Power and Energy Commons^™

Design And Fabrication Of The High Efficient Platinum-Nanoporous Gold Catalysts, Zhao-Na Liu, Jin-Tao Zhang, Fang Tian, Peng-Peng Liu, Hou-Yi Ma, Yi Ding

Journal of Electrochemistry

The nanoporous gold(NPG) electrodes with uniform pore sizes and ligaments were prepared by using a simple dealloying method.The as-prepared NPG showed high catalytic activity towards the oxidation of formic acid and formaldehyde.After tiny amount of platinum was deposited onto the NPG substrate,not only the structure stability of NPG was greatly improved,but also the Pt-Au bimetallic catalysts displayed the better catalytic activity and the stronger poison resistance towards the electrooxidation of small organic molecules than the bulk platinum due to synergistic effect between Au and Pt compositions.

Study On Electrocatalytic Oxidation Of Salbutamol At Carbon Nanotubes Modified Electrode, Ying-Liang Wei, Lu-Ping Zhang, Chen Shao, Hui Feng, Xian-Li Li

Journal of Electrochemistry

The multi-wall carbon nanotubes(MWNT) were dispersed successfully into water in the presence of dihexadecyl hydrogen phosphate(DHP) and a stable well-distributed suspension.A was formed sensor based on the multi-carbon nanotubes film coated glassy carbon electrode was developed.The electrochemical response of salbutamol was studied by square wave voltammetry.The oxidation peak potential of salbutamol at the modified electrode was observed at 0.604 V,which shifted about 40 mV negatively.The peak current increased 4.5 folds,in contrast to that at a bare electrode.Under optimal measurement conditions,there was a good linear relationship between the peak current(Ipa) and salbutamol concentration(C) in the range from 8.3 × 1 0 …

A Study Of Pd-Ir On Nickel Foam Cathode For Aluminum-Hydrogen Peroxide Semi-Fuel Cells, Ding-Wang Zhu, Dan-Dan Chen, Bi-Jin Li, Gui-Ling Wang, Dian-Xue Cao

Journal of Electrochemistry

The Pd-Ir/Ni electrodes were prepared by electrodeposition of Pd and Ir on the porous nickel foam surface.The structure,composition and state of the Pd-Ir catalyst were analyzed using SEM and XPS.The catalytic performance of Pd-Ir/Ni for H₂O₂ electroveduction at different concentrations of H₂O₂ were investigated.A limiting current density of 318 mA/cm² was obtained with 0.4 mol/L H₂O₂.The aluminum-hydrogen peroxide semi-fuel cells using different aluminum alloys as anode and Pd-Ir/Ni as cathode were assembled and tested.It was found that the fuel cell with aluminum-manganese alloy anode demonstrated a maximum power density …

Electrocatalytic Oxidation Of Salicylic Acid At Novel Gold Nanoparticle-Modified Glassy Carbon Electrode, Yan-Ping Cui, Chang-Zhu Yang, Jian Huang, Wen-Hong Pu, Jing-Dong Zhang

Journal of Electrochemistry

A gold nano-particles modified glassy carbon electrode(GNP/GCE) was prepared by the"seed-mediated gold nano-particles growth method".Field emission scanning electron microscopy,ultraviolet-visible(UV-vis) spectroscopy analysis and electroalaylsis were employed to study the morphology and electrochemical performances.The resulting electrode showed excellent electro-catalytic activity toward the oxidation of salicylic acid and the response sensitivity was 1.8 fold than that obtained on GCE.Good linear relationship was obtained between response current and salicylic acid concentration in the range of 5.0 × 10^-7 ~8.0 × 10^-5 mol/L,which could be used in the detection of trace salicylic acid.

Computational Studies Of H2, O2, And Co Adsorption On Pt And Pt-Ru Catalyst Clusters For Hydrogen Fuel Cell Applications, Huy Mai, T.J. Dhilip Kumar, P. Tarakeshwar, Naduvalath Balakrishnan

Undergraduate Research Opportunities Program (UROP)

Previous computational studies of hydrogen fuel cell catalysis primarily focus on single adsorbate and therefore do not reflect the realistic situation. Here we investigated the effect of multiple hydrogen, oxygen, and carbon monoxide adsorption on bimetallic nanoclusters as allowed by computational resources. The criteria of which we studied were adsorption energies, electron densities, electrostatic charges, and HOMO-LUMO energy gaps with respect to each structure. We found that Pt-Ru clusters have better performance than pure Pt clusters early in the adsorption course, and pure Pt clusters are more consistent than Pt-Ru clusters in a sequence of adsorbate introduction.

Congestion Mitigation In Wireless Sensor Networks Using Single-Hop Backpressure Algorithm, Vijay Shekar Mangilipalli Gangu Sham

Electrical & Computer Engineering Theses & Dissertations

Wireless sensor networks consist of a group of small components with limited resources allocated to sense the environment and transmit data to the user or interpreter. This concept is technically evolved from Sensors that are basically used to sense the environment around and collect data based on the sensing application incorporated in them. An extension to functionality of the sensors leads to the concept of sensor networks, where, in addition to gathering information at individual sensors, the data is processed and transmitted to a central station or Base station. This concept of transmitting the information from one node to the …

Modeling Of A Spray Assisted Natural Draft Cooling Tower, Kaunde K

Tanzania Journal of Engineering and Technology (TJET)

Cooling towers are one of the largest heat and mass transfer devices that are in common use. A novel type of cooling tower has been proposed in which air flow rate into the tower is drawn by ejector action of sprays instead of fans as is done in conventional mechanical forced or induced draft cooling towers. This novel design offers the potential of saving the energy cost for driving the fan. The paper presents mathematical models for momentum transfer which is the driving force causing the entrainment of air. Also the heat transfer model for co-current flow of liquid and …

Significance Of Logic Synthesis In Fpga-Based Design Of Image And Signal Processing Systems, Mariusz Rawski, Henry Selvaraj, Bogdan J. Falkowski, Tadeusz Luba

Electrical & Computer Engineering Faculty Research

This chapter, taking FIR filters as an example, presents the discussion on efficiency of different implementation methodologies of DSP algorithms targeting modern FPGA architectures. Nowadays, programmable technology provides the possibility to implement digital systems with the use of specialized embedded DSP blocks. However, this technology gives the designer the possibility to increase efficiency of designed systems by exploitation of parallelisms of implemented algorithms. Moreover, it is possible to apply special techniques, such as distributed arithmetic (DA). Since in this approach, general-purpose multipliers are replaced by combinational LUT blocks, it is possible to construct digital filters of very high performance. Additionally, …

Performance Of Air Breathing Direct Methanol Fuel Cell Under Ambient Condition, Jian-Guo Liu, Jun Gu, Tao Yu, Zhi-Gang Zou, T.S Zhao

Journal of Electrochemistry

The performance of the passive DMFC was systematically investigated under an ambient condition by simulating a wide range of temperature and humidity in a high-quality environmentally controlled room.The results indicated that the performance of the passive DMFC was nearly independent of ambient humidity from 30% to 90% RH and water produced in the cathode was expelled mostly from the cell in a liquid state.Compared with the humidity,the ambient temperature has a significant effect on the performance of the passive DMFC.The power density of 30 mW·cm^-2 were obtained at 40℃,while only 10 mW·cm^-2 at 10 ℃.

Structure And Property Of Molecular Self-Assembled Membrane With Zirconium Ion, Tian-De Wang, Rong Wang, Xia-Qin Wu, Zhi-Gang Guo, Wei-Wei Ji

Journal of Electrochemistry

According to the complex interaction between dodecyl phosphonate and stainless steel surface as well as the zirconium ion,the self-assembled monolayer and double-layer dodecyl phosphonate modified 304 type stainless steel electrode were prepared.The electrodes were characteristiced by static contact angles and electrochemical polarization methods.The results suggested that the double-layer modified stainless steel electrode had better corrosion inhibition effect than the monolayer modified electrode.

Carbon Nanotube Array Electrodes Based Supercapacitors With 3.5v Working Voltage, Hao Zhang, Gao-Ping Cao, Yu-Sheng Yang, Zhen-Nan Gu, Bin Xu, Wen-Feng Zhang

Journal of Electrochemistry

The carbon nanotube arrays(CNTA) were grown directly on the substrates of Ta and stainless steel by chemical vapor deposition.The button-like supercapacitors were fabricated based the CNTA electrodes.The electrochemical performance of CNTA based supercapacitors presentsed high working voltage(3.5 V),long cycle life,and good rate capability.The power and energy densities are were 928 kW·kg^-1 and 19 Wh·kg^-1,respectively(based on the mass of CNTA).

Direct Electrochemistry Of God On Glassy Carbon Electrode Modified With Mesoporous Carbon, Kun-Qi Wang, Lin Zhu, Wei Xing

Journal of Electrochemistry

Glucose oxidase(GOD) is immobilized on glassy carbon electrode mesoporous carbon by simple method.Cyclic voltammetric results indicated that on GOD of the modified electrode a quasi-reversible redox reaction took place(GCE) surface modified at a formal potential of-0.4294 V in 0.1 mol/L phosphate buffer solution(PBS)(pH 7.1).The electrochemical reaction consisted of a two-electron transfer coupled with a two-proton transfer.The GOD can completely catalyze oxidation of glucose via electron transfer intermedia of ferrocene monocarboxylic acid(FMCA) in saturated solutions with N₂.The bioactivity of GOD on the modified electrode with mesoporous carbon was obviously unattacked.

Electroless-Deposition Synthesis Of Highly Active Ptru/C And Ptrusn/C As Anode Catalysts For Defc, Jing Zhu, Yi Su, Hua Ma, Fang-Yi Cheng, Zhan-Liang Tao, Jing Liang, Jun Chen

Journal of Electrochemistry

In this paper,the preparation,characterization,and ethanol electrocatalytic oxidation of Pt_0.5Ru_0.5/C and Pt_0.5Ru_0.15Sn_0.35/C electrocatalysts were reported.The electroless-deposition with sensitization-activation pretreatment was applied to prepare Pt_0.5Ru_0.5/C and Pt_0.5Ru_0.15Sn_0.35/C electrocatalysts. The XRD and TEM analyses showed that the as-prepared catalysts were composed of well-dispersed PtRu or PtRuSn nanoparticles with an average particle size of about 3 nm.The electrochemical measurements demonstrated that the as-prepared Pt_0.5Ru_0.5/C and Pt_0.5Ru_0.15Sn_0.35/C catalysts exhibited much enhanced peak current density for …

Electrocatalytic Performance Of Pt/C And Pt/Wo3/C Catalysts For Methanol Oxidation, Yuan-Yuan Chu, Bing Wu, Ya-Wen Tang, Tian-Hong Lu, Ying Gao

Journal of Electrochemistry

The catalysts of Carbon supported Pt(Pt/C) and carbon supported Pt/WO₃(Pt/WO₃/C) were prepared with liquid phase reduction method.It was found that the catalytic activity and stability of the Pt/WO₃/C catalysts were increased with the addition of WO₃.When the atomic ratio of Pt and W was 1∶1,the best electrocatalytic performance of the Pt/WO₃/C catalyst for the methanol oxidation was obtained.This is attributed to the larger electrochemical surface area of Pt/WO₃/C and the weeker adsorption of CO towards the catalyst.

Preparation And Electrochemical Capacitance Of Spherical-Like Polypyrrole Doped With Heparin Sodium, Hong-Yu Mi, Xiao-Gang Zhang, Su-Dong Yang, Xiang-Guo Ye

Journal of Electrochemistry

Spherical-like polypyrrole with an average diameter of 100 nm as the electrode material for supercapacitor was prepared by a self-assembly process with heparin sodium salt as the dopant at-10 ℃.The morphology and electrochemical properties were characterized by transmission electron microscopy(TEM),cyclic voltammetry(CV),galvanostatic charge/discharge and electrochemical impedance spectroscopy(EIS) measurements.The results showed that the polypyrrole doped with heparin sodium salt exhibited good capacitive behavior.The specific capacitance of single electrode was up to 338 F/g at 3 mA/cm².

Synthesis Of Agv3O8 As High-Capacity Of Cathode Materials For Lithium Secondary Batteries Via A Soft Chemistry Technique, Xiao-Yu Cao, Tao Li, Ling-Ling Xie, Xiang-Yang Yan, Chi-Wei Wang

Journal of Electrochemistry

The layered cathode material of AgV₃O₈ has been prepared for the lithium secondary batteries via the soft chemistry technique. The so-synthesized powders were characterized by XRD(powder X-ray diffraction), SEM(scanning electron microscope) and LPSA(laser particle size analysis). The electrochemical property was investigated by the galvanostatic discharge-charge technique. The results indicated that the particale sizes of AgV₃O₈ prepared were small in the distribution of narrow range, which leads to high discharge capacity. Among them, the material synthesized at 400 ℃ displayed the first discharge capacity of 760.5 mAh/g.

The Effect Of Annealed Temperature On Properties Of Ru-Ir-Sn Oxide Anode Coatings, Lei Ji, Jun-Tao Wang, Li-Kun Xu, Wen-Bin Liu, Gui-Lin Xue

Journal of Electrochemistry

The anode coatings of Ru-Ir-Sn oxide were prepared by sol-gel method with different annealed temperatures.The influences of annealed temperature in properties of anode coatings were characterized by scanning electron microscope(SEM),energy dispersive X-ray detector(EDX),X-ray diffraction(XRD),potential of chlorine evolution,accelerated life,cyclic voltammetry and electrochemical impedance spectroscopy(EIS) tests.The results showed that the annealed temperature affected the morphology of coatings,while the electric quantities of cyclic voltammetry and double layer capacitances of anode coatings had a tendency to fall down and the potential of chlorine evolution and accelerated life had a tendency to increase as the annealed temperature increased.

Preparation And Photoelectrochemical Properties Of Fe-Doped Tio2 Nanotube Arrays, Jing Li, Lan Sun, Hui-Fang Zhuang, Cheng-Lin Wang, Rong-Gui Du, Chang-Jian Lin

Journal of Electrochemistry

The Fe-doped TiO₂ nanotube arrays were fabricated in Fe(NO₃)₃-HF mixing solutions by electrochemical anodic oxidation method,and characterized by FESEM,Raman,XPS and DRS.The effect of Fe concentratiions on photoelectrochemical property of the arrays was also investigated.The diameters and lengths of Fe-doped TiO₂ nanotube arrays were 50~90 nm and about 200 nm,respectively.Compared with the undoped TiO₂ nanotube arrays,the absorption edge of Fe-doped TiO₂ nanotube arrays appeared red shifting.The more Fe content,the larger red shifting,in addition,the photocurrent of Fe-doped TiO₂ nanotube arrays increased obviously.

Electrochemical Performances Of Copper/Activated Carbon Composites, Lan-Ting Li, Qiang Xie, Wen Yan, Yan-Yan Wang, Wen-Wen Xing

Journal of Electrochemistry

The development and improvement of electrode materials can result in the enhancement of the performances of electrochemical capacitor.In this paper various copper/activated carbon composites were prepared in the presence of different amounts(from 0% to 40%) of copper nitrate from bituminous coal.Then different electrodes were prepared from copper oxide,activated carbon and copper/activated carbon composites,respectively,and were characterized by cyclic voltammetry,alternative current(AC) impedance,charge-discharge at constant current and maintenance of the self-potential.The results showed that the proper amount of copper in copper/activated carbon composites positively influenced the electrochemical performances of electrodes,and the capacitance of copper/activated carbon composites was larger than that of the total …

Synthesis And Electrochemical Characteristics Of Li[Li(0.167)Mn(0.583)Ni(0.25)]O2 Cathode Material, Ling-Yan Yu, Wei-Hua Qiu, Fang Lian, Jia-Yuan Huang, Xao-Li Kang, Wei Liu

Journal of Electrochemistry

The cathode material of Li[Li_0.167Mn_0.583Ni_0.25]O₂ was synthesized by low-heat solid state reaction.The results of XRD and FESEM indicated that the powders of the material were well crystallized with the uniform diameters ranging from 60 nm to 100 nm and could be indexed as α-NaFeO₂ structure(R3-m space). Galvanostatic charge-discharge tests showed that the electrode delivered the capacity of about 120 mAh/g with good cyclability when cycled in 2.5~4.4V at 0.5C. When the cut-off potential was set up to 4.6V, the cathode delivered much larger capacities with the maximum of 234 mAh/g. It was …

Nuclear Energy, Steve Kraft

Native American Forum on Nuclear Issues

Abstract:

-Why Nuclear Energy?

-The lesson of the last 20 years in U.S. electricity policy:

– Diversified fuel and technology portfolio is essential

– All fuels and technologies (nuclear, coal, natural gas, renewables, efficiency) have a legitimate role

-The challenge for the future:

– Preserving/restoring diversified portfolio

– Ensuring resource adequacy, particularly in competitive markets

-Expanded use of nuclear energy is part of the answer

– Integrated used fuel management supports nuclear competitiveness

Impacts Of Weather Variations On Energy Consumption Efforts At U.S. Air Force Installations, James S. Griffin

Theses and Dissertations

Energy consumption is a national concern, as evidenced by federal laws aimed toward facility energy conservation measures for federal organizations. Factors, primarily weather variables, that significantly impact energy consumption must be addressed and understood to align resources and programs to meet federal energy reduction goals. An energy model was created and tested to produce an appropriate forecasting tool for energy consumption. Energy demand at Air Force installations primarily depends on climatic conditions, with a small portion attributed to a base level of non-climatic conditions, such as interior lighting and appliance loads. By gathering all energy consumption and meteorological data covering …

Cu Doping Lifepo4 And Its Electrochemical Performance, Ming-Sen Zheng, Shan-Ke Liu, Shi-Gang Sun, Quan-Feng Dong

Journal of Electrochemistry

LiFePO₄ and LiFePO₄ doped with Cu²⁺ ions were synthesized by solid-state reactions.The structure of LiFePO₄ and the Fe valence were analyzed by the XRD(X-ray diffraction) and XPS(X-ray photoelectron spectroscopy) respectively.The Cu doping position in LiFePO₄ is discussed.It has found that the volume of LiFePO₄ by doping Cu²⁺ ions is reduced.The minim Cu²⁺ ions doping does not almost change the binding energy of Fe₂p_1/2 in LiFePO_4.According to the experiment results,we conclude that most of the Cu²⁺ ions substitute the Fe²⁺ ions in LiFePO₄ when a …

A Study On Supercapacitor Based On Aligned Carbon Nanotubes, Xiao-Yan Ye, Yan-Zhi Wang, Hai-Yan Song, Zhuo Sun, Pin-Gang He, Yu-Zhi Fang

Journal of Electrochemistry

Large scale vertically aligned carbon nanotubes(ACNTs) with uniform length and diameter were prepared by the pyrolysis of iron(Ⅱ) phthalocyanine at low pressure.The ACNTs were activated by electrolyte-activation,acid-activation or electrochemical activation.The performance of the capacitor based on activated ACNTs was characterized by cyclic voltammograms which was of rectangular shape,impedence spectroscopy in which the phase is above 80° and the result specific capacitance was 16～32 F/g,which suggest that the ACNTs are the promising material for the supercapacitor.

Preparation And Electrochemical Performance Of Ordered Mesoporous Titanium Phosphate As Cathode Material For Li-Ion Battery, Qiong Wang, Attia Adel, Zhi-Cong Shi, Yong Yang

Journal of Electrochemistry

Ordered porous titanium phosphate materials were prepared by using the surfactant template combined with the sol-gel method. The samples were characterized by small angle X-ray diffraction(SA-XRD) method, N₂ adsorption/desorption techniques,high resolution transmission electron microscopy(HRTEM) and element analysis. It is found that the calcination temperature is a big influence on the porous structure, and electrochemical performance of the titanium phosphate materials, and the mesoporous titanium phosphate showed good performance in the electrochemical test, the first discharge capacity is 94 mAh/g at the current density of 150 mA/g. On the other hand, the no porous material with a low capacity of …

Synthesis Of Adipic Acid From Cyclohexanol By Electrochemical Oxidation Using Cr2O72-/Cr3+ As Indirect Oxidant, Zhen-Hai Liang, Yu-Qing Cui, Hong-Yan Sun

Journal of Electrochemistry

Adipic acid was synthesized by electro-oxidation of cyclohexanol taking Cr₂O₇^2-/Cr³⁺ as indirect oxidant.The best technological conditions were optimized by orthogonal experiment.The optimum condition are as follows: the temperature is 35 ℃,ratio of crude material is n(cyclohexanol)∶n(Cr₂O₇^2-)=0.4∶1 and concentration of H₂SO₄ is 4 mol·L^-1.Under these conditions,the yield of adipic acid can reach 70.29%.Moreover,The effects of concentration of Ag₂SO₄,(NH₄)₂SO₄,H₂SO₄and current density on the formation of Cr₂O₇^2-were also …

Mechanism Of The Cathode Reduction Of Ti(Ⅳ) In Molten Na3Alf6-Alf3, Hai-Bin Sun, Xiu-Rong Zuo, Zhi-Guo Zhong, Xue-Hui Hu

Journal of Electrochemistry

The mechanism of TiO₂ electrode process has been investigated by cyclic voltammetry and chronopotentiometry on the tungsten filament in molten Na₃AlF₆-AlF₃ salts at 990 ℃.The experimental results showed that electrochemical reduction of Ti(Ⅳ) precede were two steps,firstly Ti(Ⅳ) was reduced to Ti(Ⅱ),then Ti(Ⅱ) was reduced to Ti,namely: Ti(Ⅳ)→Ti(Ⅱ)→Ti.

Molten Salt Treatment Of Mno2 And Investigation On Supercapacitor Properties, Ye Chen, Zun-Bo Zhang, Wei Zhang, Liang Liu, Zhi-Min Liu

Journal of Electrochemistry

The MnO₂ prepared by solid phase method is treated by KCl-NaCl-LiCl molten salt system.The XRD patterns indicated that the crystal structures of MnO₂ sample have had the α-MnO₂ and γ-MnO₂ phase,the crystallinity of sample is increased after treated by molten salt.The electrochemical properties were tested by cyclic voltammetry,constant current charge/discharge and AC impedance.The result shows that the supercapacitor performance of the treated material has improved.The specific discharge capacitance of the treated sample are 129.07 F·g^-1,increased by 27.88% compared to 100.94 F·g^-1 of untreated sample.Long cycle life and high coulombic efficiency were also demonstrated …

Potentiometric Response Of Glucose On Mno2-GoX Carbon Paste Electrode, Cai-Juan Wang, Xiao-Ya Hu

Journal of Electrochemistry

A novel carbon paste electrode(CPE) modified with MnO₂ and glucose oxidase(GO_x), is reported. Different factors, such as the effect of supporting electrolyte, pH of solutions,various paste glues, the amount of MnO₂ and temperature, which may influence the determination of H₂O₂ and glucose were tested to optimize. Based on above, potentiometric determination of glucose was achieved in neutral solution and at 35 ℃, the electrode gave a response of 36.12～34.62 mV/pG lucose between 2.0×10^-5 mol·L-1 and 5.2×10^-3 mol·L^-1 with a detection limit of 3.3×10^-6 mol·L^-1. Moreover, this kind …

Square Wave Stripping Voltammetric Behaviors Of Rutin On Glassy Carbon Electrode And Its Application, Jun Hua, Xiao-Ying He, Fang Liao, Qing-Tao Zhu

Journal of Electrochemistry

The electrochemical behaviors of rutin(Rt) at glassy carbon electrode were studied by square wave stripping voltammeter in the presence of 0.1mol·L^-1HAc-NaAc buffer solution(pH=3.0).The sensitive oxidation peak of rutin was observed and which potential peak is 0.46V(vs.SCE).The experimental parameters,such as pH value,deposition potential and deposition time were investigated and selected.The peak currents were proportional to the concentration of rutin in range of 5.0×10^-8 mol·L^-1~1.0×10^-6mol·L^-1,and the linear regression coefficient equaled 0.99799,the detection limit was 1.1×10-8 mol·L^-1.This method was applied to the determination of rutin content in tablet with satisfactory results.