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Articles 1471 - 1500 of 2339
Full-Text Articles in Optics
Growth And Characterization Of Zno Based Semiconductor Materials And Devices, Ming Wei
Growth And Characterization Of Zno Based Semiconductor Materials And Devices, Ming Wei
Electronic Theses and Dissertations
Wide band gap semiconductors such as MgxZn1-xO represent an excellent choice for making optical photodetectors and emitters operating in the UV spectral region. High crystal and optical quality MgxZn1-xO thin films were grown epitaxially on c-plane sapphire substrates by plasma-assisted Molecular Beam Epitaxy. ZnO thin films with high crystalline quality, low defect and dislocation densities, and sub-nanometer surface roughness were achieved by applying a low temperature nucleation layer. The critical growth conditions were discussed to obtain a high quality film: the sequence of Zn and O sources for initial growth of nucleation layer, growth temperatures for both ZnO nucleation and …
Iupac Critical Evaluation Of The Rotational-Vibrational Spectra Of Water Vapor, Part Iii: Energy Levels And Transition Wavenumbers For H216o, Jonathan Tennyson, Peter F. Bernath, Linda R. Brown, Alain Campargue, Attila G. Csaszar, Ludovic Daumont, Robert R. Gamache, Joseph T. Hodges, Olga V. Naumenko, Oleg L. Polyansky
Iupac Critical Evaluation Of The Rotational-Vibrational Spectra Of Water Vapor, Part Iii: Energy Levels And Transition Wavenumbers For H216o, Jonathan Tennyson, Peter F. Bernath, Linda R. Brown, Alain Campargue, Attila G. Csaszar, Ludovic Daumont, Robert R. Gamache, Joseph T. Hodges, Olga V. Naumenko, Oleg L. Polyansky
Chemistry & Biochemistry Faculty Publications
This is the third of a series of articles reporting critically evaluated rotational-vibrational line positions, transition intensities, and energy levels, with associated critically reviewed labels and uncertainties, for all the main isotopologues of water. This paper presents experimental line positions, experimental-quality energy levels, and validated labels for rotational-vibrational transitions of the most abundant isotopologue of water, H216O. The latest version of the MARVEL (Measured Active Rotational-Vibrational Energy Levels) line-inversion procedure is used to determine the rovibrational energy levels of the electronic ground state of H216O from experimentally measured lines, together with their self-consistent uncertainties, …
Injection Locking Of Semiconductor Mode-Locked Lasers For Long-Term Stability Of Widely Tunable Frequency Combs, Charles Williams
Injection Locking Of Semiconductor Mode-Locked Lasers For Long-Term Stability Of Widely Tunable Frequency Combs, Charles Williams
Electronic Theses and Dissertations
Harmonically mode-locked semiconductor lasers with external ring cavities offer high repetition rate pulse trains while maintaining low optical linewidth via long cavity storage times. Single frequency injection locking generates widely-spaced and tunable frequency combs from these harmonically mode-locked lasers, while stabilizing the optical frequencies. The output is stabilized long-term with the help of a feedback loop utilizing either a novel technique based on Pound-Drever-Hall stabilization or by polarization spectroscopy. Error signals of both techniques are simulated and compared to experimentally obtained signals. Frequency combs spaced by 2.5 GHz and ~10 GHz are generated, with demonstrated optical sidemode suppression of unwanted …
Mesoscale Light-Matter Interactions, Kyle Douglass
Mesoscale Light-Matter Interactions, Kyle Douglass
Electronic Theses and Dissertations
Mesoscale optical phenomena occur when light interacts with a number of different types of materials, such as biological and chemical systems and fabricated nanostructures. As a framework, mesoscale optics unifies the interpretations of the interaction of light with complex media when the outcome depends significantly upon the scale of the interaction. Most importantly, it guides the process of designing an optical sensing technique by focusing on the nature and amount of information that can be extracted from a measurement. Different aspects of mesoscale optics are addressed in this dissertation which led to the solution of a number of problems in …
Fabrication Of Metallic Antenna Arrays Using Nanoimprint Lithography, Yu-Wei Lin
Fabrication Of Metallic Antenna Arrays Using Nanoimprint Lithography, Yu-Wei Lin
Electronic Theses and Dissertations
This Thesis describes the development of a cost-effective process for patterning nanoscale metal antenna arrays. Soft ultraviolet (UV) Nanoimprint Lithography (NIL) into bilayer resist was chosen since it enables repeatable large-scale replication of nanoscale patterns with good lift-off properties using a simple low-cost process. Nanofabrication often involves the use of Electron Beam Lithography (EBL) which enables the definition of nanoscale patterns on small sample regions, typically < 1 mm 2 . However its sequential nature makes the large scale production of nanostructured substrates using EBL cost-prohibitive. NIL is a pattern replication method that can reproduce nanoscale patterns in a parallel fashion, allowing the low-cost and rapid production of a large number of nanopatterned samples based on a single nanostructured master mold. Standard NIL replicates patterns by pressing a nanostructured hard mold into a soft resist layer on a substrate resulting in exposed substrate regions, followed by an optional Reactive Ion Etching (RIE) step and the subsequent deposition of e.g. metal onto the exposed substrate area. However, non-vertical sidewalls of the features in the resist layer resulting from an imperfect hard mold, from reflow of the resist layer, or from isotropic etching in the RIE step iii may cause imperfect lift-off. To overcome this problem, a bilayer resist method can be used. Using stacked resist layers with different etch rates, undercut structures can be obtained after the RIE step, allowing for easy lift-off even when using a mold with non-vertical sidewalls. Experiments were carried out using a nanostructured negative SiO2 master mold. Various material combinations and processing methods were explored. The negative master mold was transferred to a positive soft mold, leaving the original master mold unaltered. The soft mold consisted of a 5 m thick top Poly(methyl methacrylate) (PMMA), or Polyvinyl alcohol (PVA) layer, a 1.5 mm thick Polydimethylsiloxane (PDMS) buffer layer, and a glass supporting substrate. The soft mold was pressed into a bilayer of 300 nm PMMA and 350 nm of silicon based UV-curable resist that was spin-coated onto a glass slide, and cured using UV radiation. The imprinted patterns were etched using RIE, exposing the substrate, followed by metal deposition and lift-off. The experiments show that the use of soft molds enables successful pattern transfer even in the presence of small dust particles between the mold and the resist layer. Feature sizes down to 280 nm were replicated successfully
Volume Phase Masks In Photo-Thermo-Refractive Glass, Marc Segall
Volume Phase Masks In Photo-Thermo-Refractive Glass, Marc Segall
Electronic Theses and Dissertations
In many applications such as beam shaping, mode conversion, and phase encoding it is necessary to alter the spatial phase profile of a beam via a phase mask. Conventional techniques to accomplish this either involve surface relief profiling in thin films such as PMMA or refractive index modulation in bulk photorefractive crystals such as lithium niobate. These materials have been used extensively for the past several decades and perform admirably in low power conditions. However, in high power systems these materials will be destroyed, requiring a new means of producing phase masks. In this dissertation a method for producing robust …
Phase-Locking Stability Of A Quasi-Single-Cycle Pulse, Nathan Bodnar
Phase-Locking Stability Of A Quasi-Single-Cycle Pulse, Nathan Bodnar
Electronic Theses and Dissertations
There is increasing interest in the generation of very short laser pulses, even down to attosecond (10-18 s) durations. Laser systems with femtosecond pulse durations are needed for these applications. For many of these applications, positioning of the maximum electric field within the pulse envelope can affect the outcome. The peak of the electric field relative to the peak of the pulse is called the Carrier Envelope Phase (CEP). Controlling the position of the electric field becomes more important when pulse duration approaches single-cycle. This thesis focuses on the stabilization of a quasi-single-cycle laser facility. Improvements to this already-established laser …
Simulation Studying Effects Of Multiple Primary Aberrations On Donut-Shaped Gaussian Beam, Chen Zhang, K. Wang, J. Bai, Y. Liu, Guiren Wang
Simulation Studying Effects Of Multiple Primary Aberrations On Donut-Shaped Gaussian Beam, Chen Zhang, K. Wang, J. Bai, Y. Liu, Guiren Wang
Faculty Publications
In this paper, we demonstrate the variation of donut-shaped depletion pattern which influenced by multiple primary aberrations. The simulation is base on a common stimulation emission of depletion (STED) system composed by Gaussian laser and vortex phase plate. The simulation results are helpful guidelines for analyzing the aberration of depletion patterns in real situations.
Investigation Of Colored Dissolved Organic Matter (Cdom) Optical Properties, Nutrients, And Salinity In Coastal Florida: Springshed To Estuaries, Ana Rosa Arellano
Investigation Of Colored Dissolved Organic Matter (Cdom) Optical Properties, Nutrients, And Salinity In Coastal Florida: Springshed To Estuaries, Ana Rosa Arellano
USF Tampa Graduate Theses and Dissertations
Optical parameters measured via absorption spectroscopy and high-resolution fluorescence spectroscopy were used to characterize dissolved organic matter (DOM) in the springshed of Kings Bay, a spring-fed estuary located on Florida's Springs Coast. Over the past 40 years, springs supplying groundwater to Kings Bay have shown an increase in nitrate concentration. The overall goal of this project was to fingerprint wells and spring sites with elevated nitrogen concentrations using CDOM optical properties and establish relationships between nutrient and optical parameters. Samples were obtained from various sites: springs, Kings Bay surface (KBS), wells, coastal waters in and at the mouth of Crystal …
Nonlinear Effects In Magnetic Garnet Films And Nonreciprocal Optical Bloch Oscillations In Waveguide Arrays, Pradeep Kumar
Nonlinear Effects In Magnetic Garnet Films And Nonreciprocal Optical Bloch Oscillations In Waveguide Arrays, Pradeep Kumar
Dissertations, Master's Theses and Master's Reports - Open
This dissertation presents detailed experimental and theoretical investigations of nonlinear and nonreciprocal effects in magnetic garnet films. The dissertation thus comprises two major sections. The first section concentrates on the study of a new class of nonlinear magneto-optic thin film materials possessing strong higher order magnetic susceptibility for nonlinear optical applications. The focus was on enlarging the nonlinear performance of ferrite garnet films by strain generation and compositional gradients in the sputter-deposition growth of these films. Under this project several bismuth-substituted yttrium iron garnet (Bi,Y) 3 (Fe,Ga)5 O12(acronym as Bi:YIG) films have been sputter-deposited over gadolinium gallium …
Optical Waveguides And Structures For Short Haul Optical Communication Channels Within Printed Circuit Boards, Nicholas J. Riegel
Optical Waveguides And Structures For Short Haul Optical Communication Channels Within Printed Circuit Boards, Nicholas J. Riegel
Dissertations, Master's Theses and Master's Reports - Open
Optical waveguides have shown promising results for use within printed circuit boards. These optical waveguides have higher bandwidth than traditional copper transmission systems and are immune to electromagnetic interference. Design parameters for these optical waveguides are needed to ensure an optimal link budget. Modeling and simulation methods are used to determine the optimal design parameters needed in designing the waveguides. As a result, optical structures necessary for incorporating optical waveguides into printed circuit boards are designed and optimized.
Embedded siloxane polymer waveguides are investigated for their use in optical printed circuit boards. This material was chosen because it has low …
Modeling Of Mouse Eye And Errors In Ocular Parameters Affecting Refractive State, Gurinder Bawa
Modeling Of Mouse Eye And Errors In Ocular Parameters Affecting Refractive State, Gurinder Bawa
Wayne State University Dissertations
ABSTRACT
MODELING OF MOUSE EYE AND ERRORS IN OCULAR PARAMETERS AFFECTING REFRACTIVE STATE
by
GURINDER BAWA
September 2013
Advisor: Dr. Ivan Avrutsky
Major: Electrical Engineering
Degree: Doctor of Philosophy
Rodents eye are particularly used to study refractive error state of an eye and development of refractive eye. Genetic organization of rodents is similar to that of humans, which makes them interesting candidates to be researched upon. From rodents family mice models are encouraged over rats because of availability of genetically engineered models. Despite of extensive work that has been performed on mice and rat models, still no one is able …
Mode-Division Multiplexed Transmission In Few-Mode Fibers, Neng Bai
Mode-Division Multiplexed Transmission In Few-Mode Fibers, Neng Bai
Electronic Theses and Dissertations
As a promising candidate to break the single-mode fiber capacity limit, mode-division multiplexing (MDM) explores the spatial dimension to increase transmission capacity in fiberoptic communication. Two linear impairments, namely loss and multimode interference, present fundamental challenges to implementing MDM. In this dissertation, techniques to resolve these two issues are presented. To de-multiplex signals subject to multimode interference in MDM, Multiple-InputMultiple-Output (MIMO) processing using adaptive frequency-domain equalization (FDE) is proposed and investigated. Both simulations and experiments validate that FDE can reduce the algorithmic complexity significantly in comparison with the conventional time-domain equalization (TDE) while achieving similar performance as TDE. To further …
Development Of Thulium Fiber Lasers For High Average Power And High Peak Power Operation, Robert Sims
Development Of Thulium Fiber Lasers For High Average Power And High Peak Power Operation, Robert Sims
Electronic Theses and Dissertations
High power thulium fiber lasers are useful for a number of applications in both continuous-wave and pulsed operating regimes. The use of thulium as a dopant has recently gained interest due to its large bandwidth, possibility of high efficiency, possibility of high power and long wavelength ~1.8 – 2.1 μm. The longer emission wavelength of Tm-doped fiber lasers compared to Yb- and/or Er-doped fiber lasers creates the possibility for higher peak power operation due to the larger nonlinear thresholds and reduced nonlinear phase accumulation. One primary interest in Tm-doped fiber lasers has been to scale to high average powers; however, …
Active Optimal Control Strategies For Increasing The Efficiency Of Photovoltaic Cells, Sharif Aljoaba
Active Optimal Control Strategies For Increasing The Efficiency Of Photovoltaic Cells, Sharif Aljoaba
Theses and Dissertations--Electrical and Computer Engineering
Energy consumption has increased drastically during the last century. Currently, the worldwide energy consumption is about 17.4 TW and is predicted to reach 25 TW by 2035. Solar energy has emerged as one of the potential renewable energy sources. Since its first physical recognition in 1887 by Adams and Day till nowadays, research in solar energy is continuously developing. This has lead to many achievements and milestones that introduced it as one of the most reliable and sustainable energy sources. Recently, the International Energy Agency declared that solar energy is predicted to be one of the major electricity production energy …
Absorptive And Refractive Optical Nonlinearities In Organic Molecules And Semiconductors, Davorin Peceli
Absorptive And Refractive Optical Nonlinearities In Organic Molecules And Semiconductors, Davorin Peceli
Electronic Theses and Dissertations
The main purpose of this dissertation to investigate photophysical properties, third order nonlinearity and free carrier absorption and refraction in organic materials and semiconductors. Special emphasis of this dissertation is on characterization techniques of molecules with enhanced intersystem crossing rate and study of different approaches of increasing triplet quantum yield in organic molecules. Both linear and nonlinear characterization methods are described. Linear spectroscopic characterization includes absorption, fluorescence, quantum yield, anisotropy, and singletoxygen generation measurements. Nonlinear characterization, performed by picosecond and femtosecond laser systems (single and double pump-probe and Z-scan measurements), includes measurements of the triplet quantum yields, excited-state absorption, two-photon …
Non-Degenerate Two Photon Gain In Bulk Gallium Arsenide, Brendan Turnbull
Non-Degenerate Two Photon Gain In Bulk Gallium Arsenide, Brendan Turnbull
Electronic Theses and Dissertations
The purpose of this thesis is to investigate the nonlinear phenomena known as doubly-stimulated, non-degenerate two-photon emission (ND-2PE) in Gallium Arsenide (GaAs). 2PE refers to the simultaneous emission of two-photons as electrons move from the conduction band in a direct gap semiconductor to the valence band. Following the same path for describing one-photon emission (1PE) we describe 2PE as a product of the irradiance, and the negative of the loss which in this case is two-photon absorption, , the negative coming from the population inversion. We attempt to observe 2PE by using a frequency non-degenerate pump-probe experiment in which a …
Properties Of High Energy Laser Light Transmission Through Large Core Optical Cables, Christopher Kennedy
Properties Of High Energy Laser Light Transmission Through Large Core Optical Cables, Christopher Kennedy
Electronic Theses and Dissertations
Laser induced damage is of interest in studying the transmission of large amounts of optical energy through step-index, large core multimode fibers. Optical fibers often have to be routed around objects when laser light is being transmitted between two locations which require the fiber to bend into a curve. Depending on how tight the bend is, this can result in transmission losses or even catastrophic damage when the energy density of the laser pulse exceeds the damage threshold of silica glass. The purpose of this study is to: Establish a minimum bend radius that would allow high energy (GW/cm2 ) …
Beam Deflection, Matthias Münnich,
Beam Deflection, Matthias Münnich,
Electronic Theses and Dissertations
In order to fully understand the third order nonlinear optical response of materials under high irradiance excitation it is necessary to study the temporal and polarization dependence of nonlinear refraction and absorption. There are several existing approaches such as Z-scan and pump-probe techniques to determine those responses. As part of this work, these approaches will be briefly outlined before presenting beam deflection, applied from photothermal beam deflection, as an alternative experimental technique to determine the nonlinear refraction with its temporal and polarization dynamics. This technique measures the angle of the probe beam deflected via the index gradient of the material …
Wavelength Scale Resonant Structures For Integrated Photonic Applications, Matthew Weed
Wavelength Scale Resonant Structures For Integrated Photonic Applications, Matthew Weed
Electronic Theses and Dissertations
An approach to integrated frequency-comb filtering is presented, building from a background in photonic crystal cavity design and fabrication. Previous work in the development of quantum information processing devices through integrated photonic crystals consists of photonic band gap engineering and methods of on-chip photon transfer. This work leads directly to research into coupled-resonator optical waveguides which stands as a basis for the primary line of investigation. These coupled cavity systems offer the designer slow light propagation which increases photon lifetime, reduces size limitations toward on-chip integration, and offers enhanced light-matter interaction. A unique resonant structure explained by various numerical models …
The Impact Of Growth Conditions On Cubic Znmgo Ultraviolet Sensors, Ryan Boutwell
The Impact Of Growth Conditions On Cubic Znmgo Ultraviolet Sensors, Ryan Boutwell
Electronic Theses and Dissertations
Cubic Zn1-xMgxO (c-Zn1-xMgxO) thin films have opened the deep ultraviolet (DUV) spectrum to exploration by oxide optoelectronic devices. These extraordinary films are readily wet-etch-able, have inversion symmetric lattices, and are made of common and safe constituents. They also host a number of new exciting experimental and theoretical challenges. Here, the relation between growth conditions of the c-Zn1-xMgxO film and performance of fabricated ultraviolet (UV) sensors is investigated. Plasma-Enhanced Molecular Beam Epitaxy was used to grow Zn1-xMgxO thin films and formation conditions were explored by varying the growth temperature, Mg source flux, oxygen flow rate, and radio-frequency (RF) power coupled into …
Development Of Laser Spectroscopy For Elemental And Molecular Analysis, Yuan Liu
Development Of Laser Spectroscopy For Elemental And Molecular Analysis, Yuan Liu
Electronic Theses and Dissertations
Laser-Induced Breakdown Spectroscopy (LIBS) and Raman spectroscopy are still growing analytical and sensing spectroscopic techniques. They significantly reduce the time and labor cost in analysis with simplified instrumentation, and lead to minimal or no sample damage. In this dissertation, fundamental studies to improve LIBS analytical performance were performed and its fusion with Raman into one single sensor was explored. On the fundamental side, Thomson scattering was reported for the first time to simultaneously measure the electron density and temperature of laser plasmas from a solid aluminum target at atmospheric pressure. Comparison between electron and excitation temperatures brought insights into the …
Optically Isotropic Liquid Crystals For Display And Photonic Applications, Jin Yan
Optically Isotropic Liquid Crystals For Display And Photonic Applications, Jin Yan
Electronic Theses and Dissertations
For the past few decades, tremendous progress has been made on liquid crystal display (LCD) technologies in terms of stability, resolution, contrast ratio, and viewing angle. The remaining challenge is response time. The state-of-the-art response time of a nematic liquid crystal is a few milliseconds. Faster response time is desirable in order to reduce motion blur and to realize color sequential display using RGB LEDs, which triples the optical efficiency and resolution density. Polymer-stabilized blue phase liquid crystal (PS-BPLC) is a strong candidate for achieving fast response time because its self-assembled cubic structure greatly reduces the coherence length. The response …
Inverse Problems In Multiple Light Scattering, John Broky
Inverse Problems In Multiple Light Scattering, John Broky
Electronic Theses and Dissertations
The interaction between coherent waves and material systems with complex optical properties is a complicated, deterministic process. Light that scatters from such media gives rise to random fields with intricate properties. It is common perception that the randomness of these complex fields is undesired and therefore is to be removed, usually through a process of ensemble averaging. However, random fields emerging from light matter interaction contain information about the properties of the medium and a thorough analysis of the scattered light allows solving specific inverse problems. Traditional attempts to solve these kinds of inverse problems tend to rely on statistical …
Reduced Susceptibility Of Deformation Due To Vibrational And Gravitational Effects On A Focus Variable Adaptive Lens, Victoriya Relina
Reduced Susceptibility Of Deformation Due To Vibrational And Gravitational Effects On A Focus Variable Adaptive Lens, Victoriya Relina
Electronic Theses and Dissertations
Orthodox optical devices, such as lenses, mirrors, and prisms, are composed of solidstate materials, which although well studied and implemented ubiquitously are severely limited in their adaptable properties. An arguably new field of adaptive optics has emerged to further expand photonic manipulation competences of optical components. Fluid-based adaptive optical components were introduced as early as 1968 [1]; such components have the ability to change the shape of their interface surface, thus allowing for a variable curvature profile. The method of manipulation varies greatly, as does the range of surface deformations. A solid-state optical component is affected by system vibration variation …
Ytterbium-Doped Fiber-Seeded Thin-Disk Master Oscillator Power Amplifier Laser System, Christina Willis-Ott
Ytterbium-Doped Fiber-Seeded Thin-Disk Master Oscillator Power Amplifier Laser System, Christina Willis-Ott
Electronic Theses and Dissertations
Lasers which operate at both high average power and energy are in demand for a wide range of applications such as materials processing, directed energy and EUV generation. Presented in this dissertation is a high-power 1 μm ytterbium-based hybrid laser system with temporally tailored pulse shaping capability and up to 62 mJ pulses, with the expectation the system can scale to higher pulse energies. This hybrid system consists of a low power fiber seed and pre-amplifier, and a solid state thin-disk regenerative amplifier. This system has been designed to generate high power temporally tailored pulses on the nanosecond time scale. …
High Energy, High Average Power, Picosecond Laser Systems To Drive Few-Cycle Opcpa, Andreas Vaupel
High Energy, High Average Power, Picosecond Laser Systems To Drive Few-Cycle Opcpa, Andreas Vaupel
Electronic Theses and Dissertations
The invention of chirped-pulse amplification (CPA) in 1985 led to a tremendous increase in obtainable laser pulse peak intensities. Since then, several table-top, Ti:sapphire-based CPA systems exceeding the 100 TW-level with more than 10 W average power have been developed and several systems are now commercially available. Over the last decade, the complementary technology of optical parametric chirped-pulse amplification (OPCPA) has improved in its performance to a competitive level. OPCPA allows direct amplification of an almost-octave spanning bandwidth supporting few-cycle pulse durations at center wavelengths ranging from the visible to the mid-IR. The current record in peak power from a …
Pulsed Tm-Fiber Laser For Mid-Ir Generation, Pankaj Kadwani
Pulsed Tm-Fiber Laser For Mid-Ir Generation, Pankaj Kadwani
Electronic Theses and Dissertations
The thulium fiber laser has gained interest due to its long emission wavelength, large bandwidth (~1.8 – 2.1 µm), high efficiencies (~60 %), and high output power levels both in cw as well as pulsed regimes. Applications like remote sensing, machining, medical tissue ablation, and mid-infrared generation benefit from high peak power thulium laser sources. Pulsed thulium fiber laser systems are advancing rapidly towards higher peak power levels and are becoming the preferred sources for these applications. This dissertation work describes the development of novel nanosecond pulsed thulium fiber laser systems with record high peak power levels targeting mid-infrared generation. …
Magneto-Photonic Crystals For Optical Sensing Applications, Neluka Dissanayake
Magneto-Photonic Crystals For Optical Sensing Applications, Neluka Dissanayake
Dissertations, Master's Theses and Master's Reports - Open
Among the optical structures investigated for optical sensing purpose, a significant amount of research has been conducted on photonic crystal based sensors. A particular advantage of photonic crystal based sensors is that they show superior sensitivity for ultra-small volume sensing. In this study we investigate polarization changes in response to the changes in the cover index of magneto-optic active photonic band gap structures. One-dimensional photonic-band gap structures fabricated on iron garnet materials yield large polarization rotations at the band gap edges. The enhanced polarization effects serve as an excellent tool for chemical sensing showing high degree of sensitivity for photonic …
Structural, Optical And Electrical Properties Of Yttrium-Doped Hafnium Oxide Nanocrystalline Thin Films, Abhilash Kongu
Structural, Optical And Electrical Properties Of Yttrium-Doped Hafnium Oxide Nanocrystalline Thin Films, Abhilash Kongu
Open Access Theses & Dissertations
Hafnium oxide (HfO2) has emerged as the most promising high-k dielectric for Metal-Oxide-Semiconductor (MOS) devices and has been highlighted as the most suitable dielectric materials to replace silicon oxide because of its comprehensive performance. In the present research, yttrium-doped HfO2 (YDH) thin films were fabricated using RF magnetron sputter deposition onto Si (100) and quartz with a variable thickness. Cross-sectional scanning electron microscopy coupled with Filmetrics revealed that film thickness values range from 700 A° to 7500 A°. Electrical properties such as AC Resistivity and current-voltage (I-V) characteristics of YDH films were studied. YDH films that were relatively thin (<1500 A°) crystallized in monoclinic phase while thicker films crystallized in cubic phase. The band gap (Eg) of the films was calculated from the optical measurements. The band gap was found to be ∼5.60 eV for monoclinic while it is ∼6.05 eV for cubic phase of YDH films. Frequency dependence of the electrical resistivity (ρac) and the total conductivity of the films were measured. Resistivity decreased (by three orders of magnitude) with increasing frequency from 100 Hz to 1 MHz, attributed due to the hopping mechanism in YDH films. Whereas, while ρac∼1Ω-m at low frequencies (100 Hz), it decreased to ∼ 104 Ω-cm at higher frequencies (1 MHz). Aluminum (Al) metal electrodes were deposited to fabricate a thin film capacitor with YDH layer as dielectric film thereby employing Al-YDH-Si capacitor structure. The results indicate that the capacitance of the films decrease with increasing film thickness. A detailed analysis of the electrical characteristics of YDH films is presented.