over long transmission distances, affecting reliability and power quality. While the Iliceto Shield Wire Scheme (ISWS) offers a modern cost-effective solution, voltage stability remains a challenge. This study analyses voltage profile enhancement within ISWS, focusing on the Chalinze-Mbwewe section of the 132 kV transmission line, using LTSpice simulations. Due to LTSpice limitations, direct solar PV integration was mimicked by introducing a secondary voltage source at each load centre, producing 33 kV to match the original source voltage. This approach maintained improved voltage profile from Msoga Village to Mbwewe over 80.9 Kilometers. …

Load Flow And Fault Performance Evaluation Of Interconnected Minigrids In Uganda Using Digsilent Powerfactory, Prossy Mutesi, Santos Kihwele, Emmanuel Matee

Tanzania Journal of Engineering and Technology (TJET)

The increasing demand for decentralized, reliable electricity in rural Sub-Saharan Africa has catalyzed the deployment of minigrids as an intermediate electrification strategy. This study investigates two solar photovoltaic (PV) mini-grids: Kyamugarura and Kanyegaramire, located in western Uganda, approximately 3km apart. Each mini grid initially consisted of 13 kW installed photovoltaic (PV) capacity, supplying power to households and small businesses. Due to rising demand and regular evening blackouts, both mini-grids are being upgraded to 57 kWp each. The integration of these upgraded systems into the national utility grid is proposed and simulated to evaluate performance improvements under two medium-voltage interconnection options: …

Hybrid Solar - Coal Thermal Energy System For Industrial Process Heat At Sayona Drinks Limited In Tanzania, Santos Kihwele, Elisha D. Bitesigirwe

Tanzania Journal of Engineering and Technology (TJET)

Over the past two decades, global efforts to mitigate pollution from conventional energy sources have intensified, with coal remaining a major contributor to carbon emissions. While fossil fuels cannot be eliminated from thermal generation in manufacturing industries, particularly in middle‑income countries such as Tanzania, they continue to dominate as the primary energy source. Industries including food and beverage, paper, textile, paints, chemicals, and pharmaceuticals require substantial thermal energy for heating and drying, and typically rely on coal and natural gas.This study introduces a unique application of a parabolic trough solar thermal system with integrated thermal energy storage, specifically tailored to …

Modeling And Optimization Of Li-Ion Battery Recycling Process, Wang Lingling, Zhou Panpan, Ma Yulong

Dianchi(Changsha)

No abstract provided.

Review On Capacity Degradation Mechanisms And Lifetime Prediction Of Energy Storage Li-Ion Battery, Ma Yue, Chen Yanqiao, Wang Chu, Wang Xianwen, Liu Hui, Chen Yifei, Chen Lai, Yan Kang, Su Yuefeng

Dianchi(Changsha)

No abstract provided.

Opportunities And Challenges Of Cross-Border E-Commerce In Li-Ion Batteries, Ma Jingjing, Chen Xianyi

Dianchi(Changsha)

No abstract provided.

Decarbonizing Electrical Substations: An Integrative Review Of Green Technologies And Sustainable Practices Across The Infrastructure Life Cycle, Sulthan Syah Ali, Mohammed Ali Berawi, Mustika Sari

Smart City

Decarbonization of electrical infrastructure s becoming increasingly important in efforts to meet climate change mitigation targets, particularly in reducing emissions from substations. However, conventional substations continue to release significant quantities of GHG emissions throughout their life cycle As an example, a typical 500 kV substation emits around 150,000 tCO2e from construction to decommissioning. In addition, the development of green substation concepts remains limited, particularly in Indonesia where standardized approaches are not yet established. In response to the need for more sustainable power infrastructure, this study aims to identify, classify, and review all types of green technologies, practices, and innovations that …

Techno-Economic And Environmental Analysis Of Wind-Powered Green Hydrogen Production In Nigeria, Ignatius Kema Okakwu, Ayodeji Akinsoji Okubanjo, Samson Oladayo Ayanlade, Akintunde Samson Alayande, Solomon Olanrewaju Giwa, Abraham Olatide Amole, Etinosa Noma-Osaghe, Ajibola Oluwafemi Oyedeji

Al-Bahir

Green hydrogen is becoming a viable option for clean energy, and the need to reduce greenhouse gas emissions has also become a popular sustainable energy source. In this paper, we evaluate the technoeconomic and environmental feasibility of green hydrogen production from wind energy in five Nigerian cities: Kano, Jos, Maiduguri, Ikeja, and Ikorodu. Energy potential from wind energy is estimated by using the Weibull distribution method, and six wind turbines are used to calculate electricity generation and hydrogen production. Economics of wind power are estimated through levelized cost of energy (LCOE), levelized cost of hydrogen (LCOH), payback period (PBP), and …

Modelling And Analysis Of 50 Mwp Solar Pv Integration Into Tanzania’S Transmission Network: A Case Study Of Tagamenda Substation, Iringa Region, Santos Kihwele

Tanzania Journal of Science

While increasing the share of renewable energy in the grid, grid integration studies for the utility solar photovoltaic (PV) plants are vital, given their intermittency and the fact that Tanzania has never had one connected to the grid. This paper presents a 50 MWp grid integration study, including a technical analysis conducted using PSS®E software. The study investigates the grid behaviour during the integration of the 50 MWp solar plant, considering the most suitable technical and economic solutions. The study analysed the load flow under normal conditions, contingency analysis (N-1), short- circuit analysis, and voltage stability assessment. The results show …

Load Profile Analysis And Forecasting For Rural Mini Grids In Uganda, Prossy Mutesi, Santos L. Kihwele, Emmanuel S. Matee

Tanzania Journal of Science

Accurate load forecasting is essential for the reliable and cost-effective operation of rural mini grids, where constrained generation capacity and high penetration of renewable energy resources require well-informed operational decisions. This study examines electricity demand characteristics and forecasting performance for the Buzaami and Ssenyondo mini grids in Uganda, with particular focus on diurnal load profiles, peak demand behavior, and seasonal variability. 2022 operational data show extended peak demand from early morning to late evening, driven by socio-economic activities that strain resource scheduling and reliability management. To address these challenges, the study evaluates and compares Long Short-Term Memory (LSTM) networks, fuzzy …

Modulating Electronic Structure With Linearly Fused Pyrazine Units For High-Voltage And Stable Zinc-Organic Batteries Cathode, Min-Jian Zhao, Li-Bin Zhang, Jin-Tao Wang, Kun Ding, Hai-Mei Liu, Yong-Gang Wang

Journal of Electrochemistry

High-voltage n-type organic cathode materials are critical for constructing zinc-organic batteries (ZOBs) with high energy density and long cycle life. However, the intrinsically unfavorable electronic structures and relatively high LUMO energy levels of most n-type materials often lead to sluggish kinetics, high solubility, and suboptimal discharge voltages (< 0.8 V). Here, we design a small molecule, quinoxalino[2’,3’:5,6]pyrazino[2,3-f][1,10]phenanthroline (DPQP), as a ZOB cathode by introducing locally electron-deficient motifs into the conjugated backbone of aromatic compounds. The linearly fused pyrazine units extending the pyrazine–benzene framework effectively optimize the electronic structure, thereby significantly enhancing the discharge voltage. Meanwhile, the expanded π-conjugated plane suppresses dissolution and accelerates charge-transfer kinetics. Benefiting from these features, the DPQP electrode exhibits an exceptional increase in average operating voltage from 0.61 V to 1.07 V (vs. Zn²⁺/Zn) at 0.1 A·g^–1, with an overpotential of only 140 mV. Notably, no discernible voltage decay occurs as the current density increases, indicating rapid and highly reversible redox kinetics. Furthermore, the DPQP cathode delivers outstanding cycling stability, maintaining over 2000 h of continuous operation at 0.1 A·g^{–1 …}

(Co,Ni,Mn,Cu,Zn)O High-Entropy Oxide Nanotubes As Efficient Bifunctional Electrocatalyst For Oxygen Evolution And Hydrazine Oxidation Reactions, Pan-Yan Chen, Wan-Wan Wu, Heng Bian, Wei-Wei Li, Xin-Sheng Zhao, Lu Wei

Journal of Electrochemistry

High-entropy oxides (HEOs) present significant scientific challenges in both design and synthesis due to their multielement and high-entropy nature, which involves complex combinations of multiple metal cations and oxygen anions, typically arranged in equimolar ratios to achieve structural stability. Herein, one-dimensional (Co,Ni,Mn,Cu,Zn)O high-entropy oxide nanotubes (HEO-NTs) are fabricated by means of a gradient electrospinning strategy with a tailored polyvinyl alcohol (PVA) molecular weight distribution and controlled pyrolysis. Benefiting from the HEO features and the synergistic effect of multicomponent sites, the as-synthesized (Co,Ni,Mn,Cu,Zn)O HEO-NTs exhibit exceptional bifunctional electrocatalytic activity for the oxygen evolution and hydrazine oxidation reactions (OER/HzOR). This study offers …

Les Grands Chantiers De La Transition Énergétique Au Maroc: Le Cas De Dakhla-Oued Eddahab Entre Réalisations, Facteurs De Réussite Et Perspectives, Limam Boussif, Jalila Ait Soudane

Journal of Maya Heritage

Résumé: Cet article examine la dynamique de la transition énergétique au Maroc à travers une analyse descriptive et analytique du cas de Dakhla-Oued Eddahab. Dans un contexte marqué par l’accélération des politiques de décarbonation à l’échelle mondiale, le Maroc s’impose comme un acteur stratégique en matière de développement des énergies renouvelables et de l’hydrogène vert. L’étude met en lumière les principaux chantiers structurants engagés dans la région de Dakhla, notamment le développement des énergies éolienne et solaire, les projets de production d’hydrogène vert, le dessalement de l’eau de mer, ainsi que la réalisation du port Dakhla Atlantique. L’analyse montre que …

Characteristics And Implementation Paths Of Goal For Building Energy Powerhouse, Liye Xiao, Jiaofeng Pan, Xiaojiong Wang, Deqiang Sun, Mingliang Qi, Jianlei Mo, Huimin Li, Ting Wang, Jie Yang, Jie Lin, Yuchao Wang, Haiting Chen

Bulletin of Chinese Academy of Sciences (Chinese Version)

China is a major energy-consuming country, and ensuring effective energy supply is one of the core tasks for promoting national development and national rejuvenation. To guarantee national energy supply and energy security, and to vigorously develop and utilize clean and low-carbon energy, the Outline of the 15th Five-Year Plan for National Economic and Social Development of the People’s Republic of China clearly states: “We will thoroughly implement the new energy security strategy, accelerate the construction of a clean, low-carbon, safe, and efficient new energy system, and build a strong energy nation. We will promote the safe, reliable, and orderly replacement …

Molecular Catalysts For Electrochemical Nitrogen Activation Toward Sustainable Ammonia Synthesis, Jin-Xiu Han, Hao Xue, Xian-Biao Fu

Journal of Electrochemistry

Homogeneous electrocatalytic nitrogen reduction reaction (NRR) provides a powerful framework to interrogate molecular nitrogen-fixation pathways under mild conditions. By tuning the metal center, ligand architecture, and reaction medium, these systems enable capturing key intermediates and delivering mechanistic insight at the molecular-level resolution. Nevertheless, advances remain constrained by highly reduced operating potentials, intense competition from the hydrogen evolution reaction (HER), limited durability in turnover, and inadequate long-term stability.

In this review, we take electron delivery to the molecular active site as the guiding principle for organizing homogeneous electrochemical N₂ activation and transformation. We classify reported systems into direct electron transfer …

Water-Driven Solid Electrolyte Interphase Governs Continuous-Flow Ammonia Electrosynthesis, Peng-Bo Liu, Sheng-Liang Zhai, Ji Huang, Zhong-Shuo Zhang, Jie Zeng, Shao-Feng Li

Journal of Electrochemistry

Flow-cell architectures have emerged as a powerful platform for continuous and stable lithium-mediated nitrogen reduction (Li-NRR), enabling ambient-condition electrochemical ammonia synthesis and offering a promising alternative to Haber-Bosch processes. However, Li-NRR is exceptionally sensitive to trace water, and even minor variations in water content can profoundly alter interfacial chemistry. Here, we systematically investigate how initial water concentration affects Li-NRR performance in a continuous-flow cell. Excess water drives the formation of a thick solid electrolyte interphase (SEI) layer, which may impede nitrogen access to metallic lithium and hinder lithium-ion transport. As a result, the ammonia Faradaic efficiency collapses from ~61% to …

Insertion Of Noble Metal Free Cathodic Catalyst Layer With Fe-N-C Catalyst For Boosted Performance Of Pemfc, Shi Zhou, Muhammad Tariq, Asif Nadeem Tabish, Muhammad Salman, Fan-Di Ning, Muhammad Rayyan Tayyab, Ran-Ran Peng, Meng-Geng Hao, Wen-Mu Li, Xiao-Chun Zhou

Journal of Electrochemistry

Economical Fe-N-C catalysts are considered as promising alternatives to platinum group metal catalysts for proton exchange membrane fuel cells (PEMFCs). Despite exhibiting robust activity on rotating disk electrodes, their performance within membrane electrode assemblies often experiences limitations, such as decreased O₂ diffusion, high H₂O₂ formation, low proton conduction, and a lower electron transfer number. In this study, key factors, including proton transport, electron conduction, and gas diffusion within air-breathing PEMFCs, have been investigated by adjusting cathode catalyst layer (CCL) compositions. From the experimental results, the optimal peak power density was obtained when the loading of Fe-N-C …